US20080007831A1 - Optical Element - Google Patents
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- US20080007831A1 US20080007831A1 US11/575,595 US57559505A US2008007831A1 US 20080007831 A1 US20080007831 A1 US 20080007831A1 US 57559505 A US57559505 A US 57559505A US 2008007831 A1 US2008007831 A1 US 2008007831A1
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- transmitting layer
- optical element
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1814—Diffraction gratings structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1876—Diffractive Fresnel lenses; Zone plates; Kinoforms
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1876—Diffractive Fresnel lenses; Zone plates; Kinoforms
- G02B5/189—Structurally combined with optical elements not having diffractive power
- G02B5/1895—Structurally combined with optical elements not having diffractive power such optical elements having dioptric power
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1866—Transmission gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
- G02B5/1871—Transmissive phase gratings
Definitions
- the present invention relates to an optical element, an in particular to a light-converging device for converging light, such as a lens, and a diffraction device for diffracting light, such as a grating.
- a blazed grating is an optical element having a sawtooth blazed surface, which includes a plurality of light-transmitting slopes.
- a light-converging device having a blazed grating on its surface is disclosed in Non-Patent Document 1 and Patent Document 1.
- the light-converging device shown in FIG. 10 comprises a substrate 1 , which is formed of a transparent material such as plastic and has surfaces 1 a and 1 b.
- the substrate 1 has a lens shape which is symmetric around its optical axis, and has a grating 1 G formed on the surface 1 b thereof, the grating 1 G having a sawteeth-shaped cross section.
- the lens surfaces 1 a and 1 b of the light-converging device constitute a sphere or non-sphere, with its center axis being the optical axis L.
- the plurality of light-transmitting slopes composing the grating 1 G each have an annular shape whose center axis is the optical axis L, and are arrayed in a radial direction.
- steps of the grating are formed in concentric circles centered around the optical axis.
- Light 2 which enters the substrate 71 is refracted by the surface 1 a, and thereafter simultaneously receives refraction and diffraction at the surface 1 b on which the grating 1 G is formed.
- Light 3 going out from the light-converging device is converged on a detection surface 4 .
- FIG. 11 illustrates the surface 1 b as being planar.
- the device shown in FIG. 11 has a substrate 1 having a grating 1 G formed on a surface 1 b thereof, the grating 1 G having a sawteeth-like cross section.
- the substrate 1 has a refractive index n.
- the grating 1 G has a pitch ⁇ .
- the grating 1 G diffracts light 2 of the wavelength ⁇ , thus generating diffracted light such as 1 st -order diffracted light 3 and 2 nd -order diffracted light 3 ′′.
- the incident angle of the light 2 i.e., the angle between the normal of the rear face of the substrate 1 and the axis of the light 2
- the diffraction angle ⁇ of the q th -order diffracted light i.e., the angle between the normal and the diffracted light
- q is an integer representing the order of the diffracted light.
- n is the refractive index of the substrate 1 (transparent medium)
- ⁇ is the wavelength of the incident light 2 .
- the pitch ⁇ does not need to be constant across the surface of the substrate 1 , and the pitch ⁇ may be a mathematical function of position on the substrate 1 .
- the pitch ⁇ By varying the pitch ⁇ as a mathematical function of position, it becomes possible to adjust the diffraction angle in accordance with the outgoing position from the substrate 1 . By doing so, and assisted also by the spherical shape of the surfaces 1 a and 1 b, etc., it becomes possible to converge the diffracted light 3 at one point.
- This conventional technique has a construction as taught in Patent Document 1.
- a light-converging device shown in FIG. 12 is formed of two types of transparent media having different refractive indices and dispersion characteristics (plastic, UV-curing resin, or the like).
- a lens portion 1 is formed of a first material, and has a lens shape.
- a grating 1 G having a sawteeth-like cross section is formed on a surface 1 b, thus presenting a construction similar to that of the lens 1 of FIG. 10 .
- This light-converging device differs from the light-converging device of FIG. 10 in that a transparent layer 7 formed of a second material covers the lens surface 1 b on which the grating 1 G is formed.
- a surface 7 S of the transparent layer 7 does not reflect the protrusions and depressions of the grating 1 G, but has a smooth shape conforming to the lens surface 1 b.
- the second material has a higher refractive index and a lower dispersion than those of the first material.
- a method for producing the light-converging device for example, a step of pushing the lens portion 1 (already having the grating 1 G formed thereon) into a die, a step of filling the interspace between the lens portion 1 and the die with a second material and subjecting it to UV curing, a step of releasing the die from the lens portion 1 , and so on may be consecutively performed.
- Light 2 which enters the light-converging device is refracted by the surface 1 a of the lens portion 1 , and thereafter simultaneously receives refraction and diffraction by the grating 1 G.
- Light 3 going out from the light-converging device is converged on a detection surface 4 . Furthermore, when it is transmitted through the surface 7 S of the transparent layer 7 , it is further refracted so as to be converged on the detection surface 4 .
- the face 1 a and the face 1 b will be described as being planar. It is assumed that the substrate 1 has a refractive index n; the transparent layer 7 has a refractive index n′; and the grating 1 G formed on the face 1 b has a sawteeth-like cross section with a pitch ⁇ .
- Light 2 of the wavelength X is diffracted by the grating 1 G into 1 st -order diffracted light 3 , 2 nd -order diffracted light 311 , and the like.
- the relationship between the diffraction directions and the direction of sawteeth is opposite to that associated with the grating 1 G shown in FIG. 11 . This is because the refractive indices satisfy the relationship n ⁇ n′.
- the incident angle of the light 2 i.e., the angle between itself and the surface normal
- the diffraction angle ⁇ of q th -order diffracted light is given by (eq. 1) above.
- q 0
- the diffraction angle is zero.
- ⁇ 1 st -order diffracted light and ⁇ 2 nd -order diffracted light are also generated on opposite sides of the 0 th -order light 3 ′.
- the pitch ⁇ does not need to have a constant value.
- Non-Patent Document 1 Oyo Hikari Electronics Handbook (published by Shokodo Co., Ltd.), P474-477
- Patent Document 1 Japanese Laid-Open Patent Publication No. 9-127321
- Such conventional light-converging devices and diffraction devices have the following problems.
- FIG. 14 is a graph showing the dispersion characteristics of the substrate 1 of the first conventional example of a light-converging device.
- a curve 5 shown in the graph represents a relationship between the refractive index of an optical material which may be used for the substrate 1 and wavelength.
- the refractive index monotonously increases as the wavelength becomes shorter. Every optical material has such dispersion characteristics.
- n c 1.522983
- n F 1.532271.
- This plastic material is a generic material which is actually used in eyeglasses and the like.
- the refractive index n at the wavelength ⁇ is expressed by (eq. 4) below.
- n n d ⁇ ( ⁇ d ⁇ 2 ⁇ ⁇ 2 )( n d ⁇ 1)/ ⁇ ( ⁇ F ⁇ 2 ⁇ c ⁇ 2 ) (eq. 4)
- the diffraction efficiencies of 0 th -order light, 1 st -order diffracted light, and 2 nd -order diffracted light are represented by a curve 6 ′, a curve 6 , and a curve 6 ′′, respectively.
- the diffraction efficiency (curve 6 ) of 1 st -order diffracted light has a local maximum near the wavelength of 0.51 ⁇ m, but decreases away from the wavelength of 0.50 ⁇ m.
- the diffraction efficiencies of 0 th -order light and 2 nd -order diffracted light increase away from the wavelength of 0.51 ⁇ m. This is because the condition for maximum diffraction efficiency as expressed by (eq. 2) depends on the wavelength and refractive index.
- the numerator ⁇ on the right-hand side of (eq. 2) decreases, and the denominator (n ⁇ 1) increases due to dispersion characteristics.
- the numerator ⁇ on the right-hand side of (eq. 2) increases, and the denominator (n ⁇ 1) decreases.
- the light-converging device shown in FIG. 10 allows only the 1 st -order diffracted light 3 to be converged on the detection surface 4 .
- other diffracted light stray light for 1 st -order diffracted light 3
- the existence of such stray light invites deterioration in the reproduced image.
- FIG. 16 is a graph showing the dispersion characteristics (wavelength dependence characteristics of refractive index) of the materials composing the substrate 1 (first material) and the transparent layer 7 (second material) shown in FIG. 13 .
- the refractive index of the first material monotonously increases as the wavelength becomes shorter (curve 5 ).
- the refractive index of the second material also monotonously increases as the wavelength becomes shorter (curve 5 ′).
- the second material has a higher refractive index and a smaller dispersion than those of the first material. In terms of equations, this is expressed as (eq. 5) and (eq. 6) below.
- the refractive indices of the first material and second material at the C line are n C and n C ′, and that their refractive indices at the F line are n F and n F ′.
- the present invention has been made in order to solve the above problems, and a main objective thereof is to provide an optical element which, while using an optical material that is actually usable, maintains a high diffraction efficiency and suppresses stray light across a broad wavelength region.
- An optical element is an optical element comprising: a first light transmitting layer having a first sawtooth blazed surface, the first sawtooth blazed surface including a plurality of first light-transmitting slopes defining a first blaze angle; a second light transmitting layer having a second sawtooth blazed surface including a plurality of second light-transmitting slopes defining a second blaze angle, the second light transmitting layer being in contact with the first sawtooth blazed surface of the first light transmitting layer, wherein, a tilting direction of the first light-transmitting slopes and a tilting direction of the second light-transmitting slopes are opposite.
