US20080317977A1 - Light-regulation membrane - Google Patents
Light-regulation membrane Download PDFInfo
- Publication number
- US20080317977A1 US20080317977A1 US12/134,192 US13419208A US2008317977A1 US 20080317977 A1 US20080317977 A1 US 20080317977A1 US 13419208 A US13419208 A US 13419208A US 2008317977 A1 US2008317977 A1 US 2008317977A1
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- United States
- Prior art keywords
- light
- layer
- regulation membrane
- liquid crystal
- hard coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000012528 membrane Substances 0.000 title claims abstract description 58
- 239000010410 layer Substances 0.000 claims abstract description 117
- 239000004983 Polymer Dispersed Liquid Crystal Substances 0.000 claims abstract description 38
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000011247 coating layer Substances 0.000 claims abstract description 23
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 13
- 230000003667 anti-reflective effect Effects 0.000 claims abstract description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 21
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 21
- -1 polyethylene terephthalate Polymers 0.000 claims description 19
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 12
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 12
- 230000003471 anti-radiation Effects 0.000 claims description 11
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 10
- 239000004417 polycarbonate Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 230000001681 protective effect Effects 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 6
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000012748 slip agent Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000008119 colloidal silica Substances 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002318 adhesion promoter Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000012745 toughening agent Substances 0.000 claims description 3
- 239000004988 Nematic liquid crystal Substances 0.000 claims description 2
- 239000003431 cross linking reagent Substances 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 230000000903 blocking effect Effects 0.000 claims 1
- 238000002834 transmittance Methods 0.000 abstract description 6
- 230000001105 regulatory effect Effects 0.000 abstract description 4
- 230000004313 glare Effects 0.000 abstract description 2
- 239000011521 glass Substances 0.000 description 34
- 238000009413 insulation Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 230000005855 radiation Effects 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 5
- 238000009434 installation Methods 0.000 description 5
- 238000005192 partition Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000237502 Ostreidae Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/54—Additives having no specific mesophase characterised by their chemical composition
- C09K19/542—Macromolecular compounds
- C09K19/544—Macromolecular compounds as dispersing or encapsulating medium around the liquid crystal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1334—Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
- C09K2323/021—Inorganic, e.g. glass or silicon oxide
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133504—Diffusing, scattering, diffracting elements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
- G02F2201/50—Protective arrangements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/28—Adhesive materials or arrangements
Definitions
- the present invention relates to light regulation technology and more specifically, to a light-regulation membrane that utilizes two polymer compound layers to support a PDLC (polymer dispersed liquid crystal) film for regulating light and an adhesion layer for repetitively adhering on light transmissible plate e.g. transparent glass panel or the like.
- PDLC polymer dispersed liquid crystal
- a blind, Low-emissive glass or heat insulation film may be installed.
- the color of the heat insulation film produces a certain extent of light-blocking effect.
- a regular heat insulation film simply reduces the extent of the glare of the radiation of the sun. It cannot effectively block ultraviolet light.
- the heat insulation effect of conventional heat insulation films is still not perfect.
- Conventional heat insulation films tend to be oxidized, and can easily be caused to wrinkle or to fade after a long use.
- the dark color heat insulation film can block light and isolate heat.
- a color heat insulation film prohibits light from passing through the glass panel.
- a heat insulation film is used indoors or in a car, it interferes with people's sight.
- a heat insulation film is covered on a glass panel, a person can no longer regulate the transmittance of the glass panel.
- the installation procedure is complicated.
- a window blind must be mounted on the inner side of a window, it occupies much indoor space. Further, the cleaning work of a window blind is also complicated.
- a polyvision privacy glass can transform from a cloudy white translucent barrier to an optically clear state with the flick of a switch. It is produced by laminating polymer-dispersed liquid crystal film with architectural grade PVB between two layers of glass. When the power is off, the liquid crystal molecules are randomly oriented so that incident light is scattered and the polyvision privacy glass is opaque. With electricity applied, the liquid crystal molecules line up, the incident light passes through, and polyvision privacy glass looks clear.
- a polyvision privacy glass can change its transmissible status subject to the application of electric current, its installation is complicated, and the original indoor design may have to be destructed. Further, a polyvision privacy glass tends to be covered with dust and must be regularly cleaned. For protection against ultraviolet light and isolation of heat, an extra surface treatment is necessary. Therefore, a polyvision privacy glass has the drawbacks of complicated structure, expensive cost, complicated maintenance and cleaning works.
- a glass panel made by laminating PET (polyethylene terephthalate) on two opposite sides of a PDLC (polymer dispersed liquid crystal) film has the advantages of lightweight, impact resistance, high transmittance and high machinability. It is practical for many applications. However, PET will decompose and become aged soon when exposed to the radiation of the sun. Further, the surface of this kind of glass panel tends to be scratched, or damaged by a solvent.
- the light-regulation membrane comprises a surface structure, an adhesion layer for adhering on light transmissible plate, two polymer compound layers sandwiched between the hard coating layer of the surface structure and the adhesion layer, and a PDLC (polymer dispersed liquid crystal) film sandwiched between the two polymer compound layers.
- the PDLC (polymer dispersed liquid crystal) film comprises two conducting layers, and a liquid crystal layer sandwiched between the two conducting layers.
- the adhesion layer is adhered on light transmissible plate e.g. a transparent glass or the like.
- the transmittance status of the light-regulation membrane is controlled while the PDLC (polymer dispersed liquid crystal) film is connected the electric power source, and then light passing through the transmissible plate is controlled and regulated. On the contrary, when electricity is disconnected from the PDLC (polymer dispersed liquid crystal) film, light is quickly blocked by the light-regulation membrane.
- the adhesion layer is prepared from a silicone/acrylic based pressure sensitive adhesive composition, and can be directly adhered on light transmissible plate such as transparent glass, PMMA (polymethyl methacrylate) and PC (polycarbonate) panels.
- light transmissible plate such as transparent glass, PMMA (polymethyl methacrylate) and PC (polycarbonate) panels.
- the surface structure comprises an anti-stain layer prepared from thermosetting organosiloxane resin which comprises of colloidal silica and hydrolysis-condensation trialkoxysilane, a hard coating layer, and an anti-reflective layer sandwiched between the anti-stain layer and the hard coating layer.
- the anti-stain layer facilitates the cleaning work.
- the hard coating layer protects the transparent glass against cracking, having wear-resisting and solvent-resisting characteristic.
- the polymer compound layers are prepared from a plastic chemical material, for example, PET (polyethylene terephthalate), PMMA (polymethyl methacrylate) that support the PDLC (polymer dispersed liquid crystal) film without affecting its functioning.
- a plastic chemical material for example, PET (polyethylene terephthalate), PMMA (polymethyl methacrylate) that support the PDLC (polymer dispersed liquid crystal) film without affecting its functioning.
- PET polyethylene terephthalate
- PMMA polymethyl methacrylate
- the light-regulation membrane is applicable to glass curtain wall, vehicle sliding sunroof, indoor partition wall, etc.
- the glass to which the light-regulation membrane is adhered can be used as a rear projection screen.
- the light-regulation membrane provides an excellent support effect and an added function, having excellent applicability.
- the light-regulation membrane further comprises an anti-radiation layer, having anti-ultraviolet and anti-infrared characteristics.
- the anti-radiation layer can be made in any of a variety of colors.
- the anti-radiation layer also blocks infrared light rays from the radiation of the sun, producing a heat isolation effect to keep the indoor space warm in winter or cool in summer and saving much power consumption. Therefore, the invention is an environmentally friendly design.
- FIG. 1 illustrates the outer appearance of a light-regulation membrane according to the present invention.
- FIG. 2 is a three-dimension cross-sectional drawing of the light-regulation membrane according to the present invention.
- FIG. 3 is a sided-view cross-sectional drawing of the light-regulation membrane according to the present invention.
- FIG. 4 is an illustration drawing showing one of applications of the present invention.
- a light-regulation membrane in accordance with the present invention comprising a PDLC (polymer dispersed liquid crystal) film 1 , two polymer compound layers 2 , a plurality of PSA (pressure sensitive adhesive) layers 3 , a surface structure 4 , an anti-radiation layer 5 , an adhesion layer 6 , and two protective films 7 .
- PDLC polymer dispersed liquid crystal
- PSA pressure sensitive adhesive
- the PDLC film 1 comprises a liquid crystal layer 11 and two conducting layers 12 .
