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US20090020245A1 - Security paper or special paper incorporating high resistance synthetic elements and a procedure for obtaining said papers - Google Patents

Security paper or special paper incorporating high resistance synthetic elements and a procedure for obtaining said papers Download PDF

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Publication number
US20090020245A1
US20090020245A1 US11/911,080 US91108005A US2009020245A1 US 20090020245 A1 US20090020245 A1 US 20090020245A1 US 91108005 A US91108005 A US 91108005A US 2009020245 A1 US2009020245 A1 US 2009020245A1
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Prior art keywords
paper
security
elements
synthetic elements
synthetic
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US11/911,080
Inventor
Vicente Garcia Juez
Javier Baraja Carracedo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fabrica Nacional de Moneda y Timbre
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Fabrica Nacional de Moneda y Timbre
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Application filed by Fabrica Nacional de Moneda y Timbre filed Critical Fabrica Nacional de Moneda y Timbre
Assigned to FABRICA NACIONAL DE MONEDA Y TIMBRE -REAL CASA DE LA MONEDA reassignment FABRICA NACIONAL DE MONEDA Y TIMBRE -REAL CASA DE LA MONEDA ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CARRACEDO, JAVIER BARAJA, JUEZ, VICENTE GARCIA
Publication of US20090020245A1 publication Critical patent/US20090020245A1/en
Abandoned legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper

Definitions

  • the object of the present invention refers to a security or special paper that incorporates high resistance synthetic elements (fibres, microspheres, . . . ), as well as a security document manufactured with said support.
  • These synthetic elements incorporated in the security paper or special paper are usually provided different qualities such as been fluorescent, phosphorescent, luminescent, with magnetic characteristics, etc, characteristics that are visible to the naked eye all that can be observed under certain conditions, such as under ultraviolet light, magnetic sensors, etc
  • the synthetic elements incorporated by the security paper or special paper proposed by the invention provide that such characteristics conferred to these elements are embedded within them, such that the loss of properties inherent to these elements becomes more difficult as time goes by, resisting the harsh conditions that security and special documents are subject to, such as bank notes or the like.
  • the fibre manufacturing procedure is generally performed by obtaining extremely fine filaments in an extrusion line that are cut to a certain length.
  • Certain pigments are added to this type of elements to confer them the desired characteristics of fluorescence, phosphorescence, luminescence, magnetism etc, these pigments being applied after manufacturing said fibres, such said fibres are superficially impregnated.
  • the pigments usually used can basically be of two types, inorganic-based pigments are the main characteristic of which is offering good resistance to preserve the fluorescent, phosphorescent, luminescent, magnetic, and other properties, although in contrast they offer deficient response intensity.
  • the second type of pigments that can be used organic-based pigments and have bad resistance, the effects lasting little, but however, offering good response intensity.
  • the synthetic element impregnation procedure provides introducing these inside pressure tanks, until they are totally dyed by the pigments.
  • a security paper or special paper which, based on the previously mentioned technology, internally incorporates synthetic elements that are provided with pigments, either fluorescent, phosphorescent, luminescent, magnetic, etc., that confer them security features, that such pigments are highly resistant to the detachment of their own synthetic elements and that they can be easily integrated in the manufacturing process of a security paper or special paper used to manufacture security documents or special documents such as banknotes, bills of exchange, security labels, etc.
  • the object of the invention is an improved procedure for incorporating said synthetic elements in the paper forming process, preventing their caking and therefore favouring their dispersion and integration in the paper paste.
  • the pigment introduced in the paste for forming the synthetic element will be protected by the material of the element itself, preventing wear by friction and being protected from attacks from physical and chemical agents that the security document may suffer and from light, so that the features incorporated in the pigments are kept unchanged with time.
  • the material of these synthetic elements that allows integrating the pigments in the paste without their deterioration in is not viscous or polyamide but polypropylene, and has the difficulty of being a material without hydrogen free radicals and is therefore a product that is not related to the water surrounding it, that is, it is not impregnated in the water of the aqueous solution it is in, producing caking of the synthetic elements and therefore not providing a homogeneous dispersion thereof in the water.
  • aqueous solution has been achieved in which the synthetic elements are dispersed without caking, with the addition of dispersing and/or penetrating and/or antifoaming agents in the appropriate proportion. This allows them to be incorporated in the aqueous paper forming solution, achieving the homogenous dispersion of such synthetic elements inside the paste of the paper that is being formed, preventing the caking of the synthetic elements.
  • a procedure for incorporating the synthetic elements with this material is to achieve a dispersion of water and synthetic elements that is continuously stirred. Dispersing agents and/or penetrating agents and/or antifoaming agents are added to this dispersion in appropriate proportions, thus preventing the caking of the synthetic elements.
  • the dispersion is prepared in several loading and homogenising deposits prior to it being pumped to the paper production circuit in the machine.
  • FIG. 1 shows an enlarged section of paper incorporating this type of synthetic elements in its paste, such as that shown in the invention.
  • FIG. 2 equally represents an enlarged section of the paper incorporating the synthetic elements of the invention in strips.
  • FIG. 3 represents a schematic diagram of the tanks for preparing the aqueous solution of synthetic elements before being introduced in the paper manufacturing machine.
  • FIG. 1 shows an embodiment of a security paper or special paper ( 3 ) with the synthetic elements integrated in its paste, in this case in the shape of fibres ( 1 ) of the invention, in the same manner as in a traditional embodiment of the state-of-the-art, achieving that, despite these fibres being made in polypropylene, which does not present affinity towards water, such fibres are not caked or superficially retained on the paper itself, but randomly distributed inside the paper formed.
  • FIG. 2 is a variant of the embodiment of a security paper or special paper ( 3 ) wherein the synthetic elements of the invention, in this case again in the form of fibres ( 1 ), can be integrated in strips ( 4 ) by means of controlled insertion techniques for inserting such fibres inside the paper during their manufacture, controlling the depth at which said fibre strips are introduced, so that they remained superficially or embedded inside the paper thus formed.
  • FIG. 3 represents a schematic diagram for the procedure of preparing an aqueous solution of the synthetic elements, wherein these are initially conditioned inside an aqueous dispersion in a tank ( 5 ), wherein an amount of dispersing and/or penetrating and/or antifoaming agents is conditioned in an adequate amount, as well as the synthetic elements and the aqueous base for the suspension thereof, said suspension being stirred.
  • the dispersion thus prepared then goes through a homogenising step ( 6 ) and is then dosed by means of appropriate pumps ( 7 ) towards the entry in the paper manufacturing machine ( 8 ) for said synthetic elements to be integrated en masse or in a controlled manner.
  • POLISAL® is an aqueous solution of a yellowish sodium polyacrylate with an approximate density of 1.3 gr/cm3, which is a very active product for dispersion and refinement of the pigments used in the paper industry, especially for coating pigments.
  • the dispersing agent AMP-90® is an aqueous solution of 2-amino-2-methyl-1-propanol.
  • This disposing agent is colourless, with a relatively low viscosity and remains liquid at pretty low temperatures, such as ⁇ 37° C., which allows easy and adequate handling in industrial plants.
  • This product is a very efficient dispersing agent for pigments in plastic paints and, as a fatty acid salt, emulsifier in non-mixing water-liquid systems. It also provides pH stability, low odour and anticorrosive properties, and would even increase the acceptance of universal colorants.
  • This product's density is of 0.949 gr/cm3 at 25° C.
  • NOPCOWET LO® which is a synergic mixture of surface-active humectants and detergents such as Alkyl phosphate and potassium salt, which in the alkaline bleaching process facilitate the uniform impregnation of bleach in the entire paste to be treated, facilitating the elimination of waxy compounds coating the fibres. Due to its detergent effect it carries away the dirt on the fibres
  • AFRANIL MG® by BASF, which is a mixture of aliphatic hydroxide compounds in an aqueous emulsion. It has a density of approximately 0.960 gr/cm3 and a pH of approximately 9. This product has a good deaeration effect for the mixtures it is inserted into, with the advantage that water-repellent impurities do not accumulate, that is, it has a dispersing effect.
  • Security paper manufacturing tests have been performed, in which the synthetic elements of the invention have been inserted en masse in the form of fibres with a fluorescent feature, comparing it with the security paper with viscous or polyamide fibres as performed in the known state of the art.
  • These security papers have been subjected to several tests in order to verify the stability of the fluorescence characteristics of the fibres with spectacular results. These tests are basically of three types: the first are subjecting these security papers to acids, the second subjecting them to the action of detergents and the third subjecting them to extreme heat and light situations.
  • the differences may vary according to pigment colour or the type of response expected but always with an improvement upon the current state of the art.

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  • Paper (AREA)

Abstract

It consists in performing a security paper or special paper incorporating pigments within the paste of the synthetic element itself during its manufacture, providing pigment properties to said synthetic element, the pigments being protected from the attack of physical and chemical agents by the synthetic element itself.

Description

    OBJECT OF THE INVENTION
  • The object of the present invention refers to a security or special paper that incorporates high resistance synthetic elements (fibres, microspheres, . . . ), as well as a security document manufactured with said support.
  • These synthetic elements incorporated in the security paper or special paper are usually provided different qualities such as been fluorescent, phosphorescent, luminescent, with magnetic characteristics, etc, characteristics that are visible to the naked eye all that can be observed under certain conditions, such as under ultraviolet light, magnetic sensors, etc
  • The synthetic elements incorporated by the security paper or special paper proposed by the invention provide that such characteristics conferred to these elements are embedded within them, such that the loss of properties inherent to these elements becomes more difficult as time goes by, resisting the harsh conditions that security and special documents are subject to, such as bank notes or the like.
    • BACKGROUND OF THE INVENTION
  • The use of security documents incorporating fluorescent fibres and other synthetic elements with different verification and detection responses that are introduced during the paper manufacturing process such that some elements are embedded within the paper as it is formed is known in the state of the art.
  • These elements, in the case of the fibre is, for example, are generally manufactured in viscous or polyamide, substances that are related to water since they have hydrogen free radicals. These are, therefore, substances that can be easily integrated in water dispersions, which are the base of the paper manufacturing process, since the fibres the paper is made of are introduced in the paper manufacturing machine as an aqueous dispersion that will form the sheet of paper as the water is extracted.
  • The fibre manufacturing procedure is generally performed by obtaining extremely fine filaments in an extrusion line that are cut to a certain length.
  • Certain pigments are added to this type of elements to confer them the desired characteristics of fluorescence, phosphorescence, luminescence, magnetism etc, these pigments being applied after manufacturing said fibres, such said fibres are superficially impregnated.
  • The pigments usually used can basically be of two types, inorganic-based pigments are the main characteristic of which is offering good resistance to preserve the fluorescent, phosphorescent, luminescent, magnetic, and other properties, although in contrast they offer deficient response intensity.
  • The second type of pigments that can be used organic-based pigments and have bad resistance, the effects lasting little, but however, offering good response intensity.
  • The synthetic element impregnation procedure provides introducing these inside pressure tanks, until they are totally dyed by the pigments.
  • These elements, in order to be incorporated into the paper manufacturing process, are prepared in the form of a water suspension provided to the paper manufacturing process, thus being embedded inside the paper at different depths that are randomly arranged.
  • It has been demonstrated that superficially arranged pigments lose their features prematurely since light deteriorates their properties very easily, since there are only protected by the possible fibres in the paper. Moreover, since these pigments remain on the surface they can easily deteriorate by friction or the use given to the security paper they are on.
  • It has thus been demonstrated that security papers integrating elements with fluorescence, phosphorescence, luminescence, and other features lose such qualities with use, making these authentication and recognition measures practically useless for such security documents.
    • DESCRIPTION OF THE INVENTION
  • It is the object of the invention to obtain a security paper or special paper which, based on the previously mentioned technology, internally incorporates synthetic elements that are provided with pigments, either fluorescent, phosphorescent, luminescent, magnetic, etc., that confer them security features, that such pigments are highly resistant to the detachment of their own synthetic elements and that they can be easily integrated in the manufacturing process of a security paper or special paper used to manufacture security documents or special documents such as banknotes, bills of exchange, security labels, etc.
  • It is also the object of the invention to achieve the security or special document, either a banknote, bill of exchange, security label, etc that has as a substrate this security paper or special paper integrating synthetic elements with the qualities of being highly resistant to wear factors of the document itself without their characteristics being altered.
  • Also the object of the invention is an improved procedure for incorporating said synthetic elements in the paper forming process, preventing their caking and therefore favouring their dispersion and integration in the paper paste.
  • In order to carry out the object of the invention we propose using synthetic elements with the pigments or products to be conferred singular characteristics, inside the material of the element itself. The material of the element itself will protect said pigment or product provided to the fibre and conferring it the appropriate security characteristics.
  • The pigment introduced in the paste for forming the synthetic element will be protected by the material of the element itself, preventing wear by friction and being protected from attacks from physical and chemical agents that the security document may suffer and from light, so that the features incorporated in the pigments are kept unchanged with time.
  • The material of these synthetic elements that allows integrating the pigments in the paste without their deterioration in is not viscous or polyamide but polypropylene, and has the difficulty of being a material without hydrogen free radicals and is therefore a product that is not related to the water surrounding it, that is, it is not impregnated in the water of the aqueous solution it is in, producing caking of the synthetic elements and therefore not providing a homogeneous dispersion thereof in the water.
  • An aqueous solution has been achieved in which the synthetic elements are dispersed without caking, with the addition of dispersing and/or penetrating and/or antifoaming agents in the appropriate proportion. This allows them to be incorporated in the aqueous paper forming solution, achieving the homogenous dispersion of such synthetic elements inside the paste of the paper that is being formed, preventing the caking of the synthetic elements.
  • This homogeneous incorporation of the synthetic elements in the paper forming paste alarms though to be distributed inside the paper, which is compared to the effect is achieved with the viscous or polyamide fibres but with a material that does not present affinity towards water.
  • A procedure for incorporating the synthetic elements with this material is to achieve a dispersion of water and synthetic elements that is continuously stirred. Dispersing agents and/or penetrating agents and/or antifoaming agents are added to this dispersion in appropriate proportions, thus preventing the caking of the synthetic elements. The dispersion is prepared in several loading and homogenising deposits prior to it being pumped to the paper production circuit in the machine.
  • Incorporation of these synthetic elements can be performed randomly in the entire paste of the paper being formed or it can be performed in a localised manner at specific points of the paper paste, thus obtaining longitudinal strips of synthetic elements located at different levels on the thickness of the paper with such elements, which increases the degree of security of the final document thus obtained.
    • DESCRIPTION OF THE DRAWINGS
  • In order to complete the description being made and to aid towards a better comprehension of the features of the invention, according to our preferred practical embodiment thereof, we incorporate as an integral part of said description a set of drawings that are illustrative and not limiting in nature, and represent the following:
  • FIG. 1 shows an enlarged section of paper incorporating this type of synthetic elements in its paste, such as that shown in the invention.
  • FIG. 2 equally represents an enlarged section of the paper incorporating the synthetic elements of the invention in strips.
  • FIG. 3 represents a schematic diagram of the tanks for preparing the aqueous solution of synthetic elements before being introduced in the paper manufacturing machine.
    •  DETAILED DESCRIPTION OF THE DRAWINGS
  • FIG. 1 shows an embodiment of a security paper or special paper (3) with the synthetic elements integrated in its paste, in this case in the shape of fibres (1) of the invention, in the same manner as in a traditional embodiment of the state-of-the-art, achieving that, despite these fibres being made in polypropylene, which does not present affinity towards water, such fibres are not caked or superficially retained on the paper itself, but randomly distributed inside the paper formed.
  • FIG. 2 is a variant of the embodiment of a security paper or special paper (3) wherein the synthetic elements of the invention, in this case again in the form of fibres (1), can be integrated in strips (4) by means of controlled insertion techniques for inserting such fibres inside the paper during their manufacture, controlling the depth at which said fibre strips are introduced, so that they remained superficially or embedded inside the paper thus formed.
  • FIG. 3 represents a schematic diagram for the procedure of preparing an aqueous solution of the synthetic elements, wherein these are initially conditioned inside an aqueous dispersion in a tank (5), wherein an amount of dispersing and/or penetrating and/or antifoaming agents is conditioned in an adequate amount, as well as the synthetic elements and the aqueous base for the suspension thereof, said suspension being stirred.
  • The dispersion thus prepared then goes through a homogenising step (6) and is then dosed by means of appropriate pumps (7) towards the entry in the paper manufacturing machine (8) for said synthetic elements to be integrated en masse or in a controlled manner.
    • PRACTICAL EMBODIMENT OF THE INVENTION
  • Examples of dispersing products would be POLISAL® by BASF or AMP-90® by ANGUS. POLISAL® is an aqueous solution of a yellowish sodium polyacrylate with an approximate density of 1.3 gr/cm3, which is a very active product for dispersion and refinement of the pigments used in the paper industry, especially for coating pigments.
  • The dispersing agent AMP-90® is an aqueous solution of 2-amino-2-methyl-1-propanol. This disposing agent is colourless, with a relatively low viscosity and remains liquid at pretty low temperatures, such as −37° C., which allows easy and adequate handling in industrial plants. This product is a very efficient dispersing agent for pigments in plastic paints and, as a fatty acid salt, emulsifier in non-mixing water-liquid systems. It also provides pH stability, low odour and anticorrosive properties, and would even increase the acceptance of universal colorants. This product's density is of 0.949 gr/cm3 at 25° C.
  • As a penetrating product we can mention NOPCOWET LO®, which is a synergic mixture of surface-active humectants and detergents such as Alkyl phosphate and potassium salt, which in the alkaline bleaching process facilitate the uniform impregnation of bleach in the entire paste to be treated, facilitating the elimination of waxy compounds coating the fibres. Due to its detergent effect it carries away the dirt on the fibres
  • As an antifoaming product we can mention AFRANIL MG® (by BASF, which is a mixture of aliphatic hydroxide compounds in an aqueous emulsion. It has a density of approximately 0.960 gr/cm3 and a pH of approximately 9. This product has a good deaeration effect for the mixtures it is inserted into, with the advantage that water-repellent impurities do not accumulate, that is, it has a dispersing effect.
  • Security paper manufacturing tests have been performed, in which the synthetic elements of the invention have been inserted en masse in the form of fibres with a fluorescent feature, comparing it with the security paper with viscous or polyamide fibres as performed in the known state of the art. These security papers have been subjected to several tests in order to verify the stability of the fluorescence characteristics of the fibres with spectacular results. These tests are basically of three types: the first are subjecting these security papers to acids, the second subjecting them to the action of detergents and the third subjecting them to extreme heat and light situations.
  • As an example we enclose a comparative table of fibres with fluorescent response.
  • Test Performed with Fluorescent Fibres
  • The results are clearly in favour of the paper of invention.
  • % OF FLUORESCENCE REMAINING
    Security paper
    according to the Security paper of
    state of the art the invention
    Acetic acid 45-93 79-100
    Hydrochloric acid  7-92 94-100
    Sulphuricacid 11-100 96-100
    Soapy solution at 95°  7-87 95-100
    Synthetic sweat 94 94-100
    Heat 82-90 85-100
    Light  3-25 25-96
  • The differences may vary according to pigment colour or the type of response expected but always with an improvement upon the current state of the art.

Claims (9)

1. A paper incorporating synthetic elements that are provided with characteristics visible to the naked eye or under certain conditions or “ad hoc” detectors, wherein it comprises security pigments included in the paste of the synthetic element itself, which is polypropylene, and has a low melting point, below the degradation point of the pigments.
2. The procedure for manufacturing paper incorporating high resistance synthetic elements provided with characteristics that are visible to the naked eye or under certain conditions, such as defined in claim 1, wherein the synthetic elements are prepared prior to their introduction in the paper manufacturing procedure by means of an aqueous dispersion thereof in the presence of dispersing or penetrating or antifoaming agents.
3. The manufacturing procedure for paper according to claim 2, wherein the dispersion of security elements is incorporated homogenously in the paper paste during its formation process.
4. The manufacturing procedure for paper according to claim 2, wherein the dispersion of security elements is incorporated to the paper paste in a controlled manner, forming strips or bands where such synthetic elements accumulate.
5. (canceled)
6. A security document manufactured by printing on a paper as described in claim 1.
7. A manufacturing procedure for paper according to claim 2, further comprising printing a security document on the paper manufactured.
8. A manufacturing procedure for paper according to claim 3, further comprising printing a security document on the paper manufactured.
9. A manufacturing procedure for paper according to claim 4, further comprising printing a security document on the paper manufactured.
US11/911,080 2005-04-06 2005-04-06 Security paper or special paper incorporating high resistance synthetic elements and a procedure for obtaining said papers Abandoned US20090020245A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/ES2005/000179 WO2006108886A2 (en) 2005-04-06 2005-04-06 Security paper or special paper comprising high-strength synthetic elements, and method for making same

Publications (1)

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US20090020245A1 true US20090020245A1 (en) 2009-01-22

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US11/911,080 Abandoned US20090020245A1 (en) 2005-04-06 2005-04-06 Security paper or special paper incorporating high resistance synthetic elements and a procedure for obtaining said papers

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EP (1) EP1887132B1 (en)
BR (1) BRPI0520336B1 (en)
CA (1) CA2603937A1 (en)
EG (1) EG26465A (en)
PL (1) PL1887132T3 (en)
PT (1) PT1887132T (en)
WO (1) WO2006108886A2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150159054A1 (en) * 2013-12-10 2015-06-11 Martha Patricia WILD Label with adhesive and silicone-free release coating
US20170128340A1 (en) * 2010-06-23 2017-05-11 Colgate-Palmolive Company Therapeutic oral composition
US20170135922A1 (en) * 2015-11-13 2017-05-18 The Procter & Gamble Company Dentifrice Compositions With Improved Fluoride Uptake
US10366633B2 (en) 2013-12-10 2019-07-30 Iconex Llc Adhesive label with water-based release coating
US10510270B2 (en) 2013-12-10 2019-12-17 Iconex Llc Label with adhesive and silicone-free release coating

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3880706A (en) * 1970-11-16 1975-04-29 Harold Malcolm Gordon Williams Security paper containing fused thermoplastic material distributed in a regular pattern
US4552617A (en) * 1984-06-13 1985-11-12 Crane & Co. Security features in paper
US4756557A (en) * 1984-12-21 1988-07-12 G.A.O. Gesellschaft Fuer Automation Und Organisation Mbh Security document having a security thread embedded therein and methods for producing and testing the authenticity of the security document
US5989389A (en) * 1992-11-11 1999-11-23 Ab Tumba Bruk Method of producing visible, continuous streaks and/or delimited fields in paper
US20020025418A1 (en) * 2000-07-11 2002-02-28 Yoshimi Ishibashi Antifalsification recording paper and paper support therefor
US20020112833A1 (en) * 2001-02-19 2002-08-22 Luciano Beghello Security paper
US6828678B1 (en) * 2002-03-29 2004-12-07 Silicon Magnetic Systems Semiconductor topography with a fill material arranged within a plurality of valleys associated with the surface roughness of the metal layer
US20070090196A1 (en) * 2004-02-11 2007-04-26 Arjowiggins Security Relatively small security elements, production method thereof, sheet and security document comprising same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1390100A (en) * 1972-08-21 1975-04-09 Ici Ltd Process for making particulate intimate mixtures of thermo plastics and additives

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3880706A (en) * 1970-11-16 1975-04-29 Harold Malcolm Gordon Williams Security paper containing fused thermoplastic material distributed in a regular pattern
US4552617A (en) * 1984-06-13 1985-11-12 Crane & Co. Security features in paper
US4756557A (en) * 1984-12-21 1988-07-12 G.A.O. Gesellschaft Fuer Automation Und Organisation Mbh Security document having a security thread embedded therein and methods for producing and testing the authenticity of the security document
US5989389A (en) * 1992-11-11 1999-11-23 Ab Tumba Bruk Method of producing visible, continuous streaks and/or delimited fields in paper
US20020025418A1 (en) * 2000-07-11 2002-02-28 Yoshimi Ishibashi Antifalsification recording paper and paper support therefor
US20020112833A1 (en) * 2001-02-19 2002-08-22 Luciano Beghello Security paper
US6828678B1 (en) * 2002-03-29 2004-12-07 Silicon Magnetic Systems Semiconductor topography with a fill material arranged within a plurality of valleys associated with the surface roughness of the metal layer
US20070090196A1 (en) * 2004-02-11 2007-04-26 Arjowiggins Security Relatively small security elements, production method thereof, sheet and security document comprising same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170128340A1 (en) * 2010-06-23 2017-05-11 Colgate-Palmolive Company Therapeutic oral composition
US20150159054A1 (en) * 2013-12-10 2015-06-11 Martha Patricia WILD Label with adhesive and silicone-free release coating
US10366633B2 (en) 2013-12-10 2019-07-30 Iconex Llc Adhesive label with water-based release coating
US10510270B2 (en) 2013-12-10 2019-12-17 Iconex Llc Label with adhesive and silicone-free release coating
US10550293B2 (en) * 2013-12-10 2020-02-04 Iconex Llc Label with adhesive and silicone-free release coating
US10920114B2 (en) 2013-12-10 2021-02-16 Iconex Llc Label with adhesive and silicone-free release coating
US11450240B2 (en) 2013-12-10 2022-09-20 Iconex Llc Adhesive label with water-based release coating
US20170135922A1 (en) * 2015-11-13 2017-05-18 The Procter & Gamble Company Dentifrice Compositions With Improved Fluoride Uptake

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BRPI0520336B1 (en) 2017-10-17
BRPI0520336A2 (en) 2009-05-05
CA2603937A1 (en) 2006-10-19
PL1887132T3 (en) 2019-01-31
EP1887132B1 (en) 2018-08-08
WO2006108886A2 (en) 2006-10-19
EG26465A (en) 2013-11-14
EP1887132A2 (en) 2008-02-13
PT1887132T (en) 2018-10-19
WO2006108886A3 (en) 2008-07-03

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