- the first light transmitting layer has a lens shape.
- a lens-shaped member is further comprised, wherein, the first light transmitting layer is supported by the lens-shaped member.
- the first light-transmitting slopes on the first sawtooth blazed surface are arranged with an arraying pitch which varies with position on the first light transmitting layer.
- the first light transmitting layer has a refractive index n; the second light transmitting layer has a refractive index n′; the first sawtooth blazed surface has a step height d; the second sawtooth blazed surface has a step height d′; and light being used has an average wavelength ⁇ , ⁇ d′(n′ ⁇ 1) ⁇ d(n ⁇ n′) ⁇ / ⁇ is within a range of ⁇ 0.2 around an integer value.
- the first light transmitting layer has an Abbe number ⁇ ; the second light transmitting layer has an Abbe number ⁇ ′ ; the first sawtooth blazed surface has a step height d; and the second sawtooth blazed surface has a step height d′, the relationship d′/d ⁇ ′/ ⁇ 1 is satisfied.
- a refractive index and dispersion of the first light transmitting layer are higher than a refractive index and dispersion of the second light transmitting layer.
- an amount of offset ⁇ between an arbitrary one of the plurality of first light-transmitting slopes and the second light-transmitting slope through which light having been transmitted through the first light-transmitting slope is transmitted is 5% or less of an arraying pitch ⁇ of the first light-transmitting slope where the first light-transmitting slope is positioned.
- a pitch of the first sawtooth blazed surface is expressed as m ⁇
- a pitch of the second sawtooth blazed surface is expressed as n ⁇ , each of m and n being an integer of 1 or more.
- An optical element is an optical element comprising: a first light transmitting layer having a first sawtooth blazed surface, the first sawtooth blazed surface including a plurality of first light-transmitting slopes defining a first blaze angle; a second light transmitting layer having a second sawtooth blazed surface including a plurality of second light-transmitting slopes defining a second blaze angle, the second light transmitting layer being in contact with the first sawtooth blazed surface of the first light transmitting layer, wherein, when p and q are integers of different signs other than zero, 80% or more of light which is transmitted through the first light transmitting layer is diffracted as p th -order light; and 80% or more of light which is transmitted through the second light transmitting layer is diffracted as p th -order light.
- the first light transmitting layer has an Abbe number ⁇ ; the second light transmitting layer has an Abbe number ⁇ ′; the first sawtooth blazed surface has a step height d; and the second sawtooth blazed surface has a step height d′, the relationship d′/d ⁇ ′/ ⁇ 1 is satisfied.
- a refractive index and dispersion of the first light transmitting layer are higher than a refractive index and dispersion of the second light transmitting layer.
- the first light transmitting layer has a refractive index n; the second light transmitting layer has a refractive index n′; the first sawtooth blazed surface has a step height d; the second sawtooth blazed surface has a step height d′; and light being used has an average wavelength ⁇ , the relationship 0.7 ⁇
- an amount of offset ⁇ of the second sawtooth blazed surface with respect to the first sawtooth blazed surface is 5% or less of a pitch ⁇ of the first sawtooth blazed surface.
- a pitch of the first sawtooth blazed surface is expressed as m ⁇
- a pitch of the second sawtooth blazed surface is expressed as n ⁇ , each of m and n being an integer of 1 or more.
- a high diffraction efficiency can be maintained across a broad wavelength region, and stray light can be suppressed.
- the step heights of two sawteeth cross sections the variation of combinations of transparent materials can be greatly expanded.
- FIG. 1 A cross-sectional view schematically showing the general construction of an optical element according to the present invention.
- FIG. 2 A cross-sectional view showing a first embodiment of an optical element according to the present invention.
- FIG. 3 A cross-sectional view for explaining the diffraction principle of the optical element of the first embodiment.
- FIG. 4 A graph showing dispersion characteristics of a substrate 1 and a transparent layer 7 according to the first embodiment.
- FIG. 5 A graph showing the wavelength dependence of diffraction efficiency of the optical element of the first embodiment.
- FIG. 6 A graph showing the wavelength dependence of diffraction efficiency of the optical element of the first embodiment.
- FIG. 7 A cross-sectional view showing a variant of the first embodiment.
- FIG. 8 A graph showing how the wavelength dependence of diffraction efficiency of the optical element of the first embodiment changes with ⁇ / ⁇ .
- FIG. 9 A cross-sectional view showing a second embodiment of an optical element according to the present invention.
- FIG. 10 A cross-sectional view showing a first conventional example of a light-converging device.
- FIG. 11 A cross-sectional view for explaining the diffraction principle of the light-converging device shown in FIG. 10 .
- FIG. 12 A cross-sectional view showing a second conventional example of a light-converging device.
- FIG. 13 A cross-sectional view for explaining the diffraction principle of the light-converging device shown in FIG. 12 .
- FIG. 14 A graph showing the dispersion characteristics of a material that can be used as a transparent substrate of a light-converging device.
- FIG. 15 A graph showing the wavelength dependence of diffraction efficiency in the first conventional example.
- FIG. 16 A graph showing the dispersion characteristics of two types of materials used in the second conventional example.
- An optical element according to the present invention includes a first light transmitting layer having a first sawtooth blazed surface and a second light transmitting layer having a second sawtooth blazed surface, these being stacked.
- FIG. 1 schematically shows, in cross sections, first sawtooth blazed surface 10 and a second sawtooth blazed surface 20 of an optical element according to the present invention.
- the first sawtooth blazed surface 10 has a plurality of first light-transmitting slopes 12 defining a first blaze angle ⁇
- the second sawtooth blazed surface 20 has a plurality of second light-transmitting slopes 22 defining a second blaze angle ⁇ .
- the first sawtooth blazed surface 10 and the second sawtooth blazed surface 20 are each structured with a periodical array of unit features, each of whose cross section has a triangular shape.
- the height of the unit features with respect to a base plane does not need to be identical between the first sawtooth blazed surface 10 and the second sawtooth blazed surface 20 .
- the height of each unit feature (referred to as the “step height”) of the first sawtooth blazed surface 10 is denoted as “d”
- the step height of the second sawtooth blazed surface 20 is denoted as “d′”.
- the face having a relatively broader area will be referred to as a “light-transmitting slope”, and the angle between this light-transmitting slope and the base plane will be defined as a blaze angle.
- the face other than the “light-transmitting slope” is generally perpendicular to the base plane, and has substantially no effect on light diffraction.
- the aforementioned blaze angle has a value satisfying the relationships of 0° ⁇ 90° and 0° ⁇ 90°, and is an acute angle.
- the normal directions of the first and second light-transmitting slopes 12 and 22 are tilted with respect to the normal direction of the base plane by an angle which is equal to the blaze angle.
- the direction of this tilt will be referred to as “the tilting direction of the light-transmitting slope”, as indicated by thick black arrows in FIG. 1 .
- the tilting directions of the light-transmitting slopes are set exactly opposite between the first sawtooth blazed surface 10 and the second sawtooth blazed surface 20 .
- FIG. 1 illustrates a case where the base plane is planar
- the base plane may be curved.
- the blaze angles ⁇ and ⁇ do not need to have constant values across the base plane, but may vary with position.
- the first sawtooth blazed surface 10 is formed on a first light transmitting layer
- the second sawtooth blazed surface 20 is formed on a second light transmitting layer which is in contact with the first sawtooth blazed surface 10 .
- the first light transmitting layer does not need to be a plate member having a uniform thickness, but may be a substrate having a lens shape. Moreover, the first light transmitting layer may be supported on another transparent member.
- the optical element of the present embodiment is a light-converging device.
- FIG. 2 is referred to.
- the light-converging device shown in FIG. 2 is produced from two types of transparent materials (plastic, UV-curing resin, or the like) having different refractive indices and different dispersion characteristics.
- a substrate 1 which is composed of a first material has a lens shape, and has a light-incident face 1 a and a light-outgoing face 1 b.
- a grating 1 G is formed on the light-outgoing surface 1 b of the substrate 1 , the grating 1 G having a sawteeth-shaped cross section.
- the substrate 1 functions as a “first light transmitting layer”.
- the surfaces 1 a and 1 b of the substrate 1 constitute a sphere or non-sphere, with its center axis being an optical axis L.
- the plurality of light-transmitting slopes composing the grating 1 G each have an annular shape whose center axis is the optical axis L, and they are arrayed in radial directions.
- steps of the grating are formed in concentric circles centered around the optical axis.
- a transparent layer 7 which is composed of a second material is formed on the light-outgoing surface 1 b of the substrate 1 on which the grating 1 G is formed, and functions as a “second light transmitting layer”.
- a grating 7 G is formed on a surface 7 S of the transparent layer 7 , the grating 7 G having a “tilting direction” which is opposite to the “tilting direction” of the grating 1 G.
- the plurality of light-transmitting slopes composing the grating 7 G each have an annular shape whose center axis is the optical axis L, and they are arrayed in radial directions.
- each “tilting direction” shown in FIG. 1 either heads toward the optical axis L, or generally radially extends from the optical axis.
- the “tilting directions” of the two stacked gratings 1 G and 7 G are in an exactly opposite relationship, it is meant that exactly opposite “tilting directions” exist at positions of upper-lower proximity (i.e., corresponding positions), and the relationship between “tilting directions” at different positions may not necessarily be exactly opposite.