- the liquid crystal layer 11 is sandwiched between the two conducting layers 12 .
- the liquid crystal layer 11 can be prepared from a compound of hydroxyl polyfunctional (meth) acrylates and nematic liquid crystal cured with a polyisocyanate compound crosslinking agent.
- the conducting layers 12 are made by means of depositing ITO (indium tin oxide) on a base layer of PET (polyethylene terephthalate by means of spattering deposition.
- the polymer compound layers 2 are respectively formed on the two conducting layers 12 . Further, the polymer compound layers 2 are prepared from a plastic chemical material, for example, PET (polyethylene terephthalate), PMMA (polymethyl methacrylate), PC (polycarbonate), PP (polypropylene), PE (polyethylene) or PVDC (polyvinylidene chloride).
- PET polyethylene terephthalate
- PMMA polymethyl methacrylate
- PC polycarbonate
- PP polypropylene
- PE polyethylene
- PVDC polyvinylidene chloride
- the PSA (pressure sensitive adhesive) layers 3 as adhesion are disposed in-between the polymer compound layer 2 and the conductive layer 12 .
- the surface structure 4 is formed on the surface of one polymer compound layer 2 opposite to the PSA (pressure sensitive adhesive) layers 3 and the PDLC film 1 , comprising an anti-stain layer 41 , an anti-reflective layer 42 and a hard coating layer 43 .
- the hard coating layer 43 is bonded to the polymer compound layer 2 .
- the anti-reflective layer 42 is sandwiched between the anti-stain layer 41 and the hard coating layer 43 .
- the anti-stain layer 41 is for protection against dirt and stains, prepared from thermosetting organosiloxane resin which comprises of colloidal silica and hydrolysis-condensation trialkoxysilane.
- the anti-reflective layer 42 is sandwiched between the anti-stain layer 41 and the hard coating layer 43 .
- the hard coating layer 43 is sandwiched between the anti-reflective layer 42 and the polymer compound layer 2 .
- the hard coating layer 43 may be made of cross-linking copolymer acrylates and an ultraviolet absorbent, having a specific repeating structure unit and containing a certain amount of carbamate bond.
- the hard coating layer 43 can be a UV curable organic coating prepared from a mixture of multi-functional acrylates, silicone acrylate as a slip agent, a crosslinkage adhesion promoter, and photo-initiators, or a mixture of multi-functional acrylates, silicone acrylate as a slip agent, a (meth) acrylate terminated toughener, nano sized silica as inorganic filler, a silane coupling agent, and photo-initiators.
- the anti-radiation layer 5 is formed on one side of the other polymer compound layer 2 opposite to the surface structure 4 , having anti-ultraviolet and anti-infrared characteristics. Further, the anti-radiation layer 5 can be made in any of a variety of colors.
- the adhesion layer 6 is formed on one side of the anti-radiation layer 5 opposite to the polymer compound layer 2 for repetitively adhering to a transparent glass 9 .
- the adhesion layer 6 can be made of a mixture of organic silicone and acrylic pressure sensitive adhesive.
- the two protective films 7 are respectively covered on the adhesion layer 6 and the anti-stain layer 41 of the surface structure 4 .
- the protective films 7 are strippable films made of PET (polyethylene terephthalate). Before application of the light-regulation membrane, the two protective films 7 are respectively covered on the two opposite sides of the light-regulation membrane for surface protection.
- the protective film 7 is removed from the adhesion layer 6 , and then the adhesion layer 6 is adhered to the surface of the transparent glass 9 , and then the other protective film 7 is removed from the anti-stain layer 41 of the surface structure 4 , and then the positive and negative terminals of the power source 8 are respectively connected to the two conducting layers 12 .with silver conductive paste.
- the liquid crystal layer 11 of the PDLC film 1 When the power source 8 is switched off, the liquid crystal layer 11 of the PDLC film 1 is off, the molecules are not arranged in an order and the refractive index of the liquid crystal layer 11 is lower than the external polymers so that incident light is dispersed in the polymers of the light-regulation membrane, causing the light-regulation membrane to show the color of oyster white that does not admit light. At this time, the light-regulation membrane causes the glass 9 to show a frosted glass effect.
