[go: up one dir, main page]

US20080032107A1 - Strengthening Materials, Strengthening Laminates, and Composites Comprising These Strengthening Materials - Google Patents

Strengthening Materials, Strengthening Laminates, and Composites Comprising These Strengthening Materials Download PDF

Info

Publication number
US20080032107A1
US20080032107A1 US10/599,528 US59952805A US2008032107A1 US 20080032107 A1 US20080032107 A1 US 20080032107A1 US 59952805 A US59952805 A US 59952805A US 2008032107 A1 US2008032107 A1 US 2008032107A1
Authority
US
United States
Prior art keywords
strengthening
singular
thickness
layer
strengthening material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/599,528
Inventor
Geert Delansheer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OCV Fabrics Belgium BVBA
Owens Corning Intellectual Capital LLC
Original Assignee
Saint Gobain Syncoglas NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Syncoglas NV filed Critical Saint Gobain Syncoglas NV
Assigned to SAINT-GOBAIN SYNCOGLAS N.V. reassignment SAINT-GOBAIN SYNCOGLAS N.V. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DELANDSHEER, GEERT
Publication of US20080032107A1 publication Critical patent/US20080032107A1/en
Assigned to OWENS-CORNING FIBERGLAS TECHNOLOGY II, LLC reassignment OWENS-CORNING FIBERGLAS TECHNOLOGY II, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SYNCOGLASS BVBA
Assigned to OCV INTELLECTUAL CAPITAL, LLC reassignment OCV INTELLECTUAL CAPITAL, LLC CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: OWENS-CORNING FIBERGAS II, LLC
Abandoned legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02—Pile fabrics or articles having similar surface features
    • D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/026—Knitted fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/105—Ceramic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/24992—Density or compression of components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Definitions