- the edge positions (lower-blade positions) of sawteeth are aligned.
- the refractive index and dispersion of the second material in the present embodiment are lower than the refractive index and dispersion of the first material.
- the transparent layer 7 is formed so that its thickness is as thin as possible.
- the light-converging device of the present embodiment is produced in the follow manner, for example.
- the substrate 1 is provided, which has been molded so as to have a lens shape with a grating formed on a surface thereof.
- the substrate 1 is formed of a first material.
- the substrate 1 is inserted into a die (not shown) which has a molding face having the shape of a lens with a grating, and the interspace between the substrate 1 and the die is filled with a second material.
- the second material is released from the die. As a result, the light-converging device shown in FIG. 2 is obtained.
- the light 2 After light 2 entering the light-converging device of the present embodiment is refracted from the surface 1 a of the substrate 1 , the light 2 simultaneously receives refraction and diffraction at the surface 1 b of the substrate 1 on which the grating 1 G is formed. Thereafter, the light 2 simultaneously receives refraction and diffraction at the surface 7 S of the transparent layer 7 on which the grating 7 G is formed, so as to be converged on a detection surface 4 as light 3 .
- FIG. 3 illustrates each face as being planar, while also assuming that the light 2 perpendicularly enters the face.
- the substrate 1 has a refractive index n; the transparent layer 7 has a refractive index n′; the grating 1 G formed on the face 1 b has a pitch A and a cross-sectional step height d; the grating 7 G formed on the face 7 S has a pitch ⁇ and a cross-sectional step height d′.
- the wavefront of the light which is transmitted through the gratings 1 G and 7 G will be in the form of sawteeth with the pitch ⁇
- the difference ⁇ (phase difference) at the wavefront is expressed by (eq. 7) below.
- ⁇ d ′( n′ ⁇ 1) ⁇ d ( n ⁇ n ′) (eq. 7)
- n and n′ are to be each separated into a portion (first term) which does not depend on the wavelength ⁇ and a portion (second term) which depends on the wavelength ⁇ , approximations by the following two equations are possible.
- first term n 0 ⁇ ( ⁇ 0 ) ⁇
- q is an integer.
- condition under which the diffraction efficiency reaches maximum when ⁇ ⁇ 0 and under which the amount of change of
- with respect to ⁇ becomes small i.e., a condition under which a high diffraction light efficiency is maintained and stray light is suppressed across a broad wavelength region
- ⁇ d ′( n 0 ′ ⁇ 1) ⁇ d ( n 0 ⁇ n 0 ′) ⁇ / ⁇ q (eq. 12); and ⁇ d′ ⁇ ′ ⁇ d ( ⁇ ′) ⁇ / q ⁇ 0 ⁇ 0 (eq. 13).
- (eq. 13) is a conditional expression for making the amount of change of
- the number of step height parameters is now increased to two, i.e., d and d′, and therefore there can be a large number of combinations of optical materials that simultaneously satisfy (eq. 12) and (eq. 13).
- the Abbe number is a value which is in proportion with an inverse of each of ⁇ and ⁇ ′. Therefore, assuming that Abbe numbers corresponding to ⁇ and ⁇ ′ are ⁇ and ⁇ ′, (eq. 13) can be replaced by (eq. 14) below.
- the incident angle of the light 2 shown in FIG. 3 i.e., the angle between itself and the surface normal
- the diffraction angle ⁇ of q th -order diffracted light is given by (eq. 1) above.
- ⁇ 1 st -order diffracted light and ⁇ 2 nd -order diffracted light are also generated on opposite sides of the 0 th -order light 3 ′.
- the gratings have sawteeth-like cross sections, diffracted light of any ⁇ order is weakened, whereas diffracted light of any + order is intensified.
- the grating cross sections may be in the form of steps inscribed within the illustrated sawteeth shape, or may be simple protrusions and depressions.
- the pitch ⁇ does not need to have a constant value within the plane.
- d
- d′
- p th -order light is diffracted by the grating 1 G mainly at the wavelength of ⁇ 0 ;
- q th -order light is diffracted by the grating 7 G mainly at the wavelength of ⁇ 0 ′;
- (p+q) th -order light is diffracted by the entire gratings 1 G and 7 G at wavelengths in the neighborhood from ⁇ 0 to ⁇ 0 ′.
- the wavelengths ⁇ 0 and ⁇ 0 ′ are near, they do not need to be equal.
- FIG. 4 is a graph showing the dispersion characteristics of the first material composing the substrate 1 and the second material composing the transparent layer 7 of the light-converging device of the present embodiment.
- the refractive index of the first material monotonously increases as the wavelength becomes shorter (curve 5 ).
- the refractive index of the second material also monotonously increases as the wavelength becomes shorter (curve 5 ′).
- the second material has a lower refractive index and a smaller dispersion than those of the first material. Therefore, assuming that the first material and the second material have refractive indices n C and n C ′ at the C line, and refractive indices n F and n F ′ at the F line, the following two inequalities hold true.
- (eq. 17) means n 0 >n 0 ′
- (eq. 18) means ⁇ > ⁇ ′. Therefore, from (n 0 ′ ⁇ 1)>1 and (n 0 ⁇ n 0 ′)>1, there are numerous d and d′ that satisfy (eq. 12). Also from ( ⁇ ′)>0, there are numerous d and d′ that satisfy d′/d ⁇ ( ⁇ ′)/ ⁇ ′, which is a transformation of (eq. 13). Therefore, under the conditions of (eq. 17) and (eq. 18), it is easy to satisfy (eq. 12) and (eq. 13), and the absolute value of the left-hand side of (eq. 13) can be set large with a certain amount of freedom.
- an optical material having a high refractive index has a large dispersion
- an optical material having a small dispersion has a small refractive index. Therefore, there are many combinations of optical materials that simultaneously satisfy (eq. 17) and (eq. 18), resulting in a great diversity of material combinations which is beyond comparison with conventional examples.
- FIG. 5 shows the wavelength dependence of diffraction efficiency of each diffracted light in the optical element of the present embodiment.
- the grating step height d is 3.00 ⁇ m
- the step height d′ is 2.31 ⁇ m.
- the refractive index n at the wavelength ⁇ is approximated according to (eq. 4).
- 1 st -order diffracted light 6 has a local maximum near the wavelength of 0.60 ⁇ m, and the diffraction efficiency is slightly decreased in other wavelength ranges. This decrease is much smaller than in the conventional examples. Therefore, the diffraction efficiencies (curves 6 ′, 6 ′′) of 0 th -order light and 2 nd -order diffracted light, which are stray light, are kept very low. Furthermore, the aforementioned refractive index and Abbe number values pertain to plastic materials and UV resin materials, which are already at a practical level. Thus, a great improvement effect can be obtained with realistic material combinations.
- Other manners of diffraction are also permissible. For example, FIG.
- the step height d of the grating 1 G can be made smaller; and as the difference in dispersion between the substrate 1 and the transparent layer 7 ( ⁇ ′) increases and the step height d of the grating 1 G increases, it becomes possible to obtain a high diffraction efficiency in a broader wavelength range.
- An optimum value for the step height d′ of the grating 7 G is substantially uniquely determined once the other conditions (step height d of the grating 1 G and the refractive index and Abbe number of each material) are determined.
- a refraction lens when formed of a material having a high refractive index, a refraction lens can realize a short optical path length and a high NA.
- a material having a low dispersion makes it possible to suppress defocusing associated with difference in wavelengths.
- commonly-available optical materials, whether glass or plastic do not reconcile both a high refractive index and low dispersion.
- the dispersive power of refraction (wavelength dependence of refraction angle) can be canceled, by design, due to the dispersive power of diffraction (wavelength dependence of diffraction angle). As a result, it is not necessary to be concerned with the reconciliation of a high refractive index and low dispersion.
- the substrate 1 is preferably formed of a plastic material
- the transparent layer 7 is preferably formed of a UV-curing resin.
- UV-curing resins are low refractive index/low dispersion materials which suit the conditions of the present embodiment.
- plastic materials boast a certain degree of variations, and even at present are capable of guaranteeing the optical performance of FIG. 5 .
- hitherto-performed plastic material development activities in their efforts to reconcile both a high refractive index and low dispersion (high Abbe number), have tended to disregard high dispersion materials while also compromising on the realization of a high refractive index; however, once the low dispersion limitation is removed, the situation will greatly change.
- development activities of optical materials can be shifted from the reconciliation of a high refractive index and low dispersion to the reconciliation of a high refractive index and high dispersion, and to the reconciliation of a low refractive index and low dispersion, which would be more logical and natural in terms of physical properties.
- there is a great impact an effect of curtailing losses associated with material development) on the entire business.
- FIG. 7 shows a variant of the present embodiment.
- the edge positions of sawteeth cross sections are offset by ⁇ between the grating 1 G and the grating 7 G.
- FIG. 8 shows the wavelength dependence of diffraction efficiency in the case where a parameter ⁇ / ⁇ is varied under the same condition as in FIG. 5 . In order to maintain a high performance, it is preferable to satisfy
- gratings ( 1 G, 7 G) are formed on only one face ( 1 b ) of a lens in the present embodiment, similar structures may be formed on both faces ( 1 a, 1 b ) of the lens.