- the power source 8 When the power source 8 is switched on, electricity goes through the two conducting layers 12 to conduct the liquid crystal layer 11 , causing the molecules to be in the liquid arranged and/or oriented in a crystal-like way. At this time, the refractive index of the liquid crystal layer 11 is equal to the external polymers, for allowing incident light to pass. At this time, the glass 9 is seen in its original transparent status.
- the light-regulation membrane of the present invention can be adhered to any of a variety of other light transmissible plate, for example, PMMA (polymethyl methacrylate) plate or PC (polycarbonate) plate.
- the anti-radiation layer 5 can be made in any desired light transmissible color so that the light-regulation membrane shows a color effect when it is nontransmissible.
- the invention provides a light-regulation membrane that the following characteristics and advantages:
- the two conducting layers 12 of the PDLC film 1 are electrically connected to the power source 8 so that a person can switch on/off the power source 8 to change the transmittance of the light-regulation membrane so as to block light or to let light pass through the glass 9 on which the light-regulation membrane is adhered.
- the adhesion layer 6 By means of the adhesion layer 6 , the light-regulation membrane can be directly adhered to any window glass of a building without destructing the construction. Further, the adhesion layer 6 allows the light-regulation membrane for reusable application, simplifying maintenance work and saving much installation cost.
- the anti-stain layer 41 of the surface structure 4 is prepared from thermosetting organosiloxane resin which comprises of colloidal silica and hydrolysis-condensation trialkoxysilane.
- the anti-stain layer 41 of the surface structure 4 facilitates cleaning work. After the light-regulation membrane is adhered to the glass 9 , the cleaning work becomes easy. Therefore, the light-regulation membrane of the present invention is convenient and practical to use.
- the hard coating layer 43 of the surface structure 4 is made of cross-linking copolymer acrylates and ultraviolet absorbent, containing a certain amount of carbamate bond. It protects the glass 9 against cracking, having wear resisting and solvent resisting characteristics.
- the PDLC (polymer dispersed liquid crystal) film 1 is sandwiched between the polymer compound layers 2 are prepared from a plastic chemical material, for example, PET (polyethylene terephthalate), PMMA (polymethyl methacrylate), PC (polycarbonate), PP (polypropylene), PE (polyethylene) or PVDC (polyvinylidene chloride). Therefore, the polymer compound layers 2 give excellent support to the PDLC (polymer dispersed liquid crystal) film 1 without affecting the light regulation functioning of the PDLC (polymer dispersed liquid crystal) film 1 . Therefore, the light-regulation membrane is applicable to glass curtain wall, vehicle sliding sunroof, indoor partition wall, etc. When the light-regulation membrane is in the nontransmissible status, the glass 9 to which the light-regulation membrane is adhered can be used as a rear projection screen.
- a plastic chemical material for example, PET (polyethylene terephthalate), PMMA (polymethyl methacrylate), PC (polycarbonate
- the anti-radiation layer 5 has anti-ultraviolet and anti-infrared characteristics. When applied to a glass curtain wall of a building, the light-regulation membrane blocks ultraviolet from the radiation of the sun, avoiding sun radiation damage to human body skin and indoor furniture. The anti-radiation layer 5 also blocks infrared light rays from the radiation of the sun, producing a heat isolation effect to keep the indoor space warm in winter or cool in summer and saving much power consumption. Therefore, the invention is an environmentally friendly design. Further, by means of the anti-reflective layer 42 of the surface structure 4 , the light-regulation membrane has a low reflective and a high transmittance. When applied to a glass curtain wall of a building, the light-regulation membrane provides a good lighting effect, saving lighting power consumption.
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- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nonlinear Science (AREA)
- Materials Engineering (AREA)
- Mathematical Physics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
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Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/134,192 US20080317977A1 (en) | 2007-06-22 | 2008-06-06 | Light-regulation membrane |
| RU2009145217/28A RU2486554C2 (ru) | 2007-06-22 | 2008-06-20 | Светорегулирующая мембрана |
| JP2010511223A JP2010529503A (ja) | 2007-06-22 | 2008-06-20 | 調光薄膜 |
| EP08768654A EP2158517A4 (en) | 2007-06-22 | 2008-06-20 | LIGHT REGULATION MEMBRANE |
| PCT/US2008/007683 WO2009002446A1 (en) | 2007-06-22 | 2008-06-20 | Light-regulation membrane |
| KR1020097025407A KR101154172B1 (ko) | 2007-06-22 | 2008-06-20 | 광조정 멤브레인 |
| BRPI0813408-1A2A BRPI0813408A2 (pt) | 2007-06-22 | 2008-06-20 | Membrana de regulagem de luz |
| US13/168,826 US8390766B2 (en) | 2007-06-22 | 2011-06-24 | Light-regulation membrane |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/812,969 US20080316381A1 (en) | 2007-06-22 | 2007-06-22 | Light-adjusting film |
| US12/134,192 US20080317977A1 (en) | 2007-06-22 | 2008-06-06 | Light-regulation membrane |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/812,969 Continuation-In-Part US20080316381A1 (en) | 2007-06-22 | 2007-06-22 | Light-adjusting film |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/168,826 Continuation-In-Part US8390766B2 (en) | 2007-06-22 | 2011-06-24 | Light-regulation membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20080317977A1 true US20080317977A1 (en) | 2008-12-25 |
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/134,192 Abandoned US20080317977A1 (en) | 2007-06-22 | 2008-06-06 | Light-regulation membrane |
| US13/168,826 Expired - Fee Related US8390766B2 (en) | 2007-06-22 | 2011-06-24 | Light-regulation membrane |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/168,826 Expired - Fee Related US8390766B2 (en) | 2007-06-22 | 2011-06-24 | Light-regulation membrane |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US20080317977A1 (pt) |
| EP (1) | EP2158517A4 (pt) |
| JP (1) | JP2010529503A (pt) |
| KR (1) | KR101154172B1 (pt) |
| BR (1) | BRPI0813408A2 (pt) |
| RU (1) | RU2486554C2 (pt) |
| WO (1) | WO2009002446A1 (pt) |
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| US20140204294A1 (en) * | 2011-09-07 | 2014-07-24 | 3M Innovative Properties Company | Sun control window film with light control function |
| CN104335108A (zh) * | 2012-03-21 | 2015-02-04 | Q-Sys有限公司 | 使用镍基电极的聚合物分散液晶型光控体及其制备方法 |
| EP2829907A4 (en) * | 2012-03-21 | 2015-11-11 | Q Sys Co Ltd | POLYMER DISPRODUCED LIQUID CRYSTAL LIGHT CONTROL BODY WITH NICKEL BASE ELECTRODE AND METHOD OF MANUFACTURING THEREOF |
| DE112013006193B4 (de) * | 2012-12-24 | 2019-05-23 | Guardian Glass, LLC | Schaltbares Fenster mit Wärmeschutz- (low-E) Beschichtung als leitende Schicht |
| WO2016008375A1 (en) * | 2014-07-14 | 2016-01-21 | Saint-Gobain Glass France | Switchable glass structure and vehicle window cross-reference to related applications |
| CN105334658A (zh) * | 2014-07-14 | 2016-02-17 | 法国圣戈班玻璃公司 | 调光玻璃结构以及车窗 |
| EA036547B1 (ru) * | 2014-07-14 | 2020-11-20 | Сэн-Гобэн Гласс Франс | Переключаемая структура стекол и окно транспортного средства |
| US11681176B2 (en) | 2015-03-18 | 2023-06-20 | Gauzy Ltd. | Solar reflective and absorptive electrically-switchable film and glazing |
| CN105137638A (zh) * | 2015-09-29 | 2015-12-09 | 奇纬光电新材料(中国)有限公司 | 一种具有显示功能的玻璃 |
| CN105759487A (zh) * | 2016-04-27 | 2016-07-13 | 张家港康得新光电材料有限公司 | 调光膜与其制备方法 |
| US11774825B2 (en) | 2017-04-20 | 2023-10-03 | Cardinal Ig Company | High performance privacy glazing structures |
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| US10705363B2 (en) | 2017-07-13 | 2020-07-07 | Cardinal Ig Company | Electrical connection configurations for privacy glazing structures |
