US20070161341A1 - Focusing nozzle - Google Patents
Focusing nozzle Download PDFInfo
- Publication number
- US20070161341A1 US20070161341A1 US11/707,784 US70778407A US2007161341A1 US 20070161341 A1 US20070161341 A1 US 20070161341A1 US 70778407 A US70778407 A US 70778407A US 2007161341 A1 US2007161341 A1 US 2007161341A1
- Authority
- US
- United States
- Prior art keywords
- coating
- focusing
- layer
- nozzle
- hard material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000576 coating method Methods 0.000 claims abstract description 42
- 239000011248 coating agent Substances 0.000 claims abstract description 38
- 239000010410 layer Substances 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000002356 single layer Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000001247 metal acetylides Chemical class 0.000 claims description 2
- 235000019589 hardness Nutrition 0.000 description 8
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910001092 metal group alloy Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C5/00—Devices or accessories for generating abrasive blasts
- B24C5/02—Blast guns, e.g. for generating high velocity abrasive fluid jets for cutting materials
- B24C5/04—Nozzles therefor
Definitions
- the invention relates to a focusing nozzle for abrasive water jet cutting.
- the nozzle comprises a nozzle body of carbide metal formed with a bore for focusing the cutting jet. At least the bore wall of the nozzle has a single-layer or a multi-layer coating of hard material.
- Such focusing nozzles form part of cutting heads for abrasive water jet cutting in which the cutting water jet and the abrasive medium used for cutting, such as corundum or sand, are mixed in a mixing chamber in order to increase the cutting effect of the cutting water jet.
- the focusing nozzles serve to accelerate and center the water jet and the simultaneously admitted abrasive medium.
- the focusing nozzles In order to improve mixing of the abrasive medium into the water jet, the focusing nozzles generally have a funnel-like widening on the inlet side.
- the bore connected thereto and passing through the focusing nozzle has a diameter in the range of roughly 0.2-1.5 mm.
- a focusing nozzle for abrasive water jet cutting comprising:
- the objects of the invention are achieved in that the hard material coating has a layer with titanium nitride content at least on the free surface. It was surprising that the use of such a coating as a hard material coating would allow a significant improvement in the wear resistance of focusing nozzles to be achieved, since the hardnesses of the layer with titanium nitride content at the surface are hardly higher than the hardness of the hard metal base material employed, and far lower that the hardness of a diamond-like coating (DLC) already used to coat such focusing nozzles according to the prior art described above.
- the coating according to the invention can be applied in one or more layers, also by applying other hard material layers. All that is important in that the layer at the surface has a titanium nitride content.
- titanium carbonitride or titanium oxycarbonitride are also conceivable for this surface layer.
- the hardness of known DLC layers is not quite achieved with the coating according to the invention, but in favor the application of the coating according to the invention is possible without problems using CVD methods.
- the reaction gases can be selectively directed through the bore of the focusing nozzle, so that the time-consuming multiple segmenting of the nozzle body according to the prior art can be avoided.
- the increase in the service life of focusing nozzles with the coating according to the invention by comparison with focusing nozzles of uncoated hard metal is outstanding and extends up to a doubling of the service life.
- the service-life-prolonging effect surprising in view of the minor differences in hardness between base material and coating, is probably attributable to the fact that with focusing nozzles of uncoated hard metal, the wet operating conditions, exacerbated by in some cases low pH values, result in surface corrosion that causes a dissolving-out of the metallic binder from the hard metal alloy.
- the remaining superficial hard material skeleton has a considerably lower resistance to abrasion compared with a hard metal alloy bonded completely with metallic binder.
- the coating according to the invention substantially prevents surface corrosion and hence a dissolving-out of binding medium.
- the hard material coating has proved to be particularly favorable for the hard material coating to be applied as a single titanium nitride or titanium carbonitride layer.
- the most expedient layer thicknesses for the hard material coating lie in the range from 1-15 ⁇ m.
- Layers with titanium nitride content can be particularly well applied using CVD (chemical vapor deposition) processes. These processes offer the great advantage that the reaction gases can be easily directed, so that the hard material coatings produced thereby can be deposited even at points with difficult access, so that the inside walls of the narrow bores in the focusing nozzles can also be coated without problems.
