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US20060033113A1 - Nitride semiconductor light emitting diode and method of manufacturing the same - Google Patents

Nitride semiconductor light emitting diode and method of manufacturing the same Download PDF

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Publication number
US20060033113A1
US20060033113A1 US11/064,968 US6496805A US2006033113A1 US 20060033113 A1 US20060033113 A1 US 20060033113A1 US 6496805 A US6496805 A US 6496805A US 2006033113 A1 US2006033113 A1 US 2006033113A1
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layer
type
nitride semiconductor
mesh
dbr reflecting
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US11/064,968
Inventor
Jae Lee
In Kim
Yong Kim
Hyun Kim
Moon Kong
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Samsung Electro Mechanics Co Ltd
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Samsung Electro Mechanics Co Ltd
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Assigned to SAMSUNG ELECTRO-MECHANICS CO., LTD. reassignment SAMSUNG ELECTRO-MECHANICS CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KIM, HYUN KYUNG, KIM, IN EUNG, KIM, YONG CHUN, KONG, MOON HEON, LEE, JAE HOON
Publication of US20060033113A1 publication Critical patent/US20060033113A1/en
Priority to US11/933,950 priority Critical patent/US7648849B2/en
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/831Electrodes characterised by their shape
    • H10H20/8316Multi-layer electrodes comprising at least one discontinuous layer
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/832Electrodes characterised by their material
    • H10H20/835Reflective materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/84Coatings, e.g. passivation layers or antireflective coatings
    • H10H20/841Reflective coatings, e.g. dielectric Bragg reflectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/14Structure, shape, material or disposition of the bump connectors prior to the connecting process of a plurality of bump connectors
    • H01L2224/1401Structure
    • H01L2224/1403Bump connectors having different sizes, e.g. different diameters, heights or widths
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16151Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/16221Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/16225Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/81Bodies
    • H10H20/822Materials of the light-emitting regions
    • H10H20/824Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP
    • H10H20/825Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP containing nitrogen, e.g. GaN

