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US20060165148A1 - Distributed Bragg's reflector of digital-alloy multinary compound semiconductor - Google Patents

Distributed Bragg's reflector of digital-alloy multinary compound semiconductor Download PDF

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US20060165148A1
US20060165148A1 US11/322,804 US32280405A US2006165148A1 US 20060165148 A1 US20060165148 A1 US 20060165148A1 US 32280405 A US32280405 A US 32280405A US 2006165148 A1 US2006165148 A1 US 2006165148A1
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compound semiconductor
alloy
digital
semiconductor layer
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Jin Song
Won Choi
Jung Lee
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Korea Institute of Science and Technology KIST
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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00—Table-ware
    • A47G21/02—Forks; Forks with ejectors; Combined forks and spoons; Salad servers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/10—Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/18—Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities
    • H01S5/183—Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities having only vertical cavities, e.g. vertical cavity surface-emitting lasers [VCSEL]
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00—Table-ware
    • A47G21/04—Spoons; Pastry servers
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00—Table-ware
    • A47G21/10—Sugar tongs; Asparagus tongs; Other food tongs
    • A47G21/103—Chop-sticks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S2304/00—Special growth methods for semiconductor lasers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S2304/00—Special growth methods for semiconductor lasers
    • H01S2304/02—MBE
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/81—Bodies
    • H10H20/814—Bodies having reflecting means, e.g. semiconductor Bragg reflectors
    • H10H20/8142—Bodies having reflecting means, e.g. semiconductor Bragg reflectors forming resonant cavity structures

Definitions

  • the present invention relates to a distributed Bragg's reflector of a digital-alloy multinary compound semiconductor.
  • DBR distributed Bragg's reflector
  • the DBR technique can make the reflectivity to be 100% or 0% in a desired wavelength according to the refractive index difference and the thickness of each layer.
  • the technique has been introduced to mainly fabricate filters and reflectors used in current optical devices such as camera lenses.
  • the device emits a light in a direction perpendicular to a plane forming the semiconductor active layer.
  • Such device has been often utilized as a light source in connection with small optical communication and optical recording apparatuses due to its low production costs, as well as its low optical spreading and optical coupling.
  • DBRs The key components of the vertical resonator device are DBRs, which are formed relative to the semiconductor active layer.
  • DBRs are generally fabricated by laminating dielectric materials each having a different refractive index or by laminating compound semiconductors, which are lattice-matched to a substrate and have differing compositions.
  • DBR is prepared by laminating a pair of AlGaAs/GaAs.
  • DBR can be prepared by laminating a pair of InGaAlAs/InGaAlAs in case of 1.3 to 1.55 ⁇ m broadband vertical resonator surface-emitting device, wherein the former InGaAlAs and the latter InGaAlAs have differing compositions.
  • the mean reflection wavelength of DBR changes too easily, even when there is a slight change in the composition and thickness.
  • the composition of materials is subjected to DBR changes due to an unequal heating of the substrate, thereby decreasing uniformity. Furthermore, since the composition and thickness must be controlled each time DBR is fabricated, there is needed a substantial effort to maintain the conditions of apparatus for fabricating the same, which obviously decreases productivity.
  • the present invention relates to a Bragg's reflector of a digital-alloy multinary compound semiconductor, which has such excellent properties.
  • the distributed Bragg's reflector of the present invention comprises a substrate and an unit distributed Bragg's reflector (DBR) layer, as well as a multi-layer laminated on the substrate.
  • Said unit DBR layer is composed of a multi-layer laminated structure of unit digital-alloy multinary compound semiconductor layer/multinary compound semiconductor layer or unit digital-alloy multinary compound semiconductor layer/unit digital-alloy multinary compound semiconductor layer.
  • Said unit digital-alloy multinary compound semiconductor layer is composed of the multi-layer laminated structure of the first layer of multinary compound semiconductor and the second layer of a different multinary compound semiconductor on said first layer.
  • the thickness of each layer constituting the unit digital-alloy multinary compound semiconductor layer may be smaller than the wavelength of the light inside the digital-alloy multinary compound semiconductor layer.
  • the multinary compound semiconductor layer constituting said unit DBR layer can be composed of a separate digital-alloy multinary compound semiconductor layer, which has a different composition from the digital-alloy multinary compound semiconductor layer that underlies the separate digital-alloy multinary compound semiconductor layer.
  • FIG. 1 shows a general structure of a distributed Bragg's reflector and a graph showing the relationship of wavelength vs. reflectivity, which is determined from the structure.
  • FIG. 2 a shows a structure of a conventional multinary compound semiconductor.
  • FIG. 2 b shows a digital-alloy multinary compound semiconductor according to the present invention.
  • FIG. 3 shows an exemplified method of fabricating a conventional multinary compound semiconductor (a), as well as that of fabricating a digital-alloy multinary compound semiconductor according to the present invention (b).
  • FIG. 4 shows a laminated structure of 17 Al 0.9 Ga 0.1 As/GaAs-paired layers in a conventional distributed Bragg's reflector.
  • FIG. 5 shows a laminated structure of 17 digital-alloy Al 0.9 Ga 0.1 As/GaAs-paired layers in a digital-alloy distributed Bragg's reflector of the present invention.
  • FIG. 6 is a graph showing a relationship between reflectivity and wavelength in the Bragg's reflector shown in FIGS. 4 and 5 .
  • FIG. 7 shows a structure of a digital-alloy distributed Bragg's reflector vertical resonator, which utilizes a digital-alloy Al 0.9 Ga 0.1 As/GaAs structure shown in FIG. 5 .
  • FIG. 8 is a graph showing a relationship between reflectivity, wavelength and large area (3 inches) uniformity in a digital-alloy distributed Bragg's reflector vertical resonator of the present invention.
  • a one unit DBR layer comprises a multi-layer laminated structure of AlGaAs digital-alloy multinary compound semiconductor layer/GaAs layer, wherein said AlGaAs digital-alloy multinary compound semiconductor layer comprises an AlAs layer and a GaAs layer on the AlAs layer.
  • the unit digital-alloy multinary compound semiconductor layer of the present invention can be selected from a group consisting of InGa(Al)As/In(Ga)AlAs, InGaAsP/InGaAsP, InGaP/InAlP, Si/(Si)Ge, (In)GaAlAsSb/(In)GaAlAsSb, InGaAlAs(N)/InGaAlAs(N) and SiO x /TiO x .
  • the present invention provides a vertical resonator surface light-emitting laser diode, a vertical resonance light-emitting diode (LED) and a photodetector including the distributed Bragg's reflector of the present invention.
  • digital-alloy means a material prepared by multi-layer laminating each of the unit composition materials (in case of AlGaAs, AlAs and GaAs) in an uniform thickness (e.g., 1 to 2 nm thickness in fabricating multinary compound semiconductor, ternary compound semiconductor such as AlGaAs, or quaternary compound semiconductor such as InGaAlAs.
  • the digital-alloy is used for discriminating against an ordinary multinary compound semiconductor (J. D. Song, D. C. Heo, I. K. H, J. M. Kim, Y. T. Lee, S. H. Park, “Parametric study on optical properties of digital-alloy In(Gal-zAlz)As/InP grown by molecular-beam epitaxy,” Appl. phys. lett. 84, pp. 873 (2004)).
  • FIG. 2 a shows the structure of a conventional multinary compound semiconductor.
  • FIG. 2 b shows the structure of a digital-alloy multinary compound semiconductor Al 0.5 Ga 0.5 As of the present invention.
  • the composition of Al 0.5 Ga 0.5 As digital-alloy of the present invention depends on the ratio of thickness of each unit composition material.
  • FIG. 3 illustrates a method of fabricating the conventional multinary compound semiconductor (a), as well as that of the digital-alloy multinary compound semiconductor Al 0.5 Ga 0.5 As according to the present invention (b).
  • the representative compound semiconductor growth method that is, molecular beam epitaxy. From FIG. 3 , it can be noted that it is possible to grow the structure of FIG. 2 a by (a) of FIG. 3 as well as the structure of FIG. 2 b by (b) of FIG. 3 .
  • the apparatus used for fabricating the structure of FIG. 4 and FIG. 5 is a molecular beam growth apparatus, V80 manufactured by VG Semicon (UK).
  • the apparatus used an ion pump for performing a vacuum formation, wherein the vacuum before growth was 2.5 ⁇ 10 ⁇ 11 torr and the vacuum during the growth was 2 ⁇ 10 ⁇ 7 torr or less.
  • the apparatus is equipped with two Ga sources, one Al source and one As source.
  • the respective growth rate of AlAs and GaAs are 2 ⁇ /s and 2.4 ⁇ /s.
  • the GaAs growth rates of two Ga sources were set at 2.4 ⁇ /s and 0.22 ⁇ /s, respectively, so that all structures can be grown without any growth stoppage.
  • the pressure ratio of As/Ga was about 10:1.
  • GaAs substrate was heated at a temperature of 600° C. to remove the oxidizing film of the substrate surface. The temperature was then decreased to 580° C. so that GaAs, which has a thickness of about 100 nm, may be grown as a buffer. Thereafter, the structures of FIG. 4 and FIG. 5 were grown at 580°.
  • the conventional multinary compound semiconductor as shown in FIG. 4 , was fabricated by laminating the GaAs (thickness: 95.2 nm)/Al 0.9 Ga 0.1 As (thickness: 109.9 nm)-paired layer on the GaAs substrate seventeen (17) times. That is, as exemplified in (a) of FIG. 3 , in fabricating Al 0.9 Ga 0.1 As, the As source shutter is always opened (As supply state). The Al source shutter set to 2 ⁇ /s of the growth rate in growing AlAs, as well as the Ga source shutter set to 0.22 ⁇ /s of the growth rate in growing GaAs, are opened at once.
  • the growth rate of Al 0.9 Ga 0.1 As is 2.22 ⁇ /s and thus, the desired Al 0.9 Ga 0.1 As of 109.9 nm can be obtained during growth of about 495.0 seconds.
  • another Ga source is used, wherein said source is set to the growth rate of 2.4 ⁇ /s in growing GaAs (the growth period of about 396.6 seconds). Therefore, a total of two Ga sources are necessary for fabricating all structures without any interruption of growth. The entire structure is completely fabricated by laminating the Al 0.9 Ga 0.1 As/GaAs-paired layer seventeen (17) times.
  • the digital-alloy of the present invention was fabricated by multi-layer laminating on the GaAs substrate a pair of GaAs having the thickness of 95.2 nm and the digital-alloy Al 0.9 Ga 0.1 As as shown in FIG. 5 .
  • the digital-alloy Al 0.9 Ga 0.1 As was fabricated by laminating GaAs (thickness: 0.283 nm)/AlAs (thickness: 2.547 nm)-paired layer thirty-nine (39) times.
  • the thickness ratio of each unit composition material (GaAs:AlAs) is 1:9, on which the composition of Al 0.9 Ga 0.1 As digital-alloy depends.
  • the Al 0.9 Ga 0.1 As digital-alloy was manufactured as in shown in (b) of FIG. 3 .
  • the shutter of As source was always opened (As supply state), wherein the Al source shutter set to 2 ⁇ /s of the growth rate in growing AlAs and the Ga source shutter set to 2.4 ⁇ /s of the growth rate in growing GaAs were opened successively. That is, the Ga source shutter was opened for 1.2 seconds, thereby growing GaAs having the thickness of 0.283 nm. Thereafter, the Al source shutter was opened for 12.7 seconds to grow AlAs having a thickness of 2.547 nm. It does not matter whether GaAs or AlAs is grown first. Rather, it is important that the shutters of Ga and Al sources are not opened at once.
  • the shutter of Ga source and the shutter of Al source should be repetitively opened in a successive manner.
  • laminating such grown GaAs and AlAs thirty-nine (39) times it results in the formation of the Al 0.9 Ga 0.1 As digital-alloy.
  • the GaAs layer having a thickness of 95.2 nm is made by using the Ga source, which is previously set to 2.4 ⁇ /s of the growth rate in growing GaAs (growth period of about 396.6 seconds). Therefore, only one Ga source is required for fabricating all structures without any interruption of growth.
  • the entire structure was fabricated by laminating the Al 0.9 Ga 0.1 As digital-alloy/GaAs-paired layer seventeen (17) times.
  • FIG. 6 is a graph showing the computer simulation results of reflectivity vs. wavelength in the Bragg's reflector, which is shown in FIGS. 4 and 5 . From FIG. 6 , it was noted that two reflectivity were substantially identical with just a slight difference. This means that the digital-alloy Bragg's reflector of the present invention showed a refractive index identical to the conventional alloy for a light having a wavelength of 1.3 ⁇ m. This also means that the influence by each interface does not occur since the thickness of the unit composition material in the digital-alloy is merely 1/150 of the wavelength of light in the semiconductor (refractive index: ⁇ 3.5).
  • FIG. 7 shows a structure of the digital-alloy distributed Bragg's reflector vertical resonator, which utilizes the digital-alloy Al 0.9 Ga 0.1 As/GaAs structure of the present invention shown in FIG. 5 .
  • FIG. 8 is a graph showing the relationship of reflectivity, wavelength and large area (3 inches) uniformity in the digital-alloy distributed Bragg's reflector vertical resonator, which utilizes the Al 0.9 Ga 0.1 As/GaAs structure of the present invention as shown in FIG. 7 .
  • the reflectivity is sharply decreased at the central position in the determined reflectivity graph. This is because Fabry-Perot passing phenomenon occurs due to two reflectors, which are present at the upper and lower positions of the device.
  • the present invention used a distributed level [ ⁇ (determined maximum value+minimum value) ⁇ average value ⁇ /average value] as the standard of determining uniformity, which is ordinarily used in the relevant industry. In other words, as the distributed level becomes lower, it is generally considered that the substrate uniformity becomes better.
  • the large area (3 inches) distributed level of Fabry-Perot passing wavelength is 0.35%.
  • each unit composition material is grown in a time interval in the digital-alloy method shown in FIG. 2 , only a composite material (e.g., GaAs or AlAs) grows when grown on the substrate. That is, the composition change due to the substrate area and temperature imbalance during the growth period does not affect such growth of the composition material. Further, since the growth rate of the elemental compound can be measured in a direct method during the growth of the compound in the growth apparatus, the growth rate of each elemental compound can be accurately identified regardless of the experimental frequency. For these reasons, the digital-alloy semiconductor achieves both the area and time uniformity.
  • a composite material e.g., GaAs or AlAs
  • the digital-alloy distributed Bragg's reflector of the present invention has a uniform quality on the substance area and the filter and reflector having uniformly high quality can be mass produced by using the reflector.
  • the group IV semiconductors such as Si/(Si)Ge may be also be used in the semiconductor layer in some embodiments of the present invention, although Si/(Si)Ge forms a binary alloy, not a multinary alloy.
  • Si/(Si)Ge forms a binary alloy, not a multinary alloy.

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Semiconductor Lasers (AREA)

Abstract

There is provided a distributed Bragg's reflector (DBR) comprising a substrate and an unit distributed Bragg's reflector (DBR) layer, wherein a multi-layer is laminated on the substrate. The unit DBR layer is composed of a multi-layer laminated structure of unit digital-alloy multinary compound semiconductor layer/multinary compound semiconductor layer or unit digital-alloy multinary compound semiconductor layer/unit digital-alloy multinary compound semiconductor layer. The unit digital-alloy multinary compound semiconductor layer is composed of the multi-layer laminated structure of the first layer of multinary compound semiconductor and the second layer of a different multinary compound semiconductor on said first layer. The digital-alloy distributed Bragg's reflector of the present invention has a uniform quality on the substance area and the filter and reflector having uniformly high quality can be mass produced by using the reflector.

Description

    FIELD OF THE INVENTION
  • The present invention relates to a distributed Bragg's reflector of a digital-alloy multinary compound semiconductor.
    • BACKGROUND OF THE INVENTION
  • When forming materials each having a different refractive index, it is inevitable that there is a change of reflectivity within a certain wavelength range (FIG. 1). The structure formed in such a manner is referred to as a distributed Bragg's reflector (DBR).
  • In particular, the DBR technique can make the reflectivity to be 100% or 0% in a desired wavelength according to the refractive index difference and the thickness of each layer. Thus, the technique has been introduced to mainly fabricate filters and reflectors used in current optical devices such as camera lenses. A device, which is manufactured by applying the DBR technique to fabricate a semiconductor laser resonator, is referred to as a vertical resonator surface-emitting device (see H. Li, K. Iga, “Vertical Cavity Surface-Emitting Laser Devices,” Springer, Berlin, 2002). The device emits a light in a direction perpendicular to a plane forming the semiconductor active layer. Such device has been often utilized as a light source in connection with small optical communication and optical recording apparatuses due to its low production costs, as well as its low optical spreading and optical coupling.
  • The key components of the vertical resonator device are DBRs, which are formed relative to the semiconductor active layer. DBRs are generally fabricated by laminating dielectric materials each having a different refractive index or by laminating compound semiconductors, which are lattice-matched to a substrate and have differing compositions.
  • For example, in case of a commercially available vertical resonator surface-emitting device having a mean wavelength of 0.98 μm, DBR is prepared by laminating a pair of AlGaAs/GaAs. Also, DBR can be prepared by laminating a pair of InGaAlAs/InGaAlAs in case of 1.3 to 1.55 μm broadband vertical resonator surface-emitting device, wherein the former InGaAlAs and the latter InGaAlAs have differing compositions. However, the mean reflection wavelength of DBR changes too easily, even when there is a slight change in the composition and thickness.
  • In a large area semiconductor, the composition of materials is subjected to DBR changes due to an unequal heating of the substrate, thereby decreasing uniformity. Furthermore, since the composition and thickness must be controlled each time DBR is fabricated, there is needed a substantial effort to maintain the conditions of apparatus for fabricating the same, which obviously decreases productivity.
    • SUMMARY OF THE INVENTION
  • Therefore, it is an object of the present invention to provide a Bragg's reflector of a digital-alloy multinary compound semiconductor, which is capable of obtaining uniformity in mass production while displaying uniformity in fabricating a large area reflector.
  • Thus, the present invention relates to a Bragg's reflector of a digital-alloy multinary compound semiconductor, which has such excellent properties.
  • More specifically, the distributed Bragg's reflector of the present invention comprises a substrate and an unit distributed Bragg's reflector (DBR) layer, as well as a multi-layer laminated on the substrate. Said unit DBR layer is composed of a multi-layer laminated structure of unit digital-alloy multinary compound semiconductor layer/multinary compound semiconductor layer or unit digital-alloy multinary compound semiconductor layer/unit digital-alloy multinary compound semiconductor layer. Said unit digital-alloy multinary compound semiconductor layer is composed of the multi-layer laminated structure of the first layer of multinary compound semiconductor and the second layer of a different multinary compound semiconductor on said first layer.
  • In said distributed Bragg's reflector of the present invention, the thickness of each layer constituting the unit digital-alloy multinary compound semiconductor layer may be smaller than the wavelength of the light inside the digital-alloy multinary compound semiconductor layer.
  • Furthermore, the multinary compound semiconductor layer constituting said unit DBR layer can be composed of a separate digital-alloy multinary compound semiconductor layer, which has a different composition from the digital-alloy multinary compound semiconductor layer that underlies the separate digital-alloy multinary compound semiconductor layer.
  • This and other objects and advantages of the present invention will be clarified in the following detailed description of the invention provided below.
    • BRIEF DESCRIPTION OF DRAWINGS
  • The above and other objects and features of the present invention will become apparent from the following description of the preferred examples given in conjunction with the accompanying drawings:
  • FIG. 1 shows a general structure of a distributed Bragg's reflector and a graph showing the relationship of wavelength vs. reflectivity, which is determined from the structure.
  • FIG. 2 a shows a structure of a conventional multinary compound semiconductor.
  • FIG. 2 b shows a digital-alloy multinary compound semiconductor according to the present invention.
  • FIG. 3 shows an exemplified method of fabricating a conventional multinary compound semiconductor (a), as well as that of fabricating a digital-alloy multinary compound semiconductor according to the present invention (b).
  • FIG. 4 shows a laminated structure of 17 Al0.9Ga0.1As/GaAs-paired layers in a conventional distributed Bragg's reflector.
  • FIG. 5 shows a laminated structure of 17 digital-alloy Al0.9Ga0.1As/GaAs-paired layers in a digital-alloy distributed Bragg's reflector of the present invention.
  • FIG. 6 is a graph showing a relationship between reflectivity and wavelength in the Bragg's reflector shown in FIGS. 4 and 5.
  • FIG. 7 shows a structure of a digital-alloy distributed Bragg's reflector vertical resonator, which utilizes a digital-alloy Al0.9Ga0.1As/GaAs structure shown in FIG. 5.
  • FIG. 8 is a graph showing a relationship between reflectivity, wavelength and large area (3 inches) uniformity in a digital-alloy distributed Bragg's reflector vertical resonator of the present invention.
    • DETAILED DESCRIPTION OF THE PRESENT INVENTION
  • According to one embodiment of the present invention, a one unit DBR layer comprises a multi-layer laminated structure of AlGaAs digital-alloy multinary compound semiconductor layer/GaAs layer, wherein said AlGaAs digital-alloy multinary compound semiconductor layer comprises an AlAs layer and a GaAs layer on the AlAs layer.
  • Further, the unit digital-alloy multinary compound semiconductor layer of the present invention can be selected from a group consisting of InGa(Al)As/In(Ga)AlAs, InGaAsP/InGaAsP, InGaP/InAlP, Si/(Si)Ge, (In)GaAlAsSb/(In)GaAlAsSb, InGaAlAs(N)/InGaAlAs(N) and SiOx/TiOx.
  • Moreover, the present invention provides a vertical resonator surface light-emitting laser diode, a vertical resonance light-emitting diode (LED) and a photodetector including the distributed Bragg's reflector of the present invention.
  • The term “digital-alloy,” as used herein, means a material prepared by multi-layer laminating each of the unit composition materials (in case of AlGaAs, AlAs and GaAs) in an uniform thickness (e.g., 1 to 2 nm thickness in fabricating multinary compound semiconductor, ternary compound semiconductor such as AlGaAs, or quaternary compound semiconductor such as InGaAlAs. The digital-alloy is used for discriminating against an ordinary multinary compound semiconductor (J. D. Song, D. C. Heo, I. K. H, J. M. Kim, Y. T. Lee, S. H. Park, “Parametric study on optical properties of digital-alloy In(Gal-zAlz)As/InP grown by molecular-beam epitaxy,” Appl. phys. lett. 84, pp. 873 (2004)).
  • FIG. 2 a shows the structure of a conventional multinary compound semiconductor. FIG. 2 b shows the structure of a digital-alloy multinary compound semiconductor Al0.5Ga0.5As of the present invention. The composition of Al0.5Ga0.5As digital-alloy of the present invention depends on the ratio of thickness of each unit composition material. FIG. 3 illustrates a method of fabricating the conventional multinary compound semiconductor (a), as well as that of the digital-alloy multinary compound semiconductor Al0.5Ga0.5As according to the present invention (b). There is illustrated a specific action of a shutter for fabricating the conventional multinary compound semiconductor and the digital-alloy multinary compound semiconductor of the present invention by using the representative compound semiconductor growth method, that is, molecular beam epitaxy. From FIG. 3, it can be noted that it is possible to grow the structure of FIG. 2 a by (a) of FIG. 3 as well as the structure of FIG. 2 b by (b) of FIG. 3.
  • The features and effects of the present invention will now be described in detail while presenting as one embodiment the distributed Bragg's reflector fabricated by laminating the Al0.9Ga0.1As/GaAs-paired layer seventeen (17) times.
  • The apparatus used for fabricating the structure of FIG. 4 and FIG. 5 is a molecular beam growth apparatus, V80 manufactured by VG Semicon (UK). The apparatus used an ion pump for performing a vacuum formation, wherein the vacuum before growth was 2.5×10−11 torr and the vacuum during the growth was 2×10−7 torr or less. The apparatus is equipped with two Ga sources, one Al source and one As source. The respective growth rate of AlAs and GaAs are 2 Å/s and 2.4 Å/s. In growing AlGaAs, the GaAs growth rates of two Ga sources were set at 2.4 Å/s and 0.22 Å/s, respectively, so that all structures can be grown without any growth stoppage. The pressure ratio of As/Ga was about 10:1. GaAs substrate was heated at a temperature of 600° C. to remove the oxidizing film of the substrate surface. The temperature was then decreased to 580° C. so that GaAs, which has a thickness of about 100 nm, may be grown as a buffer. Thereafter, the structures of FIG. 4 and FIG. 5 were grown at 580°.
  • The conventional multinary compound semiconductor, as shown in FIG. 4, was fabricated by laminating the GaAs (thickness: 95.2 nm)/Al0.9Ga0.1As (thickness: 109.9 nm)-paired layer on the GaAs substrate seventeen (17) times. That is, as exemplified in (a) of FIG. 3, in fabricating Al0.9Ga0.1As, the As source shutter is always opened (As supply state). The Al source shutter set to 2 Å/s of the growth rate in growing AlAs, as well as the Ga source shutter set to 0.22 Å/s of the growth rate in growing GaAs, are opened at once. At this time, the growth rate of Al0.9Ga0.1As is 2.22 Å/s and thus, the desired Al0.9Ga0.1As of 109.9 nm can be obtained during growth of about 495.0 seconds. In fabricating the GaAs layer having 95.2 nm thickness, another Ga source is used, wherein said source is set to the growth rate of 2.4 Å/s in growing GaAs (the growth period of about 396.6 seconds). Therefore, a total of two Ga sources are necessary for fabricating all structures without any interruption of growth. The entire structure is completely fabricated by laminating the Al0.9Ga0.1As/GaAs-paired layer seventeen (17) times.
  • The digital-alloy of the present invention was fabricated by multi-layer laminating on the GaAs substrate a pair of GaAs having the thickness of 95.2 nm and the digital-alloy Al0.9Ga0.1As as shown in FIG. 5. Herein, the digital-alloy Al0.9Ga0.1As was fabricated by laminating GaAs (thickness: 0.283 nm)/AlAs (thickness: 2.547 nm)-paired layer thirty-nine (39) times. The thickness ratio of each unit composition material (GaAs:AlAs) is 1:9, on which the composition of Al0.9Ga0.1As digital-alloy depends. The Al0.9Ga0.1As digital-alloy was manufactured as in shown in (b) of FIG. 3. The shutter of As source was always opened (As supply state), wherein the Al source shutter set to 2 Å/s of the growth rate in growing AlAs and the Ga source shutter set to 2.4 Å/s of the growth rate in growing GaAs were opened successively. That is, the Ga source shutter was opened for 1.2 seconds, thereby growing GaAs having the thickness of 0.283 nm. Thereafter, the Al source shutter was opened for 12.7 seconds to grow AlAs having a thickness of 2.547 nm. It does not matter whether GaAs or AlAs is grown first. Rather, it is important that the shutters of Ga and Al sources are not opened at once. That is, the shutter of Ga source and the shutter of Al source should be repetitively opened in a successive manner. When laminating such grown GaAs and AlAs thirty-nine (39) times, it results in the formation of the Al0.9Ga0.1As digital-alloy. The GaAs layer having a thickness of 95.2 nm is made by using the Ga source, which is previously set to 2.4 Å/s of the growth rate in growing GaAs (growth period of about 396.6 seconds). Therefore, only one Ga source is required for fabricating all structures without any interruption of growth. The entire structure was fabricated by laminating the Al0.9Ga0.1As digital-alloy/GaAs-paired layer seventeen (17) times.
  • FIG. 6 is a graph showing the computer simulation results of reflectivity vs. wavelength in the Bragg's reflector, which is shown in FIGS. 4 and 5. From FIG. 6, it was noted that two reflectivity were substantially identical with just a slight difference. This means that the digital-alloy Bragg's reflector of the present invention showed a refractive index identical to the conventional alloy for a light having a wavelength of 1.3 μm. This also means that the influence by each interface does not occur since the thickness of the unit composition material in the digital-alloy is merely 1/150 of the wavelength of light in the semiconductor (refractive index: ≦3.5).
  • FIG. 7 shows a structure of the digital-alloy distributed Bragg's reflector vertical resonator, which utilizes the digital-alloy Al0.9Ga0.1As/GaAs structure of the present invention shown in FIG. 5. FIG. 8 is a graph showing the relationship of reflectivity, wavelength and large area (3 inches) uniformity in the digital-alloy distributed Bragg's reflector vertical resonator, which utilizes the Al0.9Ga0.1As/GaAs structure of the present invention as shown in FIG. 7.
  • As shown in FIG. 8, the reflectivity is sharply decreased at the central position in the determined reflectivity graph. This is because Fabry-Perot passing phenomenon occurs due to two reflectors, which are present at the upper and lower positions of the device. There are many methods of determining the substrate uniformity. The present invention used a distributed level [{(determined maximum value+minimum value)−average value}/average value] as the standard of determining uniformity, which is ordinarily used in the relevant industry. In other words, as the distributed level becomes lower, it is generally considered that the substrate uniformity becomes better. The large area (3 inches) distributed level of Fabry-Perot passing wavelength is 0.35%. When considering that the average distributed level of 2 inch-substrate in the industry is 1% and the area of 3 inch-substrate is almost twice as large as the 2 inch-substrate, it can be noted that the example of the present invention shows 6 times higher uniformity than the conventional DBR.
  • Since each unit composition material is grown in a time interval in the digital-alloy method shown in FIG. 2, only a composite material (e.g., GaAs or AlAs) grows when grown on the substrate. That is, the composition change due to the substrate area and temperature imbalance during the growth period does not affect such growth of the composition material. Further, since the growth rate of the elemental compound can be measured in a direct method during the growth of the compound in the growth apparatus, the growth rate of each elemental compound can be accurately identified regardless of the experimental frequency. For these reasons, the digital-alloy semiconductor achieves both the area and time uniformity.
  • Furthermore, since all multinary compounds are manufactured by using the elemental compound, the multinary compound having various compositions can be grown homogenously on one substrate. For this reason, the structure of the growing apparatus can be simplified and it is easy to maintain and operate the apparatus, thereby improving productivity. Therefore, the digital-alloy distributed Bragg's reflector of the present invention has a uniform quality on the substance area and the filter and reflector having uniformly high quality can be mass produced by using the reflector.
  • The group IV semiconductors such as Si/(Si)Ge may be also be used in the semiconductor layer in some embodiments of the present invention, although Si/(Si)Ge forms a binary alloy, not a multinary alloy. Furthermore, while the present invention has been shown and described with respect to a preferred embodiment, those skilled in the art will recognize that various changes and modifications may be made without departing from the scope of the invention as defined in the appended claims.

Claims (18)

1. A distributed Bragg's reflector (DBR) comprising a substrate and a unit distributed Bragg's reflector (DBR) layer formed by laminating a plurality of layers, on the substrate, and wherein said unit DBR layer comprises one or more of a multi-layer laminated structure of unit digital-alloy multinary compound semiconductor layer/multinary compound semiconductor layer and a first unit digital-alloy multinary compound semiconductor layer/a second unit digital-alloy multinary compound semiconductor layer, and wherein said unit digital-alloy multinary compound semiconductor layer is composed of the multi-layer laminated structure of a first layer of multinary compound semiconductor and a second layer of a different multinary compound semiconductor on said first layer.
2. The distributed Bragg's reflector according to claim 1, wherein a thickness of each layer constituting the unit digital-alloy multinary compound semiconductor layer is smaller than a wavelength of light inside the digital-alloy multinary compound semiconductor layer.
3. The distributed Bragg's reflector according to claim 1, wherein the multinary compound semiconductor layer constituting said unit DBR layer is a separate digital-alloy multinary compound semiconductor layer having a different composition from a digital-alloy multinary compound semiconductor layer that underlies the separate digital-alloy multinary compound semiconductor layer.
4. The distributed Bragg's reflector according to claim 1, wherein the unit DBR layer comprises the multi-layer laminated structure of AlGaAs digital-alloy multinary compound semiconductor layer/GaAs layer.
5. The distributed Bragg's reflector according to claim 4, wherein the AlGaAs digital-alloy multinary compound semiconductor layer comprises a AlAs layer and the GaAs layer on a AlAs layer.
6. The distributed Bragg's reflector according to claim 1, wherein the unit digital-alloy multinary compound semiconductor layer is selected from a group consisting of InGa(Al)As/In(Ga)AlAs, InGaAsP/InGaAsP, InGaP/InAlP, (1 n)GaAlAsSb/(In)GaAlAsSb, InGaAlAs(N)/InGaAlAs(N) and SiOx/TiOx.
7. A vertical resonator surface light-emitting laser diode comprising the distributed Bragg's reflector according to claim 1.
8. A vertical resonance light-emitting diode comprising the distributed Bragg's reflector according to claim 1.
9. A photodetector comprising the distributed Bragg's reflector according to claim 1.
10. A resonator comprising a substrate and at least one distributed Bragg's reflector (DBR) layer formed by laminating one or more layers on the substrate, and wherein said DBR layer comprises at least one layer of a digital-alloy multinary compound semiconductor layer, wherein the digital-alloy multinary compound semiconductor layer is formed by deposition of a plurality of layers that together form the multinary compound semiconductor layer.
11. The resonator according to claim 10, wherein a thickness of each layer constituting the digital-alloy multinary compound semiconductor layer is smaller than a wavelength of light inside the digital-alloy multinary compound semiconductor layer.
12. The resonator according to claim 10, wherein the multinary compound semiconductor layer constituting said DBR layer is a separate digital-alloy multinary compound semiconductor layer having a different composition from an underlying digital-alloy multinary compound semiconductor layer.
13. The resonator according to claim 10, wherein the DBR layer comprises the multi-layer laminated structure of AlGaAs digital-alloy multinary compound semiconductor layer/GaAs layer.
14. The resonator according to claim 13, wherein the AlGaAs digital-alloy multinary compound semiconductor layer comprises a AlAs layer and a GaAs layer on the AlAs layer.
15. The resonator according to claim 10, wherein the digital-alloy multinary compound semiconductor layer is selected from a group consisting of InGa(Al)As/In(Ga)AlAs, InGaAsP/InGaAsP, InGaP/InAlP, (In)GaAlAsSb/(In)GaAlAsSb, InGaAlAs(N)/InGaAlAs(N) and SiOx/TiOx.
16. A method of making a resonator, the method comprising:
forming a distributed Bragg's reflector (DBR) layer by laminating on a substrate a plurality layers comprising at least one digital-alloy multinary compound semiconductor layer, wherein laminating the at least one digital-alloy multinary compound semiconductor layer includes the steps of depositing a plurality of layers that together form the multinary compound semiconductor layer.
17. The method of claim 16 further comprising the step of forming in the DBR layer at least one multi-layer laminated structure of AlGaAs digital-alloy multinary compound semiconductor layer/GaAs layer by laminating a AlAs layer on a AlAs layer.
18. The method of claim 16, wherein a thickness of each layer constituting the digital-alloy multinary compound semiconductor layer is smaller than a wavelength of light inside the digital-alloy multinary compound semiconductor layer.
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