  • the present invention relates to strengthening materials suitable for use as reinforcement in composites and to strengthening laminates comprising a stack of said strengthening materials.
  • the present invention relates to composites and/or modelled composites comprising said strengthening materials and a method for the production of composites.
  • the present invention further relates to the use of a knit for the production of composites.
  • Composites or assembled multilayer structures are applied in the production of for instance boats, aircraft, cars, junction boxes, bathtubs, telephone poles, tubes, profiles and so on. Owing to their mechanical strength, relatively light weight, ability to be modelled, stiffness and resistance to for instance corrosion, composites represent an attractive alternative to for instance metal or stone.
  • the layers from which a composite is constructed are generally single layers of plastic, fibre, glass and/or other materials depending on the desired application.
  • layers in a composite can be subdivided into for instance layers which are intended to strengthen or reinforce a composite such as strengthening layers, layers intended to provide a composite with the desired thickness or the desired volume, such as thickness-providing layers, and other layers such as covering layers, for instance for an improved protection, wear resistance, surface structure and so on, and/or finishing layers, such as for instance a paint layer or antistatic layer.
  • layers which are intended to strengthen or reinforce a composite such as strengthening layers
  • layers intended to provide a composite with the desired thickness or the desired volume such as thickness-providing layers
  • other layers such as covering layers, for instance for an improved protection, wear resistance, surface structure and so on
  • finishing layers such as for instance a paint layer or antistatic layer.
  • a number of the above-mentioned functions may also be combined in one layer, such as for instance a strengthening layer which also serves to prevent or reduce wear.
  • Composites, and particularly modelled composites, are traditionally manufactured by applying the different singular layers layer by layer, optionally in a mould, until the desired composite is formed.
  • This production method is however harmful to health due to the use of toxic chemicals and due to the vapours released during curing an applied layer.
  • this method is relatively time-consuming and not sufficiently reproducible in that for instance local irregularities may occur and/or cracks in the applied layer, such as for instance during curing.
  • This traditional manufacturing is therefore unable to provide composites of a constant quality.
  • This method is moreover very labour intensive and time-consuming.
  • These strengthening materials comprise at least one singular thickness-providing layer of a knit of glass fibre and at least one strengthening layer connected to the thickness-providing layer, wherein the thickness-providing layer has less weight per surface area than the strengthening layer.
  • These strengthening materials are particularly suitable for use in the production of modelled composites owing to their excellent deformability, locally of more than 100%.
  • a typical production method for providing a composite wherein use is made of the strengthening material according to EP 0 873 441, comprises of arranging the strengthening material in a mould and subsequent modelling thereof by applying for instance a pressure or a vacuum.
  • the final composite is obtained by for instance curing resins, such as for instance polyester resins, which are impregnated in the knit of the thickness-providing layer and/or the strengthening layers either before, or during, or after modelling of the strengthening material.
  • the use of a knit of glass fibre as thickness-providing layer results in a relatively high weight of the final composite. This is undesirable because, when composites are used as car components, body armour, sporting articles, and aircraft parts, the objective is to obtain the lightest possible composite.
  • the relatively compact structure of the knit of glass fibre in the thickness-providing layer has the further drawback that the resin transport through this layer proceeds relatively slowly. This has an adverse effect on the duration of the production of a composite. It also limits the type of resin that can be used, since relatively fast-curing resins will already cure before a uniform distribution has been obtained in the strengthening material.
  • a strengthening material suitable for use as reinforcement in composites comprising at least one singular thickness-providing layer in the form of a knit of glass fibre which knit comprises at least one monofilament, and at least one singular strengthening layer connected to the singular thickness-providing layer.
  • the knit according to the present invention has at the same time a greater resistance to pressure or vacuum, so that the strengthening material retains its thickness to a greater extent during the modelling and/or impregnation when compared to knits solely of glass fibre.
  • greatly improved strength will be provided with the thickness providing layer according to the present invention as compared to a knit of glass fibre of the same weight, thus resulting in a stronger reinforcement material with the same with weight.
  • a monofilament consists of one filament, usually of a plastic material.
  • plastic materials are polyethylene, polyester, polypropylene and polyamide, although other plastic materials are also possible.
  • Preferred plastic materials are polyester and polyethylene, more preferred is polyethylene
  • monofilaments provide a greater stiffness at an equal or lower specific weight. This has the result that a significant weight-saving can be realized by using monofilaments in the singular thickness-providing layer.
  • the knit of the singular thickness-providing layer such as for instance a flat knit or other type of knit as long as a maximum thickness is provided per weight per surface area, is obtained by processing glass fibre, such as glass filament and/or glass yarn, together with one or more monofilaments to form one cohesive spatial pattern, wherein use is made of knitting techniques which are known in the prior art, such as for instance by making use of the double flatbed knitting technique.
  • the spatial pattern, the density, the composition, the type of monofilament, the type of glass fibres and the knitting technique used depend on the application of the strengthening material according to the present invention. Some considerations determining this are the desired density, the desired stiffness, the desired thickness, the desired compression strength, and combinations of these properties.
  • the singular thickness-providing layer of the strengthening material according to the present invention preferably has a thickness of 0.5 to 20 millimetres, such as 0.5, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, of 20 millimetres.
  • Optimal results are obtained with a thickness of the singular thickness-providing layer of 1 to 10 millimetres, such as 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10 millimetres.
  • the singular thickness-providing layer of the strengthening material according to the present invention preferably has a weight of 25 to 1500 g/m 2 , such as 25, 50, 75, 100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, 1200, 1300, 1400, or 1500 g/m 2 .
  • the singular thickness-providing layer of the strengthening material according to the present invention has a weight of 25 to 1000 g/m 2 , such as 50, 74, 100, 150, 200, 300, 400, 500, 600, 700, 800, 900 or 1000 g/m 2 .
  • the singular strengthening layer according to the present invention can be any material which imparts a mechanical strength or a reinforcement to the strengthening material according to the present invention.
  • Such materials are glass fibre, aramid, carbon, basalt, ceramic, twintex, mixtures of glass and thermoplastics, flax, natural fibres, or combinations hereof.
  • the strengthening material according to the present invention is finally obtained by connecting at least one singular strengthening layer to the singular thickness-providing layer.
  • Preferred examples hereof are knitting techniques such as the Rachel technique, sewing techniques such as are used in stitching machines in the clothing industry, needle punching techniques such as are used in the textile industry for manufacturing needle felt, and/or combinations thereof.
  • the singular thickness-providing layer has less weight per unit of volume than the singular strengthening layer.
  • the flexural stiffness of a final composite also depends on the distance between the different layers in a composite, such as for instance the strengthening layers. It is generally the case that the greater this distance, the greater the stiffness of the final composite.
