US20060033113A1 - Nitride semiconductor light emitting diode and method of manufacturing the same - Google Patents
Nitride semiconductor light emitting diode and method of manufacturing the same Download PDFInfo
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- US20060033113A1 US20060033113A1 US11/064,968 US6496805A US2006033113A1 US 20060033113 A1 US20060033113 A1 US 20060033113A1 US 6496805 A US6496805 A US 6496805A US 2006033113 A1 US2006033113 A1 US 2006033113A1
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- 150000004767 nitrides Chemical class 0.000 title claims abstract description 161
- 239000004065 semiconductor Substances 0.000 title claims abstract description 110
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000758 substrate Substances 0.000 claims abstract description 37
- 238000002834 transmittance Methods 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims description 25
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 21
- 230000004888 barrier function Effects 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910002704 AlGaN Inorganic materials 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 229910052741 iridium Inorganic materials 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052594 sapphire Inorganic materials 0.000 description 13
- 239000010980 sapphire Substances 0.000 description 13
- 230000008569 process Effects 0.000 description 10
- 239000013078 crystal Substances 0.000 description 8
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001451 molecular beam epitaxy Methods 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/831—Electrodes characterised by their shape
- H10H20/8316—Multi-layer electrodes comprising at least one discontinuous layer
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/832—Electrodes characterised by their material
- H10H20/835—Reflective materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/84—Coatings, e.g. passivation layers or antireflective coatings
- H10H20/841—Reflective coatings, e.g. dielectric Bragg reflectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/12—Structure, shape, material or disposition of the bump connectors prior to the connecting process
- H01L2224/14—Structure, shape, material or disposition of the bump connectors prior to the connecting process of a plurality of bump connectors
- H01L2224/1401—Structure
- H01L2224/1403—Bump connectors having different sizes, e.g. different diameters, heights or widths
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/822—Materials of the light-emitting regions
- H10H20/824—Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP
- H10H20/825—Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP containing nitrogen, e.g. GaN
Definitions
- the present invention relates to a nitride semiconductor light emitting diode, and more particularly to a nitride semiconductor light emitting diode that adopts a flip chip structure. Also, the present invention relates to a method of manufacturing the same.
- a nitride semiconductor light emitting diode is a light emitting diode used to obtain light having a blue or green wavelength band.
- the nitride semiconductor light emitting diode is made of a nitride semiconductor material having the following formula: Al x In y Ga (1-x-y) N
- a substrate used to grow such a nitride semiconductor material is limited to a sapphire substrate because of lattice matching.
- the sapphire substrate is an insulated substrate, and thus both electrodes of the nitride semiconductor light emitting diode are formed at the opposite side of the sapphire substrate, i.e., a crystal growth surface.
- a nitride semiconductor light emitting diode adopting a flip chip structure where the sapphire substrate is provided with a main light emitting surface.
- FIG. 1 shows a flip chip structure of a conventional flip chip-type nitride light emitting diode.
- a flip chip-type light emitting device 20 shown in FIG. 1 comprises a nitride semiconductor light emitting diode 10 mounted on a chip substrate 21 .
- the nitride semiconductor light emitting diode 10 comprises a sapphire substrate 11 , an n-type nitride semiconductor layer 12 disposed on the sapphire substrate 11 , an active layer 13 disposed on the n-type nitride semiconductor layer 12 , and a p-type nitride semiconductor layer 14 disposed on the active layer 13 .
- the nitride semiconductor light emitting diode 10 is mounted on the chip substrate such that electrodes 19 a and 19 b are connected to lead patterns 22 a and 22 b via conductive bumps 24 a and 24 b , respectively.
- the sapphire substrate 11 of the light emitting diode 10 is a light transmittance substrate. Consequently, the sapphire substrate 11 may be used as a light emitting surface of the flip chip-type light emitting device 20 .
- the electrodes of the nitride semiconductor light emitting diode 10 especially, the p-side electrode form ohmic contact with the p-type nitride semiconductor layer 14 , and have high reflexibility sufficient to reflect light emitted from the active layer 13 to the sapphire substrate 11 .
- the p-side electrode structure may include an ohmic contact layer 16 and a metal barrier layer 17 formed on the p-type nitride semiconductor layer 14 .
- the ohmic contact layer 16 is made of Ag or Al having high reflexibility of approximately 90% to 95% so that the ohmic contact layer 16 can improve contact resistance.
- the metal barrier layer 17 serves to prevent undesired immigration of components of the ohmic contact layer 16 .
- the metal, such as Ag or Al, forming the ohmic contact layer 16 is very sensitive to heat. As a result, the reflexibility of the ohmic contact layer 16 is lowered to approximately 60%-80%. If the reflexibility of the ohmic contact layer 16 is lowered, brightness of the flip chip-type light emitting device 20 is also lowered.
- the conventional nitride semiconductor light emitting diode 10 substantially has a planner electrode structure.
- the p-side ohmic contact layer 16 has specific resistance lower than that of the p-type nitride semiconductor layer 14 .
- a large portion of electric current is concentrated to a part A adjacent to the n-side electrode as indicated by the arrow.
- current crowding occurs.
- forward voltage is increased, light emitting efficiency of the active layer 13 disposed opposite to the n-side electrode 19 a is decreased, and heat value of the part A where the electric current is concentrated is increased, whereby reliability of the nitride semiconductor light emitting diode is considerably deteriorated.
- the present invention has been made in view of the above problems, and it is an object of the present invention to provide a nitride semiconductor light emitting diode having an improved p-side electrode structure, thereby improving current diffusion effects and reflexibility.
- a nitride semiconductor light emitting diode comprising: a light transmittance substrate that allows a nitride semiconductor to be grown thereon; an n-type nitride semiconductor layer formed on the light transmittance substrate; an active layer formed on the n-type nitride semiconductor layer; a p-type nitride semiconductor layer formed on the active layer; a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh
- difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers.
- the first and second nitride layers constituting the mesh-type DBR reflecting layer may be formed of materials satisfying the following formula: Al 1-x Ga x N (0 ⁇ x ⁇ 1).
- the first nitride layer is made of AlGaN
- the second nitride layer is made of GaN.
- the effective area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
- the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
- the nitride semiconductor light emitting diode further comprises: a metal barrier layer formed on the surface of the ohmic contact layer.
- the metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
- a method of manufacturing a nitride semiconductor light emitting diode comprising the steps of: preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon; forming an n-type nitride semiconductor layer on the light transmittance substrate; forming an active layer on the n-type nitride semiconductor layer; forming a p-type nitride semiconductor layer on the active layer; alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
- the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
- the step of forming the mesh-type DBR reflecting layer is carried out at a temperature of 500° C. to 700° C. to prevent occurrence of cracks.
- a flip chip-type light emitting device used in the present invention indicates a light emitting device having a light emitting diode mounted on a chip substrate in a flip chip structure, as shown in FIG. 1 .