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| US10564536B2 (en) | 2017-09-20 | 2020-02-18 | Coretronic Corporation | Projection screen and projection system |
| US10571792B2 (en) * | 2017-09-20 | 2020-02-25 | Coretronic Corporation | Projection device and projection system |
| US11360364B2 (en) | 2017-11-06 | 2022-06-14 | Cardinal Ig Company | Privacy glazing system with discrete electrical driver |
| US11698562B2 (en) | 2017-11-06 | 2023-07-11 | Cardinal Ig Company | Privacy glazing system with discrete electrical driver |
| EP3739377A4 (en) * | 2018-01-12 | 2021-03-03 | Toppan Printing Co., Ltd. | LIGHT ADJUSTMENT SHEET AND LIGHT ADJUSTMENT DEVICE |
| US11243421B2 (en) | 2018-05-09 | 2022-02-08 | Cardinal Ig Company | Electrically controllable privacy glazing with energy recapturing driver |
| US10968684B2 (en) | 2018-08-17 | 2021-04-06 | Cardinal Ig Company | Privacy glazing structure with asymetrical pane offsets for electrical connection configurations |
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| US12164186B2 (en) | 2018-12-02 | 2024-12-10 | Cardinal Ig Company | Electrically dynamic window structure with ultralow power consumption comprising a liquid crystal material that can switch between first and second optical transition states |
| US11474385B1 (en) | 2018-12-02 | 2022-10-18 | Cardinal Ig Company | Electrically controllable privacy glazing with ultralow power consumption comprising a liquid crystal material having a light transmittance that varies in response to application of an electric field |
| US11111720B2 (en) | 2019-02-08 | 2021-09-07 | Cardinal Ig Company | Low power driver for privacy glazing |
| US11826986B2 (en) | 2019-04-29 | 2023-11-28 | Cardinal Ig Company | Leakage current detection and control for one or more electrically controllable privacy glazing structures |
| US11175523B2 (en) | 2019-04-29 | 2021-11-16 | Cardinal Ig Company | Staggered driving electrical control of a plurality of electrically controllable privacy glazing structures |
| US11681170B2 (en) | 2019-04-29 | 2023-06-20 | Cardinal Ig Company | Staggered driving electrical control of a plurality of electrically controllable privacy glazing structures |
| US11325352B2 (en) | 2019-04-29 | 2022-05-10 | Cardinal Ig Company | Leakage current detection and control for one or more electrically controllable privacy glazing structures |
| US11448910B2 (en) | 2019-04-29 | 2022-09-20 | Cardinal Ig Company | Systems and methods for operating one or more electrically controllable privacy glazing structures |
| US12296558B2 (en) | 2019-04-29 | 2025-05-13 | Cardinal Ig Company | Leakage current detection and control for one or more electrically controllable privacy glazing structures |
| US12339532B2 (en) | 2019-04-29 | 2025-06-24 | Cardinal Ig Company | Staggered driving electrical control of a plurality of electrically controllable privacy glazing structures |
| US12498598B2 (en) | 2019-04-29 | 2025-12-16 | Cardinal Ig Company | Systems and methods for operating one or more electrically controllable privacy glazing structures |
| CN111505748A (zh) * | 2020-05-27 | 2020-08-07 | 江苏日久光电股份有限公司 | 一种调光膜及其制备方法 |
| CN112099253A (zh) * | 2020-09-14 | 2020-12-18 | 衡阳市雁证不锈钢商贸有限公司 | 一种可调光式门窗玻璃 |
| CN114518673A (zh) * | 2022-02-22 | 2022-05-20 | 重庆京东方电子科技有限公司 | 一种防窥显示装置及其控制方法和制备方法 |
| CN120886540A (zh) * | 2025-09-30 | 2025-11-04 | 宁波长阳科技股份有限公司 | 一种匀光扩散膜、制备方法及应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0813408A2 (pt) | 2014-12-30 |
| KR20100029189A (ko) | 2010-03-16 |
| KR101154172B1 (ko) | 2012-06-14 |
| EP2158517A1 (en) | 2010-03-03 |
| RU2009145217A (ru) | 2011-07-27 |
| RU2486554C2 (ru) | 2013-06-27 |
| WO2009002446A1 (en) | 2008-12-31 |
| EP2158517A4 (en) | 2012-10-31 |
| JP2010529503A (ja) | 2010-08-26 |
| US20110255035A1 (en) | 2011-10-20 |
| US8390766B2 (en) | 2013-03-05 |
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