  • this distance is provided by the singular thickness-providing layer.
  • this thickness-providing layer provides the greatest possible thickness at the lowest possible weight.
  • the strengthening material according to the present invention comprises at least two singular strengthening layers connected to one singular thickness-providing layer in the form of a knit of glass fibre and at least one monofilament, wherein the singular thickness-providing layer is situated between the two singular strengthening layers.
  • This embodiment thus provides a strengthening material comprising a singular strengthening layer—a singular thickness-providing layer—a singular strengthening layer.
  • This construction of the strengthening material according to the present invention provides the advantage that composites can be manufactured in one step which combine great strength with a low weight.
  • the advantageous properties of the above described strengthening materials are obtained by a combination of a knit of glass fibre comprising at least one monofilament and at least one strengthening layer.
  • the present invention therefore also relates to a stacked strengthening material or strengthening laminate, comprising a stack of two or more of the strengthening materials according to the present invention.
  • the above described strengthening materials can be used for the production of composites, which will result in an advantageous lower weight of these composites.
  • the present invention therefore also relates to a composite, and in particular a modelled composite, comprising a strengthening material as described above.
  • the present invention also relates to a method for the production of these composites, comprising of forming a strengthening material according to the present invention into a desired shape, impregnating the strengthening material with a resin, and allowing the resin to cure.
  • the duration of this method is considerably shortened compared to the analogous methods known from the prior art.
  • the present invention also relates to the use of a knit of glass fibre and at least one monofilament for the production of composites.
  • a strengthening material was produced consisting of three layers which were mutually connected according to the Rachel technique (for instance with a maliwatt machine from the Karl Mayer company), wherein use was made of a knitted net (weight 8 g/m 2 ) of fine-textured polyester filament of 167 dtex.
  • the used middle layer, or thickness-providing layer is a flat knit composed of a glass filament of glass yarn 136 tex.
  • the middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 900 g/m 2 .
  • this middle layer or thickness-providing layer Adhered on both sides to this middle layer or thickness-providing layer was a glass mat (strengthening layer), consisting of cut glass fibres of 50 mm length and a thickness of 25 tex, and a weight of 500 g/m 2 .
  • the total thickness of the obtained strengthening material was about 5 mm.
  • a strengthening material consisting of three layers, the middle layer or thickness-providing layer (900 g/m 2 ) of which consisted of a knit of glass filament and glass yarn, and the two outer layers or strengthening layers (450 g/m 2 ) consisted of a glass mat.
  • the total thickness of the obtained strengthening material was about 4.5 mm.
  • a strengthening material according to the present invention was produced consisting of three layers mutually connected according to the Rachel technique (for instance with a maliwatt machine from the Karl Mayer company), wherein use was made of a knitted net (weight 8 g/m 2 ) of fine-textured polyester filament of 167 dtex.
  • This strengthening material can be designated as a “sandwich” construction, such as for instance a honeycomb, wherein the middle layer serves as spacer or thickness-providing layer between the two outer layers, the main function of which is to provide strength or reinforcement.
  • the used middle layer or thickness-providing layer is a flat knit composed of a glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 33 tex monofilament, in a ratio of 136 glass to 33 PE.
  • the middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 280 g/m 2 .
  • this middle layer or thickness-providing layer Adhered on both sides to this middle layer or thickness-providing layer was a glass mat (strengthening layer), consisting of cut glass fibres of 50 mm length and a thickness of 25 tex, and a weight of 500 g/m 2 .
  • the obtained strengthening material is deformable and permits stretch of more than 75%.
  • the total thickness of the obtained strengthening material is about 4.8 mm.
  • a strengthening material consisting of three layers, the middle layer or thickness-providing layer of which consisted of a knit of glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 33 tex monofilament, in a ratio of 136 glass to 33 PE.
  • PE polyethylene filament
  • the middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 280 g/m 2 .
  • the two outer layers or strengthening layers (450 g/m 2 ) consisted of a glass mat.
  • the total thickness of the obtained strengthening material was about 4.7 mm.
  • strengthening materials 3a to 3k according to table 1 were produced consisting of three layers, the middle layer or thickness-providing layer of which consisted of a knit of glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 36 tex monofilament. All strengthening materials had a glass polyethylene (PE) ratio of 1 thread glass to 3 or 4 monofilaments polytheylene and a total thickness varying in the range of 4 to 5 mm. The weights of the thickness providing layers and the strengthening layers are depicted in Table 1.
  • Weight thickness Weight providing strengthening Total Strengthening layer layers weight material (g/m 2 ) ((g/m 2 ) (g/m 2 ) 3a 210 200 618 3b 210 300 818 3c 210 450 1118 3d 210 600 1418 3e 250 300 658 3f 175 300 783 3g 250 450 1158 3h 210 225 668 3i 280 450 1188 3j 300 450 1208 3k 200 450 1108
  • the thickness under a determined pressure of the strengthening material according to example 1 and comparative example 1 were compared, and it was found that strengthening material according to the present invention displayed about 7% less compression at the same pressure.
  • the strengthening materials were compared under different pressures (vacuum) and the results hereof are shown in table 2.
  • Table 2 shows that the strengthening material according to the present invention provides a weight-saving of 620 g/m 2 , and in addition provides less compression under pressure, which will result in a thicker composite and a better resin transport.
  • a composite in this case a helmet, was manufactured using the so-called “vacuum technique closed mould system”.
  • a first film was placed in a mould and the strengthening material according to example 2 and a polyester resin were placed thereon.
  • a second film was then placed on the strengthening material according to example 2 and, after the edges of the first film and the second film were closed, a vacuum was created between the mould and the first foil and between the first and the second film.
  • the strengthening material was modelled as according to the shape of the mould and the resin was simultaneously pressed to the outer ends of the strengthening material. After impregnating the resin in the strengthening material, i.e. through the thickness-providing layer and into the strengthening layers, and after curing of the resin, a modelled composite was obtained in the form of a helmet.
  • Table 3 shows that the strengthening material according to the present invention provides at least three advantages: 1) a shorter production time, 2) a stronger composite (900 g/m 2 against 600 g/m 2 strengthening material) with a lower weight (1188 g/m 2 against 1508 g/m 2 ), and 3) a saving of raw materials and hence a cheaper product.
  • a composite was manufactured using the so-called “injection technique closed mould system”.
  • the strengthening material according to example 2 was placed in a closed mould, in this case a mould for a helmet, with a cavity of 3 mm. After the mould had been closed, polyester resin was injected under pressure. After impregnation of the resin through the thickness-providing layer and into the strengthening layers, a composite in the form of a helmet was obtained after curing.
  • Table 4 shows that the strengthening material according to the present invention provides at least three advantages: 1) a shorter production time, 2) a stronger composite (900 g/m 2 against 600 g/m 2 strengthening material) with a lower weight (1188 g/m 2 against 1508 g/m 2 ), and 3) a saving of raw materials and hence a cheaper product.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Knitting Of Fabric (AREA)