- FIG. 1 is a side view, in section, showing a conventional flip chip-type nitride light emitting diode
- FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode according to a preferred embodiment of the present invention
- FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode according to the preferred embodiment of the present invention show in FIG. 2A ;
- FIG. 3 is a side view, in section, showing a flip chip-type nitride light emitting diode according to another preferred embodiment of the present invention.
- the p-type and n-type nitride semiconductor layers are single crystals each having the following formula: Al X In y Ga (1-X-y) N (where, 0 ⁇ x ⁇ 1, 0 ⁇ y ⁇ 1, and (0 ⁇ x+y ⁇ 1), and are grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE).
- MOCVD Metal Organic Chemical Vapor Deposition
- MBE Molecular Beam Epitaxy
- HVPE Hydride Vapor Phase Epitaxy
- the typical nitride semiconductor layers include GaN, AlGaN, and GaInN.
- the P-type nitride semiconductor layer may contain impurities, such as Mg, Zn, and Be.
- the n-type nitride semiconductor layer may contain impurities, such as Si, Ge, Se, Te, and C.
- a buffer layer for lattice matching Between the substrate and the nitride semiconductor layer is usually disposed a buffer layer for lattice matching.
- the common buffer layer may be a low-temperature core growth layer, such as AlN or GaN.
- the active layer adopted in the present invention is a layer for emitting blue-green light (having a wavelength of approximately 350 to 550 nm).
- the active layer comprises an undoped nitride semiconductor layer having a single or multiple quantum well structure.
- the active layer may be grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE), as in the p-type and n-type nitride semiconductor layer.
- MOCVD Metal Organic Chemical Vapor Deposition
- MBE Molecular Beam Epitaxy
- HVPE Hydride Vapor Phase Epitaxy
- the present invention comprises a mesh-type DBR reflecting layer.
- the mesh-type DBR reflecting layer adopted in the present invention is composed of two kinds of nitride layers having different Al content, which are alternately stacked several times.
- a refractive index of the nitride may vary depending upon the Al content. For this reason, a DBR structure having high reflexibility may be formed.
- the difference between the refractive index of one of the nitride layers and the refractive index of the other nitride layer, both of which constitute the mesh-type DBR reflecting layer is great, the thickness of the layer may be decreased, and the number of times at which the layers are stacked is decreased.
- the mesh-type DBR reflecting layer is preferably composed of two kinds of nitride layers having different Al content, difference of which is at least 30%.
- the mesh-type DBR reflecting layer is designed to obtain high reflexibility of 90% or more, preferably 95% or more, and more preferably 98% or more.
- the DBR reflecting layer of the present invention is formed in the shape of a mesh. Consequently, an ohmic contact layer, which will be formed in a subsequent process, contacts the p-type nitride semiconductor layer through a plurality of open regions arranged over the mesh-type DBE reflecting layer.
- the DBR reflecting layer which is made of nitrides, has resistance higher than that of the ohmic contact layer. As a result, electric current flowing to the active layer through the ohmic contact layer is uniformly diffused by means of the mesh-type DBR reflecting layer. Consequently, current crowding is mitigated.
- the mesh-type DBR reflecting layer is formed of a three component-based nitride satisfying the following formula: Al 1-x Ga x N (0 ⁇ x ⁇ 1) to easily adjust the Al content. More preferably, the mesh-type DBR reflecting layer is formed of a first nitride layer, such ah GaN, and a second nitride layer, such as Al 1-x Ga x N (0 ⁇ x ⁇ 1), which are alternately stacked several times.
- the nitride layers constituting the mesh-type DBR reflecting layer may be formed successively through the use of the same growth process as the p-type and n-type nitride semiconductor layers and the active layer, i.e., through the use of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). Subsequently, the nitride layers are selectively etched by means of a photolithographic process to obtain the desired mesh-type DBR reflecting layer.
- MOCVD Metal Organic Chemical Vapor Deposition
- MBE Molecular Beam Epitaxy
- HVPE Hydride Vapor Phase Epitaxy
- the ohmic contact layer adopted in the present invention is formed on the mesh-type DBR reflecting layer and the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer. Electric current flowing to the active layer though the ohmic contact layer having high reflexibility is uniformly diffused over the entire surface of the p-type nitride semiconductor layer by means of the mesh-type DBR reflecting layer having high resistance. As a result, current crowding is mitigated.
- the ohmic contact layer having high reflexibility be formed of high reflexibility sufficient to lower contact resistance between the p-type nitride semiconductor layer having a relatively high energy band gap.
- the ohmic contact layer having high reflexibility may be formed of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
- the ohmic contact layer has reflexibility of 70% or more.
- the ohmic contact layer may be formed of Ni/Ag, Zn/Ag, Ni/Al, Zn/Al, Pd/Ag, Pd/Al, Ir/Ag, Ir/Au, Pt/Ag, Pt/Al, or Ni/Ag/Pt.
- the ohmic contact layer is formed by means of an ordinary deposition or sputtering process.
- the ohmic contact layer may be thermally treated at the temperature of approximately 400° C. to 900° C. to improve the characteristics of the ohmic contact layer.
- the metal barrier layer adopted in the present invention is formed at the ohmic contact layer having high reflexibility where a p-side bonding electrode is to be formed.
- the metal barrier layer is disposed at the interface between the bonding electrode material and the ohmic contact layer material for preventing deterioration of the characteristics (especially, reflexibility and contact resistance) of the ohmic contact layer.
- the metal barrier layer may be constructed in a single-layered structure or a multiple-layered structure.
- the metal barrier layer may be made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
- the metal barrier layer may extend to the sides of the ohmic contact layer having high reflexibility. In this case, it is possible to effectively prevent occurrence of current leakage due to migration of Ag when the ohmic contact layer having high reflexibility contains Ag.
- the metal barrier layer is formed by means of an ordinary deposition or sputtering process, as in the above-described electrodes.
- the metal barrier layer may be thermally treated at a temperature of approximately 300° C. for several tens of seconds or several minutes to improve adherence.
- the p-side bonding electrode which constitutes the p-side electrode structure together with the ohmic contact layer and the metal barrier layer, is an uppermost electrode layer to be mounted on a lead through a conductive bump in the flip chip structure.
- the p-side bonding electrode is made of Au or an alloy containing Au.
- the n-side electrode formed on the n-type nitride semiconductor layer may be constructed in a single-layered structure or a multiple-layered structure.
- the n-side electrode may be made of a material selected from the group consisting of Ti, Cr, Al, Cu, and Au.
- the electrodes are formed by means of an ordinary metal layer growth process, such as deposition or a sputtering process.
- FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode 30 according to a preferred embodiment of the present invention
- FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode 30 according to the preferred embodiment of the present invention show in FIG. 2A .