- the optical element of the present embodiment has the same construction as that of the optical element of the first embodiment, except for the pitch and step height of the grating 7 G which is formed on the surface 7 S of the transparent layer 7 .
- FIG. 9 is a cross-sectional view showing diffraction at the faces 1 b and 7 S of the optical element of the present embodiment.
- the faces 1 b and 7 S are planar, and that light 2 perpendicularly enters the face 1 b.
- the substrate 1 has a refractive index n; the transparent layer 7 has a refractive index n′; the grating 1 G formed on the face 1 b has a pitch ⁇ and a cross-sectional step height d; and the grating 7 G formed on the face 7 S has a pitch ⁇ /2 and a cross-sectional step height d′/2.
- the values of d and d′ are the same as the values in the first embodiment.
- the pitch and step height conditions of the grating 1 G of the present embodiment have not changed from those of the grating 1 G of the first embodiment. Therefore (eq. 15) holds true, and p th -order light is diffracted.
- the step height is reduced to half, and therefore q/2 nd -order light is diffracted based on (eq. 16), assuming that q is an even number.
- the construction of the present embodiment will make it possible to reduce the grating step height, and therefore the manufacturing of a die which is necessary for forming the grating 7 G (cutting/grinding step, etc.) is facilitated. Due to machining errors, the actually-produced step will not be perpendicular to but tilted with respect to the base plane, this machining error leading to light scattering. An effect of reducing light scattering is obtained by reducing the grating step height.
- the pitch and step height of the grating 7 G may be multiplied by an integer, or divided by an integer.
- the pitch and step height of the grating 1 G may be multiplied by an integer, or divided by an integer, or any construction that combines these may be adopted.
- the relationship between the pitches of the gratings 1 G and 7 G in the present embodiment only needs to satisfy m ⁇ for the grating 1 G and n ⁇ for the grating 7 G, assuming that m and n are integers of 1 or more.
- An optical element according to the present invention operates as a light-converging device or a diffraction device, and is able to maintain a high diffraction efficiency across a broad wavelength region. Therefore, the optical element according to the present invention is suitably used for in an optical pickup having an imaging device and a multi-wavelength light source, or the like.
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Abstract
Description
- The present invention relates to an optical element, an in particular to a light-converging device for converging light, such as a lens, and a diffraction device for diffracting light, such as a grating.
- A blazed grating is an optical element having a sawtooth blazed surface, which includes a plurality of light-transmitting slopes. A light-converging device having a blazed grating on its surface is disclosed in Non-Patent
Document 1 andPatent Document 1. - With reference to
FIG. 10 andFIG. 11 , a conventional example of a light-converging device will be described. - The light-converging device shown in
FIG. 10 comprises asubstrate 1, which is formed of a transparent material such as plastic and hassurfaces 1 a and 1 b. Thesubstrate 1 has a lens shape which is symmetric around its optical axis, and has agrating 1G formed on thesurface 1 b thereof, thegrating 1G having a sawteeth-shaped cross section. Thelens surfaces 1 a and 1 b of the light-converging device constitute a sphere or non-sphere, with its center axis being the optical axis L. On thesurface 1 b, the plurality of light-transmitting slopes composing thegrating 1G each have an annular shape whose center axis is the optical axis L, and are arrayed in a radial direction. Thus, steps of the grating are formed in concentric circles centered around the optical axis. -
Light 2 which enters the substrate 71 is refracted by the surface 1 a, and thereafter simultaneously receives refraction and diffraction at thesurface 1 b on which thegrating 1G is formed. Light 3 going out from the light-converging device is converged on adetection surface 4. - Next, with reference to
FIG. 11 , the principle of diffraction by thelens surface 1 b of the light-converging device shown inFIG. 10 will be described. For simplicity,FIG. 11 illustrates thesurface 1 b as being planar. - The device shown in
FIG. 11 has asubstrate 1 having agrating 1G formed on asurface 1 b thereof, thegrating 1G having a sawteeth-like cross section. Thesubstrate 1 has a refractive index n. Thegrating 1G has a pitch Λ. The grating 1G diffractslight 2 of the wavelength λ, thus generating diffracted light such as 1st-order diffractedlight 3 and 2nd-order diffractedlight 3″. - For simplicity, assuming that the incident angle of the light 2 (i.e., the angle between the normal of the rear face of the
substrate 1 and the axis of the light 2) is zero, the diffraction angle θ of the qth-order diffracted light (i.e., the angle between the normal and the diffracted light) is expressed by (eq. 1) below.
sin θ=qλ/Λ (eq. 1) - Herein, q is an integer representing the order of the diffracted light.
- In the case of 0th-
order light 3′, q=0, and the diffraction angle θ is zero. Generally speaking, −1st-order diffracted light and −2nd-order diffracted light are also generated on opposite sides of the 0th-order light 3′. However, since thegrating 1G has a sawteeth-like cross section, diffracted light of any − order will be weakened, whereas diffracted light of any + order will be intensified. When a step height d in the cross section of thegrating 1G satisfies (eq. 2) below, the diffraction efficiency of the qth-order diffracted light becomes maximum.
d=|qλ/(n−1)| (eq. 2) - Herein, n is the refractive index of the substrate 1 (transparent medium), and λ is the wavelength of the
incident light 2. Note that the pitch Λ does not need to be constant across the surface of thesubstrate 1, and the pitch Λ may be a mathematical function of position on thesubstrate 1. By varying the pitch Λ as a mathematical function of position, it becomes possible to adjust the diffraction angle in accordance with the outgoing position from thesubstrate 1. By doing so, and assisted also by the spherical shape of thesurfaces 1 a and 1 b, etc., it becomes possible to converge thediffracted light 3 at one point. - Next, with reference to
FIG. 12 andFIG. 13 , another conventional technique will be described. This conventional technique has a construction as taught inPatent Document 1. - A light-converging device shown in
FIG. 12 is formed of two types of transparent media having different refractive indices and dispersion characteristics (plastic, UV-curing resin, or the like). Alens portion 1 is formed of a first material, and has a lens shape. Agrating 1G having a sawteeth-like cross section is formed on asurface 1 b, thus presenting a construction similar to that of thelens 1 ofFIG. 10 . This light-converging device differs from the light-converging device ofFIG. 10 in that atransparent layer 7 formed of a second material covers thelens surface 1 b on which thegrating 1G is formed. Asurface 7S of thetransparent layer 7 does not reflect the protrusions and depressions of thegrating 1G, but has a smooth shape conforming to thelens surface 1 b. - The second material has a higher refractive index and a lower dispersion than those of the first material. As a method for producing the light-converging device, for example, a step of pushing the lens portion 1 (already having the
grating 1G formed thereon) into a die, a step of filling the interspace between thelens portion 1 and the die with a second material and subjecting it to UV curing, a step of releasing the die from thelens portion 1, and so on may be consecutively performed. -
Light 2 which enters the light-converging device is refracted by the surface 1 a of thelens portion 1, and thereafter simultaneously receives refraction and diffraction by thegrating 1G. Light 3 going out from the light-converging device is converged on adetection surface 4. Furthermore, when it is transmitted through thesurface 7S of thetransparent layer 7, it is further refracted so as to be converged on thedetection surface 4. - Next, with reference to
FIG. 13 , the principle of diffraction by the light-converging device shown inFIG. 12 will be described. Again, for simplicity, the face 1 a and theface 1 b will be described as being planar. It is assumed that thesubstrate 1 has a refractive index n; thetransparent layer 7 has a refractive index n′; and thegrating 1G formed on theface 1 b has a sawteeth-like cross section with a pitch Λ. - Light 2 of the wavelength X is diffracted by the grating 1G into 1st-order diffracted
light 3, 2nd-order diffracted light 311, and the like. The relationship between the diffraction directions and the direction of sawteeth is opposite to that associated with thegrating 1G shown inFIG. 11 . This is because the refractive indices satisfy the relationship n<n′. - Assuming that the incident angle of the light 2 (i.e., the angle between itself and the surface normal) is zero, the diffraction angle θ of qth-order diffracted light (i.e., the angle between itself and the surface normal) is given by (eq. 1) above. In the case of 0th-
order light 3′, q=0 and the diffraction angle is zero. Generally speaking, −1st-order diffracted light and −2nd-order diffracted light are also generated on opposite sides of the 0th-order light 3′. However, by adopting a sawteeth-like grating cross section, diffracted light of any − order will be weakened, whereas diffracted light of any + order will be intensified. When a depth d of the grating cross section satisfies (eq. 3) below, the diffraction efficiency of the qth-order diffracted light becomes maximum.
d=|qλ/(n′−n)| (eq. 3) - Note that the pitch Λ does not need to have a constant value. By ensuring that the pitch Λ is a mathematical function of position, it becomes possible to adjust the diffraction angle, and assisted also by the spherical shape of the
surfaces 1 a and 1 b, etc., it becomes possible to converge thediffracted light 3 at one point. - [Non-Patent Document 1] Oyo Hikari Electronics Handbook (published by Shokodo Co., Ltd.), P474-477
- [Patent Document 1] Japanese Laid-Open Patent Publication No. 9-127321
- Such conventional light-converging devices and diffraction devices have the following problems.