Abstract

The present invention relates to a strengthening material suitable for use as reinforcement in composites, comprising at least one singular thickness-providing layer in the form of a knit of glass fibre and at least one monofilament, and at least one singular strengthening layer connected to the singular thickness-providing layer. In addition, the present invention relates to strengthening laminates comprising these strengthening materials and to composites comprising these strengthening materials and/or strengthening laminates.

Description

  • The present invention relates to strengthening materials suitable for use as reinforcement in composites and to strengthening laminates comprising a stack of said strengthening materials. In addition, the present invention relates to composites and/or modelled composites comprising said strengthening materials and a method for the production of composites. The present invention further relates to the use of a knit for the production of composites.
  • Composites or assembled multilayer structures are applied in the production of for instance boats, aircraft, cars, junction boxes, bathtubs, telephone poles, tubes, profiles and so on. Owing to their mechanical strength, relatively light weight, ability to be modelled, stiffness and resistance to for instance corrosion, composites represent an attractive alternative to for instance metal or stone.
  • The layers from which a composite is constructed are generally single layers of plastic, fibre, glass and/or other materials depending on the desired application.
  • These layers in a composite can be subdivided into for instance layers which are intended to strengthen or reinforce a composite such as strengthening layers, layers intended to provide a composite with the desired thickness or the desired volume, such as thickness-providing layers, and other layers such as covering layers, for instance for an improved protection, wear resistance, surface structure and so on, and/or finishing layers, such as for instance a paint layer or antistatic layer. A number of the above-mentioned functions may also be combined in one layer, such as for instance a strengthening layer which also serves to prevent or reduce wear.
  • Composites, and particularly modelled composites, are traditionally manufactured by applying the different singular layers layer by layer, optionally in a mould, until the desired composite is formed.
  • This production method is however harmful to health due to the use of toxic chemicals and due to the vapours released during curing an applied layer. In addition, this method is relatively time-consuming and not sufficiently reproducible in that for instance local irregularities may occur and/or cracks in the applied layer, such as for instance during curing. This traditional manufacturing is therefore unable to provide composites of a constant quality. This method is moreover very labour intensive and time-consuming.
  • These problems can be wholly or partially resolved by making use during the production of composites of so-called strengthening materials as described in the European patent EP 0 873 441.
  • These strengthening materials comprise at least one singular thickness-providing layer of a knit of glass fibre and at least one strengthening layer connected to the thickness-providing layer, wherein the thickness-providing layer has less weight per surface area than the strengthening layer.
  • These strengthening materials are particularly suitable for use in the production of modelled composites owing to their excellent deformability, locally of more than 100%.
  • A typical production method for providing a composite, wherein use is made of the strengthening material according to EP 0 873 441, comprises of arranging the strengthening material in a mould and subsequent modelling thereof by applying for instance a pressure or a vacuum. The final composite is obtained by for instance curing resins, such as for instance polyester resins, which are impregnated in the knit of the thickness-providing layer and/or the strengthening layers either before, or during, or after modelling of the strengthening material.
  • There are however a number of drawbacks associated with the use of the strengthening materials as described in EP 0 873 441.
  • Firstly, the use of a knit of glass fibre as thickness-providing layer results in a relatively high weight of the final composite. This is undesirable because, when composites are used as car components, body armour, sporting articles, and aircraft parts, the objective is to obtain the lightest possible composite.
  • Simply reducing the weight by applying a less compact knit of glass fibre in the thickness-providing layer is no solution here because the thickness-providing layer hereby becomes too thin and/or allows no or little resin transport during modelling and/or impregnation. In addition, this would also cause a reduction in the flexural stiffness of the cured composite laminate.
  • The relatively compact structure of the knit of glass fibre in the thickness-providing layer has the further drawback that the resin transport through this layer proceeds relatively slowly. This has an adverse effect on the duration of the production of a composite. It also limits the type of resin that can be used, since relatively fast-curing resins will already cure before a uniform distribution has been obtained in the strengthening material.
  • It is therefore an object of the present invention to provide a strengthening material which makes it possible to provide relatively light composites and/or modelled composites which are as strong and/or stiff compared to the composites obtained by making use of the strengthening materials known from the prior art.
  • It is a further object of the present invention to provide stronger and/or stiffer composites and/or modelled composites which are stronger and/or stiffer compared to the composites with a comparable weight obtained by making use of the strengthening materials known from the prior art.
  • It is also an object of the present invention to provide a strengthening material which retains its thickness or volume sufficiently during modelling and/or impregnation.
  • It is an additional object of the present invention to provide a strengthening material in which the resin transport takes place relatively more rapidly and more uniformly during impregnation compared to the resin transport in the strengthening materials known from the prior art.
  • It is also an object of the present invention to provide a strengthening material which can be combined with more types of resin than is possible at this moment compared to the types of resin which can be used in combination with the prior art strengthening materials.
  • The above stated objectives are achieved with a strengthening material suitable for use as reinforcement in composites, comprising at least one singular thickness-providing layer in the form of a knit of glass fibre which knit comprises at least one monofilament, and at least one singular strengthening layer connected to the singular thickness-providing layer.
  • By using a knit of glass fibre comprising a monofilament it is possible to achieve a considerable weight-saving in comparison with the use of a knit solely of glass fibre.
  • The knit according to the present invention has at the same time a greater resistance to pressure or vacuum, so that the strengthening material retains its thickness to a greater extent during the modelling and/or impregnation when compared to knits solely of glass fibre. As a consequence, greatly improved strength will be provided with the thickness providing layer according to the present invention as compared to a knit of glass fibre of the same weight, thus resulting in a stronger reinforcement material with the same with weight.
  • In addition, a better resin transport is obtained by applying the monofilament, whereby the resin will spread more rapidly and more uniformly in the knit.
