US20110253521A1 - Method for a cyclical operation of coke oven banks comprised of" heat recovery" coke oven chambers - Google Patents
Method for a cyclical operation of coke oven banks comprised of" heat recovery" coke oven chambers Download PDFInfo
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- US20110253521A1 US20110253521A1 US13/138,004 US200913138004A US2011253521A1 US 20110253521 A1 US20110253521 A1 US 20110253521A1 US 200913138004 A US200913138004 A US 200913138004A US 2011253521 A1 US2011253521 A1 US 2011253521A1
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- coke oven
- bank
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- coke
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- 239000000571 coke Substances 0.000 title claims abstract description 435
- 238000000034 method Methods 0.000 title claims abstract description 61
- 238000011084 recovery Methods 0.000 title claims description 17
- 239000002912 waste gas Substances 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 230000002123 temporal effect Effects 0.000 claims abstract description 11
- 238000004939 coking Methods 0.000 claims description 42
- 239000007789 gas Substances 0.000 claims description 30
- 239000003245 coal Substances 0.000 claims description 23
- 238000010791 quenching Methods 0.000 claims description 19
- 230000000171 quenching effect Effects 0.000 claims description 19
- 238000013459 approach Methods 0.000 claims description 11
- 239000002918 waste heat Substances 0.000 claims description 11
- 238000005201 scrubbing Methods 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims 1
- 239000000567 combustion gas Substances 0.000 description 19
- 238000002485 combustion reaction Methods 0.000 description 15
- 238000003763 carbonization Methods 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 6
- 238000000265 homogenisation Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 238000009827 uniform distribution Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000819 phase cycle Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B15/00—Other coke ovens
- C10B15/02—Other coke ovens with floor heating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B21/00—Heating of coke ovens with combustible gases
- C10B21/10—Regulating and controlling the combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B41/00—Safety devices, e.g. signalling or controlling devices for use in the discharge of coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B45/00—Other details
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/04—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being hot slag, hot residues, or heated blocks, e.g. iron blocks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22G—SUPERHEATING OF STEAM
- F22G7/00—Steam superheaters characterised by location, arrangement, or disposition
- F22G7/12—Steam superheaters characterised by location, arrangement, or disposition in flues
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Definitions
- the invention relates to a method for a cyclical operation of coke oven chambers of the “Heat Recovery” type which form part of coke oven banks, said operation particularly relating to the cyclic phases of “charging-coking-pushing” and with the procedures of pushing determining the cycle being so arranged that the production of hot coking gases utilized according to the “Heat Recovery” process for the production of steam and energy is evenly distributed over the temporal mean of the entire coking process, thus substantially improving the production of steam and energy, and in particular of electrical energy downstream of the coking process.
- the coking gas evolving on carbonization can be utilized in different ways.
- the coking gas is captured and utilized in order to recover and exploit the valuable substances contained therein, for example aromatic hydrocarbons, hydrogen, ammonia, and methane.
- the coking gas is utilized to burn it and thereby to generate heat which is exploited for the process of coal carbonization.
- These design types in turn, it is possible to pass the coking gas after combustion and exploitation of the evolving thermal energy without any further use into the environment.
- These design types are called coke ovens of the “Non-Recovery” type.
- Other design types in turn utilize the waste heat to recover steam thereof. This can be utilized, for example, to generate electrical energy.
- These design types are called coke ovens of the “Heat Recovery” type.
- coke ovens The arrangement of coke ovens is basically so taken that between 6 and 34 coke ovens are grouped together to be linked to each other in a major unit, which is also called a coke oven bank. In this manner, the production of coke can be substantially homogenized. Since the coke oven chambers have to be charged to allow for production, the charging procedure can by noticeably simplified and automated by forming groups of several coke oven chambers.
- coal carbonization is accomplished in a “charging-coking-pushing” phase cycle. While the coking cycle still lingers on with some coke oven chambers, other chambers can be charged or pushed. In this manner, a constant output of combustion gas is also achieved.
- Coke pushing is accompanied outside the coke oven chamber on the opposite side of a coke oven chamber by the filling of a coke quenching car.
- the method applied is that a combination of several coke ovens of the “Non-Recovery” type or “Heat Recovery” type is called “oven bank”. Conversely, a combination of conventional coke ovens is called “oven battery”.
- WO 2006/128612 A1 describes a method for carbonization of coal in a coke oven with combustion of coking gas, said coking gas initially streaming into a gas space above the coke cake where it is partly burnt with an understoichiometrical volume of supplied combustion air.
- This process is called primary combustion and it utilizes so-called primary combustion air for combustion.
- Partly burnt coking gas is then passed via so-called “downcomer” channels into a secondary heating space where it is completely burnt with another quantity of supplied combustion air.
- secondary combustion and it utilizes so-called secondary combustion air for combustion. Thereby the lower section of the coke cake is also heated, thus improving the coke quality.
- the invention lays claim to a device and a method for homogenization of the supply of primary combustion air into the gas space above the coke cake, so that heat distribution in the upper section of the coke cake is homogenized and a better coke product is thus obtained.
- the invention is equally exploitable for a coke oven of the “Non-Recovery” or “Heat Recovery” type.
- U.S. Pat. No. 5,968,320 A describes a coke oven of the “Heat-Recovery” type which discharges the raw coking gas from the coke oven and burns it in a boiler system in order to generate heat and electric power.
- the raw coking gas is sprayed for cleaning with a flushing liquor and burnt in a burner where it is exploited to generate steam and mechanical energy. This can be utilized, in turn, to generate electrical energy.
- a negative pressure furnished by installing a suction blower downstream of the combustion chamber is generated in the combustion chamber.
- a control of the quantity of combustion gas is only feasible in a simple manner via a change in cycle times.
- an intermediate arrangement of tanks or accumulator facilities for hot combustion gas is not desired.
- a change in cycle times can only be accomplished via a precisely controlled temporal sequence of the controlled approach to the coke oven chambers. From conventional horizontal-type coking chamber technique, the sequence of such a controlled approach is known under the name “pushing schedule”. It is also determined by the duration of the coal charging procedure and by the maximum travel speed of the oven service machines.
- a precisely planned set-up of a pushing schedule allows for a simple homogenization of the stream of hot combustion gas.
- Combustion gas is understood to cover a gas, too, that is completely burnt and streams out from a coke oven chamber. But it may also be a partly burnt coking gas if it is burnt in the succeeding auxiliary facilities or in the boilers.
- the invention solves this task by providing a device that combines the coke oven chambers of the “Heat Recovery” type in a distinct number to coke oven banks and by providing a method that controllably approaches these coke oven chambers in an exactly determined sequence for coke pushing. Since the so-called “charging-coking-pushing” cycle terminates with the pushing cycle, the entire cycle for the individual coke oven chambers is controlled with the end of this pushing cycle. The temporal approach to the individual coke oven chambers is so accomplished that the temporal duration of the charging and pushing procedures performed without production of hot combustion gas is distributed over all coke oven banks and over all coke oven chambers. Hot combustion gas is then continually produced during the coking cycle. Owing to the exactly controlled temporal distribution of the cycles over all coke oven banks and coke oven chambers, the production of hot waste gas is so homogenized that control facilities like gas accumulator, tube switches or intermediate tanks are no longer required.
- the coke oven chambers are so configured that they are steadily linked in a spatial integration to form coke oven banks.
- the spatial integration can be accomplished in an even or odd number.
- a linkage is considered to be a constructive encirclement of coke oven chambers. It can be of any arbitrary configuration. It can be implemented by brickwork or jacketing around. But it may also be implemented by an intermediate wall.
- the term “pushing cycle” is deemed to mean both parts of the coking cycle “pushing and charging”. Coal is preferably not preheated and directly charged into the oven pre-warmed by the preceding coking cycle.
- the charging machine is always combined with a quenching car that can controllably approach the opening to be charged so as to allow for a pushing procedure.
- the pushing procedure is preferably so accomplished that the charging procedure is performed by proceeding from the frontal front-end side coke oven chamber wall while the pushing procedure is performed by proceeding from the frontal rear-end side coke oven chamber wall.
- two coke oven banks each are connected in pairs to one boiler.
- the coke oven is comprised of ten coke oven banks, then the entire unit is comprised of five boilers. These are utilized to generate steam and energy.
- the boilers are supplied with hot coking gas coming from the coke oven banks. This is advantageously accomplished through a piping that is linked via a collecting device to the individual coke oven chambers.
- a controlled approach to the individual coke oven chambers for charging is so accomplished that only one coke oven chamber of the individual coke oven bank is initially approached. For example, this is the first coke oven chamber of a coke oven bank.
- a coke oven chamber of the next but one third coke oven bank is approached after approaching the first coke oven chamber of the first coke oven bank.
- Another boiler (boiler number 2 ) is linked to the third coke oven bank, thus avoiding an additional maximal volume flow which would lead to an uneven supply of combustion gas into the boilers.
- This proceeding is applied on all coke oven chambers of the first coke oven chambers each of the next but one coke oven bank each until the first coke oven chamber of the last but one coke oven bank has been pushed and charged. These procedures represent a first pushing cycle.
- a controlled approach to the individual coke oven chambers also depends on the temperature gradient in the coke oven bank.
- the coal charging procedure initially entails a temperature drop in the oven, it is generally of some importance for a constant heat budget of an individual oven y that the adjacent ovens y+1 and y ⁇ 1 are not served immediately, i.e. a few hours, after oven y, if possible. This would entail a temperature drop in an entire oven bank section. It is purposive to choose the charging cycle in such a manner that the adjacent ovens y+1 and y ⁇ 1 are served only after at least 24 hours.
- Claim is particularly laid to a method for cyclical operation of a sequence of an even or odd number of coke oven banks of the “Heat Recovery” type comprised of an even or odd number of coke oven chambers, wherein
- the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- This method is characterized by the term “pushing schedule 2*x/1*(x+1)/2”.
- X represents the number of coke oven chambers per coke oven bank.
- the pushing schedule may be varied. This is feasible in the extent in which a substantial homogenization of the combustion gas stream is effected. For example, a pushing schedule “2*x/1*x/1” is also feasible. It would mean that
- the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- a simpler mode of operation consists in approaching the first coke oven chamber of the next coke oven bank each.
- the corresponding pushing schedule is then called 1*x /2′′′. This requires substantially less expenditure on movements of the charging machine. The homogenization of the combustion gas stream, however, will then be less. Likewise, adjacent coke oven chambers are more strongly charged with heat.
- the pushing schedule means that
- the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- the boilers are utilized to generate steam in order to drive a turbine.
- This propellant energy can be exploited arbitrarily.
- the propellant energy is preferably exploited to generate electrical energy.
- the boiler system is equipped with appropriate devices. These devices include heater facilities, boilers, turbines, steam separators, shafts and generators. Supplementary facilities may also be provided, if the mechanical energy is to be utilized in a different manner.
- the waste gases are preferably fed into a device for gas cleaning to minimize environmental pollution possibly caused by the coke making process.
- sulfuric compounds are removed from the waste gas during the gas cleaning process so that the gas cleaning facility preferably is a desulphurization facility.
- this may be a gas scrubbing unit applying a gas-absorbing solvent.
- the coal is loaded by a coal charging car from the frontal side into the coke oven chamber.
- the door is closed.
- the coke is removed from the coke oven chamber.
- the coking process basically takes approx. 20 to 90 hours.
- pushing is effected towards the other side of the coke oven chamber.
- Coke oven chamber doors easy and quickly to handle are located on either side of the coke oven chamber.
- hot coke Upon charging, hot coke is pushed into a coke quenching car. To execute the invention, it can approach the single coke oven chambers individually.
- the coke quenching car may be provided with a cooling facility. But to be able to quickly execute the discharging processes, it is preferably equipped with a facility for protection from high temperatures. After pushing and discharging of the hot coke, it is preferably passed with the quenching car into a completely cooling facility. For example, this is a coke quenching tower. But it may also be, for example, a coke dry quenching facility.
- the coke oven chambers are combined in even or odd number to coke oven banks.
- the coke oven bank is preferably comprised of 6 to 34 coke oven chambers.
- the coke oven bank is exactly comprised of 10 to 18 coke oven chambers.
- the coke oven bank is comprised of 14 coke oven chambers.
- To supply the boilers or boiler facilities with hot waste gas they are preferably linked to pairs of coke oven banks. This is accomplished via pipelines and appropriate collecting facilities. In theory, however, it is also conceivable to link the boilers or boiler facilities to three coke oven banks each, but in this case the distribution of hot gas is much more difficult.
- one boiler is linked to two coke oven banks. However, it is also conceivable to link one boiler to one, three or more coke oven banks.
- the inventive method provides the benefit of a uniform supply of hot combustion gas to boilers or boiler facilities of coke oven systems. Consequently, the generation of steam by the boiler systems is substantially homogenized. As a result hereof, the generation of electrical energy is much easier. The output of contaminants and pollutants from a coke oven system is thus reduced noticeably. If electrical power is generated by the inventive process, then the generation of electrical power, too, is homogenized and optimized.
- FIG. 1 shows the quantity of raw gas from a coke oven that typically evolved in a coking cycle.
- FIG. 2 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with said cycle schedule having been set-up according to a 2*x/1*(x+1)/2′′ pushing schedule.
- FIG. 3 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with said cycle schedule having been set-up according to the 2*x/1*x/1′′ pushing schedule.
- FIG. 4 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with the cycle schedule obeying to the 1*x/2′′ pushing schedule.
- FIG. 5 shows an inventive arrangement of coke oven banks in a coking system with boilers and downstream arranged auxiliary facilities.
- FIG. 1 shows the raw gas quantity of coking gas evolving on coal carbonization above the coke cake and mainly comprised of hydrogen, carbon monoxide, methane, and water steam constituents. It is determined in volumetric units of standard cubic meters per hour over the entire time of the coking cycle.
- the raw gas quantity is directly proportional to the quantity of completely burnt coking gas that streams-in as combustion gas from a coke oven chamber.
- FIG. 2 shows a cycle schedule for the “charging-coking-pushing” cycle with the 28/15/2′′ pushing schedule.
- Each little rectangular square represents a coke oven chamber arranged in the coke oven bank.
- the individual coke oven banks are enumerated in the first line of the graphical representation and vertically confined by the beams. These bear a numbering from 1 to 10.
- Each coke oven bank is comprised of 14 coke oven chambers; these are numbered in the second line and bear a numbering from 1 to 140.
- the time periods of the individual cycles are indicated in the third and fourth line (fractions of an hour and hours, display in minutes).
- the second column at right from the fifth column on indicates a campaign cycle of the pusher machine.
- the first coke oven chamber of the first coke oven bank is pushed.
- the first coke oven chamber of the third coke oven bank, and then the first coke oven chamber of the fifth, and then the first coke oven chamber of the seventh and finally the first coke oven chamber of the ninth coke oven bank is pushed.
- the second pushing cycle starts. It commences with the second coke oven chamber of the second coke oven bank.
- the second coke oven chamber of the fourth coke oven bank is pushed.
- the third pushing cycle starts upon the end of this cycle. It commences with the third coke oven chamber of the first coke oven bank.
- the last coke oven chamber of the first coke oven bank is pushed.
- coke oven chamber number 126 the last coke oven chamber of the ninth coke oven bank, is pushed. In this manner, a very uniform distribution of the cycles over the entire coking facility is achieved.
- FIG. 3 shows another cycle schedule for the “charging-coking-pushing” cycle with the “28/14/1” pushing schedule.
- the first coke oven chamber of the first coke oven bank is pushed.
- the first coke oven chamber of the third coke oven bank, and then the first coke oven chamber of the fifth, and then the first coke oven chamber of the seventh and finally the first coke oven chamber of the ninth coke oven bank is pushed.
- the second pushing cycle starts. It commences with the first coke oven chamber of the second coke oven bank.
- the first coke oven chamber of the fourth coke oven bank is pushed.
- the third pushing cycle starts upon the end of this cycle. It commences with the second coke oven chamber of the first coke oven bank.
- the last coke oven chamber of the second coke oven bank is pushed.
- coke oven chamber number 140 the last coke oven chamber of the last coke oven bank, is pushed.
- FIG. 4 shows another cycle schedule for the “charging-coking-pushing” cycle with the “14/2” pushing schedule.
- the first coke oven chamber of the first coke oven bank is pushed.
- the first coke oven chamber of the second coke oven bank is pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed.
- the second pushing cycle starts next. It commences with the third coke oven chamber of the first coke oven bank.
- coke oven chamber number 140 the last coke oven chamber of the last coke oven bank, is pushed. Applying this pushing schedule allows for a simple mode of operation of the pusher machine and enables a uniform distribution of the cycles over the entire coking facility.
- FIG. 5 shows an inventive coke oven arrangement including the boiler systems and the associated auxiliary devices. Shown here are the coke oven banks ( 1 ) I to X and the boilers facilities ( 2 ) A to E associated therewith. These are linked in pairs via supply lines ( 3 ) to the coke oven banks ( 1 ) including the associated supply facilities. They supply the boiler facilities ( 2 ) with hot waste gas. The boilers ( 2 ) supply steam energy to turbines located downstream. The cooled and flashed waste gas streaming from the boilers flows via waste gas lines ( 4 ) and is passed into a gas cleaning facility ( 5 ). A fan ( 6 ) generates a negative pressure in order to facilitate off-streaming. Waste gases are then passed through a waste gas line into a waste gas chimney ( 7 ).
- the charging machine ( 8 ) is also shown here. It supplies the coke oven chambers ( 1 ) of the coke oven banks ( 2 ) with coal, said charging machine being fed with coal from a compacting facility ( 9 ) and a coal reservoir ( 10 ).
- the charging machine ( 8 ) may be followed by a pusher machine ( 11 ) which pushes the coke from the coke oven chambers.
- the coke quenching car ( 12 ) is shown here, too. It discharges the individual coke oven chambers and carries the coke into a coke quenching tower ( 13 ). Appropriate storage facilities ( 14 ) are located downstream.
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Abstract
A method for cyclical operation of a coke oven facility which includes an even number of coke oven banks which in turn include an even number of coke oven chambers is shown. Located downstream of the coke oven banks are boiler facilities which drive turbines with the hot waste gases from the coke oven banks. Energy is recovered in this manner. The coke oven chambers are pushed and charged in an exactly determined cycle so that the production of hot waste gas over the temporal mean can be homogenized.
Description
- The invention relates to a method for a cyclical operation of coke oven chambers of the “Heat Recovery” type which form part of coke oven banks, said operation particularly relating to the cyclic phases of “charging-coking-pushing” and with the procedures of pushing determining the cycle being so arranged that the production of hot coking gases utilized according to the “Heat Recovery” process for the production of steam and energy is evenly distributed over the temporal mean of the entire coking process, thus substantially improving the production of steam and energy, and in particular of electrical energy downstream of the coking process.
- On carbonization of coal, the coking gas evolving on carbonization can be utilized in different ways. In some design types, the coking gas is captured and utilized in order to recover and exploit the valuable substances contained therein, for example aromatic hydrocarbons, hydrogen, ammonia, and methane. In other design types, the coking gas is utilized to burn it and thereby to generate heat which is exploited for the process of coal carbonization. With these design types, in turn, it is possible to pass the coking gas after combustion and exploitation of the evolving thermal energy without any further use into the environment. These design types are called coke ovens of the “Non-Recovery” type. Other design types in turn utilize the waste heat to recover steam thereof. This can be utilized, for example, to generate electrical energy. These design types are called coke ovens of the “Heat Recovery” type.
- The arrangement of coke ovens is basically so taken that between 6 and 34 coke ovens are grouped together to be linked to each other in a major unit, which is also called a coke oven bank. In this manner, the production of coke can be substantially homogenized. Since the coke oven chambers have to be charged to allow for production, the charging procedure can by noticeably simplified and automated by forming groups of several coke oven chambers.
- The reason is that coal carbonization is accomplished in a “charging-coking-pushing” phase cycle. While the coking cycle still lingers on with some coke oven chambers, other chambers can be charged or pushed. In this manner, a constant output of combustion gas is also achieved. Coke pushing is accompanied outside the coke oven chamber on the opposite side of a coke oven chamber by the filling of a coke quenching car. In the denomination of oven combinations the method applied is that a combination of several coke ovens of the “Non-Recovery” type or “Heat Recovery” type is called “oven bank”. Conversely, a combination of conventional coke ovens is called “oven battery”.
- WO 2006/128612 A1 describes a method for carbonization of coal in a coke oven with combustion of coking gas, said coking gas initially streaming into a gas space above the coke cake where it is partly burnt with an understoichiometrical volume of supplied combustion air. This process is called primary combustion and it utilizes so-called primary combustion air for combustion. Partly burnt coking gas is then passed via so-called “downcomer” channels into a secondary heating space where it is completely burnt with another quantity of supplied combustion air. This process is called secondary combustion and it utilizes so-called secondary combustion air for combustion. Thereby the lower section of the coke cake is also heated, thus improving the coke quality. The invention lays claim to a device and a method for homogenization of the supply of primary combustion air into the gas space above the coke cake, so that heat distribution in the upper section of the coke cake is homogenized and a better coke product is thus obtained. The invention is equally exploitable for a coke oven of the “Non-Recovery” or “Heat Recovery” type.
- U.S. Pat. No. 5,968,320 A describes a coke oven of the “Heat-Recovery” type which discharges the raw coking gas from the coke oven and burns it in a boiler system in order to generate heat and electric power. The raw coking gas is sprayed for cleaning with a flushing liquor and burnt in a burner where it is exploited to generate steam and mechanical energy. This can be utilized, in turn, to generate electrical energy. To facilitate combustion and to avoid costly installation of compressors and measuring equipment, a negative pressure furnished by installing a suction blower downstream of the combustion chamber is generated in the combustion chamber. By way of this device, the unevenness in furnishing waste gases from coal carbonization which occurs on operation of the described coke oven chambers is also homogenized. But viewed over the entire period of coal carbonization, homogenization is not complete.
- Systems described hereinabove utilize the heat from coal carbonization and from the succeeding combustion process to recover steam and energy. But they have a drawback in that the output of hot combustion gas over the temporal mean must nearly be completely constant in order to ensure even supply of combustion gas to the boilers which generate steam from the effluent heat of coal carbonization. These boilers must be supplied with the most even possible quantity of combustion gas in order to ensure optimal operation of turbines and driven devices further downstream.
- Viewed over a coking cycle, the output of combustion gas from a single coke oven chamber is not constant. It is known that a maximum quantity of raw gas is released during the initial 20% of the coking cycle, said quantity decreasing strongly in the course of coal carbonization. A typical quantity of hot combustion gas measured over the time of one coking cycle of a coke oven chamber is shown as an example in
FIG. 1 . Now if all coke oven chambers of one bank were served consecutively within a short time interval, i.e. pushed and charged, then the corresponding boiler located further downstream would be overstressed by this instant over-supply of hot flue gas and it would no longer work within its optimal working range. For this reason it is of substantial interest to configure the controlled approach to the ovens in such a manner that only one oven each per boiler is served over the entire time period. - A control of the quantity of combustion gas is only feasible in a simple manner via a change in cycle times. For cost considerations, an intermediate arrangement of tanks or accumulator facilities for hot combustion gas is not desired. A change in cycle times, in turn, can only be accomplished via a precisely controlled temporal sequence of the controlled approach to the coke oven chambers. From conventional horizontal-type coking chamber technique, the sequence of such a controlled approach is known under the name “pushing schedule”. It is also determined by the duration of the coal charging procedure and by the maximum travel speed of the oven service machines. A precisely planned set-up of a pushing schedule allows for a simple homogenization of the stream of hot combustion gas.
- Now, therefore, it is the object to provide a simple process and method that allows for controlling the quantity of combustion gas by changing the cycle times or the pushing schedule. Combustion gas is understood to cover a gas, too, that is completely burnt and streams out from a coke oven chamber. But it may also be a partly burnt coking gas if it is burnt in the succeeding auxiliary facilities or in the boilers.
- The invention solves this task by providing a device that combines the coke oven chambers of the “Heat Recovery” type in a distinct number to coke oven banks and by providing a method that controllably approaches these coke oven chambers in an exactly determined sequence for coke pushing. Since the so-called “charging-coking-pushing” cycle terminates with the pushing cycle, the entire cycle for the individual coke oven chambers is controlled with the end of this pushing cycle. The temporal approach to the individual coke oven chambers is so accomplished that the temporal duration of the charging and pushing procedures performed without production of hot combustion gas is distributed over all coke oven banks and over all coke oven chambers. Hot combustion gas is then continually produced during the coking cycle. Owing to the exactly controlled temporal distribution of the cycles over all coke oven banks and coke oven chambers, the production of hot waste gas is so homogenized that control facilities like gas accumulator, tube switches or intermediate tanks are no longer required.
- For the execution of the inventive device, the coke oven chambers are so configured that they are steadily linked in a spatial integration to form coke oven banks. The spatial integration can be accomplished in an even or odd number. A linkage is considered to be a constructive encirclement of coke oven chambers. It can be of any arbitrary configuration. It can be implemented by brickwork or jacketing around. But it may also be implemented by an intermediate wall. The term “pushing cycle” is deemed to mean both parts of the coking cycle “pushing and charging”. Coal is preferably not preheated and directly charged into the oven pre-warmed by the preceding coking cycle.
- It is important that all coke oven chambers can be controllably approached by one charging machine and by one pushing machine so that the charging and pushing procedures can be executed by one machine. Basically the charging machine is always combined with a quenching car that can controllably approach the opening to be charged so as to allow for a pushing procedure. The pushing procedure is preferably so accomplished that the charging procedure is performed by proceeding from the frontal front-end side coke oven chamber wall while the pushing procedure is performed by proceeding from the frontal rear-end side coke oven chamber wall. An automation and a time-related non-retarded performance of the individual cycles is possible in this manner.
- To execute the inventive device, preferably two coke oven banks each are connected in pairs to one boiler. For example, if the coke oven is comprised of ten coke oven banks, then the entire unit is comprised of five boilers. These are utilized to generate steam and energy. The boilers are supplied with hot coking gas coming from the coke oven banks. This is advantageously accomplished through a piping that is linked via a collecting device to the individual coke oven chambers.
- A controlled approach to the individual coke oven chambers for charging is so accomplished that only one coke oven chamber of the individual coke oven bank is initially approached. For example, this is the first coke oven chamber of a coke oven bank. To distribute the charging procedures as evenly as possible over the entire time duration, a coke oven chamber of the next but one third coke oven bank is approached after approaching the first coke oven chamber of the first coke oven bank. This is of some advantage because another boiler (boiler number 2) is linked to the third coke oven bank, thus avoiding an additional maximal volume flow which would lead to an uneven supply of combustion gas into the boilers. This proceeding is applied on all coke oven chambers of the first coke oven chambers each of the next but one coke oven bank each until the first coke oven chamber of the last but one coke oven bank has been pushed and charged. These procedures represent a first pushing cycle.
- Other pushing cycles follow to charge and push the further coke oven chambers. These will then serve the next coke oven chamber each of the next coke oven bank each. In this manner, the second coke oven chambers of the coke oven chambers of the second and of the next but one coke oven chambers each are controllably approached until the second coke oven chamber of the last coke oven bank has been approached. In the next pushing cycle, the coke oven banks succeeding next in this sequence are pushed and charged. For example, these are the third coke oven chambers of the first and of the next but one coke oven bank(s).
- A controlled approach to the individual coke oven chambers also depends on the temperature gradient in the coke oven bank. As the coal charging procedure initially entails a temperature drop in the oven, it is generally of some importance for a constant heat budget of an individual oven y that the adjacent ovens y+1 and y−1 are not served immediately, i.e. a few hours, after oven y, if possible. This would entail a temperature drop in an entire oven bank section. It is purposive to choose the charging cycle in such a manner that the adjacent ovens y+1 and y−1 are served only after at least 24 hours.
- If all coke oven chambers except for the last ones have been pushed and charged, the pushing and charging of the last coke oven chambers of the first and of the next but one coke oven bank each is accomplished in the last cycle. In this manner, a very even production of waste heat is passed into the boiler facilities over the temporal mean of all coking cycles so that a very even supply of waste heat to the boilers is feasible.
- Claim is particularly laid to a method for cyclical operation of a sequence of an even or odd number of coke oven banks of the “Heat Recovery” type comprised of an even or odd number of coke oven chambers, wherein
-
- the coke oven banks (1) proper are composed of a sequence of at least four coke oven chambers of the “Heat Recovery” type, and wherein
- the coke oven banks are linked to a boiler system in which the heat of hot waste gases from coke oven banks is utilized to generate steam, and
- the coke oven chambers are pushed and charged within exactly determined time intervals from the frontal side with a coke pusher machine into the opposite direction of a coke oven chamber, and that directly after pushing a renewed charging of the individual coke oven chambers and a renewed coking cycle are accomplished,
and which is characterized in that - in a first pushing cycle the first coke oven chamber of the first coke oven bank is initially pushed and charged, and wherein the first coke oven chamber of the next but one coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last but one coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number, and
- in a succeeding pushing cycle the next coke oven chamber of the next coke oven bank within this sequence is initially pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged, and
- in a succeeding pushing cycle the next but one coke oven chamber in this sequence of the first coke oven bank is pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged, and
- in a final pushing cycle the coke oven chamber being the last one in this sequence of the first coke oven bank is pushed and charged, and wherein then in successive order the last coke oven chamber each of the next but one coke oven bank is pushed and charged until the coke oven chamber being the last one in this sequence of the last but one coke oven bank has been pushed and charged so that
- a very even production of waste heat can be passed in this manner into the boiler facilities so that the boilers can be supplied very evenly with waste heat.
- In a preferred embodiment, the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- This method is characterized by the term “pushing
schedule 2*x/1*(x+1)/2”. X represents the number of coke oven chambers per coke oven bank. Thedesignation 2*x indicates the difference in the number of coke oven chambers on controlled approaching and it means that aftercoke oven chamber 1 the coke oven chamber 29 (difference 28=2*14) is approached. As has been described hereinabove, this is the first coke oven bank of the next but one coke oven chamber. Then, in the succeeding charging cycle, the second coke oven chamber of next coke oven bank is approached, i.e. coke oven chamber 16 (difference 15=1*(14+1)). Finally, in the succeeding pushing cycle, the third coke oven chamber of the first coke oven bank is pushed (2″). With a coke oven chamber number of 14, the pushing schedule is then called 28/15/2. - The pushing schedule may be varied. This is feasible in the extent in which a substantial homogenization of the combustion gas stream is effected. For example, a pushing schedule “2*x/1*x/1” is also feasible. It would mean that
-
- in a first pushing cycle the first coke oven chamber of the first coke oven bank is initially pushed and charged, and wherein the first coke oven chamber each of the next but one coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last but one coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number, and
- in a succeeding pushing cycle the first coke oven chamber of the next coke oven bank is initially pushed and charged, and wherein then in successive order the first coke oven chamber each of the next but one coke oven bank is pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed and charged, and
- in a succeeding pushing cycle the coke oven chamber being the next one in this sequence of the first coke oven bank is pushed and charged, and wherein then in successive order the coke oven chamber each being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the next one in this sequence of the last coke oven bank has been pushed and charged, and
- in a final pushing cycle the coke oven chamber being the last one in this sequence of the next coke oven bank is pushed and charged, and wherein then in successive order the last coke oven chamber each of the next but one coke oven bank is pushed and charged until the coke oven chamber being the last one in this sequence of the last coke oven bank has been pushed and charged.
- In a preferred embodiment, the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- A simpler mode of operation consists in approaching the first coke oven chamber of the next coke oven bank each. The corresponding pushing schedule is then called 1*x /2′″. This requires substantially less expenditure on movements of the charging machine. The homogenization of the combustion gas stream, however, will then be less. Likewise, adjacent coke oven chambers are more strongly charged with heat. The pushing schedule means that
-
- in a first pushing cycle the first coke oven chamber of the first coke oven bank is initially pushed and charged, and wherein the first coke oven chamber each of the next coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number, and
- in a succeeding pushing cycle the next but one coke oven chamber of the next coke oven bank within this sequence is initially pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged, and
- in a final pushing cycle the last coke oven chamber of the first coke oven bank is pushed and charged, and wherein then in successive order the coke oven chamber being the last one each within this sequence of the next coke oven bank is pushed and charged until the last coke oven chamber of the last coke oven bank has been pushed and charged.
- In a preferred embodiment, the method is so devised that relative to the coke oven banks exactly half the number of boiler systems is existing so that these are linked in pairs to the boilers.
- In this manner, too, a homogenization of the volume of combustion gas stream is feasible.
- The boilers are utilized to generate steam in order to drive a turbine. This propellant energy can be exploited arbitrarily. The propellant energy is preferably exploited to generate electrical energy. To this effect the boiler system is equipped with appropriate devices. These devices include heater facilities, boilers, turbines, steam separators, shafts and generators. Supplementary facilities may also be provided, if the mechanical energy is to be utilized in a different manner.
- On passing through the boiler system, the waste gases are preferably fed into a device for gas cleaning to minimize environmental pollution possibly caused by the coke making process. In particular, sulfuric compounds are removed from the waste gas during the gas cleaning process so that the gas cleaning facility preferably is a desulphurization facility. For example, this may be a gas scrubbing unit applying a gas-absorbing solvent.
- For charging, the coal is loaded by a coal charging car from the frontal side into the coke oven chamber. As a result of the preceding coking process, it is still hot so that no other procedures for coal carbonization are required. At the beginning of the coking process, the door is closed. After the coking process, the coke is removed from the coke oven chamber. Depending on the coal cake height, charging density, and coke oven type, the coking process basically takes approx. 20 to 90 hours. In an advantageous embodiment of the present invention, pushing is effected towards the other side of the coke oven chamber. Coke oven chamber doors easy and quickly to handle are located on either side of the coke oven chamber.
- Upon charging, hot coke is pushed into a coke quenching car. To execute the invention, it can approach the single coke oven chambers individually. The coke quenching car may be provided with a cooling facility. But to be able to quickly execute the discharging processes, it is preferably equipped with a facility for protection from high temperatures. After pushing and discharging of the hot coke, it is preferably passed with the quenching car into a completely cooling facility. For example, this is a coke quenching tower. But it may also be, for example, a coke dry quenching facility.
- To execute the inventive method, the coke oven chambers are combined in even or odd number to coke oven banks. In the inventive embodiment, the coke oven bank is preferably comprised of 6 to 34 coke oven chambers. In a particularly preferred version of the inventive embodiment, the coke oven bank is exactly comprised of 10 to 18 coke oven chambers. In a typical embodiment, the coke oven bank is comprised of 14 coke oven chambers. To supply the boilers or boiler facilities with hot waste gas, they are preferably linked to pairs of coke oven banks. This is accomplished via pipelines and appropriate collecting facilities. In theory, however, it is also conceivable to link the boilers or boiler facilities to three coke oven banks each, but in this case the distribution of hot gas is much more difficult. Preferably one boiler is linked to two coke oven banks. However, it is also conceivable to link one boiler to one, three or more coke oven banks.
- The inventive method provides the benefit of a uniform supply of hot combustion gas to boilers or boiler facilities of coke oven systems. Consequently, the generation of steam by the boiler systems is substantially homogenized. As a result hereof, the generation of electrical energy is much easier. The output of contaminants and pollutants from a coke oven system is thus reduced noticeably. If electrical power is generated by the inventive process, then the generation of electrical power, too, is homogenized and optimized.
- The inventive configuration of a method for carbonization of coal is explained in greater detail by way of five drawings, with the inventive method not being restricted to this embodiment.
-
FIG. 1 shows the quantity of raw gas from a coke oven that typically evolved in a coking cycle.FIG. 2 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with said cycle schedule having been set-up according to a 2*x/1*(x+1)/2″ pushing schedule.FIG. 3 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with said cycle schedule having been set-up according to the 2*x/1*x/1″ pushing schedule.FIG. 4 shows a cycle schedule of charging procedures for coke oven chambers that are linked in pairs to a system of boilers, with the cycle schedule obeying to the 1*x/2″ pushing schedule.FIG. 5 shows an inventive arrangement of coke oven banks in a coking system with boilers and downstream arranged auxiliary facilities. -
FIG. 1 shows the raw gas quantity of coking gas evolving on coal carbonization above the coke cake and mainly comprised of hydrogen, carbon monoxide, methane, and water steam constituents. It is determined in volumetric units of standard cubic meters per hour over the entire time of the coking cycle. The raw gas quantity is directly proportional to the quantity of completely burnt coking gas that streams-in as combustion gas from a coke oven chamber. -
FIG. 2 shows a cycle schedule for the “charging-coking-pushing” cycle with the 28/15/2″ pushing schedule. Each little rectangular square represents a coke oven chamber arranged in the coke oven bank. The individual coke oven banks are enumerated in the first line of the graphical representation and vertically confined by the beams. These bear a numbering from 1 to 10. Each coke oven bank is comprised of 14 coke oven chambers; these are numbered in the second line and bear a numbering from 1 to 140. The time periods of the individual cycles are indicated in the third and fourth line (fractions of an hour and hours, display in minutes). The second column at right from the fifth column on indicates a campaign cycle of the pusher machine. To begin with, the first coke oven chamber of the first coke oven bank is pushed. Next the first coke oven chamber of the third coke oven bank, and then the first coke oven chamber of the fifth, and then the first coke oven chamber of the seventh and finally the first coke oven chamber of the ninth coke oven bank is pushed. Next the second pushing cycle starts. It commences with the second coke oven chamber of the second coke oven bank. Then the second coke oven chamber of the fourth coke oven bank is pushed. The third pushing cycle starts upon the end of this cycle. It commences with the third coke oven chamber of the first coke oven bank. Finally, in the last pushing cycle, the last coke oven chamber of the first coke oven bank is pushed. Ultimately, coke oven chamber number 126, the last coke oven chamber of the ninth coke oven bank, is pushed. In this manner, a very uniform distribution of the cycles over the entire coking facility is achieved. -
FIG. 3 shows another cycle schedule for the “charging-coking-pushing” cycle with the “28/14/1” pushing schedule. To begin with, the first coke oven chamber of the first coke oven bank is pushed. Next the first coke oven chamber of the third coke oven bank, and then the first coke oven chamber of the fifth, and then the first coke oven chamber of the seventh and finally the first coke oven chamber of the ninth coke oven bank is pushed. Next the second pushing cycle starts. It commences with the first coke oven chamber of the second coke oven bank. Then the first coke oven chamber of the fourth coke oven bank is pushed. The third pushing cycle starts upon the end of this cycle. It commences with the second coke oven chamber of the first coke oven bank. Finally, in the last pushing cycle, the last coke oven chamber of the second coke oven bank is pushed. Ultimately, coke oven chamber number 140, the last coke oven chamber of the last coke oven bank, is pushed. - In this manner, a very uniform distribution of the cycles over the entire coking facility is also achieved.
-
FIG. 4 shows another cycle schedule for the “charging-coking-pushing” cycle with the “14/2” pushing schedule. To begin with, the first coke oven chamber of the first coke oven bank is pushed. Next the first coke oven chamber of the second coke oven bank is pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed. The second pushing cycle starts next. It commences with the third coke oven chamber of the first coke oven bank. Finally, coke oven chamber number 140, the last coke oven chamber of the last coke oven bank, is pushed. Applying this pushing schedule allows for a simple mode of operation of the pusher machine and enables a uniform distribution of the cycles over the entire coking facility. -
FIG. 5 shows an inventive coke oven arrangement including the boiler systems and the associated auxiliary devices. Shown here are the coke oven banks (1) I to X and the boilers facilities (2) A to E associated therewith. These are linked in pairs via supply lines (3) to the coke oven banks (1) including the associated supply facilities. They supply the boiler facilities (2) with hot waste gas. The boilers (2) supply steam energy to turbines located downstream. The cooled and flashed waste gas streaming from the boilers flows via waste gas lines (4) and is passed into a gas cleaning facility (5). A fan (6) generates a negative pressure in order to facilitate off-streaming. Waste gases are then passed through a waste gas line into a waste gas chimney (7). The charging machine (8) is also shown here. It supplies the coke oven chambers (1) of the coke oven banks (2) with coal, said charging machine being fed with coal from a compacting facility (9) and a coal reservoir (10). The charging machine (8) may be followed by a pusher machine (11) which pushes the coke from the coke oven chambers. Finally, the coke quenching car (12) is shown here, too. It discharges the individual coke oven chambers and carries the coke into a coke quenching tower (13). Appropriate storage facilities (14) are located downstream. -
- 1 Coke oven bank
- 2 Boiler
- 3 Supply line
- 4 Waste gas line
- 5 Gas cleaning facility
- 6 Fan
- 7 Waste gas chimney
- 8 Charging machine
- 9 Compacting facility
- 10 Coal reservoir container
- 11 Pushing machine
- 12 Coke quenching car
- 13 Coke Quenching Tower
- 14 Storage facilities
Claims (16)
1-15. (canceled)
16. A method for cyclical operation of a sequence coke oven banks of the “Heat Recovery” type in an even or odd number comprised of at least four coke oven banks, comprising an even or odd number of coke oven chambers, wherein:
the coke oven banks proper comprise a sequence of at least four coke oven chambers of the “Heat Recovery” type;
the coke oven banks are linked to a boiler system in which the heat of hot waste gases from the coke oven banks is utilized to generate steam; and
the coke oven chambers are pushed and charged within exactly determined time intervals from the frontal side with a coke pusher machine into the opposite direction of a coke oven chamber, and that directly after pushing a renewed charging of the individual coke oven chambers and a renewed coking cycle are accomplished, the process comprising:
in a first pushing cycle the first coke oven chamber of the first coke oven bank is initially pushed and charged, and wherein the first coke oven chamber each of the next but one coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last but one coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number; and
in a succeeding second pushing cycle the next coke oven chamber of the next coke oven bank within this sequence is initially pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged; and
in a succeeding third pushing cycle the next but one coke oven chamber in this sequence of the first coke oven bank is pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged; and
in a final pushing cycle the coke oven chamber being the last one in this sequence of the first coke oven bank is pushed and charged, and wherein then in successive order the last coke oven chamber each of the next but one coke oven bank is pushed and charged until the coke oven chamber being the last one in this sequence of the last but one coke oven bank has been pushed and charged so that:
over the temporal mean of all coking cycles a very even production of waste heat can be passed in this manner into the boiler facilities so that the boilers can be supplied very evenly with waste heat.
17. A method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks, wherein:
the coke oven banks proper are comprised of a sequence of at least four coke oven chambers of the “Heat Recovery” type;
the coke oven banks are linked to a boiler system in which the heat of hot waste gases from coke oven banks is utilized to generate steam so that exactly half the number of boiler systems is provided; and
the coke oven chambers are pushed and charged within exactly determined time intervals from the frontal side with a coke pusher machine into the opposite direction of a coke oven chamber, and that directly after pushing a renewed charging of the individual coke oven chambers and a renewed coking cycle are accomplished, comprising :
pushing and charging, in a first pushing cycle, the first coke oven chamber of the first coke oven bank and the first coke oven chamber each of the next but one coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last but one coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number; and
pushing and charging in a succeeding pushing cycle the first coke oven chamber of the next coke oven bank, and wherein then in successive order the first coke oven chamber each of the next but one coke oven bank is pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed and charged, and
pushing and charging in a succeeding pushing cycle the coke oven chamber being the next one in this sequence of the first coke oven bank, and then in successive order the coke oven chamber each being the same in this sequence of the next but one coke oven bank is pushed and charged until the coke oven chamber being the next one in this sequence of the last coke oven bank has been pushed and charged; and
pushing and charging in a final pushing cycle the coke oven chamber being the last one in this sequence of the coke oven bank, and wherein then in successive order the last coke oven chamber each of the next but one coke oven bank is pushed and charged until the coke oven chamber being the last one in this sequence of the last coke oven bank has been pushed and charged; so that
over the temporal mean of all coking cycles a very even production of waste heat can be passed in this manner into the boiler facilities so that the boilers can be supplied very evenly with waste heat.
18. A method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks, wherein
the coke oven banks proper are comprised of a sequence of at least four coke oven chambers of the “Heat Recovery” type;
the coke oven banks are linked to a boiler system in which the heat of hot waste gases from coke oven banks is utilized to generate steam so that exactly half the number of boiler systems is provided; and
the coke oven chambers are pushed and charged within exactly determined time intervals from the frontal side with a coke pusher machine into the opposite direction of a coke oven chamber, and that directly after pushing a renewed charging of the individual coke oven chambers and a renewed coking cycle are accomplished, comprising:
in a first pushing cycle the first coke oven chamber of the first coke oven bank is initially pushed and charged, and wherein the first coke oven chamber each of the next coke oven bank is consecutively pushed and charged until the first coke oven chamber of the last coke oven bank has been pushed and charged, if the number of coke oven chambers per coke oven bank is an even number;
in a succeeding pushing cycle the next but one coke oven chamber of the next coke oven bank within this sequence is initially pushed and charged, and wherein then in successive order the coke oven chamber being the same in this sequence of the next coke oven bank is pushed and charged until the coke oven chamber being the same in this sequence of the last coke oven bank has been pushed and charged; and
in a final pushing cycle the last coke oven chamber of the first coke oven bank is pushed and charged, and wherein then in successive order the coke oven chamber being the last one each within this sequence of the next coke oven bank is pushed and charged until the last coke oven chamber of the last coke oven bank has been pushed and charged; such that
over the temporal mean of all coking cycles a very even production of waste heat can be passed in this manner into the boiler facilities so that the boilers can be supplied very evenly with waste heat.
19. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 16 , wherein the hot steam from the boiler systems is utilized to drive a turbine and to generate electricity.
20. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 19 , wherein the hot waste gases are passed to a desulphurization stage after they have left the boiler system.
21. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 20 , wherein the device for desulphurization is a gas scrubbing unit.
22. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 16 , wherein the hot coke is passed into a coke quenching car after pushing, said coke quenching car being able to approach the single coke oven chambers individually for coke pushing.
23. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 22 , wherein the hot coke from the coke quenching car is passed into a facility suitable for coke quenching, this being for example a coke quenching tower.
24. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 23 , wherein the hot coke from the coke quenching car is passed into a facility suitable for coke quenching, this being for example a coke dry quenching facility.
25. The method for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 16 , wherein the individual coke oven chamber ovens are charged by a coal charging machine that can approach the single coke oven chambers individually.
26. A device for cyclical operation of a sequence of an even or odd number of at least four coke oven banks in accordance to the method of claim 16 , wherein the number of coke oven chambers per coke oven bank ranges between six and thirty-four.
27. The device for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 26 , wherein the number of coke oven chambers per coke oven bank amounts to exactly fourteen.
28. The device for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 26 , wherein each coke oven bank is linked to one boiler.
29. The device for cyclical operation of a sequence of an even number of at least four coke oven banks as defined in claim 26 , wherein the number of coke oven banks per boiler amounts to two, so that the boilers are linked in pairs to the coke oven banks.
30. The device for cyclical operation of a sequence of an even or odd number of at least four coke oven banks as defined in claim 26 , wherein there are at least 6 coke oven banks, and that the number of coke oven banks per boiler amounts to three.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008064209.6 | 2008-12-22 | ||
| DE102008064209A DE102008064209B4 (en) | 2008-12-22 | 2008-12-22 | Method and apparatus for the cyclical operation of coke oven benches from "heat recovery" coke oven chambers |
| PCT/EP2009/009103 WO2010072378A2 (en) | 2008-12-22 | 2009-12-18 | Method for cyclically operating coke oven banks from "heat recovery" coke oven chambers |
Publications (1)
| Publication Number | Publication Date |
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| US20110253521A1 true US20110253521A1 (en) | 2011-10-20 |
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| US13/138,004 Abandoned US20110253521A1 (en) | 2008-12-22 | 2009-12-18 | Method for a cyclical operation of coke oven banks comprised of" heat recovery" coke oven chambers |
Country Status (18)
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| US (1) | US20110253521A1 (en) |
| EP (1) | EP2367902A2 (en) |
| JP (1) | JP2012513507A (en) |
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| TW (1) | TWI429739B (en) |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2367902A2 (en) | 2011-09-28 |
| AR074864A1 (en) | 2011-02-16 |
| DE102008064209A1 (en) | 2010-07-01 |
| NZ592942A (en) | 2014-04-30 |
| CA2748330A1 (en) | 2010-07-01 |
| KR20110110105A (en) | 2011-10-06 |
| ZA201104524B (en) | 2012-03-28 |
| EA201170861A1 (en) | 2011-12-30 |
| JP2012513507A (en) | 2012-06-14 |
| TW201030137A (en) | 2010-08-16 |
| MX2011006717A (en) | 2011-09-21 |
| WO2010072378A2 (en) | 2010-07-01 |
| DE102008064209B4 (en) | 2010-11-18 |
| AU2009331894A1 (en) | 2011-07-14 |
| WO2010072378A3 (en) | 2010-08-19 |
| TWI429739B (en) | 2014-03-11 |
| AP2011005726A0 (en) | 2011-06-30 |
| CO6390062A2 (en) | 2012-02-29 |
| BRPI0923537A2 (en) | 2016-01-26 |
| CN102257101A (en) | 2011-11-23 |
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