- CVD chemical vapor deposition
- a hard metal with up to 1.5 wt. % cobalt as metallic binder, up to 3 wt. % mixed carbides, and tungsten carbide with a grain size of less than 0.4 ⁇ m as rest has proved to be effective as base material for the focusing nozzle.
- Focusing nozzles with 76 mm length, 9 mm outer diameter and 0.7 mm bore diameter were produced by extrusion and sintering from a hard metal alloy with 1 wt. % cobalt as metallic binder and tungsten carbide with 0.2 ⁇ m mean grain size as a remainder.
- the focusing nozzles had a hardness of 2550 HV 10 .
- Some of the focusing nozzles were subsequently coated at the surface, including the bore wall, with a 6.5 ⁇ m thick TiN layer in a medium-temperature CVD process.
- the layer hardness was roughly 2450 HV 0.1 .
- the focusing nozzles had a golden yellow coloration.
- Focusing nozzles were produced as described under example 1. Some of these focusing nozzles were coated at the surface, including the bore wall, with a two-layer hard material coating consisting of an 8 ⁇ m thick TiCN layer and a 4 ⁇ m thick TiN layer in a medium-temperature CVD process. The uppermost layer of the coating was the TiN layer. The hardness of the coating was approx. 2450 HV 0.1 .
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Vapour Deposition (AREA)
- Coating Apparatus (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Abstract
A focusing nozzle for abrasive water jet cutting has a nozzle body of carbide metal formed with a bore. At least the bore wall is formed with a single-layer or multi-layer coating of hard material. The hard material coating has a coat with titanium nitride content at least at the free surface.
Description
- This is a continuing application, under 35 U.S.C. § 120, of copending international application PCT/AT2005/000320, filed Aug. 9, 2005, which designated the United States; this application also claims the priority, under 35 U.S.C. § 119, of Austrian application GM 591/2004, filed Aug. 16, 2004; the prior applications are herewith incorporated by reference in their entirety.
- 1. Field of the Invention
- The invention relates to a focusing nozzle for abrasive water jet cutting. The nozzle comprises a nozzle body of carbide metal formed with a bore for focusing the cutting jet. At least the bore wall of the nozzle has a single-layer or a multi-layer coating of hard material.
- Such focusing nozzles form part of cutting heads for abrasive water jet cutting in which the cutting water jet and the abrasive medium used for cutting, such as corundum or sand, are mixed in a mixing chamber in order to increase the cutting effect of the cutting water jet. The focusing nozzles serve to accelerate and center the water jet and the simultaneously admitted abrasive medium. In order to improve mixing of the abrasive medium into the water jet, the focusing nozzles generally have a funnel-like widening on the inlet side. The bore connected thereto and passing through the focusing nozzle has a diameter in the range of roughly 0.2-1.5 mm. Despite the enclosure of the abrasive medium in the water jet, the focusing nozzles are subjected to very severe wear. If the wear on the bore wall is too severe, the centering effect is no longer sufficient and the nozzle has to be replaced. As each nozzle change involves a prolonged and therefore costly interruption in the work process, considerable efforts have been made in the past to increase the service life of such focusing nozzles as far as possible. For example, highly wear-resistant tungsten carbide-based, hard metal alloys with very low metallic binder contents or even ceramic materials were frequently used for such focusing nozzles. But even using these high-grade materials, the achievable service lives were still not sufficiently satisfactory.
- In order to further increase the service life, efforts were therefore made to protect the inner wall of the through-bored centering nozzle against excessive wear by using coatings of hard material. The problem here is that it is difficult to uniformly apply a protective coating of hard material to the inner walls of these relatively long bores of small diameter.
- International PCT publication WO 98/15386, for example, describes a focusing nozzle whose inner wall has a wear-resistant, diamond-like coating of amorphous carbon (DLC). The coating is applied by means of a laser arc coating method, wherein a highly activated plasma has to be generated in the vacuum by means of a pulsed arc discharge between a source of the coating material and the nozzle to be coated. For this, the surface to be coated must be freely accessible so that the focusing nozzle can be split into several segments for coating of the bore wall. After coating, these segments have to be tightly assembled again, a process involving a considerable amount of work.
