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US20100004125A1 - Pesticidal Mixtures - Google Patents

Pesticidal Mixtures Download PDF

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Publication number
US20100004125A1
US20100004125A1 US12/525,319 US52531908A US2010004125A1 US 20100004125 A1 US20100004125 A1 US 20100004125A1 US 52531908 A US52531908 A US 52531908A US 2010004125 A1 US2010004125 A1 US 2010004125A1
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Prior art keywords
mixture
plants
compound
formula
species
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Inventor
Dirk Voeste
Egon Haden
Hassan Oloumi-Sadeghi
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BASF SE
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BASF SE
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Assigned to BASF SE reassignment BASF SE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: VOESTE, DIRK, HADEN, EGON, OLOUMI-SADEGHI, HASSAN
Assigned to BASF SE reassignment BASF SE CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S ADDRESS. DOCUMENT PREVIOUSLY RECORDED AT REEL 023101 FRAME 0017 Assignors: VOESTE, DIRK, HADEN, EGON, OLOUMI-SADEGHI, HASSAN
Publication of US20100004125A1 publication Critical patent/US20100004125A1/en
Abandoned legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to pesticidal mixtures comprising
  • the invention relates to a method for controlling phytopathogenic harmful fungi using mixtures of the compound I with the compound II and to the use of the compound I with the compound II for preparing such mixtures and compositions comprising these mixtures.
  • the present invention also relates to plant-protecting mixtures and to a method of improving the health of plants by applying said mixtures to the plants or the locus thereof.
  • the invention relates to a method of controlling fungi and/or improving the health of plants, which comprises treating a site, for example a plant or a plant propagation material, that is infested or liable to be infested by fungi with the pesticides pre-sent in a inventive mixture in any desired sequence or simultaneously, that is, jointly or separately.
  • the invention relates to a method of controlling harmful insects or nematodes, which comprises treating a site, for example a plant or a plant propagation material, that is infested or liable to be infested by said pests with the pesticides present in a inventive mixture in any desired sequence or simultaneously, that is, jointly or separately.
  • Another problem encountered concerns the need to have available pest control agents which are effective against a broad spectrum of pests and pathogens.
  • compositions that improve plants a process which is commonly and hereinafter referred to as “plant health”.
  • plant health a process which is commonly and hereinafter referred to as “plant health”.
  • advantageous properties are improved crop characteristics including: emergence, crop yields, protein content, oil content, starch content, more developed root system (improved root growth), improved stress tolerance (e.g.
  • tillering increase, increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, greener leaf color, pigment content, photosynthetic activity, less input needed (such as fertilizers or water), less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, enhanced plant vigor, increased plant stand and early and better germination; or any other advantages familiar to a person skilled in the art.
  • Another difficulty in relation to the use of pesticides is that the repeated and exclusive application of an individual pesticidal compound leads in many cases to a rapid selection of pests or pathogens that have developed natural or adapted resistance against the active compound in question.
  • EP-A 0 545 834 discloses a mixture of triticonazole with imidacloprid.
  • WO 99/63826 discloses mixtures of clothianidine with other fungicides except Azolyl-methylcycloalkanes.
  • the compounds of formulae I and II are capable of forming salts or adducts with inorganic or organic acids or with metal ions.
  • inorganic acids examples include hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, sulfuric acid, phosphoric acid and nitric acid.
  • Suitable organic acids are, for example, formic acid, carbonic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, p-toluenesulfonic acid, salicylic acid, p-aminosalicylic acid, 2-phenoxybenzoic acid or 2-acetoxybenzoic acid.
  • formic acid carbonic acid and alkanoic acids
  • acetic acid such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid
  • glycolic acid lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, p-toluenesulfonic acid, salicylic acid, p-aminosalicylic acid, 2-phen
  • Suitable metal ions are in particular the ions of the elements of the first to eighth transition group, especially chromium, manganese, iron, cobalt, nickel, copper, zinc, and additionally those of the second main group, especially calcium and magnesium, and of the third and fourth main group, in particular aluminum, tin and lead. If appropriate, the metals can be present in the different valencies that they can assume.
  • the active compounds mentioned above can also be employed in the form of their agriculturally compatible salts. These are usually the alkali metal or alkaline earth metal salts, such as sodium, potassium or calcium salts.
