US20090181148A1 - Shelf-stable milk concentrates for preparing acidified milk based beverages - Google Patents
Shelf-stable milk concentrates for preparing acidified milk based beverages Download PDFInfo
- Publication number
- US20090181148A1 US20090181148A1 US12/302,574 US30257407A US2009181148A1 US 20090181148 A1 US20090181148 A1 US 20090181148A1 US 30257407 A US30257407 A US 30257407A US 2009181148 A1 US2009181148 A1 US 2009181148A1
- Authority
- US
- United States
- Prior art keywords
- milk
- base composition
- weight
- carbohydrate
- sweetener
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
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- 235000013336 milk Nutrition 0.000 title claims abstract description 34
- 239000008267 milk Substances 0.000 title claims abstract description 34
- 210000004080 milk Anatomy 0.000 title claims abstract description 34
- 235000020167 acidified milk Nutrition 0.000 title claims abstract description 25
- 239000012141 concentrate Substances 0.000 title description 17
- 239000000203 mixture Substances 0.000 claims abstract description 105
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 39
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 39
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 39
- 235000014633 carbohydrates Nutrition 0.000 claims abstract description 39
- 235000021239 milk protein Nutrition 0.000 claims abstract description 39
- 235000000346 sugar Nutrition 0.000 claims abstract description 38
- 239000003381 stabilizer Substances 0.000 claims abstract description 36
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000003599 food sweetener Nutrition 0.000 claims abstract description 26
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- 238000010438 heat treatment Methods 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 14
- 239000000796 flavoring agent Substances 0.000 claims description 14
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 10
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 11
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 10
- 239000005720 sucrose Substances 0.000 description 10
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- 102000011632 Caseins Human genes 0.000 description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 4
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- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- 108010011485 Aspartame Proteins 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 229920000084 Gum arabic Polymers 0.000 description 3
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Chemical compound OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 3
- 239000000205 acacia gum Substances 0.000 description 3
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- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 3
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- 239000005018 casein Substances 0.000 description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 3
- 235000021240 caseins Nutrition 0.000 description 3
- 238000004925 denaturation Methods 0.000 description 3
- 230000036425 denaturation Effects 0.000 description 3
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- 239000000416 hydrocolloid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 210000002966 serum Anatomy 0.000 description 3
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- 229940088594 vitamin Drugs 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 235000008939 whole milk Nutrition 0.000 description 3
- 235000019737 Animal fat Nutrition 0.000 description 2
- 240000008886 Ceratonia siliqua Species 0.000 description 2
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 235000021243 milk fat Nutrition 0.000 description 2
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- 238000005086 pumping Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 244000298697 Actinidia deliciosa Species 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 102000004506 Blood Proteins Human genes 0.000 description 1
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- 244000060011 Cocos nucifera Species 0.000 description 1
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
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- 229930195725 Mannitol Natural products 0.000 description 1
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- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000004376 Sucralose Substances 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
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- 239000000619 acesulfame-K Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000008122 artificial sweetener Substances 0.000 description 1
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- 108010033929 calcium caseinate Proteins 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 239000008103 glucose Substances 0.000 description 1
- -1 gums Substances 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 235000019534 high fructose corn syrup Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
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- 239000008101 lactose Substances 0.000 description 1
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
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- 239000002689 soil Substances 0.000 description 1
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- 238000003756 stirring Methods 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/156—Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners
- A23C9/1565—Acidified milk products, e.g. milk flavoured with fruit juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B11/00—Preservation of milk or dairy products
- A23B11/10—Preservation of milk or milk preparations
- A23B11/12—Preservation of milk or milk preparations by heating
- A23B11/13—Preservation of milk or milk preparations by heating the materials being loose unpacked
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C1/00—Concentration, evaporation or drying
- A23C1/14—Concentration, evaporation or drying combined with other treatment
- A23C1/16—Concentration, evaporation or drying combined with other treatment using additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/154—Milk preparations; Milk powder or milk powder preparations containing additives containing thickening substances, eggs or cereal preparations; Milk gels
- A23C9/1542—Acidified milk products containing thickening agents or acidified milk gels, e.g. acidified by fruit juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof containing fruit or vegetable juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/38—Other non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/385—Concentrates of non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/60—Sweeteners
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/66—Proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/68—Acidifying substances
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/212—Starch; Modified starch; Starch derivatives, e.g. esters or ethers
- A23L29/219—Chemically modified starch; Reaction or complexation products of starch with other chemicals
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
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Definitions
- the present invention relates to beverages, more precisely to shelf-stable liquid base compositions useful for the preparation of acidified milk based beverages, especially by means of beverage dispensing machines.
- Acidified milk beverages are very popular today as they offer simultaneously sweetness and freshness to consumers. These beverages further provide well known milk nutrients like proteins or minerals and, when acidity is achieved by means of fruits juices, the latter further bring flavours or vitamins in addition to the mere acidifying effect.
- U.S. Pat. No. 3,800,052 discloses the preparation of a sour, “ready-to-drink” milk beverage having a good whiteness and stability made by adding acid to skim milk to bring the pH of the beverage within the range of 3.5 to 3.7. Acid is added to skim milk and water in predetermined proportions, then sugar and the whole is subject to moderate heating (around 70° C.), refined and flavoured if necessary and eventually bottled as is for storage or for direct consumption.
- U.S. Pat. No. 4,194,019 describes a method for preparing an acidified milk beverage which has milk protein stably dispersed therein and which is “ready-to-drink” without dilution, when subjecting an acidified skimmed milk having a milk solid-not-fat (SNF) content of 0.5 to 3.5 weight % and a pH value of 3.0 to 3.9 to heat treatment at ultra-high temperature.
- Acidic pH is due to lactic fermentation and addition of sugar is optional.
- U.S. Pat. No. 4,192,901 eventually discloses a method for manufacturing a concentrate defined as “milk-containing acid syrup” which is further used for preparing beverages by dilution with water.
- the inventors have addressed a specific issue, i.e. the stabilization of milk proteins by monitoring the casein/sugar ratio and subsequently subjecting the acidified milk-sugar mixture to ultra-high temperature heating: inventors have assumed that during said ultra-high temperature heat treatment, casein undergoes some form of reaction with sugar and, hydrophilic property of the casein is significantly enhanced.
- Beverage dispensing machines or visual bowls are also quite popular in modern communities so they are frequently used for dispensing various kinds of beverages in cans or even as freshly prepared fruits juices or similar beverages.
- refrigerated conditions like those which should apply to “ready-to-drink” milk based beverages are necessary, this is leading to use complex and expensive techniques or machines.
- cleaning is a critical factor.
- An approach would be to allow preparation of such acidified milk based beverages immediately before consumption, for instance by storing separately sensitive or non compatible components like e.g. milk and acid or fruit juice and then mix them on demand. This way proved in fact unduly complex and expensive and, also, not suitable for use in conventional beverage dispensing machines.
- the present invention offers an innovative and quite efficient solution to the skilled artisan while providing him a storable, shelf-stable, concentrated base composition which already comprises all the ingredients necessary for preparing an attractive, acidified milk based beverage by mere dilution with water, namely by dilution in a beverage dispensing or vending machine.
- the present invention primarily refers to a shelf-stable liquid base composition useful for preparing acidified milk based beverages, e.g. in beverage dispensers, said liquid base composition comprising:
- the invention further refers to a method for preparing the said base composition, which method comprises the sequence provided here below:
- the invention also refers to another method for preparing the said liquid base composition, which method comprises the sequence provided here below:
- the invention eventually, refers to a method for preparing acidified milk based beverages by dilution of the relevant liquid base composition with an appropriate amount of water and to the beverages so afforded as well.
- the dilution of the liquid base composition with an appropriate amount of water refers to diluting one part of said base composition with 2 to 7 parts or water. Dilution can occur preferably in a beverage dispensing machine under controlled dilution conditions. Controlled dilution conditions may require the use of a pump for pumping the base composition at a certain flow rate and during a controlled time and a pump for pumping the water at another flow rate and during a controlled time and mixing said base composition and water in order to obtain the desired ratio.
- the acidified milk based beverage is preferably delivered with a protein content of from 0.02 to 5% SNF and with sugar equivalent of from 7 to 10 weight %.
