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US20080001210A1 - Self-aligned element isolation film structure in a flash cell and forming method thereof - Google Patents

Self-aligned element isolation film structure in a flash cell and forming method thereof Download PDF

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Publication number
US20080001210A1
US20080001210A1 US11/900,721 US90072107A US2008001210A1 US 20080001210 A1 US20080001210 A1 US 20080001210A1 US 90072107 A US90072107 A US 90072107A US 2008001210 A1 US2008001210 A1 US 2008001210A1
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Prior art keywords
floating gate
flash memory
element isolation
memory cell
isolation film
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US11/900,721
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Chul Yoon
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    • H10W10/011
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/30Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B69/00Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/0411Manufacture or treatment of FETs having insulated gates [IGFET] of FETs having floating gates
    • H10W10/10

Definitions

  • the present disclosure relates to a semiconductor device, and more particularly, to a self-aligned element isolation film structure in a flash memory cell and a forming method thereof.
  • flash memory devices which are nonvolatile memory devices, comprise a stacked structure of a floating gate and a control gate.
  • An element isolation process for isolating elements is performed between the floating gates.
  • Such an element isolation process is performed on a substrate before a process of forming the floating gates, and a shallow trench isolation (STI) process is typically used to isolate the elements.
  • STI shallow trench isolation
  • the floating gate overlaps the STI element isolation film.
  • the overlapping of the floating gate on the STI element isolation film causes reduction of the element area such that the size reduction of a cell array is obstructed or inhibited.
  • a silicon nitride film is deposited, a patterning process of forming a field region is performed, a dry etching process is performed, a chemical vapor deposition (CVD) process is performed with an insulating material, a polishing process is performed, and a wet etching process of etching the deposited silicon nitride film is then performed.
  • CVD chemical vapor deposition
  • a flash gate process is performed after the element isolation process. Specifically, after the element isolation process, the floating gate forming process is performed as the flash gate forming process. Because the floating gate process is performed after the element isolation process, the floating gates must share a portion of the insulating element isolation film made of an insulating material for reliable isolation. The shared portion affects the cell size, thereby causing a problem in the flash memory device of which the cell size is particularly important.
  • FIGS. 1 to 4 are schematic sectional views explaining an example self-aligned element isolation film structure in a flash memory cell and an example forming method thereof.
  • the examples described herein provide an element isolation film structure in a flash memory cell capable of reducing the size of a cell array of the flash memory device.
  • An example method of forming a self-aligned element isolation film structure in a flash memory cell forms an insulating layer on a semiconductor substrate; forms a floating gate pattern on the insulating layer; selectively implants ions in a portion of the insulating layer that is exposed by the floating gate pattern; and forms a self-aligned element isolation film on the floating gate pattern by oxidizing and growing the portion of the insulating layer to which the ion implantation is performed.
  • the forming of the floating gate pattern may comprise forming a photo resist pattern, in which an element isolation region is exposed, on the floating gate layer and selectively etching the exposed portion of the floating gate layer using the photo resist pattern as an etching mask to expose the surface of the insulating layer.
  • the example method may further comprise heating the insulating layer to which the ion implantation has been performed.
  • the floating gate pattern may be made of a poly silicon film and the poly silicon film may be used as an ion implantation mask for shielding a portion of the insulating layer under the floating gate pattern at the time of the ion implantation.
  • An example self-aligned element isolation structure in a flash memory cell includes a floating gate pattern formed on a semiconductor substrate with an insulating layer interposed therebetween and an element isolation film which is grown in a self-aligned manner at the side of the floating gate patterns with a thickness larger than that of the insulating layer to fill a space between the floating gate patterns.
  • an insulating layer 200 as a tunnel dielectric layer is formed on a semiconductor substrate 100 .
  • the element isolation is not performed before forming the insulating layer 200 .
  • a conductive floating gate layer 300 for example, a conductive poly silicon film used for a floating gate of a flash memory device is formed on the insulating layer 200 .
  • the poly silicon film can be formed by a chemical vapor deposition (CVD) method.
  • CVD chemical vapor deposition
  • a photo resist pattern 400 used as an etching mask at the time of patterning the floating gate 300 is formed.
  • the photo resist pattern 400 is formed to expose a portion of the floating gate layer 300 where a field region for setting an active region to be formed with the floating gate is located.
  • a floating gate pattern 301 is formed. At this time, the insulating layer 200 under the floating gate layer 300 is exposed. Specifically, it is preferable to perform the patterning so that the insulating layer 200 is not removed by the etching process.
  • an ion implantation process is performed on the exposed portion of the insulating layer 200 .
  • the floating gate pattern 301 selectively prevents the ion implantation.
  • the portion of the insulating layer 200 which is exposed by the floating gate pattern is again oxidized and grown. Specifically, this portion grows thicker by the oxidation than the insulating layer 200 . Therefore, the thick insulating portion 201 is formed to fill the spaces between the floating gate patterns 301 , such that the isolation between the floating gate patterns 301 or the element isolation is accomplished by the insulating material portion 201 formed during the oxidation. Then, a control gate and the like is formed on the floating gate pattern 301 to complete the flash memory device.
  • the example method described above when cell regions are formed in a flash memory device, it is not necessary to first perform the process of isolating the elements, that is, the element isolation process, and it is possible to form the isolation portion between the elements in a self-aligned manner using the poly silicon film as the floating gate. Therefore, it is possible to compensate for the area of the overlapped portion between the floating gate and the inter-elements isolation portion. Because the cell array includes a plurality of cells, it is important to make the cell size small in the flash memory device. Using the example method described herein, it is also possible to prevent the floating gate and the element isolation film from overlapping each other, such that it is effective for securing a small cell size.