- the flip chip-type nitride semiconductor light emitting diode 30 comprises a nitride semiconductor growth substrate 31 , such as a sapphire substrate, an n-type nitride semiconductor layer 32 disposed on the nitride semiconductor growth substrate 31 , an active layer 33 disposed on the n-type nitride semiconductor layer 32 , and a p-type nitride semiconductor layer 34 disposed on the active layer 33 .
- the nitride semiconductor light emitting diode 30 has an n-side electrode 39 a formed on the upper surface of the n-type nitride semiconductor layer 32 , which is exposed by means of mesa etching.
- a p-side electrode structure adopted in the nitride semiconductor light emitting diode 30 includes a mesh-type DBR reflecting layer 35 , an ohmic contact layer 36 , and a bonding electrode 39 b .
- the ohmic contact layer 36 is formed on the p-type nitride semiconductor layer 34 .
- the ohmic contact layer 36 is constructed in a mesh structure having a plurality of open regions, by which the p-type nitride semiconductor layer 34 is partially exposed.
- the bonding electrode 39 b is formed on the upper surface of the ohmic contact layer 35 .
- the mesh-type DBR reflecting layer 35 comprises first and second nitride layers 35 a and 35 b having different Al content, which are alternately stacked several times.
- difference of the Al content between the first and second nitride layers 35 a and 35 b is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers 35 a and 35 b .
- the mesh-type DBR reflecting layer 35 may be an AlGaN-based nitride layer.
- the first nitride layer 35 a is GaN
- the second nitride layer 35 b is AlGaN. In this case, the mesh-type DBR reflecting layer 35 has high reflexibility.
- the mesh-type DBR reflecting layer 35 maintains stable reflexibility at high temperature, unlike the ohmic contact material having high reflexibility, such as Ag or Al. Consequently, the total reflexibility is prevented from being deteriorated by the area of the mesh-type DBR reflecting layer 35 even when the temperature is high.
- the first and second nitride layers 35 a and 35 b are undoped crystal layers, although each of the first and second nitride layers 35 a and 35 b may be manufactured in the shape of an amorphous layer.
- a crack may occur at an ordinary crystal growth temperature (more than 1000° C.). Consequently, it is preferable to grow the mesh-type DBR reflecting layer 35 at a temperature of 500° C. to 700° C.
- the mesh-type DBR reflecting layer 35 has a plurality of open regions, which are arranged in the mesh structure.
- the ohmic contact layer 36 formed on the mesh-type DBR reflecting layer 35 contacts the p-type nitride semiconductor layer 34 through the open regions of the mesh-type DBR reflecting layer 35 to form ohmic contact.
- the mesh-type DBR reflecting layer 35 has resistance higher than that of the ohmic contact layer 36 . Consequently, electric current flowing from the p-side bonding electrode 39 b to the n-side electrode 39 a through the ohmic contact layer 36 is uniformly diffused by means of the mesh structure of the mesh-type DBR reflecting layer, as indicated by the arrow in FIG. 2A .
- the effective area of the mesh-type DBR reflecting layer 35 i.e., the area of the mesh-type DBR reflecting layer 35 excluding the open regions of the mesh-type DBR reflecting layer 35 ), since brightness is increased by virtue of high reflexibility. It is necessary, however, that sufficient contact area be provided between the p-type nitride semiconductor layer 34 and the ohmic contact layer 36 .
- the effective area of the mesh-type DBR reflecting layer 35 is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer 34 .
- the mesh-type DBR reflecting layer 35 adopted in the present invention is composed of a nitride layer, such as AlGaN. Consequently, the mesh-type DBR reflecting layer 35 can be successively formed by means of the same growth process as the p-type and n-type nitride semiconductor layers 34 and 32 and the active layer 33 .
- the mesh-type DBR reflecting layer 35 when the mesh-type DBR reflecting layer 35 is composed of a first nitride layer 36 a , such as GaN, and a second nitride layer 36 b , such as AlGaN, the mesh-type DBR reflecting layer 35 can be manufactured using trimethylgallium (TMG), trimethylaluminum (TMA), and ammonia (NH 4 ) as a source gas under conditions similar to the single crystal growth process of the nitride in a MOCVD chamber where a single crystal growth process for a light emitting structure is carried out. As described above, the mesh-type DBR reflecting layer 35 is not limited to the single crystal.
- the mesh-type DBR reflecting layer 35 is preferably manufactured in the shape of an amorphous layer, which is grown at low temperature.
- the mesh-type DBR reflecting layer 35 can be grown at a temperature lower than the single crystal growing temperature, for example, 500° C. to 700° C.
- FIG. 3 is a side view, in section, showing a flip chip-type light emitting device 60 according to another preferred embodiment of the present invention.
- the flip chip-type light emitting device 60 comprises a chip substrate 61 and a nitride light emitting diode 50 disposed on the chip substrate 61 .
- the nitride semiconductor light emitting diode 50 comprises a nitride semiconductor growth substrate 51 , such as a sapphire substrate, an n-type nitride semiconductor layer 52 disposed on the nitride semiconductor growth substrate 51 , an active layer 53 disposed on the n-type nitride semiconductor layer 52 , and a p-type nitride semiconductor layer 54 disposed on the active layer 53 .
- the nitride semiconductor light emitting diode 50 is mounted on the chip substrate 61 such that electrodes 69 a and 69 b are connected to lead patterns 62 a and 62 b via conductive bumps 64 a and 64 b , respectively.
- the nitride semiconductor light emitting diode 50 has an n-side electrode 59 a formed on the upper surface of the n-type nitride semiconductor layer 52 , which is exposed by means of mesa etching.
- a p-side electrode structure adopted in the nitride semiconductor light emitting diode 50 includes a mesh-type DBR reflecting layer 55 , an ohmic contact layer 56 , and a bonding electrode 59 b , which are similar to those shown in FIG. 2A .
- a metal barrier layer 57 is formed on the surface of the ohmic contact layer 56 such that the metal barrier layer 57 surrounds both sides of the ohmic contact layer 56 .
- the metal barrier layer 57 serves to prevent immigration of the material of the ohmic contact layer 56 , such as Al, and mixture of Au component at the interface between the p-side bonding electrode 59 b and the ohmic contact layer 56 .
- the sapphire substrate 51 of the light emitting diode 50 in the flip chip-type light emitting device is a light transmittance substrate. Consequently, the sapphire substrate 51 serves as a light emitting surface of the flip chip-type light emitting device 60 .
- the mesh-type DBR reflecting layer 55 and the ohmic contact layer 56 serve as reflecting layers at the opposite side so that the amount of the emitted light can be increased.
- the mesh-type DBR reflecting layer 55 has high reflexibility of 90% or more.
- the mesh-type DBR reflecting layer 55 maintains stable reflexibility at high temperature. Consequently, reflecting performance of the mesh-type DBR reflecting layer 55 is improved.
- the mesh-type DBR reflecting layer 55 diffuses electric current provided though the ohmic contact layer 56 , whereby current crowding is mitigated.