- the beverage is also preferably delivered with a pH comprised between 3.6 and 4.2. A pH below 4.2 is preferred in order to guarantee a better machine hygiene.
- the acidified milk based beverage experiences physical stability for at least 1 hour after dispensing.
- One of the main characteristics of the invention consists in a well adjusted balance of selected ingredients and their proportions in the base composition, more precisely the milk proteins, a first class of carbohydrates such as sugars or sugar substitutes acting as sweeteners, a second class of carbohydrates acting as stabilizers like gums, pectins or the like acting as stabilizers and acid components.
- This adjusted balance provides the conditions necessary for stabilizing the base composition and the “ready-to-drink” beverage as well.
- This base composition represents another important feature of this invention.
- This shelf-stable milk base is designed for application in beverage dispensers such as e.g. visual bowls and juice dispensers. In both cases, the milk base offers convenience, ease of handling over ready to drink beverages and less hygiene concerns. For machine hygiene safety, the pH of the concentrate base composition and reconstituted beverage is designed to stay below 4.2.
- the specific heat treatment of selected ingredients like milk proteins represents another feature of the invention as it is leading to denaturation of milk proteins to such an extent that they remain stable when subjected to subsequent treatments like acidifying, homogenising, pasteurising or the like and filling.
- the stability of the base composition so achieved is further reflected in the “ready-to-drink” acidified milk base beverages, which are prepared by mere dilution with an appropriate amount of water.
- the liquid base composition comprises from about 2.0 to about 10 weight %, preferably from about 3.6 to about 6.0 weight % of denatured milk protein.
- proportions of milk proteins of are preferably expressed when referring to “solid-not-fat” or “SNF” milk components although simple weight percent may also be used to that purpose.
- SNF solid-not-fat
- Weight percent are expressed as referring to the total weight of the base composition, i.e. the concentrate.
- Suitable sources of milk proteins subjected to denaturing within the frame of this invention are conveniently selected form fresh and powder whole or semi skimmed or fully skimmed milk.
- Sodium caseinate, calcium caseinate, milk protein isolates, milk protein concentrates or whey proteins can also be used.
- the milk proteins have been denatured by heat treatment.
- Said treatment is generally performed by subjecting a liquid source of milk proteins at temperatures comprised between about 80 to about 120° C., over a period of about 1 to 20 minutes depending on the manufacturing capabilities, preferably from 110 to 120° C. to a period of 2 to 5 minutes.
- the selected temperature and time conditions need to be addressed to achieve a degree of denaturation of at least 75%.
- the milk protein denaturing heat treatment may also be carried out as part of the processing for transforming liquid milk into heat milk powder. Therefore, high heat milk powder can be used when heat treatment has already been applied to the milk proteins to denature them.
- High heat milk powder refers to powder having a whey protein nitrogen index below 1.5 mg N/g.
- the “whey protein nitrogen index” refers to the amount of still denaturable serum protein left in the powder as described in literature, especially, in “Walstra, P., J. T. M. Wouters, T. J. Geurts, Dairy Science and Technology, Second ed, Boca Raton: CRC Taylor & Francis”, page 530. A subsequent heat treatment can consequently be reduced to 85° C. for a few seconds or may even not be necessary.
- the said heat treatment can be performed either in the presence of carbohydrates such as those mentioned here below, or not.
- Carbohydrates are also key ingredients within the frame of the present invention; they comprise two groups each of them having a specific role to play:
- Proportions of carbohydrate base sweeteners when referred to within the frame of the invention, are preferably expressed as “sugar equivalents” although simple weight percent may also be used to that purpose.
- the terms “sugar equivalents” within the frame of this invention are meant to qualify ingredients such as non-carbohydrate based, artificial, sweeteners that can replace sucrose. In terms of concentration by weight, for example a milk base containing 40% wt sucrose is equivalent in terms of sweetness to a milk base containing approximately 0.2% wt of aspartame.
- Non-carbohydrate based sweeteners like e.g. Splenda®, Acesulfame K®, aspartame or Stevia® are conveniently used within the frame of the present invention.
- sugar equivalents of artificial sweeteners and other carbohydrates based sweeteners relative sweetening powders compared to sucrose, the conversion factors were taken from literature:
- Sugar equivalent levels are usually comprised between about 15 to about 80 weight %, preferably between about 30 and 60 wt % and most preferably between 40 and 55%.
- Polysaccharides stabilizers are useful for achieving the desired viscosity and density and best results have been achieved in terms of viscosity range between 15 to 250 mPa ⁇ s, preferably, between 15 to 100 mPa ⁇ s of the base composition. It has been observed that physical stability of the base composition is also closely related to the viscosity value. In particular, when viscosity of the base composition is lower than 15 mPa ⁇ s, the base composition is not stable and milk solid tends to separate from serum and to settle at the bottom of container. Phase separation raises an important issue, in particular, for delivering beverages in a beverage dispenser where no regular stirring takes place and therefore quality of the final beverage can be dramatically affected with high milk solid content variations in the final beverage.
- One feature of the invention lies in selecting the most adequate polysaccharide to be used as stabilizer. It has been surprisingly observed, however, that a level and type of stabilizer that allowed having a stable base composition did not necessarily provide a stable “ready-to-drink” beverage after dilution with water.
- the goal of this invention is to provide stability for both the base composition and the final beverage and, furthermore, to select a stabilizer that does not increase the viscosity of the said base too much and that, at the same time, provides an acceptable mouth feel in the final beverage.
- the advantage of not increasing the viscosity of the composition too much is essentially that the composition can be pumped using conventional dispenser equipment and can be diluted easily at cold or ambient temperature while providing an homogeneously mixed beverage with water as a diluent, thus allowing to use these base compositions even with very simple beverage dispensers.
- the amount of stabilizer used is dependent on the amount of milk proteins in the base; within the frame of this invention, the most suitable proportions of the carbohydrate based stabilizers (or polysaccharides) are comprised between about 0.35 to about 1.5 weight %, preferably from about 0.50 to about 1.00 weight %.
- the choice of the stabilizer is also directed by the pH of the base composition, as the selected stabilizer needs to remain fairly active and stable at pH range below 4, preferably from 3.0 to about 3.8 during the whole processing and during storage over prolonged periods.
- a base composition having e.g., pectin or pectin derivatives, carrageenan or carrageenan derivatives or mixtures of same, guar gum, locust bean and sodium carboxymethylcellulose represents preferred stabilizers.
- a SNF content of 3.6 weight % of from 40 to 70 weight % of sugar equivalent concentration (which corresponds for example to 0.2 to 0.35 weight % of aspartame) and of high methyl ester pectin of about 0.4 and 0.7 weight % provide fairly stable base compositions; however, when the said base is diluted with water, solid particles tend to settle at the bottom of the container thus giving a beverage having an in-cup stability of max. 6 hours.
- polysaccharides such as acacia gum can be used at levels between 0.5 to 1 weight percent, proteins do not coagulate after acidification and a homogenous product was obtained.
- Pectin or pectin derivatives like that mentioned above can also be combined with other hydrocolloids such as K-carrageenan, sodium carboxymethylcellulose and acacia gum: satisfying results have been obtained with both variants.
- base compositions using non-sugar sweetener preferably require the use of a combination of pectin or pectin derivatives and another stabilizer having a thickening function in order to raise the viscosity of the base composition at or above 15 mPa ⁇ s. If only pectin is used, viscosity may not so be reached and a stability issue may be so appear.
- the additional stabilizer is preferably chosen in the group of K-carrageenan, sodium carboxymethylcellulose and acacia gum, guar gum and locust bean and combinations thereof.
- Fat can also be present in the mixture subject to heat treatment mentioned here above. In order to avoid fat stability in the composition by fat migrating and forming fat globules at the surface of the liquid, it is also preferred that that fat is between 0.1 to 2% weight of the base composition.
- fat it is meant milk fat coming from whole or semi skimmed milk used as source of proteins or, added fat like animal or vegetable fat, when fully skimmed milk is used as source of proteins.
- Animal fat may comprises e.g. butter oil or gee whereas vegetal fat may comprise e.g. palm kernel, coconut, sunflower or soil oil.
- fresh milk or milk powder is blended at 50° C. with water, emulsifier, sugar and melted fat if ever.
