US20050100402A1 - Block paving sand - Google Patents
Block paving sand Download PDFInfo
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- US20050100402A1 US20050100402A1 US11/001,484 US148404A US2005100402A1 US 20050100402 A1 US20050100402 A1 US 20050100402A1 US 148404 A US148404 A US 148404A US 2005100402 A1 US2005100402 A1 US 2005100402A1
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- United States
- Prior art keywords
- water soluble
- soluble polymer
- polymer
- weight
- construct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004576 sand Substances 0.000 title claims abstract description 29
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 35
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims description 71
- 239000000945 filler Substances 0.000 claims description 18
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 230000002363 herbicidal effect Effects 0.000 claims description 6
- 239000004009 herbicide Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 230000000855 fungicidal effect Effects 0.000 claims description 5
- 239000000417 fungicide Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 235000011087 fumaric acid Nutrition 0.000 claims description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 4
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 4
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims 7
- 239000002861 polymer material Substances 0.000 claims 1
- 230000003019 stabilising effect Effects 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 150000004760 silicates Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000001012 protector Effects 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/886—Powder spraying, e.g. wet or dry powder spraying, plasma spraying
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to an improved sand for use in block paving applications, clay paviors, slabs and any other products in relation to the laying of paths, driveways, forecourts, patios and the like, or to any similar application where stability is required.
- Embodiments of the invention may also find utility for filling gaps between sections of runways and in various other heavy duty civil engineering applications.
- cementitious material including a polymer component for use in laying paving slabs and the like.
- These cementitious materials may be used as a base layer or as a jointing compound, but are disadvantageous in that once set, it is extremely difficult to clean up spillages and splashes which can cause staining of the paving slabs and the like. This is because cementitious materials tend to set permanently and cannot thereafter be removed without chipping or other physical force. These materials are also messy and unpleasant to apply, being in a paste-like cementitious form that is wholly unsuited as a jointing compound for block paving and the like.
- a coloured asphaltic paving material is known from JP 61254701.
- This material comprises a resin emulsion, quartz sand pigment, silica asphalt emulsion, a thickening agent and a defoaming agent.
- This material is used in a manner similar to ordinary asphalt, being spread in fluid form onto a surface (e.g. a tennis court) and allowed to set. It is wholly unsuitable for use as a jointing compound for block paving, being messy to apply and requiring heating.
- a non-cementitious, non-asphaltic material for filling gaps between paving blocks or the like, the material comprising dried sand or silicates mixed with a water-soluble polymer.
- a method of stabilising paving blocks or the like comprising a plurality of blocks laid adjacent to each other with gaps therebetween, wherein the gaps are filled with a non-cementitious, non-asphaltic material comprising dried sand or silicates mixed with a water-soluble polymer, and wherein water is applied to the material near upper surfaces of the blocks.
- a material for filling gaps between paving blocks or the like each 106.5 kg of the material comprising: 100 kg kiln dried sand; 5 kg powdered vinyl acetate/versatate copolymer with kaolin filler and polyvinyl alcohol colloid protector; 0.5 kg herbicide/fungicide and 1 kg crystalline sodium silicate.
- paving blocks or the like in the context of the present application may encompass block paved roads or driveways or the like, clay paviors, slabs and any other products in relation to the laying of paths, driveways, forecourts (including petrol/gasoline station forecourts), patios, airport runways, roads and other civil engineering applications.
- the present invention is directed to a filler for use in block paving applications and the like, including a sand and a binder material, wherein the components for the material includes at least 3% by weight water-soluble polymer, and will generally include from 3% to 25% by weight water-soluble polymer. In a particularly preferred embodiment, the material includes from 4% to 10% by weight water-soluble polymer.
- the dried sand or silicates may be kiln dried, and the water-soluble polymer is preferably dispersed throughout the dried sand or silicates as a fine powdered or granulated formulation.
- a water-soluble polymer component in the material means that the application of water to the material once it has been filled into the gaps between adjacent blocks will tend to dissolve at least a part of the polymer component. The polymer solution will then tend to coat the sand or silicate particles, causing them to adhere to each other upon drying.
- the water-soluble polymer is preferably chosen so as to cause the material to set solid after being wetted and subsequently dried. Water may be applied by way of a hosepipe or the like, or by way of natural rainfall.
- the water-soluble polymer component advantageously comprises grains or particles coated with a solubilising agent which, upon contact with water, enhances the solubility of the polymer component in the water.