  • In contrast to glass fibre, a monofilament consists of one filament, usually of a plastic material. Examples of such plastic materials are polyethylene, polyester, polypropylene and polyamide, although other plastic materials are also possible. Preferred plastic materials are polyester and polyethylene, more preferred is polyethylene
  • Compared to glass fibres, monofilaments provide a greater stiffness at an equal or lower specific weight. This has the result that a significant weight-saving can be realized by using monofilaments in the singular thickness-providing layer.
  • The knit of the singular thickness-providing layer, such as for instance a flat knit or other type of knit as long as a maximum thickness is provided per weight per surface area, is obtained by processing glass fibre, such as glass filament and/or glass yarn, together with one or more monofilaments to form one cohesive spatial pattern, wherein use is made of knitting techniques which are known in the prior art, such as for instance by making use of the double flatbed knitting technique.
  • The spatial pattern, the density, the composition, the type of monofilament, the type of glass fibres and the knitting technique used depend on the application of the strengthening material according to the present invention. Some considerations determining this are the desired density, the desired stiffness, the desired thickness, the desired compression strength, and combinations of these properties.
  • The singular thickness-providing layer of the strengthening material according to the present invention preferably has a thickness of 0.5 to 20 millimetres, such as 0.5, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, of 20 millimetres. Optimal results are obtained with a thickness of the singular thickness-providing layer of 1 to 10 millimetres, such as 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10 millimetres.
  • In addition, the singular thickness-providing layer of the strengthening material according to the present invention preferably has a weight of 25 to 1500 g/m2, such as 25, 50, 75, 100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, 1200, 1300, 1400, or 1500 g/m2.
  • It is recommended that the singular thickness-providing layer of the strengthening material according to the present invention has a weight of 25 to 1000 g/m2, such as 50, 74, 100, 150, 200, 300, 400, 500, 600, 700, 800, 900 or 1000 g/m2.
  • The singular strengthening layer according to the present invention, usually in the form of a non-woven, a woven fabric or a membrane, can be any material which imparts a mechanical strength or a reinforcement to the strengthening material according to the present invention.
  • Examples of such materials are glass fibre, aramid, carbon, basalt, ceramic, twintex, mixtures of glass and thermoplastics, flax, natural fibres, or combinations hereof.
  • The strengthening material according to the present invention is finally obtained by connecting at least one singular strengthening layer to the singular thickness-providing layer.
  • Many techniques are known which can be used to form such a connection between the singular thickness-providing layer and the singular strengthening layer. Preferred examples hereof are knitting techniques such as the Rachel technique, sewing techniques such as are used in stitching machines in the clothing industry, needle punching techniques such as are used in the textile industry for manufacturing needle felt, and/or combinations thereof.
  • It is particularly recommended in the strengthening material according to the present invention that the singular thickness-providing layer has less weight per unit of volume than the singular strengthening layer.
  • The reason for this is that the flexural stiffness of a final composite also depends on the distance between the different layers in a composite, such as for instance the strengthening layers. It is generally the case that the greater this distance, the greater the stiffness of the final composite.
  • In the strengthening material according to the present invention this distance is provided by the singular thickness-providing layer. Partly with a view to the weight of the final composite, it is therefore advantageous if this thickness-providing layer provides the greatest possible thickness at the lowest possible weight.
  • According to a preferred embodiment, the strengthening material according to the present invention comprises at least two singular strengthening layers connected to one singular thickness-providing layer in the form of a knit of glass fibre and at least one monofilament, wherein the singular thickness-providing layer is situated between the two singular strengthening layers. This embodiment thus provides a strengthening material comprising a singular strengthening layer—a singular thickness-providing layer—a singular strengthening layer.
  • This construction of the strengthening material according to the present invention provides the advantage that composites can be manufactured in one step which combine great strength with a low weight.
  • The advantageous properties of the above described strengthening materials are obtained by a combination of a knit of glass fibre comprising at least one monofilament and at least one strengthening layer.
  • It will be apparent to the person with ordinary skill in the art that these properties are also obtained if a plurality of these strengthening materials are stacked to form a woven fabric or laminate, wherein the singular strengthening materials are mutually connected, using for instance the above described techniques such as knitting techniques, sewing techniques, needle punching techniques and/or combinations thereof, or using adhesion techniques such as chemical adhesion.
  • The present invention therefore also relates to a stacked strengthening material or strengthening laminate, comprising a stack of two or more of the strengthening materials according to the present invention.
  • The above described strengthening materials can be used for the production of composites, which will result in an advantageous lower weight of these composites. The present invention therefore also relates to a composite, and in particular a modelled composite, comprising a strengthening material as described above.
  • The present invention also relates to a method for the production of these composites, comprising of forming a strengthening material according to the present invention into a desired shape, impregnating the strengthening material with a resin, and allowing the resin to cure.
  • Owing to the surprising properties, and especially the improved resin transport, of the knit of glass fibre and monofilament in the thickness-providing layer, the duration of this method is considerably shortened compared to the analogous methods known from the prior art.
  • For reasons already stated above, the present invention also relates to the use of a knit of glass fibre and at least one monofilament for the production of composites.
  • The present invention will be further elucidated with reference to the following examples, which are only given by way of illustration and are not intended to limit the invention in any way whatsoever.
    • EXAMPLES Comparative Example 1
  • A strengthening material was produced consisting of three layers which were mutually connected according to the Rachel technique (for instance with a maliwatt machine from the Karl Mayer company), wherein use was made of a knitted net (weight 8 g/m2) of fine-textured polyester filament of 167 dtex.
  • The used middle layer, or thickness-providing layer, is a flat knit composed of a glass filament of glass yarn 136 tex. The middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 900 g/m2.
  • Adhered on both sides to this middle layer or thickness-providing layer was a glass mat (strengthening layer), consisting of cut glass fibres of 50 mm length and a thickness of 25 tex, and a weight of 500 g/m2.