- Some of the sugar is used to dissolve the hydrocolloid (stabilizer) in hot water (70-80° C.) at high speed.
- the hydrocolloid solution is then added to the milk base and the mixture is heat treated as mentioned here above. After heat treatment, the milk and sugar concentrate is homogenized and cooled down to e.g. 4° C.
- Low heat milk powder refers to powder having whey protein nitrogen index above 6 mg N/g.
- Medium heat milk powder refers to powder having whey nitrogen index between 1.5 and 6 mg N/g.
- Another advantage of using high heat milk powder is the higher viscosity that it brings compared to low and medium heat powders.
- dilution of the base composition with an appropriate amount of water refers to diluting one part of said base composition with 2 to 7 parts or water, e.g. in a beverage dispensing machine.
- Dilution of the concentrate leads to a product with pH lower than 4.2, with a sugar content of from 5 to 10 g/100 ml and milk protein content of from 0.01 to 1.8 g/100 ml.
- the mixture once subjected to the heat treatment leading to denaturation of the milk proteins is then cooled to temperature below 10° C. and subsequently brought to the convenient pH range; said pH range is a further key feature of the invention.
- such a low pH is not recommended for the consumption of a “ready-to-drink” beverage due to taste issues and most of the acidified beverages are usually consumed at a pH range of 4.0 to 4.4.
- this dilemma is conveniently solved by means of preparing a base composition the pH range of which can be lowered to an optimal level for the milk proteins, i.e. a pH of about 3.0 to about 3.5, without affecting the said milk proteins and by diluting it subsequently with the appropriate amount of water and so bringing the final beverage to pH between 3.6. and 4.2.
- the pH of the concentrates is designed so that the pH of the final beverage is between 4.0 and 4.1.
- Acidifying agents usable within the frame on the invention comprise edible organic acids such as e.g. citric, malic, tartaric or lactic acid.
- the selected acids are mixed with water in the ratio of about 30:70 and used to acidify the heated mixture of sugars, stabilizer, milk proteins and fat. Acidification is generally performed at 4° C. and by adding the above mixture to the acid solution. This type of acidification is preferred because the milk proteins pass quickly below the isoelectric point around 4.6 and then stay in a pH range of below 4.
- Acidification can also be performed by means of fruit juices/concentrates like apple, pear, lemon juice, orange juices, kiwi juice or exotic fruit juices to which acid content has been adjusted accordingly. When doing so the acidification further brings selected flavor components or vitamins. Of course artificial flavor components or minerals or micronutrients can also be added to the whole mixture.
- Flavors and colorants are usually added to the mixture before final heat treatment, e.g. pasteurization. Nutrients like vitamins, minerals (Ca ++ and Mg ++ ) etc. can be added at this stage without flavor and insolubility issues. In all cases, the dosage of these ingredients must be calculated based on the dilution factor to achieve the proper final beverages.
- the base composition is heat treated to e.g. 100° C. for 10 sec using either direct or indirect method, then aseptically homogenized, cooled to 30° C. and eventually poured into suitable containers aseptically, or by clean or hot filling.
- sucrose and 45 g of partially skimmed milk were mixed at 50° C. with added hydrated solution of stabilizers such as K-carrageenan and pectin.
- stabilizers such as K-carrageenan and pectin.
- the solution was heat treated for 2 minutes at 120° C. to denature the proteins, then homogenized and cooled down to 4° C.
- the pH of the solution was quickly adjusted to 3.5 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage.
- the acidified product (with viscosity of 50 mPa ⁇ s) was mixed for 30 minutes and then pasteurized and poured aseptically into storage containers.
- the resulting base concentrate had 2.40% weight of SNF and 40% weight of sugar equivalent.
- Such a product will be consumed after dilution of 1 part of concentrate with 4 parts of water giving acidified milk based beverage having a final pH of 4.0.
- sucrose and 45 g of partially skimmed milk were mixed at 50° C. with added hydrated solution of stabilizers such as K-carrageenan and pectin.
- stabilizers such as K-carrageenan and pectin.
- 0.02 g of sucralose from Splenda® was added to the mixture. The solution was heat treated for 1 minute at 100° C., then homogenized and cooled down to 4° C.
- the pH of the solution was quickly adjusted to 3.5 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage.
- the acidified product (with viscosity of 45 mPa ⁇ s) was mixed for 30 minutes and then sterilized and poured aseptically into storage containers.
- the resulting base concentrate had 2.40% weight of SNF and 32% weight of sugar equivalent.
- a final milk based beverage having a pH of 4.0 has been obtained by dilution of 1 part of the base composition with 4 parts of water.
- the pH of the solution quickly adjusted to 3.3 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage.
- the acidified product (with viscosity of 60 mPa ⁇ s) was mixed for 30 minutes, sterilized and poured aseptically into storage containers.
- the resulting base concentrate had 4.40% weight of SNF and 46% weight of sugar equivalent.
- a final acidified milk based beverage is prepared by dilution of 1 part of base composition with 5 parts of water leading to final pH of 4.0.
- the pH of the solution was quickly adjusted to 3.2 with agitation by addition of 30% malic acid solution. Colours (0.1 g) and flavours (0.35 g) are added at this stage.
- the product had viscosity of 100 mPa ⁇ s. The concentration of colours and flavours is 7 times higher than in a corresponding “ready-to-drink” beverage.
- the acidified product was mixed for 30 minutes, sterilized and aseptically filled.
- the resulting base concentrate had 6.00% weight of SNF and 54% weight of sugar equivalent.
- a final acidified milk based beverage is prepared by dilution of 1 part of base composition with 6 parts of water (pH 4.1).
- the pH of the solution was quickly adjusted to 3.2 with agitation by addition of 30% malic acid solution. Colours (0.1 g) and flavours (0.35 g) are added at this stage.
- the product had viscosity of 200 mPa ⁇ s
- the acidified product was mixed for 30 minutes, pasteurised and then poured in a clean manner into storage containers.
- the resulting base concentrate had 6.00% weight of SNF and 46% weight of sugar equivalent.
- a final acidified milk based beverage is prepared by dilution of 1 part of base composition with 6 parts of water (pH 4.1).
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- Non-Alcoholic Beverages (AREA)
Abstract
A shelf-stable liquid base composition useful for preparing acidified milk based beverages, e.g. by dilution with water in a beverage dispensing machine, comprises: from about 2 to about 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components; from about 15 to about 80 weight %, expressed as sugar equivalents, of a carbohydrate based or non carbohydrate based sweetener; from about 0.35 to about 1.50 weight % of a carbohydrate based stabilizer; and an acidifying agent present in amounts necessary for achieving a pH of about 3.0 to about 3.8 of the said base composition. Methods for preparing such a base composition and acidified milk based beverages prepared by means of such a base composition.
Description
- The present invention relates to beverages, more precisely to shelf-stable liquid base compositions useful for the preparation of acidified milk based beverages, especially by means of beverage dispensing machines.
- Acidified milk beverages are very popular today as they offer simultaneously sweetness and freshness to consumers. These beverages further provide well known milk nutrients like proteins or minerals and, when acidity is achieved by means of fruits juices, the latter further bring flavours or vitamins in addition to the mere acidifying effect.
- Most of the acidified milk based beverages are available today as “ready-to-drink” beverages, which require storage at refrigerated conditions and, consequently, which have a limited shelf life. Several attempts have been made in the past to increase stability and storage period of said “ready-to-drink” beverages, e.g. by controlling pH with suitable stabilizers, increasing sugar content or removal of undesired components like certain milk or juice electrolytes (see e.g. U.S. Pat. No. 4,676,988).
- U.S. Pat. No. 3,800,052 discloses the preparation of a sour, “ready-to-drink” milk beverage having a good whiteness and stability made by adding acid to skim milk to bring the pH of the beverage within the range of 3.5 to 3.7. Acid is added to skim milk and water in predetermined proportions, then sugar and the whole is subject to moderate heating (around 70° C.), refined and flavoured if necessary and eventually bottled as is for storage or for direct consumption.
- U.S. Pat. No. 4,194,019 describes a method for preparing an acidified milk beverage which has milk protein stably dispersed therein and which is “ready-to-drink” without dilution, when subjecting an acidified skimmed milk having a milk solid-not-fat (SNF) content of 0.5 to 3.5 weight % and a pH value of 3.0 to 3.9 to heat treatment at ultra-high temperature. Acidic pH is due to lactic fermentation and addition of sugar is optional.
- U.S. Pat. No. 4,192,901 eventually discloses a method for manufacturing a concentrate defined as “milk-containing acid syrup” which is further used for preparing beverages by dilution with water. In this case, the inventors have addressed a specific issue, i.e. the stabilization of milk proteins by monitoring the casein/sugar ratio and subsequently subjecting the acidified milk-sugar mixture to ultra-high temperature heating: inventors have assumed that during said ultra-high temperature heat treatment, casein undergoes some form of reaction with sugar and, hydrophilic property of the casein is significantly enhanced.
- Beverage dispensing machines or visual bowls are also quite popular in modern communities so they are frequently used for dispensing various kinds of beverages in cans or even as freshly prepared fruits juices or similar beverages. When refrigerated conditions like those which should apply to “ready-to-drink” milk based beverages are necessary, this is leading to use complex and expensive techniques or machines. Further, when working with milk based beverages hygiene is a critical factor.
- An approach would be to allow preparation of such acidified milk based beverages immediately before consumption, for instance by storing separately sensitive or non compatible components like e.g. milk and acid or fruit juice and then mix them on demand. This way proved in fact unduly complex and expensive and, also, not suitable for use in conventional beverage dispensing machines.
- An other way to by-pass the above difficulties or drawbacks would be using stable concentrated base compositions which would simply be diluted with water on demand, i.e. just before consumption. The art, unfortunately, does not provide today any appropriate solution to the skilled artisan.
- The present invention offers an innovative and quite efficient solution to the skilled artisan while providing him a storable, shelf-stable, concentrated base composition which already comprises all the ingredients necessary for preparing an attractive, acidified milk based beverage by mere dilution with water, namely by dilution in a beverage dispensing or vending machine.
- Further features or advantages of the present invention shall appear in the specification here below.
- The present invention primarily refers to a shelf-stable liquid base composition useful for preparing acidified milk based beverages, e.g. in beverage dispensers, said liquid base composition comprising:
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- a. from about 2 to about 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components;
- b. from about 15 to about 80 weight %, expressed as sugar equivalents, of a carbohydrate based and/or non carbohydrate based sweetener;
- c. from about 0.35 to about 1.50 weight % of a carbohydrate based stabilizer; and
- d. an acidifying agent present in amounts necessary for achieving a pH of about 3.0 to about 3.8 of the said base composition.
- The invention further refers to a method for preparing the said base composition, which method comprises the sequence provided here below:
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- heating a source of milk proteins at about 80 to about 120° C. over a period of about 1 to about 20 minutes to achieve denaturising of the said milk proteins;
- mixing the source of denatured milk proteins with a carbohydrate based or non carbohydrate based sweetener and with a carbohydrate based stabilizer;
- bringing the above mixture to a pH of about 3.0 to about 3.8 while mixing it with an acidifying agent; and
- sterilizing or pasteurising the above acidified mixture and subsequently pouring it into containers.
- The invention also refers to another method for preparing the said liquid base composition, which method comprises the sequence provided here below:
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- heating a source of milk proteins at about 80 to about 120° C. over a period of about 1 to about 20 minutes in presence of a carbohydrate based or non carbohydrate based sweetener and of a carbohydrate based stabilizer;
- cooling down the heat treated mixture and bringing it to a pH of about 3.0 to about 3.8 while mixing it with an acidifying agent; and
- sterilizing or pasteurising the above acidified mixture and subsequently pouring it aseptically into containers.
- The invention, eventually, refers to a method for preparing acidified milk based beverages by dilution of the relevant liquid base composition with an appropriate amount of water and to the beverages so afforded as well.
- In the acidified milk based beverage, the dilution of the liquid base composition with an appropriate amount of water refers to diluting one part of said base composition with 2 to 7 parts or water. Dilution can occur preferably in a beverage dispensing machine under controlled dilution conditions. Controlled dilution conditions may require the use of a pump for pumping the base composition at a certain flow rate and during a controlled time and a pump for pumping the water at another flow rate and during a controlled time and mixing said base composition and water in order to obtain the desired ratio.
- The acidified milk based beverage is preferably delivered with a protein content of from 0.02 to 5% SNF and with sugar equivalent of from 7 to 10 weight %. The beverage is also preferably delivered with a pH comprised between 3.6 and 4.2. A pH below 4.2 is preferred in order to guarantee a better machine hygiene. As a result of the base composition as designed, the acidified milk based beverage experiences physical stability for at least 1 hour after dispensing.
- One of the main characteristics of the invention consists in a well adjusted balance of selected ingredients and their proportions in the base composition, more precisely the milk proteins, a first class of carbohydrates such as sugars or sugar substitutes acting as sweeteners, a second class of carbohydrates acting as stabilizers like gums, pectins or the like acting as stabilizers and acid components. This adjusted balance provides the conditions necessary for stabilizing the base composition and the “ready-to-drink” beverage as well.
- The use of this base composition represents another important feature of this invention. This shelf-stable milk base is designed for application in beverage dispensers such as e.g. visual bowls and juice dispensers. In both cases, the milk base offers convenience, ease of handling over ready to drink beverages and less hygiene concerns. For machine hygiene safety, the pH of the concentrate base composition and reconstituted beverage is designed to stay below 4.2.
- The specific heat treatment of selected ingredients like milk proteins represents another feature of the invention as it is leading to denaturation of milk proteins to such an extent that they remain stable when subjected to subsequent treatments like acidifying, homogenising, pasteurising or the like and filling. Surprisingly, the stability of the base composition so achieved is further reflected in the “ready-to-drink” acidified milk base beverages, which are prepared by mere dilution with an appropriate amount of water.
- According to the invention the liquid base composition comprises from about 2.0 to about 10 weight %, preferably from about 3.6 to about 6.0 weight % of denatured milk protein. Within the frame of the invention, proportions of milk proteins of are preferably expressed when referring to “solid-not-fat” or “SNF” milk components although simple weight percent may also be used to that purpose. In such a case 2.0 to 10 weight % (SNF) would be equivalent to 0.7 to 3.6 g of milk proteins in 100 grams of base composition. Weight percent are expressed as referring to the total weight of the base composition, i.e. the concentrate.
- Suitable sources of milk proteins subjected to denaturing within the frame of this invention are conveniently selected form fresh and powder whole or semi skimmed or fully skimmed milk. Sodium caseinate, calcium caseinate, milk protein isolates, milk protein concentrates or whey proteins can also be used.
- According to the invention the milk proteins have been denatured by heat treatment. Said treatment is generally performed by subjecting a liquid source of milk proteins at temperatures comprised between about 80 to about 120° C., over a period of about 1 to 20 minutes depending on the manufacturing capabilities, preferably from 110 to 120° C. to a period of 2 to 5 minutes. The selected temperature and time conditions need to be addressed to achieve a degree of denaturation of at least 75%. The milk protein denaturing heat treatment may also be carried out as part of the processing for transforming liquid milk into heat milk powder. Therefore, high heat milk powder can be used when heat treatment has already been applied to the milk proteins to denature them. High heat milk powder refers to powder having a whey protein nitrogen index below 1.5 mg N/g. The “whey protein nitrogen index” refers to the amount of still denaturable serum protein left in the powder as described in literature, especially, in “Walstra, P., J. T. M. Wouters, T. J. Geurts, Dairy Science and Technology, Second ed, Boca Raton: CRC Taylor & Francis”, page 530. A subsequent heat treatment can consequently be reduced to 85° C. for a few seconds or may even not be necessary.
- The said heat treatment can be performed either in the presence of carbohydrates such as those mentioned here below, or not.
- Carbohydrates are also key ingredients within the frame of the present invention; they comprise two groups each of them having a specific role to play:
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- a first group of carbohydrates consisting of sugars which act, mainly, as sweeteners in the “ready-to-drink” beverage. The term sugars is intended to cover ingredients such as fructose, glucose, maltose, sucrose, lactose, dextrose, high fructose corn syrup or sugar substitutes like e.g. sorbitol, mannitol, xylitol or combinations thereof. These carbohydrates also offer the advantage of reducing the water activity of the base composition and consequently, further reducing the risk of growth from bacteria, yeasts or moulds;
- a second group of carbohydrates comprises polysaccharides acting as stabilizers in both the base composition and the acidified milk base “ready-to-drink” beverage. Such polysaccharides are preferably selected among gums, pectins or pectin derivatives, cellulose derivatives like sodium carboxymethylcellulose, carrageenan or carrageenan derivatives or mixtures of same. One of their main functions consists in controlling the viscosity and the stability of the base composition, especially when the latter is designed for beverage dispensing or vending machines.
- Proportions of carbohydrate base sweeteners, when referred to within the frame of the invention, are preferably expressed as “sugar equivalents” although simple weight percent may also be used to that purpose. The terms “sugar equivalents” within the frame of this invention, are meant to qualify ingredients such as non-carbohydrate based, artificial, sweeteners that can replace sucrose. In terms of concentration by weight, for example a milk base containing 40% wt sucrose is equivalent in terms of sweetness to a milk base containing approximately 0.2% wt of aspartame.
- Non-carbohydrate based sweeteners like e.g. Splenda®, Acesulfame K®, aspartame or Stevia® are conveniently used within the frame of the present invention. For calculation of sugar equivalents of artificial sweeteners and other carbohydrates based sweeteners, relative sweetening powders compared to sucrose, the conversion factors were taken from literature:
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- “Birch, G. Ingredients handbook sweeteners, Second ed. Surrey: Leatherhead Publishing” and,
- “Alexander, R. J. Sweeteners: nutritive, St. Paul: Eagan Press”, page 40.
- Sugar equivalent levels are usually comprised between about 15 to about 80 weight %, preferably between about 30 and 60 wt % and most preferably between 40 and 55%.
- It has been observed that, by setting the level of sucrose between 40 and 55 weight %, good stability of the base composition could be achieved over a period running up to 12 months at 20° C.: the term “shelf-stable” or “storable” used throughout the current specification qualifies these conditions, although shorter storage periods or lower storage temperatures may be contemplated. No serum separation or precipitates were observed in the said base composition. After dilution with water, a “ready-to-drink” beverage was achieved which remained quite stable over 1 week of storage at refrigerated conditions.
- When the level of sucrose was set in the range of 30 to less than 40%, good stability of the corresponding base composition was also achieved over a period running up to 6 months at ambient conditions; minor serum separation but with some sedimentation, however, have been observed in the base composition but this effect did not prevent convenient dilution of the said base with water and no specific negative effect was noticed in the “ready-to-drink” acidified beverage.
- Polysaccharides stabilizers are useful for achieving the desired viscosity and density and best results have been achieved in terms of viscosity range between 15 to 250 mPa·s, preferably, between 15 to 100 mPa·s of the base composition. It has been observed that physical stability of the base composition is also closely related to the viscosity value. In particular, when viscosity of the base composition is lower than 15 mPa·s, the base composition is not stable and milk solid tends to separate from serum and to settle at the bottom of container. Phase separation raises an important issue, in particular, for delivering beverages in a beverage dispenser where no regular stirring takes place and therefore quality of the final beverage can be dramatically affected with high milk solid content variations in the final beverage.
- One feature of the invention lies in selecting the most adequate polysaccharide to be used as stabilizer. It has been surprisingly observed, however, that a level and type of stabilizer that allowed having a stable base composition did not necessarily provide a stable “ready-to-drink” beverage after dilution with water.
- Therefore the goal of this invention is to provide stability for both the base composition and the final beverage and, furthermore, to select a stabilizer that does not increase the viscosity of the said base too much and that, at the same time, provides an acceptable mouth feel in the final beverage. The advantage of not increasing the viscosity of the composition too much is essentially that the composition can be pumped using conventional dispenser equipment and can be diluted easily at cold or ambient temperature while providing an homogeneously mixed beverage with water as a diluent, thus allowing to use these base compositions even with very simple beverage dispensers. Further, the amount of stabilizer used is dependent on the amount of milk proteins in the base; within the frame of this invention, the most suitable proportions of the carbohydrate based stabilizers (or polysaccharides) are comprised between about 0.35 to about 1.5 weight %, preferably from about 0.50 to about 1.00 weight %.
- Eventually, the choice of the stabilizer is also directed by the pH of the base composition, as the selected stabilizer needs to remain fairly active and stable at pH range below 4, preferably from 3.0 to about 3.8 during the whole processing and during storage over prolonged periods.
- Among the various polysaccharides mentioned here above, i.e. gums, pectin or pectin derivatives, carrageenan or carrageenan derivatives or mixtures of same, guar gum, locust bean and sodium carboxymethylcellulose represents preferred stabilizers. When preparing a base composition having e.g. a SNF content of 3.6 weight %, of from 40 to 70 weight % of sugar equivalent concentration (which corresponds for example to 0.2 to 0.35 weight % of aspartame) and of high methyl ester pectin of about 0.4 and 0.7 weight % provide fairly stable base compositions; however, when the said base is diluted with water, solid particles tend to settle at the bottom of the container thus giving a beverage having an in-cup stability of max. 6 hours.
- Best performances have been achieved by means of using high methyl ester pectin concentration ranging from 0.7 to 1 weight % and both the base composition and the final beverages exhibit the required stability and mouth feel.
- Other polysaccharides such as acacia gum can be used at levels between 0.5 to 1 weight percent, proteins do not coagulate after acidification and a homogenous product was obtained.
- Pectin or pectin derivatives like that mentioned above can also be combined with other hydrocolloids such as K-carrageenan, sodium carboxymethylcellulose and acacia gum: satisfying results have been obtained with both variants.
- In particular, base compositions using non-sugar sweetener preferably require the use of a combination of pectin or pectin derivatives and another stabilizer having a thickening function in order to raise the viscosity of the base composition at or above 15 mPa·s. If only pectin is used, viscosity may not so be reached and a stability issue may be so appear. The additional stabilizer is preferably chosen in the group of K-carrageenan, sodium carboxymethylcellulose and acacia gum, guar gum and locust bean and combinations thereof.
- Fat can also be present in the mixture subject to heat treatment mentioned here above. In order to avoid fat stability in the composition by fat migrating and forming fat globules at the surface of the liquid, it is also preferred that that fat is between 0.1 to 2% weight of the base composition. By fat it is meant milk fat coming from whole or semi skimmed milk used as source of proteins or, added fat like animal or vegetable fat, when fully skimmed milk is used as source of proteins. Animal fat may comprises e.g. butter oil or gee whereas vegetal fat may comprise e.g. palm kernel, coconut, sunflower or soil oil.
- Usually, fresh milk or milk powder is blended at 50° C. with water, emulsifier, sugar and melted fat if ever. Some of the sugar is used to dissolve the hydrocolloid (stabilizer) in hot water (70-80° C.) at high speed. The hydrocolloid solution is then added to the milk base and the mixture is heat treated as mentioned here above. After heat treatment, the milk and sugar concentrate is homogenized and cooled down to e.g. 4° C.
- It has been observed that when working with “high heat milk powder” i.e., with whey protein nitrogen index below 1.5 mg N/g, the pre heat treatment could be reduced to 85° C. for a few seconds before cooling to 4° C. or eliminated. If using low or medium heat milk powders, the heat treatment should be adjusted accordingly. Low heat milk powder refers to powder having whey protein nitrogen index above 6 mg N/g. Medium heat milk powder refers to powder having whey nitrogen index between 1.5 and 6 mg N/g.
- Another advantage of using high heat milk powder is the higher viscosity that it brings compared to low and medium heat powders.
- According to the invention, dilution of the base composition with an appropriate amount of water refers to diluting one part of said base composition with 2 to 7 parts or water, e.g. in a beverage dispensing machine. Dilution of the concentrate leads to a product with pH lower than 4.2, with a sugar content of from 5 to 10 g/100 ml and milk protein content of from 0.01 to 1.8 g/100 ml.
- According to the invention the mixture once subjected to the heat treatment leading to denaturation of the milk proteins is then cooled to temperature below 10° C. and subsequently brought to the convenient pH range; said pH range is a further key feature of the invention. Usually, from a mere stability point of view it is recommended to decrease the pH of the concentrate base composition to below 3.7 in order to obtain a stable isoelectric point of the milk proteins. However, such a low pH is not recommended for the consumption of a “ready-to-drink” beverage due to taste issues and most of the acidified beverages are usually consumed at a pH range of 4.0 to 4.4.
- Thanks to the present invention this dilemma is conveniently solved by means of preparing a base composition the pH range of which can be lowered to an optimal level for the milk proteins, i.e. a pH of about 3.0 to about 3.5, without affecting the said milk proteins and by diluting it subsequently with the appropriate amount of water and so bringing the final beverage to pH between 3.6. and 4.2.
- For applications with beverage dispensers and visual bowls, it is important that the concentrates or final beverages are kept refrigerated after opening and the pH of the product is below 4.2; therefore, below the pH range where pathogenic bacteria can grow. For best results, the pH of the concentrates is designed so that the pH of the final beverage is between 4.0 and 4.1.
- Acidifying agents usable within the frame on the invention comprise edible organic acids such as e.g. citric, malic, tartaric or lactic acid. The selected acids are mixed with water in the ratio of about 30:70 and used to acidify the heated mixture of sugars, stabilizer, milk proteins and fat. Acidification is generally performed at 4° C. and by adding the above mixture to the acid solution. This type of acidification is preferred because the milk proteins pass quickly below the isoelectric point around 4.6 and then stay in a pH range of below 4.
- Acidification can also be performed by means of fruit juices/concentrates like apple, pear, lemon juice, orange juices, kiwi juice or exotic fruit juices to which acid content has been adjusted accordingly. When doing so the acidification further brings selected flavor components or vitamins. Of course artificial flavor components or minerals or micronutrients can also be added to the whole mixture.
- Flavors and colorants are usually added to the mixture before final heat treatment, e.g. pasteurization. Nutrients like vitamins, minerals (Ca++ and Mg++) etc. can be added at this stage without flavor and insolubility issues. In all cases, the dosage of these ingredients must be calculated based on the dilution factor to achieve the proper final beverages.
- The base composition is heat treated to e.g. 100° C. for 10 sec using either direct or indirect method, then aseptically homogenized, cooled to 30° C. and eventually poured into suitable containers aseptically, or by clean or hot filling.
- The following examples shall only illustrate some of the embodiments of the invention.
- 40 g sucrose and 45 g of partially skimmed milk were mixed at 50° C. with added hydrated solution of stabilizers such as K-carrageenan and pectin. The solution was heat treated for 2 minutes at 120° C. to denature the proteins, then homogenized and cooled down to 4° C.
- The pH of the solution was quickly adjusted to 3.5 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage. The acidified product (with viscosity of 50 mPa·s) was mixed for 30 minutes and then pasteurized and poured aseptically into storage containers.
- The resulting base concentrate had 2.40% weight of SNF and 40% weight of sugar equivalent.
- Such a product will be consumed after dilution of 1 part of concentrate with 4 parts of water giving acidified milk based beverage having a final pH of 4.0.
- 20 g sucrose and 45 g of partially skimmed milk were mixed at 50° C. with added hydrated solution of stabilizers such as K-carrageenan and pectin. To increase the sweetness level, 0.02 g of sucralose from Splenda® was added to the mixture. The solution was heat treated for 1 minute at 100° C., then homogenized and cooled down to 4° C.
- The pH of the solution was quickly adjusted to 3.5 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage. The acidified product (with viscosity of 45 mPa·s) was mixed for 30 minutes and then sterilized and poured aseptically into storage containers.
- The resulting base concentrate had 2.40% weight of SNF and 32% weight of sugar equivalent.
- A final milk based beverage having a pH of 4.0 has been obtained by dilution of 1 part of the base composition with 4 parts of water.
- 46 g sucrose and 33.4 g of fresh whole milk and 1.5 g of skimmed milk powder were mixed at 50° C. with added hydrated solution of pectin. The solution was heat-treated, then homogenized and cooled down to 20° C.
- The pH of the solution quickly adjusted to 3.3 with agitation by addition of 30% citric acid solution. Colours and flavours are added at this stage. The acidified product (with viscosity of 60 mPa·s) was mixed for 30 minutes, sterilized and poured aseptically into storage containers.
- The resulting base concentrate had 4.40% weight of SNF and 46% weight of sugar equivalent.
- A final acidified milk based beverage is prepared by dilution of 1 part of base composition with 5 parts of water leading to final pH of 4.0.
- 28 g sucrose and 36.2 g of fresh whole milk, 2 g of “milk powder high heat” and 0.09 g of Splenda® sweetener were mixed at 50° C. with added hydrated solution of stabilizers such as 0.5% weight of CMC (Carboxymethylcellulose) and pectin 0.7 weight %. The solution was cooled down to 20° C.
- The pH of the solution was quickly adjusted to 3.2 with agitation by addition of 30% malic acid solution. Colours (0.1 g) and flavours (0.35 g) are added at this stage. The product had viscosity of 100 mPa·s. The concentration of colours and flavours is 7 times higher than in a corresponding “ready-to-drink” beverage. The acidified product was mixed for 30 minutes, sterilized and aseptically filled.
- The resulting base concentrate had 6.00% weight of SNF and 54% weight of sugar equivalent.
- A final acidified milk based beverage is prepared by dilution of 1 part of base composition with 6 parts of water (pH 4.1).
- 0.14 grams of Splenda® sweetener and 6.1 g of “milk powder high heat” were mixed at ambient conditions with added hydrated solution of stabilizers such as pectin and carboxymethyl cellulose The solution was heat treated for few seconds at 85° C. and then cooled down to 4° C.
- The pH of the solution was quickly adjusted to 3.2 with agitation by addition of 30% malic acid solution. Colours (0.1 g) and flavours (0.35 g) are added at this stage. The product had viscosity of 200 mPa·s The acidified product was mixed for 30 minutes, pasteurised and then poured in a clean manner into storage containers.
- The resulting base concentrate had 6.00% weight of SNF and 46% weight of sugar equivalent.
- A final acidified milk based beverage is prepared by dilution of 1 part of base composition with 6 parts of water (pH 4.1).
Claims (25)
1. A shelf-stable liquid base composition for preparing acidified milk based beverages comprising:
from about 2 to about 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components;
from about 15 to about 80 weight %, expressed as sugar equivalents, of a carbohydrate based and/or non carbohydrate based sweetener;
from about 0.35 to about 1.50 weight % of a carbohydrate based stabilizer; and
an acidifying agent present in an amount sufficient for achieving a pH of about 3.0 to about 3.8 of the base composition.
2. The liquid base composition according to claim 1 , wherein the viscosity is from 15 to 250 mPa·s.
3. The liquid base composition according to claim 1 , wherein the denatured milk proteins are milk proteins subjected to heat treatment.
4. The liquid base composition according to claim 1 , wherein the carbohydrate-based sweetener is a mono- or polysaccharide selected from the group consisting of sugars, sugar substitutes, sugar derivatives and mixtures of same.
5. The liquid base composition according to claim 1 , wherein the carbohydrate-based stabilizer is a polysaccharide selected from the group consisting of gums, pectins and pectin derivatives, cellulose derivatives, carrageenan and carrageenan derivatives and mixtures of same.
6. The liquid base composition according to claim 1 , wherein the sweetener is essentially a non-carbohydrate based sweetener and the stabilizer comprises pectin and at least a stabilizer having a thickening function.
7. The liquid base composition according to claim 1 , wherein the acidifying agent is selected from the group consisting of a comestible acid and a source of comestible acid.
8. The liquid base composition according to claim 1 , which further comprises a component selected from the group consisting of fats, colorants, flavours and micronutrients.
9. A method for preparing a shelf-stable liquid base composition which comprises:
heating a source of milk proteins at about 80 to about 120° C. over a period of about 1 to about 20 minutes to achieve denaturing of the milk proteins;
mixing the source of denatured milk proteins with a sweetener and with a carbohydrate based stabilizer;
bringing the above mixture to a pH of about 3.0 to about 3.8 while mixing it with an acidifying agent; and
sterilizing or pasteurising the above acidified mixture and subsequently pouring it into containers.
10. A method for preparing a liquid base composition which comprises:
heating a source of milk proteins at about 80 to about 120° C. over a period of about 1 to about 20 minutes in presence of a sweetener and a carbohydrate based stabilizer;
cooling the heat treated mixture and bringing it to a pH of about 3.0 to about 3.8 while mixing it with an acidifying agent; and
sterilizing or pasteurising the above acidified mixture and subsequently pouring it into containers.
11. The method according to claim 9 , wherein the sweetener is a mono- or polysaccharide selected from the group consisting of sugars, sugar substitutes, sugar derivatives and mixtures of same.
12. The method according to claim 9 , wherein the carbohydrate-based stabilizer is a polysaccharide selected from the group consisting of gums, pectins and pectin derivatives, cellulose derivatives, carrageenan and carrageenan derivatives and mixtures of same.
13. The method according to claim 9 , wherein the acidifying agent is selected from the group consisting of edible acid and a source of edible acid.
14. The method according to claim 9 , wherein the mixture is subjected to heat treatment further comprises fat or a source of fat.
15. The method according to claim 9 , wherein at least one component selected from the group consisting of flavours, colorants and micronutrients is added to the acidified mixture prior to sterilisation or pasteurisation.
16. A method for preparing acidified milk based beverages, which comprises diluting one part of a liquid base composition comprising: from about 2 to about 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components; from about 15 to about 80 weight %, expressed as sugar equivalents, of a carbohydrate based and/or non carbohydrate based sweetener;
from about 0.35 to about 1.50 weight % of a carbohydrate based stabilizer; and an acidifying agent present in an amount sufficient for achieving a pH of about 3.0 to about 3.8 of the base composition with 2 to 7 parts of water.
17. A method according to claim 16 , wherein the acidified milk based beverage has a protein content of from 0.02 to 5% solid non fat (SNF), sugar equivalent of from 7 to 10 weight % and pH between 3.6 and 4.2.
18. The method according to claim 16 wherein the preparation of the acidified milk based beverage is performed by means of a beverage-dispensing machine.
19. An acidified milk based beverage prepared comprising one part of a composition comprising: from about 2 to about 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components; from about 15 to about 80 weight %, expressed as sugar equivalents, of a carbohydrate based and/or non carbohydrate based sweetener; from about 0.35 to about 1.50 weight % of a carbohydrate based stabilizer; and an acidifying agent present in an amount sufficient for achieving a pH of about 3.0 to about 3.8 of the base composition and at least two parts water.
20. The method according to claim 10 , wherein the sweetener is a mono- or polysaccharide selected from the group consisting of sugars, sugar substitutes, sugar derivatives and mixtures of same.
21. The method according to claim 10 , wherein the carbohydrate-based stabilizer is a polysaccharide selected from the group consisting of gums, pectins and pectin derivatives, cellulose derivatives, carrageenan and carrageenan derivatives and mixtures of same.
22. The method according to claim 10 , wherein the acidifying agent is selected from the group consisting of edible acid and a source of edible acid.
23. The method according to claim 10 , wherein the mixture subjected to heat treatment further comprises fat or a source of fat.
24. The method according to claim 10 , wherein at least one component selected from the group consisting of flavours, colorants and micronutrients are added to the acidified mixture prior to sterilisation or pasteurisation.
25. A liquid composition comprising:
2 to 10 weight % of denatured milk proteins expressed as solid-not-fat (SNF) milk components;
15 to 80 weight %, expressed as sugar equivalents, of a sweetener;
0.35 to 1.50 weight % of a stabilizer; and
an agent for reducing a pH of the composition to 3.0 to 3.8.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06012031A EP1867234B1 (en) | 2006-06-12 | 2006-06-12 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
| EP06012031.8 | 2006-06-12 | ||
| EP06125864.6 | 2006-12-12 | ||
| EP06125864.6A EP1946646B1 (en) | 2006-12-12 | 2006-12-12 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
| PCT/EP2007/055735 WO2007144333A1 (en) | 2006-06-12 | 2007-06-12 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2007/055735 A-371-Of-International WO2007144333A1 (en) | 2006-06-12 | 2007-06-12 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/734,637 Division US9781942B2 (en) | 2006-06-12 | 2015-06-09 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
Publications (1)
| Publication Number | Publication Date |
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| US20090181148A1 true US20090181148A1 (en) | 2009-07-16 |
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| US12/302,574 Abandoned US20090181148A1 (en) | 2006-06-12 | 2007-06-12 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
| US14/734,637 Expired - Fee Related US9781942B2 (en) | 2006-06-12 | 2015-06-09 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/734,637 Expired - Fee Related US9781942B2 (en) | 2006-06-12 | 2015-06-09 | Shelf-stable milk concentrates for preparing acidified milk based beverages |
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| Country | Link |
|---|---|
| US (2) | US20090181148A1 (en) |
| JP (1) | JP2009539392A (en) |
| KR (1) | KR101435222B1 (en) |
| AU (1) | AU2007260073B2 (en) |
| CA (1) | CA2655075C (en) |
| MX (1) | MX2008015856A (en) |
| MY (1) | MY149633A (en) |
| NZ (1) | NZ573480A (en) |
| RU (1) | RU2445777C2 (en) |
| SG (1) | SG2014013247A (en) |
| WO (1) | WO2007144333A1 (en) |
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| US20110305799A1 (en) * | 2010-06-10 | 2011-12-15 | Abbott Laboratories | Substantially clear nutritional liquids comprising calcium hmb and soluble protein |
| WO2013134627A1 (en) * | 2012-03-09 | 2013-09-12 | Kraft Foods Group Brands Llc | Beverage concentrates with increased viscosity and shelf life and methods of making the same |
| US20140272000A1 (en) * | 2013-03-14 | 2014-09-18 | Metabolic Technologies, Inc. | Liquids and Foodstuffs Containing beta-hydroxy-beta-methylbutyrate (HMB) in the Free Acid Form and Methods of Manufacturing or Producing the Same |
| CN104114033A (en) * | 2011-12-22 | 2014-10-22 | 雀巢产品技术援助有限公司 | Composition for the preparation of homemade frozen confections |
| US20150296819A1 (en) * | 2012-10-31 | 2015-10-22 | Calpis Co., Ltd | Concentrate-type milk-based acidic beverage and method for producing the same |
| WO2016034877A1 (en) * | 2014-09-02 | 2016-03-10 | Britvic Soft Drinks Limited | Composition |
| US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
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| BR112012005422B1 (en) * | 2009-09-11 | 2020-12-08 | Kraft Foods Group Brands Llc | liquid beverage concentrate and flavored liquid beverage concentrate |
| US8293299B2 (en) * | 2009-09-11 | 2012-10-23 | Kraft Foods Global Brands Llc | Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable Concentrated liquids |
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| CA2970476A1 (en) * | 2014-12-11 | 2016-06-16 | Danone S.A. | Method for packaging a high textured dairy product |
| CH715825A1 (en) * | 2019-02-08 | 2020-08-14 | Emmi Schweiz Ag | Process for the production of a cold mixed milk beverage. |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3800052A (en) * | 1970-11-26 | 1974-03-26 | Calpis Food Ind Co Ltd | Preparation of an acidified milk beverage |
| US3996391A (en) * | 1974-12-17 | 1976-12-07 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Method for production of syrup for soft drink |
| US3996390A (en) * | 1975-10-08 | 1976-12-07 | Merck & Co., Inc. | Acidified milk gel and method of producing the same |
| US4031264A (en) * | 1975-05-15 | 1977-06-21 | Dso "Bulgarplod" | Method for producing durable fruit-dairy and vegetable-dairy drinks |
| US4192901A (en) * | 1977-12-27 | 1980-03-11 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Milk-containing acid syrup |
| US4194019A (en) * | 1976-04-08 | 1980-03-18 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Preparation of an acidified milk beverage |
| US4212893A (en) * | 1978-02-10 | 1980-07-15 | Honey Bee Corporation | Acidified whole milk beverage and method of preparation |
| US4676988A (en) * | 1984-03-19 | 1987-06-30 | General Mills, Inc. | Low-acid juice-milk beverages, juice and milk components therefor and methods of preparation |
| US6171633B1 (en) * | 1998-08-14 | 2001-01-09 | Natura, Inc. | Milk-based drink |
| US6475539B1 (en) * | 1998-05-07 | 2002-11-05 | Abbott Laboratories | Nutritionally complete low pH enteral formula |
| US20030054079A1 (en) * | 1999-11-03 | 2003-03-20 | Moo Technologies, Inc. | Ultra-high temperature pasteurized milk concentrate, package, dispenser and method of producing same |
| US20040071821A1 (en) * | 2002-01-23 | 2004-04-15 | Jamshid Ashourian | Stabilized milk product containing juice |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3966390A (en) | 1973-08-21 | 1976-06-29 | Hitachi Chemical Company, Ltd. | Mold for polyimide, polyamide, or polyamide-imide resin which has noble metal layer on its surface to be in contact with resin |
| JPS54107555A (en) * | 1978-02-10 | 1979-08-23 | Hanii Bii Kk | Whole milk containing acidic drink |
| US4919960A (en) * | 1987-09-08 | 1990-04-24 | Dairy Research, Inc. | Process of making a carbonated liquid dairy product |
| EP0385051A1 (en) | 1989-03-02 | 1990-09-05 | FRILK (R) société anonyme | Beverage with a pH of 3,6 - 4,2 on the base of not-acidified milk and process for the fabrication of such a beverage |
| FR2670365B1 (en) | 1990-12-18 | 1993-12-24 | Eurial | MILK BEVERAGE AND PROCESS FOR ITS PREPARATION. |
| US5766666A (en) * | 1994-11-25 | 1998-06-16 | Borden Foods Corporation | Process for preparing reduced fat and fat free sweetened condensed milk |
| US5648112A (en) | 1995-03-28 | 1997-07-15 | The Procter & Gamble Company | Process for preparing chilled beverage products containing milk and a food acid |
| JP3387457B2 (en) | 1999-08-27 | 2003-03-17 | 不二製油株式会社 | Acidic protein food, its production method and stabilizer |
| JP3313104B2 (en) | 1999-10-27 | 2002-08-12 | カルピス株式会社 | Method for producing milk-containing acidic beverage |
| JP3400777B2 (en) | 1999-10-27 | 2003-04-28 | カルピス株式会社 | Low-calorie milk-containing acidic beverage |
| JP2004517633A (en) * | 2001-01-23 | 2004-06-17 | アショーリアン、ジャムシッド | Stabilized milk products containing fruit and juice |
| JP4412579B2 (en) * | 2003-05-09 | 2010-02-10 | ハウス食品株式会社 | Milk flavored acidic beverage and material for obtaining the same |
| NZ532296A (en) | 2004-04-14 | 2006-11-30 | Fonterra Co Operative Group | Dairy product and process for making carbonated milk beverages |
| US7380494B2 (en) * | 2004-07-23 | 2008-06-03 | Unilever Bestfoods North America, Division Of Conopco, Inc. | Dispensing machine |
| WO2008138900A2 (en) * | 2007-05-11 | 2008-11-20 | Novozymes A/S | Method for producing an acidified milk drink |
-
2007
- 2007-06-12 WO PCT/EP2007/055735 patent/WO2007144333A1/en not_active Ceased
- 2007-06-12 RU RU2008152034/10A patent/RU2445777C2/en active
- 2007-06-12 CA CA2655075A patent/CA2655075C/en active Active
- 2007-06-12 MX MX2008015856A patent/MX2008015856A/en active IP Right Grant
- 2007-06-12 KR KR1020087030248A patent/KR101435222B1/en active Active
- 2007-06-12 JP JP2009514775A patent/JP2009539392A/en active Pending
- 2007-06-12 NZ NZ573480A patent/NZ573480A/en not_active IP Right Cessation
- 2007-06-12 AU AU2007260073A patent/AU2007260073B2/en active Active
- 2007-06-12 US US12/302,574 patent/US20090181148A1/en not_active Abandoned
- 2007-06-12 MY MYPI20084713A patent/MY149633A/en unknown
- 2007-06-12 SG SG2014013247A patent/SG2014013247A/en unknown
-
2015
- 2015-06-09 US US14/734,637 patent/US9781942B2/en not_active Expired - Fee Related
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3800052A (en) * | 1970-11-26 | 1974-03-26 | Calpis Food Ind Co Ltd | Preparation of an acidified milk beverage |
| US3996391A (en) * | 1974-12-17 | 1976-12-07 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Method for production of syrup for soft drink |
| US4031264A (en) * | 1975-05-15 | 1977-06-21 | Dso "Bulgarplod" | Method for producing durable fruit-dairy and vegetable-dairy drinks |
| US3996390A (en) * | 1975-10-08 | 1976-12-07 | Merck & Co., Inc. | Acidified milk gel and method of producing the same |
| US4194019A (en) * | 1976-04-08 | 1980-03-18 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Preparation of an acidified milk beverage |
| US4192901A (en) * | 1977-12-27 | 1980-03-11 | Calpis Shokuhin Kogyo Kabushiki Kaisha | Milk-containing acid syrup |
| US4212893A (en) * | 1978-02-10 | 1980-07-15 | Honey Bee Corporation | Acidified whole milk beverage and method of preparation |
| US4676988A (en) * | 1984-03-19 | 1987-06-30 | General Mills, Inc. | Low-acid juice-milk beverages, juice and milk components therefor and methods of preparation |
| US6475539B1 (en) * | 1998-05-07 | 2002-11-05 | Abbott Laboratories | Nutritionally complete low pH enteral formula |
| US6171633B1 (en) * | 1998-08-14 | 2001-01-09 | Natura, Inc. | Milk-based drink |
| US20030054079A1 (en) * | 1999-11-03 | 2003-03-20 | Moo Technologies, Inc. | Ultra-high temperature pasteurized milk concentrate, package, dispenser and method of producing same |
| US20040071821A1 (en) * | 2002-01-23 | 2004-04-15 | Jamshid Ashourian | Stabilized milk product containing juice |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110305799A1 (en) * | 2010-06-10 | 2011-12-15 | Abbott Laboratories | Substantially clear nutritional liquids comprising calcium hmb and soluble protein |
| US9521859B2 (en) * | 2010-06-10 | 2016-12-20 | Normanella T. Dewille | Substantially clear nutritional liquids comprising calcium HMB and soluble protein |
| CN104114033A (en) * | 2011-12-22 | 2014-10-22 | 雀巢产品技术援助有限公司 | Composition for the preparation of homemade frozen confections |
| US20150140193A1 (en) * | 2011-12-22 | 2015-05-21 | Nestec S.A. | Composition for the preparation of homemade frozen confections |
| WO2013134627A1 (en) * | 2012-03-09 | 2013-09-12 | Kraft Foods Group Brands Llc | Beverage concentrates with increased viscosity and shelf life and methods of making the same |
| CN104168781A (en) * | 2012-03-09 | 2014-11-26 | 卡夫食品集团品牌有限责任公司 | Beverage concentrates with increased viscosity and shelf life and methods of making the same |
| US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
| US20150296819A1 (en) * | 2012-10-31 | 2015-10-22 | Calpis Co., Ltd | Concentrate-type milk-based acidic beverage and method for producing the same |
| US20140272000A1 (en) * | 2013-03-14 | 2014-09-18 | Metabolic Technologies, Inc. | Liquids and Foodstuffs Containing beta-hydroxy-beta-methylbutyrate (HMB) in the Free Acid Form and Methods of Manufacturing or Producing the Same |
| WO2016034877A1 (en) * | 2014-09-02 | 2016-03-10 | Britvic Soft Drinks Limited | Composition |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101435222B1 (en) | 2014-08-29 |
| RU2008152034A (en) | 2010-07-20 |
| US9781942B2 (en) | 2017-10-10 |
| US20150264953A1 (en) | 2015-09-24 |
| MY149633A (en) | 2013-09-13 |
| RU2445777C2 (en) | 2012-03-27 |
| KR20090016580A (en) | 2009-02-16 |
| MX2008015856A (en) | 2009-01-12 |
| JP2009539392A (en) | 2009-11-19 |
| SG2014013247A (en) | 2014-05-29 |
| AU2007260073B2 (en) | 2014-01-16 |
| CA2655075A1 (en) | 2007-12-21 |
| CA2655075C (en) | 2015-02-03 |
| WO2007144333A1 (en) | 2007-12-21 |
| NZ573480A (en) | 2011-11-25 |
| AU2007260073A1 (en) | 2007-12-21 |
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