US20080105913A1 - Semiconductor Structures - Google Patents
Semiconductor Structures Download PDFInfo
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- US20080105913A1 US20080105913A1 US11/971,785 US97178508A US2008105913A1 US 20080105913 A1 US20080105913 A1 US 20080105913A1 US 97178508 A US97178508 A US 97178508A US 2008105913 A1 US2008105913 A1 US 2008105913A1
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- United States
- Prior art keywords
- electrically conductive
- trenches
- bitlines
- electrically
- insulative material
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- Abandoned
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 claims description 147
- 239000003990 capacitor Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 16
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- -1 tungsten nitride Chemical class 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 claims description 2
- 229910021342 tungsten silicide Inorganic materials 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 27
- 238000000034 method Methods 0.000 abstract description 14
- 230000015654 memory Effects 0.000 description 44
- 239000004020 conductor Substances 0.000 description 30
- 238000012545 processing Methods 0.000 description 30
- 239000000203 mixture Substances 0.000 description 22
- 239000012634 fragment Substances 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 230000002093 peripheral effect Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 125000006850 spacer group Chemical group 0.000 description 7
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
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- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000945 filler Substances 0.000 description 3
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
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- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000003491 array Methods 0.000 description 2
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- 239000002210 silicon-based material Substances 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/30—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
- H10B12/48—Data lines or contacts therefor
- H10B12/482—Bit lines
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
- H10B12/033—Making the capacitor or connections thereto the capacitor extending over the transistor
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/09—Manufacture or treatment with simultaneous manufacture of the peripheral circuit region and memory cells
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/50—Peripheral circuit region structures
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D1/00—Resistors, capacitors or inductors
- H10D1/60—Capacitors
- H10D1/68—Capacitors having no potential barriers
- H10D1/692—Electrodes
- H10D1/711—Electrodes having non-planar surfaces, e.g. formed by texturisation
- H10D1/716—Electrodes having non-planar surfaces, e.g. formed by texturisation having vertical extensions
Definitions
- the invention pertains to semiconductor structures, and to methods of forming semiconductor constructions.
- the semiconductor memory constructions are typically integrated with other circuitry on a single semiconductor chip. Such other circuitry is provided peripherally to the memory array, and can be utilized, for example, for reading of information from the memory array or writing of information to the memory array.
- Continuing goals during semiconductor chip fabrication are to increase the level of integration while maintaining, or even improving, device performance; to increase device throughput; and to reduce costs. Accordingly, it is desirable to develop improved methods for fabrication of integrated circuitry. It is also desirable to develop integrated circuitry having improved performance characteristics.
- the invention encompasses a method of forming a semiconductor construction.
- a substrate is provided to have a defined memory array region.
- the substrate comprises, within the memory array region, a plurality of storage node contacts within an insulative material.
- the storage node contacts have uppermost surfaces covered by the insulative material.
- Trenches are formed within the insulative material.
- Electrically conductive bitline material is formed to fill the trenches.
- the bitline material is patterned into a plurality of spaced bitlines. At least portions of individual bitlines are elevationally above the storage node contact uppermost surfaces.
- Insulative caps are formed within the trenches and over the bitlines. After the bitline material is formed, and before the insulative caps are formed, electrically conductive structures are formed to extend through the insulative material in locations between the bitlines. The electrically conductive structures extend to the storage node contacts.
- the invention encompasses yet another method of forming a semiconductor construction.
- a substrate is provided to have a defined memory array region.
- the substrate comprises, within the memory array region, a plurality of storage node contacts covered by an insulative material.
- Trenches are formed within the insulative material.
- the trenches have faceted upper portions. The facets slope upwardly and outwardly relative to the trenches. Uppermost and outermost faceted edges of adjacent trenches are spaced from one another by intervening regions of the insulative material.
- the trenches are filled with electrically conductive bitline material.
- the bitline material extends over the trench faceted portions but not over the intervening regions of the insulative material.
- the bitline material is utilized as an etch mask during an etch to form first openings extending through the intervening insulative material to the storage node contacts.
- a filler material is formed within the first openings. After the filler material is formed, the bitline material is recessed within the trenches to form unfilled regions of the trenches above the bitline material. Insulative caps are formed within the unfilled regions of the trenches over the bitline material. After the insulative caps are formed, at least some of the filler material is removed to form second openings extending to the storage node contacts. Electrically conductive material is formed within the second openings and electrically coupled to the storage node contacts.
- FIG. 2 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 1 .
- FIG. 4 is an expanded region of the FIG. 3 wafer fragment, with such expanded region being diagrammatically illustrated in FIG. 3 as the region “ 4 ”.
- FIG. 6 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 5 .
- FIG. 7 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 6 .
- FIG. 8 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 7 .
- FIG. 11 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 10 .
- FIG. 12 is a view of the FIG. 1 wafer fragment shown at a processing stage subsequent to that of FIG. 11 .
- FIG. 13 is a diagrammatic, cross-sectional view of the FIG. 1 wafer fragment shown at a processing stage identical to that of FIG. 6 , and is a starting point for discussion of a second embodiment aspect of the present invention.
- FIG. 16 is a view of the FIG. 13 wafer fragment shown at a processing stage subsequent to that of FIG. 15 .
- FIG. 18 is a view of the FIG. 13 wafer fragment shown at a processing stage subsequent to that of FIG. 17 .
- FIG. 19 is a view of the FIG. 13 wafer fragment shown at a processing stage subsequent to that of FIG. 18 .
- FIG. 20 is a diagrammatic view of a computer illustrating an exemplary application of the present invention.
- FIG. 22 is a high-level block diagram of an electronic system according to an exemplary aspect of the present invention.
- the invention can be considered to comprise methods in which a disposable hard mask is utilized in conjunction with a damascene process so that a self-aligned contact etch can be used during local interconnect fabrication.
- a standard damascene flow can be utilized in conjunction with incorporation of an additional etch to create a flared (i.e., faceted, prograde) top etch profile. Such creates an overhang adjacent damascene-formed trenches.
- the material creates self-aligning spacers on the overhang.
- the self-aligning spacers can then be used for self-aligned contact etches.
- conductive material can be provided within the trenches and etched back to form bitlines.
- Insulative material can then be provided over the conductive material to provide an insulative surface that can subsequently be utilized to support capacitor constructions, such as, for example, container-capacitor constructions.
- the containers can be formed with a high-margin process since the bitlines are buried beneath the insulative material prior to fabrication of the capacitors.
- Particular aspects of the invention can advantageously form self-aligning spacers, and enable the spacers to be formed simultaneously with other process steps.
- FIGS. 1-23 Particular exemplary aspects of the invention are described with reference to FIGS. 1-23 .
- Interconnects 16 can correspond to storage node contacts, and specifically can ultimately be utilized for electrically coupling capacitor storage nodes with other circuitry.
- the storage node contacts 16 are shown electrically connected to circuitry 18 .
- Such circuitry can correspond to transistor devices associated with wordlines. Specifically, the transistor devices can have source/drain regions which electrically couple with the conductive columns 16 , and which ultimately are utilized for passing bits of data to and from capacitors that are also coupled with the columns 16 .
- Electrically conductive columns 16 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of conductively-doped silicon.
- Storage node contacts 16 comprise uppermost surfaces 17 . Such uppermost surfaces are part of a planarized surface 19 that extends across storage nodes contacts 16 and insulative material 14 .
- a second insulative material 20 extends over planarized surface 19 , and accordingly extends over insulative material 14 and storage node contacts 16 .
- Insulative material 20 can be an etch stop in subsequent processing, and can comprise, consist essentially of, or consist of, for example, silicon nitride or silicon dioxide formed from tetra-ethyl-ortho-silicate (TEOS).
- TEOS tetra-ethyl-ortho-silicate
- insulative materials 14 and 20 can be together considered to be a single insulative material comprising the composition of layer 20 over the composition of layer 14 .
- storage node contacts 16 can be considered to be within the insulative material comprising combined layers 14 and 20 , and to have the uppermost surfaces covered by such insulative material.
- a third insulative material 22 is over insulative material 20 .
- Insulative material 22 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of borophosphosilicate glass (BPSG) and/or phosphosilicate glass (PSG).
- BPSG borophosphosilicate glass
- PSG phosphosilicate glass
- insulative materials 22 and 20 are of suitable composition relative to one another such that material 22 can be selectively etched relative to material 20 .