- the solubilising agent will tend gradually to be washed away from exposed regions of the material subject to repeated rainfall or wetting, the set polymer component in these regions will tend to be relatively insoluble and thus will remain relatively stable, becoming more and more so over time.
- a degree of elastomeric flexibility is retained so as to allow for thermal expansion and mechanical deformation due to heavy vehicles passing over the block paving, and any cracks or defects in the material once laid will tend to be self-healing upon subsequent rainfall or wetting.
- the polymer will only be dissolved in regions close to the tops of the gaps between adjacent blocks where water can penetrate, thereby causing the material to set solid only at and close to the tops of the gaps. This provides room for thermal expansion and contraction of the blocks below the surface of the block paving. Furthermore, as the top surface of the material is eroded through natural causes, further rainfall or the like will tend to cause newly-exposed areas of the material to harden, thereby extending the life of the block paving.
- the polymer is only partially soluble in water under conditions of normal rainfall or application of water through a hosepipe or the like, thereby helping to prevent the material from setting solid below the exposed surfaces.
- the material of embodiments of the present invention is non-cementitious (i.e. does not contain any cement or cement-like components), and non-asphaltic (i.e. does not contain asphalt or asphalt-like components).
- the material is preferably applied in a dry powdered or particulate form, and may thus easily be swept or otherwise applied into interstitial gaps in block paved surfaces or the like. Because the material does not set until water is applied and can safely be exposed to air or oxygen without setting, it is easy to store and handle. Furthermore, even once set, materials of embodiments of the present invention can be resolvated simply through the addition of water, allowing spillages and the like to be cleaned away with relative ease.
- Polymers suitable for use with the present invention include polyvinyl family polymers such as vinyl acetate polymer and vinyl acetate/versatate copolymer (for example that sold under the trade names of RHOXIMAT® PAV 33 or RHOXIMAT® PAV 43), styrene maleic anhydride, styrene butadiene copolymer (with an optional kaolin filler, for example as sold under the trade name of RHOXIMAT® PSB 150), hydroxymethyl cellulose, hydroxyethyl cellulose, 2-butenedioic acid polymer and methoxyethene polymer. It will be appreciated that other water-soluble polymers may be effective.
- the polymer component is preferably mixed in with the other components as a powdered or granulated formulation.
- the material of the present invention may include herbicide and/or fuingicide (for example ACTICIDE® EP powder), powdered silicates (for example sodium silicate) and/or one or more colorants or dyes.
- herbicide and/or fuingicide for example ACTICIDE® EP powder
- powdered silicates for example sodium silicate
- a particularly preferred formulation for the material of the present invention is made up in the following relative proportions: 100 kg kiln dried sand; 5 kg powdered vinyl acetate/versatate copolymer with kaolin filler and polyvinyl alcohol colloid protector; 0.5 kg herbicide/fungicide; 1 kg crystalline sodium silicate.
- the present invention is suitable not just for block paving applications, but for any application where blocks or slabs or the like are laid and require interstitial stabilisation.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Materials Engineering (AREA)
- Inert Electrodes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
An improved block paving sand comprising kiln dried sand mixed with a water-soluble polymer. The block paving sand is filled into gaps between blocks and then water is applied thereto. Upon contact with the water, the polymer coats the sand and then sets hard, thereby stabilising the block paving.
Description
- This application claims priority of UK patent application No 0126344.1, filed Nov. 2, 2001 and UK patent application No. 0219379.5, filed Aug. 20, 2002.
- Not Applicable
- Not Applicable
- 1. Field of the Invention
- The present invention relates to an improved sand for use in block paving applications, clay paviors, slabs and any other products in relation to the laying of paths, driveways, forecourts, patios and the like, or to any similar application where stability is required. Embodiments of the invention may also find utility for filling gaps between sections of runways and in various other heavy duty civil engineering applications.
- 2. General Background of the Invention
- When laying block paving, for example as part of a road or driveway, it is known to fill the gaps between adjacent blocks with kiln dried sand so as to provide structural stability to the blocks. However, ordinary kiln dried sand has the disadvantage that it tends to disperse and disappear from between the blocks, especially during wet and windy weather or when the road or driveway is being swept, leaving gaps between the blocks. These gaps eventually result in structural instability, since the blocks then become free to move with respect to each other. Furthermore, the block paved road or driveway becomes unsightly, and weeds may grow in the gaps between the blocks. Indeed, ordinary kiln dried sand allows weeds to grow between the blocks even when the gaps are filled with the sand.