- the present invention provides a nitride semiconductor light emitting diode having an improved p-side electrode structure where a mesh-type DBR reflecting layer is composed of two kinds of nitride layers having different Al content to decrease electric current concentrated to the region adjacent to an n-side electrode. Consequently, the present invention has the effect of mitigating current crowding and increasing reflexibility, and therefore improving overall light emitting efficiency.
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Abstract
The present invention provides a flip chip-type nitride semiconductor light emitting diode. The nitride semiconductor light emitting diode comprises a light transmittance substrate, an n-type nitride semiconductor layer, an active layer, a p-type nitride semiconductor layer and a mesh-type DBR reflecting layer. The mesh-type DBR reflecting layer has a plurality of open regions. The mesh-type DBR reflecting layer is composed of first and second nitride layers having different Al content. The first and second nitride layers are alternately stacked several times to form the mesh-type DBR reflecting layer. An ohmic contact layer is formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer.
Description
- The present application is based on, and claims priority from, Korean Application No. 2004-63214, filed on Aug. 11, 2004, the disclosure of which is incorporated by reference herein in its entirety.
- 1. Field of the Invention
- The present invention relates to a nitride semiconductor light emitting diode, and more particularly to a nitride semiconductor light emitting diode that adopts a flip chip structure. Also, the present invention relates to a method of manufacturing the same.
- 2. Description of the Related Art
- Generally, a nitride semiconductor light emitting diode is a light emitting diode used to obtain light having a blue or green wavelength band. The nitride semiconductor light emitting diode is made of a nitride semiconductor material having the following formula:
AlxInyGa(1-x-y)N - Where, 0≦x≦1, 0≦y≦1, and 0≦x+y≦1
- A substrate used to grow such a nitride semiconductor material is limited to a sapphire substrate because of lattice matching. The sapphire substrate is an insulated substrate, and thus both electrodes of the nitride semiconductor light emitting diode are formed at the opposite side of the sapphire substrate, i.e., a crystal growth surface. Considering the above-mentioned structural characteristics, there has been briskly developed a nitride semiconductor light emitting diode adopting a flip chip structure where the sapphire substrate is provided with a main light emitting surface.
-
FIG. 1 shows a flip chip structure of a conventional flip chip-type nitride light emitting diode. - A flip chip-type
light emitting device 20 shown inFIG. 1 comprises a nitride semiconductorlight emitting diode 10 mounted on achip substrate 21. The nitride semiconductorlight emitting diode 10 comprises asapphire substrate 11, an n-typenitride semiconductor layer 12 disposed on thesapphire substrate 11, anactive layer 13 disposed on the n-typenitride semiconductor layer 12, and a p-typenitride semiconductor layer 14 disposed on theactive layer 13. The nitride semiconductorlight emitting diode 10 is mounted on the chip substrate such that 19 a and 19 b are connected toelectrodes 22 a and 22 b vialead patterns 24 a and 24 b, respectively. Theconductive bumps sapphire substrate 11 of thelight emitting diode 10 is a light transmittance substrate. Consequently, thesapphire substrate 11 may be used as a light emitting surface of the flip chip-typelight emitting device 20. - It is required that the electrodes of the nitride semiconductor
light emitting diode 10, especially, the p-side electrode form ohmic contact with the p-typenitride semiconductor layer 14, and have high reflexibility sufficient to reflect light emitted from theactive layer 13 to thesapphire substrate 11. - As shown in
FIG. 1 , therefore, the p-side electrode structure may include anohmic contact layer 16 and ametal barrier layer 17 formed on the p-typenitride semiconductor layer 14. Theohmic contact layer 16 is made of Ag or Al having high reflexibility of approximately 90% to 95% so that theohmic contact layer 16 can improve contact resistance. Themetal barrier layer 17 serves to prevent undesired immigration of components of theohmic contact layer 16. - However, the metal, such as Ag or Al, forming the
ohmic contact layer 16 is very sensitive to heat. As a result, the reflexibility of theohmic contact layer 16 is lowered to approximately 60%-80%. If the reflexibility of theohmic contact layer 16 is lowered, brightness of the flip chip-typelight emitting device 20 is also lowered. - Also, the conventional nitride semiconductor
light emitting diode 10 substantially has a planner electrode structure. Specifically, the p-sideohmic contact layer 16 has specific resistance lower than that of the p-typenitride semiconductor layer 14. As a result, a large portion of electric current is concentrated to a part A adjacent to the n-side electrode as indicated by the arrow. In other words, current crowding occurs. When the current crowding occurs, forward voltage is increased, light emitting efficiency of theactive layer 13 disposed opposite to the n-side electrode 19 a is decreased, and heat value of the part A where the electric current is concentrated is increased, whereby reliability of the nitride semiconductor light emitting diode is considerably deteriorated. - Therefore, the present invention has been made in view of the above problems, and it is an object of the present invention to provide a nitride semiconductor light emitting diode having an improved p-side electrode structure, thereby improving current diffusion effects and reflexibility.
- It is another object of the present invention to provide a method of manufacturing such a nitride semiconductor light emitting diode.
- In accordance with one aspect of the present invention, the above and other objects can be accomplished by the provision of a nitride semiconductor light emitting diode comprising: a light transmittance substrate that allows a nitride semiconductor to be grown thereon; an n-type nitride semiconductor layer formed on the light transmittance substrate; an active layer formed on the n-type nitride semiconductor layer; a p-type nitride semiconductor layer formed on the active layer; a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
- Preferably, difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers.
- The first and second nitride layers constituting the mesh-type DBR reflecting layer may be formed of materials satisfying the following formula: Al1-xGaxN (0≦x≦1). Preferably, the first nitride layer is made of AlGaN, and the second nitride layer is made of GaN.
- Preferably, the effective area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
- The ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof. In a specific embodiment of the present invention, the nitride semiconductor light emitting diode further comprises: a metal barrier layer formed on the surface of the ohmic contact layer. The metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
- In accordance with another aspect of the present invention, there is provided a method of manufacturing a nitride semiconductor light emitting diode, the method comprising the steps of: preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon; forming an n-type nitride semiconductor layer on the light transmittance substrate; forming an active layer on the n-type nitride semiconductor layer; forming a p-type nitride semiconductor layer on the active layer; alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
- Preferably, the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
- In a specific embodiment of the present invention, the step of forming the mesh-type DBR reflecting layer is carried out at a temperature of 500° C. to 700° C. to prevent occurrence of cracks.
- The term “a flip chip-type light emitting device” used in the present invention indicates a light emitting device having a light emitting diode mounted on a chip substrate in a flip chip structure, as shown in
FIG. 1 . - The above and other objects, features and other advantages of the present invention will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings, in which:
-
FIG. 1 is a side view, in section, showing a conventional flip chip-type nitride light emitting diode; -
FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductor light emitting diode according to a preferred embodiment of the present invention; -
FIG. 2B is a plan view of the flip chip-type nitride semiconductor light emitting diode according to the preferred embodiment of the present invention show inFIG. 2A ; and -
FIG. 3 is a side view, in section, showing a flip chip-type nitride light emitting diode according to another preferred embodiment of the present invention. - A detailed description of components of a nitride semiconductor light emitting diode according to the present invention will be given hereinafter.
- P-Type and N-Type Nitride Semiconductor Layers
- The p-type and n-type nitride semiconductor layers are single crystals each having the following formula: AlXInyGa(1-X-y)N (where, 0≦x≦1, 0≦y≦1, and (0≦x+y≦1), and are grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). The typical nitride semiconductor layers include GaN, AlGaN, and GaInN.
- The P-type nitride semiconductor layer may contain impurities, such as Mg, Zn, and Be. The n-type nitride semiconductor layer may contain impurities, such as Si, Ge, Se, Te, and C. Between the substrate and the nitride semiconductor layer is usually disposed a buffer layer for lattice matching. The common buffer layer may be a low-temperature core growth layer, such as AlN or GaN.
- Active Layer
- The active layer adopted in the present invention is a layer for emitting blue-green light (having a wavelength of approximately 350 to 550 nm). The active layer comprises an undoped nitride semiconductor layer having a single or multiple quantum well structure. The active layer may be grown by means of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE), as in the p-type and n-type nitride semiconductor layer.
- Mesh-Type DBR Reflecting Layer
- The present invention comprises a mesh-type DBR reflecting layer. The mesh-type DBR reflecting layer adopted in the present invention is composed of two kinds of nitride layers having different Al content, which are alternately stacked several times. Generally, a refractive index of the nitride may vary depending upon the Al content. For this reason, a DBR structure having high reflexibility may be formed. When the difference between the refractive index of one of the nitride layers and the refractive index of the other nitride layer, both of which constitute the mesh-type DBR reflecting layer, is great, the thickness of the layer may be decreased, and the number of times at which the layers are stacked is decreased. Consequently, the mesh-type DBR reflecting layer is preferably composed of two kinds of nitride layers having different Al content, difference of which is at least 30%. Generally, the mesh-type DBR reflecting layer is designed to obtain high reflexibility of 90% or more, preferably 95% or more, and more preferably 98% or more.
- The DBR reflecting layer of the present invention is formed in the shape of a mesh. Consequently, an ohmic contact layer, which will be formed in a subsequent process, contacts the p-type nitride semiconductor layer through a plurality of open regions arranged over the mesh-type DBE reflecting layer. The DBR reflecting layer, which is made of nitrides, has resistance higher than that of the ohmic contact layer. As a result, electric current flowing to the active layer through the ohmic contact layer is uniformly diffused by means of the mesh-type DBR reflecting layer. Consequently, current crowding is mitigated.
- Preferably, the mesh-type DBR reflecting layer is formed of a three component-based nitride satisfying the following formula: Al1-xGaxN (0≦x≦1) to easily adjust the Al content. More preferably, the mesh-type DBR reflecting layer is formed of a first nitride layer, such ah GaN, and a second nitride layer, such as Al1-xGaxN (0≦x≦1), which are alternately stacked several times.
- The nitride layers constituting the mesh-type DBR reflecting layer may be formed successively through the use of the same growth process as the p-type and n-type nitride semiconductor layers and the active layer, i.e., through the use of Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy (MBE), or Hydride Vapor Phase Epitaxy (HVPE). Subsequently, the nitride layers are selectively etched by means of a photolithographic process to obtain the desired mesh-type DBR reflecting layer.
- Ohmic Contact Layer
- As described above, the ohmic contact layer adopted in the present invention is formed on the mesh-type DBR reflecting layer and the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer. Electric current flowing to the active layer though the ohmic contact layer having high reflexibility is uniformly diffused over the entire surface of the p-type nitride semiconductor layer by means of the mesh-type DBR reflecting layer having high resistance. As a result, current crowding is mitigated.
- It is required that the ohmic contact layer having high reflexibility be formed of high reflexibility sufficient to lower contact resistance between the p-type nitride semiconductor layer having a relatively high energy band gap.
- In order to decrease the contact resistance and to increase the reflexibility, the ohmic contact layer having high reflexibility may be formed of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof. Preferably, the ohmic contact layer has reflexibility of 70% or more. Specifically, the ohmic contact layer may be formed of Ni/Ag, Zn/Ag, Ni/Al, Zn/Al, Pd/Ag, Pd/Al, Ir/Ag, Ir/Au, Pt/Ag, Pt/Al, or Ni/Ag/Pt.
- The ohmic contact layer is formed by means of an ordinary deposition or sputtering process. The ohmic contact layer may be thermally treated at the temperature of approximately 400° C. to 900° C. to improve the characteristics of the ohmic contact layer.
- Metal Barrier Layer
- The metal barrier layer adopted in the present invention is formed at the ohmic contact layer having high reflexibility where a p-side bonding electrode is to be formed. The metal barrier layer is disposed at the interface between the bonding electrode material and the ohmic contact layer material for preventing deterioration of the characteristics (especially, reflexibility and contact resistance) of the ohmic contact layer. The metal barrier layer may be constructed in a single-layered structure or a multiple-layered structure. The metal barrier layer may be made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
- The metal barrier layer may extend to the sides of the ohmic contact layer having high reflexibility. In this case, it is possible to effectively prevent occurrence of current leakage due to migration of Ag when the ohmic contact layer having high reflexibility contains Ag.
- The metal barrier layer is formed by means of an ordinary deposition or sputtering process, as in the above-described electrodes. The metal barrier layer may be thermally treated at a temperature of approximately 300° C. for several tens of seconds or several minutes to improve adherence.
- P-Side Bonding Electrode and N-Side Electrode
- The p-side bonding electrode, which constitutes the p-side electrode structure together with the ohmic contact layer and the metal barrier layer, is an uppermost electrode layer to be mounted on a lead through a conductive bump in the flip chip structure. Generally, the p-side bonding electrode is made of Au or an alloy containing Au.
- The n-side electrode formed on the n-type nitride semiconductor layer may be constructed in a single-layered structure or a multiple-layered structure. The n-side electrode may be made of a material selected from the group consisting of Ti, Cr, Al, Cu, and Au.
- The electrodes are formed by means of an ordinary metal layer growth process, such as deposition or a sputtering process.
- Now, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
-
FIG. 2A is a side view, in section, showing a flip chip-type nitride semiconductorlight emitting diode 30 according to a preferred embodiment of the present invention, andFIG. 2B is a plan view of the flip chip-type nitride semiconductorlight emitting diode 30 according to the preferred embodiment of the present invention show inFIG. 2A . - Referring to
FIG. 2A , the flip chip-type nitride semiconductorlight emitting diode 30 comprises a nitridesemiconductor growth substrate 31, such as a sapphire substrate, an n-typenitride semiconductor layer 32 disposed on the nitridesemiconductor growth substrate 31, anactive layer 33 disposed on the n-typenitride semiconductor layer 32, and a p-typenitride semiconductor layer 34 disposed on theactive layer 33. - The nitride semiconductor
light emitting diode 30 has an n-side electrode 39 a formed on the upper surface of the n-typenitride semiconductor layer 32, which is exposed by means of mesa etching. A p-side electrode structure adopted in the nitride semiconductorlight emitting diode 30 includes a mesh-typeDBR reflecting layer 35, anohmic contact layer 36, and abonding electrode 39 b. Theohmic contact layer 36 is formed on the p-typenitride semiconductor layer 34. Theohmic contact layer 36 is constructed in a mesh structure having a plurality of open regions, by which the p-typenitride semiconductor layer 34 is partially exposed. Thebonding electrode 39 b is formed on the upper surface of theohmic contact layer 35. - The mesh-type
DBR reflecting layer 35 comprises first and second nitride layers 35 a and 35 b having different Al content, which are alternately stacked several times. Preferably, difference of the Al content between the first and second nitride layers 35 a and 35 b is at least 30% to sufficiently ensure difference between the refractive indices of the first and second nitride layers 35 a and 35 b. For example, the mesh-typeDBR reflecting layer 35 may be an AlGaN-based nitride layer. In a preferred embodiment of the present invention, thefirst nitride layer 35 a is GaN, and thesecond nitride layer 35 b is AlGaN. In this case, the mesh-typeDBR reflecting layer 35 has high reflexibility. Also, the mesh-typeDBR reflecting layer 35 maintains stable reflexibility at high temperature, unlike the ohmic contact material having high reflexibility, such as Ag or Al. Consequently, the total reflexibility is prevented from being deteriorated by the area of the mesh-typeDBR reflecting layer 35 even when the temperature is high. - The first and second nitride layers 35 a and 35 b are undoped crystal layers, although each of the first and second nitride layers 35 a and 35 b may be manufactured in the shape of an amorphous layer. In a specific embodiment of the present invention, it is necessary that one of the first and second nitride layers 35 a and 35 b have high content of Al to ensure sufficient refractive index. In the nitride having high Al content, however, a crack may occur at an ordinary crystal growth temperature (more than 1000° C.). Consequently, it is preferable to grow the mesh-type
DBR reflecting layer 35 at a temperature of 500° C. to 700° C. - As shown in
FIG. 3B , the mesh-typeDBR reflecting layer 35 has a plurality of open regions, which are arranged in the mesh structure. Theohmic contact layer 36 formed on the mesh-typeDBR reflecting layer 35 contacts the p-typenitride semiconductor layer 34 through the open regions of the mesh-typeDBR reflecting layer 35 to form ohmic contact. The mesh-typeDBR reflecting layer 35 has resistance higher than that of theohmic contact layer 36. Consequently, electric current flowing from the p-side bonding electrode 39 b to the n-side electrode 39 a through theohmic contact layer 36 is uniformly diffused by means of the mesh structure of the mesh-type DBR reflecting layer, as indicated by the arrow inFIG. 2A . - It is preferable to increase the effective area of the mesh-type DBR reflecting layer 35 (i.e., the area of the mesh-type
DBR reflecting layer 35 excluding the open regions of the mesh-type DBR reflecting layer 35), since brightness is increased by virtue of high reflexibility. It is necessary, however, that sufficient contact area be provided between the p-typenitride semiconductor layer 34 and theohmic contact layer 36. Preferably, the effective area of the mesh-typeDBR reflecting layer 35 is approximately 20% to 60% of the upper surface area of the p-typenitride semiconductor layer 34. - The mesh-type
DBR reflecting layer 35 adopted in the present invention is composed of a nitride layer, such as AlGaN. Consequently, the mesh-typeDBR reflecting layer 35 can be successively formed by means of the same growth process as the p-type and n-type nitride semiconductor layers 34 and 32 and theactive layer 33. For example, when the mesh-typeDBR reflecting layer 35 is composed of a first nitride layer 36 a, such as GaN, and a second nitride layer 36 b, such as AlGaN, the mesh-typeDBR reflecting layer 35 can be manufactured using trimethylgallium (TMG), trimethylaluminum (TMA), and ammonia (NH4) as a source gas under conditions similar to the single crystal growth process of the nitride in a MOCVD chamber where a single crystal growth process for a light emitting structure is carried out. As described above, the mesh-typeDBR reflecting layer 35 is not limited to the single crystal. When Al content of the mesh-typeDBR reflecting layer 35 is high, the mesh-typeDBR reflecting layer 35 is preferably manufactured in the shape of an amorphous layer, which is grown at low temperature. In this case, the mesh-typeDBR reflecting layer 35 can be grown at a temperature lower than the single crystal growing temperature, for example, 500° C. to 700° C. -
FIG. 3 is a side view, in section, showing a flip chip-typelight emitting device 60 according to another preferred embodiment of the present invention. - As shown in
FIG. 3 , the flip chip-typelight emitting device 60 comprises achip substrate 61 and a nitridelight emitting diode 50 disposed on thechip substrate 61. The nitride semiconductorlight emitting diode 50 comprises a nitridesemiconductor growth substrate 51, such as a sapphire substrate, an n-typenitride semiconductor layer 52 disposed on the nitridesemiconductor growth substrate 51, anactive layer 53 disposed on the n-typenitride semiconductor layer 52, and a p-typenitride semiconductor layer 54 disposed on theactive layer 53. The nitride semiconductorlight emitting diode 50 is mounted on thechip substrate 61 such that electrodes 69 a and 69 b are connected to lead 62 a and 62 b viapatterns 64 a and 64 b, respectively.conductive bumps - The nitride semiconductor
light emitting diode 50 has an n-side electrode 59 a formed on the upper surface of the n-typenitride semiconductor layer 52, which is exposed by means of mesa etching. A p-side electrode structure adopted in the nitride semiconductorlight emitting diode 50 includes a mesh-typeDBR reflecting layer 55, anohmic contact layer 56, and abonding electrode 59 b, which are similar to those shown inFIG. 2A . In addition, ametal barrier layer 57 is formed on the surface of theohmic contact layer 56 such that themetal barrier layer 57 surrounds both sides of theohmic contact layer 56. Themetal barrier layer 57 serves to prevent immigration of the material of theohmic contact layer 56, such as Al, and mixture of Au component at the interface between the p-side bonding electrode 59 b and theohmic contact layer 56. - As described above, the
sapphire substrate 51 of thelight emitting diode 50 in the flip chip-type light emitting device is a light transmittance substrate. Consequently, thesapphire substrate 51 serves as a light emitting surface of the flip chip-typelight emitting device 60. In this structure, the mesh-typeDBR reflecting layer 55 and theohmic contact layer 56 serve as reflecting layers at the opposite side so that the amount of the emitted light can be increased. Especially, the mesh-typeDBR reflecting layer 55 has high reflexibility of 90% or more. Also, the mesh-typeDBR reflecting layer 55 maintains stable reflexibility at high temperature. Consequently, reflecting performance of the mesh-typeDBR reflecting layer 55 is improved. Moreover, the mesh-typeDBR reflecting layer 55 diffuses electric current provided though theohmic contact layer 56, whereby current crowding is mitigated. - As apparent from the above description, the present invention provides a nitride semiconductor light emitting diode having an improved p-side electrode structure where a mesh-type DBR reflecting layer is composed of two kinds of nitride layers having different Al content to decrease electric current concentrated to the region adjacent to an n-side electrode. Consequently, the present invention has the effect of mitigating current crowding and increasing reflexibility, and therefore improving overall light emitting efficiency.
- Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.
Claims (19)
1. A nitride semiconductor light emitting diode comprising:
a light transmittance substrate that allows a nitride semiconductor to be grown thereon;
an n-type nitride semiconductor layer formed on the light transmittance substrate;
an active layer formed on the n-type nitride semiconductor layer;
a p-type nitride semiconductor layer formed on the active layer;
a mesh-type DBR reflecting layer formed on the p-type nitride semiconductor layer, the mesh-type DBR reflecting layer having a plurality of open regions, the mesh-type DBR reflecting layer being composed of first and second nitride layers having different Al content, the first and second nitride layers being alternately stacked several times to form the mesh-type DBR reflecting layer; and
an ohmic contact layer formed on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
2. The diode as set forth in claim 1 , wherein difference of the Al content between the first and second nitride layers constituting the mesh-type DBR reflecting layer is at least 30%.
3. The diode as set forth in claim 1 , wherein the first and second nitride layers constituting the mesh-type DBR reflecting layer are formed of materials satisfying the following formula.
Al1-xGaxN (0≦x≦1)
4. The diode as set forth in claim 3 , wherein the first nitride layer is made of GaN, and the second nitride layer is made of AlGaN.
5. The diode as set forth in claim 1 , wherein the area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
6. The diode as set forth in claim 1 , wherein the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
7. The diode as set forth in claim 1 , further comprising a metal barrier layer formed on the surface of the ohmic contact layer.
8. The diode as set forth in claim 7 , wherein the metal barrier layer is made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
9. A flip chip-type light emitting device comprising the nitride semiconductor light emitting diode as set forth in claim 1 .
10. A method of manufacturing a nitride semiconductor. light emitting diode, the method comprising the steps of:
preparing a light transmittance substrate that allows a nitride semiconductor to be grown thereon;
forming an n-type nitride semiconductor layer on the light transmittance substrate;
forming an active layer on the n-type nitride semiconductor layer;
forming a p-type nitride semiconductor layer on the active layer;
alternately stacking first and second nitride layers having different Al content on the p-type nitride semiconductor layer several times to form a mesh-type DBR reflecting layer having a plurality of open regions; and
forming an ohmic contact layer on the mesh-type DBR reflecting layer and on the p-type nitride semiconductor layer exposed through the open regions of the mesh-type DBR reflecting layer.
11. The method as set forth in claim 10 , wherein the step of forming the mesh-type DBR reflecting layer comprises alternately stacking the first and second nitride layers having Al content different from each other by at least 30% several times.
12. The method as set forth in claim 10 , wherein the first and second nitride layers constituting the mesh-type DBR reflecting layer are formed of materials satisfying the following formula.
Al1-xGaxN (0≦x≦1)
13. The method as set forth in claim 10 , wherein the step of forming the mesh-type DBR reflecting layer comprises alternately stacking the first nitride layers made of AlGaN and the second nitride layers made of GaN several times.
14. The method as set forth in claim 10 , wherein the area of the mesh-type DBR reflecting layer is approximately 20% to 60% of the upper surface area of the p-type nitride semiconductor layer.
15. The method as set forth in claim 10 , wherein the step of forming the n-type nitride semiconductor layer, the step of forming the active layer, the step of forming the p-type nitride semiconductor layer, and the step of forming the mesh-type DBR reflecting layer are carried out successively in the same chamber.
16. The method as set forth in claim 10 , wherein the step of forming the mesh-type DBR, reflecting layer is carried out at a temperature of 500° C. to 700° C.
17. The method as set forth in claim 10 , wherein the ohmic contact layer comprises at least one layer made of a material selected from the group consisting of Ag, Ni, Al, Ph, Pd, Ir, Ru, Mg, Zn, Pt, Au, and composites thereof.
18. The method as set forth in claim 10 , further comprising the step of:
forming a metal barrier layer on the surface of the ohmic contact layer.
19. The method as set forth in claim 18 , wherein the metal barrier layer comprises at least one layer made of a material selected from the group consisting of Ni, Al, Cu, Cr, Ti, and composites thereof.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6486044B2 (en) * | 1999-10-29 | 2002-11-26 | Ohio University | Band gap engineering of amorphous Al-Ga-N alloys |
| US20050247950A1 (en) * | 2004-05-06 | 2005-11-10 | Cree, Inc. | Lift-off process for GaN films formed on SiC substrates and devices fabricated using the method |
| US20060208273A1 (en) * | 2003-08-08 | 2006-09-21 | Sang-Kyu Kang | Nitride micro light emitting diode with high brightness and method of manufacturing the same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4486044A (en) * | 1982-08-06 | 1984-12-04 | Tank-Tote Co. | Apparatus for supporting and transporting a gas cylinder |
| JP2000091701A (en) | 1998-09-04 | 2000-03-31 | Hewlett Packard Co <Hp> | Reflection mirror, semiconductor laser, formation of reflection mirror, and manufacture of semiconductor laser |
| US6573537B1 (en) | 1999-12-22 | 2003-06-03 | Lumileds Lighting, U.S., Llc | Highly reflective ohmic contacts to III-nitride flip-chip LEDs |
| JP4239508B2 (en) | 2002-08-01 | 2009-03-18 | 日亜化学工業株式会社 | Light emitting element |
| TW586246B (en) * | 2002-10-28 | 2004-05-01 | Super Nova Optoelectronics Cor | Manufacturing method of white light LED and the light-emitting device thereof |
| US7332365B2 (en) * | 2004-05-18 | 2008-02-19 | Cree, Inc. | Method for fabricating group-III nitride devices and devices fabricated using method |
-
2004
- 2004-08-11 KR KR1020040063214A patent/KR100576870B1/en not_active Expired - Fee Related
-
2005
- 2005-02-25 US US11/064,968 patent/US20060033113A1/en not_active Abandoned
- 2005-02-28 JP JP2005053462A patent/JP2006054420A/en active Pending
-
2007
- 2007-11-01 US US11/933,950 patent/US7648849B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6486044B2 (en) * | 1999-10-29 | 2002-11-26 | Ohio University | Band gap engineering of amorphous Al-Ga-N alloys |
| US20060208273A1 (en) * | 2003-08-08 | 2006-09-21 | Sang-Kyu Kang | Nitride micro light emitting diode with high brightness and method of manufacturing the same |
| US20050247950A1 (en) * | 2004-05-06 | 2005-11-10 | Cree, Inc. | Lift-off process for GaN films formed on SiC substrates and devices fabricated using the method |
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| US9356190B2 (en) * | 2012-06-21 | 2016-05-31 | Xiamen Sanan Optoelectronics Technology Co., Ltd. | GaN-based LED |
| EP2750207A3 (en) * | 2012-12-12 | 2015-12-09 | Seoul Viosys Co., Ltd. | Light-emitting diode and method of fabricating the same |
| EP2743997A3 (en) * | 2012-12-12 | 2015-12-09 | Seoul Viosys Co., Ltd. | Light-emitting diode and method of fabricating the same |
| US9401456B2 (en) * | 2012-12-14 | 2016-07-26 | Seoul Viosys Co., Ltd. | Light-emitting diode with improved light extraction efficiency |
| US9978910B2 (en) * | 2012-12-14 | 2018-05-22 | Seoul Viosys Co., Ltd. | Light-emitting diode with improved light extraction efficiency |
| US20150280074A1 (en) * | 2012-12-14 | 2015-10-01 | Seoul Viosys Co., Ltd. | Light-emitting diode with improved light extraction efficiency |
| US10243109B2 (en) | 2012-12-14 | 2019-03-26 | Seoul Viosys Co., Ltd. | Light-emitting diode with improved light extraction efficiency |
| US20170077355A1 (en) * | 2012-12-14 | 2017-03-16 | Seoul Viosys Co., Ltd. | Light-emitting diode with improved light extraction efficiency |
| TWI596801B (en) * | 2012-12-14 | 2017-08-21 | 首爾偉傲世有限公司 | Enhancing the light extraction efficiency of the light-emitting diode by using a reflective layer |
| US9425359B2 (en) | 2013-02-04 | 2016-08-23 | Industrial Technology Research Institute | Light emitting diode |
| US20140231851A1 (en) * | 2013-02-04 | 2014-08-21 | Industrial Technology Research Institute | Light emitting diode |
| US9548424B2 (en) | 2013-02-04 | 2017-01-17 | Industrial Technology Research Institute | Light emitting diode |
| US9391239B2 (en) * | 2013-02-04 | 2016-07-12 | Industrial Technology Research Institute | Light emitting diode |
| US20160099385A1 (en) * | 2013-04-22 | 2016-04-07 | Korea Polytechnic University Industry Academic Cooperation Foundation | Method for Manufacturing Vertical Type Light Emitting Diode, Vertical Type Light Emitting Diode, Method for Manufacturing Ultraviolet Ray Light Emitting Diode, and Ultraviolet Ray Light Emitting Diode |
| US10014442B2 (en) * | 2013-04-22 | 2018-07-03 | Korea Polytechnic University Industry Academic Cooperation Foundation | Method for manufacturing vertical type light emitting diode, vertical type light emitting diode, method for manufacturing ultraviolet ray light emitting diode, and ultraviolet ray light emitting diode |
| US10840400B2 (en) * | 2013-08-29 | 2020-11-17 | Taiwan Semiconductor Manufacturing Co., Ltd. | Photovoltaic device with back reflector |
| CN109638100A (en) * | 2013-08-29 | 2019-04-16 | 台湾积体电路制造股份有限公司 | Photovoltaic device with backside reflection body |
| US20150059850A1 (en) * | 2013-08-29 | 2015-03-05 | Tsmc Solar Ltd. | Photovoltaic device with back reflector |
| CN104576857A (en) * | 2013-10-15 | 2015-04-29 | 上海工程技术大学 | Flip LED chip structure with high reflection layer and manufacturing method of flip LED chip structure |
| CN104037295A (en) * | 2014-06-16 | 2014-09-10 | 江苏汉莱科技有限公司 | LED (Light-Emitting Diode) flip chip and manufacturing method thereof |
| CN104253184A (en) * | 2014-09-24 | 2014-12-31 | 山西飞虹微纳米光电科技有限公司 | Blue light LED (Light Emitting Diode) epitaxial structure with gradually-changed DBR (Distributed Bragg Reflector) layer |
| CN104409585A (en) * | 2014-11-28 | 2015-03-11 | 杭州士兰明芯科技有限公司 | Vertical LED structure and manufacturing method thereof |
| US20180226541A1 (en) * | 2015-08-24 | 2018-08-09 | Lg Innotek Co., Ltd. | Light emitting element |
| US10763394B2 (en) * | 2015-08-24 | 2020-09-01 | Lg Innotek Co., Ltd. | Light emitting element having excellent contact between semiconductor layer and electrode |
| US11018279B2 (en) | 2015-08-24 | 2021-05-25 | Lg Innotek Co., Ltd. | Light emitting element having excellent contact between semiconductor layer and electrode |
| CN105047785A (en) * | 2015-09-09 | 2015-11-11 | 厦门乾照光电股份有限公司 | Light emitting diode with micro optimal transmission system |
| CN111129237A (en) * | 2018-01-02 | 2020-05-08 | 首尔伟傲世有限公司 | Display device with light-emitting stacked structure |
| EP4107792A4 (en) * | 2020-03-20 | 2024-03-27 | Sensor Electronic Technology, Inc. | OPTOELECTRONIC DEVICE WITH REDUCED OPTICAL LOSS |
| US12100779B2 (en) | 2020-03-20 | 2024-09-24 | Sensor Electronic Technology, Inc. | Optoelectronic device with reduced optical loss |
| CN112542533A (en) * | 2020-12-01 | 2021-03-23 | 北京大学 | High-photoelectric-conversion-rate inverted-structure deep ultraviolet micro-LED and preparation method thereof |
| CN112951955A (en) * | 2021-01-26 | 2021-06-11 | 华灿光电(浙江)有限公司 | Ultraviolet light-emitting diode epitaxial wafer and preparation method thereof |
| CN113644180A (en) * | 2021-08-05 | 2021-11-12 | 厦门士兰明镓化合物半导体有限公司 | Flip-chip LED chip and preparation method thereof |
| CN114141925A (en) * | 2021-12-01 | 2022-03-04 | 厦门三安光电有限公司 | Light emitting diode |
| WO2024033375A1 (en) * | 2022-08-10 | 2024-02-15 | Ams-Osram International Gmbh | Optoelectronic semiconductor component with an epitaxially grown layer and method for producing the optoelectronic semiconductor component |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100576870B1 (en) | 2006-05-10 |
| JP2006054420A (en) | 2006-02-23 |
| US20080064133A1 (en) | 2008-03-13 |
| KR20060014608A (en) | 2006-02-16 |
| US7648849B2 (en) | 2010-01-19 |
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