- the construction 10 is shown divided into two defined regions 4 and 6 , with a dashed line 7 diagrammatically separating such two defined regions from one another.
- the defined region 6 can correspond to a memory array region of the construction, and the region 4 can correspond to a region understood to be peripheral to the memory array region.
- DRAM circuitry is formed within the memory array region 6
- peripheral circuitry is formed within the peripheral region 4 .
- a trench 24 is formed within the peripheral region 4 to extend through insulative materials 14 and 20 , and a wider trench 26 is formed over trench 24 to extend through insulative material 22 and to stop on material 20 . Additionally, trenches 28 are formed to extend through insulative material 22 in memory array region 6 , and to stop on layer 20 . Trenches 24 , 26 and 28 can be formed utilizing standard damascene processing.
- material 22 is subjected to an etch which forms faceted upper portions 30 of trench 26 , and faceted upper portions 32 of trenches 28 .
- material 22 comprises, consists essentially of, or consists of a silicon oxide (such as, for example, BPSG) the facet etch can be accomplished utilizing the following conditions:
- any suitable chemistry can be utilized for the facet etch.
- O 2 can be utilized to facet etch a resist, and then standard oxide etch chemistry can be utilized to transfer the facets to underlying oxide.
- an argon presputter can also be utilized to accomplish the facet etch.
- FIG. 4 shows an expanded region of FIG. 3 , and is utilized to illustrate various aspects of facets of exemplary embodiments of the present invention.
- the shown trench 28 has a bottom periphery with a horizontally-extending width “W”.
- W can be, for example, at least about 50 ⁇ ; in some cases from about 50 ⁇ to about 500 ⁇ ; from about 50 ⁇ to about 1000 ⁇ ; or from about 50 ⁇ to about 500 ⁇ .
- the trench has a pair of facets 32 on opposing sides of the trench relative to one another.
- the facet on the shown left side of the trench has a horizontally-extending width “X”, and the facet on the right side of the trench has a horizontally extending width “Y”.
- Dimensions of the horizontally extending widths X and Y can be from about 10% to about 400% of the dimension of horizontally extending width “W”, and can be, for example, from about 10% to about 50% of the horizontally-extending width “W”, or in particular aspects can be from about 15% to about 25% of the horizontally-extending width “W”.
- each of the widths “X” and “Y” can be from about 50 ⁇ to about 300 ⁇ , and in particular aspects can be from about 100 ⁇ to about 300 ⁇ .
- the shown facets can be considered to extend upwardly and outwardly relative to the trench 28 with which the facets are associated.
- each of the shown facets can be considered to have a slope which extends upwardly and outwardly relative to a vertical sidewall of the trench with which the facets are associated.
- the vertical sidewalls are labeled as 34 in the FIG. 4 view.
- a vertically-extending sidewall can be considered to define a normal axis. Exemplary normal axes are shown extending upwardly beyond the sidewalls, with the extensions of the normal axes being shown in dashed lines and labeled as 35 in the FIG. 4 view.
- a faceted portion of a trench is defined as a portion of the trench having a slope angled at from about 10° to about 80° relative to a normal axis defined by a sidewall (specifically, a substantially vertical sidewall) of the trench (with the angles between the facet slopes and the normal axes defined by the sidewalls being designated by the label 37 in FIG. 4 ), with the facet of the faceted portion being the surface sloped at from about 10° to about 80° relative to the normal axis defined by the sidewall.
- a typical of a facet angle slope to the normal axis defined by a sidewall will be from about 10° to about 45°.
- angle of a facet surface slope to a normal axis defined by a sidewall 34 will be greater than 20° and less than or equal to about 45°; and in some aspects the angle of a facet surface slope to a normal axis defined by a sidewall 34 will be greater than 30° and less than or equal to about 45°.
- the insulative material 22 between adjacent trenches of the memory array region 6 forms pillars 40 having uppermost edges 41 .
- the faceted portions have uppermost and outermost edges (or corners) 43 , and the uppermost and outermost faceted portion edges 43 of adjacent trenches are spaced from one another by intervening regions of insulative material corresponding to the uppermost surfaces 41 of pillars 40 .
- electrically conductive material is formed within trenches 26 and 28 , over the facets 30 and 32 , and over the intervening regions 41 between adjacent faceted portions.
- the shown conductive material comprises three compositions 46 , 48 and 50 .
- Composition 46 can comprise, consist essentially of, or consist of titanium;
- composition 48 can comprise, consist essentially of, or consist of titanium nitride and/or tungsten nitride;
- composition 50 can comprise, consist essentially of, or consist of tungsten.
- the conductive material of the combined compositions 46 , 48 and 50 can be referred to as a material 46 / 48 / 50 .
- Such material can be considered a bitline material, in that the material is ultimately patterned into bitlines.
- bitline material is shown comprising three compositions, it is to be understood that any suitable conductive material can be utilized.
- metal silicide such as, for example, tungsten silicide
- bitline material can be incorporated into the bitline material in addition to, or alternatively to, one of the stated compositions 46 , 48 and 50 .
- construction 10 is subjected to planarization (such as, for example, chemical-mechanical polishing) to form a planarized upper surface 51 extending across insulative material 22 and across the conductive material 46 / 48 / 50 .
- planarization removes the conductive material from over the intervening regions 41 between the faceted portions while leaving the conductive material within the trenches 26 and 28 , and over the faceted portions 30 and 32 .
- the intervening regions 41 are directly over conductive pedestals 16 . Accordingly the planarization of the conductive material 46 / 48 / 50 has removed the material from directly over storage node contacts 16 , while leaving trenches 26 and 28 substantially filled with the conductive material.
- the bitline material 46 / 48 / 50 at the processing stage of FIG. 6 can be considered to be provided to fill trenches 28 , extend over faceted top portions of the trenches, and not extend over the locations 41 .
- locations 41 can be considered node interconnect locations, in that electrically conductive interconnects are ultimately formed to extend through locations 41 and to contact conductive nodes corresponding to conductive columns 16 .
- trench 26 has been formed substantially simultaneously with trenches 28 ( FIG. 2 ), and has been filled with conductive material 46 / 48 / 50 substantially simultaneously with the filling of trenches 28 .
- a mask 54 is provided to protect peripheral region 4 of construction 10 .
- conductive material 46 / 48 / 50 is utilized as another mask during an etch to form openings 56 extending through the intervening regions 41 ( FIG. 6 ) of insulative material 22 , through insulative material 20 , and to the uppermost surfaces 17 of storage node contacts 16 .
- the conductive material 46 / 48 / 50 extending across faceted regions 32 forms overhangs which act as a hard mask, and accordingly openings 56 can be considered to be self-aligned relative to the bitline material 46 / 48 / 50 within trenches 28 . It is noted that the self-alignment is in the plane of the shown cross-sectional view of FIG.
- a conductive material 60 is formed to extend over bitline material 46 / 48 / 50 and insulative material 22 , and to extend within openings 56 to physically contact the uppermost surfaces of storage node contacts 16 .
- Material 60 can comprise any suitable conductive composition or combination of compositions, and in particular aspects will comprise conductively-doped silicon.
- the silicon can be conductively-doped as deposited, or can be deposited in a substantially undoped form and subsequently doped by any suitable methodologies, (such as, for example, implanting).
- material 60 is subjected to planarization (such as, for example, chemical-mechanical polishing) to remove material 60 from over bitline material 46 / 48 / 50 and insulative material 22 .
- planarization such as, for example, chemical-mechanical polishing
- the interconnects extend from direct physical contact with storage node contacts 16 to a planarized uppermost surface 61 extending across construction 10 .
- the interconnects can be considered to be electrically conductive columns or structures between trenches 28 .
- bitline material 46 / 48 / 50 is recessed within trenches 26 and 28 . Such can be accomplished with an etch selective for materials 46 / 48 / 50 relative to materials 22 and 60 , and/or by providing a patterned mask (not shown) to protect materials 22 and 60 during the etch of bitline material 46 / 48 / 50 .
- the etch of bitline material 46 / 48 / 50 will utilize an ammonium peroxide mixture (which is generally selective for metals relative to oxides of silicon) and/or a dry etch.