- It is accordingly an object of the invention to provide a coating to the inner wall of a hard metal focusing nozzle which overcomes the above-mentioned disadvantages of the heretofore-known devices and methods of this general type and which is sufficiently resistant to wear, and at the same time is easy to apply without time-consuming segmenting of the nozzle.
- With the foregoing and other objects in view there is provided, in accordance with the invention, a focusing nozzle for abrasive water jet cutting, comprising:
-
- a nozzle body of hard metal;
- said nozzle body having a bore formed therein with a bore wall for focusing an abrasive water cutting jet; and
- a coating of hard material on said bore wall, said coating having a layer with a content of titanium nitride at least at a free surface thereof.
- In other words, the objects of the invention are achieved in that the hard material coating has a layer with titanium nitride content at least on the free surface. It was surprising that the use of such a coating as a hard material coating would allow a significant improvement in the wear resistance of focusing nozzles to be achieved, since the hardnesses of the layer with titanium nitride content at the surface are hardly higher than the hardness of the hard metal base material employed, and far lower that the hardness of a diamond-like coating (DLC) already used to coat such focusing nozzles according to the prior art described above. The coating according to the invention can be applied in one or more layers, also by applying other hard material layers. All that is important in that the layer at the surface has a titanium nitride content. Apart from pure titanium nitride, titanium carbonitride or titanium oxycarbonitride, for example, are also conceivable for this surface layer. Although the hardness of known DLC layers is not quite achieved with the coating according to the invention, but in favor the application of the coating according to the invention is possible without problems using CVD methods.
- With this coating method, the reaction gases can be selectively directed through the bore of the focusing nozzle, so that the time-consuming multiple segmenting of the nozzle body according to the prior art can be avoided. The increase in the service life of focusing nozzles with the coating according to the invention by comparison with focusing nozzles of uncoated hard metal is outstanding and extends up to a doubling of the service life.
- The service-life-prolonging effect, surprising in view of the minor differences in hardness between base material and coating, is probably attributable to the fact that with focusing nozzles of uncoated hard metal, the wet operating conditions, exacerbated by in some cases low pH values, result in surface corrosion that causes a dissolving-out of the metallic binder from the hard metal alloy. The remaining superficial hard material skeleton has a considerably lower resistance to abrasion compared with a hard metal alloy bonded completely with metallic binder. The coating according to the invention substantially prevents surface corrosion and hence a dissolving-out of binding medium.
- Even when working with jets in which no significant dissolving-out of metallic binder occurs due to a high pH value, a considerable improvement in the service life can be ascertained as a result of the coating according to the invention attributable to the additional smoothing effect of the coating, particularly in the area immediately behind the entry cone of the focusing nozzle. The smoother surface in this area calms the incoherent jet zone far more quickly, leading to a great reduction in wear.
- It has proved to be particularly favorable for the hard material coating to be applied as a single titanium nitride or titanium carbonitride layer.
- The most expedient layer thicknesses for the hard material coating lie in the range from 1-15 μm.
- Layers with titanium nitride content can be particularly well applied using CVD (chemical vapor deposition) processes. These processes offer the great advantage that the reaction gases can be easily directed, so that the hard material coatings produced thereby can be deposited even at points with difficult access, so that the inside walls of the narrow bores in the focusing nozzles can also be coated without problems.
- A hard metal with up to 1.5 wt. % cobalt as metallic binder, up to 3 wt. % mixed carbides, and tungsten carbide with a grain size of less than 0.4 μm as rest has proved to be effective as base material for the focusing nozzle.
- Other features which are considered as characteristic for the invention are set forth in the appended claims.
- Although the invention is illustrated and described herein as embodied in a jet focusing nozzle, it is nevertheless not intended to be limited to the details shown, since various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims.
- The construction and method of operation of the invention, however, together with additional objects and advantages thereof will be best understood from the following description of specific embodiments, as represented by the implementation examples.
- The invention is described in greater detail below by reference to two specific examples.
- Focusing nozzles with 76 mm length, 9 mm outer diameter and 0.7 mm bore diameter were produced by extrusion and sintering from a hard metal alloy with 1 wt. % cobalt as metallic binder and tungsten carbide with 0.2 μm mean grain size as a remainder. The focusing nozzles had a hardness of 2550 HV10. Some of the focusing nozzles were subsequently coated at the surface, including the bore wall, with a 6.5 μm thick TiN layer in a medium-temperature CVD process. The layer hardness was roughly 2450 HV0.1. The focusing nozzles had a golden yellow coloration. In a comparison test with uncoated reference nozzles, some of the focusing nozzles coated according to the invention were used under practical conditions for water jet cutting. The water pressure was 2250 bar, with a pH value of the water of 6.1. Sand with a mean grain size of 260 μm and a feed rate of 9 g/s was used as abrasive medium. As a result, prolongations of the service life of the coated focusing nozzles compared with the uncoated focusing nozzles in the order of a factor of 1.8 to 2.1 were observed.
- Focusing nozzles were produced as described under example 1. Some of these focusing nozzles were coated at the surface, including the bore wall, with a two-layer hard material coating consisting of an 8 μm thick TiCN layer and a 4 μm thick TiN layer in a medium-temperature CVD process. The uppermost layer of the coating was the TiN layer. The hardness of the coating was approx. 2450 HV0.1.
- In the comparison test between the focusing nozzles coated according to the invention and the uncoated reference nozzles during water jet cutting, the water pressure was 2250 bar, the pH value of the water 7.3. Sand with a grain size of 260 μm and a feed rate of 9 g/s was again used as abrasive medium. As a result, prolongations of the service life of the coated focusing nozzles according to the invention compared with the uncoated focusing nozzles in the order of a factor of 1.3 to 1.6 were observed.
Claims (7)
1. A focusing nozzle for abrasive water jet cutting, comprising:
a nozzle body of hard metal;
said nozzle body having a bore formed therein with a bore wall for focusing an abrasive water cutting jet; and
a coating of hard material on said bore wall, said coating having a layer with a titanium nitride content at least at a free surface thereof.
2. The focusing nozzle according to claim 1 , wherein said coating is a single-layer coating.
3. The focusing nozzle according to claim 1 , wherein said coating is a multi-layer coating.
4. The focusing nozzle according to claim 1 , wherein said hard material coating is a single titanium nitride layer or a single titanium carbonitride layer.
5. The focusing nozzle according to claim 1 , wherein said hard material coating has a layer thickness in a range from 1 to 15 μm.
6. The focusing nozzle according to claim 5 , wherein said coating is a CVD process coating.
7. The The focusing nozzle according to claim 1 , wherein said hard metal of said nozzle body comprises up to 1.5 wt. % cobalt as a metallic binder, up to 3 wt. % mixed carbides, and a remainder tungsten carbide with a grain size of less than 0.4 μm.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ATGM591/2004 | 2004-08-16 | ||
| AT0059104U AT7925U1 (en) | 2004-08-16 | 2004-08-16 | focusing nozzle |
| PCT/AT2005/000320 WO2006017873A1 (en) | 2004-08-16 | 2005-08-09 | Focussing nozzle |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/AT2005/000320 Continuation WO2006017873A1 (en) | 2004-08-16 | 2005-08-09 | Focussing nozzle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20070161341A1 true US20070161341A1 (en) | 2007-07-12 |
Family
ID=34916765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/707,784 Abandoned US20070161341A1 (en) | 2004-08-16 | 2007-02-16 | Focusing nozzle |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20070161341A1 (en) |
| EP (1) | EP1796875B1 (en) |
| AT (2) | AT7925U1 (en) |
| CA (1) | CA2577151C (en) |
| DE (1) | DE502005004834D1 (en) |
| DK (1) | DK1796875T3 (en) |
| ES (1) | ES2307199T3 (en) |
| MX (1) | MX2007001816A (en) |
| PL (1) | PL1796875T3 (en) |
| WO (1) | WO2006017873A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100044025A1 (en) * | 2008-08-20 | 2010-02-25 | Martindale James G | Fluid perforating/cutting nozzle |
| US20100088894A1 (en) * | 2008-10-10 | 2010-04-15 | Stark Roger M | Method for preparing abrasive waterjet mixing tubes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5363556A (en) * | 1992-03-27 | 1994-11-15 | General Electric Company | Water jet mixing tubes used in water jet cutting devices and method of preparation thereof |
| US5626508A (en) * | 1995-04-20 | 1997-05-06 | Aqua-Dyne, Inc. | Focusing nozzle |
| US6425805B1 (en) * | 1999-05-21 | 2002-07-30 | Kennametal Pc Inc. | Superhard material article of manufacture |
| US6846221B2 (en) * | 2001-04-11 | 2005-01-25 | Lai East Laser Applications, Inc. | Adaptive nozzle system for high-energy abrasive stream cutting |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19640920C1 (en) * | 1996-10-04 | 1998-01-22 | Saechsische Werkzeug Und Sonde | Focussing nozzle for cutting by abrasive water-jet |
-
2004
- 2004-08-16 AT AT0059104U patent/AT7925U1/en not_active IP Right Cessation
-
2005
- 2005-08-09 CA CA2577151A patent/CA2577151C/en not_active Expired - Fee Related
- 2005-08-09 DE DE502005004834T patent/DE502005004834D1/en not_active Expired - Lifetime
- 2005-08-09 DK DK05769987T patent/DK1796875T3/en active
- 2005-08-09 WO PCT/AT2005/000320 patent/WO2006017873A1/en not_active Ceased
- 2005-08-09 ES ES05769987T patent/ES2307199T3/en not_active Expired - Lifetime
- 2005-08-09 MX MX2007001816A patent/MX2007001816A/en active IP Right Grant
- 2005-08-09 EP EP05769987A patent/EP1796875B1/en not_active Expired - Lifetime
- 2005-08-09 AT AT05769987T patent/ATE401992T1/en active
- 2005-08-09 PL PL05769987T patent/PL1796875T3/en unknown
-
2007
- 2007-02-16 US US11/707,784 patent/US20070161341A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5363556A (en) * | 1992-03-27 | 1994-11-15 | General Electric Company | Water jet mixing tubes used in water jet cutting devices and method of preparation thereof |
| US5626508A (en) * | 1995-04-20 | 1997-05-06 | Aqua-Dyne, Inc. | Focusing nozzle |
| US6425805B1 (en) * | 1999-05-21 | 2002-07-30 | Kennametal Pc Inc. | Superhard material article of manufacture |
| US20030045217A1 (en) * | 1999-05-21 | 2003-03-06 | Massa Ted R. | Superhard material article of manufacture |
| US6846221B2 (en) * | 2001-04-11 | 2005-01-25 | Lai East Laser Applications, Inc. | Adaptive nozzle system for high-energy abrasive stream cutting |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100044025A1 (en) * | 2008-08-20 | 2010-02-25 | Martindale James G | Fluid perforating/cutting nozzle |
| US7832481B2 (en) | 2008-08-20 | 2010-11-16 | Martindale James G | Fluid perforating/cutting nozzle |
| US20100088894A1 (en) * | 2008-10-10 | 2010-04-15 | Stark Roger M | Method for preparing abrasive waterjet mixing tubes |
Also Published As
| Publication number | Publication date |
|---|---|
| DK1796875T3 (en) | 2008-11-17 |
| MX2007001816A (en) | 2007-04-26 |
| ATE401992T1 (en) | 2008-08-15 |
| EP1796875A1 (en) | 2007-06-20 |
| PL1796875T3 (en) | 2009-01-30 |
| DE502005004834D1 (en) | 2008-09-04 |
| WO2006017873A1 (en) | 2006-02-23 |
| ES2307199T3 (en) | 2008-11-16 |
| CA2577151A1 (en) | 2006-02-23 |
| CA2577151C (en) | 2013-01-22 |
| AT7925U1 (en) | 2005-11-15 |
| EP1796875B1 (en) | 2008-07-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- AFTER EXAMINER'S ANSWER OR BOARD OF APPEALS DECISION |