-
FIG. 14 is a graph showing the dispersion characteristics of thesubstrate 1 of the first conventional example of a light-converging device. Acurve 5 shown in the graph represents a relationship between the refractive index of an optical material which may be used for thesubstrate 1 and wavelength. As can be seen fromFIG. 14 , in the visible light region, the refractive index monotonously increases as the wavelength becomes shorter. Every optical material has such dispersion characteristics. For example, in the case of ZEONEX, a refractive index at the C line (wavelength λc=0.6563 μm) is nc=1.522983; and a refractive index at the F line (wavelength λF=0.4861 μm) is nF=1.532271. In the case of polycarbonate, a refractive index at the C line is nc=1.578401; and a refractive index at the F line is nF=1.597809. -
FIG. 15 is a graph showing a relationship between diffraction efficiency and wavelength in the case where thesubstrate 1 is produced from a plastic material whose refractive index at the d line (wavelength λd=0.5876 μm) is nd=1.60 and whose Abbe number is v=33. This plastic material is a generic material which is actually used in eyeglasses and the like. The grating has a structure as shown inFIG. 11 , where step height d=0.83 μm. By approximation, the refractive index n at the wavelength λ is expressed by (eq. 4) below.
n=n d−(λd −2−λ−2)(n d−1)/ν(λF −2−λc −2) (eq. 4) - In the graph of
FIG. 15 , the diffraction efficiencies of 0th-order light, 1st-order diffracted light, and 2nd-order diffracted light are represented by acurve 6′, acurve 6, and acurve 6″, respectively. - The diffraction efficiency (curve 6) of 1st-order diffracted light has a local maximum near the wavelength of 0.51 μm, but decreases away from the wavelength of 0.50 μm. The diffraction efficiencies of 0th-order light and 2nd-order diffracted light increase away from the wavelength of 0.51 μm. This is because the condition for maximum diffraction efficiency as expressed by (eq. 2) depends on the wavelength and refractive index.
- As the wavelength becomes smaller than the optimum value (0.51 μm) for 1st-order diffraction, the numerator λ on the right-hand side of (eq. 2) decreases, and the denominator (n−1) increases due to dispersion characteristics. On the other hand, as the wavelength becomes greater than the optimum value (0.51 μm) for 1st-order diffraction, the numerator λ on the right-hand side of (eq. 2) increases, and the denominator (n−1) decreases. Thus, as the wavelength shifts away from the value at which the efficiency of 1st-order diffraction is maximum, both the refractive index (denominator) and the wavelength (numerator) change so that the diffraction efficiency drastically decreases.
- Therefore, as for light of a specific wavelength, the light-converging device shown in
FIG. 10 allows only the 1st-order diffracted light 3 to be converged on thedetection surface 4. However, as for light of any other wavelength, other diffracted light (stray light for 1st-order diffracted light 3) such as 0th-order light 3′ and 2nd-order diffracted light 3″ will occur. When the light-converging device is used as a camera lens, the existence of such stray light invites deterioration in the reproduced image. - The light-converging device shown in
FIG. 12 andFIG. 13 can solve such problems.FIG. 16 is a graph showing the dispersion characteristics (wavelength dependence characteristics of refractive index) of the materials composing the substrate 1 (first material) and the transparent layer 7 (second material) shown inFIG. 13 . - The refractive index of the first material monotonously increases as the wavelength becomes shorter (curve 5). The refractive index of the second material also monotonously increases as the wavelength becomes shorter (
curve 5′). The second material has a higher refractive index and a smaller dispersion than those of the first material. In terms of equations, this is expressed as (eq. 5) and (eq. 6) below.
n F′>nF and nC′>nC (eq. 5)
(n C ′−n C)/(n F ′−n F)>1 (eq. 6) - Herein, it is assumed that the refractive indices of the first material and second material at the C line are nC and nC′, and that their refractive indices at the F line are nF and nF′.
- If (eq. 5) and (eq. 6) can be satisfied, deviation from the condition for maximum diffraction efficiency as expressed by (eq. 3) can be alleviated. In other words, when the wavelength becomes smaller than the optimum value due to the dispersion characteristics of the
substrate 1 and thetransparent layer 7, the numerator λ on the right-hand side of (eq. 3) will decrease, but the denominator (n′−n) will also decrease. On the other hand, when the wavelength becomes greater than the optimum value, the numerator λ on the right-hand side of (eq. 3) will increase, but the denominator (n′−n) will also increase. In either case, deviation from the condition for maximum diffraction efficiency is alleviated. - However, generally speaking, dispersion increases as the refractive index increases. In other words, an optical material having a relatively high refractive index has a relatively large dispersion, and an optical material having a relatively small dispersion has a relatively small refractive index. Therefore, there are very few combinations of optical materials that simultaneously satisfy (eq. 5) and (eq. 6). If at all there is, the effect will be small (e.g., the left-hand side of (eq. 6) becoming closer to 1). Therefore, in actuality, the light-converging device shown in
FIG. 12 has not been put to practical use. - The present invention has been made in order to solve the above problems, and a main objective thereof is to provide an optical element which, while using an optical material that is actually usable, maintains a high diffraction efficiency and suppresses stray light across a broad wavelength region.
- An optical element according to the present invention is an optical element comprising: a first light transmitting layer having a first sawtooth blazed surface, the first sawtooth blazed surface including a plurality of first light-transmitting slopes defining a first blaze angle; a second light transmitting layer having a second sawtooth blazed surface including a plurality of second light-transmitting slopes defining a second blaze angle, the second light transmitting layer being in contact with the first sawtooth blazed surface of the first light transmitting layer, wherein, a tilting direction of the first light-transmitting slopes and a tilting direction of the second light-transmitting slopes are opposite.
- In a preferred embodiment, the first light transmitting layer has a lens shape.
- In a preferred embodiment, a lens-shaped member is further comprised, wherein, the first light transmitting layer is supported by the lens-shaped member.
- In a preferred embodiment, the first light-transmitting slopes on the first sawtooth blazed surface are arranged with an arraying pitch which varies with position on the first light transmitting layer.
- In a preferred embodiment, when the first light transmitting layer has a refractive index n; the second light transmitting layer has a refractive index n′; the first sawtooth blazed surface has a step height d; the second sawtooth blazed surface has a step height d′; and light being used has an average wavelength λ, {d′(n′−1)−d(n−n′)}/λ is within a range of ±0.2 around an integer value.
- In a preferred embodiment, when the first light transmitting layer has an Abbe number ν; the second light transmitting layer has an Abbe number ν′ ; the first sawtooth blazed surface has a step height d; and the second sawtooth blazed surface has a step height d′, the relationship d′/d<ν′/ν−1 is satisfied.
- In a preferred embodiment, a refractive index and dispersion of the first light transmitting layer are higher than a refractive index and dispersion of the second light transmitting layer.
- In a preferred embodiment, an amount of offset δ between an arbitrary one of the plurality of first light-transmitting slopes and the second light-transmitting slope through which light having been transmitted through the first light-transmitting slope is transmitted is 5% or less of an arraying pitch Λ of the first light-transmitting slope where the first light-transmitting slope is positioned.
- In a preferred embodiment, when a pitch of the first sawtooth blazed surface is expressed as m×Λ, a pitch of the second sawtooth blazed surface is expressed as n×Λ, each of m and n being an integer of 1 or more.
- An optical element according to the present invention is an optical element comprising: a first light transmitting layer having a first sawtooth blazed surface, the first sawtooth blazed surface including a plurality of first light-transmitting slopes defining a first blaze angle; a second light transmitting layer having a second sawtooth blazed surface including a plurality of second light-transmitting slopes defining a second blaze angle, the second light transmitting layer being in contact with the first sawtooth blazed surface of the first light transmitting layer, wherein, when p and q are integers of different signs other than zero, 80% or more of light which is transmitted through the first light transmitting layer is diffracted as pth-order light; and 80% or more of light which is transmitted through the second light transmitting layer is diffracted as pth-order light.
- In a preferred embodiment, when the first light transmitting layer has an Abbe number ν; the second light transmitting layer has an Abbe number ν′; the first sawtooth blazed surface has a step height d; and the second sawtooth blazed surface has a step height d′, the relationship d′/d<ν′/ν−1 is satisfied.
- In a preferred embodiment, a refractive index and dispersion of the first light transmitting layer are higher than a refractive index and dispersion of the second light transmitting layer.
- In a preferred embodiment, the relationship p+q=1 is satisfied.
- In a preferred embodiment, when the first light transmitting layer has a refractive index n; the second light transmitting layer has a refractive index n′; the first sawtooth blazed surface has a step height d; the second sawtooth blazed surface has a step height d′; and light being used has an average wavelength λ, the relationship 0.7λ<|(n−n′)d/p|<1.2λ; and the relationship 0.7λ<|(n′−1)d′/q|<1.2λ are satisfied.
- In a preferred embodiment, an amount of offset δ of the second sawtooth blazed surface with respect to the first sawtooth blazed surface is 5% or less of a pitch Λ of the first sawtooth blazed surface.
- In a preferred embodiment, when a pitch of the first sawtooth blazed surface is expressed as m×Λ, a pitch of the second sawtooth blazed surface is expressed as n×Λ, each of m and n being an integer of 1 or more.
- According to the present invention, owing to a novel arrangement of two stacked gratings, a high diffraction efficiency can be maintained across a broad wavelength region, and stray light can be suppressed. Moreover, by adjusting the step heights of two sawteeth cross sections, the variation of combinations of transparent materials can be greatly expanded.
- [
FIG. 1 ] A cross-sectional view schematically showing the general construction of an optical element according to the present invention. - [
FIG. 2 ] A cross-sectional view showing a first embodiment of an optical element according to the present invention. - [
FIG. 3 ] A cross-sectional view for explaining the diffraction principle of the optical element of the first embodiment. - [
FIG. 4 ] A graph showing dispersion characteristics of asubstrate 1 and atransparent layer 7 according to the first embodiment. - [
FIG. 5 ] A graph showing the wavelength dependence of diffraction efficiency of the optical element of the first embodiment. - [
FIG. 6 ] A graph showing the wavelength dependence of diffraction efficiency of the optical element of the first embodiment. - [
FIG. 7 ] A cross-sectional view showing a variant of the first embodiment. - [
FIG. 8 ] A graph showing how the wavelength dependence of diffraction efficiency of the optical element of the first embodiment changes with δ/Λ. - [
FIG. 9 ] A cross-sectional view showing a second embodiment of an optical element according to the present invention. - [
FIG. 10 ] A cross-sectional view showing a first conventional example of a light-converging device. - [
FIG. 11 ] A cross-sectional view for explaining the diffraction principle of the light-converging device shown inFIG. 10 . - [
FIG. 12 ] A cross-sectional view showing a second conventional example of a light-converging device. - [
FIG. 13 ] A cross-sectional view for explaining the diffraction principle of the light-converging device shown inFIG. 12 . - [
FIG. 14 ] A graph showing the dispersion characteristics of a material that can be used as a transparent substrate of a light-converging device. - [
FIG. 15 ] A graph showing the wavelength dependence of diffraction efficiency in the first conventional example. - [
FIG. 16 ] A graph showing the dispersion characteristics of two types of materials used in the second conventional example. - 1 substrate (first light transmitting layer)
- 1G grating (first sawtooth blazed surface)
- 1 a, 1 b surface of substrate
- 2 incident light
- 3 1st-order diffracted light
- 3′ 0th-order light
- 3″ 2nd-order diffracted light
- 4 detection surface
- 7 transparent layer (second light transmitting layer)
- 7S surface of transparent layer
- 7G grating (second sawtooth blazed surface)
- 10 first sawtooth blazed surface
- 12 first light-transmitting slope
- 20 second sawtooth blazed surface
- 22 second light-transmitting slope
- L optical axis
- α a first blaze angle
- β second blaze angle
- An optical element according to the present invention includes a first light transmitting layer having a first sawtooth blazed surface and a second light transmitting layer having a second sawtooth blazed surface, these being stacked. First, with reference to
FIG. 1 , the outline of the construction of an optical element according to the present invention will be described. -
FIG. 1 schematically shows, in cross sections, first sawtooth blazedsurface 10 and a second sawtooth blazedsurface 20 of an optical element according to the present invention. The first sawtooth blazedsurface 10 has a plurality of first light-transmittingslopes 12 defining a first blaze angle α, whereas the second sawtooth blazedsurface 20 has a plurality of second light-transmittingslopes 22 defining a second blaze angle β. - The first sawtooth blazed
surface 10 and the second sawtooth blazedsurface 20 are each structured with a periodical array of unit features, each of whose cross section has a triangular shape. The height of the unit features with respect to a base plane does not need to be identical between the first sawtooth blazedsurface 10 and the second sawtooth blazedsurface 20. In the example shown, the height of each unit feature (referred to as the “step height”) of the first sawtooth blazedsurface 10 is denoted as “d”, whereas the step height of the second sawtooth blazedsurface 20 is denoted as “d′”. - In the present specification, between the two faces constituting the surface of each unit feature, the face having a relatively broader area will be referred to as a “light-transmitting slope”, and the angle between this light-transmitting slope and the base plane will be defined as a blaze angle. Between the two faces constituting the surface of each unit feature, the face other than the “light-transmitting slope” is generally perpendicular to the base plane, and has substantially no effect on light diffraction.
- The aforementioned blaze angle has a value satisfying the relationships of 0°<α<90° and 0°<β<90°, and is an acute angle. The normal directions of the first and second light-transmitting
12 and 22 are tilted with respect to the normal direction of the base plane by an angle which is equal to the blaze angle. In the present specification, the direction of this tilt will be referred to as “the tilting direction of the light-transmitting slope”, as indicated by thick black arrows inslopes FIG. 1 . In the present invention, the tilting directions of the light-transmitting slopes are set exactly opposite between the first sawtooth blazedsurface 10 and the second sawtooth blazedsurface 20. - Although
FIG. 1 illustrates a case where the base plane is planar, the base plane may be curved. Moreover, the blaze angles α and β do not need to have constant values across the base plane, but may vary with position. - Although not explicitly shown in
FIG. 1 , the first sawtooth blazedsurface 10 is formed on a first light transmitting layer, whereas the second sawtooth blazedsurface 20 is formed on a second light transmitting layer which is in contact with the first sawtooth blazedsurface 10. The first light transmitting layer does not need to be a plate member having a uniform thickness, but may be a substrate having a lens shape. Moreover, the first light transmitting layer may be supported on another transparent member. - Through descriptions of preferred embodiments of the present invention, it will be explained what sort of functions and effects are exhibited by an optical element according to the present invention adopting the aforementioned construction.
- Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings.
- With reference to
FIG. 2 toFIG. 8 , a first embodiment of the optical element according to the present invention will be described. The optical element of the present embodiment is a light-converging device. - First,
FIG. 2 is referred to. The light-converging device shown inFIG. 2 is produced from two types of transparent materials (plastic, UV-curing resin, or the like) having different refractive indices and different dispersion characteristics. Asubstrate 1 which is composed of a first material has a lens shape, and has a light-incident face 1 a and a light-outgoing face 1 b. A grating 1G is formed on the light-outgoingsurface 1 b of thesubstrate 1, the grating 1G having a sawteeth-shaped cross section. Thesubstrate 1 functions as a “first light transmitting layer”. - The
surfaces 1 a and 1 b of thesubstrate 1 constitute a sphere or non-sphere, with its center axis being an optical axis L. On thesurface 1 b, the plurality of light-transmitting slopes composing the grating 1G each have an annular shape whose center axis is the optical axis L, and they are arrayed in radial directions. Thus, steps of the grating are formed in concentric circles centered around the optical axis. - A
transparent layer 7 which is composed of a second material is formed on the light-outgoingsurface 1 b of thesubstrate 1 on which the grating 1G is formed, and functions as a “second light transmitting layer”. A grating 7G is formed on asurface 7S of thetransparent layer 7, the grating 7G having a “tilting direction” which is opposite to the “tilting direction” of the grating 1G. On thesurface 7S, too, the plurality of light-transmitting slopes composing the grating 7G each have an annular shape whose center axis is the optical axis L, and they are arrayed in radial directions. - In the present embodiment, each “tilting direction” shown in
FIG. 1 either heads toward the optical axis L, or generally radially extends from the optical axis. Thus, in the present embodiment, when the “tilting directions” of the two 1G and 7G are in an exactly opposite relationship, it is meant that exactly opposite “tilting directions” exist at positions of upper-lower proximity (i.e., corresponding positions), and the relationship between “tilting directions” at different positions may not necessarily be exactly opposite.stacked gratings - Between the grating 1G and the grating 7G, the edge positions (lower-blade positions) of sawteeth are aligned. The refractive index and dispersion of the second material in the present embodiment are lower than the refractive index and dispersion of the first material. Preferably, the
transparent layer 7 is formed so that its thickness is as thin as possible. - The light-converging device of the present embodiment is produced in the follow manner, for example.
- First, the
substrate 1 is provided, which has been molded so as to have a lens shape with a grating formed on a surface thereof. Thesubstrate 1 is formed of a first material. Next, thesubstrate 1 is inserted into a die (not shown) which has a molding face having the shape of a lens with a grating, and the interspace between thesubstrate 1 and the die is filled with a second material. After curing the second material by a method such as UV curing or thermosetting, the second material is released from the die. As a result, the light-converging device shown inFIG. 2 is obtained. - After
light 2 entering the light-converging device of the present embodiment is refracted from the surface 1 a of thesubstrate 1, thelight 2 simultaneously receives refraction and diffraction at thesurface 1 b of thesubstrate 1 on which the grating 1G is formed. Thereafter, thelight 2 simultaneously receives refraction and diffraction at thesurface 7S of thetransparent layer 7 on which the grating 7G is formed, so as to be converged on adetection surface 4 aslight 3. - Next, with reference to
FIG. 3 , the diffraction by the optical element of the present embodiment will be described. For simplicity,FIG. 3 illustrates each face as being planar, while also assuming that thelight 2 perpendicularly enters the face. - Firstly, it is assumed that the
substrate 1 has a refractive index n; thetransparent layer 7 has a refractive index n′; the grating 1G formed on theface 1 b has a pitch A and a cross-sectional step height d; the grating 7G formed on theface 7S has a pitch Λ and a cross-sectional step height d′. In this case, the wavefront of the light which is transmitted through the 1G and 7G will be in the form of sawteeth with the pitch Λ The difference Δ (phase difference) at the wavefront is expressed by (eq. 7) below.gratings
Δ=d′(n′−1)−d(n−n′) (eq. 7) - When the refractive indices n and n′ are to be each separated into a portion (first term) which does not depend on the wavelength λ and a portion (second term) which depends on the wavelength λ, approximations by the following two equations are possible.
n=n 0−(λ−λ0)σ (eq. 8)
n′=n 0′−(λ−λ0)σ′ (eq. 9) - These equations are each obtained by a first-order approximation which is coarser than (eq. 4). Herein, n0, n0′, λ0, σ, and σ′ are all positive numbers, where: λ0 is a central wavelength; n0 and n0′ are refractive indices at the central wavelength; and σ and σ′ are coefficients of dispersion. Therefore, a phase difference Δ can be expressed by (eq. 10) below.
Δ=d′(n0′−1)−d(n0−n0′)−(λ−λ0){d′σ′−d(σ−σ′)} (eq. 10) - Since the
light 2 will have the phase difference Δ with a period of the pitch Λ, diffracted waves such as 1st-order diffractedlight 3, and 2nd-order diffracted light 3″ will be generated. Thus, a condition under which the diffraction efficiency of qth-order diffracted light becomes maximum is given by (eq. 11) below.
Δ=qλ (eq. 11) - Herein, q is an integer.
- Therefore, the condition under which the diffraction efficiency reaches maximum when λ=λ0 and under which the amount of change of |Δ/λ| with respect to λ becomes small (i.e., a condition under which a high diffraction light efficiency is maintained and stray light is suppressed across a broad wavelength region) is expressed by the following two equations:
{d′(n 0′−1)−d(n 0 −n 0′)}/λ=q (eq. 12);
and
{d′σ′−d(σ−σ′)}/qλ 0<0 (eq. 13). - (eq. 12) is a conditional expression for the diffraction efficiency to become maximum when λ=λ0 (if the left-hand side is within a deviation of 0.2 or less with respect to the integer q, then it is fairly within the neighborhood of the local maximum). On the other hand, (eq. 13) is a conditional expression for making the amount of change of |Δ/λ| with respect to λ small. As the absolute value of the left-hand side of (eq. 13) becomes greater, the amount of change of |Δ/λ| with respect to λ can be made smaller.
- Unlike in the conventional examples, the number of step height parameters is now increased to two, i.e., d and d′, and therefore there can be a large number of combinations of optical materials that simultaneously satisfy (eq. 12) and (eq. 13). Note that the Abbe number is a value which is in proportion with an inverse of each of σ and σ′. Therefore, assuming that Abbe numbers corresponding to σ and σ′ are ν and ν′, (eq. 13) can be replaced by (eq. 14) below.
d′/d<ν′/ν−1 (eq. 14) - Now, the description will be continued by assuming that q=1. For simplicity, it is assumed that the incident angle of the
light 2 shown inFIG. 3 (i.e., the angle between itself and the surface normal) is zero. In this case, the diffraction angle θ of qth-order diffracted light (i.e., the angle between itself and the surface normal) is given by (eq. 1) above. As for 0th-order light 3′, q=0, and the diffraction angle is zero. Generally speaking, −1st-order diffracted light and −2nd-order diffracted light are also generated on opposite sides of the 0th-order light 3′. However, since the gratings have sawteeth-like cross sections, diffracted light of any − order is weakened, whereas diffracted light of any + order is intensified. - Note that, instead of being sawteeth-like as shown, the grating cross sections may be in the form of steps inscribed within the illustrated sawteeth shape, or may be simple protrusions and depressions.
- The pitch Λ does not need to have a constant value within the plane. By ensuring that the pitch Λ is a mathematical function of position, it becomes possible to adjust the diffraction angle, and assisted also by the spherical shape of the
surfaces 1 a and 1 b, etc., it becomes possible to converge the diffractedlight 3 at one point. - The diffraction phenomenon at the
1G and 7G can also be explained as follows. Assuming that p and q are integers, suppose that the step height d and d′ satisfy the following two equations.gratings
d=|pλ 0/(n−n′)| (eq. 15)
d′=|qλ 0′/(n′−1)| (eq. 16) - In this case, pth-order light is diffracted by the grating 1G mainly at the wavelength of λ0; qth-order light is diffracted by the grating 7G mainly at the wavelength of λ0′; and (p+q)th-order light is diffracted by the
1G and 7G at wavelengths in the neighborhood from λ0 to λ0′. In the example ofentire gratings FIG. 3 , the relationship p+q=1 holds. Although the wavelengths λ0 and λ0′ are near, they do not need to be equal. -
FIG. 4 is a graph showing the dispersion characteristics of the first material composing thesubstrate 1 and the second material composing thetransparent layer 7 of the light-converging device of the present embodiment. The refractive index of the first material monotonously increases as the wavelength becomes shorter (curve 5). The refractive index of the second material also monotonously increases as the wavelength becomes shorter (curve 5′). The second material has a lower refractive index and a smaller dispersion than those of the first material. Therefore, assuming that the first material and the second material have refractive indices nC and nC′ at the C line, and refractive indices nF and nF′ at the F line, the following two inequalities hold true.
nF′<nF and nC′<nC (eq. 17)
(n C ′−n C)/(n F ′−n F)<1 (eq. 18) - (eq. 17) means n0>n0′, and (eq. 18) means σ>ν′. Therefore, from (n0′−1)>1 and (n0−n0′)>1, there are numerous d and d′ that satisfy (eq. 12). Also from (σ−σ′)>0, there are numerous d and d′ that satisfy d′/d<(σ−σ′)/σ′, which is a transformation of (eq. 13). Therefore, under the conditions of (eq. 17) and (eq. 18), it is easy to satisfy (eq. 12) and (eq. 13), and the absolute value of the left-hand side of (eq. 13) can be set large with a certain amount of freedom.
- Generally speaking, an optical material having a high refractive index has a large dispersion, and an optical material having a small dispersion has a small refractive index. Therefore, there are many combinations of optical materials that simultaneously satisfy (eq. 17) and (eq. 18), resulting in a great diversity of material combinations which is beyond comparison with conventional examples.
- Note that the condition under which the diffraction efficiency reaches maximum when λ=λ0 and under which the amount of change of |Δ/λ| with respect to λ becomes small is still (eq. 12) and (eq. 13). It will be appreciated that, even if the refractive index condition is the same as the relationships of (eq. 5) and (eq. 6) of the conventional example, similar effects can be obtained so long as (eq. 12) and (eq. 13) are satisfied.
-
FIG. 5 shows the wavelength dependence of diffraction efficiency of each diffracted light in the optical element of the present embodiment. In this optical element, thesubstrate 1 is formed of a plastic material whose refractive index is nd=1.67 and Abbe number is ν=20, and thetransparent layer 7 is formed of a UV resin whose refractive index is nd=1.49 and Abbe number is ν=59. The grating step height d is 3.00 μm, and the step height d′ is 2.31 μm. The refractive index n at the wavelength λ is approximated according to (eq. 4). - As shown in
FIG. 5 , 1st-order diffractedlight 6 has a local maximum near the wavelength of 0.60 μm, and the diffraction efficiency is slightly decreased in other wavelength ranges. This decrease is much smaller than in the conventional examples. Therefore, the diffraction efficiencies (curves 6′, 6″) of 0th-order light and 2nd-order diffracted light, which are stray light, are kept very low. Furthermore, the aforementioned refractive index and Abbe number values pertain to plastic materials and UV resin materials, which are already at a practical level. Thus, a great improvement effect can be obtained with realistic material combinations. -
FIG. 5 is a model in which −1st-order light for light of λ0=0.540 μm is diffracted by the grating 1G, +2nd-order light for light of λ0′=0.566 μm is diffracted by the grating 7G, and 1st-order light is diffracted by the 1G and 7G. Other manners of diffraction are also permissible. For example,entire gratings FIG. 6 is a graph showing results of calculating the diffraction efficiency obtained when the step heights of the sawteeth cross sections of the respective gratings are d=5.10 μm and d′=3.10 μm, the material of thesubstrate 1 has a refractive index nd=1.67 and an Abbe number ν=18, and the material of thetransparent layer 7 has a refractive index nd=1.49 and an Abbe number ν=59. There is shown the diffraction efficiency of each diffracted light, in the case where −2nd-order light for light of λ0=0.459 μm is diffracted by the grating 1G, +3rd-order light for light of λ0′=0.506 μm is diffracted by the grating 7G, and 1st-order light is diffracted by the 1G and 7G.entire gratings - In the results of
FIG. 6 , central wavelengths λ0 and λ0′ of diffraction are shifted toward the shorter wavelength side than inFIG. 5 . In the example ofFIG. 6 , the grating step heights are greater, but its characteristics are further improved from the characteristics ofFIG. 5 . - From the inventors' calculations, it has been found that: as the difference in refractive index between the
substrate 1 and the transparent layer 7 (n0−-n0′) increases, the step height d of the grating 1G can be made smaller; and as the difference in dispersion between thesubstrate 1 and the transparent layer 7 (σ−σ′) increases and the step height d of the grating 1G increases, it becomes possible to obtain a high diffraction efficiency in a broader wavelength range. An optimum value for the step height d′ of the grating 7G is substantially uniquely determined once the other conditions (step height d of the grating 1G and the refractive index and Abbe number of each material) are determined. - Generally speaking, when formed of a material having a high refractive index, a refraction lens can realize a short optical path length and a high NA. On the other hand, a material having a low dispersion makes it possible to suppress defocusing associated with difference in wavelengths. However, commonly-available optical materials, whether glass or plastic, do not reconcile both a high refractive index and low dispersion. On the other hand, with a lens having gratings formed thereon as in the present embodiment, the dispersive power of refraction (wavelength dependence of refraction angle) can be canceled, by design, due to the dispersive power of diffraction (wavelength dependence of diffraction angle). As a result, it is not necessary to be concerned with the reconciliation of a high refractive index and low dispersion.
- From the standpoint of ease of manufacture, the
substrate 1 is preferably formed of a plastic material, and thetransparent layer 7 is preferably formed of a UV-curing resin. Fortunately, UV-curing resins are low refractive index/low dispersion materials which suit the conditions of the present embodiment. Moreover, plastic materials boast a certain degree of variations, and even at present are capable of guaranteeing the optical performance ofFIG. 5 . Moreover, hitherto-performed plastic material development activities, in their efforts to reconcile both a high refractive index and low dispersion (high Abbe number), have tended to disregard high dispersion materials while also compromising on the realization of a high refractive index; however, once the low dispersion limitation is removed, the situation will greatly change. Therefore, according to the present embodiment, development activities of optical materials can be shifted from the reconciliation of a high refractive index and low dispersion to the reconciliation of a high refractive index and high dispersion, and to the reconciliation of a low refractive index and low dispersion, which would be more logical and natural in terms of physical properties. Thus, there is a great impact (an effect of curtailing losses associated with material development) on the entire business. -
FIG. 7 shows a variant of the present embodiment. In this example, the edge positions of sawteeth cross sections are offset by δ between the grating 1G and the grating 7G.FIG. 8 shows the wavelength dependence of diffraction efficiency in the case where a parameter δ/Λ is varied under the same condition as inFIG. 5 . In order to maintain a high performance, it is preferable to satisfy |δ/Λ|<0.05. - Although gratings (1G, 7G) are formed on only one face (1 b) of a lens in the present embodiment, similar structures may be formed on both faces (1 a, 1 b) of the lens.
- Next, with reference to
FIG. 9 , a second embodiment of the optical element according to the present invention will be described. The optical element of the present embodiment has the same construction as that of the optical element of the first embodiment, except for the pitch and step height of the grating 7G which is formed on thesurface 7S of thetransparent layer 7. -
FIG. 9 is a cross-sectional view showing diffraction at the 1 b and 7S of the optical element of the present embodiment. For simplicity, it is assumed that thefaces 1 b and 7S are planar, and thatfaces light 2 perpendicularly enters theface 1 b. - The
substrate 1 has a refractive index n; thetransparent layer 7 has a refractive index n′; the grating 1G formed on theface 1 b has a pitch Λ and a cross-sectional step height d; and the grating 7G formed on theface 7S has a pitch Λ/2 and a cross-sectional step height d′/2. The values of d and d′ are the same as the values in the first embodiment. - The pitch and step height conditions of the grating 1G of the present embodiment have not changed from those of the grating 1G of the first embodiment. Therefore (eq. 15) holds true, and pth-order light is diffracted. On the other hand, in the grating 7G, the step height is reduced to half, and therefore q/2nd-order light is diffracted based on (eq. 16), assuming that q is an even number.
- Thus, q in the right-hand side of (eq. 1) is changed to q/2, but the pitch Λ is also reduced to half (Λ/2) at the same time. Thus, the value of the right-hand side of (eq. 1) does not change, and the diffraction angle θ does not change. As a result, in the
1G and 7G as a whole, diffracted light is generated in the same direction and with the same intensity as in the first embodiment. Therefore, although the pitch and step height of the grating 7G are different, the optical element of the present embodiment provides quite the same effects as those of the first embodiment.gratings - When adopted in a grating having a large pitch, the construction of the present embodiment will make it possible to reduce the grating step height, and therefore the manufacturing of a die which is necessary for forming the grating 7G (cutting/grinding step, etc.) is facilitated. Due to machining errors, the actually-produced step will not be perpendicular to but tilted with respect to the base plane, this machining error leading to light scattering. An effect of reducing light scattering is obtained by reducing the grating step height.
- The present embodiment is not limited to those having the illustrated construction. For example, the pitch and step height of the grating 7G may be multiplied by an integer, or divided by an integer. Moreover, the pitch and step height of the grating 1G may be multiplied by an integer, or divided by an integer, or any construction that combines these may be adopted. However, in the case where the step height is divided by an integer, it is necessary that the step height satisfies (eq. 15) and (eq. 16), and at least are not less than their minimum values (i.e., values when p=1,q=1). The relationship between the pitches of the
1G and 7G in the present embodiment only needs to satisfy m×Λ for the grating 1G and n×Λ for the grating 7G, assuming that m and n are integers of 1 or more.gratings - An optical element according to the present invention operates as a light-converging device or a diffraction device, and is able to maintain a high diffraction efficiency across a broad wavelength region. Therefore, the optical element according to the present invention is suitably used for in an optical pickup having an imaging device and a multi-wavelength light source, or the like.
Claims (16)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004283857 | 2004-09-29 | ||
| JP2004-283857 | 2004-09-29 | ||
| PCT/JP2005/017773 WO2006035785A1 (en) | 2004-09-29 | 2005-09-27 | Optical element |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2005/017773 A-371-Of-International WO2006035785A1 (en) | 2004-09-29 | 2005-09-27 | Optical element |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/165,106 Division US8451539B2 (en) | 2004-09-29 | 2011-06-21 | Optical element having transmitting layers with respective blazed surfaces and Abbe numbers |
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| Publication Number | Publication Date |
|---|---|
| US20080007831A1 true US20080007831A1 (en) | 2008-01-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/575,595 Abandoned US20080007831A1 (en) | 2004-09-29 | 2005-09-27 | Optical Element |
| US13/165,106 Expired - Fee Related US8451539B2 (en) | 2004-09-29 | 2011-06-21 | Optical element having transmitting layers with respective blazed surfaces and Abbe numbers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/165,106 Expired - Fee Related US8451539B2 (en) | 2004-09-29 | 2011-06-21 | Optical element having transmitting layers with respective blazed surfaces and Abbe numbers |
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| Country | Link |
|---|---|
| US (2) | US20080007831A1 (en) |
| EP (1) | EP1806604A4 (en) |
| JP (1) | JP4714152B2 (en) |
| KR (1) | KR20070064592A (en) |
| CN (1) | CN100510793C (en) |
| WO (1) | WO2006035785A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120008210A1 (en) * | 2010-02-26 | 2012-01-12 | Panasonic Corporation | Diffractive lens and image capture device using the same |
| US20120113518A1 (en) * | 2009-11-02 | 2012-05-10 | Takamasa Ando | Diffraction grating lens and image capture apparatus using the same |
| US20120170121A1 (en) * | 2010-08-19 | 2012-07-05 | Panasonic Corporation | Diffraction grating lens and imaging device in which the same is used |
| US11678740B2 (en) | 2021-03-16 | 2023-06-20 | Inno-Sports Co., Ltd. | Frame with minimized thickness when folded |
| US11686429B2 (en) | 2020-01-20 | 2023-06-27 | Inno-Sports Co., Ltd. | Supporting assembly and frame having same |
| US11690444B2 (en) | 2021-02-04 | 2023-07-04 | Inno-Sports Co., Ltd. | Foldable frame and table having same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006106435A (en) * | 2004-10-06 | 2006-04-20 | Canon Inc | Optical equipment |
| JP4927646B2 (en) * | 2007-06-06 | 2012-05-09 | 住友電工ハードメタル株式会社 | Laser microlenses |
| US9045933B2 (en) * | 2011-06-06 | 2015-06-02 | The Board Of Trustees Of The University Of Illinois | Energy-efficient smart window system |
| JP5360625B2 (en) * | 2012-02-08 | 2013-12-04 | 住友電工ハードメタル株式会社 | Laser microlenses |
| TWI627449B (en) * | 2016-04-15 | 2018-06-21 | 中央研究院 | Curved diffraction grating, spectrometer and curved diffraction grating manufacturing method |
| JP7394315B2 (en) * | 2019-09-25 | 2023-12-08 | パナソニックIpマネジメント株式会社 | lighting equipment |
| CN113205899B (en) * | 2021-04-25 | 2023-02-28 | 中国工程物理研究院激光聚变研究中心 | A kind of X-ray refraction blazed grating and its preparation method |
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- 2005-09-27 JP JP2006537761A patent/JP4714152B2/en not_active Expired - Fee Related
- 2005-09-27 EP EP05787554A patent/EP1806604A4/en not_active Ceased
- 2005-09-27 KR KR1020077004754A patent/KR20070064592A/en not_active Withdrawn
- 2005-09-27 CN CNB2005800215271A patent/CN100510793C/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN100510793C (en) | 2009-07-08 |
| JPWO2006035785A1 (en) | 2008-05-15 |
| US8451539B2 (en) | 2013-05-28 |
| KR20070064592A (en) | 2007-06-21 |
| EP1806604A1 (en) | 2007-07-11 |
| EP1806604A4 (en) | 2009-03-11 |
| JP4714152B2 (en) | 2011-06-29 |
| WO2006035785A1 (en) | 2006-04-06 |
| CN1977191A (en) | 2007-06-06 |
| US20110249345A1 (en) | 2011-10-13 |
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