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  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Abstract

A self-aligned element isolation film structure in a flash memory cell and a forming method thereof are disclosed. An example method of forming a self-aligned element isolation film structure in a flash memory cell forms an insulating layer on a semiconductor substrate and forms a floating gate pattern on the insulating layer. The example method selectively implants ions in a portion of the insulating layer exposed by the floating gate pattern and forms a self-aligned element isolation film on the floating gate pattern by oxidizing and growing the portion of the insulating layer to which the ion implantation is performed.

Description

  • The present application is a divisional of U.S. patent application Ser. No. 11/023,277, filed Dec. 27, 2004, pending.
  • TECHNICAL FIELD
  • The present disclosure relates to a semiconductor device, and more particularly, to a self-aligned element isolation film structure in a flash memory cell and a forming method thereof.
  • BACKGROUND
  • In general, flash memory devices, which are nonvolatile memory devices, comprise a stacked structure of a floating gate and a control gate. An element isolation process for isolating elements is performed between the floating gates. Such an element isolation process is performed on a substrate before a process of forming the floating gates, and a shallow trench isolation (STI) process is typically used to isolate the elements.
  • When the element isolation is implemented using the STI process, the floating gate overlaps the STI element isolation film. The overlapping of the floating gate on the STI element isolation film causes reduction of the element area such that the size reduction of a cell array is obstructed or inhibited. Specifically, in the conventional element isolation process such as the STI process of isolating the elements in a flash memory cell region, a silicon nitride film is deposited, a patterning process of forming a field region is performed, a dry etching process is performed, a chemical vapor deposition (CVD) process is performed with an insulating material, a polishing process is performed, and a wet etching process of etching the deposited silicon nitride film is then performed.
  • A flash gate process is performed after the element isolation process. Specifically, after the element isolation process, the floating gate forming process is performed as the flash gate forming process. Because the floating gate process is performed after the element isolation process, the floating gates must share a portion of the insulating element isolation film made of an insulating material for reliable isolation. The shared portion affects the cell size, thereby causing a problem in the flash memory device of which the cell size is particularly important.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIGS. 1 to 4 are schematic sectional views explaining an example self-aligned element isolation film structure in a flash memory cell and an example forming method thereof.
  • DETAILED DESCRIPTION
  • In general, the examples described herein provide an element isolation film structure in a flash memory cell capable of reducing the size of a cell array of the flash memory device. An example method of forming a self-aligned element isolation film structure in a flash memory cell forms an insulating layer on a semiconductor substrate; forms a floating gate pattern on the insulating layer; selectively implants ions in a portion of the insulating layer that is exposed by the floating gate pattern; and forms a self-aligned element isolation film on the floating gate pattern by oxidizing and growing the portion of the insulating layer to which the ion implantation is performed.
  • The forming of the floating gate pattern may comprise forming a photo resist pattern, in which an element isolation region is exposed, on the floating gate layer and selectively etching the exposed portion of the floating gate layer using the photo resist pattern as an etching mask to expose the surface of the insulating layer.