- Trenches 28 can be initially formed to a total depth “D” of from about 1000 ⁇ to about 6000 ⁇ , and the remaining depth “R” after reduction of the height of bitline material 46 / 48 / 50 can be from about 5000 ⁇ to about 3000 ⁇ .
- the remaining depth “R” is typically from about 750 ⁇ to about 1250 ⁇ , with a common dimension being about 1000 ⁇ .
- insulative caps 64 are formed within openings 26 and 28 , and over the recessed bitline material 46 / 48 / 50 .
- Such caps can be formed by providing an insulative material over material 22 and within openings 26 and 28 , and subsequently subjecting the material to planarization to form the shown planarized upper surface 65 extending across material 22 and material 64 .
- Insulative material 64 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of silicon nitride.
- an insulative material 70 is formed over planarized surface 65 , and subsequently capacitor structures 72 , 74 , 76 and 78 are formed within the insulative material.
- Each of the capacitor structures comprises a first electrode ( 82 , 84 , 86 and 88 ), a dielectric material ( 92 , 94 , 96 and 98 ) and a second electrode ( 99 ).
- the first electrodes 82 , 84 , 86 and 88 will be recognized by persons of ordinary skill in the art as being storage nodes. Accordingly, the conductive columns of material 60 connect storage nodes of capacitors 72 , 74 , 76 and 78 with the storage node contacts 16 , and ultimately with the circuitry 18 .
- circuitry 18 can comprise transistor devices, and accordingly the construction of FIG. 12 can comprise capacitor constructions electrically coupled with transistor devices through the interconnecting storage node contacts 16 and conductive material 60 .
- a capacitor coupled to a transistor device is a unit cell of a DRAM.
- the construction of FIG. 12 can comprise a plurality of DRAM unit cells associated with memory region 6 .
- Each of the capacitors 72 , 74 , 76 and 78 is in one-to-one correspondence with a conductive column of material 60 .
- the capacitors are shown as container-type capacitors, but it is to be understood that any suitable capacitor type can be utilized.
- FIGS. 1-12 illustrate one aspect in which faceted portions associated with trenches are utilized during fabrication of bitlines and conductive pedestals between the bitlines. Another exemplary aspect is described with reference to FIGS. 13-19 .
- construction 10 is illustrated at a processing stage identical to that of the above-discussed FIG. 6 .
- the construction 10 of FIG. 13 is, however, shown comprising a conductive material 100 in place of material 46 / 48 / 50 of FIG. 6 .
- Such change in provided for convenience, and it is to be understood that the material 100 of FIG. 13 can, and typically would, comprise the material 46 / 48 / 50 discussed above with reference to FIG. 6 .
- material 100 has been utilized as a mask during an etch of materials 20 and 22 .
- a suitable etch is an anisotropic oxide/nitride dry etch, with material 100 comprising tungsten and functioning as a hard mask.
- the etch forms self-aligned spacers from the material 22 remaining against material 100 and under the faceted portions 30 and 32 .
- the alignment of the spacers formed from material 22 relative to material 100 is within the plane of the cross-sectional view of FIG. 14 . It is noted that some self-alignment can also occur in directions orthogonal to the shown cross-sectional view (i.e., directions in and out of the page relative to the shown cross-sectional view).
- the etch of materials 20 and 22 forms pedestals 102 , 104 , 106 , 108 and 110 comprising conductive material 100 and adjacent material 22 spacers.
- the etch also forms openings 112 and 114 adjacent the pedestal 102 associated with peripheral region 4 ; and forms openings 116 , 118 and 120 between the pedestals 104 , 106 , 108 and 110 associated with the memory array region 6 of the substrate.
- the openings 116 , 118 and 120 extend down to upper surfaces 17 of storage node contacts 16 .
- Insulative material 122 is provided within the openings 112 , 114 , 116 , 118 and 120 .
- Insulative material 122 can comprise, consist essentially of, or consist of, for example, a spin-on dielectric and/or silicon dioxide which has not been spun-on.
- Construction 10 is shown having a planarized upper surface 123 at the processing stage of FIG. 15 . Such can be accomplished by forming insulative material 122 to extend over material 100 and within the openings 112 , 114 , 116 , 118 and 120 , and subsequently subjecting construction 10 to planarization (such as, for example, chemical-mechanical polishing) to form the planarized upper surface.
- planarization such as, for example, chemical-mechanical polishing
- conductive material 100 is subjected to an etch which reduces the height of the conductive material within trenches 26 and 28 , and which accordingly reopens portions of trenches 26 and 28 above the remaining portion of conductive material 100 .
- the etch of conductive material 100 can be identical to an etch of material 46 / 48 / 50 discussed above with reference to FIG. 10 .
- material 100 will predominately comprise tungsten, and the etch can comprise a tungsten etch-back of the conductive material.
- an insulative material 130 is provided to fill the portions of trenches 26 and 28 over recessed material 100 .
- Insulative material 130 can comprise, consist essentially of, or consist of, for example, silicon nitride.
- construction 10 comprises a planarized upper surface 131 at the processing stage of FIG. 17 . Such can be formed by initially providing material 130 to be over insulative material 122 as well as within the openings 26 and 28 , and subsequently planarizing the material 130 to form the planarized upper surface.
- a mask 132 is formed to protect peripheral region 4 during an etch over memory array region 6 .
- Such etch selectively removes the material 122 relative to material 130 , and thus forms openings 134 , 136 and 138 extending to storage node contacts 16 .
- material 122 consists essentially of silicon dioxide and material 130 consists essentially of silicon nitride, and accordingly the selective etch utilized to form openings 134 , 136 and 138 is an etch selective for silicon dioxide relative to silicon nitride.
- Conductive material 140 can comprise any suitable material, and in particular aspects will comprise, consist essentially of, or consist of metals, metal compositions and/or conductively-doped silicon.
- construction 10 comprises a planarized upper surface 141 . Such can be accomplished by initially forming material 140 to cover materials 130 and 122 , as well as extending within openings 134 , 136 and 138 , and then subjecting construction 10 to planarization to form the planarized upper surface extending across materials 122 , 130 and 140 . In subsequent processing (not shown) capacitors analogous to the capacitors of FIG. 12 can be formed on surface 141 .
- FIGS. 13-19 An advantage of the embodiment of FIGS. 13-19 relative to that of FIGS. 1-12 is that it can be easier to utilize a wider variety of conductive materials for material 140 of FIG. 19 than for the material 60 of FIG. 8 .
- Such advantage occurs because the processing of FIGS. 1-12 utilizes an etch at the processing stage of FIG. 10 which is preferably selective for the metal-containing bitline material 46 / 48 / 50 relative to the conductive material 60 , whereas the conductive material 140 is formed after the etch of the bitline material 100 .
- the embodiment of FIGS. 12-19 eliminates dependence on the selectivity for etching conductive material 100 relative to material 140 .
- FIG. 21 Such is illustrated in the block diagram of the motherboard 404 shown in FIG. 21 .
- the addressing circuitry is illustrated as 410 and the read circuitry is illustrated as 412 .
- Various components of computer system 400 can comprise one or more of the memory constructions described previously in this disclosure.
- Processor device 406 can correspond to a processor module, and associated memory utilized with the module can comprise teachings of the present invention.
- Memory device 408 can correspond to a memory module.
- SIMMs single in-line memory modules
- DIMMs dual in-line memory modules
- the memory device can be incorporated into any of a variety of designs which provide different methods of reading from and writing to memory cells of the device.
- One such method is the page mode operation.
- Page mode operations in a DRAM are defined by the method of accessing a row of a memory cell arrays and randomly accessing different columns of the array. Data stored at the row and column intersection can be read and output while that column is accessed.
- Memory device 408 can comprise memory formed in accordance with one or more aspects of the present invention.
- the control unit 704 coordinates all operations of the processor 702 , the memory device 706 and the I/O devices 708 by continuously cycling through a set of operations that cause instructions to be fetched from the memory device 706 and executed.
- the memory device 706 includes, but is not limited to, random access memory (RAM) devices, read-only memory (ROM) devices, and peripheral devices such as a floppy disk drive and a compact disk CD-ROM drive.
- RAM random access memory
- ROM read-only memory
- peripheral devices such as a floppy disk drive and a compact disk CD-ROM drive.
- the illustrated power circuitry 816 includes power supply circuitry 880 , circuitry 882 for providing a reference voltage, circuitry 884 for providing the first wordline with pulses, circuitry 886 for providing the second wordline with pulses, and circuitry 888 for providing the bitline with pulses.
- the system 800 also includes a processor 822 , or memory controller for memory accessing.
- the memory device 802 receives control signals from the processor 822 over wiring or metallization lines.
- the memory device 802 is used to store data which is accessed via I/O lines. It will be appreciated by those skilled in the art that additional circuitry and control signals can be provided, and that the memory device 802 has been simplified to help focus on the invention.
- At least one of the processor 822 or memory device 802 can include a memory construction of the type described previously in this disclosure.
- Applications for memory cells can include electronic systems for use in memory modules, device drivers, power modules, communication modems, processor modules, and application-specific modules, and may include multilayer, multichip modules.
- Such circuitry can further be a subcomponent of a variety of electronic systems, such as a clock, a television, a cell phone, a personal computer, an automobile, an industrial control system, an aircraft, and others.
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Abstract
The invention includes methods of forming semiconductor constructions in which electrically conductive structures are formed between bitlines to electrically connect with storage node contacts. The bitlines can be formed within trenches having faceted top portions. The invention also includes semiconductor structures containing trenches with faceted top portions, and containing bitlines within the trenches.
Description
- The invention pertains to semiconductor structures, and to methods of forming semiconductor constructions.
- Semiconductor memory constructions typically comprise arrays of tightly-spaced lines (bitlines and wordlines), together with data storage structures. For instance, dynamic random access memory (DRAM) comprises tightly-spaced wordlines and bitlines together with capacitors, with the capacitors being utilized as data storage devices.
- The semiconductor memory constructions are typically integrated with other circuitry on a single semiconductor chip. Such other circuitry is provided peripherally to the memory array, and can be utilized, for example, for reading of information from the memory array or writing of information to the memory array.
- Continuing goals during semiconductor chip fabrication are to increase the level of integration while maintaining, or even improving, device performance; to increase device throughput; and to reduce costs. Accordingly, it is desirable to develop improved methods for fabrication of integrated circuitry. It is also desirable to develop integrated circuitry having improved performance characteristics.
- In one aspect, the invention encompasses a method of forming a semiconductor construction. A substrate is provided to have a defined memory array region. The substrate comprises, within the memory array region, a plurality of storage node contacts within an insulative material. The storage node contacts have uppermost surfaces covered by the insulative material. Trenches are formed within the insulative material. Electrically conductive bitline material is formed to fill the trenches. The bitline material is patterned into a plurality of spaced bitlines. At least portions of individual bitlines are elevationally above the storage node contact uppermost surfaces. Insulative caps are formed within the trenches and over the bitlines. After the bitline material is formed, and before the insulative caps are formed, electrically conductive structures are formed to extend through the insulative material in locations between the bitlines. The electrically conductive structures extend to the storage node contacts.
- In one aspect, the invention encompasses yet another method of forming a semiconductor construction. A substrate is provided to have a defined memory array region. The substrate comprises, within the memory array region, a plurality of storage node contacts covered by an insulative material. Trenches are formed within the insulative material. The trenches have faceted upper portions. The facets slope upwardly and outwardly relative to the trenches. Uppermost and outermost faceted edges of adjacent trenches are spaced from one another by intervening regions of the insulative material. The trenches are filled with electrically conductive bitline material. The bitline material extends over the trench faceted portions but not over the intervening regions of the insulative material. The bitline material is utilized as an etch mask during an etch to form first openings extending through the intervening insulative material to the storage node contacts. A filler material is formed within the first openings. After the filler material is formed, the bitline material is recessed within the trenches to form unfilled regions of the trenches above the bitline material. Insulative caps are formed within the unfilled regions of the trenches over the bitline material. After the insulative caps are formed, at least some of the filler material is removed to form second openings extending to the storage node contacts. Electrically conductive material is formed within the second openings and electrically coupled to the storage node contacts.
- In one aspect, the invention includes a semiconductor structure. The structure comprises a substrate which includes a plurality of storage node contacts within an insulative material. A plurality of trenches are within the insulative material, with the trenches having faceted top portions. The electrically conductive bitlines extend within the trenches. The bitlines only partially fill the trenches. At least portions of individual bitlines are elevationally above the storage node contacts. The bitlines are a plurality of bitlines, with adjacent bitlines being spaced from one another by intervening locations. Insulative caps are within the trenches and over the bitlines. Electrically conductive columns extend through the insulative material in the intervening locations between the bitlines. The electrically conductive columns are electrically coupled with the storage node contacts. The faceted top portions of the trenches slope outwardly and upwardly from the trenches, and uppermost surfaces of the faceted portions are directly against the electrically conductive columns.
- Preferred embodiments of the invention are described below with reference to the following accompanying drawings.
-
FIG. 1 is a diagrammatic, cross-sectional view of a semiconductor wafer fragment at a preliminary processing stage of an exemplary aspect of an embodiment of the present invention. -
FIG. 2 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 1 . -
FIG. 3 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 2 . -
FIG. 4 is an expanded region of theFIG. 3 wafer fragment, with such expanded region being diagrammatically illustrated inFIG. 3 as the region “4”. -
FIG. 5 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 3 . -
FIG. 6 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 5 . -
FIG. 7 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 6 . -
FIG. 8 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 7 . -
FIG. 9 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 8 . -
FIG. 10 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 9 . -
FIG. 11 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 10 . -
FIG. 12 is a view of theFIG. 1 wafer fragment shown at a processing stage subsequent to that ofFIG. 11 . -
FIG. 13 is a diagrammatic, cross-sectional view of theFIG. 1 wafer fragment shown at a processing stage identical to that ofFIG. 6 , and is a starting point for discussion of a second embodiment aspect of the present invention. -
FIG. 14 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 13 . -
FIG. 15 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 14 . -
FIG. 16 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 15 . -
FIG. 17 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 16 . -
FIG. 18 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 17 . -
FIG. 19 is a view of theFIG. 13 wafer fragment shown at a processing stage subsequent to that ofFIG. 18 . -
FIG. 20 is a diagrammatic view of a computer illustrating an exemplary application of the present invention. -
FIG. 21 is a block diagram showing particular features of the motherboard of theFIG. 20 computer. -
FIG. 22 is a high-level block diagram of an electronic system according to an exemplary aspect of the present invention. -
FIG. 23 is a simplified block diagram of an exemplary memory device according to an aspect of the present invention. - This disclosure of the invention is submitted in furtherance of the constitutional purposes of the U.S. Patent Laws “to promote the progress of science and useful arts” (Article 1, Section 8).
- In some aspects the invention can be considered to comprise methods in which a disposable hard mask is utilized in conjunction with a damascene process so that a self-aligned contact etch can be used during local interconnect fabrication. A standard damascene flow can be utilized in conjunction with incorporation of an additional etch to create a flared (i.e., faceted, prograde) top etch profile. Such creates an overhang adjacent damascene-formed trenches. When the trenches are filled with material, the material creates self-aligning spacers on the overhang. The self-aligning spacers can then be used for self-aligned contact etches. At some point in the process, conductive material can be provided within the trenches and etched back to form bitlines. Insulative material can then be provided over the conductive material to provide an insulative surface that can subsequently be utilized to support capacitor constructions, such as, for example, container-capacitor constructions. In some aspects, the containers can be formed with a high-margin process since the bitlines are buried beneath the insulative material prior to fabrication of the capacitors. Particular aspects of the invention can advantageously form self-aligning spacers, and enable the spacers to be formed simultaneously with other process steps.