  • mixtures of the compound of formula I and the compound of formula II are used. Under certain conditions, it may be advantageous to combine the mixture with further active compounds II. Mixtures of three or more compounds may be suitable.
  • the pure active compounds which, if required, may be mixed with further active compounds III against harmful fungi or other pests, such as insects, arachnids or nematodes, or else herbicidal or growth-regulating active compounds or fertilizers as further active components.
  • Preferred further fungicides III are those selected from the group consisting of
  • carbamates diethofencarb, flubenthiavalicarb, iprovalicarb, propamocarb, valiphenal, N-(1-(1-(4-cyanophenyl)ethanesulfonyl)-but-2-yl) carbamic acid-(4-fluorophenyl) ester;
  • More preferred further fungicides are those selected from the group consisting of
  • carboxamides such as boscalid, carboxin, metalaxyl, oxadixyl, dimethomorph; silthiofam, mandipropamid;
  • active compounds selected from inorganic active compounds: sulphur, Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate; others: guazatine, streptomycin.
  • Preferred further insecticides III are those selected from the groups consisting of
  • Carbamates aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxy-carboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, triazamate; A.3.
  • Pyrethroids acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-, yfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flu-cythrinate, flu
  • Juvenile hormone mimics hydroprene, kinoprene, methoprene, fenoxycarb, pyriproxyfen; A.5. Nicotinic receptor agonists/antagonists compounds: acetamiprid, bensultap, cartap hydrochloride, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, nicotine, spinosad (allosteric agonist), thiacloprid, thiocyclam, thiosultap-sodium, the thiazol compound of formula ( 1 )
  • A.6. GABA gated chloride channel antagonist compounds chlordane, endosulfan, gamma-HCH (lindane); acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, vaniliprole, 5-Amino-1-(2,6-dichloro-4-trifluoromethyl-phenyl)-4-trifluoromethanesulfinyl-1H-pyrazole-3-carbothioic acid amide
  • Chloride channel activators abamectin, emamectin benzoate, milbemectin, lepimectin; A.8.
  • METI I compounds fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, rotenone; A.9.
  • METI II and III compounds acequinocyl, fluacyprim, hydramethylnon; A.10.
  • Uncouplers of oxidative phosphorylation chlorfenapyr, DNOC; A.11.
  • Inhibitors of oxidative phosphorylation azocyclotin, cyhexatin, diafenthiuron, fenbutatin oxide, propargite, tetradifon; A.12.
  • Moulting disruptors cyromazine, chromafenozide, halofenozide, methoxyfenozi-de, tebufenozide; A.13.
  • Synergists piperonyl butoxide, tribufos; A.14.
  • Sodium channel blocker compounds indoxacarb, metaflumizone; A.15.
  • Fumigants methyl bromide, chloropicrin sulfuryl fluoride; A.16.
  • Selective feeding blockers crylotie, pymetrozine, flonicamid; A.17.
  • Mite growth inhibitors clofentezine, hexythiazox, etoxazole; A.18.
  • Chitin synthesis inhibitors buprofezin, bistrifluoron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron; A.19.
  • Lipid biosynthesis inhibitors spirodiclofen, spiromesifen, spirotetramat; A.20. octapaminergic agonsits: amitraz; A.21. ryanodine receptor modulators: flubendiamide; A.22.
  • aluminium phosphide amidoflumet, benclothiaz, benzoximate, bifenazate, borax, bromopropylate, cyanide, cyenopyrafen, cyflumetofen, chinomethionate, dicofol, fluoroacetate, phosphine, pyridalyl, pyrifluquinazon, sulfur, tartar emetic; A.23.
  • Anthranilamides chloranthraniliprole, 5-Bromo-2-(3-chloro-pyridin-2-yl)-2H-pyrazole-3-carboxylic acid (4-cyano-2-methyl-6-methylcarbamoyl-phenyl)-amide; A.25.
  • Microbial disruptors Bacillus thuringiensis subsp. Israelensi, Bacillus sphaericus, Bacillus thuringiensis subsp. Aizawai, Bacillus thuringiensis subsp. Kurstaki, Bacillus thuringiensis subsp. Tenebrionis.
  • a preferred embodiment of the invention relates to mixtures of the compounds of formulae I and II with a compound III from the group of the carbamates as defined above.