  • The total weight of the strengthening material expressed in weight/m2 is 500+900+500+8=1908 g/m2. The total thickness of the obtained strengthening material was about 5 mm.
    • Comparative Example 2
  • In similar manner as described in comparative example 1, a strengthening material was produced consisting of three layers, the middle layer or thickness-providing layer (900 g/m2) of which consisted of a knit of glass filament and glass yarn, and the two outer layers or strengthening layers (450 g/m2) consisted of a glass mat.
  • The total weight of the strengthening material expressed in weight/m2 is 300+900+300+8=1508 g/m2. The total thickness of the obtained strengthening material was about 4.5 mm.
    • Example 1
  • A strengthening material according to the present invention was produced consisting of three layers mutually connected according to the Rachel technique (for instance with a maliwatt machine from the Karl Mayer company), wherein use was made of a knitted net (weight 8 g/m2) of fine-textured polyester filament of 167 dtex.
  • This strengthening material can be designated as a “sandwich” construction, such as for instance a honeycomb, wherein the middle layer serves as spacer or thickness-providing layer between the two outer layers, the main function of which is to provide strength or reinforcement.
  • The used middle layer or thickness-providing layer is a flat knit composed of a glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 33 tex monofilament, in a ratio of 136 glass to 33 PE. The middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 280 g/m2.
  • Adhered on both sides to this middle layer or thickness-providing layer was a glass mat (strengthening layer), consisting of cut glass fibres of 50 mm length and a thickness of 25 tex, and a weight of 500 g/m2.
  • The obtained strengthening material is deformable and permits stretch of more than 75%. The total weight of the strengthening material expressed in weight/m2 is 500+280+500+8=1288 g/m2. The total thickness of the obtained strengthening material is about 4.8 mm.
    • Example 2
  • In similar manner as described in example 1, a strengthening material was produced consisting of three layers, the middle layer or thickness-providing layer of which consisted of a knit of glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 33 tex monofilament, in a ratio of 136 glass to 33 PE.
  • The middle layer or thickness-providing layer has a thickness of about 4 mm and a weight of about 280 g/m2. The two outer layers or strengthening layers (450 g/m2) consisted of a glass mat. The total weight of the strengthening material expressed in weight/m2 is 450+280+450+8=1188 g/m2. The total thickness of the obtained strengthening material was about 4.7 mm.
    • Example 3
  • In similar manner as described in example 1, strengthening materials 3a to 3k according to table 1 were produced consisting of three layers, the middle layer or thickness-providing layer of which consisted of a knit of glass filament, glass yarn 136 tex, and a polyethylene filament (PE), 36 tex monofilament. All strengthening materials had a glass polyethylene (PE) ratio of 1 thread glass to 3 or 4 monofilaments polytheylene and a total thickness varying in the range of 4 to 5 mm. The weights of the thickness providing layers and the strengthening layers are depicted in Table 1.
  • TABLE 1
    Weight thickness Weight
    providing strengthening Total
    Strengthening layer layers weight
    material (g/m2) ((g/m2) (g/m2)
    3a 210 200 618
    3b 210 300 818
    3c 210 450 1118
    3d 210 600 1418
    3e 250 300 658
    3f 175 300 783
    3g 250 450 1158
    3h 210 225 668
    3i 280 450 1188
    3j 300 450 1208
    3k 200 450 1108
    • Example 4
  • The thickness under a determined pressure of the strengthening material according to example 1 and comparative example 1 were compared, and it was found that strengthening material according to the present invention displayed about 7% less compression at the same pressure. The strengthening materials were compared under different pressures (vacuum) and the results hereof are shown in table 2.
  • TABLE 2
    Type of Thickness at a Thickness at a
    strengthening pressure of 0.5 pressure of 1
    material Weight/m2 kg/cm2 kg/cm2
    Comparative 1908 g 2.2 mm 2.0 mm
    example 1
    Example 1 1288 g 2.35 mm 2.15 mm
  • Table 2 shows that the strengthening material according to the present invention provides a weight-saving of 620 g/m2, and in addition provides less compression under pressure, which will result in a thicker composite and a better resin transport.
  • Improved resistance to compression as compared to similar strengthening materials comprising a thickness providing layer of only a glass knit of the same weight were obtained using the strengthening materials 3a to 3k according to example 3.
    • Example 5
  • A composite, in this case a helmet, was manufactured using the so-called “vacuum technique closed mould system”. In summary, a first film was placed in a mould and the strengthening material according to example 2 and a polyester resin were placed thereon. A second film was then placed on the strengthening material according to example 2 and, after the edges of the first film and the second film were closed, a vacuum was created between the mould and the first foil and between the first and the second film.
  • Under the influence of the vacuum the strengthening material was modelled as according to the shape of the mould and the resin was simultaneously pressed to the outer ends of the strengthening material. After impregnating the resin in the strengthening material, i.e. through the thickness-providing layer and into the strengthening layers, and after curing of the resin, a modelled composite was obtained in the form of a helmet.
  • This method was repeated wherein use was made of the strengthening material according to comparative example 2 instead of the strengthening material of example 2.
  • The time required for a full impregnation of both strengthening materials was measured, and this is shown in table 3.
  • TABLE 3
    strengthening material Weight/m2 impregnation time
    Comparative example 2 1508 g 23 minutes
    Example 2 1188 g 17 minutes
  • Table 3 shows that the strengthening material according to the present invention provides at least three advantages: 1) a shorter production time, 2) a stronger composite (900 g/m2 against 600 g/m2 strengthening material) with a lower weight (1188 g/m2 against 1508 g/m2), and 3) a saving of raw materials and hence a cheaper product.
  • Reduced impregnation times as compared to strengthening materials comprising a thickness providing layer of a glass knit of the same weight were obtained using the strengthening materials 3a to 3k according to example 3.
    • Example 6
  • A composite was manufactured using the so-called “injection technique closed mould system”. In summary, the strengthening material according to example 2 was placed in a closed mould, in this case a mould for a helmet, with a cavity of 3 mm. After the mould had been closed, polyester resin was injected under pressure. After impregnation of the resin through the thickness-providing layer and into the strengthening layers, a composite in the form of a helmet was obtained after curing.
  • This method was repeated wherein use was made of the strengthening material according to comparative example 2 instead of the strengthening material of example 2.
  • The time required for a full impregnation of both strengthening materials was measured, and this time is shown in table 3.
  • TABLE 4
    strengthening material Weight/m2 impregnation time
    Comparative example 2 1508 g   15 minutes
    Example 2 1188 g <10 minutes
  • Table 4 shows that the strengthening material according to the present invention provides at least three advantages: 1) a shorter production time, 2) a stronger composite (900 g/m2 against 600 g/m2 strengthening material) with a lower weight (1188 g/m2 against 1508 g/m2), and 3) a saving of raw materials and hence a cheaper product.