- Particular exemplary aspects of the invention are described with reference to
FIGS. 1-23 . - Referring initially to
FIG. 1 , asemiconductor wafer fragment 10 is illustrated at a preliminary processing stage.Wafer fragment 10 comprises asubstrate 12. Such substrate can, for example, comprise monocrystalline silicon lightly-doped with background p-type dopant. To aid in interpretation of the claims that follow, the terms “semiconductive substrate” and “semiconductor substrate” are defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above. - An
insulative material 14 is provided oversubstrate 12, and a plurality of electricallyconductive interconnects 16 are within the insulative material.Interconnects 16 can correspond to storage node contacts, and specifically can ultimately be utilized for electrically coupling capacitor storage nodes with other circuitry. Thestorage node contacts 16 are shown electrically connected tocircuitry 18. Such circuitry can correspond to transistor devices associated with wordlines. Specifically, the transistor devices can have source/drain regions which electrically couple with theconductive columns 16, and which ultimately are utilized for passing bits of data to and from capacitors that are also coupled with thecolumns 16. -
Insulative material 14 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of borophosphosilicate glass. - Electrically
conductive columns 16 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of conductively-doped silicon. -
Storage node contacts 16 comprise uppermost surfaces 17. Such uppermost surfaces are part of aplanarized surface 19 that extends acrossstorage nodes contacts 16 andinsulative material 14. - A
second insulative material 20 extends overplanarized surface 19, and accordingly extends overinsulative material 14 andstorage node contacts 16.Insulative material 20 can be an etch stop in subsequent processing, and can comprise, consist essentially of, or consist of, for example, silicon nitride or silicon dioxide formed from tetra-ethyl-ortho-silicate (TEOS). In some aspects, 14 and 20 can be together considered to be a single insulative material comprising the composition ofinsulative materials layer 20 over the composition oflayer 14. In such aspects,storage node contacts 16 can be considered to be within the insulative material comprising combined 14 and 20, and to have the uppermost surfaces covered by such insulative material.layers - A
third insulative material 22 is overinsulative material 20.Insulative material 22 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of borophosphosilicate glass (BPSG) and/or phosphosilicate glass (PSG). Preferably, 22 and 20 are of suitable composition relative to one another such thatinsulative materials material 22 can be selectively etched relative tomaterial 20. - The
construction 10 is shown divided into two defined 4 and 6, with a dashedregions line 7 diagrammatically separating such two defined regions from one another. The definedregion 6 can correspond to a memory array region of the construction, and theregion 4 can correspond to a region understood to be peripheral to the memory array region. In particular aspects of the invention, DRAM circuitry is formed within thememory array region 6, and peripheral circuitry is formed within theperipheral region 4. - Referring next to
FIG. 2 , atrench 24 is formed within theperipheral region 4 to extend through 14 and 20, and ainsulative materials wider trench 26 is formed overtrench 24 to extend throughinsulative material 22 and to stop onmaterial 20. Additionally,trenches 28 are formed to extend throughinsulative material 22 inmemory array region 6, and to stop onlayer 20. 24, 26 and 28 can be formed utilizing standard damascene processing.Trenches - Referring next to
FIG. 3 ,material 22 is subjected to an etch which forms facetedupper portions 30 oftrench 26, and facetedupper portions 32 oftrenches 28. Ifmaterial 22 comprises, consists essentially of, or consists of a silicon oxide (such as, for example, BPSG) the facet etch can be accomplished utilizing the following conditions: -
- argon or fluorine gas at a flow rate of from about 2 standard cubic centimeters per minute (sccm) to about 500 sccm;
- CF4O at a flow rate of from 0 to about 500 sccm;
- CH2F2 at a flow rate of from 0 to about 500 sccm
- pressure of from about 1 milliTorr to about 5000 milliTorr; and
- power of from about 5 watts to about 5000 watts.
- It is to be understood, however, that any suitable chemistry can be utilized for the facet etch. For instance, O2 can be utilized to facet etch a resist, and then standard oxide etch chemistry can be utilized to transfer the facets to underlying oxide. Also, in some aspects an argon presputter can also be utilized to accomplish the facet etch.
-
FIG. 4 shows an expanded region ofFIG. 3 , and is utilized to illustrate various aspects of facets of exemplary embodiments of the present invention. In the cross-sectional view ofFIG. 4 , it can be seen that the showntrench 28 has a bottom periphery with a horizontally-extending width “W”. Such width can be, for example, at least about 50 Å; in some cases from about 50 Å to about 500 Å; from about 50 Å to about 1000 Å; or from about 50 Å to about 500 Å. Also in the shown cross-sectional view, the trench has a pair offacets 32 on opposing sides of the trench relative to one another. The facet on the shown left side of the trench has a horizontally-extending width “X”, and the facet on the right side of the trench has a horizontally extending width “Y”. Dimensions of the horizontally extending widths X and Y can be from about 10% to about 400% of the dimension of horizontally extending width “W”, and can be, for example, from about 10% to about 50% of the horizontally-extending width “W”, or in particular aspects can be from about 15% to about 25% of the horizontally-extending width “W”. In some aspects, each of the widths “X” and “Y” can be from about 50 Å to about 300 Å, and in particular aspects can be from about 100 Å to about 300 Å. - The shown facets can be considered to extend upwardly and outwardly relative to the
trench 28 with which the facets are associated. In other words, each of the shown facets can be considered to have a slope which extends upwardly and outwardly relative to a vertical sidewall of the trench with which the facets are associated. The vertical sidewalls are labeled as 34 in theFIG. 4 view. A vertically-extending sidewall can be considered to define a normal axis. Exemplary normal axes are shown extending upwardly beyond the sidewalls, with the extensions of the normal axes being shown in dashed lines and labeled as 35 in theFIG. 4 view. For purposes of interpreting this disclosure and the claims that follow, a faceted portion of a trench is defined as a portion of the trench having a slope angled at from about 10° to about 80° relative to a normal axis defined by a sidewall (specifically, a substantially vertical sidewall) of the trench (with the angles between the facet slopes and the normal axes defined by the sidewalls being designated by thelabel 37 inFIG. 4 ), with the facet of the faceted portion being the surface sloped at from about 10° to about 80° relative to the normal axis defined by the sidewall. A typical of a facet angle slope to the normal axis defined by a sidewall will be from about 10° to about 45°. In particular aspects the angle of a facet surface slope to a normal axis defined by asidewall 34 will be greater than 20° and less than or equal to about 45°; and in some aspects the angle of a facet surface slope to a normal axis defined by asidewall 34 will be greater than 30° and less than or equal to about 45°. - Referring back to
FIG. 3 , theinsulative material 22 between adjacent trenches of thememory array region 6 forms pillars 40 having uppermost edges 41. The faceted portions have uppermost and outermost edges (or corners) 43, and the uppermost and outermost faceted portion edges 43 of adjacent trenches are spaced from one another by intervening regions of insulative material corresponding to the uppermost surfaces 41 of pillars 40. - Referring to
FIG. 5 , electrically conductive material is formed within 26 and 28, over thetrenches 30 and 32, and over the interveningfacets regions 41 between adjacent faceted portions. The shown conductive material comprises three 46, 48 and 50.compositions Composition 46 can comprise, consist essentially of, or consist of titanium;composition 48 can comprise, consist essentially of, or consist of titanium nitride and/or tungsten nitride; andcomposition 50 can comprise, consist essentially of, or consist of tungsten. The conductive material of the combined 46, 48 and 50 can be referred to as acompositions material 46/48/50. Such material can be considered a bitline material, in that the material is ultimately patterned into bitlines. Although the bitline material is shown comprising three compositions, it is to be understood that any suitable conductive material can be utilized. For instance, metal silicide (such as, for example, tungsten silicide) can be incorporated into the bitline material in addition to, or alternatively to, one of the stated 46, 48 and 50.compositions - Referring next to
FIG. 6 ,construction 10 is subjected to planarization (such as, for example, chemical-mechanical polishing) to form a planarizedupper surface 51 extending acrossinsulative material 22 and across theconductive material 46/48/50. The planarization removes the conductive material from over the interveningregions 41 between the faceted portions while leaving the conductive material within the 26 and 28, and over thetrenches 30 and 32.faceted portions - It is noted that the intervening
regions 41 are directly overconductive pedestals 16. Accordingly the planarization of theconductive material 46/48/50 has removed the material from directly overstorage node contacts 16, while leaving 26 and 28 substantially filled with the conductive material.trenches - The
bitline material 46/48/50 at the processing stage ofFIG. 6 can be considered to be provided to filltrenches 28, extend over faceted top portions of the trenches, and not extend over thelocations 41. In some aspects,locations 41 can be considered node interconnect locations, in that electrically conductive interconnects are ultimately formed to extend throughlocations 41 and to contact conductive nodes corresponding toconductive columns 16. - It is noted that in the shown aspect of the
invention trench 26 has been formed substantially simultaneously with trenches 28 (FIG. 2 ), and has been filled withconductive material 46/48/50 substantially simultaneously with the filling oftrenches 28. - Referring next to
FIG. 7 , amask 54 is provided to protectperipheral region 4 ofconstruction 10. Subsequently,conductive material 46/48/50 is utilized as another mask during an etch to formopenings 56 extending through the intervening regions 41 (FIG. 6 ) ofinsulative material 22, throughinsulative material 20, and to the uppermost surfaces 17 ofstorage node contacts 16. Theconductive material 46/48/50 extending acrossfaceted regions 32 forms overhangs which act as a hard mask, and accordinglyopenings 56 can be considered to be self-aligned relative to thebitline material 46/48/50 withintrenches 28. It is noted that the self-alignment is in the plane of the shown cross-sectional view ofFIG. 7 , and that there typically would not be self-alignment orthogonally to such plane, (i.e., in and out of the page of the shown view ofFIG. 7 ). Accordingly, additional masking (not shown) would be utilized to accomplish desired alignments orthogonally to the plane of the view ofFIG. 7 . - Referring next to
FIG. 8 , mask 54 (FIG. 7 ) is removed. Subsequently, aconductive material 60 is formed to extend overbitline material 46/48/50 andinsulative material 22, and to extend withinopenings 56 to physically contact the uppermost surfaces ofstorage node contacts 16.Material 60 can comprise any suitable conductive composition or combination of compositions, and in particular aspects will comprise conductively-doped silicon. The silicon can be conductively-doped as deposited, or can be deposited in a substantially undoped form and subsequently doped by any suitable methodologies, (such as, for example, implanting). - Referring next to
FIG. 9 ,material 60 is subjected to planarization (such as, for example, chemical-mechanical polishing) to removematerial 60 from overbitline material 46/48/50 andinsulative material 22.Such leaves material 60 within intervening regions betweentrenches 28 as electrically conductive interconnects. The interconnects extend from direct physical contact withstorage node contacts 16 to a planarizeduppermost surface 61 extending acrossconstruction 10. The interconnects can be considered to be electrically conductive columns or structures betweentrenches 28. - Referring next to
FIG. 10 ,bitline material 46/48/50 is recessed within 26 and 28. Such can be accomplished with an etch selective fortrenches materials 46/48/50 relative to 22 and 60, and/or by providing a patterned mask (not shown) to protectmaterials 22 and 60 during the etch ofmaterials bitline material 46/48/50. In exemplary aspects, the etch ofbitline material 46/48/50 will utilize an ammonium peroxide mixture (which is generally selective for metals relative to oxides of silicon) and/or a dry etch. - The reduction in height of
bitline material 46/48/50 forms openings in the 26 and 28 above the remaining bitline material, and patterns bitlines withintrenches trenches 28 from the remainingmaterial 46/48/50.Trenches 28 can be initially formed to a total depth “D” of from about 1000 Å to about 6000 Å, and the remaining depth “R” after reduction of the height ofbitline material 46/48/50 can be from about 5000 Å to about 3000 Å. The remaining depth “R” is typically from about 750 Å to about 1250 Å, with a common dimension being about 1000 Å. - Referring next to
FIG. 11 , insulative caps 64 are formed within 26 and 28, and over the recessedopenings bitline material 46/48/50. Such caps can be formed by providing an insulative material overmaterial 22 and within 26 and 28, and subsequently subjecting the material to planarization to form the shown planarizedopenings upper surface 65 extending acrossmaterial 22 andmaterial 64.Insulative material 64 can comprise any suitable composition or combination of compositions, and in particular aspects will comprise, consist essentially of, or consist of silicon nitride. - Referring next to
FIG. 12 , aninsulative material 70 is formed overplanarized surface 65, and subsequently capacitor 72, 74, 76 and 78 are formed within the insulative material. Each of the capacitor structures comprises a first electrode (82, 84, 86 and 88), a dielectric material (92, 94, 96 and 98) and a second electrode (99). Thestructures 82, 84, 86 and 88 will be recognized by persons of ordinary skill in the art as being storage nodes. Accordingly, the conductive columns offirst electrodes material 60 connect storage nodes of 72, 74, 76 and 78 with thecapacitors storage node contacts 16, and ultimately with thecircuitry 18. As discussed previously,circuitry 18 can comprise transistor devices, and accordingly the construction ofFIG. 12 can comprise capacitor constructions electrically coupled with transistor devices through the interconnectingstorage node contacts 16 andconductive material 60. As will be recognized by persons of ordinary skill in the art, a capacitor coupled to a transistor device is a unit cell of a DRAM. Accordingly, the construction ofFIG. 12 can comprise a plurality of DRAM unit cells associated withmemory region 6. Each of the 72, 74, 76 and 78 is in one-to-one correspondence with a conductive column ofcapacitors material 60. The capacitors are shown as container-type capacitors, but it is to be understood that any suitable capacitor type can be utilized. -
FIGS. 1-12 illustrate one aspect in which faceted portions associated with trenches are utilized during fabrication of bitlines and conductive pedestals between the bitlines. Another exemplary aspect is described with reference toFIGS. 13-19 . - Referring initially to
FIG. 13 ,construction 10 is illustrated at a processing stage identical to that of the above-discussedFIG. 6 . Theconstruction 10 ofFIG. 13 is, however, shown comprising aconductive material 100 in place ofmaterial 46/48/50 ofFIG. 6 . Such change in provided for convenience, and it is to be understood that thematerial 100 ofFIG. 13 can, and typically would, comprise the material 46/48/50 discussed above with reference toFIG. 6 . - Referring next to
FIG. 14 ,material 100 has been utilized as a mask during an etch of 20 and 22. A suitable etch is an anisotropic oxide/nitride dry etch, withmaterials material 100 comprising tungsten and functioning as a hard mask. The etch forms self-aligned spacers from thematerial 22 remaining againstmaterial 100 and under the 30 and 32. The alignment of the spacers formed fromfaceted portions material 22 relative tomaterial 100 is within the plane of the cross-sectional view ofFIG. 14 . It is noted that some self-alignment can also occur in directions orthogonal to the shown cross-sectional view (i.e., directions in and out of the page relative to the shown cross-sectional view). - The etch of
20 and 22 forms pedestals 102, 104, 106, 108 and 110 comprisingmaterials conductive material 100 andadjacent material 22 spacers. The etch also forms 112 and 114 adjacent theopenings pedestal 102 associated withperipheral region 4; and 116, 118 and 120 between theforms openings 104, 106, 108 and 110 associated with thepedestals memory array region 6 of the substrate. The 116, 118 and 120 extend down toopenings upper surfaces 17 ofstorage node contacts 16. - Referring next to
FIG. 15 , an electricallyinsulative material 122 is provided within the 112, 114, 116, 118 and 120.openings Insulative material 122 can comprise, consist essentially of, or consist of, for example, a spin-on dielectric and/or silicon dioxide which has not been spun-on. -
Construction 10 is shown having a planarizedupper surface 123 at the processing stage ofFIG. 15 . Such can be accomplished by forminginsulative material 122 to extend overmaterial 100 and within the 112, 114, 116, 118 and 120, and subsequently subjectingopenings construction 10 to planarization (such as, for example, chemical-mechanical polishing) to form the planarized upper surface. - Referring next to
FIG. 16 ,conductive material 100 is subjected to an etch which reduces the height of the conductive material within 26 and 28, and which accordingly reopens portions oftrenches 26 and 28 above the remaining portion oftrenches conductive material 100. The etch ofconductive material 100 can be identical to an etch ofmaterial 46/48/50 discussed above with reference toFIG. 10 . In particular aspects,material 100 will predominately comprise tungsten, and the etch can comprise a tungsten etch-back of the conductive material. - Referring next to
FIG. 17 , aninsulative material 130 is provided to fill the portions of 26 and 28 over recessedtrenches material 100.Insulative material 130 can comprise, consist essentially of, or consist of, for example, silicon nitride. In the shown aspect of the invention,construction 10 comprises a planarizedupper surface 131 at the processing stage ofFIG. 17 . Such can be formed by initially providingmaterial 130 to be overinsulative material 122 as well as within the 26 and 28, and subsequently planarizing the material 130 to form the planarized upper surface.openings - Referring next to
FIG. 18 , amask 132 is formed to protectperipheral region 4 during an etch overmemory array region 6. Such etch selectively removes thematerial 122 relative tomaterial 130, and thus forms 134, 136 and 138 extending toopenings storage node contacts 16. In exemplary aspects of the invention,material 122 consists essentially of silicon dioxide andmaterial 130 consists essentially of silicon nitride, and accordingly the selective etch utilized to form 134, 136 and 138 is an etch selective for silicon dioxide relative to silicon nitride.openings - Referring next to
FIG. 19 , mask 132 (FIG. 18 ) is removed andconductive material 140 is formed within the 134, 136 and 138.openings Conductive material 140 can comprise any suitable material, and in particular aspects will comprise, consist essentially of, or consist of metals, metal compositions and/or conductively-doped silicon. In the shown aspect of the invention,construction 10 comprises a planarizedupper surface 141. Such can be accomplished by initially formingmaterial 140 to cover 130 and 122, as well as extending withinmaterials 134, 136 and 138, and then subjectingopenings construction 10 to planarization to form the planarized upper surface extending across 122, 130 and 140. In subsequent processing (not shown) capacitors analogous to the capacitors ofmaterials FIG. 12 can be formed onsurface 141. - An advantage of the embodiment of
FIGS. 13-19 relative to that ofFIGS. 1-12 is that it can be easier to utilize a wider variety of conductive materials formaterial 140 ofFIG. 19 than for thematerial 60 ofFIG. 8 . Such advantage occurs because the processing ofFIGS. 1-12 utilizes an etch at the processing stage ofFIG. 10 which is preferably selective for the metal-containingbitline material 46/48/50 relative to theconductive material 60, whereas theconductive material 140 is formed after the etch of thebitline material 100. Accordingly, the embodiment ofFIGS. 12-19 eliminates dependence on the selectivity for etchingconductive material 100 relative tomaterial 140. -
FIG. 20 illustrates generally, by way of example but not by way of limitation, an embodiment of acomputer system 400 according to an aspect of the present invention.Computer system 400 includes amonitor 401 or other communication output device, akeyboard 402 or other communication input device, and amotherboard 404.Motherboard 404 can carry amicroprocessor 406 or other data processing unit, and at least onememory device 408.Memory device 408 can comprise various aspects of the invention described above.Memory device 408 can comprise an array of memory cells, and such array can be coupled with addressing circuitry for accessing individual memory cells in the array. Further, the memory cell array can be coupled to a read circuit for reading data from the memory cells. The addressing and read circuitry can be utilized for conveying information betweenmemory device 408 andprocessor 406. Such is illustrated in the block diagram of themotherboard 404 shown inFIG. 21 . In such block diagram, the addressing circuitry is illustrated as 410 and the read circuitry is illustrated as 412. Various components ofcomputer system 400, includingprocessor 406, can comprise one or more of the memory constructions described previously in this disclosure. -
Processor device 406 can correspond to a processor module, and associated memory utilized with the module can comprise teachings of the present invention. -
Memory device 408 can correspond to a memory module. For example, single in-line memory modules (SIMMs) and dual in-line memory modules (DIMMs) may be used in the implementation which utilize the teachings of the present invention. The memory device can be incorporated into any of a variety of designs which provide different methods of reading from and writing to memory cells of the device. One such method is the page mode operation. Page mode operations in a DRAM are defined by the method of accessing a row of a memory cell arrays and randomly accessing different columns of the array. Data stored at the row and column intersection can be read and output while that column is accessed. - An alternate type of device is the extended data output (EDO) memory which allows data stored at a memory array address to be available as output after the addressed column has been closed. This memory can increase some communication speeds by allowing shorter access signals without reducing the time in which memory output data is available on a memory bus. Other alternative types of devices include SDRAM, DDR SDRAM, SLDRAM, VRAM and Direct RDRAM, as well as others such as SRAM or Flash memories.
-
Memory device 408 can comprise memory formed in accordance with one or more aspects of the present invention. -
FIG. 22 illustrates a simplified block diagram of a high-level organization of various embodiments of an exemplaryelectronic system 700 of the present invention.System 700 can correspond to, for example, a computer system, a process control system, or any other system that employs a processor and associated memory.Electronic system 700 has functional elements, including a processor or arithmetic/logic unit (ALU) 702, acontrol unit 704, amemory device unit 706 and an input/output (I/O)device 708. Generally,electronic system 700 will have a native set of instructions that specify operations to be performed on data by theprocessor 702 and other interactions between theprocessor 702, thememory device unit 706 and the I/O devices 708. Thecontrol unit 704 coordinates all operations of theprocessor 702, thememory device 706 and the I/O devices 708 by continuously cycling through a set of operations that cause instructions to be fetched from thememory device 706 and executed. In various embodiments, thememory device 706 includes, but is not limited to, random access memory (RAM) devices, read-only memory (ROM) devices, and peripheral devices such as a floppy disk drive and a compact disk CD-ROM drive. One of ordinary skill in the art will understand, upon reading and comprehending this disclosure, that any of the illustrated electrical components are capable of being fabricated to include memory constructions in accordance with various aspects of the present invention. -
FIG. 23 is a simplified block diagram of a high-level organization of various embodiments of an exemplaryelectronic system 800. Thesystem 800 includes amemory device 802 that has an array ofmemory cells 804,address decoder 806,row access circuitry 808,column access circuitry 810, read/writecontrol circuitry 812 for controlling operations, and input/output circuitry 814. Thememory device 802 further includespower circuitry 816, andsensors 820, such as current sensors for determining whether a memory cell is in a low-threshold conducting state or in a high-threshold non-conducting state. The illustratedpower circuitry 816 includespower supply circuitry 880,circuitry 882 for providing a reference voltage,circuitry 884 for providing the first wordline with pulses,circuitry 886 for providing the second wordline with pulses, andcircuitry 888 for providing the bitline with pulses. Thesystem 800 also includes aprocessor 822, or memory controller for memory accessing. - The
memory device 802 receives control signals from theprocessor 822 over wiring or metallization lines. Thememory device 802 is used to store data which is accessed via I/O lines. It will be appreciated by those skilled in the art that additional circuitry and control signals can be provided, and that thememory device 802 has been simplified to help focus on the invention. At least one of theprocessor 822 ormemory device 802 can include a memory construction of the type described previously in this disclosure. - The various illustrated systems of this disclosure are intended to provide a general understanding of various applications for the circuitry and structures of the present invention, and are not intended to serve as a complete description of all the elements and features of an electronic system using memory cells in accordance with aspects of the present invention. One of the ordinary skill in the art will understand that the various electronic systems can be fabricated in single-package processing units, or even on a single semiconductor chip, in order to reduce the communication time between the processor and the memory device(s).
- Applications for memory cells can include electronic systems for use in memory modules, device drivers, power modules, communication modems, processor modules, and application-specific modules, and may include multilayer, multichip modules. Such circuitry can further be a subcomponent of a variety of electronic systems, such as a clock, a television, a cell phone, a personal computer, an automobile, an industrial control system, an aircraft, and others.
- In compliance with the statute, the invention has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the invention is not limited to the specific features shown and described, since the means herein disclosed comprise preferred forms of putting the invention into effect. The invention is, therefore, claimed in any of its forms or modifications within the proper scope of the appended claims appropriately interpreted in accordance with the doctrine of equivalents.
Claims (8)
1-22. (canceled)
23. A semiconductor structure, comprising:
a substrate comprising a plurality of storage node contacts within an electrically insulative material;
a plurality of trenches within the electrically insulative material, the trenches having faceted top portions;
a plurality of electrically conductive bitlines extending within the trenches, the electrically conductive bitlines only partially filling the trenches, at least portions of individual electrically conductive bitlines being elevationally above the storage node contacts; adjacent electrically conductive bitlines being spaced from one another by intervening locations of the electrically insulative material;
insulative caps within the trenches and over the electrically conductive bitlines; and
electrically conductive columns extending through the insulative material in the intervening locations between the electrically conductive bitlines; the electrically conductive columns being electrically coupled with the storage node contacts; the faceted top portions of the trenches sloping outwardly and upwardly from interior regions of the trenches and having uppermost surfaces directly against the electrically conductive columns.
24. A semiconductor structure, comprising:
a substrate comprising a plurality of storage node contacts within an electrically insulative material;
a plurality of trenches within the electrically insulative material, the trenches having faceted top portions;
a plurality of electrically conductive bitlines extending within the trenches, the electrically conductive bitlines only partially filling the trenches, at least portions of individual electrically conductive bitlines being elevationally above the storage node contacts; adjacent electrically conductive bitlines being spaced from one another by intervening locations of the electrically insulative material;
insulative caps within the trenches and over the electrically conductive bitlines;
electrically conductive columns extending through the insulative material in the intervening locations between the electrically conductive bitlines; the electrically conductive columns being electrically coupled with the storage node contacts; the faceted top portions of the trenches sloping outwardly and upwardly from interior regions of the trenches and having uppermost surfaces directly against the electrically conductive columns; and
wherein:
an individual trench of said plurality of trenches has, in a cross-sectional view, a bottom periphery with a horizontally-extending width;
a pair of the facets are associated with said individual trench in the cross-sectional view, with the individual facets of said pair being on opposing sides of the individual trench relative to one another; and
the individual facets of the pair have horizontally-extending widths in the cross-sectional view of from about 10% to about 400% of the horizontally-extending width of the bottom periphery.
25. The structure of claim 24 wherein the individual facets of the pair have horizontally-extending widths in the cross-sectional view of from about 10% to about 50% of the horizontally-extending width of the bottom periphery.
26. A semiconductor structure, comprising:
a substrate comprising a plurality of storage node contacts within an electrically insulative material;
a plurality of trenches within the electrically insulative material, the trenches having faceted top portions;
a plurality of electrically conductive bitlines extending within the trenches, the electrically conductive bitlines only partially filling the trenches, at least portions of individual electrically conductive bitlines being elevationally above the storage node contacts; adjacent electrically conductive bitlines being spaced from one another by intervening locations of the electrically insulative material;
insulative caps within the trenches and over the electrically conductive bitlines;
electrically conductive columns extending through the insulative material in the intervening locations between the electrically conductive bitlines; the electrically conductive columns being electrically coupled with the storage node contacts; the faceted top portions of the trenches sloping outwardly and upwardly from interior regions of the trenches and having uppermost surfaces directly against the electrically conductive columns; and
wherein:
an individual trench of said plurality of trenches has, in a cross-sectional view, a bottom periphery with a horizontally-extending width of from about 50 Å to about 5000 Å;
a pair of the facets are associated with said individual trench in the cross-sectional view, with the individual facets of said pair being on opposing sides of the individual trench relative to one another; and
the individual facets of the pair have horizontally-extending widths in the cross-sectional view of from about 50 Å to about 300 Å.
27. The structure of claim 23 wherein the electrically conductive columns consist essentially of conductively-doped silicon.
28. The structure of claim 23 wherein the electrically conductive bitlines comprise one or more of titanium, titanium nitride, tungsten nitride, tungsten silicide, and tungsten.
29. The structure of claim 23 further comprising a plurality of capacitors having storage nodes electrically coupled with the electrically conductive columns, the capacitors being in one-to-one correspondence with the electrically conductive columns.
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| US11/971,785 US20080105913A1 (en) | 2005-04-06 | 2008-01-09 | Semiconductor Structures |
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| US11/099,972 US7341909B2 (en) | 2005-04-06 | 2005-04-06 | Methods of forming semiconductor constructions |
| US11/971,785 US20080105913A1 (en) | 2005-04-06 | 2008-01-09 | Semiconductor Structures |
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| US7557015B2 (en) * | 2005-03-18 | 2009-07-07 | Micron Technology, Inc. | Methods of forming pluralities of capacitors |
| US7341909B2 (en) * | 2005-04-06 | 2008-03-11 | Micron Technology, Inc. | Methods of forming semiconductor constructions |
| US7544563B2 (en) * | 2005-05-18 | 2009-06-09 | Micron Technology, Inc. | Methods of forming a plurality of capacitors |
| US7521351B2 (en) * | 2005-06-30 | 2009-04-21 | Infineon Technologies Ag | Method for forming a semiconductor product and semiconductor product |
| US7364966B2 (en) * | 2005-08-22 | 2008-04-29 | Micron Technology, Inc. | Method for forming a buried digit line with self aligning spacing layer and contact plugs during the formation of a semiconductor device, semiconductor devices, and systems including same |
| US7902081B2 (en) * | 2006-10-11 | 2011-03-08 | Micron Technology, Inc. | Methods of etching polysilicon and methods of forming pluralities of capacitors |
| US7785962B2 (en) | 2007-02-26 | 2010-08-31 | Micron Technology, Inc. | Methods of forming a plurality of capacitors |
| US7923373B2 (en) | 2007-06-04 | 2011-04-12 | Micron Technology, Inc. | Pitch multiplication using self-assembling materials |
| US7682924B2 (en) * | 2007-08-13 | 2010-03-23 | Micron Technology, Inc. | Methods of forming a plurality of capacitors |
| KR101108711B1 (en) * | 2007-08-23 | 2012-01-30 | 삼성전자주식회사 | An active pattern structure, a method of forming the same, a nonvolatile memory device and a method of manufacturing the same. |
| US8388851B2 (en) | 2008-01-08 | 2013-03-05 | Micron Technology, Inc. | Capacitor forming methods |
| US8274777B2 (en) | 2008-04-08 | 2012-09-25 | Micron Technology, Inc. | High aspect ratio openings |
| US7759193B2 (en) * | 2008-07-09 | 2010-07-20 | Micron Technology, Inc. | Methods of forming a plurality of capacitors |
| JP2010021465A (en) * | 2008-07-14 | 2010-01-28 | Nec Electronics Corp | Nonvolatile semiconductor memory device |
| US8518788B2 (en) | 2010-08-11 | 2013-08-27 | Micron Technology, Inc. | Methods of forming a plurality of capacitors |
| US8691690B2 (en) | 2010-09-13 | 2014-04-08 | International Business Machines Corporation | Contact formation method incorporating preventative etch step reducing interlayer dielectric material flake defects |
| DE102011101035B4 (en) * | 2011-05-10 | 2014-07-10 | Infineon Technologies Ag | A method of manufacturing a terminal region on a sidewall of a semiconductor body |
| US9076680B2 (en) | 2011-10-18 | 2015-07-07 | Micron Technology, Inc. | Integrated circuitry, methods of forming capacitors, and methods of forming integrated circuitry comprising an array of capacitors and circuitry peripheral to the array |
| US8592279B2 (en) | 2011-12-15 | 2013-11-26 | Semicondcutor Components Industries, LLC | Electronic device including a tapered trench and a conductive structure therein and a process of forming the same |
| US8541302B2 (en) * | 2011-12-15 | 2013-09-24 | Semiconductor Components Industries, Llc | Electronic device including a trench with a facet and a conductive structure therein and a process of forming the same |
| US8946043B2 (en) | 2011-12-21 | 2015-02-03 | Micron Technology, Inc. | Methods of forming capacitors |
| US9240548B2 (en) * | 2012-05-31 | 2016-01-19 | Micron Technology, Inc. | Memory arrays and methods of forming an array of memory cells |
| US8652926B1 (en) | 2012-07-26 | 2014-02-18 | Micron Technology, Inc. | Methods of forming capacitors |
| KR102071528B1 (en) | 2013-08-12 | 2020-03-02 | 삼성전자주식회사 | Semiconductor device comprising one-body type support |
| US9589847B1 (en) * | 2016-02-18 | 2017-03-07 | International Business Machines Corporation | Metal layer tip to tip short |
| US10833087B2 (en) | 2018-08-21 | 2020-11-10 | Micron Technology, Inc. | Semiconductor devices including transistors comprising a charge trapping material, and related systems and methods |
| US10553607B1 (en) * | 2018-08-24 | 2020-02-04 | Micron Technology, Inc. | Method of forming an array of elevationally-extending strings of programmable memory cells and method of forming an array of elevationally-extending strings of memory cells |
| CN112885782B (en) * | 2019-11-30 | 2022-06-24 | 长鑫存储技术有限公司 | Semiconductor structure and method of making the same |
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| US7517754B2 (en) | 2009-04-14 |
| US20080113501A1 (en) | 2008-05-15 |
| US7341909B2 (en) | 2008-03-11 |
| US20060228880A1 (en) | 2006-10-12 |
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