  • The example method may further comprise heating the insulating layer to which the ion implantation has been performed. The floating gate pattern may be made of a poly silicon film and the poly silicon film may be used as an ion implantation mask for shielding a portion of the insulating layer under the floating gate pattern at the time of the ion implantation.
  • An example self-aligned element isolation structure in a flash memory cell includes a floating gate pattern formed on a semiconductor substrate with an insulating layer interposed therebetween and an element isolation film which is grown in a self-aligned manner at the side of the floating gate patterns with a thickness larger than that of the insulating layer to fill a space between the floating gate patterns.
  • Using the example method and apparatus described herein, it is possible to provide a method of forming an element isolation film in a flash memory cell capable of reducing a size of cell array of flash memory device.
  • Now referring to FIG. 1, in forming the self-aligned element isolation film, an insulating layer 200 as a tunnel dielectric layer is formed on a semiconductor substrate 100. At this time, in contrast to known methods, the element isolation is not performed before forming the insulating layer 200.
  • Referring to FIG. 2, a conductive floating gate layer 300, for example, a conductive poly silicon film used for a floating gate of a flash memory device is formed on the insulating layer 200. The poly silicon film can be formed by a chemical vapor deposition (CVD) method. Then, a photo resist pattern 400 used as an etching mask at the time of patterning the floating gate 300 is formed. The photo resist pattern 400 is formed to expose a portion of the floating gate layer 300 where a field region for setting an active region to be formed with the floating gate is located.
  • Referring to FIG. 3, by patterning the floating gate layer 300, that is, by selectively etching and removing a portion exposed by the photo resist pattern 400, a floating gate pattern 301 is formed. At this time, the insulating layer 200 under the floating gate layer 300 is exposed. Specifically, it is preferable to perform the patterning so that the insulating layer 200 is not removed by the etching process.
  • Further, an ion implantation process is performed on the exposed portion of the insulating layer 200. In a portion of the insulating layer 200 which is shielded by the floating gate pattern 301, the floating gate pattern 301 selectively prevents the ion implantation.
  • Referring to FIG. 4, if oxidation is performed after performing the ion implantation on a portion of the insulating layer 200, which will be an isolated region, and performing a post-treatment of the ion implantation, for example, a heat treatment, the portion of the insulating layer 200 which is exposed by the floating gate pattern is again oxidized and grown. Specifically, this portion grows thicker by the oxidation than the insulating layer 200. Therefore, the thick insulating portion 201 is formed to fill the spaces between the floating gate patterns 301, such that the isolation between the floating gate patterns 301 or the element isolation is accomplished by the insulating material portion 201 formed during the oxidation. Then, a control gate and the like is formed on the floating gate pattern 301 to complete the flash memory device.
  • Using the example method described above, when cell regions are formed in a flash memory device, it is not necessary to first perform the process of isolating the elements, that is, the element isolation process, and it is possible to form the isolation portion between the elements in a self-aligned manner using the poly silicon film as the floating gate. Therefore, it is possible to compensate for the area of the overlapped portion between the floating gate and the inter-elements isolation portion. Because the cell array includes a plurality of cells, it is important to make the cell size small in the flash memory device. Using the example method described herein, it is also possible to prevent the floating gate and the element isolation film from overlapping each other, such that it is effective for securing a small cell size.
  • While the examples herein have been described in detail with reference to example embodiments, it is to be understood that the coverage of this patent is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the sprit and scope of the appended claims.

Claims (14)

1. A self-aligned element isolation film structure in a flash memory cell, comprising:
a floating gate pattern on a semiconductor substrate with an insulating layer therebetween; and
an element isolation film, grown in a self-aligned manner at a side of the floating gate pattern with a thickness larger than that of the insulating layer to fill a space between adjacent floating gates.
2. The self-aligned element isolation film structure in the flash memory cell of claim 1, wherein the floating gate pattern comprises a polysilicon film.
3. The self-aligned element isolation film structure in a flash memory cell of claim 1, wherein the element isolation film comprises an oxide film.
4. The flash memory cell of claim 3, wherein the element isolation film comprises a thermal oxide.
5. The flash memory cell of claim 1, wherein the insulating layer comprises a tunnel dielectric layer.
6. The flash memory cell of claim 1, further comprising an ion implantation region in a portion of the substrate not covered by the floating gate pattern.
7. The flash memory cell of claim 1, further comprising a control gate on or over the floating gate.
8. A flash memory cell, comprising:
a floating gate pattern on a semiconductor substrate with an insulating layer therebetween, the floating gate pattern comprising a plurality of floating gates; and
a self-aligned element isolation film at sides of the floating gate pattern having a thickness greater than that of the insulating layer to fill a space between adjacent floating gates.
9. The flash memory cell of claim 8, wherein the floating gate pattern comprises a polysilicon film.
10. The flash memory cell of claim 8, wherein the element isolation film comprises an oxide film.
11. The flash memory cell of claim 10, wherein the element isolation film comprises a thermal oxide.
12. The flash memory cell of claim 8, wherein the insulating layer comprises a tunnel dielectric layer.
13. The flash memory cell of claim 8, further comprising an ion implantation region in a portion of the substrate not covered by the floating gate pattern.
14. The flash memory cell of claim 8, further comprising a control gate on or over the floating gate.
US11/900,721 2003-12-27 2007-09-11 Self-aligned element isolation film structure in a flash cell and forming method thereof Abandoned US20080001210A1 (en)

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KR1020030098332A KR100545183B1 (en) 2003-12-27 2003-12-27 Structure of self-aligned device separator in flash cell and method of forming the same
US11/023,277 US7312122B2 (en) 2003-12-27 2004-12-27 Self-aligned element isolation film structure in a flash cell and forming method thereof
US11/900,721 US20080001210A1 (en) 2003-12-27 2007-09-11 Self-aligned element isolation film structure in a flash cell and forming method thereof

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5740105A (en) * 1994-05-27 1998-04-14 Texas Instruments Incorporated Memory cell array with LOCOS free isolation
US6271561B2 (en) * 1993-07-27 2001-08-07 Micron Technology, Inc. Method for fabricating floating gate semiconductor devices with trench isolation structures and self aligned floating gates
US20020168819A1 (en) * 2001-05-14 2002-11-14 Horng-Huei Tseng Flash memory with conformal floating gate and the method of making the same
US6642105B2 (en) * 1999-12-24 2003-11-04 Samsung Electronics Co., Ltd. Semiconductor device having multi-gate insulating layers and methods of fabricating the same
US6969653B2 (en) * 2002-12-30 2005-11-29 Dongbuanam Semiconductor, Inc. Methods of manufacturing and-type flash memory devices

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW309647B (en) * 1995-12-30 1997-07-01 Hyundai Electronics Ind
US6066530A (en) * 1998-04-09 2000-05-23 Advanced Micro Devices, Inc. Oxygen implant self-aligned, floating gate and isolation structure
US6369421B1 (en) * 1998-06-29 2002-04-09 Advanced Micro Devices, Inc. EEPROM having stacked dielectric to increase programming speed

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6271561B2 (en) * 1993-07-27 2001-08-07 Micron Technology, Inc. Method for fabricating floating gate semiconductor devices with trench isolation structures and self aligned floating gates
US5740105A (en) * 1994-05-27 1998-04-14 Texas Instruments Incorporated Memory cell array with LOCOS free isolation
US6642105B2 (en) * 1999-12-24 2003-11-04 Samsung Electronics Co., Ltd. Semiconductor device having multi-gate insulating layers and methods of fabricating the same
US20020168819A1 (en) * 2001-05-14 2002-11-14 Horng-Huei Tseng Flash memory with conformal floating gate and the method of making the same
US6969653B2 (en) * 2002-12-30 2005-11-29 Dongbuanam Semiconductor, Inc. Methods of manufacturing and-type flash memory devices

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KR100545183B1 (en) 2006-01-24
US20050139899A1 (en) 2005-06-30
US7312122B2 (en) 2007-12-25

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