- It is known to provide a polymeric sealant to block paved roads or driveways after laying, which can help to ameliorate these problems, but the application of sealant is time consuming and expensive.
- It is also known, for example from U.S. Pat. No. 5,244,304, JP2285103 and JP 10265251, to provide a cementitious material including a polymer component for use in laying paving slabs and the like. These cementitious materials may be used as a base layer or as a jointing compound, but are disadvantageous in that once set, it is extremely difficult to clean up spillages and splashes which can cause staining of the paving slabs and the like. This is because cementitious materials tend to set permanently and cannot thereafter be removed without chipping or other physical force. These materials are also messy and unpleasant to apply, being in a paste-like cementitious form that is wholly unsuited as a jointing compound for block paving and the like.
- Other jointing compounds known, for example, from DE 4421970, WO 00/50355 and WO 97/07303, use mixtures of liquid polybutadiene, a flow enhancer and dry particulate material such as sand, crushed glass or fine aggregate. These mixtures are advantageous in that they are relatively easy to handle and do not adhere to paving slabs or the like when spilled thereon. However, the mixtures are designed to set upon exposure to air or oxygen, which can make handling difficult and means that the mixtures require careful storage. Furthermore, flow enhancers generally contain environmentally-unfriendly organic solvents. It will be appreciated that polybutadiene is not a water-soluble polymer.
- Finally, a coloured asphaltic paving material is known from JP 61254701. This material comprises a resin emulsion, quartz sand pigment, silica asphalt emulsion, a thickening agent and a defoaming agent. This material is used in a manner similar to ordinary asphalt, being spread in fluid form onto a surface (e.g. a tennis court) and allowed to set. It is wholly unsuitable for use as a jointing compound for block paving, being messy to apply and requiring heating.
- According to a first aspect of the present invention, there is provided a non-cementitious, non-asphaltic material for filling gaps between paving blocks or the like, the material comprising dried sand or silicates mixed with a water-soluble polymer.
- According to a second aspect of the present invention, there is provided a method of stabilising paving blocks or the like comprising a plurality of blocks laid adjacent to each other with gaps therebetween, wherein the gaps are filled with a non-cementitious, non-asphaltic material comprising dried sand or silicates mixed with a water-soluble polymer, and wherein water is applied to the material near upper surfaces of the blocks.
- According to a third aspect of the present invention, there is provided a material for filling gaps between paving blocks or the like, each 106.5 kg of the material comprising: 100 kg kiln dried sand; 5 kg powdered vinyl acetate/versatate copolymer with kaolin filler and polyvinyl alcohol colloid protector; 0.5 kg herbicide/fungicide and 1 kg crystalline sodium silicate.
- There are no drawings submitted.
- For the avoidance of doubt, the expression “paving blocks or the like” in the context of the present application may encompass block paved roads or driveways or the like, clay paviors, slabs and any other products in relation to the laying of paths, driveways, forecourts (including petrol/gasoline station forecourts), patios, airport runways, roads and other civil engineering applications.
- Preferably, the present invention is directed to a filler for use in block paving applications and the like, including a sand and a binder material, wherein the components for the material includes at least 3% by weight water-soluble polymer, and will generally include from 3% to 25% by weight water-soluble polymer. In a particularly preferred embodiment, the material includes from 4% to 10% by weight water-soluble polymer.
- The dried sand or silicates may be kiln dried, and the water-soluble polymer is preferably dispersed throughout the dried sand or silicates as a fine powdered or granulated formulation.
- The provision of a water-soluble polymer component in the material means that the application of water to the material once it has been filled into the gaps between adjacent blocks will tend to dissolve at least a part of the polymer component. The polymer solution will then tend to coat the sand or silicate particles, causing them to adhere to each other upon drying. Indeed, the water-soluble polymer is preferably chosen so as to cause the material to set solid after being wetted and subsequently dried. Water may be applied by way of a hosepipe or the like, or by way of natural rainfall. The water-soluble polymer component advantageously comprises grains or particles coated with a solubilising agent which, upon contact with water, enhances the solubility of the polymer component in the water. Because the solubilising agent will tend gradually to be washed away from exposed regions of the material subject to repeated rainfall or wetting, the set polymer component in these regions will tend to be relatively insoluble and thus will remain relatively stable, becoming more and more so over time. However, a degree of elastomeric flexibility is retained so as to allow for thermal expansion and mechanical deformation due to heavy vehicles passing over the block paving, and any cracks or defects in the material once laid will tend to be self-healing upon subsequent rainfall or wetting.
- Generally, the polymer will only be dissolved in regions close to the tops of the gaps between adjacent blocks where water can penetrate, thereby causing the material to set solid only at and close to the tops of the gaps. This provides room for thermal expansion and contraction of the blocks below the surface of the block paving. Furthermore, as the top surface of the material is eroded through natural causes, further rainfall or the like will tend to cause newly-exposed areas of the material to harden, thereby extending the life of the block paving.
- It is preferred that the polymer is only partially soluble in water under conditions of normal rainfall or application of water through a hosepipe or the like, thereby helping to prevent the material from setting solid below the exposed surfaces.
- For the avoidance of doubt, it is emphasised that the material of embodiments of the present invention is non-cementitious (i.e. does not contain any cement or cement-like components), and non-asphaltic (i.e. does not contain asphalt or asphalt-like components). The material is preferably applied in a dry powdered or particulate form, and may thus easily be swept or otherwise applied into interstitial gaps in block paved surfaces or the like. Because the material does not set until water is applied and can safely be exposed to air or oxygen without setting, it is easy to store and handle. Furthermore, even once set, materials of embodiments of the present invention can be resolvated simply through the addition of water, allowing spillages and the like to be cleaned away with relative ease.
- Polymers suitable for use with the present invention include polyvinyl family polymers such as vinyl acetate polymer and vinyl acetate/versatate copolymer (for example that sold under the trade names of RHOXIMAT® PAV 33 or RHOXIMAT® PAV 43), styrene maleic anhydride, styrene butadiene copolymer (with an optional kaolin filler, for example as sold under the trade name of RHOXIMAT® PSB 150), hydroxymethyl cellulose, hydroxyethyl cellulose, 2-butenedioic acid polymer and methoxyethene polymer. It will be appreciated that other water-soluble polymers may be effective. The polymer component is preferably mixed in with the other components as a powdered or granulated formulation.
- In addition to dried sand or silicates and water-soluble polymer, the material of the present invention may include herbicide and/or fuingicide (for example ACTICIDE® EP powder), powdered silicates (for example sodium silicate) and/or one or more colorants or dyes.
- A particularly preferred formulation for the material of the present invention is made up in the following relative proportions: 100 kg kiln dried sand; 5 kg powdered vinyl acetate/versatate copolymer with kaolin filler and polyvinyl alcohol colloid protector; 0.5 kg herbicide/fungicide; 1 kg crystalline sodium silicate.
- It is to be noted that the present invention is suitable not just for block paving applications, but for any application where blocks or slabs or the like are laid and require interstitial stabilisation.
- The preferred features of the invention are applicable to all aspects of the invention and may be used in any possible combination.
- Throughout the description and claims of this specification, the words “comprise” and “contain” and variations of the words, for example “comprising” and “comprises”, mean “including but not limited to”, and are not intended to (and do not) exclude other components, integers, moieties, additives or steps.
Claims (38)
1-15. (canceled)
16. A construct of paving blocks comprising:
laying a course of paving blocks in a generally adjacent relation having space therebetween forming an upper surface;
filling the spaces with a filler material consisting essentially of a dry mixture of a water soluble polymer in an amount of about 3% by weight to about 25% by weight and the remainder is selected from a group comprising sand and silicate;
applying water to the filler material at or near the upper surface;
whereby the filler material at least partially polymerizes and binds the paving blocks in said construct.
17. The construct of claim 16 wherein said water soluble polymer is in an amount of about 4% by weight and about 10% by weight.
18. The construct of claim 17 wherein said water soluble polymer is in an amount of about 4% by weight and about 5% by weight.
19. The construct of claim 16 wherein the water soluble polymer is a polyvinyl family polymer.
20. The construct of claim 1 wherein the water soluble polymer is vinyl acetate polymer.
21. The construct of claim 20 wherein the vinyl acetate polymer is a vinyl acetate/versatate copolymer.
22. The construct of claim 16 wherein the water soluble polymer is selected from a group comprising: styrene maleic anhydride, hydroxymethyl cellulose, hydroxyethyl cellulose, 2-butenedioic acid polymer, methoxyethene polymer and styrene butadiene copolymer.
23. The construct of claim 16 wherein the filler material includes at least one of an additive selected from a group comprising a herbicide and a fungicide.
24. The construct of claim 16 wherein the filler material includes at least one of an additive selected from a group comprising powdered sodium silicate and crystalline sodium silicate.
25. The construct of claim 16 wherein the filler material includes a colorant.
26. The construct of claim 16 wherein the sand of the filler material is kiln dried sand.
27. The construct of claim 16 wherein the particles of the water soluble polymer material are coated with a solubilising agent.
28. A non-cementitious, non-asphaltic particulate dry material for filling spaces between a course of paving blocks consisting essentially of a dried sand mixed with a water soluble polymer and further comprising at least one of an additive selected from a group comprising powdered and crystalline silicate.
29. The material of claim 28 wherein said water soluble polymer is in an amount of about 3% by weight to about 25% by weight.
30. The material of claim 28 wherein said water soluble polymer is in an amount of about 4% by weight and about 10% by weight.
31. The material of claim 28 wherein said water soluble polymer is in an amount of about 4% by weight and about 5% by weight.
32. The material of claim 28 wherein the water soluble polymer is a polyvinyl family polymer.
33. The material of claim 28 the water soluble polymer is vinyl acetate polymer.
34. The material of claim 28 wherein the vinyl acetate polymer is a vinyl acetate/versatate copolymer.
35. The material of claim 28 wherein the water soluble polymer is selected from a group comprising: styrene maleic anhydride, hydroxymethyl cellulose, hydroxyethyl cellulose, 2-butenedioic acid polymer, methoxyethene polymer and styrene butadiene copolymer.
36. The material of claim 28 wherein the filler material includes at least one of an additive selected from a group comprising a herbicide and a fungicide.
37. The material of claim 28 wherein the silicate is sodium silicate.
38. The material of claim 28 wherein the filler material includes a colorant.
39. The material of claim 28 wherein the sand of the filler material is kiln dried sand.
40. The material of claim 28 wherein the particles of the water soluble polymer are coated with a solubilising agent.
41. A non-cementitious, non-asphaltic particulate dry material for filling spaces between a course of paving blocks comprising a particulate water soluble polymer in an amount of about 3% by weight to about 25% by weight, the particles of said particulate water soluble polymer being coated with a solubilising agent and the remainder of said material comprising sand.
42. The material of claim 41 wherein said water soluble polymer is in an amount of about 4% by weight and about 10% by weight.
43. The material of claim 41 wherein said water soluble polymer is in an amount of about 4% by weight and about 5% by weight.
44. The material of claim 41 wherein the water soluble polymer is a polyvinyl family polymer.
45. The material of claim 41 wherein the water soluble polymer is vinyl acetate polymer.
46. The material of claim 45 wherein the vinyl acetate polymer is a vinyl acetate/versatate copolymer.
47. The material of claim 41 wherein the water soluble polymer is selected from a group comprising: styrene maleic anhydride, hydroxymethyl cellulose, hydroxyethyl cellulose, 2-butenedioic acid polymer, methoxyethene polymer and styrene butadiene copolymer.
48. The material of claim 41 wherein the filler material includes at least one of an additive selected from a group comprising a herbicide and a fungicide.
49. The material of claim 40 wherein the filler material includes silicate as an additive.
50. The material of claim 49 wherein the silicate additive is selected from a group comprising powdered sodium silicate and crystalline sodium silicate.
51. The material of claim 41 wherein the filler material includes a colorant.
52. The material of claim 41 wherein the sand of the filler material is kiln dried sand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/001,484 US20050100402A1 (en) | 2001-11-02 | 2004-12-01 | Block paving sand |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0126344.1A GB0126344D0 (en) | 2001-11-02 | 2001-11-02 | Improved block paving sand |
| GB0126344.1 | 2001-11-02 | ||
| GB0219379A GB2381529B (en) | 2001-11-02 | 2002-08-20 | Improved block paving sand |
| GB0219379.5 | 2002-08-20 | ||
| US10/231,828 US6926990B2 (en) | 2002-08-29 | 2002-08-29 | Fuel cell having porous electrodes and method for forming same |
| US11/001,484 US20050100402A1 (en) | 2001-11-02 | 2004-12-01 | Block paving sand |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/231,828 Division US6926990B2 (en) | 2001-11-02 | 2002-08-29 | Fuel cell having porous electrodes and method for forming same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20050100402A1 true US20050100402A1 (en) | 2005-05-12 |
Family
ID=31976831
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/231,828 Expired - Fee Related US6926990B2 (en) | 2001-11-02 | 2002-08-29 | Fuel cell having porous electrodes and method for forming same |
| US11/001,484 Abandoned US20050100402A1 (en) | 2001-11-02 | 2004-12-01 | Block paving sand |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/231,828 Expired - Fee Related US6926990B2 (en) | 2001-11-02 | 2002-08-29 | Fuel cell having porous electrodes and method for forming same |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US6926990B2 (en) |
| CN (1) | CN100459249C (en) |
| AU (1) | AU2003262749A1 (en) |
| GB (1) | GB2408381B (en) |
| WO (1) | WO2004021468A2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100904203B1 (en) * | 2007-07-04 | 2009-06-23 | 한국과학기술연구원 | Method for producing electrode-electrolyte composite powder for fuel cell |
| US8765327B2 (en) * | 2010-07-12 | 2014-07-01 | 3M Innovative Properties Company | Fuel cell electrodes with conduction networks |
| US20190280307A1 (en) * | 2018-03-08 | 2019-09-12 | GM Global Technology Operations LLC | Composite electrode layer for polymer electrolyte fuel cell |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4031291A (en) | 1976-04-05 | 1977-06-21 | Malcolm A. Fullenwider | Hydrogen-oxidizing catalyst, and fuel cell electrode using same |
| US5843519A (en) * | 1994-10-17 | 1998-12-01 | Tanaka Kikinzoku Kogyo K.K. | Process for forming a catalyst layer on an electrode by spray-drying |
| JPH08227716A (en) * | 1995-02-22 | 1996-09-03 | Tanaka Kikinzoku Kogyo Kk | Raw material for electrode of polymer solid oxide fuel cell and method for producing the same |
| DE19509748C2 (en) | 1995-03-17 | 1997-01-23 | Deutsche Forsch Luft Raumfahrt | Process for producing a composite of electrode material, catalyst material and a solid electrolyte membrane |
| DE19509749C2 (en) | 1995-03-17 | 1997-01-23 | Deutsche Forsch Luft Raumfahrt | Process for producing a composite of electrode material, catalyst material and a solid electrolyte membrane |
| US6338809B1 (en) | 1997-02-24 | 2002-01-15 | Superior Micropowders Llc | Aerosol method and apparatus, particulate products, and electronic devices made therefrom |
| JP3564975B2 (en) * | 1997-10-23 | 2004-09-15 | トヨタ自動車株式会社 | Fuel cell electrode and method of manufacturing fuel cell electrode |
| CN1619868A (en) * | 1997-11-25 | 2005-05-25 | 日本电池株式会社 | Solid polymer electrolyte-catalyst composite electrode, electrode for fuel cell, and process for producing these electrodes |
| JP3869568B2 (en) | 1998-11-30 | 2007-01-17 | 本田技研工業株式会社 | Fuel cell electrode |
| JP2000182625A (en) | 1998-12-11 | 2000-06-30 | Toyota Motor Corp | Fuel cell electrode and method of manufacturing the same |
| US6399202B1 (en) | 1999-10-12 | 2002-06-04 | Cabot Corporation | Modified carbon products useful in gas diffusion electrodes |
-
2002
- 2002-08-29 US US10/231,828 patent/US6926990B2/en not_active Expired - Fee Related
-
2003
- 2003-08-20 AU AU2003262749A patent/AU2003262749A1/en not_active Abandoned
- 2003-08-20 WO PCT/US2003/026098 patent/WO2004021468A2/en not_active Ceased
- 2003-08-20 CN CNB038207184A patent/CN100459249C/en not_active Expired - Fee Related
- 2003-08-20 GB GB0505402A patent/GB2408381B/en not_active Expired - Fee Related
-
2004
- 2004-12-01 US US11/001,484 patent/US20050100402A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN100459249C (en) | 2009-02-04 |
| GB2408381A (en) | 2005-05-25 |
| US6926990B2 (en) | 2005-08-09 |
| AU2003262749A8 (en) | 2004-03-19 |
| WO2004021468A3 (en) | 2004-12-23 |
| CN1679187A (en) | 2005-10-05 |
| US20040043282A1 (en) | 2004-03-04 |
| AU2003262749A1 (en) | 2004-03-19 |
| WO2004021468A2 (en) | 2004-03-11 |
| GB0505402D0 (en) | 2005-04-20 |
| GB2408381B (en) | 2006-10-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |