[go: up one dir, main page]

US20110192141A1 - Exhaust system component having a combination of a heat exchanger and a catalytic converter, motor vehicle having the component and method of operating the component - Google Patents

Exhaust system component having a combination of a heat exchanger and a catalytic converter, motor vehicle having the component and method of operating the component Download PDF

Info

Publication number
US20110192141A1
US20110192141A1 US13/036,192 US201113036192A US2011192141A1 US 20110192141 A1 US20110192141 A1 US 20110192141A1 US 201113036192 A US201113036192 A US 201113036192A US 2011192141 A1 US2011192141 A1 US 2011192141A1
Authority
US
United States
Prior art keywords
catalytic converter
converter body
heat exchanger
flow path
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/036,192
Inventor
Sven Schepers
Rolf Brück
Sigrid Limbeck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vitesco Technologies Lohmar Verwaltungs GmbH
Original Assignee
Emitec Gesellschaft fuer Emissionstechnologie mbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Emitec Gesellschaft fuer Emissionstechnologie mbH filed Critical Emitec Gesellschaft fuer Emissionstechnologie mbH
Publication of US20110192141A1 publication Critical patent/US20110192141A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2882Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
    • F01N3/2889Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices with heat exchangers in a single housing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N5/00Exhaust or silencing apparatus combined or associated with devices profiting by exhaust energy
    • F01N5/02Exhaust or silencing apparatus combined or associated with devices profiting by exhaust energy the devices using heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • F28D7/0075Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with particular circuits for the same heat exchange medium, e.g. with the same heat exchange medium flowing through sections having different heat exchange capacities or for heating or cooling the same heat exchange medium at different temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/06Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits having a single U-bend
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/014Stoichiometric gasoline engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/02Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/02Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • F28D7/163Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing
    • F28D7/1669Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing the conduit assemblies having an annular shape; the conduits being assembled around a central distribution tube
    • F28D7/1676Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing the conduit assemblies having an annular shape; the conduits being assembled around a central distribution tube with particular pattern of flow of the heat exchange media, e.g. change of flow direction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to a combination of a heat exchanger and a catalytic converter in a common housing as a component of an exhaust system.
  • the component serves, in particular, to recover energy from an exhaust stream and to optimize light-off behavior of the catalytic converter provided in the housing.
  • the invention also relates to a motor vehicle having the component and a method of operating the component.
  • Exhaust gas from an internal combustion engine of a motor vehicle has thermal energy which can be converted into electrical energy, for example through the use of a thermo-electric generator in order, for example, to charge a battery or some other energy storage device or to supply required energy directly to electric consumers. Energy is therefore available to a greater extent for the operation of the motor vehicle.
  • a thermo-electric generator has a plurality of thermo-electric transducer elements.
  • Thermo-electric materials are of a type that can convert the effectively thermal energy into electrical energy (Seebeck effect) and vice versa (Peltier effect).
  • the Seebeck effect is based on the phenomenon of the conversion of thermal energy into electrical energy and is used to generate thermo-electrical energy.
  • the Peltier effect is the converse of the Seebeck effect and is a phenomenon which is associated with the adsorption of heat and is caused in relation to a flow of current through different materials.
  • the Peltier effect has already been proposed, for example, for thermo-electric cooling.
  • thermo-electric generators for use in motor vehicles.
  • such generators have usually been very expensive to manufacture and have been characterized by a relatively low level of efficiency.
  • a further decisive feature is the overall size of components for recovering energy from the exhaust gas.
  • a maximum amount of energy is to be recovered from the stream of exhaust gas accompanied by the smallest possible overall size.
  • the individual components of the emission control system are brought as quickly as possible to the operating temperature at all operating points of the internal combustion engine in order to permit wide-ranging conversion of pollutants which are contained in the exhaust gas.
  • an object of the invention to provide an exhaust system component having a combination of a heat exchanger and a catalytic converter, a motor vehicle having the component and a method of operating the component, which overcome the hereinafore-mentioned disadvantages and at least partially solve the highlighted problems of the heretofore-known devices and methods of this general type.
  • the intention is to specify a component of an exhaust system which permits the highest possible level of efficiency in terms of the conversion of the thermal energy which is made available from the exhaust gas into thermal energy of a medium of the heat exchanger and which also increases the effectiveness of the emission control of the component at all of the operating points of the internal combustion engine.
  • the intention is to obtain a structure which is as compact as possible.
  • a component of an exhaust system for an internal combustion engine comprises at least one housing having an inlet and an outlet for an exhaust gas and at least one inflow and one outflow for a medium, and a heat exchanger around which the exhaust gas can flow.
  • the heat exchanger has at least one first flow path for the medium.
  • the heat exchanger has a first thermal mass and a catalytic converter body through which the exhaust gas can flow.
  • the catalytic converter body has a second thermal mass. The heat exchanger and the catalytic converter body are disposed together in the housing.
  • the medium which is used in the heat exchanger is, in particular, a fluid, and preferably substantially water can be used, wherein, in particular, also long-chained hydrocarbon compounds, that is to say oils or lubricants, can be used.
  • the component is defined by the fact that the heat exchanger and catalytic converter body represent assemblies of the component which are independent of one another and which accordingly have separate thermal masses or heat contents which are separated from one another.
  • the heat exchanger is formed, in particular, by tube systems through which a medium flows, so that the tube system forms a first thermal mass
  • the catalytic converter body is formed, in particular, by at least partially structured metal foils which are wound, wrapped or stacked and themselves define a second thermal mass.
  • the tube system of the heat exchanger is, in particular, constructed from a plurality of tubes which are connected to one another and which are disposed inside the housing of the component and through which a medium flows along a single flow path or along a plurality of flow paths.
  • the heat exchanger can also be provided as a single-component element, for example as a wall element through which the medium can flow and which has, in particular, breakthroughs, and around which the exhaust gas can therefore flow. In this case, the medium flows through the heat exchanger along a single flow path.
  • the configuration of the catalytic converter body and heat exchanger in a housing ensures that the exhaust gas and/or the catalytic converter body is/are heated by the heat exchanger, with the result that the catalytic converter body can reach or maintain its operating temperature above the light-off temperature as quickly as possible and for as long as possible.
  • the light-off temperature of the catalytic converter body is defined as the temperature above which the catalytic coating reacts with the pollutants in the exhaust gas.
  • the housing has an inner wall, a central axis, a first end side and a second end side disposed along the central axis.
  • the inlet for the exhaust gas is disposed at the first end side and the outlet is disposed at the second end side.
  • the catalytic converter body is disposed along the central axis and has an outer circumferential surface and an inner circumferential surface extending parallel to the central axis.
  • the inner circumferential surface is fluidically connected directly to the inlet, permitting the exhaust gas to flow radially through the catalytic converter body from the inner circumferential surface to the outer circumferential surface.
  • the at least one first flow path of the heat exchanger at least partially surrounds the catalytic converter body at the outer circumferential surface.
  • annular channel is disposed at the inner wall of the housing.
  • the annular channel is fluidically connected to the outer circumferential surface of the catalytic converter body and directly to the outlet, and the annular channel at least partially surrounds the catalytic converter body and the at least one first flow path.
  • the catalytic converter body of the present invention through which there can be radial flow, corresponds, in particular, to the construction of the radial catalytic converters according to International Publication No. WO 02/40838 A1, corresponding to U.S. Pat. No. 7,252,809 or International Publication No. WO 02/81879 A1, corresponding to U.S. Pat. No. 7,276,211, the entire contents of which are hereby incorporated by reference.
  • a heating element for example in the form of a heating-type catalytic converter, is disposed upstream of the inlet of the housing or inside the inner space which is present in the radial catalytic converter.
  • the catalytic converter body preferably has a cylindrical construction and has in its interior a cavity through which the exhaust gas can flow from the outlet of the housing.
  • the exhaust gas is, if appropriate, diverted there by diversion devices so that it flows outward through the catalytic converter body in the radial direction and leaves the catalytic converter body through the outer circumferential surface.
  • the at least one first flow path of the heat exchanger is preferably disposed directly on the outer circumferential surface of the catalytic converter body.
  • these tubes run, in particular, in the axial direction parallel to the central axis and are distributed uniformly over the outer circumferential surface of the catalytic converter body.
  • a heat exchanging section over a particularly large surface is generated through such a preferred configuration of the heat exchanger so that the highest possible quantity of the thermal energy which is available in the exhaust gas is transmitted to the medium of the heat exchanger.
  • the heat exchanger is preferably disposed in this case inside the annular channel which preferably surrounds the entire circumference of the catalytic converter body and is disposed between the outer circumferential surface of the catalytic body and the inner wall of the housing.
  • the annular channel is embodied in such a way that it is preferably closed off with respect to the exhaust gas inlet, so that after flowing out of the catalytic converter body the exhaust gas is conducted away through the annular channel accompanied by a preceding and/or simultaneous flow around the heat exchanger in the direction of the exhaust gas outlet.
  • the housing and the heat exchanger are provided, in particular, with guiding elements for the exhaust gas so that the smallest possible pressure loss due to eddying or other resistances in the exhaust gas stream is achieved.
  • the heat exchanger can also be constructed as a planar hollow element which has, in particular, breakthroughs so that the exhaust gas can flow through and around the hollow element.
  • a plurality of layers of these wall-shaped elements can also be disposed in combination with pipelines or tube lines between the catalytic converter body and the housing.
  • At least one second flow path is provided which at least partially penetrates the catalytic converter body, and in particular over its entire axial extent.
  • the second flow path of the heat exchanger can have an identical construction to the first flow path in this case.
  • it is disposed in the catalytic converter body in such a way that it is provided inside a radially outer section of the catalytic converter, so that the exhaust gas, coming from the inlet of the housing, overflows a first catalytically active region of the catalytic converter, and only then flows along the at least one second flow path of the heat exchanger.
  • the catalytic converter body has, for the purpose of accommodating the at least one second flow path, in particular holes or cutouts, into which the structures which are provided for the second flow path can be inserted.
  • the heat exchanger is embodied at least in two stages and the at least one first flow path, which is disposed outside the catalytic converter body, is assigned to a first stage, and the at least one second flow path, which penetrates the catalytic converter body, is assigned to a second stage of the heat exchanger.
  • Implementing the heat exchanger with two stages means, in particular, that the latter has two inflows or outflows through which the at least one first flow path or second flow path can be respectively separately supplied with a medium.
  • the media can, however, be embodied in different ways or also in the same way.
  • This preferred embodiment ensures that the heat exchanger has, in particular, at least two temperature ranges for the medium, the first temperature range caused by the configuration of the at least one first flow path and the second temperature range caused by the configuration of the at least one second flow path.
  • the media which have different temperatures can then be fed, in the region of a thermo-electric generator, to the transducer elements which are particularly suitable for the respective temperature range.
  • the energy efficiency of a thermo-electric generator or of the component according to the invention is therefore increased further.
  • the required volume of the medium which is used to supply thermal energies to the catalytic converter body at critical operating points of the internal combustion engine is kept very small since only the at least one second flow path of the heat exchanger is used to heat the catalytic converter body. It is not necessary in this case for a heated medium to heat and flow through the at least one first flow path. The most rapid possible heating, and therefore operational capability, of the catalytic converter body can be achieved by this advantageous embodiment.
  • the catalytic converter zones which are disposed in the region of the second flow path can also have relatively low specific thermal capacities so that they heat up more quickly, if appropriate, as a result of the medium, and therefore permit an operational capability of the catalytic converter within a relative short time.
  • the second flow path of the heat exchanger can also be embodied as a volume which is enclosed in itself without an inflow and outflow for a medium.
  • the second flow path is filled with a phase change material which can act as a latent heat storage device for the catalytic converter body.
  • the phase change material which is provided in the second flow path is heated, the material will change its phase state, for example from solid to liquid, through the absorption of a specific quantity of heat.
  • the catalytic converter body has, opposite the at least one second flow path of the heat exchanger, at least one first compensation element which permits the catalytic converter body to expand in the radial direction.
  • This is meant to refer in this case, in particular, to cutouts which can absorb expansion of the catalytic converter in the radial direction without loading the second flow paths of the heat exchanger with compressive stresses or displacing those flow paths.
  • cutouts it is also possible to provide structures in the at least partially structured metal foils of the catalytic converter body. The structures can compensate for radial expansion of the catalytic converter body due to the thermal stressing caused by bending or a certain degree of compressibility.
  • the catalytic converter body has at least one second compensation element which permits the catalytic converter body to expand in the axial direction.
  • These second compensation elements are, in particular, suitable for compensating for the expansion of the catalytic converter body in the axial direction in such a way that the flow paths which are provided for the exhaust gas are maintained.
  • these second compensation elements are also intended to avoid tensile stresses or compressive stresses which could be transmitted to first or second flow paths.
  • the second compensation elements are integrated, in particular, into holding elements which secure first and/or second flow paths in their position in the housing, in particular in the radial direction.
  • connections of the second compensation elements to the first flow path and/or to the second flow path can be embodied as sliding seats.
  • the second compensation elements are integrated into the first and/or the second flow path.
  • the flow paths which are constructed in the form of pipelines or tube lines can have bends, or, for example, omega-shaped interlaced connections which permit axial mobility and therefore compensate for expansion of the catalytic converter body in the axial direction.
  • the holding elements which secure the catalytic converter body and flow paths with respect to one another can also be embodied in a fixed fashion in the axial direction.
  • the at least one first flow path and/or the at least one second flow path have/has a catalytically active coating.
  • regions of the inner wall of the housing or regions of the annular channel can also be provided with a catalytically active coating, with the result that, on one hand, the most complete conversion possible of the pollutants in the exhaust gas is achieved and, on the other hand, the largest possible quantity of thermal energy arising from the exothermic catalytic reaction of the exhaust gas can be conducted away to the heat exchanger. If appropriate, it is also possible to dispense with coating of the flow paths if the transfer of heat is made worse by the catalytic coating.
  • Coatings for oxidation catalytic converters are preferably provided for the catalytically active coating of the catalytic converter body or of the further regions of the component.
  • An exothermic reaction which increases the thermal energy in the exhaust gas, is generated in the catalytic converter body as a result of the catalytic conversion of components of the exhaust gas. This further increased thermal energy of the exhaust gas is conducted away by the medium through the heat exchanger and is advantageously converted outside the component into electrical energy.
  • the catalytic converter body and the further regions can, if appropriate, be embodied with various coatings and/or catalysts.
  • a motor vehicle especially a passenger car, comprising a component according to the invention.
  • the method comprises providing a component according to the invention, and heating the catalytic converter body, at least at certain times, by using the heat exchanger as a heating element.
  • FIG. 1 is a diagrammatic, longitudinal-sectional view of a first embodiment variant of a component
  • FIG. 2 is a cross-sectional view of the first embodiment variant of the component
  • FIG. 3 is a perspective view of a metal foil of a catalytic converter body.
  • FIG. 4 is a plan view of a motor vehicle in which components are integrated.
  • FIG. 1 there is seen a first embodiment variant of a component 1 in a longitudinal-sectional view.
  • the component 1 has a housing 4 with a first end side 17 and a second end side 18 .
  • An inlet 5 for exhaust gas 7 is disposed at the first end side 17 .
  • the exhaust gas 7 passes through the inlet 5 into a cavity in a catalytic converter body 13 .
  • An outlet 6 for the exhaust gas 7 is provided on the second end side 18 of the housing 4 of the component 1 .
  • the catalytic converter body 13 extends parallel and concentrically with respect to a central axis 16 of the housing 4 of the component 1 and is represented herein as a catalytic converter body 13 through which there can be a radial flow.
  • the exhaust gas 7 is diverted in the interior of the catalytic converter body 13 and flows through an inner circumferential surface 20 into a honeycomb body structure of the catalytic converter body 13 .
  • the exhaust gas 7 flows through the catalytic converter body 13 in the radial direction, flows out of the catalytic converter body through an outer circumferential surface 19 and impacts against a heat exchanger 11 in an annular channel 21 .
  • the heat exchanger 11 is represented in the right-hand half of the figure by a first flow path 15 .
  • the heat exchanger 11 has a first thermal mass 12 and the catalytic converter body 13 has a second thermal mass 14 .
  • the heat exchanger 11 is illustrated in one embodiment as a pipeline through which a medium 10 flows.
  • the pipelines of this first flow path 15 are configured in this case in such a way that irrespective of the configuration of an inflow 8 and of an outflow 9 , a uniform flow through the pipelines over the entire volume of the heat exchanger 11 is obtained and therefore an optimum exchange of heat between the medium 10 and the exhaust gas 7 is made possible.
  • the exhaust gas 7 is diverted in the region of the heat exchanger 11 in the annular channel 21 and flows around the heat exchanger 11 in the direction of the outlet 6 of the housing 4 .
  • the annular channel 21 is bounded by an inner wall 22 of the housing 4 and by the outer circumferential surface 19 of the catalytic converter body 13 .
  • the annular channel 21 is embodied so as to be closed off with respect to the first end side 17 of the housing 4 and so as to be open with respect to the second end side 18 , so that the exhaust gas flows through the annular channel 21 in the direction of the outlet 6 of the housing 4 .
  • an embodiment of the heat exchanger 11 is illustrated with a first flow path 15 and a second flow path 23 .
  • the second flow path 23 is disposed substantially inside the catalytic converter body 13 .
  • the first flow path 15 is connected to the inflow 8 through which the medium 10 is introduced.
  • the medium 10 leaves the housing 4 through the outflow 9 , after flowing through the first flow path 15 .
  • the inflow 8 and the outflow 9 for the second flow path 23 are not illustrated in FIG. 1 .
  • the latter can have a separate inflow 8 and outflow 9 or else be connected to the illustrated inflow 8 and outflow 9 so that the second flow path 23 is connected parallel to the first flow path 15 .
  • the heat exchanger 11 can therefore be operated as a single-stage or as an at least two-stage heat exchanger. Given a parallel connection of the first flow path 15 and the second flow path 23 , a single-stage heat exchanger 11 is implemented. Given an embodiment of the heat exchanger 11 with a separate inflow 8 and outflow 9 for the first flow path 15 , on one hand, and at least the second flow path 23 , on the other hand, a two-stage heat exchanger is implemented which can, in particular, supply differently temperature-conditioned media 10 to a thermo-electric generator so that thermal elements with maximum levels of efficiency for respectively different temperature ranges can be utilized as efficiently as possible. In this context, a first stage 25 of the heat exchanger 11 is formed by the first flow path 15 , and a second stage 26 of the heat exchanger 11 is formed by the second flow path 23 .
  • the component 1 has second compensation elements 29 which are, in particular, components of the catalytic converter body 13 and serve to secure the first flow path 15 and/or the second flow path 23 .
  • These second compensation elements 29 are suitable, in particular, for compensating for expansion of the catalytic converter body 13 in axial direction 30 due to thermal stressing by virtue of the fact that they are embodied in a particularly compressible fashion.
  • FIG. 2 is a diagrammatic view of a cross section through the first embodiment variant of the component 1 .
  • FIG. 2 is, in particular, an illustration of the fact that the exhaust gas 7 flows through the catalytic converter body 13 in a radial direction 28 , and in this context is conducted, in particular, through structures 37 of metal foil 35 of the catalytic converter body 13 in predefined flow channels 36 from the inner circumferential surface 20 to the outer circumferential surface 19 of the catalytic converter body 13 .
  • the heat exchanger 11 is illustrated with a first flow path 15 and a second flow path 23 , which together define a first thermal mass 12 .
  • the catalytic converter body 13 has a second thermal mass 14 .
  • first compensation elements 27 are provided which are intended to permit or compensate for expansion of the catalytic converter body 13 in the radial direction 28 .
  • These first compensation elements 27 can, in particular, be embodied as cutouts which are illustrated or as bendable or compressible structure elements of the metal foil 35 .
  • the exhaust gas 7 flows through the outer circumferential surface 19 of the catalytic converter body 13 into the annular channel 21 and flows in this case around the first flow path 15 of the heat exchanger 11 and is carried onward in the direction of the outlet 6 of the housing 4 through the annular channel 21 which is bounded, in particular, by the inner wall 22 of the housing 4 and the outer circumferential surface 19 of the catalytic converter body 13 .
  • the first flow path 15 and the second flow path 23 are illustrated herein in a two-stage embodiment of the heat exchanger 11 , wherein the first flow path 15 is provided as a first stage 25 with an inflow 8 and an outflow 9 for a medium 10 , and the second flow path 23 is embodied as a second stage 26 , also with an inflow 8 and an outflow 9 for a medium 10 .
  • the medium 10 which is used for the first stage 25 can differ in this case, in particular, from the medium 10 used in the second stage 26 in that it has optimum thermal conduction properties and thermal transport properties for the respective temperature range.
  • the first flow paths 15 or second flow paths 23 are each connected to one another and therefore connected in parallel so that a uniform flow through the first flow path 15 and the second flow path 23 is ensured over the entire volume of the heat exchanger 11 .
  • devices are provided which can bring about or improve homogenization of the flow of medium in the heat exchanger 11 .
  • FIG. 3 is a diagrammatic, perspective view of a metal foil 35 of the catalytic converter body 13 which is manufactured, in particular, from a plurality of such metal foils which are stacked one on top of the other (in a manner which is not illustrated herein).
  • Flow channels 36 are formed in this case in the radial direction 28 by at least partially present structures 37 of the metal foil 35 .
  • the exhaust gas 7 which flows into the catalytic converter body 13 along a central axis 16 , is conducted through the flow channels 36 from the inner circumferential surface 20 to the outer circumferential surface 19 of the catalytic converter body 13 .
  • FIG. 4 is a block diagram illustrating a preferred purpose for the use of such a component 1 in a motor vehicle 31 with an internal combustion engine 3 .
  • the exhaust gas 7 which is generated in the internal combustion engine 3 , for example a spark ignition engine or a diesel engine, flows on into an exhaust system 2 .
  • the component 1 is advantageously connected directly downstream of the internal combustion engine 3 .
  • the component 1 may be part of the exhaust system 2 itself or, if appropriate, also part of an exhaust gas recirculation system 32 , in which recourse can be particularly advantageously made to a radiator 33 by virtue of the fact that a temperature gradient between the medium 10 of the heat exchanger 11 of the component 1 and a cooling medium 39 of the radiator 33 can be harnessed as electrical energy within the scope of a thermo-electric generator 38 .
  • the exhaust gas 7 can also be supplied to an exhaust gas treatment unit 34 before it is discharged into the surroundings in a purified form.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

A component of an exhaust gas system for an internal combustion engine includes at least one housing with an inlet and an outlet for an exhaust gas and at least one inflow and one outflow for a medium. The component has a heat exchanger around which the exhaust gas can flow. The heat exchanger has a first thermal mass and a catalytic converter body through which the exhaust gas can flow. The catalytic converter body has a second thermal mass. A motor vehicle having a component and a method for operating a component, are also provided.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This is a continuation, under 35 U.S.C. §120, of copending International Application No. PCT/EP2009/060563, filed Aug. 14, 2009, which designated the United States; this application also claims the priority, under 35 U.S.C. §119, of German Patent Application DE 10 2008 044 711.0, filed Aug. 28, 2008; the prior applications are herewith incorporated by reference in their entirety.
  • BACKGROUND OF THE INVENTION Field of the Invention
  • The present invention relates to a combination of a heat exchanger and a catalytic converter in a common housing as a component of an exhaust system. The component serves, in particular, to recover energy from an exhaust stream and to optimize light-off behavior of the catalytic converter provided in the housing. The invention also relates to a motor vehicle having the component and a method of operating the component.
  • Exhaust gas from an internal combustion engine of a motor vehicle has thermal energy which can be converted into electrical energy, for example through the use of a thermo-electric generator in order, for example, to charge a battery or some other energy storage device or to supply required energy directly to electric consumers. Energy is therefore available to a greater extent for the operation of the motor vehicle. Such a thermo-electric generator has a plurality of thermo-electric transducer elements. Thermo-electric materials are of a type that can convert the effectively thermal energy into electrical energy (Seebeck effect) and vice versa (Peltier effect). The Seebeck effect is based on the phenomenon of the conversion of thermal energy into electrical energy and is used to generate thermo-electrical energy. The Peltier effect is the converse of the Seebeck effect and is a phenomenon which is associated with the adsorption of heat and is caused in relation to a flow of current through different materials. The Peltier effect has already been proposed, for example, for thermo-electric cooling.
  • Attempts have already been made to make available corresponding thermo-electric generators for use in motor vehicles. However, such generators have usually been very expensive to manufacture and have been characterized by a relatively low level of efficiency. As a result, it has not been possible to achieve series compatibility. A further decisive feature is the overall size of components for recovering energy from the exhaust gas. In that context, a maximum amount of energy is to be recovered from the stream of exhaust gas accompanied by the smallest possible overall size. At the same time it is to be ensured that the individual components of the emission control system are brought as quickly as possible to the operating temperature at all operating points of the internal combustion engine in order to permit wide-ranging conversion of pollutants which are contained in the exhaust gas.
  • SUMMARY OF THE INVENTION
  • It is accordingly an object of the invention to provide an exhaust system component having a combination of a heat exchanger and a catalytic converter, a motor vehicle having the component and a method of operating the component, which overcome the hereinafore-mentioned disadvantages and at least partially solve the highlighted problems of the heretofore-known devices and methods of this general type. In particular, the intention is to specify a component of an exhaust system which permits the highest possible level of efficiency in terms of the conversion of the thermal energy which is made available from the exhaust gas into thermal energy of a medium of the heat exchanger and which also increases the effectiveness of the emission control of the component at all of the operating points of the internal combustion engine. At the same time, the intention is to obtain a structure which is as compact as possible.
  • With the foregoing and other objects in view there is provided, in accordance with the invention, a component of an exhaust system for an internal combustion engine. The component comprises at least one housing having an inlet and an outlet for an exhaust gas and at least one inflow and one outflow for a medium, and a heat exchanger around which the exhaust gas can flow. The heat exchanger has at least one first flow path for the medium. The heat exchanger has a first thermal mass and a catalytic converter body through which the exhaust gas can flow. The catalytic converter body has a second thermal mass. The heat exchanger and the catalytic converter body are disposed together in the housing.
  • The medium which is used in the heat exchanger is, in particular, a fluid, and preferably substantially water can be used, wherein, in particular, also long-chained hydrocarbon compounds, that is to say oils or lubricants, can be used. The component is defined by the fact that the heat exchanger and catalytic converter body represent assemblies of the component which are independent of one another and which accordingly have separate thermal masses or heat contents which are separated from one another. In this context, the heat exchanger is formed, in particular, by tube systems through which a medium flows, so that the tube system forms a first thermal mass, and the catalytic converter body is formed, in particular, by at least partially structured metal foils which are wound, wrapped or stacked and themselves define a second thermal mass. The tube system of the heat exchanger is, in particular, constructed from a plurality of tubes which are connected to one another and which are disposed inside the housing of the component and through which a medium flows along a single flow path or along a plurality of flow paths. The heat exchanger can also be provided as a single-component element, for example as a wall element through which the medium can flow and which has, in particular, breakthroughs, and around which the exhaust gas can therefore flow. In this case, the medium flows through the heat exchanger along a single flow path.
  • As a result of the configuration of the catalytic converter body and heat exchanger in a housing, it is possible for a very high level of effectiveness of the transfer of heat to be achieved by utilizing the catalytically generated heat, with the result that a maximum amount of thermal energy is carried away through the heat exchanger and, if appropriate, can be converted into electrical energy outside the housing of the component by thermo-electric transducer elements. At the same time, the configuration of the heat exchanger and catalytic converter body in a housing ensures that the exhaust gas and/or the catalytic converter body is/are heated by the heat exchanger, with the result that the catalytic converter body can reach or maintain its operating temperature above the light-off temperature as quickly as possible and for as long as possible. The light-off temperature of the catalytic converter body is defined as the temperature above which the catalytic coating reacts with the pollutants in the exhaust gas.
  • In accordance with another feature of the invention, the housing has an inner wall, a central axis, a first end side and a second end side disposed along the central axis. The inlet for the exhaust gas is disposed at the first end side and the outlet is disposed at the second end side. The catalytic converter body is disposed along the central axis and has an outer circumferential surface and an inner circumferential surface extending parallel to the central axis. The inner circumferential surface is fluidically connected directly to the inlet, permitting the exhaust gas to flow radially through the catalytic converter body from the inner circumferential surface to the outer circumferential surface. The at least one first flow path of the heat exchanger at least partially surrounds the catalytic converter body at the outer circumferential surface. An annular channel is disposed at the inner wall of the housing. The annular channel is fluidically connected to the outer circumferential surface of the catalytic converter body and directly to the outlet, and the annular channel at least partially surrounds the catalytic converter body and the at least one first flow path.
  • The catalytic converter body of the present invention, through which there can be radial flow, corresponds, in particular, to the construction of the radial catalytic converters according to International Publication No. WO 02/40838 A1, corresponding to U.S. Pat. No. 7,252,809 or International Publication No. WO 02/81879 A1, corresponding to U.S. Pat. No. 7,276,211, the entire contents of which are hereby incorporated by reference. In this context, it is in particular also possible to use radial catalytic converters with heating elements which, according to one particularly advantageous embodiment, can improve the cold start behavior of the catalytic converter body. In particular, such a heating element, for example in the form of a heating-type catalytic converter, is disposed upstream of the inlet of the housing or inside the inner space which is present in the radial catalytic converter.
  • In addition to the one exhaust gas inlet and exhaust gas outlet, it is also, of course, possible for a plurality of outlets and inlets to be provided in the housing. The catalytic converter body preferably has a cylindrical construction and has in its interior a cavity through which the exhaust gas can flow from the outlet of the housing. The exhaust gas is, if appropriate, diverted there by diversion devices so that it flows outward through the catalytic converter body in the radial direction and leaves the catalytic converter body through the outer circumferential surface. The at least one first flow path of the heat exchanger is preferably disposed directly on the outer circumferential surface of the catalytic converter body. Given an embodiment of the heat exchanger as a tube system, these tubes run, in particular, in the axial direction parallel to the central axis and are distributed uniformly over the outer circumferential surface of the catalytic converter body. A heat exchanging section over a particularly large surface is generated through such a preferred configuration of the heat exchanger so that the highest possible quantity of the thermal energy which is available in the exhaust gas is transmitted to the medium of the heat exchanger. The heat exchanger is preferably disposed in this case inside the annular channel which preferably surrounds the entire circumference of the catalytic converter body and is disposed between the outer circumferential surface of the catalytic body and the inner wall of the housing. The annular channel is embodied in such a way that it is preferably closed off with respect to the exhaust gas inlet, so that after flowing out of the catalytic converter body the exhaust gas is conducted away through the annular channel accompanied by a preceding and/or simultaneous flow around the heat exchanger in the direction of the exhaust gas outlet. In this context, the housing and the heat exchanger are provided, in particular, with guiding elements for the exhaust gas so that the smallest possible pressure loss due to eddying or other resistances in the exhaust gas stream is achieved. Furthermore, the heat exchanger can also be constructed as a planar hollow element which has, in particular, breakthroughs so that the exhaust gas can flow through and around the hollow element. In this context, a plurality of layers of these wall-shaped elements can also be disposed in combination with pipelines or tube lines between the catalytic converter body and the housing.
  • In accordance with a further feature of the invention, at least one second flow path is provided which at least partially penetrates the catalytic converter body, and in particular over its entire axial extent. The second flow path of the heat exchanger can have an identical construction to the first flow path in this case. In particular, it is disposed in the catalytic converter body in such a way that it is provided inside a radially outer section of the catalytic converter, so that the exhaust gas, coming from the inlet of the housing, overflows a first catalytically active region of the catalytic converter, and only then flows along the at least one second flow path of the heat exchanger. The catalytic converter body has, for the purpose of accommodating the at least one second flow path, in particular holes or cutouts, into which the structures which are provided for the second flow path can be inserted.
  • In accordance with an added feature of the invention, the heat exchanger is embodied at least in two stages and the at least one first flow path, which is disposed outside the catalytic converter body, is assigned to a first stage, and the at least one second flow path, which penetrates the catalytic converter body, is assigned to a second stage of the heat exchanger. Implementing the heat exchanger with two stages means, in particular, that the latter has two inflows or outflows through which the at least one first flow path or second flow path can be respectively separately supplied with a medium. In this context, the media can, however, be embodied in different ways or also in the same way. This preferred embodiment ensures that the heat exchanger has, in particular, at least two temperature ranges for the medium, the first temperature range caused by the configuration of the at least one first flow path and the second temperature range caused by the configuration of the at least one second flow path. The media which have different temperatures can then be fed, in the region of a thermo-electric generator, to the transducer elements which are particularly suitable for the respective temperature range. The energy efficiency of a thermo-electric generator or of the component according to the invention is therefore increased further. At the same time, the required volume of the medium which is used to supply thermal energies to the catalytic converter body at critical operating points of the internal combustion engine is kept very small since only the at least one second flow path of the heat exchanger is used to heat the catalytic converter body. It is not necessary in this case for a heated medium to heat and flow through the at least one first flow path. The most rapid possible heating, and therefore operational capability, of the catalytic converter body can be achieved by this advantageous embodiment.
  • In accordance with an additional feature of the component of the invention, the catalytic converter zones which are disposed in the region of the second flow path can also have relatively low specific thermal capacities so that they heat up more quickly, if appropriate, as a result of the medium, and therefore permit an operational capability of the catalytic converter within a relative short time.
  • In accordance with yet another feature of the component of the invention, the second flow path of the heat exchanger can also be embodied as a volume which is enclosed in itself without an inflow and outflow for a medium. In such a development, the second flow path is filled with a phase change material which can act as a latent heat storage device for the catalytic converter body. When the phase change material which is provided in the second flow path is heated, the material will change its phase state, for example from solid to liquid, through the absorption of a specific quantity of heat. Lowering the temperature of the catalytic converter body below the light-off temperature due to unfavorable operating points of the internal combustion engine and, in particular, in the case of a cold start can then be compensated through an outputting of heat of the phase change material due to a renewed change of phase, for example from liquid to solid. The catalytic converter body is heated and remains above the light-off temperature. With such an embodiment, a compensation volume which can absorb the change in volume of the medium due to the change of phase is to be provided within the second flow path.
  • In accordance with yet another feature of the component of the invention, the catalytic converter body has, opposite the at least one second flow path of the heat exchanger, at least one first compensation element which permits the catalytic converter body to expand in the radial direction. This is meant to refer in this case, in particular, to cutouts which can absorb expansion of the catalytic converter in the radial direction without loading the second flow paths of the heat exchanger with compressive stresses or displacing those flow paths. In addition to cutouts, it is also possible to provide structures in the at least partially structured metal foils of the catalytic converter body. The structures can compensate for radial expansion of the catalytic converter body due to the thermal stressing caused by bending or a certain degree of compressibility.
  • In accordance with yet a further feature of the component of the invention, the catalytic converter body has at least one second compensation element which permits the catalytic converter body to expand in the axial direction. These second compensation elements are, in particular, suitable for compensating for the expansion of the catalytic converter body in the axial direction in such a way that the flow paths which are provided for the exhaust gas are maintained. Furthermore, these second compensation elements are also intended to avoid tensile stresses or compressive stresses which could be transmitted to first or second flow paths. The second compensation elements are integrated, in particular, into holding elements which secure first and/or second flow paths in their position in the housing, in particular in the radial direction. For this purpose, the connections of the second compensation elements to the first flow path and/or to the second flow path can be embodied as sliding seats. According to another advantageous embodiment, the second compensation elements are integrated into the first and/or the second flow path. For this purpose, in particular the flow paths which are constructed in the form of pipelines or tube lines can have bends, or, for example, omega-shaped interlaced connections which permit axial mobility and therefore compensate for expansion of the catalytic converter body in the axial direction. In this case, the holding elements which secure the catalytic converter body and flow paths with respect to one another can also be embodied in a fixed fashion in the axial direction.
  • In accordance with yet an added feature of the invention, the at least one first flow path and/or the at least one second flow path have/has a catalytically active coating. In addition, regions of the inner wall of the housing or regions of the annular channel can also be provided with a catalytically active coating, with the result that, on one hand, the most complete conversion possible of the pollutants in the exhaust gas is achieved and, on the other hand, the largest possible quantity of thermal energy arising from the exothermic catalytic reaction of the exhaust gas can be conducted away to the heat exchanger. If appropriate, it is also possible to dispense with coating of the flow paths if the transfer of heat is made worse by the catalytic coating.
  • Coatings for oxidation catalytic converters are preferably provided for the catalytically active coating of the catalytic converter body or of the further regions of the component. An exothermic reaction, which increases the thermal energy in the exhaust gas, is generated in the catalytic converter body as a result of the catalytic conversion of components of the exhaust gas. This further increased thermal energy of the exhaust gas is conducted away by the medium through the heat exchanger and is advantageously converted outside the component into electrical energy. The catalytic converter body and the further regions can, if appropriate, be embodied with various coatings and/or catalysts.
  • With the objects of the invention in view, there is also provided a motor vehicle, especially a passenger car, comprising a component according to the invention.
  • With the objects of the invention in view, there is concomitantly provided a method for operating a component. The method comprises providing a component according to the invention, and heating the catalytic converter body, at least at certain times, by using the heat exchanger as a heating element.
  • Other features which are considered as characteristic for the invention are set forth in the appended claims, noting that the features which are specified individually in the claims can be combined with one another in any desired technically appropriate way and indicate further embodiments of the invention.
  • Although the invention is illustrated and described herein as embodied in an exhaust system component having a combination of a heat exchanger and a catalytic converter, a motor vehicle having the component and a method of operating the component, it is nevertheless not intended to be limited to the details shown, since various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims.
  • The construction and method of operation of the invention, however, together with additional objects and advantages thereof will be best understood from the following description of specific embodiments when read in connection with the accompanying drawings.
  • BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING
  • FIG. 1 is a diagrammatic, longitudinal-sectional view of a first embodiment variant of a component;
  • FIG. 2 is a cross-sectional view of the first embodiment variant of the component;
  • FIG. 3 is a perspective view of a metal foil of a catalytic converter body; and
  • FIG. 4 is a plan view of a motor vehicle in which components are integrated.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Referring now in detail to the figures of the drawing for explaining the invention and the technical field in more detail by showing particularly preferred structural variants to which the invention is not restricted, and first, particularly, to FIG. 1 thereof, there is seen a first embodiment variant of a component 1 in a longitudinal-sectional view. The component 1 has a housing 4 with a first end side 17 and a second end side 18. An inlet 5 for exhaust gas 7 is disposed at the first end side 17. The exhaust gas 7 passes through the inlet 5 into a cavity in a catalytic converter body 13. An outlet 6 for the exhaust gas 7 is provided on the second end side 18 of the housing 4 of the component 1. The catalytic converter body 13 extends parallel and concentrically with respect to a central axis 16 of the housing 4 of the component 1 and is represented herein as a catalytic converter body 13 through which there can be a radial flow. The exhaust gas 7 is diverted in the interior of the catalytic converter body 13 and flows through an inner circumferential surface 20 into a honeycomb body structure of the catalytic converter body 13. The exhaust gas 7 flows through the catalytic converter body 13 in the radial direction, flows out of the catalytic converter body through an outer circumferential surface 19 and impacts against a heat exchanger 11 in an annular channel 21. The heat exchanger 11 is represented in the right-hand half of the figure by a first flow path 15. In this connection, the heat exchanger 11 has a first thermal mass 12 and the catalytic converter body 13 has a second thermal mass 14. The heat exchanger 11 is illustrated in one embodiment as a pipeline through which a medium 10 flows. The pipelines of this first flow path 15 are configured in this case in such a way that irrespective of the configuration of an inflow 8 and of an outflow 9, a uniform flow through the pipelines over the entire volume of the heat exchanger 11 is obtained and therefore an optimum exchange of heat between the medium 10 and the exhaust gas 7 is made possible. The exhaust gas 7 is diverted in the region of the heat exchanger 11 in the annular channel 21 and flows around the heat exchanger 11 in the direction of the outlet 6 of the housing 4. The annular channel 21 is bounded by an inner wall 22 of the housing 4 and by the outer circumferential surface 19 of the catalytic converter body 13. The annular channel 21 is embodied so as to be closed off with respect to the first end side 17 of the housing 4 and so as to be open with respect to the second end side 18, so that the exhaust gas flows through the annular channel 21 in the direction of the outlet 6 of the housing 4.
  • In the left-hand half of the illustration in FIG. 1, an embodiment of the heat exchanger 11 is illustrated with a first flow path 15 and a second flow path 23. In this case, the second flow path 23 is disposed substantially inside the catalytic converter body 13. The first flow path 15 is connected to the inflow 8 through which the medium 10 is introduced. The medium 10 leaves the housing 4 through the outflow 9, after flowing through the first flow path 15. The inflow 8 and the outflow 9 for the second flow path 23 are not illustrated in FIG. 1. The latter can have a separate inflow 8 and outflow 9 or else be connected to the illustrated inflow 8 and outflow 9 so that the second flow path 23 is connected parallel to the first flow path 15.
  • The heat exchanger 11 can therefore be operated as a single-stage or as an at least two-stage heat exchanger. Given a parallel connection of the first flow path 15 and the second flow path 23, a single-stage heat exchanger 11 is implemented. Given an embodiment of the heat exchanger 11 with a separate inflow 8 and outflow 9 for the first flow path 15, on one hand, and at least the second flow path 23, on the other hand, a two-stage heat exchanger is implemented which can, in particular, supply differently temperature-conditioned media 10 to a thermo-electric generator so that thermal elements with maximum levels of efficiency for respectively different temperature ranges can be utilized as efficiently as possible. In this context, a first stage 25 of the heat exchanger 11 is formed by the first flow path 15, and a second stage 26 of the heat exchanger 11 is formed by the second flow path 23.
  • Furthermore, the component 1 has second compensation elements 29 which are, in particular, components of the catalytic converter body 13 and serve to secure the first flow path 15 and/or the second flow path 23. These second compensation elements 29 are suitable, in particular, for compensating for expansion of the catalytic converter body 13 in axial direction 30 due to thermal stressing by virtue of the fact that they are embodied in a particularly compressible fashion.
  • FIG. 2 is a diagrammatic view of a cross section through the first embodiment variant of the component 1. FIG. 2 is, in particular, an illustration of the fact that the exhaust gas 7 flows through the catalytic converter body 13 in a radial direction 28, and in this context is conducted, in particular, through structures 37 of metal foil 35 of the catalytic converter body 13 in predefined flow channels 36 from the inner circumferential surface 20 to the outer circumferential surface 19 of the catalytic converter body 13. In this illustration, the heat exchanger 11 is illustrated with a first flow path 15 and a second flow path 23, which together define a first thermal mass 12. The catalytic converter body 13 has a second thermal mass 14. The exhaust gas 7 flows through the catalytic converter body in the radial direction 28, and already impacts in the catalytic converter body 13 on the second flow path 23 of the heat exchanger 11, which is shown herein in a tubular configuration. In this context, first compensation elements 27 are provided which are intended to permit or compensate for expansion of the catalytic converter body 13 in the radial direction 28. These first compensation elements 27 can, in particular, be embodied as cutouts which are illustrated or as bendable or compressible structure elements of the metal foil 35. The exhaust gas 7 flows through the outer circumferential surface 19 of the catalytic converter body 13 into the annular channel 21 and flows in this case around the first flow path 15 of the heat exchanger 11 and is carried onward in the direction of the outlet 6 of the housing 4 through the annular channel 21 which is bounded, in particular, by the inner wall 22 of the housing 4 and the outer circumferential surface 19 of the catalytic converter body 13. The first flow path 15 and the second flow path 23 are illustrated herein in a two-stage embodiment of the heat exchanger 11, wherein the first flow path 15 is provided as a first stage 25 with an inflow 8 and an outflow 9 for a medium 10, and the second flow path 23 is embodied as a second stage 26, also with an inflow 8 and an outflow 9 for a medium 10. The medium 10 which is used for the first stage 25 can differ in this case, in particular, from the medium 10 used in the second stage 26 in that it has optimum thermal conduction properties and thermal transport properties for the respective temperature range. The first flow paths 15 or second flow paths 23 are each connected to one another and therefore connected in parallel so that a uniform flow through the first flow path 15 and the second flow path 23 is ensured over the entire volume of the heat exchanger 11. In particular, in the first flow paths 15 and the second flow paths 23, devices are provided which can bring about or improve homogenization of the flow of medium in the heat exchanger 11.
  • FIG. 3 is a diagrammatic, perspective view of a metal foil 35 of the catalytic converter body 13 which is manufactured, in particular, from a plurality of such metal foils which are stacked one on top of the other (in a manner which is not illustrated herein). Flow channels 36 are formed in this case in the radial direction 28 by at least partially present structures 37 of the metal foil 35. The exhaust gas 7, which flows into the catalytic converter body 13 along a central axis 16, is conducted through the flow channels 36 from the inner circumferential surface 20 to the outer circumferential surface 19 of the catalytic converter body 13.
  • FIG. 4 is a block diagram illustrating a preferred purpose for the use of such a component 1 in a motor vehicle 31 with an internal combustion engine 3. The exhaust gas 7 which is generated in the internal combustion engine 3, for example a spark ignition engine or a diesel engine, flows on into an exhaust system 2. In this context, the component 1 is advantageously connected directly downstream of the internal combustion engine 3. The component 1 may be part of the exhaust system 2 itself or, if appropriate, also part of an exhaust gas recirculation system 32, in which recourse can be particularly advantageously made to a radiator 33 by virtue of the fact that a temperature gradient between the medium 10 of the heat exchanger 11 of the component 1 and a cooling medium 39 of the radiator 33 can be harnessed as electrical energy within the scope of a thermo-electric generator 38. After being treated by the component 1, the exhaust gas 7 can also be supplied to an exhaust gas treatment unit 34 before it is discharged into the surroundings in a purified form.

Claims (10)

1. A component of an exhaust system for an internal combustion engine, the component comprising:
at least one housing having an inlet and an outlet for an exhaust gas and at least one inflow and one outflow for a medium; and
a heat exchanger around which the exhaust gas can flow, said heat exchanger having at least one first flow path for the medium, said heat exchanger having a first thermal mass and a catalytic converter body through which the exhaust gas can flow, said catalytic converter body having a second thermal mass;
said heat exchanger and said catalytic converter body being disposed together in said housing.
2. The component according to claim 1, wherein:
said housing has an inner wall, a central axis, a first end side and a second end side disposed along said central axis;
said inlet is disposed at said first end side and said outlet is disposed at said second end side;
said catalytic converter body is disposed along said central axis and has an outer circumferential surface and an inner circumferential surface extending parallel to said central axis;
said inner circumferential surface is fluidically connected directly to said inlet, permitting the exhaust gas to flow radially through said catalytic converter body from said inner circumferential surface to said outer circumferential surface;
said at least one first flow path at least partially surrounds said catalytic converter body at said outer circumferential surface; and
an annular channel is disposed at said inner wall of said housing, said annular channel is fluidically connected to said outer circumferential surface of said catalytic converter body and directly to said outlet, and said annular channel at least partially surrounds said catalytic converter body and said at least one first flow path.
3. The component according to claim 1, which further comprises at least one second flow path at least partially penetrating said catalytic converter body.
4. The component according to claim 3, wherein:
said heat exchanger has at least a first stage and a second stage;
said at least one first flow path is disposed outside said catalytic converter body and is associated with said first stage; and
said at least one second flow path, at least partially penetrating said catalytic converter body, is associated with said second stage of said heat exchanger.
5. The component according to claim 3, wherein said catalytic converter body has compensation elements, disposed opposite said at least one second flow path of said heat exchanger, for permitting said catalytic converter body to expand in radial direction.
6. The component according to claim 1, wherein said catalytic converter body has compensation elements for permitting said catalytic converter body to expand in axial direction.
7. The component according to claim 3, wherein:
said catalytic converter body has first compensation elements, disposed opposite said at least one second flow path of said heat exchanger, for permitting said catalytic converter body to expand in radial direction; and
said catalytic converter body has second compensation elements for permitting said catalytic converter body to expand in axial direction.
8. The component according to claim 3, which further comprises a catalytically active coating disposed on at least one of said at least one first flow path or said at least one second flow path.
9. A motor vehicle, comprising a component according to claim 1.
10. A method for operating a component, the method comprising the following steps:
providing a component according to claim 1; and
heating said catalytic converter body, at least at certain times, by using said heat exchanger as a heating element.
US13/036,192 2008-08-28 2011-02-28 Exhaust system component having a combination of a heat exchanger and a catalytic converter, motor vehicle having the component and method of operating the component Abandoned US20110192141A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008044711A DE102008044711A1 (en) 2008-08-28 2008-08-28 Combination of heat exchanger and catalyst as a component of an exhaust system
DE102008044711.0 2008-08-28
PCT/EP2009/060563 WO2010023118A1 (en) 2008-08-28 2009-08-14 Combination of a heat exchanger and catalyst as a component of an exhaust gas system

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/060563 Continuation WO2010023118A1 (en) 2008-08-28 2009-08-14 Combination of a heat exchanger and catalyst as a component of an exhaust gas system

Publications (1)

Publication Number Publication Date
US20110192141A1 true US20110192141A1 (en) 2011-08-11

Family

ID=41057314

Family Applications (1)

Application Number Title Priority Date Filing Date
US13/036,192 Abandoned US20110192141A1 (en) 2008-08-28 2011-02-28 Exhaust system component having a combination of a heat exchanger and a catalytic converter, motor vehicle having the component and method of operating the component

Country Status (8)

Country Link
US (1) US20110192141A1 (en)
EP (1) EP2324217B1 (en)
JP (1) JP2012500930A (en)
DE (1) DE102008044711A1 (en)
DK (1) DK2324217T3 (en)
ES (1) ES2387244T3 (en)
PL (1) PL2324217T3 (en)
WO (1) WO2010023118A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110223067A1 (en) * 2010-03-09 2011-09-15 Gm Global Technology Operations, Inc. Thermal management exhaust treatment device and method of manufacture
US20140373798A1 (en) * 2012-02-03 2014-12-25 Valeo Systemes De Controle Moteur Heat exchanger, in particular for a vehicle comprising a heat engine
US9279623B2 (en) 2011-04-13 2016-03-08 Emitec Gesellschaft Fuer Emissionstechnologie Mbh Device having a heat exchanger for a thermoelectric generator of a motor vehicle and motor vehicle having the device
US20180230884A1 (en) * 2015-10-23 2018-08-16 Ngk Insulators, Ltd. Exhaust heat recovery device
CN109563756A (en) * 2016-08-16 2019-04-02 大陆汽车有限公司 Component of exhaust system and method for exhaust aftertreatment
US10247144B2 (en) 2013-05-21 2019-04-02 Robert Bosch Gmbh Engine exhaust gas recirculation cooling system with integrated latent heat storage device
US20210215432A1 (en) * 2018-05-31 2021-07-15 Dow Global Technologies Llc Apparatus and method of use thereof
CN115540663A (en) * 2022-11-30 2022-12-30 广东高而美制冷设备有限公司 Phase change heat accumulator, air conditioning system and heat charging and taking method for air conditioning
US12098233B2 (en) 2018-05-31 2024-09-24 Dow Global Technologies Llc Devolatilizer design

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010012629A1 (en) * 2010-03-24 2011-09-29 Emitec Gesellschaft Für Emissionstechnologie Mbh Device comprising a catalyst carrier body and a thermoelectric generator arranged in a housing
CN102917794A (en) * 2010-05-31 2013-02-06 康宁股份有限公司 Honeycomb-body-based fluidic interconnectors and methods of making the same
DE102010062333A1 (en) * 2010-12-02 2012-06-06 Robert Bosch Gmbh Apparatus for supplying an exhaust aftertreatment system with a reducing agent
DE102011113307A1 (en) * 2011-09-14 2013-03-14 Emitec Gesellschaft Für Emissionstechnologie Mbh Thermoelectric generator with compact design
FR3010504B1 (en) * 2013-09-10 2017-12-15 Valeo Systemes Thermiques MODULE AND THERMO-ELECTRIC DEVICE, PARTICULARLY FOR GENERATING AN ELECTRICAL CURRENT IN A MOTOR VEHICLE
GB2523787B (en) * 2014-03-03 2016-10-19 Psj Tech Ltd Apparatus and method for thermal energy recovery
KR101563664B1 (en) 2014-03-14 2015-10-27 삼성중공업 주식회사 Apparatus for reducing methane
KR101616319B1 (en) * 2014-03-27 2016-04-28 삼성중공업 주식회사 Apparatus for reducing methane
DE102017220441B4 (en) * 2017-11-16 2025-12-11 Ford Global Technologies, Llc Internal combustion engine with cooled exhaust gas recirculation and energy recovery
EP3543637A1 (en) * 2018-03-22 2019-09-25 Casale Sa Shell and tube heat exchanger
DE102018208098A1 (en) 2018-05-23 2019-11-28 Continental Automotive Gmbh Honeycomb body and process for producing the honeycomb body

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5033264A (en) * 1989-06-16 1991-07-23 Tecogen Inc. Compact cogeneration system
US5531968A (en) * 1993-06-04 1996-07-02 Scambia Industrial Developments Ag Catalytic converter for the catalytic treatment of exhaust gas
US5645803A (en) * 1994-04-11 1997-07-08 Scambia Industrial Developments Aktiengesellschaft Catalyst means for the catalytic treatment of exhaust gas catalytic converter
US5809776A (en) * 1996-07-29 1998-09-22 Outboard Marine Corporation Catalytic converter with radial outflow and by-pass valve
US6564545B1 (en) * 2002-01-31 2003-05-20 Visteon Global Technologies, Inc. Superintegration of three way catalyst and heat exchanger for HCCI engine intake air temperature control
US6584760B1 (en) * 2000-09-12 2003-07-01 Hybrid Power Generation Systems, Inc. Emissions control in a recuperated gas turbine engine
US6702190B1 (en) * 2001-07-02 2004-03-09 Arvin Technologies, Inc. Heat transfer system for a vehicle
US6730274B1 (en) * 1999-03-04 2004-05-04 Honda Giken Koygo Kabushiki Kaisha Exhaust heat exchanger with catalyst
US7252809B2 (en) * 2000-11-14 2007-08-07 Emitec Gesellschaft Fuer Emissionstechnologie Mbh Radial-flow and segmented honeycomb body

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB797783A (en) * 1956-08-07 1958-07-09 Oxy Catalyst Inc Improvements in or relating to heaters for use with internal combustion engines
JPH06205939A (en) * 1993-01-07 1994-07-26 Mitsubishi Heavy Ind Ltd Exhaust gas purifier for internal combustion engine
JPH08158860A (en) * 1994-12-02 1996-06-18 Usui Internatl Ind Co Ltd Metal support
JPH08266868A (en) * 1995-03-29 1996-10-15 Kawasaki Heavy Ind Ltd Method and apparatus for removing nitrogen oxides
JP2001038195A (en) * 1999-06-28 2001-02-13 Basf Ag Reactor provided with heat-exchanger plate
DE10117086A1 (en) 2001-04-06 2002-10-17 Emitec Emissionstechnologie Process for producing a one-piece, structured sheet metal foil with a hole, sheet metal foil and honeycomb body
JP2003185379A (en) * 2001-12-25 2003-07-03 Honda Motor Co Ltd Heat exchanger
JP4010807B2 (en) * 2001-12-26 2007-11-21 三洋電機株式会社 Air conditioner
JP2007085266A (en) * 2005-09-22 2007-04-05 Toyota Motor Corp Exhaust heat exchanger

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5033264A (en) * 1989-06-16 1991-07-23 Tecogen Inc. Compact cogeneration system
US5531968A (en) * 1993-06-04 1996-07-02 Scambia Industrial Developments Ag Catalytic converter for the catalytic treatment of exhaust gas
US5645803A (en) * 1994-04-11 1997-07-08 Scambia Industrial Developments Aktiengesellschaft Catalyst means for the catalytic treatment of exhaust gas catalytic converter
US5809776A (en) * 1996-07-29 1998-09-22 Outboard Marine Corporation Catalytic converter with radial outflow and by-pass valve
US6730274B1 (en) * 1999-03-04 2004-05-04 Honda Giken Koygo Kabushiki Kaisha Exhaust heat exchanger with catalyst
US6584760B1 (en) * 2000-09-12 2003-07-01 Hybrid Power Generation Systems, Inc. Emissions control in a recuperated gas turbine engine
US7252809B2 (en) * 2000-11-14 2007-08-07 Emitec Gesellschaft Fuer Emissionstechnologie Mbh Radial-flow and segmented honeycomb body
US6702190B1 (en) * 2001-07-02 2004-03-09 Arvin Technologies, Inc. Heat transfer system for a vehicle
US6564545B1 (en) * 2002-01-31 2003-05-20 Visteon Global Technologies, Inc. Superintegration of three way catalyst and heat exchanger for HCCI engine intake air temperature control

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110223067A1 (en) * 2010-03-09 2011-09-15 Gm Global Technology Operations, Inc. Thermal management exhaust treatment device and method of manufacture
US8715580B2 (en) 2010-03-09 2014-05-06 GM Global Technology Operations LLC Thermal management exhaust treatment device and method of manufacture
US9279623B2 (en) 2011-04-13 2016-03-08 Emitec Gesellschaft Fuer Emissionstechnologie Mbh Device having a heat exchanger for a thermoelectric generator of a motor vehicle and motor vehicle having the device
US20140373798A1 (en) * 2012-02-03 2014-12-25 Valeo Systemes De Controle Moteur Heat exchanger, in particular for a vehicle comprising a heat engine
US10247144B2 (en) 2013-05-21 2019-04-02 Robert Bosch Gmbh Engine exhaust gas recirculation cooling system with integrated latent heat storage device
US20180230884A1 (en) * 2015-10-23 2018-08-16 Ngk Insulators, Ltd. Exhaust heat recovery device
US10494974B2 (en) * 2015-10-23 2019-12-03 Ngk Insulators, Ltd. Exhaust heat recovery device
CN109563756A (en) * 2016-08-16 2019-04-02 大陆汽车有限公司 Component of exhaust system and method for exhaust aftertreatment
US20190186317A1 (en) * 2016-08-16 2019-06-20 Continental Automotive Gmbh Component Of An Exhaust Gas System And Method For Exhaust Gas After-Treatment
US10837337B2 (en) * 2016-08-16 2020-11-17 Vitesco Technologies GmbH Component of an exhaust gas system and method for exhaust gas after-treatment
US20210215432A1 (en) * 2018-05-31 2021-07-15 Dow Global Technologies Llc Apparatus and method of use thereof
US12098233B2 (en) 2018-05-31 2024-09-24 Dow Global Technologies Llc Devolatilizer design
CN115540663A (en) * 2022-11-30 2022-12-30 广东高而美制冷设备有限公司 Phase change heat accumulator, air conditioning system and heat charging and taking method for air conditioning

Also Published As

Publication number Publication date
PL2324217T3 (en) 2012-10-31
ES2387244T3 (en) 2012-09-18
JP2012500930A (en) 2012-01-12
WO2010023118A1 (en) 2010-03-04
EP2324217A1 (en) 2011-05-25
DK2324217T3 (en) 2012-08-20
DE102008044711A1 (en) 2010-03-04
EP2324217B1 (en) 2012-05-16

Similar Documents

Publication Publication Date Title
US20110192141A1 (en) Exhaust system component having a combination of a heat exchanger and a catalytic converter, motor vehicle having the component and method of operating the component
JP5559153B2 (en) Device for generating electrical energy from exhaust gas heat
US9494063B2 (en) Exhaust gas system with circulation heat pipe
JP4085998B2 (en) Waste heat recovery device
CN103673676B (en) heat transfer unit
US8752369B2 (en) Latent heat storage catalyst for an exhaust system in an internal combustion engine
US9279623B2 (en) Device having a heat exchanger for a thermoelectric generator of a motor vehicle and motor vehicle having the device
EP1884634B1 (en) Support structure of exhaust system heat exchanger
US9127894B2 (en) Device having a heat exchanger for a thermoelectric generator of a motor vehicle and motor vehicle having the device
JP5893556B2 (en) Thermoelectric power generator, method of manufacturing thermoelectric power generator, and method of generating power using thermoelectric power generator
US20060107656A1 (en) Exhaust gas after-treatment unit with countercurrent housing and corresponding process for exhaust gas after-treatment
US8281573B2 (en) Evaporation unit for producing gaseous ammonia and device and motor vehicle having an evaporation unit
JPWO2019026560A1 (en) Heat recovery device and heat recovery system
US20140208725A1 (en) Heat exchanger of an internal combustion engine
US10837337B2 (en) Component of an exhaust gas system and method for exhaust gas after-treatment
CN104205384B (en) Thermoelectric generator with heat exchanger
JPH04347320A (en) Catalyst heating device
JP2015102041A (en) Thermoelectric generator
US20150325767A1 (en) Thermoelectric generator
EP2614878B1 (en) Electrically heated catalyst
WO2015060199A1 (en) Chemical heat storage device
US20120297753A1 (en) Exhaust system with heat accumulator
JP2015004457A (en) Chemical heat storage device
RU2735048C1 (en) Device for recuperating heat of waste gas
JP2016186229A (en) Exhaust emission control device

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION