US20090091054A1 - Device and Process for Producing Pellets From a Plastic Melt - Google Patents
Device and Process for Producing Pellets From a Plastic Melt Download PDFInfo
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- US20090091054A1 US20090091054A1 US12/227,229 US22722907A US2009091054A1 US 20090091054 A1 US20090091054 A1 US 20090091054A1 US 22722907 A US22722907 A US 22722907A US 2009091054 A1 US2009091054 A1 US 2009091054A1
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- energy
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- process chamber
- plastic melt
- process fluid
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- 238000000034 method Methods 0.000 title claims abstract description 163
- 230000008569 process Effects 0.000 title claims abstract description 162
- 239000004033 plastic Substances 0.000 title claims abstract description 62
- 229920003023 plastic Polymers 0.000 title claims abstract description 62
- 239000008188 pellet Substances 0.000 title claims abstract description 32
- 239000012530 fluid Substances 0.000 claims abstract description 87
- 239000008187 granular material Substances 0.000 claims abstract description 47
- 238000005086 pumping Methods 0.000 claims abstract description 21
- 238000001125 extrusion Methods 0.000 claims abstract description 13
- 239000000284 extract Substances 0.000 claims abstract description 4
- 238000011084 recovery Methods 0.000 claims description 27
- 239000000126 substance Substances 0.000 claims description 14
- 239000000155 melt Substances 0.000 claims description 9
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- 239000004794 expanded polystyrene Substances 0.000 claims description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000426 Microplastic Polymers 0.000 description 1
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
- B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
Definitions
- the invention relates to a device for producing pellets from a plastic melt according to the preamble of claim 1 , to a corresponding process according to the preamble of claim 11 and to an application according to claim 13 .
- An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process, but is not limited thereto.
- Another area of application for the production of pellets from molten plastics by extrusion according to the invention is, for example, the production of granules by dropletizing of molten plastics, wherein a process chamber is filled with pressurized gas and is provided in the lower region with a liquid bath for collecting the granules, with a pressurized process fluid.
- a melt of plastic material is forced through a perforated plate in the upper region of the process chamber, whereupon, under the influence of surface tension and/or through the action of vibrations or other stresses, the issuing, as it were, “extruded” strands of the plastic melt disaggregate into a chain of droplets, similarly as in a chopping device, wherein, under the influence of the gas, which may serve also as a coolant, and/or through immersion in the process fluid, said droplets solidify by cooling or other reactions.
- a plastic melt is pressed through a plate provided with holes, a so-called perforated plate.
- the holes are arranged in one or more circles of holes or in an annular pattern, the respective centre point being aligned with a drive shaft of a cutter arrangement of a chopping device.
- the issuing plastic strands are chopped into small fragments by the cutter arrangement, which runs more or less directly on the surface of the perforated plate.
- a process fluid usually process water, which is delivered with the cutters, said fragments are then removed from the site of their production in a process chamber, there taking place intensive cooling and, therefore, solidification of the chopped fragments.
- the pellets thus produced for example, by the underwater hot-face or dropletization process are transported out of the process chamber by the process fluid and are conventionally supplied through pipes to a separation device in which, given sufficient holding time, the pellets are separated from the process fluid and are subsequently supplied to a drying unit.
- a coaxial vortex is normally produced in the housing of such a device, more particularly about the rotation axis of the cutter arrangement, i.e. about the shaft, there being an area of reduced pressure at the centre of such vortex. If the central pressure falls below a critical value, which depends also on other process parameters, this may lead to outgassing and vaporization of the process fluid, this resulting, on account of corresponding vapour bubbles, in considerably diminished transport and cooling properties of the process fluid.
- the inside diameter of the pipe should not be less than 25 to 40 mm. If use is made of sufficiently wide and/or particularly long pipes (e.g. in order to exploit a certain geodetic height of a column of the process fluid), this may, in turn, have the disadvantage that there is a corresponding increase in the holding time of the pellets in the process fluid, which may therefore possibly result in too great a cooling effect.
- squeeze valves already locally limited in their application in the prior art, which are capable of effecting a sufficient increase in pressure through a locally limited reduction of the cross-section in the outgoing pipe if the inner width of the squeezing gap is of or below the order of magnitude of the produced pellet diameter.
- squeeze valves harbour the great risk of, or lead in any case to, an obstruction of the outgoing pipe, something which, of course, is not desirable.
- a further application for a device or process for producing pellets from a plastic melt by extrusion according to the invention relates to systems which process plastic melts containing substances which, under the conditions prevailing during discharge from the holes in the perforated plate, would outgas out of the plastic melt if the ambient pressure were not high enough.
- Such attendant substances in the melt may, in the simplest case, be water, which may be contained in the plastic material. However, these may also be functional substances, such as flame retardants, propellants for foamable plastics or desired or undesired reaction products of the plastic melt itself.
- the object of the invention is achieved by a device having the features according to claim 1 , by a process having the features according to claim 11 and by an application having the features according to claim 13 . Further embodiments of the invention are defined in the respective subclaims.
- the device according to the invention for producing pellets from a plastic melt by extrusion comprises a perforated plate from which the plastic melt is extruded at a pressure above the ambient pressure; a process chamber into which the plastic melt is extruded; a chopping device for chopping strands of the plastic melt extruded from the perforated plate into individual granules, the process chamber being filled with a process fluid; and a pumping device which supplies the process fluid to the process chamber at a pressure above the ambient pressure, the pressure of the process fluid with the therein contained granules being reduced downstream of the process chamber.
- the pressure of the process fluid together with the therein contained granules is reduced, it not being the case, as described in the aforementioned publication, that first the pressure of the process fluid itself is reduced, whereupon only thereafter are the granules removed from the system.
- an energy converter provided downstream of the process chamber, wherein said energy converter extracts at least some of the pressure energy from the process fluid with the therein contained granules, reduces the pressure of the process fluid with the therein contained granules and converts at least some of the extracted energy into a reusable form of energy.
- An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process or, alternatively, for example, to the production of granules by dropletization of molten plastics.
- Momentum energy is particularly advantageous as a reusable form of energy.
- the energy converter according to the invention may be, for example, a turbine.
- a turbine is, by general definition, a machine that converts the kinetic and pressure energy of a moving fluid into mechanically usable energy, e.g. in the form of torque.
- the general counterparts thereto are, for example, piston engines or displacement machines, such as the driving cylinders of steam engines, in which the kinetic energy of the moving fluid plays only a subordinate role with regard to energy conversion.
- the kinetic energy of the process fluid can thereby be actively converted into an angular momentum, where the corresponding inlet guide vanes and impeller blades of such a turbine can be so arranged that the momentum inherent in the process fluid with the therein contained granules is converted into an angular momentum of the impeller.
- the thus driven impeller of the turbine can then be transmitted via a shaft to a drive or output unit which is capable, for example, of driving an electric generator. Consequently, a turbine arrangement according to the invention dispenses with the need to select particularly narrow pipe cross-sections in order to build up a required backpressure.
- the energy converter according to the invention may also be in the form of a flexible-tube pump with reverse energy flow direction.
- flexible-tube pumps are counted among the displacement machines in terms of their characteristics.
- Such a flexible-tube pump with reverse energy flow direction is based on the principle that a flexible tube is pinched off completely or up to a certain extent, the pinched-off portion being moved further along the tube. Depending on the speed of movement of the pinched-off portion and the cross-section of the rest of the tube, therefore, a precisely predeterminable volumetric flow rate is permitted.
- Flexible-tube pumps in the conventional sense, i.e. without reverse energy flow direction as in the invention, operate in such a manner that a motor drives a shaft on which two or more pinch shoes or pinch rollers compress a tube supported on the inside of a cylinder segment, the contents of the tube being permanently pushed forward by the rotational movement of the shaft.
- the driving energy of the motor is converted into a rotational movement which, in turn, sets in flow the fluid that is to be transported in the tube, with a certain application of pressure to the fluid that is to be transported. This is where the invention makes precisely opposite use of a flexible-tube pump, i.e.
- the application of pressure to the process fluid with the therein contained granules in the flexible-tube pump causes a corresponding rotational movement which can be picked off at an output shaft and be reused.
- the output shaft may be fitted with an electric generator, it additionally being possible, as also in the case of a turbine or in the case of other conceivable energy converters according to the invention, to provide a frequency converter with braking resistor or an electric energy-recovery unit.
- a flexible-tube pump with reverse energy flow direction according to the invention is relatively insensitive with regard to obstructions, because at no point, except in the region of the advancing pinched-off portions, is the inside width of the tube seriously constricted.
- the pinched-off portions migrate with the pinch device along the tube and open again completely at the end of the delivery inflow, with the result that there is no agglomeration or, consequently, obstruction with pellet particles by reason of the absence of contact pressure of adhesion of the particles to the tube or any similar possibility of blockage.
- the volumetric flow rate of the process fluid with the therein contained pellets can be controlled with regard to the adjusted volumetric flow rate and with regard to the thus generated pressure, wherein the delivery characteristics of the pumping device according to the invention with regard to the generated pressure from said volumetric flow rate are exploited in order to monitor a constancy of the energy flow through suitable adjustment of the drive thereof.
- a pipe for the process fluid has a damping element for damping and compensating pulsations, having preferably an air chamber.
- the energy converter according to the invention may also be a gear pump with reverse energy flow direction, wherein the energy inherent in the process fluid with the therein contained pellets is extracted relatively simply in suitable manner through conversion of the corresponding momentum into an angular momentum.
- gear pumps are counted among the displacement machines in terms of their characteristics.
- suitable energy converters according to the invention may also, in terms of their design, be based on known centrifugal pumps, radial pumps, diagonal pumps or axial pumps.
- the principle of energy conversion according to the invention may be based on the fact that the process fluid with the therein contained granules is conducted into a housing similar, for example, to a conventional centrifugal-pump housing, the process fluid being set, if necessary with the assistance of inlet guide vanes, in a rotational movement relative to the axis of an impeller.
- the kinetic energy of the process fluid with the therein contained granules is thereby converted into an angular momentum.
- the angular momentum is then transmitted to an impeller.
- the device according to the invention may have essentially no stationary constriction of a flow cross-section downstream of the process chamber, i.e. there is no permanently stationary constriction. Consequently, it will always be possible for the available inside width between corresponding components to be greater than a critical size of agglomerations that may occur and are to be expected under certain operating conditions, such as at the startup of a production process, with the result that, in a particularly preferred embodiment, blockages of the device can be prevented.
- housings, inlet guide vanes and impellers as well as of other elements of the energy converter according to the intervention as hereinbefore described in preferred embodiments, will have an influence on the prevention of blockages of the device, wherein the provision of the energy converter according to the invention makes this simple and cost-effective to achieve in comparison with the prior art as initially described.
- an energy-recovery device may be provided by means of which the extracted and converted energy can be recovered to the pumping device.
- the energy that can be extracted by the energy converter is just as great as the energy previously required to build up the pressure by the pumping device, because, in practice, it is necessary to take account of hydraulic, mechanical and other losses, it having to be considered that the efficiency of the pumps, turbines and similar equipment preferably provided according to the invention will not be 100% and is, moreover, also dependent on the rotational speed. Consequently, in the case of the energy-recovery device provided according to the invention, intermediate gear drives may under certain circumstances have an influence on the overall efficiency, i.e. they may, to a certain extent, either improve or worsen the overall efficiency.
- the energy-recovery device may provide for mechanical, electrical, pneumatic or hydraulic energy recovery or a combination thereof.
- the energy-recovery device is connected to the energy converter according to the invention, wherein, in turn, the energy-recovery device may be connected to a further pumping device additional to the hereinbefore-described actual pumping device, this making it possible to compensate for hydraulic and any other losses in the overall device.
- a control loop may be provided by means of which the pressure in the process chamber is adjustable such that said pressure is slightly above, preferably just above, the pressure at which the process fluid evaporates at the prevailing temperature.
- control loop more particularly the same control loop as described in the preceding paragraph, by means of which the pressure in the process chamber is adjustable such that said pressure is slightly above, preferably just above, the pressure at which attendant substances contained in the plastic melt evaporate at the prevailing temperature.
- control loop may be so connected (or not be connected) to the energy converter and/or optionally also to the energy-recovery device as to provide the possibility of corresponding closed-loop/open-loop control.
- the process according to the invention serves to produce pellets from a plastic melt by extrusion.
- An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process or, alternatively, for example, to the production of granules by dropletization of molten plastics.
- a plastic melt is produced, the plastic melt being extruded at a pressure above the ambient pressure through a perforated plate into a process chamber filled with a process fluid.
- a pumping device supplies the process fluid to the process chamber at a pressure above the ambient pressure.
- the pressure of the process fluid with the therein contained granules is reduced downstream of the process chamber.
- at least some of the pressure energy is extracted from the process fluid with the therein contained granules by an energy converter provided downstream of the process chamber, the pressure of the process fluid with the therein contained granules being reduced and at least some of the extracted energy being converted into a reusable form of energy.
- the extracted and converted energy may be recovered to the pumping device through an energy-recovery device, as has likewise already been explained hereinbefore in connection with the device according to the invention.
- a device for producing pellets from a plastic melt with the hereinbefore-described features and/or a process for producing pellets from a plastic melt with the hereinbefore-described features finds application in the processing of a plastic melt with attendant substances, which attendant substances will outgas unless there is a sufficient pressure above the ambient pressure in a melt supply arrangement and/or in the process chamber.
- the plastic melt with attendant substances is expanded polystyrene (EPS).
- FIG. 1 shows a diagrammatic view of a system set-up with a device according to the invention
- FIGS. 2 a to c show three different embodiments of detail A according to the invention from FIG. 1 ;
- FIGS. 3 a and b show two different embodiments of detail B from FIG. 1 .
- FIG. 4 shows a first embodiment of an energy converter according to the invention
- FIG. 5 shows a second embodiment of an energy converter according to the invention
- FIG. 6 shows a third embodiment of the energy converter according to the invention.
- FIG. 7 shows a detail view of a chopping device according to an embodiment of the invention.
- FIG. 1 shows a diagrammatic representation of a system set-up with a device for producing pellets according to an embodiment of the invention.
- a plastic melt that is to be pelletized is supplied to the pelletization site, namely to the chopping device identified by reference character 3 in FIG. 1 .
- an energy converter 6 which extracts at least some of the pressure energy from the process fluid with the therein contained granules, reducing the pressure of the process fluid with the therein contained granules and converting at least some of the extracted energy into a reusable form of energy.
- the energy converter 6 may be preferably a turbine, a flexible-tube pump with reverse energy flow direction or a gear pump with reverse energy flow direction.
- a pipe for the process fluid may, as shown in FIG. 1 , be provided with a damping element 15 for damping and compensating pulsations, being provided preferably with an air chamber.
- the process fluid with the therein contained granules is supplied to a separator 8 in which the process fluid is separated from the granules.
- the granules are then delivered to a store 9 for separated pellets.
- the process fluid 4 is collected in a container 10 for process fluid and is returned to a pumping circuit, wherein, according to FIG. 1 , the suction side of the pumping device 5 is fluidically connected to the container 10 .
- control loop 14 by means of which the pressure in the process chamber 2 is adjustable such that said pressure is slightly above, preferably just above, the pressure at which the process fluid evaporates at the prevailing temperature and/or such that said pressure is slightly above, preferably just above, the pressure at which attendant substances contained in the plastic melt evaporate at the prevailing temperature.
- the control loop 14 is so connected to the energy converter 6 and/or optionally to an energy-recovery device 7 as to allow a corresponding closed-loop/open-loop control.
- Detail A in FIG. 1 identifies the energy-recovery device 7 , which provides for the energy reusably converted by the energy converter 6 according to the invention to be recovered in order to operate the device, more particularly in order to drive the pumping device 5 .
- FIGS. 2 a to 2 c present three different embodiments of the energy-recovery device 7 according to detail A in FIG. 1 .
- the energy-recovery device 7 recovers the extracted and converted energy to the pumping device 5 .
- FIG. 2 a presents an energy-recovery device 7 with energy recovery via an electromechanical gear drive and with an inverter.
- FIG. 2 b presents an energy-recovery device 7 with a hydraulic gear drive.
- FIG. 2 c presents an energy-recovery device 7 with a mechanical gear drive.
- the respective drive ends of the energy-recovery devices 7 are each connected to the energy converter 6 , the output ends of the respective energy-recovery devices 7 being connected to the pumping device 5 .
- FIG. 3 presents two different embodiments of a plastic-melt supply arrangement according to detail B in FIG. 1 .
- FIG. 3 a presents a plastic-melt supply arrangement with an extruder 11 with drive, wherein the melt is supplied via a melt pump 13 onward to the chopping device 3 in FIG. 1 .
- FIG. 3 b presents a reactor 12 from which the melt is supplied via a melt pump 13 to the chopping device 3 from FIG. 1 .
- FIG. 4 presents an embodiment of an energy converter 6 according to the invention, said energy converter 6 being in the form of a turbine, in a perspective, partially exploded view.
- the process fluid 4 with the therein contained granules is supplied via a tangential inlet to the turbine.
- the turbine housing accommodates an impeller with impeller vanes, the process fluid with the therein contained granules being carried radially inwards and being discharged via an axial outlet in a housing cover of the turbine. As it passes through the turbine according to FIG.
- the process fluid 4 with the therein contained granules transmits pressure energy by momentum transfer to the impeller vanes of the impeller of the turbine, thereby driving the impeller and thus the output of the turbine, with the result that the pressure of the process fluid 4 with the therein contained granules is reduced and at least some of the extracted energy is converted according to the invention into a reusable form of energy.
- FIG. 5 presents a further preferred embodiment of an energy converter 6 according to the invention, namely a sectional view of a gear pump.
- the gear pump has a reverse energy flow direction, i.e. it is actually not used as a pump, but, as it flows through the gear pump, the pressure of the process fluid with the therein contained granules sets said pump in motion, where said motion, i.e. the rotational motion of the corresponding gearwheels of the gear pump, is then reusable.
- FIG. 6 presents a further preferred embodiment of an energy converter 6 according to the invention, namely a flexible-tube pump with reverse energy flow direction, which flexible-tube pump was already described hereinbefore.
- FIG. 7 presents an embodiment of a chopping device 3 in a partially cut-away side elevation view.
- a plastic melt is supplied via a perforated plate 1 to a process chamber 2 .
- Process fluid flows into the process chamber from above, indicated by an arrow in FIG. 7 , at a pressure that is above the ambient pressure.
- the process chamber is completely filled with process fluid 4 .
- the process fluid 4 with the therein contained granules is discharged from the process chamber 2 via an outlet.
- the flow direction of the process fluid is presented by arrows in FIG. 7 .
- the chopping device 3 further has a cutter head which is connected by a shaft to an electric motor, whereby the strands of the plastic melt extruded into the process chamber 2 are chopped into individual granules.
- the device according to the invention, the process according to the invention and the corresponding application according to the invention provide a simple and cost-effective means of safely guaranteeing the reliable production of pellets under all operating conditions.
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- Engineering & Computer Science (AREA)
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- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Glanulating (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
- The invention relates to a device for producing pellets from a plastic melt according to the preamble of claim 1, to a corresponding process according to the preamble of
claim 11 and to an application according toclaim 13. - An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process, but is not limited thereto.
- Another area of application for the production of pellets from molten plastics by extrusion according to the invention is, for example, the production of granules by dropletizing of molten plastics, wherein a process chamber is filled with pressurized gas and is provided in the lower region with a liquid bath for collecting the granules, with a pressurized process fluid. A melt of plastic material is forced through a perforated plate in the upper region of the process chamber, whereupon, under the influence of surface tension and/or through the action of vibrations or other stresses, the issuing, as it were, “extruded” strands of the plastic melt disaggregate into a chain of droplets, similarly as in a chopping device, wherein, under the influence of the gas, which may serve also as a coolant, and/or through immersion in the process fluid, said droplets solidify by cooling or other reactions.
- In the underwater hot-face process, a plastic melt is pressed through a plate provided with holes, a so-called perforated plate. Typically, the holes are arranged in one or more circles of holes or in an annular pattern, the respective centre point being aligned with a drive shaft of a cutter arrangement of a chopping device. The issuing plastic strands are chopped into small fragments by the cutter arrangement, which runs more or less directly on the surface of the perforated plate. By means of a process fluid, usually process water, which is delivered with the cutters, said fragments are then removed from the site of their production in a process chamber, there taking place intensive cooling and, therefore, solidification of the chopped fragments. The pellets thus produced, for example, by the underwater hot-face or dropletization process are transported out of the process chamber by the process fluid and are conventionally supplied through pipes to a separation device in which, given sufficient holding time, the pellets are separated from the process fluid and are subsequently supplied to a drying unit.
- Usually, as a consequence of the geometry of the inlet and outlet of the process fluid to and from the process chamber and/or as a consequence of the cutter arrangement and the shaft for moving the cutter arrangement, a coaxial vortex is normally produced in the housing of such a device, more particularly about the rotation axis of the cutter arrangement, i.e. about the shaft, there being an area of reduced pressure at the centre of such vortex. If the central pressure falls below a critical value, which depends also on other process parameters, this may lead to outgassing and vaporization of the process fluid, this resulting, on account of corresponding vapour bubbles, in considerably diminished transport and cooling properties of the process fluid. This gives rise to a significant deterioration in the reliable operation of a prior-art underwater hot-face or dropletization system. Furthermore, if a vapour bubble occurs directly at the perforated plate, this may result, because of the thereby reduced cooling, in agglutination and gumming-up of the openings of the circle of holes by the plastic melt, which can lead, in the worst case, to a complete stoppage in the production of plastic pellets.
- It is possible—for example by reducing the cross-section of the pipes for the inlet and outlet of the process fluid to and from the process chamber or by exploiting a certain geodetic height of a column of the process fluid by means of appropriate arrangement of the device—to generate a higher backpressure of the process fluid in the process chamber, which will counteract the formation of a vacuum—and in the worst case—of vapour bubbles in the process fluid there. However, such prior-art solutions give rise to other serious disadvantages. For instance, especially in the case of pipes of small cross-section, there may, particularly at the start of a production run, be agglomerations of granules, since those process parameters that are required for a smooth operation process cannot be achieved immediately upon startup of the device. Such agglomerations easily lead to obstructions in the outgoing pipe and can therefore result in a complete stoppage of the production process. In practice, it has been demonstrated that, depending on the pellets, size of system and type of plastic material being processed, the inside diameter of the pipe should not be less than 25 to 40 mm. If use is made of sufficiently wide and/or particularly long pipes (e.g. in order to exploit a certain geodetic height of a column of the process fluid), this may, in turn, have the disadvantage that there is a corresponding increase in the holding time of the pellets in the process fluid, which may therefore possibly result in too great a cooling effect. The undesirable consequence thereof is to prevent the possibility of using the inherent heat of the pellets for the drying thereof, with the result that the energy required for drying must be additionally supplied at corresponding cost. Moreover, in the case of some plastic materials, this suppresses desired crystallization processes, this resulting in additional process steps and necessitating considerable further technical and financial expenditure.
- If one were simply to increase the flow of the process fluid, i.e. the flow rate thereof, although reducing the holding time, this measure would, in turn, give rise to the occurrence of the above-mentioned central bubble, because the vacuum produced at the centre increases approximately with the square of the rotational speed of the process fluid in a vortex, it then being possible for the central bubble to form. The influence of the flow rate of the process fluid is further amplified by the rotational speed of the cutters of a chopping device.
- There are squeeze valves, already locally limited in their application in the prior art, which are capable of effecting a sufficient increase in pressure through a locally limited reduction of the cross-section in the outgoing pipe if the inner width of the squeezing gap is of or below the order of magnitude of the produced pellet diameter. However, such squeeze valves harbour the great risk of, or lead in any case to, an obstruction of the outgoing pipe, something which, of course, is not desirable.
- A further application for a device or process for producing pellets from a plastic melt by extrusion according to the invention relates to systems which process plastic melts containing substances which, under the conditions prevailing during discharge from the holes in the perforated plate, would outgas out of the plastic melt if the ambient pressure were not high enough. Such attendant substances in the melt may, in the simplest case, be water, which may be contained in the plastic material. However, these may also be functional substances, such as flame retardants, propellants for foamable plastics or desired or undesired reaction products of the plastic melt itself. As a consequence of a required increase in the pressure in the process chamber and in the downstream outgoing pipe system, such substances remain dissolved in the plastic melt until, as a result of the cooling effect that occurs on account of the process fluid, the plastic melt has solidified to such an extent that the outgassing, and therefore swelling, of the produced plastic-melt pellets is effectively suppressed.
- Known from document EP 1 522 395 A2 is a process and device for the thermal crystallization of a molten polyester polymer in a fluid wherein, having been extruded from a perforated plate and chopped by a chopping device, the strands of the corresponding plastic melt are chopped into individual granules which reside for a certain time in a pressurized process fluid, the granules being separated from the pressurized process fluid by a separation device.
- It is therefore an object of the present invention to provide a device, process and corresponding application for producing pellets from a plastic melt, said device, process and application overcoming the disadvantages associated with the prior art and, more particularly, to provide a device, process and application which, in relatively simple, energy-saving and, therefore, cost-effective manner, permit the safe and reliable production of pellets under essentially all operating conditions.
- The object of the invention is achieved by a device having the features according to claim 1, by a process having the features according to
claim 11 and by an application having the features according toclaim 13. Further embodiments of the invention are defined in the respective subclaims. - The device according to the invention for producing pellets from a plastic melt by extrusion comprises a perforated plate from which the plastic melt is extruded at a pressure above the ambient pressure; a process chamber into which the plastic melt is extruded; a chopping device for chopping strands of the plastic melt extruded from the perforated plate into individual granules, the process chamber being filled with a process fluid; and a pumping device which supplies the process fluid to the process chamber at a pressure above the ambient pressure, the pressure of the process fluid with the therein contained granules being reduced downstream of the process chamber. Contrary to the device known, for example, from the aforementioned EP 1 522 395 A2, therefore, according to the invention the pressure of the process fluid together with the therein contained granules is reduced, it not being the case, as described in the aforementioned publication, that first the pressure of the process fluid itself is reduced, whereupon only thereafter are the granules removed from the system. Further provided according to the invention is an energy converter provided downstream of the process chamber, wherein said energy converter extracts at least some of the pressure energy from the process fluid with the therein contained granules, reduces the pressure of the process fluid with the therein contained granules and converts at least some of the extracted energy into a reusable form of energy. An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process or, alternatively, for example, to the production of granules by dropletization of molten plastics.
- The invention is based, in particular, on the following consideration, that pressure, too, constitutes a certain form of energy, where the energy E contained in a volume element V at pressure p is calculated as E=p×V. According to the invention, at least some of this pressure energy is extracted by the energy converter according to the invention and is converted into another, reusable form of energy. Contrary to the above-described prior art, therefore, the use of the energy converter according to the invention makes it possible, in simple and cost-effective manner, to ensure the safe and reliable production of pellets under all operating conditions. In particular, a sufficient pressure can always been made available, despite which, according to the invention, at least some of the extracted energy is or can be actively converted downstream of a process chamber into a reusable form of energy.
- The generation of a backpressure as in the prior art, as was described hereinbefore —namely, for example, through the use of narrowed pipe cross-sections, local constrictions in the form of nozzles or through geodetic height differences in a system which produce a fluid column pressure—is, by contrast, as explained hereinbefore, not only passive, i.e. difficult or impossible to adjust to different process parameters, but is also not totally safe and reliable under all operating conditions. Furthermore, the prior-art solutions, such as different geodetic heights of the elements of a system, can in some cases only be realized with very great constructional effort. By contrast, the device according to the invention offers all the hereinbefore-described advantages, because the pressure energy can be actively reduced by the energy converter according to the invention and can be converted into a reusable form of energy.
- Momentum energy is particularly advantageous as a reusable form of energy.
- The energy converter according to the invention may be, for example, a turbine. A turbine is, by general definition, a machine that converts the kinetic and pressure energy of a moving fluid into mechanically usable energy, e.g. in the form of torque. The general counterparts thereto are, for example, piston engines or displacement machines, such as the driving cylinders of steam engines, in which the kinetic energy of the moving fluid plays only a subordinate role with regard to energy conversion. Thus, according to the invention, in the case of a turbine, the kinetic energy of the process fluid can thereby be actively converted into an angular momentum, where the corresponding inlet guide vanes and impeller blades of such a turbine can be so arranged that the momentum inherent in the process fluid with the therein contained granules is converted into an angular momentum of the impeller. The thus driven impeller of the turbine can then be transmitted via a shaft to a drive or output unit which is capable, for example, of driving an electric generator. Consequently, a turbine arrangement according to the invention dispenses with the need to select particularly narrow pipe cross-sections in order to build up a required backpressure.
- The energy converter according to the invention may also be in the form of a flexible-tube pump with reverse energy flow direction. Generally, flexible-tube pumps are counted among the displacement machines in terms of their characteristics.
- Such a flexible-tube pump with reverse energy flow direction is based on the principle that a flexible tube is pinched off completely or up to a certain extent, the pinched-off portion being moved further along the tube. Depending on the speed of movement of the pinched-off portion and the cross-section of the rest of the tube, therefore, a precisely predeterminable volumetric flow rate is permitted. A predetermined quantity of energy is released by the pressure upstream of the pinched-off portion using the formula work=force×distance, where the work corresponds to a certain quantity of energy. The same consideration applies if, instead of a linear movement of the pinched-off portion, there is a circular movement, as may be provided according to the invention by a flexible-tube pump arrangement with reverse energy flow direction.
- Flexible-tube pumps in the conventional sense, i.e. without reverse energy flow direction as in the invention, operate in such a manner that a motor drives a shaft on which two or more pinch shoes or pinch rollers compress a tube supported on the inside of a cylinder segment, the contents of the tube being permanently pushed forward by the rotational movement of the shaft. First of all, the driving energy of the motor is converted into a rotational movement which, in turn, sets in flow the fluid that is to be transported in the tube, with a certain application of pressure to the fluid that is to be transported. This is where the invention makes precisely opposite use of a flexible-tube pump, i.e. according to the invention, the application of pressure to the process fluid with the therein contained granules in the flexible-tube pump causes a corresponding rotational movement which can be picked off at an output shaft and be reused. For example, the output shaft may be fitted with an electric generator, it additionally being possible, as also in the case of a turbine or in the case of other conceivable energy converters according to the invention, to provide a frequency converter with braking resistor or an electric energy-recovery unit.
- A flexible-tube pump with reverse energy flow direction according to the invention is relatively insensitive with regard to obstructions, because at no point, except in the region of the advancing pinched-off portions, is the inside width of the tube seriously constricted. The pinched-off portions migrate with the pinch device along the tube and open again completely at the end of the delivery inflow, with the result that there is no agglomeration or, consequently, obstruction with pellet particles by reason of the absence of contact pressure of adhesion of the particles to the tube or any similar possibility of blockage.
- Generally, according to the invention, the volumetric flow rate of the process fluid with the therein contained pellets can be controlled with regard to the adjusted volumetric flow rate and with regard to the thus generated pressure, wherein the delivery characteristics of the pumping device according to the invention with regard to the generated pressure from said volumetric flow rate are exploited in order to monitor a constancy of the energy flow through suitable adjustment of the drive thereof.
- According to the invention, a pipe for the process fluid has a damping element for damping and compensating pulsations, having preferably an air chamber.
- The energy converter according to the invention may also be a gear pump with reverse energy flow direction, wherein the energy inherent in the process fluid with the therein contained pellets is extracted relatively simply in suitable manner through conversion of the corresponding momentum into an angular momentum. Generally, gear pumps are counted among the displacement machines in terms of their characteristics.
- Generally, suitable energy converters according to the invention may also, in terms of their design, be based on known centrifugal pumps, radial pumps, diagonal pumps or axial pumps.
- The principle of energy conversion according to the invention may be based on the fact that the process fluid with the therein contained granules is conducted into a housing similar, for example, to a conventional centrifugal-pump housing, the process fluid being set, if necessary with the assistance of inlet guide vanes, in a rotational movement relative to the axis of an impeller. The kinetic energy of the process fluid with the therein contained granules is thereby converted into an angular momentum. The angular momentum is then transmitted to an impeller.
- The device according to the invention may have essentially no stationary constriction of a flow cross-section downstream of the process chamber, i.e. there is no permanently stationary constriction. Consequently, it will always be possible for the available inside width between corresponding components to be greater than a critical size of agglomerations that may occur and are to be expected under certain operating conditions, such as at the startup of a production process, with the result that, in a particularly preferred embodiment, blockages of the device can be prevented.
- In particular, the design of housings, inlet guide vanes and impellers as well as of other elements of the energy converter according to the intervention as hereinbefore described in preferred embodiments, will have an influence on the prevention of blockages of the device, wherein the provision of the energy converter according to the invention makes this simple and cost-effective to achieve in comparison with the prior art as initially described.
- According to the invention, an energy-recovery device may be provided by means of which the extracted and converted energy can be recovered to the pumping device. In addition to exclusively electric energy recovery, it is also possible to provide mechanical or hydraulic energy recovery. At any rate, the energy balance of the overall device is thereby significantly improved. In the theoretical energy balance, the energy that can be extracted by the energy converter is just as great as the energy previously required to build up the pressure by the pumping device, because, in practice, it is necessary to take account of hydraulic, mechanical and other losses, it having to be considered that the efficiency of the pumps, turbines and similar equipment preferably provided according to the invention will not be 100% and is, moreover, also dependent on the rotational speed. Consequently, in the case of the energy-recovery device provided according to the invention, intermediate gear drives may under certain circumstances have an influence on the overall efficiency, i.e. they may, to a certain extent, either improve or worsen the overall efficiency.
- As already indicated, the energy-recovery device may provide for mechanical, electrical, pneumatic or hydraulic energy recovery or a combination thereof.
- According to the invention, the energy-recovery device is connected to the energy converter according to the invention, wherein, in turn, the energy-recovery device may be connected to a further pumping device additional to the hereinbefore-described actual pumping device, this making it possible to compensate for hydraulic and any other losses in the overall device.
- According to the invention, a control loop may be provided by means of which the pressure in the process chamber is adjustable such that said pressure is slightly above, preferably just above, the pressure at which the process fluid evaporates at the prevailing temperature. This offers the advantage that extrusion can take place with minimal stressing of the material and, consequently, with particular reliability, especially where highly volatile process fluid is employed.
- According to the invention, it is also possible to provide a control loop, more particularly the same control loop as described in the preceding paragraph, by means of which the pressure in the process chamber is adjustable such that said pressure is slightly above, preferably just above, the pressure at which attendant substances contained in the plastic melt evaporate at the prevailing temperature. This offers the further advantage that extrusion can take place with minimal stressing of the material and, consequently, with particular reliability, especially where a plastic melt with highly volatile attendant substances is employed.
- According to an embodiment of the invention, the control loop may be so connected (or not be connected) to the energy converter and/or optionally also to the energy-recovery device as to provide the possibility of corresponding closed-loop/open-loop control.
- The process according to the invention serves to produce pellets from a plastic melt by extrusion. An area of application for the production of pellets from molten plastics by extrusion according to the invention relates, for example, to the use of an underwater hot-face process or, alternatively, for example, to the production of granules by dropletization of molten plastics. In the process according to the invention, a plastic melt is produced, the plastic melt being extruded at a pressure above the ambient pressure through a perforated plate into a process chamber filled with a process fluid. The strands of the plastic melt extruded from the perforated plate are chopped into individual granules, use being made in a particularly preferred embodiment of a chopping device, wherein, according to the invention, a pumping device supplies the process fluid to the process chamber at a pressure above the ambient pressure. The pressure of the process fluid with the therein contained granules is reduced downstream of the process chamber. According to the invention, at least some of the pressure energy is extracted from the process fluid with the therein contained granules by an energy converter provided downstream of the process chamber, the pressure of the process fluid with the therein contained granules being reduced and at least some of the extracted energy being converted into a reusable form of energy.
- The statements made hereinbefore in connection with the device according to the invention also apply accordingly, insofar as applicable, to the process according to the invention.
- In the process according to the invention, the extracted and converted energy may be recovered to the pumping device through an energy-recovery device, as has likewise already been explained hereinbefore in connection with the device according to the invention.
- According to the invention, a device for producing pellets from a plastic melt with the hereinbefore-described features and/or a process for producing pellets from a plastic melt with the hereinbefore-described features finds application in the processing of a plastic melt with attendant substances, which attendant substances will outgas unless there is a sufficient pressure above the ambient pressure in a melt supply arrangement and/or in the process chamber. Preferably, the plastic melt with attendant substances is expanded polystyrene (EPS).
- Hereinbelow, the invention will be more fully explained on the basis of preferred illustrative embodiments with reference to the appended drawings, in which:
-
FIG. 1 shows a diagrammatic view of a system set-up with a device according to the invention; -
FIGS. 2 a to c show three different embodiments of detail A according to the invention fromFIG. 1 ; -
FIGS. 3 a and b show two different embodiments of detail B fromFIG. 1 . -
FIG. 4 shows a first embodiment of an energy converter according to the invention; -
FIG. 5 shows a second embodiment of an energy converter according to the invention; -
FIG. 6 shows a third embodiment of the energy converter according to the invention; and -
FIG. 7 shows a detail view of a chopping device according to an embodiment of the invention. -
FIG. 1 shows a diagrammatic representation of a system set-up with a device for producing pellets according to an embodiment of the invention. - By means of a plastic-melt supply arrangement, which is reproduced by detail B in
FIG. 1 , where detail B will be explained in still further detail with reference toFIG. 3 , a plastic melt that is to be pelletized is supplied to the pelletization site, namely to the chopping device identified byreference character 3 inFIG. 1 . - An embodiment of said
chopping device 3 will be explained in still further detail with reference toFIG. 7 . Having been chopped into individual granules by or in thechopping device 3, the plastic melt then finds itself in a process fluid 4 (not explicitly shown inFIG. 1 ), merely the flow direction of the process fluid being indicated by arrows, wherein the process fluid is supplied at a pressure above the ambient pressure by anupstream pumping device 5, usually a pump, to a process chamber 2 (not shown inFIG. 1 ) or to thechopping device 3. According to the invention, provided downstream of the process chamber or choppingdevice 3 is anenergy converter 6 which extracts at least some of the pressure energy from the process fluid with the therein contained granules, reducing the pressure of the process fluid with the therein contained granules and converting at least some of the extracted energy into a reusable form of energy. Theenergy converter 6 may be preferably a turbine, a flexible-tube pump with reverse energy flow direction or a gear pump with reverse energy flow direction. According to the invention, a pipe for the process fluid may, as shown inFIG. 1 , be provided with a dampingelement 15 for damping and compensating pulsations, being provided preferably with an air chamber. After pressure energy has been extracted according to the invention by theenergy converter 6 from the process fluid with the therein contained granules, the process fluid with the therein contained granules is supplied to a separator 8 in which the process fluid is separated from the granules. The granules are then delivered to astore 9 for separated pellets. The process fluid 4 is collected in acontainer 10 for process fluid and is returned to a pumping circuit, wherein, according toFIG. 1 , the suction side of thepumping device 5 is fluidically connected to thecontainer 10. There may be provided acontrol loop 14 by means of which the pressure in theprocess chamber 2 is adjustable such that said pressure is slightly above, preferably just above, the pressure at which the process fluid evaporates at the prevailing temperature and/or such that said pressure is slightly above, preferably just above, the pressure at which attendant substances contained in the plastic melt evaporate at the prevailing temperature. According to the embodiment of the invention presented inFIG. 1 , thecontrol loop 14 is so connected to theenergy converter 6 and/or optionally to an energy-recovery device 7 as to allow a corresponding closed-loop/open-loop control. Detail A inFIG. 1 identifies the energy-recovery device 7, which provides for the energy reusably converted by theenergy converter 6 according to the invention to be recovered in order to operate the device, more particularly in order to drive thepumping device 5. - Detail A will now be explained in greater detail with reference to
FIGS. 2 a to 2 c. -
FIGS. 2 a to 2 c present three different embodiments of the energy-recovery device 7 according to detail A inFIG. 1 . The energy-recovery device 7 recovers the extracted and converted energy to thepumping device 5.FIG. 2 a presents an energy-recovery device 7 with energy recovery via an electromechanical gear drive and with an inverter.FIG. 2 b presents an energy-recovery device 7 with a hydraulic gear drive.FIG. 2 c presents an energy-recovery device 7 with a mechanical gear drive. The respective drive ends of the energy-recovery devices 7 are each connected to theenergy converter 6, the output ends of the respective energy-recovery devices 7 being connected to thepumping device 5. -
FIG. 3 presents two different embodiments of a plastic-melt supply arrangement according to detail B inFIG. 1 .FIG. 3 a presents a plastic-melt supply arrangement with anextruder 11 with drive, wherein the melt is supplied via amelt pump 13 onward to thechopping device 3 inFIG. 1 .FIG. 3 b presents areactor 12 from which the melt is supplied via amelt pump 13 to thechopping device 3 fromFIG. 1 . -
FIG. 4 presents an embodiment of anenergy converter 6 according to the invention, saidenergy converter 6 being in the form of a turbine, in a perspective, partially exploded view. The process fluid 4 with the therein contained granules is supplied via a tangential inlet to the turbine. The turbine housing accommodates an impeller with impeller vanes, the process fluid with the therein contained granules being carried radially inwards and being discharged via an axial outlet in a housing cover of the turbine. As it passes through the turbine according toFIG. 4 , the process fluid 4 with the therein contained granules transmits pressure energy by momentum transfer to the impeller vanes of the impeller of the turbine, thereby driving the impeller and thus the output of the turbine, with the result that the pressure of the process fluid 4 with the therein contained granules is reduced and at least some of the extracted energy is converted according to the invention into a reusable form of energy. -
FIG. 5 presents a further preferred embodiment of anenergy converter 6 according to the invention, namely a sectional view of a gear pump. According to the invention, the gear pump has a reverse energy flow direction, i.e. it is actually not used as a pump, but, as it flows through the gear pump, the pressure of the process fluid with the therein contained granules sets said pump in motion, where said motion, i.e. the rotational motion of the corresponding gearwheels of the gear pump, is then reusable. -
FIG. 6 presents a further preferred embodiment of anenergy converter 6 according to the invention, namely a flexible-tube pump with reverse energy flow direction, which flexible-tube pump was already described hereinbefore. -
FIG. 7 presents an embodiment of achopping device 3 in a partially cut-away side elevation view. A plastic melt is supplied via a perforated plate 1 to aprocess chamber 2. Process fluid flows into the process chamber from above, indicated by an arrow inFIG. 7 , at a pressure that is above the ambient pressure. The process chamber is completely filled with process fluid 4. The process fluid 4 with the therein contained granules is discharged from theprocess chamber 2 via an outlet. The flow direction of the process fluid is presented by arrows inFIG. 7 . Thechopping device 3 further has a cutter head which is connected by a shaft to an electric motor, whereby the strands of the plastic melt extruded into theprocess chamber 2 are chopped into individual granules. - The device according to the invention, the process according to the invention and the corresponding application according to the invention provide a simple and cost-effective means of safely guaranteeing the reliable production of pellets under all operating conditions.
Claims (20)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006022555 | 2006-05-15 | ||
| DE102006022555A DE102006022555B4 (en) | 2006-05-15 | 2006-05-15 | Device and method for producing a granulate from a plastic melt |
| DE102006022555.4 | 2006-05-15 | ||
| PCT/EP2007/003780 WO2007131613A1 (en) | 2006-05-15 | 2007-04-27 | Device and method for producing granules from a polymer melt |
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| US20090091054A1 true US20090091054A1 (en) | 2009-04-09 |
| US7874823B2 US7874823B2 (en) | 2011-01-25 |
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| US12/227,229 Expired - Fee Related US7874823B2 (en) | 2006-05-15 | 2007-04-27 | Device and process for producing pellets from a plastic melt |
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| US (1) | US7874823B2 (en) |
| EP (1) | EP2018256B1 (en) |
| JP (1) | JP4963320B2 (en) |
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| RU (1) | RU2433040C2 (en) |
| TW (1) | TWI374081B (en) |
| WO (1) | WO2007131613A1 (en) |
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| JP4473856B2 (en) * | 2004-03-31 | 2010-06-02 | 長春石油化學股▲分▼有限公司 | Method for producing ethylene-vinyl alcohol copolymer pellets |
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2006
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- 2007-03-05 TW TW096107512A patent/TWI374081B/en active
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- 2007-04-27 WO PCT/EP2007/003780 patent/WO2007131613A1/en not_active Ceased
- 2007-04-27 KR KR1020087027729A patent/KR101325285B1/en active Active
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- 2007-04-27 EP EP07724707A patent/EP2018256B1/en active Active
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- 2007-04-27 DE DE502007004933T patent/DE502007004933D1/en active Active
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090108480A1 (en) * | 2006-03-22 | 2009-04-30 | Basf Se | Method and device for granulating polymer melts containing blowing agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011092250A1 (en) | 2010-01-28 | 2011-08-04 | Total Petrochemicals Research Feluy | Method to start-up a process to make expandable vinyl aromatic polymers |
| EP2353832A1 (en) | 2010-01-28 | 2011-08-10 | Total Petrochemicals Research Feluy | Method to start-up a process to make expandable vinyl aromatic polymers |
| US8801982B2 (en) | 2010-01-28 | 2014-08-12 | Total Research & Technology Feluy | Method to start-up a process to make expandable vinyl aromatic polymers |
Also Published As
| Publication number | Publication date |
|---|---|
| US7874823B2 (en) | 2011-01-25 |
| BRPI0711826A2 (en) | 2012-01-17 |
| BRPI0711826B1 (en) | 2018-06-26 |
| EP2018256A1 (en) | 2009-01-28 |
| EP2018256B1 (en) | 2010-09-01 |
| DE102006022555A1 (en) | 2007-11-22 |
| CN101448615A (en) | 2009-06-03 |
| WO2007131613A1 (en) | 2007-11-22 |
| CN101448615B (en) | 2012-08-29 |
| JP4963320B2 (en) | 2012-06-27 |
| RU2433040C2 (en) | 2011-11-10 |
| JP2009537345A (en) | 2009-10-29 |
| KR101325285B1 (en) | 2013-11-01 |
| RU2008141355A (en) | 2010-06-20 |
| DE502007004933D1 (en) | 2010-10-14 |
| TW200744812A (en) | 2007-12-16 |
| KR20090010054A (en) | 2009-01-28 |
| DE102006022555B4 (en) | 2010-12-16 |
| TWI374081B (en) | 2012-10-11 |
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