Definitions

  • the present invention relates to a nitride semiconductor light emitting diode, and more particularly to a nitride semiconductor light emitting diode that adopts a flip chip structure. Also, the present invention relates to a method of manufacturing the same.
  • a nitride semiconductor light emitting diode is a light emitting diode used to obtain light having a blue or green wavelength band.
  • the nitride semiconductor light emitting diode is made of a nitride semiconductor material having the following formula: Al x In y Ga (1-x-y) N
  • a substrate used to grow such a nitride semiconductor material is limited to a sapphire substrate because of lattice matching.
  • the sapphire substrate is an insulated substrate, and thus both electrodes of the nitride semiconductor light emitting diode are formed at the opposite side of the sapphire substrate, i.e., a crystal growth surface.
  • a nitride semiconductor light emitting diode adopting a flip chip structure where the sapphire substrate is provided with a main light emitting surface.
  • FIG. 1 shows a flip chip structure of a conventional flip chip-type nitride light emitting diode.
  • a flip chip-type light emitting device 20 shown in FIG. 1 comprises a nitride semiconductor light emitting diode 10 mounted on a chip substrate 21 .
  • the nitride semiconductor light emitting diode 10 comprises a sapphire substrate 11 , an n-type nitride semiconductor layer 12 disposed on the sapphire substrate 11 , an active layer 13 disposed on the n-type nitride semiconductor layer 12 , and a p-type nitride semiconductor layer 14 disposed on the active layer 13 .
  • the nitride semiconductor light emitting diode 10 is mounted on the chip substrate such that electrodes 19 a and 19 b are connected to lead patterns 22 a and 22 b via conductive bumps 24 a and 24 b , respectively.
  • the sapphire substrate 11 of the light emitting diode 10 is a light transmittance substrate. Consequently, the sapphire substrate 11 may be used as a light emitting surface of the flip chip-type light emitting device 20 .
  • the electrodes of the nitride semiconductor light emitting diode 10 especially, the p-side electrode form ohmic contact with the p-type nitride semiconductor layer 14 , and have high reflexibility sufficient to reflect light emitted from the active layer 13 to the sapphire substrate 11 .
  • the p-side electrode structure may include an ohmic contact layer 16 and a metal barrier layer 17 formed on the p-type nitride semiconductor layer 14 .
  • the ohmic contact layer 16 is made of Ag or Al having high reflexibility of approximately 90% to 95% so that the ohmic contact layer 16 can improve contact resistance.
  • the metal barrier layer 17 serves to prevent undesired immigration of components of the ohmic contact layer 16 .
  • the metal, such as Ag or Al, forming the ohmic contact layer 16 is very sensitive to heat. As a result, the reflexibility of the ohmic contact layer 16 is lowered to approximately 60%-80%. If the reflexibility of the ohmic contact layer 16 is lowered, brightness of the flip chip-type light emitting device 20 is also lowered.
  • the conventional nitride semiconductor light emitting diode 10 substantially has a planner electrode structure.
  • the p-side ohmic contact layer 16 has specific resistance lower than that of the p-type nitride semiconductor layer 14 .
  • a large portion of electric current is concentrated to a part A adjacent to the n-side electrode as indicated by the arrow.
  • current crowding occurs.
  • forward voltage is increased, light emitting efficiency of the active layer 13 disposed opposite to the n-side electrode 19 a is decreased, and heat value of the part A where the electric current is concentrated is increased, whereby reliability of the nitride semiconductor light emitting diode is considerably deteriorated.
  • the present invention has been made in view of the above problems, and it is an object of the present invention to provide a nitride semiconductor light emitting diode having an improved p-side electrode structure, thereby improving current diffusion effects and reflexibility.
  • a nitride semiconductor light emitting diode comprising: a light transmittance substrate that allows a nitride semiconductor to be grown thereon; an n-type nitride semiconductor layer formed on the light transmittance substrate; an active layer formed on the n-type nitride semiconductor layer; a p-type nitride semiconductor layer formed on the active layer; a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh
  • difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers.
  • the first and second nitride layers constituting the mesh-type DBR reflecting layer may be formed of materials satisfying the following formula: Al 1-x Ga x N (0 ⁇ x ⁇ 1).
  • the first nitride layer is made of AlGaN
  • the second nitride layer is made of GaN.
  • the effective area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
  • the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
  • the nitride semiconductor light emitting diode further comprises: a metal barrier layer formed on the surface of the ohmic contact layer.
  • the metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
  • a method of manufacturing a nitride semiconductor light emitting diode comprising the steps of: preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon; forming an n-type nitride semiconductor layer on the light transmittance substrate; forming an active layer on the n-type nitride semiconductor layer; forming a p-type nitride semiconductor layer on the active layer; alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
  • the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
  • the step of forming the mesh-type DBR reflecting layer is carried out at a temperature of 500° C. to 700° C. to prevent occurrence of cracks.
  • a flip chip-type light emitting device used in the present invention indicates a light emitting device having a light emitting diode mounted on a chip substrate in a flip chip structure, as shown in FIG. 1 .
  • FIG. 1 is a side view, in section, showing a conventional flip chip-type nitride light emitting diode
  • FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode according to a preferred embodiment of the present invention
  • FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode according to the preferred embodiment of the present invention show in FIG. 2A ;
  • FIG. 3 is a side view, in section, showing a flip chip-type nitride light emitting diode according to another preferred embodiment of the present invention.
  • the p-type and n-type nitride semiconductor layers are single crystals each having the following formula: Al X In y Ga (1-X-y) N (where, 0 ⁇ x ⁇ 1, 0 ⁇ y ⁇ 1, and (0 ⁇ x+y ⁇ 1), and are grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE).
  • MOCVD Metal Organic Chemical Vapor Deposition
  • MBE Molecular Beam Epitaxy
  • HVPE Hydride Vapor Phase Epitaxy
  • the typical nitride semiconductor layers include GaN, AlGaN, and GaInN.
  • the P-type nitride semiconductor layer may contain impurities, such as Mg, Zn, and Be.
  • the n-type nitride semiconductor layer may contain impurities, such as Si, Ge, Se, Te, and C.
  • a buffer layer for lattice matching Between the substrate and the nitride semiconductor layer is usually disposed a buffer layer for lattice matching.
  • the common buffer layer may be a low-temperature core growth layer, such as AlN or GaN.
  • the active layer adopted in the present invention is a layer for emitting blue-green light (having a wavelength of approximately 350 to 550 nm).
  • the active layer comprises an undoped nitride semiconductor layer having a single or multiple quantum well structure.
  • the active layer may be grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE), as in the p-type and n-type nitride semiconductor layer.
  • MOCVD Metal Organic Chemical Vapor Deposition
  • MBE Molecular Beam Epitaxy
  • HVPE Hydride Vapor Phase Epitaxy
  • the present invention comprises a mesh-type DBR reflecting layer.
  • the mesh-type DBR reflecting layer adopted in the present invention is composed of two kinds of nitride layers having different Al content, which are alternately stacked several times.
  • a refractive index of the nitride may vary depending upon the Al content. For this reason, a DBR structure having high reflexibility may be formed.
  • the difference between the refractive index of one of the nitride layers and the refractive index of the other nitride layer, both of which constitute the mesh-type DBR reflecting layer is great, the thickness of the layer may be decreased, and the number of times at which the layers are stacked is decreased.
  • the mesh-type DBR reflecting layer is preferably composed of two kinds of nitride layers having different Al content, difference of which is at least 30%.
  • the mesh-type DBR reflecting layer is designed to obtain high reflexibility of 90% or more, preferably 95% or more, and more preferably 98% or more.
  • the DBR reflecting layer of the present invention is formed in the shape of a mesh. Consequently, an ohmic contact layer, which will be formed in a subsequent process, contacts the p-type nitride semiconductor layer through a plurality of open regions arranged over the mesh-type DBE reflecting layer.
  • the DBR reflecting layer which is made of nitrides, has resistance higher than that of the ohmic contact layer. As a result, electric current flowing to the active layer through the ohmic contact layer is uniformly diffused by means of the mesh-type DBR reflecting layer. Consequently, current crowding is mitigated.
  • the mesh-type DBR reflecting layer is formed of a three component-based nitride satisfying the following formula: Al 1-x Ga x N (0 ⁇ x ⁇ 1) to easily adjust the Al content. More preferably, the mesh-type DBR reflecting layer is formed of a first nitride layer, such ah GaN, and a second nitride layer, such as Al 1-x Ga x N (0 ⁇ x ⁇ 1), which are alternately stacked several times.
  • the nitride layers constituting the mesh-type DBR reflecting layer may be formed successively through the use of the same growth process as the p-type and n-type nitride semiconductor layers and the active layer, i.e., through the use of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). Subsequently, the nitride layers are selectively etched by means of a photolithographic process to obtain the desired mesh-type DBR reflecting layer.
  • MOCVD Metal Organic Chemical Vapor Deposition
  • MBE Molecular Beam Epitaxy
  • HVPE Hydride Vapor Phase Epitaxy
  • the ohmic contact layer adopted in the present invention is formed on the mesh-type DBR reflecting layer and the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer. Electric current flowing to the active layer though the ohmic contact layer having high reflexibility is uniformly diffused over the entire surface of the p-type nitride semiconductor layer by means of the mesh-type DBR reflecting layer having high resistance. As a result, current crowding is mitigated.
  • the ohmic contact layer having high reflexibility be formed of high reflexibility sufficient to lower contact resistance between the p-type nitride semiconductor layer having a relatively high energy band gap.
  • the ohmic contact layer having high reflexibility may be formed of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
  • the ohmic contact layer has reflexibility of 70% or more.
  • the ohmic contact layer may be formed of Ni/Ag, Zn/Ag, Ni/Al, Zn/Al, Pd/Ag, Pd/Al, Ir/Ag, Ir/Au, Pt/Ag, Pt/Al, or Ni/Ag/Pt.
  • the ohmic contact layer is formed by means of an ordinary deposition or sputtering process.
  • the ohmic contact layer may be thermally treated at the temperature of approximately 400° C. to 900° C. to improve the characteristics of the ohmic contact layer.
  • the metal barrier layer adopted in the present invention is formed at the ohmic contact layer having high reflexibility where a p-side bonding electrode is to be formed.
  • the metal barrier layer is disposed at the interface between the bonding electrode material and the ohmic contact layer material for preventing deterioration of the characteristics (especially, reflexibility and contact resistance) of the ohmic contact layer.
  • the metal barrier layer may be constructed in a single-layered structure or a multiple-layered structure.
  • the metal barrier layer may be made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
  • the metal barrier layer may extend to the sides of the ohmic contact layer having high reflexibility. In this case, it is possible to effectively prevent occurrence of current leakage due to migration of Ag when the ohmic contact layer having high reflexibility contains Ag.
  • the metal barrier layer is formed by means of an ordinary deposition or sputtering process, as in the above-described electrodes.
  • the metal barrier layer may be thermally treated at a temperature of approximately 300° C. for several tens of seconds or several minutes to improve adherence.
  • the p-side bonding electrode which constitutes the p-side electrode structure together with the ohmic contact layer and the metal barrier layer, is an uppermost electrode layer to be mounted on a lead through a conductive bump in the flip chip structure.
  • the p-side bonding electrode is made of Au or an alloy containing Au.
  • the n-side electrode formed on the n-type nitride semiconductor layer may be constructed in a single-layered structure or a multiple-layered structure.
  • the n-side electrode may be made of a material selected from the group consisting of Ti, Cr, Al, Cu, and Au.
  • the electrodes are formed by means of an ordinary metal layer growth process, such as deposition or a sputtering process.
  • FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode 30 according to a preferred embodiment of the present invention
  • FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode 30 according to the preferred embodiment of the present invention show in FIG. 2A .
  • the flip chip-type nitride semiconductor light emitting diode 30 comprises a nitride semiconductor growth substrate 31 , such as a sapphire substrate, an n-type nitride semiconductor layer 32 disposed on the nitride semiconductor growth substrate 31 , an active layer 33 disposed on the n-type nitride semiconductor layer 32 , and a p-type nitride semiconductor layer 34 disposed on the active layer 33 .
  • the nitride semiconductor light emitting diode 30 has an n-side electrode 39 a formed on the upper surface of the n-type nitride semiconductor layer 32 , which is exposed by means of mesa etching.
  • a p-side electrode structure adopted in the nitride semiconductor light emitting diode 30 includes a mesh-type DBR reflecting layer 35 , an ohmic contact layer 36 , and a bonding electrode 39 b .
  • the ohmic contact layer 36 is formed on the p-type nitride semiconductor layer 34 .
  • the ohmic contact layer 36 is constructed in a mesh structure having a plurality of open regions, by which the p-type nitride semiconductor layer 34 is partially exposed.
  • the bonding electrode 39 b is formed on the upper surface of the ohmic contact layer 35 .
  • the mesh-type DBR reflecting layer 35 comprises first and second nitride layers 35 a and 35 b having different Al content, which are alternately stacked several times.
  • difference of the Al content between the first and second nitride layers 35 a and 35 b is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers 35 a and 35 b .
  • the mesh-type DBR reflecting layer 35 may be an AlGaN-based nitride layer.
  • the first nitride layer 35 a is GaN
  • the second nitride layer 35 b is AlGaN. In this case, the mesh-type DBR reflecting layer 35 has high reflexibility.
  • the mesh-type DBR reflecting layer 35 maintains stable reflexibility at high temperature, unlike the ohmic contact material having high reflexibility, such as Ag or Al. Consequently, the total reflexibility is prevented from being deteriorated by the area of the mesh-type DBR reflecting layer 35 even when the temperature is high.
  • the first and second nitride layers 35 a and 35 b are undoped crystal layers, although each of the first and second nitride layers 35 a and 35 b may be manufactured in the shape of an amorphous layer.
  • a crack may occur at an ordinary crystal growth temperature (more than 1000° C.). Consequently, it is preferable to grow the mesh-type DBR reflecting layer 35 at a temperature of 500° C. to 700° C.
  • the mesh-type DBR reflecting layer 35 has a plurality of open regions, which are arranged in the mesh structure.
  • the ohmic contact layer 36 formed on the mesh-type DBR reflecting layer 35 contacts the p-type nitride semiconductor layer 34 through the open regions of the mesh-type DBR reflecting layer 35 to form ohmic contact.
  • the mesh-type DBR reflecting layer 35 has resistance higher than that of the ohmic contact layer 36 . Consequently, electric current flowing from the p-side bonding electrode 39 b to the n-side electrode 39 a through the ohmic contact layer 36 is uniformly diffused by means of the mesh structure of the mesh-type DBR reflecting layer, as indicated by the arrow in FIG. 2A .
  • the effective area of the mesh-type DBR reflecting layer 35 i.e., the area of the mesh-type DBR reflecting layer 35 excluding the open regions of the mesh-type DBR reflecting layer 35 ), since brightness is increased by virtue of high reflexibility. It is necessary, however, that sufficient contact area be provided between the p-type nitride semiconductor layer 34 and the ohmic contact layer 36 .
  • the effective area of the mesh-type DBR reflecting layer 35 is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer 34 .
  • the mesh-type DBR reflecting layer 35 adopted in the present invention is composed of a nitride layer, such as AlGaN. Consequently, the mesh-type DBR reflecting layer 35 can be successively formed by means of the same growth process as the p-type and n-type nitride semiconductor layers 34 and 32 and the active layer 33 .
  • the mesh-type DBR reflecting layer 35 when the mesh-type DBR reflecting layer 35 is composed of a first nitride layer 36 a , such as GaN, and a second nitride layer 36 b , such as AlGaN, the mesh-type DBR reflecting layer 35 can be manufactured using trimethylgallium (TMG), trimethylaluminum (TMA), and ammonia (NH 4 ) as a source gas under conditions similar to the single crystal growth process of the nitride in a MOCVD chamber where a single crystal growth process for a light emitting structure is carried out. As described above, the mesh-type DBR reflecting layer 35 is not limited to the single crystal.
  • the mesh-type DBR reflecting layer 35 is preferably manufactured in the shape of an amorphous layer, which is grown at low temperature.
  • the mesh-type DBR reflecting layer 35 can be grown at a temperature lower than the single crystal growing temperature, for example, 500° C. to 700° C.
  • FIG. 3 is a side view, in section, showing a flip chip-type light emitting device 60 according to another preferred embodiment of the present invention.
  • the flip chip-type light emitting device 60 comprises a chip substrate 61 and a nitride light emitting diode 50 disposed on the chip substrate 61 .
  • the nitride semiconductor light emitting diode 50 comprises a nitride semiconductor growth substrate 51 , such as a sapphire substrate, an n-type nitride semiconductor layer 52 disposed on the nitride semiconductor growth substrate 51 , an active layer 53 disposed on the n-type nitride semiconductor layer 52 , and a p-type nitride semiconductor layer 54 disposed on the active layer 53 .
  • the nitride semiconductor light emitting diode 50 is mounted on the chip substrate 61 such that electrodes 69 a and 69 b are connected to lead patterns 62 a and 62 b via conductive bumps 64 a and 64 b , respectively.
  • the nitride semiconductor light emitting diode 50 has an n-side electrode 59 a formed on the upper surface of the n-type nitride semiconductor layer 52 , which is exposed by means of mesa etching.
  • a p-side electrode structure adopted in the nitride semiconductor light emitting diode 50 includes a mesh-type DBR reflecting layer 55 , an ohmic contact layer 56 , and a bonding electrode 59 b , which are similar to those shown in FIG. 2A .
  • a metal barrier layer 57 is formed on the surface of the ohmic contact layer 56 such that the metal barrier layer 57 surrounds both sides of the ohmic contact layer 56 .
  • the metal barrier layer 57 serves to prevent immigration of the material of the ohmic contact layer 56 , such as Al, and mixture of Au component at the interface between the p-side bonding electrode 59 b and the ohmic contact layer 56 .
  • the sapphire substrate 51 of the light emitting diode 50 in the flip chip-type light emitting device is a light transmittance substrate. Consequently, the sapphire substrate 51 serves as a light emitting surface of the flip chip-type light emitting device 60 .
  • the mesh-type DBR reflecting layer 55 and the ohmic contact layer 56 serve as reflecting layers at the opposite side so that the amount of the emitted light can be increased.
  • the mesh-type DBR reflecting layer 55 has high reflexibility of 90% or more.
  • the mesh-type DBR reflecting layer 55 maintains stable reflexibility at high temperature. Consequently, reflecting performance of the mesh-type DBR reflecting layer 55 is improved.
  • the mesh-type DBR reflecting layer 55 diffuses electric current provided though the ohmic contact layer 56 , whereby current crowding is mitigated.
  • the present invention provides a nitride semiconductor light emitting diode having an improved p-side electrode structure where a mesh-type DBR reflecting layer is composed of two kinds of nitride layers having different Al content to decrease electric current concentrated to the region adjacent to an n-side electrode. Consequently, the present invention has the effect of mitigating current crowding and increasing reflexibility, and therefore improving overall light emitting efficiency.

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Abstract

The present invention provides a flip chip-type nitride semiconductor light emitting diode. The nitride semiconductor light emitting diode comprises a light transmittance substrate, an n-type nitride semiconductor layer, an active layer, a p-type nitride semiconductor layer and a mesh-type DBR reflecting layer. The mesh-type DBR reflecting layer has a plurality of open regions. The mesh-type DBR reflecting layer is composed of first and second nitride layers having different Al content. The first and second nitride layers are alternately stacked several times to form the mesh-type DBR reflecting layer. An ohmic contact layer is formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer.

Description

    RELATED APPLICATION
  • The present application is based on, and claims priority from, Korean Application No. 2004-63214, filed on Aug. 11, 2004, the disclosure of which is incorporated by reference herein in its entirety.
  • BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to a nitride semiconductor light emitting diode, and more particularly to a nitride semiconductor light emitting diode that adopts a flip chip structure. Also, the present invention relates to a method of manufacturing the same.
  • 2. Description of the Related Art
  • Generally, a nitride semiconductor light emitting diode is a light emitting diode used to obtain light having a blue or green wavelength band. The nitride semiconductor light emitting diode is made of a nitride semiconductor material having the following formula:
    AlxInyGa(1-x-y)N
  • Where, 0≦x≦1, 0≦y≦1, and 0≦x+y≦1
  • A substrate used to grow such a nitride semiconductor material is limited to a sapphire substrate because of lattice matching. The sapphire substrate is an insulated substrate, and thus both electrodes of the nitride semiconductor light emitting diode are formed at the opposite side of the sapphire substrate, i.e., a crystal growth surface. Considering the above-mentioned structural characteristics, there has been briskly developed a nitride semiconductor light emitting diode adopting a flip chip structure where the sapphire substrate is provided with a main light emitting surface.
  • FIG. 1 shows a flip chip structure of a conventional flip chip-type nitride light emitting diode.
  • A flip chip-type light emitting device 20 shown in FIG. 1 comprises a nitride semiconductor light emitting diode 10 mounted on a chip substrate 21. The nitride semiconductor light emitting diode 10 comprises a sapphire substrate 11, an n-type nitride semiconductor layer 12 disposed on the sapphire substrate 11, an active layer 13 disposed on the n-type nitride semiconductor layer 12, and a p-type nitride semiconductor layer 14 disposed on the active layer 13. The nitride semiconductor light emitting diode 10 is mounted on the chip substrate such that electrodes 19 a and 19 b are connected to lead patterns 22 a and 22 b via conductive bumps 24 a and 24 b, respectively. The sapphire substrate 11 of the light emitting diode 10 is a light transmittance substrate. Consequently, the sapphire substrate 11 may be used as a light emitting surface of the flip chip-type light emitting device 20.
  • It is required that the electrodes of the nitride semiconductor light emitting diode 10, especially, the p-side electrode form ohmic contact with the p-type nitride semiconductor layer 14, and have high reflexibility sufficient to reflect light emitted from the active layer 13 to the sapphire substrate 11.
  • As shown in FIG. 1, therefore, the p-side electrode structure may include an ohmic contact layer 16 and a metal barrier layer 17 formed on the p-type nitride semiconductor layer 14. The ohmic contact layer 16 is made of Ag or Al having high reflexibility of approximately 90% to 95% so that the ohmic contact layer 16 can improve contact resistance. The metal barrier layer 17 serves to prevent undesired immigration of components of the ohmic contact layer 16.
  • However, the metal, such as Ag or Al, forming the ohmic contact layer 16 is very sensitive to heat. As a result, the reflexibility of the ohmic contact layer 16 is lowered to approximately 60%-80%. If the reflexibility of the ohmic contact layer 16 is lowered, brightness of the flip chip-type light emitting device 20 is also lowered.
  • Also, the conventional nitride semiconductor light emitting diode 10 substantially has a planner electrode structure. Specifically, the p-side ohmic contact layer 16 has specific resistance lower than that of the p-type nitride semiconductor layer 14. As a result, a large portion of electric current is concentrated to a part A adjacent to the n-side electrode as indicated by the arrow. In other words, current crowding occurs. When the current crowding occurs, forward voltage is increased, light emitting efficiency of the active layer 13 disposed opposite to the n-side electrode 19 a is decreased, and heat value of the part A where the electric current is concentrated is increased, whereby reliability of the nitride semiconductor light emitting diode is considerably deteriorated.
  • SUMMARY OF THE INVENTION
  • Therefore, the present invention has been made in view of the above problems, and it is an object of the present invention to provide a nitride semiconductor light emitting diode having an improved p-side electrode structure, thereby improving current diffusion effects and reflexibility.
  • It is another object of the present invention to provide a method of manufacturing such a nitride semiconductor light emitting diode.
  • In accordance with one aspect of the present invention, the above and other objects can be accomplished by the provision of a nitride semiconductor light emitting diode comprising: a light transmittance substrate that allows a nitride semiconductor to be grown thereon; an n-type nitride semiconductor layer formed on the light transmittance substrate; an active layer formed on the n-type nitride semiconductor layer; a p-type nitride semiconductor layer formed on the active layer; a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
  • Preferably, difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers.
  • The first and second nitride layers constituting the mesh-type DBR reflecting layer may be formed of materials satisfying the following formula: Al1-xGaxN (0≦x≦1). Preferably, the first nitride layer is made of AlGaN, and the second nitride layer is made of GaN.
  • Preferably, the effective area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
  • The ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof. In a specific embodiment of the present invention, the nitride semiconductor light emitting diode further comprises: a metal barrier layer formed on the surface of the ohmic contact layer. The metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
  • In accordance with another aspect of the present invention, there is provided a method of manufacturing a nitride semiconductor light emitting diode, the method comprising the steps of: preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon; forming an n-type nitride semiconductor layer on the light transmittance substrate; forming an active layer on the n-type nitride semiconductor layer; forming a p-type nitride semiconductor layer on the active layer; alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
  • Preferably, the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
  • In a specific embodiment of the present invention, the step of forming the mesh-type DBR reflecting layer is carried out at a temperature of 500° C. to 700° C. to prevent occurrence of cracks.
  • The term “a flip chip-type light emitting device” used in the present invention indicates a light emitting device having a light emitting diode mounted on a chip substrate in a flip chip structure, as shown in FIG. 1.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The above and other objects, features and other advantages of the present invention will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings, in which:
  • FIG. 1 is a side view, in section, showing a conventional flip chip-type nitride light emitting diode;
  • FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode according to a preferred embodiment of the present invention;
  • FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode according to the preferred embodiment of the present invention show in FIG. 2A; and
  • FIG. 3 is a side view, in section, showing a flip chip-type nitride light emitting diode according to another preferred embodiment of the present invention.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • A detailed description of components of a nitride semiconductor light emitting diode according to the present invention will be given hereinafter.
  • P-Type and N-Type Nitride Semiconductor Layers
  • The p-type and n-type nitride semiconductor layers are single crystals each having the following formula: AlXInyGa(1-X-y)N (where, 0≦x≦1, 0≦y≦1, and (0≦x+y≦1), and are grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). The typical nitride semiconductor layers include GaN, AlGaN, and GaInN.
  • The P-type nitride semiconductor layer may contain impurities, such as Mg, Zn, and Be. The n-type nitride semiconductor layer may contain impurities, such as Si, Ge, Se, Te, and C. Between the substrate and the nitride semiconductor layer is usually disposed a buffer layer for lattice matching. The common buffer layer may be a low-temperature core growth layer, such as AlN or GaN.
  • Active Layer
  • The active layer adopted in the present invention is a layer for emitting blue-green light (having a wavelength of approximately 350 to 550 nm). The active layer comprises an undoped nitride semiconductor layer having a single or multiple quantum well structure. The active layer may be grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE), as in the p-type and n-type nitride semiconductor layer.
  • Mesh-Type DBR Reflecting Layer
  • The present invention comprises a mesh-type DBR reflecting layer. The mesh-type DBR reflecting layer adopted in the present invention is composed of two kinds of nitride layers having different Al content, which are alternately stacked several times. Generally, a refractive index of the nitride may vary depending upon the Al content. For this reason, a DBR structure having high reflexibility may be formed. When the difference between the refractive index of one of the nitride layers and the refractive index of the other nitride layer, both of which constitute the mesh-type DBR reflecting layer, is great, the thickness of the layer may be decreased, and the number of times at which the layers are stacked is decreased. Consequently, the mesh-type DBR reflecting layer is preferably composed of two kinds of nitride layers having different Al content, difference of which is at least 30%. Generally, the mesh-type DBR reflecting layer is designed to obtain high reflexibility of 90% or more, preferably 95% or more, and more preferably 98% or more.
  • The DBR reflecting layer of the present invention is formed in the shape of a mesh. Consequently, an ohmic contact layer, which will be formed in a subsequent process, contacts the p-type nitride semiconductor layer through a plurality of open regions arranged over the mesh-type DBE reflecting layer. The DBR reflecting layer, which is made of nitrides, has resistance higher than that of the ohmic contact layer. As a result, electric current flowing to the active layer through the ohmic contact layer is uniformly diffused by means of the mesh-type DBR reflecting layer. Consequently, current crowding is mitigated.
  • Preferably, the mesh-type DBR reflecting layer is formed of a three component-based nitride satisfying the following formula: Al1-xGaxN (0≦x≦1) to easily adjust the Al content. More preferably, the mesh-type DBR reflecting layer is formed of a first nitride layer, such ah GaN, and a second nitride layer, such as Al1-xGaxN (0≦x≦1), which are alternately stacked several times.
  • The nitride layers constituting the mesh-type DBR reflecting layer may be formed successively through the use of the same growth process as the p-type and n-type nitride semiconductor layers and the active layer, i.e., through the use of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). Subsequently, the nitride layers are selectively etched by means of a photolithographic process to obtain the desired mesh-type DBR reflecting layer.
  • Ohmic Contact Layer
  • As described above, the ohmic contact layer adopted in the present invention is formed on the mesh-type DBR reflecting layer and the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer. Electric current flowing to the active layer though the ohmic contact layer having high reflexibility is uniformly diffused over the entire surface of the p-type nitride semiconductor layer by means of the mesh-type DBR reflecting layer having high resistance. As a result, current crowding is mitigated.
  • It is required that the ohmic contact layer having high reflexibility be formed of high reflexibility sufficient to lower contact resistance between the p-type nitride semiconductor layer having a relatively high energy band gap.
  • In order to decrease the contact resistance and to increase the reflexibility, the ohmic contact layer having high reflexibility may be formed of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof. Preferably, the ohmic contact layer has reflexibility of 70% or more. Specifically, the ohmic contact layer may be formed of Ni/Ag, Zn/Ag, Ni/Al, Zn/Al, Pd/Ag, Pd/Al, Ir/Ag, Ir/Au, Pt/Ag, Pt/Al, or Ni/Ag/Pt.
  • The ohmic contact layer is formed by means of an ordinary deposition or sputtering process. The ohmic contact layer may be thermally treated at the temperature of approximately 400° C. to 900° C. to improve the characteristics of the ohmic contact layer.
  • Metal Barrier Layer
  • The metal barrier layer adopted in the present invention is formed at the ohmic contact layer having high reflexibility where a p-side bonding electrode is to be formed. The metal barrier layer is disposed at the interface between the bonding electrode material and the ohmic contact layer material for preventing deterioration of the characteristics (especially, reflexibility and contact resistance) of the ohmic contact layer. The metal barrier layer may be constructed in a single-layered structure or a multiple-layered structure. The metal barrier layer may be made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
  • The metal barrier layer may extend to the sides of the ohmic contact layer having high reflexibility. In this case, it is possible to effectively prevent occurrence of current leakage due to migration of Ag when the ohmic contact layer having high reflexibility contains Ag.
  • The metal barrier layer is formed by means of an ordinary deposition or sputtering process, as in the above-described electrodes. The metal barrier layer may be thermally treated at a temperature of approximately 300° C. for several tens of seconds or several minutes to improve adherence.
  • P-Side Bonding Electrode and N-Side Electrode
  • The p-side bonding electrode, which constitutes the p-side electrode structure together with the ohmic contact layer and the metal barrier layer, is an uppermost electrode layer to be mounted on a lead through a conductive bump in the flip chip structure. Generally, the p-side bonding electrode is made of Au or an alloy containing Au.
  • The n-side electrode formed on the n-type nitride semiconductor layer may be constructed in a single-layered structure or a multiple-layered structure. The n-side electrode may be made of a material selected from the group consisting of Ti, Cr, Al, Cu, and Au.
  • The electrodes are formed by means of an ordinary metal layer growth process, such as deposition or a sputtering process.
  • Now, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
  • FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode 30 according to a preferred embodiment of the present invention, and FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode 30 according to the preferred embodiment of the present invention show in FIG. 2A.
  • Referring to FIG. 2A, the flip chip-type nitride semiconductor light emitting diode 30 comprises a nitride semiconductor growth substrate 31, such as a sapphire substrate, an n-type nitride semiconductor layer 32 disposed on the nitride semiconductor growth substrate 31, an active layer 33 disposed on the n-type nitride semiconductor layer 32, and a p-type nitride semiconductor layer 34 disposed on the active layer 33.
  • The nitride semiconductor light emitting diode 30 has an n-side electrode 39 a formed on the upper surface of the n-type nitride semiconductor layer 32, which is exposed by means of mesa etching. A p-side electrode structure adopted in the nitride semiconductor light emitting diode 30 includes a mesh-type DBR reflecting layer 35, an ohmic contact layer 36, and a bonding electrode 39 b. The ohmic contact layer 36 is formed on the p-type nitride semiconductor layer 34. The ohmic contact layer 36 is constructed in a mesh structure having a plurality of open regions, by which the p-type nitride semiconductor layer 34 is partially exposed. The bonding electrode 39 b is formed on the upper surface of the ohmic contact layer 35.
  • The mesh-type DBR reflecting layer 35 comprises first and second nitride layers 35 a and 35 b having different Al content, which are alternately stacked several times. Preferably, difference of the Al content between the first and second nitride layers 35 a and 35 b is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers 35 a and 35 b. For example, the mesh-type DBR reflecting layer 35 may be an AlGaN-based nitride layer. In a preferred embodiment of the present invention, the first nitride layer 35 a is GaN, and the second nitride layer 35 b is AlGaN. In this case, the mesh-type DBR reflecting layer 35 has high reflexibility. Also, the mesh-type DBR reflecting layer 35 maintains stable reflexibility at high temperature, unlike the ohmic contact material having high reflexibility, such as Ag or Al. Consequently, the total reflexibility is prevented from being deteriorated by the area of the mesh-type DBR reflecting layer 35 even when the temperature is high.
  • The first and second nitride layers 35 a and 35 b are undoped crystal layers, although each of the first and second nitride layers 35 a and 35 b may be manufactured in the shape of an amorphous layer. In a specific embodiment of the present invention, it is necessary that one of the first and second nitride layers 35 a and 35 b have high content of Al to ensure sufficient refractive index. In the nitride having high Al content, however, a crack may occur at an ordinary crystal growth temperature (more than 1000° C.). Consequently, it is preferable to grow the mesh-type DBR reflecting layer 35 at a temperature of 500° C. to 700° C.
  • As shown in FIG. 3B, the mesh-type DBR reflecting layer 35 has a plurality of open regions, which are arranged in the mesh structure. The ohmic contact layer 36 formed on the mesh-type DBR reflecting layer 35 contacts the p-type nitride semiconductor layer 34 through the open regions of the mesh-type DBR reflecting layer 35 to form ohmic contact. The mesh-type DBR reflecting layer 35 has resistance higher than that of the ohmic contact layer 36. Consequently, electric current flowing from the p-side bonding electrode 39 b to the n-side electrode 39 a through the ohmic contact layer 36 is uniformly diffused by means of the mesh structure of the mesh-type DBR reflecting layer, as indicated by the arrow in FIG. 2A.
  • It is preferable to increase the effective area of the mesh-type DBR reflecting layer 35 (i.e., the area of the mesh-type DBR reflecting layer 35 excluding the open regions of the mesh-type DBR reflecting layer 35), since brightness is increased by virtue of high reflexibility. It is necessary, however, that sufficient contact area be provided between the p-type nitride semiconductor layer 34 and the ohmic contact layer 36. Preferably, the effective area of the mesh-type DBR reflecting layer 35 is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer 34.
  • The mesh-type DBR reflecting layer 35 adopted in the present invention is composed of a nitride layer, such as AlGaN. Consequently, the mesh-type DBR reflecting layer 35 can be successively formed by means of the same growth process as the p-type and n-type nitride semiconductor layers 34 and 32 and the active layer 33. For example, when the mesh-type DBR reflecting layer 35 is composed of a first nitride layer 36 a, such as GaN, and a second nitride layer 36 b, such as AlGaN, the mesh-type DBR reflecting layer 35 can be manufactured using trimethylgallium (TMG), trimethylaluminum (TMA), and ammonia (NH4) as a source gas under conditions similar to the single crystal growth process of the nitride in a MOCVD chamber where a single crystal growth process for a light emitting structure is carried out. As described above, the mesh-type DBR reflecting layer 35 is not limited to the single crystal. When Al content of the mesh-type DBR reflecting layer 35 is high, the mesh-type DBR reflecting layer 35 is preferably manufactured in the shape of an amorphous layer, which is grown at low temperature. In this case, the mesh-type DBR reflecting layer 35 can be grown at a temperature lower than the single crystal growing temperature, for example, 500° C. to 700° C.
  • FIG. 3 is a side view, in section, showing a flip chip-type light emitting device 60 according to another preferred embodiment of the present invention.
  • As shown in FIG. 3, the flip chip-type light emitting device 60 comprises a chip substrate 61 and a nitride light emitting diode 50 disposed on the chip substrate 61. The nitride semiconductor light emitting diode 50 comprises a nitride semiconductor growth substrate 51, such as a sapphire substrate, an n-type nitride semiconductor layer 52 disposed on the nitride semiconductor growth substrate 51, an active layer 53 disposed on the n-type nitride semiconductor layer 52, and a p-type nitride semiconductor layer 54 disposed on the active layer 53. The nitride semiconductor light emitting diode 50 is mounted on the chip substrate 61 such that electrodes 69 a and 69 b are connected to lead patterns 62 a and 62 b via conductive bumps 64 a and 64 b, respectively.
  • The nitride semiconductor light emitting diode 50 has an n-side electrode 59 a formed on the upper surface of the n-type nitride semiconductor layer 52, which is exposed by means of mesa etching. A p-side electrode structure adopted in the nitride semiconductor light emitting diode 50 includes a mesh-type DBR reflecting layer 55, an ohmic contact layer 56, and a bonding electrode 59 b, which are similar to those shown in FIG. 2A. In addition, a metal barrier layer 57 is formed on the surface of the ohmic contact layer 56 such that the metal barrier layer 57 surrounds both sides of the ohmic contact layer 56. The metal barrier layer 57 serves to prevent immigration of the material of the ohmic contact layer 56, such as Al, and mixture of Au component at the interface between the p-side bonding electrode 59 b and the ohmic contact layer 56.
  • As described above, the sapphire substrate 51 of the light emitting diode 50 in the flip chip-type light emitting device is a light transmittance substrate. Consequently, the sapphire substrate 51 serves as a light emitting surface of the flip chip-type light emitting device 60. In this structure, the mesh-type DBR reflecting layer 55 and the ohmic contact layer 56 serve as reflecting layers at the opposite side so that the amount of the emitted light can be increased. Especially, the mesh-type DBR reflecting layer 55 has high reflexibility of 90% or more. Also, the mesh-type DBR reflecting layer 55 maintains stable reflexibility at high temperature. Consequently, reflecting performance of the mesh-type DBR reflecting layer 55 is improved. Moreover, the mesh-type DBR reflecting layer 55 diffuses electric current provided though the ohmic contact layer 56, whereby current crowding is mitigated.
  • As apparent from the above description, the present invention provides a nitride semiconductor light emitting diode having an improved p-side electrode structure where a mesh-type DBR reflecting layer is composed of two kinds of nitride layers having different Al content to decrease electric current concentrated to the region adjacent to an n-side electrode. Consequently, the present invention has the effect of mitigating current crowding and increasing reflexibility, and therefore improving overall light emitting efficiency.
  • Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.

Claims (19)

1. A nitride semiconductor light emitting diode comprising:
a light transmittance substrate that allows a nitride semiconductor to be grown thereon;
an n-type nitride semiconductor layer formed on the light transmittance substrate;
an active layer formed on the n-type nitride semiconductor layer;
a p-type nitride semiconductor layer formed on the active layer;
a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and
an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
2. The diode as set forth in claim 1, wherein difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30%.
3. The diode as set forth in claim 1, wherein the first and second nitride layers constituting the mesh-type DBR reflecting layer are formed of materials satisfying the following formula.

Al1-xGaxN (0≦x≦1)
4. The diode as set forth in claim 3, wherein the first nitride layer is made of GaN, and the second nitride layer is made of AlGaN.
5. The diode as set forth in claim 1, wherein the area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
6. The diode as set forth in claim 1, wherein the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
7. The diode as set forth in claim 1, further comprising a metal barrier layer formed on the surface of the ohmic contact layer.
8. The diode as set forth in claim 7, wherein the metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
9. A flip chip-type light emitting device comprising the nitride semiconductor light emitting diode as set forth in claim 1.
10. A method of manufacturing a nitride semiconductor. light emitting diode, the method comprising the steps of:
preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon;
forming an n-type nitride semiconductor layer on the light transmittance substrate;
forming an active layer on the n-type nitride semiconductor layer;
forming a p-type nitride semiconductor layer on the active layer;
alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and
forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
11. The method as set forth in claim 10, wherein the step of forming the mesh-type DBR reflecting layer comprises alternately stacking the first and second nitride layers having Al content different from each other by at least 30% several times.
12. The method as set forth in claim 10, wherein the first and second nitride layers constituting the mesh-type DBR reflecting layer are formed of materials satisfying the following formula.

Al1-xGaxN (0≦x≦1)
13. The method as set forth in claim 10, wherein the step of forming the mesh-type DBR reflecting layer comprises alternately stacking the first nitride layers made of AlGaN and the second nitride layers made of GaN several times.
14. The method as set forth in claim 10, wherein the area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
15. The method as set forth in claim 10, wherein the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
16. The method as set forth in claim 10, wherein the step of forming the mesh-type DBR, reflecting layer is carried out at a temperature of 500° C. to 700° C.
17. The method as set forth in claim 10, wherein the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
18. The method as set forth in claim 10, further comprising the step of:
forming a metal barrier layer on the surface of the ohmic contact layer.
19. The method as set forth in claim 18, wherein the metal barrier layer comprises at least one layer made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
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Cited By (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080142782A1 (en) * 2006-12-15 2008-06-19 Samsung Electro-Mechanics Co., Ltd. Light emitting device
US20080157107A1 (en) * 2006-12-29 2008-07-03 Epitech Technology Corporation Light-emitting diode and method for manufacturing the same
CN100449805C (en) * 2006-11-08 2009-01-07 吴质朴 Manufacturing method of aluminum gallium indium phosphide compound semiconductor light emitter
WO2009121319A1 (en) * 2008-03-31 2009-10-08 Osram Opto Semiconductors Gmbh Opto-electronic semiconductor chip and method for producing the same
US20090261318A1 (en) * 2008-04-22 2009-10-22 Cheong Hung Seob Semiconductor light emitting device
US20100032701A1 (en) * 2008-08-05 2010-02-11 Sharp Kabushiki Kaisha Nitride semiconductor light emitting device and method of manufacturing the same
US20100171135A1 (en) * 2007-04-26 2010-07-08 Karl Engl Optoelectronic Semiconductor Body and Method for Producing the Same
CN101807650A (en) * 2010-03-19 2010-08-18 厦门市三安光电科技有限公司 Gallium nitride-based high-brightness light-emitting diode with distributed Bragg reflecting layer and manufacturing process thereof
US20100230698A1 (en) * 2007-09-28 2010-09-16 Patrick Rode Optoelectronic Semiconductor Body
CN101859861A (en) * 2010-05-13 2010-10-13 厦门市三安光电科技有限公司 GaN-based flip-chip light-emitting diode with double reflecting layers and preparation method thereof
EP1995794A4 (en) * 2006-03-10 2011-08-31 Panasonic Elec Works Co Ltd LIGHT EMITTING DEVICE
DE102010009717A1 (en) * 2010-03-01 2011-09-01 Osram Opto Semiconductors Gmbh LED chip
CN102208512A (en) * 2010-03-24 2011-10-05 日立电线株式会社 Light emitting diode
US20110272724A1 (en) * 2010-05-04 2011-11-10 Xiamen Sanan Optoelectronics Technology Co., Ltd. Algainp-based light-emitting diode with double reflective layers and fabrication method thereof
US20110278538A1 (en) * 2010-05-11 2011-11-17 Ko Hyung Duk Semiconductor light emitting device and method for fabricating the same
CN102479916A (en) * 2010-11-26 2012-05-30 金龙国际公司 Light-emitting diode chip structure
US8212273B2 (en) 2007-07-19 2012-07-03 Photonstar Led Limited Vertical LED with conductive vias
EP2159852A4 (en) * 2007-06-15 2012-09-26 Rohm Co Ltd LIGHT-EMITTING SEMICONDUCTOR ELEMENT
EP2485280A3 (en) * 2007-11-26 2013-01-16 LG Innotek Co., Ltd. Semiconductor light emitting device
US20130146906A1 (en) * 2011-11-25 2013-06-13 Lg Innotek Co., Ltd. Ultraviolet semiconductor light emitting device
US20130320370A1 (en) * 2012-05-29 2013-12-05 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US20140231851A1 (en) * 2013-02-04 2014-08-21 Industrial Technology Research Institute Light emitting diode
CN104037295A (en) * 2014-06-16 2014-09-10 江苏汉莱科技有限公司 LED (Light-Emitting Diode) flip chip and manufacturing method thereof
CN104253184A (en) * 2014-09-24 2014-12-31 山西飞虹微纳米光电科技有限公司 Blue light LED (Light Emitting Diode) epitaxial structure with gradually-changed DBR (Distributed Bragg Reflector) layer
US20150059850A1 (en) * 2013-08-29 2015-03-05 Tsmc Solar Ltd. Photovoltaic device with back reflector
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US20150060880A1 (en) * 2012-06-21 2015-03-05 Xiamen Sanan Optoelectronics Technology Co., Ltd. GaN-Based LED
CN104409585A (en) * 2014-11-28 2015-03-11 杭州士兰明芯科技有限公司 Vertical LED structure and manufacturing method thereof
CN104576857A (en) * 2013-10-15 2015-04-29 上海工程技术大学 Flip LED chip structure with high reflection layer and manufacturing method of flip LED chip structure
US20150280074A1 (en) * 2012-12-14 2015-10-01 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
CN105047785A (en) * 2015-09-09 2015-11-11 厦门乾照光电股份有限公司 Light emitting diode with micro optimal transmission system
EP2750207A3 (en) * 2012-12-12 2015-12-09 Seoul Viosys Co., Ltd. Light-emitting diode and method of fabricating the same
US20160099385A1 (en) * 2013-04-22 2016-04-07 Korea Polytechnic University Industry Academic Cooperation Foundation Method for Manufacturing Vertical Type Light Emitting Diode, Vertical Type Light Emitting Diode, Method for Manufacturing Ultraviolet Ray Light Emitting Diode, and Ultraviolet Ray Light Emitting Diode
US9425359B2 (en) 2013-02-04 2016-08-23 Industrial Technology Research Institute Light emitting diode
US9548424B2 (en) 2013-02-04 2017-01-17 Industrial Technology Research Institute Light emitting diode
US9577165B2 (en) 2011-08-31 2017-02-21 Osram Opto Semiconductor Gmbh Light emitting diode chip
US20180226541A1 (en) * 2015-08-24 2018-08-09 Lg Innotek Co., Ltd. Light emitting element
CN111129237A (en) * 2018-01-02 2020-05-08 首尔伟傲世有限公司 Display device with light-emitting stacked structure
EP2430673B1 (en) * 2009-05-11 2020-05-27 Cree, Inc. Semiconductor light emitting diodes having reflective structures and methods of fabricating same
CN112542533A (en) * 2020-12-01 2021-03-23 北京大学 High-photoelectric-conversion-rate inverted-structure deep ultraviolet micro-LED and preparation method thereof
CN112951955A (en) * 2021-01-26 2021-06-11 华灿光电(浙江)有限公司 Ultraviolet light-emitting diode epitaxial wafer and preparation method thereof
CN113644180A (en) * 2021-08-05 2021-11-12 厦门士兰明镓化合物半导体有限公司 Flip-chip LED chip and preparation method thereof
CN114141925A (en) * 2021-12-01 2022-03-04 厦门三安光电有限公司 Light emitting diode
WO2024033375A1 (en) * 2022-08-10 2024-02-15 Ams-Osram International Gmbh Optoelectronic semiconductor component with an epitaxially grown layer and method for producing the optoelectronic semiconductor component
EP4107792A4 (en) * 2020-03-20 2024-03-27 Sensor Electronic Technology, Inc. OPTOELECTRONIC DEVICE WITH REDUCED OPTICAL LOSS

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4880951B2 (en) * 2005-09-06 2012-02-22 キヤノン株式会社 Semiconductor device, thin film transistor, and thin film diode
KR100752696B1 (en) * 2006-02-16 2007-08-29 삼성전기주식회사 Vertical GaN-based Light-Emitting Diode Device
JP2007273975A (en) * 2006-03-10 2007-10-18 Matsushita Electric Works Ltd Light-emitting device
KR100771227B1 (en) 2006-03-17 2007-10-29 한국광기술원 Nitride-based light emitting device having a dielectric DVR and its manufacturing method
JP5048960B2 (en) * 2006-03-20 2012-10-17 パナソニック株式会社 Semiconductor light emitting device
KR100812738B1 (en) * 2006-08-14 2008-03-12 삼성전기주식회사 Surface irregularities forming method and manufacturing method of nitride based semiconductor light emitting device using the same
KR100826375B1 (en) * 2006-08-24 2008-05-02 삼성전기주식회사 Nitride semiconductor light emitting device and manufacturing method
US8878245B2 (en) * 2006-11-30 2014-11-04 Cree, Inc. Transistors and method for making ohmic contact to transistors
US9484499B2 (en) * 2007-04-20 2016-11-01 Cree, Inc. Transparent ohmic contacts on light emitting diodes with carrier substrates
DE102007019775B4 (en) * 2007-04-26 2024-11-28 OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung optoelectronic component
KR101393353B1 (en) * 2007-10-29 2014-05-13 서울바이오시스 주식회사 Light emitting diode
JP2009238931A (en) * 2008-03-26 2009-10-15 Panasonic Electric Works Co Ltd Semiconductor light-emitting element and manufacturing method therefor, and luminaire using the element
CN102089703B (en) * 2008-06-13 2013-10-16 3M创新有限公司 Illumination device with progressive injection
JP5390604B2 (en) * 2008-06-13 2014-01-15 スリーエム イノベイティブ プロパティズ カンパニー Collimated light engine
JP5151758B2 (en) * 2008-07-18 2013-02-27 豊田合成株式会社 Light emitting element
KR101478335B1 (en) * 2008-08-21 2015-01-02 서울바이오시스 주식회사 Ultra violet light emitting diode with a aluminum reflection structure and fabrication method of the same
US8870436B2 (en) * 2008-09-17 2014-10-28 3M Innovative Properties Company Patterned adhesives for reflectors
US8149351B2 (en) * 2008-12-08 2012-04-03 3M Innovative Properties Company Passive and hybrid daylight-coupled backlights for sunlight viewable displays
WO2010078424A1 (en) 2008-12-30 2010-07-08 3M Innovative Properties Company Lighting assembly
JP5600121B2 (en) 2009-01-15 2014-10-01 スリーエム イノベイティブ プロパティズ カンパニー Light block
JP5237854B2 (en) * 2009-02-24 2013-07-17 パナソニック株式会社 Light emitting device
JP2012524381A (en) 2009-04-15 2012-10-11 スリーエム イノベイティブ プロパティズ カンパニー Black light for light guide and display system with optical film containing voids
TWI605276B (en) 2009-04-15 2017-11-11 3M新設資產公司 Optical construction and display system incorporating same
CN102460125B (en) 2009-04-15 2015-11-25 3M创新有限公司 Prevent the blooming of optical coupled
US9291752B2 (en) 2013-08-19 2016-03-22 3M Innovative Properties Company Retroreflecting optical construction
US8534849B2 (en) 2009-04-15 2013-09-17 3M Innovative Properties Company Retroreflecting optical construction
US8741715B2 (en) * 2009-04-29 2014-06-03 Cree, Inc. Gate electrodes for millimeter-wave operation and methods of fabrication
WO2010141261A2 (en) 2009-06-02 2010-12-09 3M Innovative Properties Company Light redirecting film and display system incorporating same
US8339542B2 (en) * 2009-06-26 2012-12-25 3M Innovative Properties Company Passive and hybrid daylight-coupled N-stack and collapsible backlights for sunlight viewable displays
US9151460B2 (en) 2009-07-21 2015-10-06 3M Innovative Properties Company Light assembly
JP5837495B2 (en) 2009-08-25 2015-12-24 スリーエム イノベイティブ プロパティズ カンパニー Light redirecting film and display system incorporating the same
US8982468B2 (en) 2009-10-24 2015-03-17 3M Innovative Properties Company Voided diffuser
EP2491439A4 (en) 2009-10-24 2017-08-16 3M Innovative Properties Company Gradient low index article and method
CN102576119B (en) 2009-10-24 2014-03-26 3M创新有限公司 Light source and display system incorporating same
US8228463B2 (en) * 2009-11-18 2012-07-24 3M Innovative Properties Company Passive daylight-coupled backlight with turning film having prisms with chaos for sunlight viewable displays
KR101716922B1 (en) 2009-12-08 2017-03-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Optical constructions incorporating a light guide and low refractive index films
BR112012015602A2 (en) 2009-12-21 2016-03-22 3M Innovative Properties Co transflective articles and light assemblies
JP6356420B2 (en) 2010-04-14 2018-07-11 スリーエム イノベイティブ プロパティズ カンパニー Patterned gradient polymer film and method
EP2558289B1 (en) 2010-04-15 2018-12-26 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
WO2011129831A1 (en) 2010-04-15 2011-10-20 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
EP2558290B1 (en) 2010-04-15 2019-01-23 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
KR101842728B1 (en) 2010-05-07 2018-03-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Antireflective films comprising microstructured surface
US9070851B2 (en) 2010-09-24 2015-06-30 Seoul Semiconductor Co., Ltd. Wafer-level light emitting diode package and method of fabricating the same
EP2624318A4 (en) * 2010-09-30 2015-11-11 Dowa Electronics Materials Co Ltd GROUP III ELEMENT NITRIDE SEMICONDUCTOR LIGHT EMITTING ELEMENT AND METHOD FOR MANUFACTURING THE SAME
US8384852B2 (en) 2010-11-22 2013-02-26 3M Innovative Properties Company Hybrid daylight-coupled backlights for sunlight viewable displays
WO2012161824A1 (en) 2011-03-03 2012-11-29 3M Innovative Properties Company Projection system
TWI529963B (en) 2011-07-25 2016-04-11 廣鎵光電股份有限公司 Light-emitting element structure
KR101989207B1 (en) 2011-11-23 2019-06-13 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Optical stack with asymmetric diffuser
US9389355B2 (en) 2012-03-20 2016-07-12 3M Innovative Properties Company Structured optical film
KR102217128B1 (en) * 2014-06-26 2021-02-18 서울바이오시스 주식회사 Light emitting diode and method of fabricating the same
EP3037868A1 (en) 2012-08-22 2016-06-29 3M Innovative Properties Company Polarizing beam splitter
US9229141B2 (en) 2012-12-13 2016-01-05 3M Innovative Properties Company Optical assembly
KR102076241B1 (en) * 2013-08-07 2020-02-12 엘지이노텍 주식회사 Ultraviolet Light Emitting Device
SG11201608892PA (en) 2014-04-25 2016-11-29 3M Innovative Properties Co Textured coating for optical products
USD826871S1 (en) 2014-12-11 2018-08-28 Cree, Inc. Light emitting diode device
CN205944139U (en) 2016-03-30 2017-02-08 首尔伟傲世有限公司 Ultraviolet ray light -emitting diode spare and contain this emitting diode module
JP6432654B2 (en) * 2017-08-16 2018-12-05 日亜化学工業株式会社 Semiconductor light emitting device
TWI743722B (en) 2020-03-30 2021-10-21 元太科技工業股份有限公司 Display device
CN113809206B (en) * 2020-06-11 2025-01-07 苏州晶湛半导体有限公司 Semiconductor structure and method for manufacturing the same
WO2021253179A1 (en) * 2020-06-15 2021-12-23 泉州三安半导体科技有限公司 Light-emitting diode

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6486044B2 (en) * 1999-10-29 2002-11-26 Ohio University Band gap engineering of amorphous Al-Ga-N alloys
US20050247950A1 (en) * 2004-05-06 2005-11-10 Cree, Inc. Lift-off process for GaN films formed on SiC substrates and devices fabricated using the method
US20060208273A1 (en) * 2003-08-08 2006-09-21 Sang-Kyu Kang Nitride micro light emitting diode with high brightness and method of manufacturing the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4486044A (en) * 1982-08-06 1984-12-04 Tank-Tote Co. Apparatus for supporting and transporting a gas cylinder
JP2000091701A (en) 1998-09-04 2000-03-31 Hewlett Packard Co <Hp> Reflection mirror, semiconductor laser, formation of reflection mirror, and manufacture of semiconductor laser
US6573537B1 (en) 1999-12-22 2003-06-03 Lumileds Lighting, U.S., Llc Highly reflective ohmic contacts to III-nitride flip-chip LEDs
JP4239508B2 (en) 2002-08-01 2009-03-18 日亜化学工業株式会社 Light emitting element
TW586246B (en) * 2002-10-28 2004-05-01 Super Nova Optoelectronics Cor Manufacturing method of white light LED and the light-emitting device thereof
US7332365B2 (en) * 2004-05-18 2008-02-19 Cree, Inc. Method for fabricating group-III nitride devices and devices fabricated using method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6486044B2 (en) * 1999-10-29 2002-11-26 Ohio University Band gap engineering of amorphous Al-Ga-N alloys
US20060208273A1 (en) * 2003-08-08 2006-09-21 Sang-Kyu Kang Nitride micro light emitting diode with high brightness and method of manufacturing the same
US20050247950A1 (en) * 2004-05-06 2005-11-10 Cree, Inc. Lift-off process for GaN films formed on SiC substrates and devices fabricated using the method

Cited By (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1995794A4 (en) * 2006-03-10 2011-08-31 Panasonic Elec Works Co Ltd LIGHT EMITTING DEVICE
CN100449805C (en) * 2006-11-08 2009-01-07 吴质朴 Manufacturing method of aluminum gallium indium phosphide compound semiconductor light emitter
US8030664B2 (en) * 2006-12-15 2011-10-04 Samsung Led Co., Ltd. Light emitting device
US20080142782A1 (en) * 2006-12-15 2008-06-19 Samsung Electro-Mechanics Co., Ltd. Light emitting device
US8471268B2 (en) 2006-12-15 2013-06-25 Samsung Electronics Co., Ltd. Light emitting device
US20080157107A1 (en) * 2006-12-29 2008-07-03 Epitech Technology Corporation Light-emitting diode and method for manufacturing the same
US7675077B2 (en) * 2006-12-29 2010-03-09 Epistar Corporation Light-emitting diode and method for manufacturing the same
US8653540B2 (en) 2007-04-26 2014-02-18 Osram Opto Semiconductors Gmbh Optoelectronic semiconductor body and method for producing the same
US20100171135A1 (en) * 2007-04-26 2010-07-08 Karl Engl Optoelectronic Semiconductor Body and Method for Producing the Same
US8450751B2 (en) 2007-04-26 2013-05-28 Osram Opto Semiconductors Gmbh Optoelectronic semiconductor body and method for producing the same
EP2159852A4 (en) * 2007-06-15 2012-09-26 Rohm Co Ltd LIGHT-EMITTING SEMICONDUCTOR ELEMENT
US8212273B2 (en) 2007-07-19 2012-07-03 Photonstar Led Limited Vertical LED with conductive vias
US8362506B2 (en) 2007-09-28 2013-01-29 Osram Opto Semiconductors Gmbh Optoelectronic semiconductor body
US20100230698A1 (en) * 2007-09-28 2010-09-16 Patrick Rode Optoelectronic Semiconductor Body
US8618571B2 (en) 2007-11-26 2013-12-31 Lg Innotek Co., Ltd. Semiconductor light emitting device having a reflective layer
EP2201618B1 (en) * 2007-11-26 2014-06-18 LG Innotek Co., Ltd. Semiconductor light emitting device
EP2485280A3 (en) * 2007-11-26 2013-01-16 LG Innotek Co., Ltd. Semiconductor light emitting device
US8969902B2 (en) 2007-11-26 2015-03-03 Lg Innotek Co., Ltd. Semiconductor light emitting device
US9472739B2 (en) 2007-11-26 2016-10-18 Lg Innotek Co., Ltd. Semiconductor light emitting device
US8928052B2 (en) 2008-03-31 2015-01-06 Osram Opto Semiconductors Gmbh Optoelectronic semiconductor chip and method for producing same
US20110049555A1 (en) * 2008-03-31 2011-03-03 Karl Engl Optoelectronic Semiconductor Chip and Method for Producing Same
WO2009121319A1 (en) * 2008-03-31 2009-10-08 Osram Opto Semiconductors Gmbh Opto-electronic semiconductor chip and method for producing the same
US8106415B2 (en) * 2008-04-22 2012-01-31 Lg Innotek Co., Ltd. Semiconductor light emitting device
KR100986557B1 (en) * 2008-04-22 2010-10-07 엘지이노텍 주식회사 Semiconductor light emitting device and manufacturing method thereof
US20090261318A1 (en) * 2008-04-22 2009-10-22 Cheong Hung Seob Semiconductor light emitting device
US8319243B2 (en) 2008-08-05 2012-11-27 Sharp Kabushiki Kaisha Nitride semiconductor light-emitting device and method of manufacturing the same
US8063410B2 (en) 2008-08-05 2011-11-22 Sharp Kabushiki Kaisha Nitride semiconductor light emitting device and method of manufacturing the same
US20100032701A1 (en) * 2008-08-05 2010-02-11 Sharp Kabushiki Kaisha Nitride semiconductor light emitting device and method of manufacturing the same
EP2430673B1 (en) * 2009-05-11 2020-05-27 Cree, Inc. Semiconductor light emitting diodes having reflective structures and methods of fabricating same
DE102010009717A1 (en) * 2010-03-01 2011-09-01 Osram Opto Semiconductors Gmbh LED chip
US8872209B2 (en) 2010-03-01 2014-10-28 Osram Opto Semiconductors Gmbh Light emitting diode chip
CN101807650A (en) * 2010-03-19 2010-08-18 厦门市三安光电科技有限公司 Gallium nitride-based high-brightness light-emitting diode with distributed Bragg reflecting layer and manufacturing process thereof
CN102208512A (en) * 2010-03-24 2011-10-05 日立电线株式会社 Light emitting diode
US8399906B2 (en) * 2010-05-04 2013-03-19 Xiamen Sanan Optoelectronics Technology Co., Ltd. AlGaInP-based light-emitting diode with double reflective layers and fabrication method thereof
US20110272724A1 (en) * 2010-05-04 2011-11-10 Xiamen Sanan Optoelectronics Technology Co., Ltd. Algainp-based light-emitting diode with double reflective layers and fabrication method thereof
US20110278538A1 (en) * 2010-05-11 2011-11-17 Ko Hyung Duk Semiconductor light emitting device and method for fabricating the same
US8993993B2 (en) * 2010-05-11 2015-03-31 Samsung Electronics Co., Ltd. Semiconductor light emitting device and method for fabricating the same
CN101859861A (en) * 2010-05-13 2010-10-13 厦门市三安光电科技有限公司 GaN-based flip-chip light-emitting diode with double reflecting layers and preparation method thereof
CN102479916A (en) * 2010-11-26 2012-05-30 金龙国际公司 Light-emitting diode chip structure
US9577165B2 (en) 2011-08-31 2017-02-21 Osram Opto Semiconductor Gmbh Light emitting diode chip
US10043958B2 (en) 2011-08-31 2018-08-07 Osram Opto Semiconductors Gmbh Light emitting diode chip
US20130146906A1 (en) * 2011-11-25 2013-06-13 Lg Innotek Co., Ltd. Ultraviolet semiconductor light emitting device
US11862756B2 (en) 2012-05-29 2024-01-02 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US10553760B2 (en) 2012-05-29 2020-02-04 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US9911903B2 (en) 2012-05-29 2018-03-06 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US9450152B2 (en) * 2012-05-29 2016-09-20 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US12266739B2 (en) 2012-05-29 2025-04-01 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US20130320370A1 (en) * 2012-05-29 2013-12-05 Micron Technology, Inc. Solid state transducer dies having reflective features over contacts and associated systems and methods
US20150060880A1 (en) * 2012-06-21 2015-03-05 Xiamen Sanan Optoelectronics Technology Co., Ltd. GaN-Based LED
US20150060879A1 (en) * 2012-06-21 2015-03-05 Xiamen Sanan Optoelectronics Technology Co., Ltd. GaN-Based LED
US9190395B2 (en) * 2012-06-21 2015-11-17 Xiamen Sanan Optoelectronics Technology Co., Ltd. GaN-based LED
US9356190B2 (en) * 2012-06-21 2016-05-31 Xiamen Sanan Optoelectronics Technology Co., Ltd. GaN-based LED
EP2750207A3 (en) * 2012-12-12 2015-12-09 Seoul Viosys Co., Ltd. Light-emitting diode and method of fabricating the same
EP2743997A3 (en) * 2012-12-12 2015-12-09 Seoul Viosys Co., Ltd. Light-emitting diode and method of fabricating the same
US9401456B2 (en) * 2012-12-14 2016-07-26 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
US9978910B2 (en) * 2012-12-14 2018-05-22 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
US20150280074A1 (en) * 2012-12-14 2015-10-01 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
US10243109B2 (en) 2012-12-14 2019-03-26 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
US20170077355A1 (en) * 2012-12-14 2017-03-16 Seoul Viosys Co., Ltd. Light-emitting diode with improved light extraction efficiency
TWI596801B (en) * 2012-12-14 2017-08-21 首爾偉傲世有限公司 Enhancing the light extraction efficiency of the light-emitting diode by using a reflective layer
US9425359B2 (en) 2013-02-04 2016-08-23 Industrial Technology Research Institute Light emitting diode
US20140231851A1 (en) * 2013-02-04 2014-08-21 Industrial Technology Research Institute Light emitting diode
US9548424B2 (en) 2013-02-04 2017-01-17 Industrial Technology Research Institute Light emitting diode
US9391239B2 (en) * 2013-02-04 2016-07-12 Industrial Technology Research Institute Light emitting diode
US20160099385A1 (en) * 2013-04-22 2016-04-07 Korea Polytechnic University Industry Academic Cooperation Foundation Method for Manufacturing Vertical Type Light Emitting Diode, Vertical Type Light Emitting Diode, Method for Manufacturing Ultraviolet Ray Light Emitting Diode, and Ultraviolet Ray Light Emitting Diode
US10014442B2 (en) * 2013-04-22 2018-07-03 Korea Polytechnic University Industry Academic Cooperation Foundation Method for manufacturing vertical type light emitting diode, vertical type light emitting diode, method for manufacturing ultraviolet ray light emitting diode, and ultraviolet ray light emitting diode
US10840400B2 (en) * 2013-08-29 2020-11-17 Taiwan Semiconductor Manufacturing Co., Ltd. Photovoltaic device with back reflector
CN109638100A (en) * 2013-08-29 2019-04-16 台湾积体电路制造股份有限公司 Photovoltaic device with backside reflection body
US20150059850A1 (en) * 2013-08-29 2015-03-05 Tsmc Solar Ltd. Photovoltaic device with back reflector
CN104576857A (en) * 2013-10-15 2015-04-29 上海工程技术大学 Flip LED chip structure with high reflection layer and manufacturing method of flip LED chip structure
CN104037295A (en) * 2014-06-16 2014-09-10 江苏汉莱科技有限公司 LED (Light-Emitting Diode) flip chip and manufacturing method thereof
CN104253184A (en) * 2014-09-24 2014-12-31 山西飞虹微纳米光电科技有限公司 Blue light LED (Light Emitting Diode) epitaxial structure with gradually-changed DBR (Distributed Bragg Reflector) layer
CN104409585A (en) * 2014-11-28 2015-03-11 杭州士兰明芯科技有限公司 Vertical LED structure and manufacturing method thereof
US20180226541A1 (en) * 2015-08-24 2018-08-09 Lg Innotek Co., Ltd. Light emitting element
US10763394B2 (en) * 2015-08-24 2020-09-01 Lg Innotek Co., Ltd. Light emitting element having excellent contact between semiconductor layer and electrode
US11018279B2 (en) 2015-08-24 2021-05-25 Lg Innotek Co., Ltd. Light emitting element having excellent contact between semiconductor layer and electrode
CN105047785A (en) * 2015-09-09 2015-11-11 厦门乾照光电股份有限公司 Light emitting diode with micro optimal transmission system
CN111129237A (en) * 2018-01-02 2020-05-08 首尔伟傲世有限公司 Display device with light-emitting stacked structure
EP4107792A4 (en) * 2020-03-20 2024-03-27 Sensor Electronic Technology, Inc. OPTOELECTRONIC DEVICE WITH REDUCED OPTICAL LOSS
US12100779B2 (en) 2020-03-20 2024-09-24 Sensor Electronic Technology, Inc. Optoelectronic device with reduced optical loss
CN112542533A (en) * 2020-12-01 2021-03-23 北京大学 High-photoelectric-conversion-rate inverted-structure deep ultraviolet micro-LED and preparation method thereof
CN112951955A (en) * 2021-01-26 2021-06-11 华灿光电(浙江)有限公司 Ultraviolet light-emitting diode epitaxial wafer and preparation method thereof
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WO2024033375A1 (en) * 2022-08-10 2024-02-15 Ams-Osram International Gmbh Optoelectronic semiconductor component with an epitaxially grown layer and method for producing the optoelectronic semiconductor component

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