  • Carbamates are preferably selected from carbofuran, carbosulfan, and thiodicarb.
  • Another preferred embodiment of the invention relates to mixtures of the compounds of formulae I and II with a compound III from the group of the pyrethroids as defined above.
  • Pyrethroids are preferably selected from bifenthrin, cyfluthrin, cypermethrin, alpha-cypermethrin, and tefluthrin.
  • Nicotinic receptor agonists/antagonists compounds are preferably selected from acetamiprid, dinotefuran, imidacloprid, spinosad, thiamethoxam, and thiacloprid.
  • Another preferred embodiment of the invention relates to mixtures of the compounds of formulae I and II with a compound III from the group of the GABA gated chloride channel antagonist compounds as defined in the outset.
  • a preferred GABA gated chloride channel antagonist compound is fipronil.
  • the mixtures according to the invention are used for combating harmful fungi and harmful insects or nematodes.
  • the mixtures according to the invention are used for combating harmful fungi.
  • the mixtures according to the invention are used for combating harmful insects or nematodes.
  • the mixtures according to the invention are used for a method of controlling fungi and/or improving the health of plants, which comprises treating a site, for example a plant or a plant propagation material, that is infested or liable to be infested by fungi with the compound of formula I, and the compound II, in any desired sequence or simultaneously, that is, jointly or separately.
  • the mixtures according to the invention are used for a method of controlling harmful insects or nematodes, which comprises treating a site, for example a plant or a plant propagation material, that is infested or liable to be infested by fungi with the compound of formula I, and the compound II, in any desired sequence or simultaneously, that is, jointly or separately.
  • the mixtures according to the invention are used for a method of improving the health of plants, which comprises treating a site, for example a plant or a plant propagation material, that is infested or liable to be infested by fungi with the compound of formula I, and the compound II, in any desired sequence or simultaneously, that is, jointly or separately.
  • the application the compound of formula I, and the compound II, can be made in the absence of pest pressure.
  • the mixtures according to the invention comprise the compound of formula I and compound of formula II in a synergistic effective amount and are used for improving the health of plants.
  • Such method can be applied under pest pressure or in the absence of pest pressure.
  • the mixtures according to the invention are used for for foliar application in living crops of plants, for soil applications prior to sowing or planting, including overall soil treatment and furrow applications, as well as, in particular, for dressing applications on plant propagation material.
  • the latter term embraces seeds of all kinds (fruit, tubers, grains), cuttings, cut shoots and the like.
  • One particular field of application is the treatment of all kinds of seeds.
  • the mixtures according to the invention are especially important for controlling a large number of fungi and insects or nematodes on a variety of crop plants such as wheat, corn, rye, barley, oats, sorghum, rice, maize, grass, bananas, cotton, soy beans, coffee, sugar cane, grapevines, fruit species, ornamentals and vegetables such as cucumbers, beans, drybeans, tomatoes, potatoes, lettuce, cucurbits, cabbage, carrots, cruciferous, sunflowers and cucurbits, and on the seeds of these plants or on pasture and on seeds of pasture.
  • the mixtures according to the present invention are applied on soybeans.
  • the mixtures according the present invention are applied on seeds.
  • the mixtures according to the present invention are applied on seeds of soybeans.
  • the mixtures are suitable for controlling each of the following harmful fungi:
  • inventive mixtures are suitable for combating pests of the orders Coleoptera, Lepidoptera, Thysanoptera, Homoptera, Isoptera , and Orthoptera.
  • Plant parasitic nematodes such as Meloidogyne, Globodera, Heterodera, Radopholus, Rotylenchulus, Pratylenchus and other genera.
  • Suitable targets for seed treatment are various crop seeds, fruit species, vegetables, spices and ornamental seed, for example corn/maize (sweet and field), durum wheat, soybean, wheat, barley, oats, rye, triticale, bananas, rice, cotton, sunflower, potatoes, pasture, alfalfa, grasses, turf, sorghum, rapeseed, Brassica spp., sugar beet, egg-plants, tomato, lettuce, iceberg lettuce, pepper, cucumber, squash, melon, bean, dry-beans, peas, leek, garlic, onion, cabbage, carrot, tuber such as sugar cane, tobacco, coffee, turf and forage, cruciferous, cucurbits, grapevines, pepper, fodder beet, oil seed rape, pansy, impatiens, petunia and geranium.
  • corn/maize sweet and field
  • durum wheat soybean, wheat, barley, oats, rye, triticale, banana
  • seed treatment comprises all suitable seed treatment techniques known in the art, such as, but not limited to, seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multilayer coating, seed encrusting, seed dripping, and seed pelleting.
  • the active ingredient mixtures according to the invention are especially advantageous for seed treatment of oil seed rape, wheat, corn, rye, barley, oats, sorghum, sunflowers, rice, maize, turf and forage, cotton, sugar beet, beans, peas, soybeans, ornamentals, and vegetables such as cucurbits, tomatoes, eggplant, potatoes, pepper, lettuce, cabbage, carrots, cruciferous.
  • Especially preferred is the seed treatment of oil seed rape, wheat, beans, corn, soybeans, cotton, sorghum, sugar beet, rice, vegetables, and ornamentals.
  • the mixtures according to the invention are most preferably used for the seed treatment of oil seed rape.
  • mixtures according to the invention may also be used in crops which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods.
  • mixtures according to the invention can be employed in transgenic crops which are resistant to herbicides from the group consisting of the sulfonylureas, imida-zolinones, glufosinate-ammonium or glyphosate-isopropylammonium and analogous active substances (see for example, EP-A 242 236, EP-A 242 246) (WO 92/00377) (EP-A 257 993, U.S. Pat. No. 5,013,659) or in transgenic crop plants, for example cotton, with the capability of producing Bacillus thuringiensis toxins (Bt toxins) which make the plants resistant to certain pests (EP-A 142 924, EP-A 193 259).
  • herbicides from the group consisting of the sulfonylureas, imida-zolinones, glufosinate-ammonium or glyphosate-isopropylammonium and analogous active substances
  • Bt toxins Bacillus
  • mixtures according to the invention can be used also for the treatment of plants which have modified characteristics in comparison with existing plants consist, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures).
  • a number of cases have been described of recombinant modifications of crop plants for the purpose of modifying the starch synthesized in the plants (e.g. WO 92/11376, WO 92/14827, WO 91/19806) or of transgenic crop plants having a modified fatty acid composition (WO 91/13972).
  • the compounds of formula I and II and optionally the further active ingredient(s) can be applied simultaneously, that is jointly or separately, or in succession; the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
  • the compounds of formula I and II are usually applied in an effective amount, preferably in a weight ratio of from 100:1 to 1:100, in particular from 20:1 to 1:20, preferably from 10:1 to 1:10.
  • the mixture of compounds of formula I and II and the further active compound III are usually applied in an effective amount, preferably in a weight ratio of from 1000:1 to 1:1000.
  • the application rates of the mixtures according to the invention are, especially in the case of areas under agricultural cultivation, from 5 to 2 000 g/ha, preferably from 50 to 1 500 g/ha, in particular from 50 to 750 g/ha.
  • the application rates of the compound of formula I are from 1 g to 1 kg/ha, preferably from 10 to 900 g/ha, in particular from 20 to 750 g/ha.
  • the application rates of the compound of formula II are from 1 g to 1 kg/ha, preferably from 10 to 750 g/ha, in particular from 20 to 500 g/ha.
  • the application rates of the further active compound III are from 1 g to 1 kg/ha, preferably from 5 to 900 g/ha, in particular from 10 to 750 g/ha.
  • the application rates of the mixture according to the invention are generally from 3 kg: 30 g a.i./100 kg, 100 g: 1 g a.i./100 kg, 30 g :3 kg a.i./100 kg or 1 g: 10 g a.i./100 kg.
  • the rates can be higher.
  • a further embodiment of the present invention is directed to the seeds being treated with the mixture according to the present invention.
  • novel active ingredient mixtures have very advantageous curative, preventive and systemic fungicidal properties for protecting cultivated plants.
  • said active ingredient mixtures can be used to inhibit or destroy the pathogens that occur on plants or parts of plants (fruit, blossoms, leaves, stems, tubers, roots) of different crops or useful plants, while at the same time those parts of plants which grow later are also protected from attack by such pathogens.
  • Active ingredient mixtures have the special advantage of being highly active against diseases in the soil that mostly occur in the early stages of plant development.
  • the separate or joint application of the compounds of formula I and compounds II and optionally of the further active ingredient or of a mixture according to the invention is carried out by treating the seeds, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
  • the active compounds, and the mixtures according to the invention can be prepared, for example, in the form of directly sprayable solutions, powders and suspensions or in the form of highly concentrated aqueous, oily or other suspensions, dispersions, emulsions, oil dispersions, pastes, dusts, compositions for spreading or granules, and be applied by spraying, atomizing, dusting, broadcasting or watering or colored suspension, solution, emulsion to be applied as such or as water based slurry with seed treatment machinery.
  • the use form depends on the particular purpose; in each case, it should ensure a distribution of the mixture according to the invention, which is as fine and uniform as possible.
  • the active compounds, and the mixtures can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the compound according to the invention.
  • the formulations are prepared in a known manner (see e.g. for review U.S. Pat. No. 3,060,084, EP-A 707 445 (for liquid concentrates), Browning, “Agglomeration”, Chemical Engineering, Dec. 4, 1967,147-48, Perry's Chemical Engineer's Handbook, 4th Ed., McGraw-Hill, New York, 1963, pages 8-57 and et seq. WO 91/13546, U.S. Pat. No. 4,172,714, U.S. Pat. No. 4,144,050, U.S. Pat. No. 3,920,442, U.S. Pat. No. 5,180,587, U.S. Pat. No. 5,232,701, U.S. Pat. No.
  • auxiliaries suitable for the formulation of agrochemicals such as solvents and/or carriers, if desired emulsifiers, surfactants and dispersants, preservatives, anti-foaming agents, anti-freezing agents, for seed treatment formulation also optionally colorants and/or binders and/or gelling agents.
  • solvents examples include water, aromatic solvents (for example Solvesso products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters.
  • aromatic solvents for example Solvesso products, xylene
  • paraffins for example mineral oil fractions
  • alcohols for example methanol, butanol, pentanol, benzyl alcohol
  • ketones for example cyclohexanone, gamma-butyrolactone
  • NMP pyrrolidones
  • acetates glycols
  • fatty acid dimethylamides examples of fatty acids and fatty acid esters.
  • Suitable emulsifiers are nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates).
  • dispersants examples include lignin-sulfite waste liquors and methylcellulose.
  • Suitable surfactants used are alkali metal, alkaline earth metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalene-sulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl poly
  • Substances which are suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, highly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone or water.
  • mineral oil fractions of medium to high boiling point such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin
  • anti-freezing agents such as glycerin, ethylene glycol, propylene glycol and bactericides such as can be added to the formulation.
  • Suitable antifoaming agents are for example antifoaming agents based on silicon or magnesium stearate.
  • Suitable preservatives are for example dichlorophen und enzylalkoholhemiformal.
  • Seed Treatment formulations may additionally comprise binders and optionally colorants.
  • Binders can be added to improve the adhesion of the active materials on the seeds after treatment.
  • Suitable binders are block copolymers EO/PO surfactants but also polyvinylalcoholsl, polyvinylpyrrolidones, polyacrylates, polymethacrylates, polybutenes, polyisobutylenes, polystyrene, polyethyleneamines, polyethyleneamides, polyethyleneimines (Lupasol®, Polymin®), polyethers, polyurethans, polyvinylacetate, ty-lose and copolymers derived from these polymers.
  • colorants can be included in the formulation.
  • Suitable colorants or dyes for seed treatment formulations are Rhodamin B, C.I. Pigment Red 112, C.I. Solvent Red 1, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.
  • Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with a solid carrier.
  • Granules for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to solid carriers.
  • solid carriers examples include mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, for example, ammonium sulfate, ammonium phosphate
  • the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the active compound(s).
  • the active compound(s) are employed in a purity of from 90% to 100% by weight, preferably 95% to 100% by weight (according to NMR spectrum).
  • respective formulations can be diluted 2-10 fold leading to concentrations in the ready to use preparations of 0,01 to 60% by weight active compound by weight, preferably 0, 1 to 40% by weight.
  • the compound(s) of formula I, and the mixtures can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading or pouring.
  • the use forms depend entirely on the intended purposes; they are intended to ensure in each case the finest possible distribution of the active compound(s) according to the invention.
  • Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water.
  • emulsions, pastes or oil dispersions the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier.
  • concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil and such concentrates are suitable for dilution with water.