Claims (15)

1. Strengthening material suitable for use as reinforcement in composites, comprising at least one singular thickness-providing layer in the form of a knit of glass fibre which knit comprises at least one monofilament, and at least one singular strengthening layer connected to the singular thickness-providing layer.
2. Strengthening material as claimed in claim 1, wherein the monofilament is chosen from the group consisting of polyethylene, polyester, polypropylene, polyamide, synthetic materials and combinations thereof.
3. Strengthening material as claimed in claim 1 or 2, wherein the singular thickness-providing layer has a thickness of 0.5 up to and including 20 millimetres.
4. Strengthening material as claimed in any of the claims 1-3, wherein the singular thickness-providing layer has a thickness of 1 up to and including 10 millimetres.
5. Strengthening material as claimed in any of the claims 1-4, wherein the singular thickness-providing layer has a weight of 25 up to and including 1500 g/m2.
6. Strengthening material as claimed in any of the claims 1-5, wherein the singular thickness-providing layer has a weight of 50 up to and including 1000 g/m2.
7. Strengthening material as claimed in any of the claims 1-6, wherein the singular strengthening layer is chosen from the group consisting of glass fibre, aramid, carbon, basalt, ceramic, twintex, mixtures of glass and thermoplastics, flax, natural fibres, and combinations thereof.
8. Strengthening material as claimed in any of the claims 1-7, wherein the singular strengthening layer is a non-woven, a woven fabric or a membrane.
9. Strengthening material as claimed in any of the claims 1-8, wherein the singular thickness-providing layer has less weight per unit of volume than the singular strengthening layer.
10. Strengthening material as claimed in any of the claims 1-9, wherein the singular thickness-providing layer and the singular strengthening layer are mutually connected by knitting techniques, sewing techniques, needle punching techniques and/or combinations thereof.
11. Strengthening material as claimed in any of the claims 1-10, comprising at least two singular strengthening layers connected to one singular thickness-providing layer in the form of a knit of glass fibre and at least one monofilament, wherein the singular thickness-providing layer is situated between the two singular strengthening layers.
12. Strengthening laminate comprising a stack of two or more of the strengthening materials as claimed in any of the claims 1-11.
13. Composite comprising a strengthening material according to any of the claims 1-11 or a strengthening laminate according to claim 12.
14. Method for the production of composites, comprising of forming a strengthening material according to any of the claims 1-11 or a strengthening laminate according to claim 12 into a desired shape, impregnating the strengthening material with a resin, and allowing the resin to cure.
15. Use of a knit of glass fibre comprising at least one polymeric monofilament for the production of composites.
US10/599,528 2004-03-30 2005-03-29 Strengthening Materials, Strengthening Laminates, and Composites Comprising These Strengthening Materials Abandoned US20080032107A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL1025846 2004-03-30
NL1025846A NL1025846C2 (en) 2004-03-30 2004-03-30 Reinforcement materials, reinforcement blankets, and composites comprising these reinforcement materials.
PCT/EP2005/003369 WO2005095696A1 (en) 2004-03-30 2005-03-29 Strengthening materials, strengthening laminates, and composites comprising these strengthening materials

Publications (1)

Publication Number Publication Date
US20080032107A1 true US20080032107A1 (en) 2008-02-07

Family

ID=34963335

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/599,528 Abandoned US20080032107A1 (en) 2004-03-30 2005-03-29 Strengthening Materials, Strengthening Laminates, and Composites Comprising These Strengthening Materials

Country Status (5)

Country Link
US (1) US20080032107A1 (en)
EP (1) EP1745169A1 (en)
JP (1) JP2007530810A (en)
NL (1) NL1025846C2 (en)
WO (1) WO2005095696A1 (en)

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1771216A (en) * 1925-10-26 1930-07-22 Gossler Oscar Insulating body of spun glass
US3669823A (en) * 1969-06-04 1972-06-13 Curlator Corp Non-woven web
US3934064A (en) * 1971-11-24 1976-01-20 E. I. Du Pont De Nemours And Company Composite structures of knitted glass fabric and thermoplastic polyfluoroethylene resin sheet
US4070519A (en) * 1976-04-27 1978-01-24 Huyck Corporation High temperature filter fabrics
US4250221A (en) * 1976-04-29 1981-02-10 Consolidated Fiberglass Products Co. Fiberglass mat
US4278820A (en) * 1978-10-05 1981-07-14 Showa Denka K.K. Process for preparing monoalkylene glycol monoethers
US4350727A (en) * 1980-07-09 1982-09-21 Lydall, Inc. Synergistic textile composite
US4532176A (en) * 1980-07-11 1985-07-30 Imperial Chemical Industries Limited Fibrous material comprised of vermiculite coated fibers
US4696850A (en) * 1986-03-25 1987-09-29 Firma Carl Freudenberg Iron-on interlining composite of knit layer and nonwoven layer of similar structure
US4892780A (en) * 1987-07-16 1990-01-09 Cochran William H Fiber reinforcement for resin composites
US4911973A (en) * 1988-03-14 1990-03-27 Owens-Corning Fiberglas Corporation Reinforcement blanket formed by sewing together layers of fiber-reinforcement materials
US5166480A (en) * 1988-04-23 1992-11-24 Vorwerk & Co. Interholding Gmbh Knitted fabric panel structure and process of manufacture
US5480697A (en) * 1991-01-12 1996-01-02 Vorwerk & Co. Interholding Gmbh Structural part based on a sandwich fabric
US5582893A (en) * 1992-08-31 1996-12-10 Boettger; Wolfgang Spacing fabric
US5612114A (en) * 1993-11-06 1997-03-18 Hoechst Aktiengesellschaft Textile composite, production thereof and use thereof
US6037035A (en) * 1994-02-23 2000-03-14 Vorwerk & Co. Interholding Gmbh Spacer fabric
US20030102604A1 (en) * 2001-07-23 2003-06-05 Mack Patrick E. Three-dimensional spacer fabric resin interlaminar infusion media process and vacuum-induced reinforcing composite laminate structures
US20070010154A1 (en) * 1995-03-02 2007-01-11 N.V. Syncoglas S.A. Reinforcement material

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2628448B1 (en) * 1988-03-14 1990-11-16 Chomarat & Cie TEXTILE REINFORCEMENT FOR USE IN THE PRODUCTION OF LAMINATED COMPLEXES AND LAMINATED COMPLEXES IN THE FORM COMPRISING SUCH AN ARMATURE
FR2646442B1 (en) * 1989-04-28 1993-04-02 Chomarat & Cie TEXTILE REINFORCEMENT FOR USE IN THE PRODUCTION OF COMPOSITE MATERIALS AND SHAPED ARTICLES HAVING SUCH AN REINFORCEMENT
JPH0711548A (en) * 1993-06-18 1995-01-13 Unitika Ltd Thick knitted fabric
DE19530928C2 (en) * 1995-08-23 1998-12-03 Mayer Textilmaschf Composite part made of knitted fabric
FR2780419B1 (en) * 1998-06-30 2000-09-29 Chomarat & Cie GLASS KNITS, COMPLEX TEXTILE STRUCTURES AND COMPOSITES
JP4075197B2 (en) * 1999-03-16 2008-04-16 日東紡績株式会社 Pile network, composite material and manufacturing method thereof
GB9930567D0 (en) * 1999-12-23 2000-02-16 Scott & Fyfe Ltd Reinforced panel structure
AU2002326922B2 (en) * 2001-09-17 2007-07-05 Verdant Technologies, Inc. Three-dimensional knit spacer fabric sandwich composite

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1771216A (en) * 1925-10-26 1930-07-22 Gossler Oscar Insulating body of spun glass
US3669823A (en) * 1969-06-04 1972-06-13 Curlator Corp Non-woven web
US3934064A (en) * 1971-11-24 1976-01-20 E. I. Du Pont De Nemours And Company Composite structures of knitted glass fabric and thermoplastic polyfluoroethylene resin sheet
US4070519A (en) * 1976-04-27 1978-01-24 Huyck Corporation High temperature filter fabrics
US4250221A (en) * 1976-04-29 1981-02-10 Consolidated Fiberglass Products Co. Fiberglass mat
US4278820A (en) * 1978-10-05 1981-07-14 Showa Denka K.K. Process for preparing monoalkylene glycol monoethers
US4350727A (en) * 1980-07-09 1982-09-21 Lydall, Inc. Synergistic textile composite
US4532176A (en) * 1980-07-11 1985-07-30 Imperial Chemical Industries Limited Fibrous material comprised of vermiculite coated fibers
US4696850A (en) * 1986-03-25 1987-09-29 Firma Carl Freudenberg Iron-on interlining composite of knit layer and nonwoven layer of similar structure
US4892780A (en) * 1987-07-16 1990-01-09 Cochran William H Fiber reinforcement for resin composites
US4911973A (en) * 1988-03-14 1990-03-27 Owens-Corning Fiberglas Corporation Reinforcement blanket formed by sewing together layers of fiber-reinforcement materials
US5166480A (en) * 1988-04-23 1992-11-24 Vorwerk & Co. Interholding Gmbh Knitted fabric panel structure and process of manufacture
US5480697A (en) * 1991-01-12 1996-01-02 Vorwerk & Co. Interholding Gmbh Structural part based on a sandwich fabric
US5582893A (en) * 1992-08-31 1996-12-10 Boettger; Wolfgang Spacing fabric
US5612114A (en) * 1993-11-06 1997-03-18 Hoechst Aktiengesellschaft Textile composite, production thereof and use thereof
US6037035A (en) * 1994-02-23 2000-03-14 Vorwerk & Co. Interholding Gmbh Spacer fabric
US20070010154A1 (en) * 1995-03-02 2007-01-11 N.V. Syncoglas S.A. Reinforcement material
US20030102604A1 (en) * 2001-07-23 2003-06-05 Mack Patrick E. Three-dimensional spacer fabric resin interlaminar infusion media process and vacuum-induced reinforcing composite laminate structures

Also Published As

Publication number Publication date
WO2005095696A1 (en) 2005-10-13
NL1025846C2 (en) 2005-10-03
JP2007530810A (en) 2007-11-01
EP1745169A1 (en) 2007-01-24

Similar Documents

Publication Publication Date Title
US5529826A (en) Fabric-faced thermoplastic composite panel
FI93331B (en) A usable multilayer combination of reinforcing materials for plastic parts and a method for producing a fiber-reinforced plastic material
CN100548643C (en) Composite laminate connected by wire tufts
EP0822062B1 (en) Fiber-reinforced plastic using a composite substrate
US20090252916A1 (en) Composite material assembly
US20060121805A1 (en) Non-woven, uni-directional multi-axial reinforcement fabric and composite article
CN1860016B (en) Crimp-free infusible reinforcement fabric and composite reinforced material therefrom
CZ4309U1 (en) Reinforced fibrous structure
KR102307989B1 (en) Fiber reinforced composite material having a hollow section and method for manufacturing the same
KR101873142B1 (en) Method and apparatus for manufacturing a sandwich component
JPH01201546A (en) Production of lightweight sandwich structural material
KR102196438B1 (en) Carbon Fiber Grid for Reinforcement And Manufacturing Method Of The Same
KR101938847B1 (en) Composite material having excellent strength and lightweight and method for manufacturing the same
US20200180266A1 (en) Composite laminate resin and fiberglass structure
KR101776432B1 (en) A composite for roof of an automaobile and a method for preparation thereof
KR101135406B1 (en) Non-woven shaft impregnable reinforcing fabric and composite stiffener made therefrom
US20080032107A1 (en) Strengthening Materials, Strengthening Laminates, and Composites Comprising These Strengthening Materials
US20090162604A1 (en) Knitted Infusion Fabric
CA3122042C (en) Method for the preparation of composite material in sandwich form
KR101543598B1 (en) Natural fiber fabric multilayer structure and method for manufacturing the same
US20070010154A1 (en) Reinforcement material
US20200406581A1 (en) Composite laminate resin and fiberglass structure
EP1111110A3 (en) Reinforced panel structure
US20070193490A1 (en) Complex matting with a layer of volumized fibers
RU2635225C2 (en) Multilayered part

Legal Events

Date Code Title Description
AS Assignment

Owner name: SAINT-GOBAIN SYNCOGLAS N.V., BELGIUM

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DELANDSHEER, GEERT;REEL/FRAME:019315/0276

Effective date: 20070516

AS Assignment

Owner name: OWENS-CORNING FIBERGLAS TECHNOLOGY II, LLC, OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SYNCOGLASS BVBA;REEL/FRAME:023535/0445

Effective date: 20080124

AS Assignment

Owner name: OCV INTELLECTUAL CAPITAL, LLC, OHIO

Free format text: CHANGE OF NAME;ASSIGNOR:OWENS-CORNING FIBERGAS II, LLC;REEL/FRAME:023541/0257

Effective date: 20071130

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION