US20060144875A1 - Flexible container containing a liquid product, and a process for making a liquid-filled, flexible container - Google Patents
Flexible container containing a liquid product, and a process for making a liquid-filled, flexible container Download PDFInfo
- Publication number
- US20060144875A1 US20060144875A1 US11/312,316 US31231605A US2006144875A1 US 20060144875 A1 US20060144875 A1 US 20060144875A1 US 31231605 A US31231605 A US 31231605A US 2006144875 A1 US2006144875 A1 US 2006144875A1
- Authority
- US
- United States
- Prior art keywords
- closure
- flexible container
- liquid product
- liquid
- self
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 31
- 239000012263 liquid product Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000007789 sealing Methods 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 4
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 7
- 239000002985 plastic film Substances 0.000 description 4
- 229920006255 plastic film Polymers 0.000 description 4
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 239000013536 elastomeric material Substances 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D75/5861—Spouts
- B65D75/5872—Non-integral spouts
- B65D75/5883—Non-integral spouts connected to the package at the sealed junction of two package walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/04—Deformable containers producing the flow, e.g. squeeze bottles
- B05B11/047—Deformable containers producing the flow, e.g. squeeze bottles characterised by the outlet or venting means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/008—Standing pouches, i.e. "Standbeutel"
Definitions
- the present invention relates to a flexible container containing a liquid product, and to a process for making a liquid-filled, flexible container.
- the flexible container may be, for example, a pouch or bag, and it is preferably made from a plastic film.
- Flexible pouches which comprise some sort of spout are useful as packaging for various sorts of products including drinks.
- the spout may be closed by means of a screw cap, or a flip-top cap.
- U.S. Pat. No. 5,307,955 issued on May 3, 1994, discloses a lightweight bottom delivery package for fluid products which incorporates a closure comprising a self-sealing valve and a flip-top cap.
- the flexible container according to the present invention contains a liquid product, wherein the flexible container comprises a closure having an inner end and an outer end, the closure being fixed through the wall of the flexible container such that the inner end of the closure lies within the flexible container and is in contact with the liquid product, and the outer end of the closure lies outside of the flexible container, wherein the closure has an open position and a closed position, and wherein the outer end of the closure is connected to a valve.
- the valve is a self-sealing valve which opens when the closure is in the open position and when pressure is applied to the liquid product within the flexible container, and which closes when the pressure is released.
- the present invention further relates to a process for making such a flexible container.
- FIG. 1 a shows cross-section, A-A, of a flexible container with a closure according to the present invention. The closure is shown in the open position.
- FIG. 1 b shows a top view of the flexible container and closure.
- FIG. 2 a shows cross-section, A-A, of a flexible container with a closure according to the present invention. The closure is shown in the open position.
- FIG. 3 shows an assembly view of a flexible container and closure according to the present invention in perspective.
- FIG. 4 shows a perspective view of the liquid-filled, flexible container of the present invention.
- the closure of the present invention may consist of two concentric cylinders: an outer female cylinder and an inner male cylinder.
- the inner male cylinder has a blind end, and has at least one hole in the curved cylinder wall.
- a closure as described in WO99/05446, published on Feb. 4, 1999 may be used.
- the female part has an axial bore and a plug which closes off the bore.
- a cooperating male part is provided, and the plug and the male part are provided with cooperating connection devices which connect the plug with the male part when the male part is inserted into the bore and which maintain this connection when the male part is inserted further into the bore.
- the plug is provided with at least one hooking part which keeps the plug in the bore until the plug and the male part are connected to each other while the male part is inserted into the bore.
- the male and female parts of the connecting device may cooperate by means of a simple push-pull action, or these two components may be connected by means of a screw thread. These variations are illustrated in FIGS. 2 and 4 of WO00/66448, published on Nov. 9, 2000.
- the connecting device further comprises a self-sealing valve.
- a self-sealing valve is typically made from an elastomeric material such as silicone or thermoplastic elastomer (TPE).
- TPE thermoplastic elastomer
- the valve has one or more slits cut through the elastomeric material.
- the valve may have two mutually orthogonal slits. The rate at which liquid product is dispensed under pressure from the container may be controlled by selecting the size and configuration of the slits in the self-sealing valve.
- Self-sealing valves are commercially available, one example of such valves is sold under the Trade Name SimpliSqueeze, supplied by Seaquist Closures, of Mukwonago, Wis., US.
- flexible containers of the present invention are formed from plastic film or films which are sealed together at the edge in order to form a closed container.
- the container is provided with an opening which is sealed around the closure.
- the plastic film is made from polyethylene, polypropylene, polyester or laminate thereof and has a thickness of from 50 to 250 micrometers.
- the liquid which fills the liquid container may be of any type of liquid, including relatively viscous gels and pastes.
- the only limitation upon viscosity is that it should be possible to dispense the liquid under pressure through the self-sealing valve.
- suitable liquid products include detergent products, for example dish washing detergent liquid, and fabric treatment products, for example fabric softening liquid compositions.
- FIG. 1 illustrates a closure comprising a female part ( 10 ) which comprises a collar ( 12 ) which is secured within the opening of the flexible container ( 2 ).
- the female part ( 10 ) further comprises an axial bore ( 14 ) and a plug ( 16 ).
- the plug ( 16 ) is provided with at least one hooking part ( 18 ) which enables the plug ( 16 ) to be removably sealed within the axial bore ( 14 ).
- the male part ( 20 ) comprises a cylindrical section ( 22 ) which fits within the axial bore ( 14 ) of the female part ( 10 ) and which can be moved axially therein.
- the end ( 26 ) of the cylindrical section ( 22 ) removably engages with the plug ( 16 ).
- the male part ( 20 ) and the female part ( 10 ) are mutually interconnected by means of a screw thread ( 28 ) so that the male part ( 20 ) moves axially within the bore ( 14 ) of the female part ( 10 ) when the screw thread ( 28 ) is engaged, thereby releasing the plug ( 16 ) from the bore ( 14 ), and moves axially in the opposite direction when the screw thread ( 28 ) is disengaged thereby closing bore ( 14 ) with the plug ( 16 ).
- the open position is illustrated by FIG. 1 ; the closed position is illustrated by FIG. 2 .
- the male part ( 20 ) comprises an axial bore ( 24 ).
- the axial bore ( 24 ) houses a self-sealing valve ( 30 ).
- a cap ( 40 ) covers the closure assembly.
- the cap ( 40 ) may be clipped onto the male part ( 20 ) to facilitate the opening and closing of the closure.
- the resulting assembly provides a one-way valve closure wherein the self-sealing valve ( 30 ) does not permit air to be vented back into the flexible container ( 2 ).
- the closure has a closed position ( FIG. 2 ) which is the position in which the plug ( 16 ) is engaged within the bore ( 14 ). In the closed position no liquid can be dispensed from the flexible container ( 2 ). The closed position prevents leakage or accidental dispensing during transport and during storage.
- the closure has an open position ( FIG. 1 ) which is the position in which the plug ( 16 ) is disengaged from the bore ( 14 ). In the open position no liquid is discharged until the liquid pressure exceeds the threshold pressure of the self-sealing valve ( 30 ). When the threshold pressure is exceeded, the self-sealing valve ( 30 ) opens and liquid is dispensed from the container ( 2 ) until the applied pressure is released and the self-sealing valve ( 30 ) recloses.
- the liquid within the flexible container ( 2 ) is free, or at least substantially free of any gas, for example the liquid is free, or at least substantially free of any air.
- FIG. 3 shows an assembly view of a flexible container and closure according to the present invention in perspective.
- FIG. 4 shows a perspective view of the liquid-filled, flexible container of the present invention, incorporating the closure described in detail above.
- the container shown in FIG. 4 is self standing, wherein the closure is positioned at the top of the flexible container ( 2 ) when the container is self-standing on the base ( 3 ).
- the liquid-filled flexible container is formed and filled by the following process steps:
- the self-sealing valve ( 30 ) is integrally molded into the male part ( 20 ) of the closure. More preferably the self-sealing valve ( 30 ) is molded into the male part ( 20 ) of the closure by means of a co-injection process.
- the female part ( 10 ) of the closure is sealed by means of a releasably fitted plug ( 16 ) such as is described in WO00/66448.
- This process facilitates the filling of the flexible bag with the exclusion of essentially any gas, in particular with the exclusion of essentially any air.
- the male and female parts of the closure are fitted together by means of a screw thread ( 28 ), and wherein the closure is opened by rotating the male part ( 20 ) relative to the female part ( 10 ), and wherein the closure is closed by counter-rotating the male part ( 20 ) relative to the female part ( 10 ).
- the advantages of the closure of the present invention include the avoidance of leaking or accidental discharge which may occur when a self-sealing valve is used as the only closing means, or even when a self-sealing valve is used in combination with a flip-top cap. Further, since the closure is between the fluid and the valve, it eliminates concerns about long term product compatibility with the valve material since product contact with the valve only occurs at point of use.
- liquid-filled, flexible container which is made by the process described above may be made such that the liquid is substantially free of gas.
- the closure described avoids the ingress of any gas, such as air, into the liquid-filled container during normal use.
- the self-sealing valve avoids or minimizes dripping of liquid during use, and consequently the closure of the invention is mess-free.
- the flexible container is light-weight and cheap to manufacture and transport.
- a further advantage is that the present invention does not have any removable part, such as a screw cap, that consumer may lose after opening the package.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Bag Frames (AREA)
- Closures For Containers (AREA)
- Packages (AREA)
- Basic Packing Technique (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04078548A EP1676784A1 (en) | 2004-12-29 | 2004-12-29 | Flexible container containing a liquid product, and a process for making a liquid-filled, flexible container |
| EP04078548.7 | 2004-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20060144875A1 true US20060144875A1 (en) | 2006-07-06 |
Family
ID=34928788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/312,316 Abandoned US20060144875A1 (en) | 2004-12-29 | 2005-12-20 | Flexible container containing a liquid product, and a process for making a liquid-filled, flexible container |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20060144875A1 (es) |
| EP (1) | EP1676784A1 (es) |
| CN (1) | CN101080352A (es) |
| AR (1) | AR052859A1 (es) |
| BR (1) | BRPI0519670A2 (es) |
| MX (1) | MX2007008062A (es) |
| WO (1) | WO2006071660A1 (es) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100163585A1 (en) * | 2007-02-21 | 2010-07-01 | Johnsondiversey, Inc. | Dispensing closure |
| US20100176151A1 (en) * | 2009-01-09 | 2010-07-15 | Johnson James W | Poppet seal fitment for a collapsible bag |
| US9327885B2 (en) * | 2013-02-12 | 2016-05-03 | Pacplus Co., Ltd. | Stopper system, stopper, and container having stopper |
| US20170275064A1 (en) * | 2014-11-03 | 2017-09-28 | Georg Menshen Gmbh & Co. Kg | Pourer of a container |
| US10961025B2 (en) * | 2016-12-08 | 2021-03-30 | Fujimori Kogyo Co., Ltd. | Pouring spout of container |
| US20210387787A1 (en) * | 2020-06-12 | 2021-12-16 | Sonia Gonzales | Infant formula receptacle with pliable pouch, and infant feeding systems |
| US20220009688A1 (en) * | 2018-10-30 | 2022-01-13 | Fujimori Kogyo Co., Ltd. | Pouring spout |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2065860A1 (en) * | 2007-11-29 | 2009-06-03 | The Procter and Gamble Company | Apparatus for providing a cleaning composition |
| AU2010234593B2 (en) * | 2009-04-06 | 2014-04-10 | Neverfail Springwater Limited | Ribbed water spike |
| EP3508436B1 (en) * | 2009-09-11 | 2024-11-20 | Kraft Foods Group Brands LLC | Shelf stable concentrated liquids |
| JP6157848B2 (ja) * | 2012-12-18 | 2017-07-05 | 株式会社細川洋行 | 逆止弁および逆止弁付き容器 |
| EP2937293B1 (en) * | 2012-12-18 | 2018-02-21 | Hosokawa Yoko Co., Ltd. | Check valve and container with check valve |
| JP6097848B2 (ja) * | 2013-11-26 | 2017-03-15 | ネステク ソシエテ アノニム | 消費可能製品パッケージ用のアダプタ及びこれを使用する方法 |
| TWI688524B (zh) * | 2015-03-17 | 2020-03-21 | 美商陶氏全球科技有限責任公司 | 用於撓性容器之撓性配件 |
| WO2017113906A1 (zh) * | 2015-12-29 | 2017-07-06 | 胡绍勤 | 一种输液容器 |
| DE102016114107A1 (de) * | 2016-07-29 | 2018-02-01 | Vorwerk & Co. Interholding Gmbh | Reinigungseinrichtung für ein Feuchtreinigungsgerät |
| CN110198832B (zh) | 2017-02-21 | 2021-07-09 | 宝洁公司 | 制备开孔的柔性容器的方法 |
| CN110225865B (zh) | 2017-02-22 | 2021-12-31 | 宝洁公司 | 制备具有结构支撑框架的柔性容器的方法 |
| EP3601068A1 (en) * | 2017-03-24 | 2020-02-05 | The Procter and Gamble Company | Methods of opening flexible containers |
| US11338975B2 (en) | 2018-05-16 | 2022-05-24 | The Procter & Gamble Company | Container blanks for flexible packages and methods of making flexible packages |
| CN108792235A (zh) * | 2018-06-26 | 2018-11-13 | 郭彪 | 一种防菌包装袋及制造工艺 |
| KR20240048360A (ko) * | 2022-10-06 | 2024-04-15 | 주식회사 경동나비엔 | 플렉시블 탱크 |
| CN116654446B (zh) * | 2023-07-05 | 2026-01-20 | 塔罗斯科技股份有限公司 | 一种饮料包装袋 |
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| US2139289A (en) * | 1936-12-24 | 1938-12-06 | Emil G Skoda | Condiment dispenser |
| US2208201A (en) * | 1938-03-09 | 1940-07-16 | West Co | Cap for collapsible tubes and other containers |
| US2970723A (en) * | 1952-12-16 | 1961-02-07 | Flax Valer | Manufacture of collapsible tubular container made of flexible materials |
| US3138293A (en) * | 1961-03-15 | 1964-06-23 | Scholle Container Corp | Paperboard dispensing container |
| US3244332A (en) * | 1964-11-18 | 1966-04-05 | Howard L Rogers | Self-closing cap |
| US3445042A (en) * | 1967-07-17 | 1969-05-20 | Austin E Elmore | Closure for a fluid dispensing container having a flexible slitted diaphragm |
| US3874563A (en) * | 1973-06-19 | 1975-04-01 | Gilbert Schwartzman | Applicator having multiple valve assemblies |
| US4561570A (en) * | 1982-12-21 | 1985-12-31 | Wella Aktiengesellschaft | Automatic locking device for a flexible container |
| US4826044A (en) * | 1988-05-31 | 1989-05-02 | Owens-Illinois Closure Inc. | Dispenser for viscous fluids |
| US5102013A (en) * | 1989-07-11 | 1992-04-07 | Cebal | Tube type container with plural flow controller |
| US5139182A (en) * | 1989-08-16 | 1992-08-18 | Constandinos Appla | Closure and dispensing device for containers |
| US5275312A (en) * | 1991-10-10 | 1994-01-04 | Sofar Spa | One-way valve suitable for use in particular in a container supplying a liquid under pressure |
| US5292033A (en) * | 1990-11-16 | 1994-03-08 | L'oreal | Dispenser for a liquid to pasty product and subplate for a dispenser of this kind |
| US5358152A (en) * | 1993-08-03 | 1994-10-25 | Sprintvest Corporation Nv | Detergent doser |
| US5402920A (en) * | 1993-07-29 | 1995-04-04 | Dhillon; Sunny S. | No spill container |
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| US4445551A (en) | 1981-11-09 | 1984-05-01 | Bond Curtis J | Quick-disconnect coupling and valve assembly |
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| JP2003054657A (ja) * | 2001-05-14 | 2003-02-26 | Nomuko Medical:Kk | 液体バッグ |
-
2004
- 2004-12-29 EP EP04078548A patent/EP1676784A1/en not_active Withdrawn
-
2005
- 2005-12-20 CN CNA2005800434940A patent/CN101080352A/zh active Pending
- 2005-12-20 BR BRPI0519670-1A patent/BRPI0519670A2/pt not_active IP Right Cessation
- 2005-12-20 MX MX2007008062A patent/MX2007008062A/es unknown
- 2005-12-20 WO PCT/US2005/046286 patent/WO2006071660A1/en not_active Ceased
- 2005-12-20 US US11/312,316 patent/US20060144875A1/en not_active Abandoned
- 2005-12-29 AR ARP050105636A patent/AR052859A1/es unknown
Patent Citations (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2139289A (en) * | 1936-12-24 | 1938-12-06 | Emil G Skoda | Condiment dispenser |
| US2208201A (en) * | 1938-03-09 | 1940-07-16 | West Co | Cap for collapsible tubes and other containers |
| US2970723A (en) * | 1952-12-16 | 1961-02-07 | Flax Valer | Manufacture of collapsible tubular container made of flexible materials |
| US3138293A (en) * | 1961-03-15 | 1964-06-23 | Scholle Container Corp | Paperboard dispensing container |
| US3244332A (en) * | 1964-11-18 | 1966-04-05 | Howard L Rogers | Self-closing cap |
| US3445042A (en) * | 1967-07-17 | 1969-05-20 | Austin E Elmore | Closure for a fluid dispensing container having a flexible slitted diaphragm |
| US3874563A (en) * | 1973-06-19 | 1975-04-01 | Gilbert Schwartzman | Applicator having multiple valve assemblies |
| US4561570A (en) * | 1982-12-21 | 1985-12-31 | Wella Aktiengesellschaft | Automatic locking device for a flexible container |
| US4826044A (en) * | 1988-05-31 | 1989-05-02 | Owens-Illinois Closure Inc. | Dispenser for viscous fluids |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20100163585A1 (en) * | 2007-02-21 | 2010-07-01 | Johnsondiversey, Inc. | Dispensing closure |
| US8490840B2 (en) | 2007-02-21 | 2013-07-23 | Diversey, Inc. | Dispensing closure |
| US20100176151A1 (en) * | 2009-01-09 | 2010-07-15 | Johnson James W | Poppet seal fitment for a collapsible bag |
| US8448820B2 (en) * | 2009-01-09 | 2013-05-28 | Liqui-Box Corporation | Poppet seal fitment for a collapsible bag |
| US9327885B2 (en) * | 2013-02-12 | 2016-05-03 | Pacplus Co., Ltd. | Stopper system, stopper, and container having stopper |
| US20170275064A1 (en) * | 2014-11-03 | 2017-09-28 | Georg Menshen Gmbh & Co. Kg | Pourer of a container |
| US10301084B2 (en) * | 2014-11-03 | 2019-05-28 | Georg Menshen Gmbh & Co. Kg | Container spout |
| US10961025B2 (en) * | 2016-12-08 | 2021-03-30 | Fujimori Kogyo Co., Ltd. | Pouring spout of container |
| US20220009688A1 (en) * | 2018-10-30 | 2022-01-13 | Fujimori Kogyo Co., Ltd. | Pouring spout |
| US11623807B2 (en) * | 2018-10-30 | 2023-04-11 | Fujimori Kogyo Co., Ltd. | Pouring spout |
| US20210387787A1 (en) * | 2020-06-12 | 2021-12-16 | Sonia Gonzales | Infant formula receptacle with pliable pouch, and infant feeding systems |
| US11667459B2 (en) * | 2020-06-12 | 2023-06-06 | Sonia Gonzales | Infant formula receptacle with pliable pouch, and infant feeding systems |
Also Published As
| Publication number | Publication date |
|---|---|
| AR052859A1 (es) | 2007-04-04 |
| BRPI0519670A2 (pt) | 2009-03-03 |
| CN101080352A (zh) | 2007-11-28 |
| EP1676784A1 (en) | 2006-07-05 |
| MX2007008062A (es) | 2007-07-17 |
| WO2006071660A1 (en) | 2006-07-06 |
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