  • the active compound concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1% per weight.
  • the active compound(s) may also be used successfully in the ultra-low-volume process (ULV), it being possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compound without additives.
  • UUV ultra-low-volume process
  • the active compound(s) 10 parts by weight of the active compound(s) are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetters or other auxiliaries are added. The active compound(s) dissolves upon dilution with water, whereby a formulation with 10% (w/w) of active compound(s) is obtained.
  • Emulsions EW, EO, ES
  • 25 parts by weight of the active compound(s) are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight).
  • This mixture is introduced into 30 parts by weight of water by means of an emulsifier machine (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion, whereby a formulation with 25% (w/w) of active compound(s) is obtained.
  • an emulsifier machine e.g. Ultraturrax
  • 50 parts by weight of the active compound(s) are ground finely with addition of 50 parts by weight of dispersants and wetters and made as water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active compound(s), whereby a formulation with 50% (w/w) of active compound(s) is obtained.
  • 75 parts by weight of the active compound(s) are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetters and silica gel. Dilution with water gives a stable dispersion or solution of the active compound(s), whereby a formulation with 75% (w/w) of active compound(s) is obtained.
  • 0.5 part by weight of the active compound(s) is ground finely and associated with 95.5 parts by weight of carriers, whereby a formulation with 0.5% (w/w) of active compound(s) is obtained.
  • Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted for foliar use.
  • Conventional seed treatment formulations include for example flowable concentrates FS, solutions LS, powders for dry treatment DS, water dispersible powders for slurry treatment WS, water-soluble powders SS and emulsion ES and EC and gel formulation GF. These formulation can be applied to the seed diluted or undiluted. Application to the seeds is carried out before sowing, either directly on the seeds.
  • a FS formulation is used for seed treatment.
  • a FS formulation may comprise 1-800 g/l of active ingredient, 1-200 g/l Surfactant, 0 to 200 g/l antifreezing agent, 0 to 400 g/l of binder, 0 to 200 g/l of a pigment and up to 1 liter of a solvent, preferably water.
  • the active compound concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1%.
  • the active compounds may also be used successfully in the ultra-low-volume process (ULV), it being possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compound without additives.
  • UUV ultra-low-volume process
  • oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate not until immediately prior to use (tank mix).
  • These agents can be admixed with the agents according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.
  • Suitable adjuvants in this sense are in particular: organically modified polysiloxanes, for example Break Thru S 240®; alcohol alkoxylates, for example Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30®; EO/PO block polymers, for example Pluronic RPE 2035® and Genapol B®; alcohol ethoxylates, for example Lutensol XP 80®; and sodium dioctylsulfosuccinate, for example Leophen RA®.
  • organically modified polysiloxanes for example Break Thru S 240®
  • alcohol alkoxylates for example Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30®
  • EO/PO block polymers for example Pluronic RPE 2035® and Genapol B®
  • alcohol ethoxylates for example Lutensol XP 80®
  • the testing of the mixtures according to the present invention shows that said mixtures are effective in controlling fungi and/or insects and/or nematodes, and improving plant health.
  • the compounds were dissolved with DMSO in a concentration about 10000 ppm a.i.
  • the stock solutions were pipetted onto a micro titer plate (MTP) and diluted with water to the given concentrations.
  • a spore suspension of Pyricularia oryzae in a 2% aqueous biomalt solution was added then.
  • the plates were placed in a water vapor-saturated chamber at a temperature of 18° C.
  • the MTPs were measured at 405 nm 7 days after the inoculation.
  • the measured parameters were compared to the growth of the active compound-free control variant and the fungus-free and active compound-free blank value to determine the relative growth in % of the pathogens in the individual active compounds.
  • the efficacy (E) is calculated as follows using Abbot's formula:
  • ⁇ corresponds to the fungicidal infection of the treated plants in % and ⁇ corresponds to the fungicidal infection of the untreated (control) plants in %
  • An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants are not infected.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
US12/525,319 2007-02-05 2008-02-04 Pesticidal Mixtures Abandoned US20100004125A1 (en)

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US88811207P 2007-02-05 2007-02-05
PCT/EP2008/051334 WO2008095891A1 (en) 2007-02-05 2008-02-04 Pesticidal mixtures
US12/525,319 US20100004125A1 (en) 2007-02-05 2008-02-04 Pesticidal Mixtures

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WO2010043552A1 (en) * 2008-10-16 2010-04-22 Basf Se Pesticidal mixtures comprising metaflumizone and an azole fungicide
JP5365159B2 (ja) * 2008-11-25 2013-12-11 住友化学株式会社 有害生物防除用組成物及び有害生物の防除方法
EP2484210A1 (en) 2011-02-08 2012-08-08 Basf Se Pesticidal compositions
CN103283768B (zh) * 2012-03-05 2016-06-08 陕西韦尔奇作物保护有限公司 一种含灭菌唑的农药组合物
CN102875257B (zh) * 2012-10-23 2014-11-05 广西田园生化股份有限公司 一种防治甘蔗螟虫的药肥颗粒剂
CN104938517A (zh) * 2015-06-17 2015-09-30 广东中迅农科股份有限公司 含有吡唑醚菌酯和灭菌唑以及噻虫胺的悬浮种衣剂
CN106070294B (zh) * 2016-06-14 2018-10-26 泉州橙天贸易有限公司 一种含噻虫胺和唑蚜威的农药组合物
CN112273392A (zh) * 2020-11-03 2021-01-29 中诚国联（河南）生物科技有限公司 含噻虫胺和吡虫啉的药肥颗粒剂在防治花生蛴螬中的应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2754424A1 (fr) * 1996-10-16 1998-04-17 Rhone Poulenc Agrochimie Composition fongicide synergique comprenant un compose triazole
US6680325B2 (en) * 1998-06-10 2004-01-20 Bayer Aktiengesellschaft Agents for combating plant pests
US20050009703A1 (en) * 2001-08-16 2005-01-13 Ulrike Wachendorff-Neumann Fungicidal active substance combinations containing trifloxystrobin
WO2006066810A2 (de) * 2004-12-20 2006-06-29 Basf Aktiengesellschaft Verfahren zur bekämpfung von pilzkrankheiten bei leguminosen
WO2006089876A1 (en) * 2005-02-22 2006-08-31 Basf Aktiengesellschaft Composition and method for improving plant health

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1893023A2 (en) * 2004-08-17 2008-03-05 Syngeta Participations AG Aqueous neonicotinoid compositions for seed treatment
US20080194599A1 (en) * 2005-05-31 2008-08-14 Syngenta Crop Protection, Inc. Method of Mollusc Control

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2754424A1 (fr) * 1996-10-16 1998-04-17 Rhone Poulenc Agrochimie Composition fongicide synergique comprenant un compose triazole
US6680325B2 (en) * 1998-06-10 2004-01-20 Bayer Aktiengesellschaft Agents for combating plant pests
US20050009703A1 (en) * 2001-08-16 2005-01-13 Ulrike Wachendorff-Neumann Fungicidal active substance combinations containing trifloxystrobin
WO2006066810A2 (de) * 2004-12-20 2006-06-29 Basf Aktiengesellschaft Verfahren zur bekämpfung von pilzkrankheiten bei leguminosen
US20080153824A1 (en) * 2004-12-20 2008-06-26 Basf Aktiengesellschaft Method for Controlling Fungal Diseases in Leguminous Plants
WO2006089876A1 (en) * 2005-02-22 2006-08-31 Basf Aktiengesellschaft Composition and method for improving plant health

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CABA abstract 2001:3472 (2001). *
Derwent abstract 1998-253287, abstracting FR 2754424 (1998). *

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EP2117314A1 (en) 2009-11-18
IL199854A0 (en) 2010-04-15
CR10954A (es) 2009-08-12
AU2008212957A1 (en) 2008-08-14
WO2008095891A1 (en) 2008-08-14
CA2675363A1 (en) 2008-08-14
CL2008000361A1 (es) 2008-06-13
CN101610677A (zh) 2009-12-23
PE20081414A1 (es) 2008-12-05
KR20090108732A (ko) 2009-10-16
ECSP099613A (es) 2009-10-30
EA200901036A1 (ru) 2010-02-26
BRPI0806949A2 (pt) 2014-05-06
MX2009007566A (es) 2009-07-22
TW200845903A (en) 2008-12-01
AR065170A1 (es) 2009-05-20
JP2010517975A (ja) 2010-05-27

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