US20040163712A1 - Mass flow controller and method of operation of mass flow controller - Google Patents
Mass flow controller and method of operation of mass flow controller Download PDFInfo
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- US20040163712A1 US20040163712A1 US10/786,520 US78652004A US2004163712A1 US 20040163712 A1 US20040163712 A1 US 20040163712A1 US 78652004 A US78652004 A US 78652004A US 2004163712 A1 US2004163712 A1 US 2004163712A1
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- orifice
- magnetic flux
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Classifications
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D7/00—Control of flow
- G05D7/06—Control of flow characterised by the use of electric means
- G05D7/0617—Control of flow characterised by the use of electric means specially adapted for fluid materials
- G05D7/0629—Control of flow characterised by the use of electric means specially adapted for fluid materials characterised by the type of regulator means
- G05D7/0635—Control of flow characterised by the use of electric means specially adapted for fluid materials characterised by the type of regulator means by action on throttling means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/0318—Processes
- Y10T137/0324—With control of flow by a condition or characteristic of a fluid
- Y10T137/0368—By speed of fluid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/7722—Line condition change responsive valves
- Y10T137/7758—Pilot or servo controlled
- Y10T137/7759—Responsive to change in rate of fluid flow
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/7722—Line condition change responsive valves
- Y10T137/7758—Pilot or servo controlled
- Y10T137/7761—Electrically actuated valve
Definitions
- the present invention relates to mass flow controllers.
- Mass flow controllers are known in the art for controlling the specific amount of flow of a fluid, necessary for a particular process, e.g., in semiconductor manufacturing processes, such as chemical vapor deposition or the like. Mass flow controllers are known to be capable of sensing the flow occurring through the controller and modifying or controlling that flow as necessary to achieve the required control of the mass of the fluid delivered to the particular process.
- Sensing the flow is a function of the type of fluid utilized and the physical effect used to sense the amount of flow.
- One typical type of physical effect to sense mass flow is to measure the temperature differential between the upstream and downstream heater/sensor coils exposed to the fluid flow.
- Other systems may use absolute and/or differential pressure changes, light-absorption, or the momentum change (e.g., paddle wheel) to measure the flow.
- Modifying or controlling the flow is typically made in response to the sensed flow as it relates to the desired flow by modifying a cross-sectional opening area available to the fluid for flowing.
- An orifice provides the variable cross sectional opening area for flow, where the flow control is dictated by the positioning and motion of a plunger/diaphragm or needle stem in the orifice in response to a flow control signal.
- the flow control signal is generated in response to the measurement of the flow sensor.
- a servo control section generates a control signal that drives the positioning of the plunger/diaphragm or needle stem, typically through the use of a solenoid type of driver.
- the solenoid driver has a ferromagnetic core surrounded by a coil.
- the plunger/diaphragm typically made of ferromagnetic material, is held close to the orifice by a spring.
- the energizing of the coil generates a magnetic field that pulls the plunger/diaphragm away from the orifice while the spring pulls it toward the orifice.
- the distance between the orifice and the plunger/diaphragm is dependent upon the relative strengths of the magnetic field and the spring.
- the proportional control valve by its nature is not an open and shut valve. The closer the needle stem or plunger/diaphragm is to the orifice, the more restricted the flow becomes, until the flow is shut off, and the more it is withdrawn the more the flow increases, until it no longer affects the amount of flow.
- the mass flow controller particularly when used in high precision semiconductor manufacturing processes and the like, is part of a tool that has limited space available for the flow controllers, particularly if there are multiple mass flow controllers that are positioned in the immediate area of the actual discharge of the fluid into the tool's process chamber.
- the present invention utilizes a closed loop magnetic flux path passing through the body of the controller in the direction of flow from its input to its output to magnetically operate a flexible plunger button valve assembly that is normally spring biased into the shut position.
- a current generated from a servo control section of a mass flow controller generates magnetic flux to pull the plunger valve assembly away from an orifice and allow more fluid to flow through.
- FIG. 1A shows a mass flow controller of the prior art
- FIG. 1B shows magnetic flux path through a mass flow controller of FIG. 1A
- FIG. 2 shows an exploded view of the mass flow controller of FIG. 1A
- FIG. 3A shows a mass flow controller according to one embodiment of the present invention
- FIG. 3B shows a bypass assembly of FIG. 3A according to one embodiment
- FIGS. 3 C- 3 G show various embodiments of a bypass assembly
- FIG. 3H shows magnetic flux path through a mass flow controller of FIG. 3A
- FIG. 4 shows an exploded view of the mass flow controller of FIG. 3A
- FIG. 5 shows a sectional view of the mass flow controller of FIG. 3A along sectional line A-A′;
- FIG. 6A shows a side view of the button assembly and orifice plate shown in FIGS. 3A and 4;
- FIG. 6B shows a side view of the button assembly and orifice plate according to another embodiment
- FIGS. 7A and 7B show different configurations of an orifice plate
- FIG. 7C shows a side view of an orifice plate and button plunger assembly
- FIG. 8 shows an exploded view of a mass flow controller according to another embodiment of the present invention.
- FIG. 9 shows magnetic flux path through a mass flow controller according to another embodiment of the present invention.
- FIG. 10 shows magnetic flux path through a mass flow controller according to yet another embodiment of the present invention.
- FIG. 11 shows a mass flow controller according to another embodiment of the present invention.
- FIG. 12 shows the mass flow controller of FIG. 11, rotated 90° about the vertical axis
- FIG. 13 shows the mass flow controller of FIG. 11 with securing screws
- FIG. 14 shows an exploded view of a portion of the mass flow controller of FIG. 11, rotated 90° about the axis perpendicular to the vertical axis;
- FIGS. 15 and 16 show a portion of the bypass assembly according to two embodiments of the present invention.
- FIG. 17 shows a plunger button assembly according to one embodiment
- FIG. 18 shows an orifice plate according to one embodiment
- FIG. 19 shows the magnetic flux path through the mass flow controller of FIGS. 11 and 12.
- FIG. 1A shows an assembled controller 10
- FIG. 2 shows an exploded view of parts of controller 10
- Mass flow controller 10 has three main sections: a sensor section 20 , a valve section 30 , and a mass controller block section 40 .
- a fluid input fitting 11 and a fluid output fitting 12 are sealed to respective input and output ends of block section 40 through metal O-rings 13 .
- other seals are also suitable, such as knife edge, O-ring, C-ring, and flat gasket, made of materials such as metal, polymer, and elastomer.
- a cover 14 enclosing sensor section 20 and valve section 30 is secured to input and output fittings 11 and 12 by screws 15 .
- FIG. 1A Gas or fluid enters input fitting 11 through an opening 16 in input fitting 11 .
- the flow of fluid through mass flow controller 10 is shown in the dark lines in FIG. 1A.
- Opening 16 opens into a bypass assembly 17 , which has an input plenum 18 and an output plenum 19 , and which is located within block section 40 .
- Sensor section 20 is secured to block section 40 via appropriate seals 22 . While a majority of the fluid passes along bypass assembly 17 , a portion of the fluid travels through sensor section 20 along a sensor tube 23 .
- Bypass assembly 17 restricts the flow of fluid along one of a plurality of channels or grooves formed in the generally cylindrical outer surface of bypass assembly 17 and into output plenum 19 .
- this is for the purpose of generating a laminar flow such that a portion of the fluid passing from input plenum 18 into a sensor bypass line 21 and into sensor portion 20 is linearly proportional to the fluid passing from input plenum 18 to output plenum 19 through the plurality of channels or grooves in bypass assembly 17 .
- Sensor section 20 typically includes multiple coils 24 wrapped around sensor tube 23 .
- thermal energy is transferred from the coils to the flowing fluid.
- the amount of thermal energy transferred from the coils to the fluid is inversely proportional to the fluid temperature.
- Thermal energy transfer from the upstream coil and the downstream coil to the fluid is disproportionate because the fluid temperature is different at the upstream coil than at the downstream coil.
- This difference in heat transfer from the upstream coil and the downstream coil results in a temperature differential between the coils which manifests as a change in the relative resistance of the two coils. This change in resistance is directly proportional to the amount of fluid flowing through sensor tube 23 .
- a resistor circuit (not shown), which is coupled to the upstream and downstream coils, is configured to form a balanced bridge network when there is no fluid flow.
- the bridge network measures the change of the resistance in the coils and generates a signal corresponding to the flow of fluid through sensor tube 23 .
- Valve section 30 includes an upper housing 31 enclosing a wound coil assembly 32 of a solenoid valve, which consists of a pole assembly or plug 33 .
- Pole assembly 33 has a lower housing 34 , which together with upper housing 31 , are secured to block section 40 and sealed with an O-ring 35 or other appropriate seal.
- a plunger button assembly 37 having a flat sealing surface 46 , is held in a cavity in lower housing 34 of pole assembly 33 by a plunger button capture ring 36 .
- Plunger button capture ring 36 , plunger button assembly 37 , and a plunger button assembly pre-tensioning ring 38 are in abutting relation to an orifice plate 39 , which is sealed to block portion 40 by an O-ring 41 or other appropriate seal.
- Orifice plate 39 has an opening 42 into which fluid flows from fluid flow path 25 , where the flow of the fluid is controlled by the position of the plunger button assembly 37 , relative to orifice opening 42 .
- the relative position of plunger button assembly 37 is controlled by magnetic flux generated in core 33 in response to the signal generated from sensor block 20 .
- Coil 32 is held in place by a top cap 43 and a pole nut 44 .
- Top cap 43 is sealed with an O-ring 45 .
- FIG. 1B shows the magnetic flux path of controller 10 . As seen from FIG. 1B, the magnetic flux only travels through valve section 30 to control the position of plunger button assembly 37 , and not through either sensor section 20 , bypass assembly 17 , or block 40 .
- FIG. 3A shows an assembled controller 300
- FIG. 4 shows an exploded view of parts of controller 300
- Mass flow controller 300 includes an input fitting 311 attached to an input magnetic flux plate 312 , typically made of ferromagnetic material, where both input fitting 311 and input magnetic flux plate 312 have an opening 313 through which fluid enters and an output fitting 314 attached to an output magnetic flux plate 315 , typically made of ferromagnetic material, where both output fitting 314 and output magnetic flux plate 315 have an opening 316 through which fluid exits.
- a mass controller block 320 is sealed between input magnetic flux plate 312 and output magnetic flux plate 315 by O-rings 321 or other appropriate seals, which can be metal, plated metal, polymeric, or elastomeric material.
- bypass assembly 317 can be a single part with longitudinal grooves or channels 350 formed directly thereon, or in other embodiments, bypass assembly can be formed from more than one part, as shown in FIG. 3B.
- bypass assembly 317 can be formed from an inner core 355 and an outer sleeve 360 having grooves 350 formed along the outer perimeter.
- Inner core 355 can be of a ferromagnetic material, while outer sleeve 360 can be of a non-magnetic material.
- inner core 355 is made of a non-magnetic material, and outer sleeve 360 is made of a ferromagnetic material.
- FIGS. 3 C- 3 G Other embodiments of bypass assembly 317 are shown in FIGS. 3 C- 3 G.
- a bypass assembly 317 includes a ferromagnetic core and pathways along the longitudinal direction of the bypass assembly that allow fluid to flow from one end of the assembly to the other.
- ferromagnetic core 355 is surrounded by concentric tubes 361 held in place by ribs 362 . Fluid flows along channels created by concentric tubes 361 and ribs 363 .
- FIG. 3D ferromagnetic core 355 is surrounded by longitudinal tubes 363 in one or more layers, enclosed by a non-magnetic body 364 . Fluid flows through tubes 363 .
- FIG. 3C ferromagnetic core 355 is surrounded by concentric tubes 361 held in place by ribs 362 . Fluid flows along channels created by concentric tubes 361 and ribs 363 .
- FIG. 3D ferromagnetic core 355 is surrounded by longitudinal tubes 363 in one or more layers, enclosed by a
- ferromagnetic core 355 is surrounded by one or more laminated sheets 365 having channels 366 , which can be formed by laminating a channeled sheet 367 to a flat sheet 368 . Laminated sheet 365 is then wound around ferromagnetic core 355 . Additional sheets can be wound around an inner sheet to provide multiple channels through which fluid can flow.
- ferromagnetic core 355 is surrounded by a porous material 369 , which allows fluid to flow through.
- core 355 is made of a ferromagnetic porous (sintered) material.
- core 355 functions as the path for both the magnetic flux as well as the fluid flow through bypass assembly 317 .
- the fluid flows along longitudinal flow groves along the outer circumference of bypass assembly 317 . Fluid also flows through distribution holes 318 to a flow sensor input line 319 formed within block 320 . Input line 319 directs the flow to a sensor unit 322 , which is secured to block 320 by screws 323 and two O-rings 324 or other appropriate seals. One O-ring 324 seals the interface between sensor unit 322 and input line 319 of block 320 and second O-ring 324 seals the interface between sensor unit 322 and an output line 325 formed within block 320 .
- Fluid from output line 325 and bypass assembly 317 travels through a plunger button assembly capture spacer 326 , typically made of ferromagnetic material, a plunger button assembly 327 , (which includes a plunger made of ferromagnetic material, a spring, and a sealing surface), a plunger button pre-tension spacer 328 , an orifice plate 329 typically made of non-magnetic material, and an orifice metal O-ring 330 or other seal, and out through opening 316 in output fitting 314 .
- Plunger button assembly 327 and orifice plate 329 are shown in greater detail in FIG. 6A.
- Plunger button assembly capture spacer 326 secures plunger button assembly 327 , spacer 328 , orifice plate 329 , and O-ring 330 within a cavity in output magnetic flux plate 315 .
- mass flow controller 300 of the present invention includes a magnetic field generating unit 340 .
- Magnetic field generating unit 340 includes a coil 341 and a core 342 inserted into a cylindrical opening within coil 341 .
- Core 342 is a cylindrical plug, typically made of a ferromagnetic material, which is inserted into openings in the upper portion of input magnetic flux plate 312 and output magnetic flux plate 315 .
- Magnetic flux generated by unit 340 is directed down through input magnetic flux plate 312 , to bypass assembly 317 , to plunger button assembly 327 , and back up through output magnetic flux plate 315 .
- FIG. 3H shows the magnetic flux path of controller 300 . As seen in FIG.
- the magnetic flux travels substantially with the fluid flow within the body of controller 300 , i.e., from input magnetic flux plate 312 and through bypass assembly 317 to output magnetic flux plate 315 . This is contrasted with the magnetic flux path of conventional controllers, such as shown in FIG. 1B.
- FIG. 5 is a sectional view of mass flow controller 300 along sectional line A-A′ of FIG. 3A.
- FIG. 5 shows that sensor unit 322 is rotated approximately 90° from the orientation of conventional mass flow controller 10 shown in FIGS. 1A and 2.
- Sensor unit 322 is a conventionally known and used thermal mass flow sensor. The majority of the fluid flows through bypass assembly 317 along flow grooves 350 formed longitudinally on the outer surface of bypass assembly 317 .
- Sensor tube 344 has wrapped around its outside a first heater/sensor coil 345 and a second heater/sensor coil 346 , which are connected to terminals 347 .
- first coil 345 Passing current through first coil 345 heats the fluid as it passes through sensor tube 344 in the vicinity of first coil 345 .
- Current is also passed through second coil 346 wrapped around sensor tube 344 in the downstream flow direction of the fluid, i.e., towards output line 325 .
- second coil 346 As the fluid passes second coil 346 , it gets hotter.
- the amount of heat transferred from coils 345 and 346 to the fluid is different because the fluid temperature is different at coils 345 and 346 . This in turn changes the relative resistance of coils 345 and 346 , which is measured as a voltage differential in an electrical bridge (i.e., a Wheatstone bridge).
- Controller unit 300 includes electronic circuitry, not shown, to calculate the mass flow based upon the sensed change in voltage.
- a servo control section of controller 300 then generates a current signal for magnetic field generating unit 340 , which in turn generates magnetic flux proportional to the signal to move plunger button assembly 327 to control the flow.
- the servo control system generates current through the coil to generate sufficient magnetic flux until the error signal is minimized or approximately zero.
- Such systems are conventional and known to those skilled in the art.
- FIG. 6A shows, in more detail, plunger button assembly 327 and orifice plate 329 according to one embodiment.
- Orifice plate 329 is generally flat on both faces, with the face toward button assembly 327 having a frusto-conical portion 600 .
- Frusto-conical portion 600 has an opening 610 extending through orifice plate 329 such that fluid can flow through orifice plate 329 to opening 316 in output fitting 314 .
- Plunger button assembly 327 has a smooth flat sealing surface 620 that sits on to frusto-conical portion 600 .
- Plunger button assembly 327 also has openings 331 located outside sealing surface 620 for fluid to pass through.
- a spacer 328 shown in FIG.
- Spacer 328 is intended for the purpose of creating an appropriate amount of compression between plunger button assembly 327 and frusto-conical portion 600 by allowing a spring 625 in plunger button assembly 327 to bend to a desired extent by plunger button assembly capture spacer 326 .
- the thinner the spacer 328 the greater the bending of spring 625 in plunger button assembly 327 , consequently creating greater compression between plunger button assembly 327 and frusto-conical portion 600 .
- the amount of fluid flowing into opening 610 depends on the positioning of plunger button assembly 327 in relation to orifice plate 329 .
- plunger button assembly 327 As the attractive force to plunger button assembly 327 , which is created by the magnetic flux, increases, plunger button assembly 327 is moved away from orifice plate 329 , thereby increasing the amount of fluid flowing into opening 610 .
- the spring pushes button assembly 327 towards orifice plate 329 , thereby decreasing the fluid flow into opening 610 .
- the spring force of the spring should be as small as possible, yet sufficient to seal opening 610 to give a zero flow through opening 610 . Zero flow means less than 0.5% of the mass flow controller range.
- FIG. 6B shows another embodiment of plunger button assembly 327 in which a magnet 626 is attached to the side of plunger button assembly opposite sealing surface 620 .
- plunger button assembly 327 can be moved either away from or towards orifice plate 329 , thereby controlling the flow of fluid through orifice plate 329 .
- the magnetic flux creates a pole on the end of bypass assembly 317 that is opposite in polarity to magnet 626
- the attractive force between bypass assembly 317 and plunger button assembly 327 via magnet 626
- bypass assembly 317 will force plunger button assembly 327 into orifice plate 329 , which will shut off the fluid flow.
- a desired fluid flow can be obtained depending on the magnitude and direction of the flux and the strength of magnet 626 .
- opening 610 in orifice plate 329 is a central through hole.
- opening 610 can be an annular ring of slots 700 (shown in FIG. 7A) or holes 710 (shown in FIG. 7B), or a combination of both.
- the annular ring of holes or slots extend through protruded portions 720 of orifice plate 329 , shown in FIG. 7C.
- Plunger button assembly 327 has a central hole 730 or slots (not shown) and sealing surface 740 , which abuts against protruded portions 720 of orifice plate 329 .
- protruded portions 720 are sealed against sealing surface 740 , thereby preventing fluid from flowing through the holes or slots in orifice plate 329 .
- plunger button assembly 327 is pulled away from orifice plate 329 to allow fluid flow through orifice plate 329 .
- the size and number of slots 700 or holes 710 can be chosen to make the mass flow controller for a desired flow rate.
- the area of the slots (FIG. 7A) or holes (FIG. 7B) should be minimized to reduce the back pressure, resulting in less force required (less magnetic flux and therefore less current required) to move plunger button assembly 327 .
- this area must not be minimized to the extent that choking occurs when fluid is attempting to pass through orifice plate 329 . Choking can also occur in the peripheral area of the slots or holes. Therefore, the peripheral area of the slots or holes should be greater than or equal to the cross-sectional area of the slots or holes. Referring to FIGS.
- the peripheral area can be defined as the perimeter of the slots or holes times a displacement distance d.
- Distance d is the maximum distance between plunger button assembly 327 and the end of protruded portions 720 for a given flow rate, as shown in FIG. 7C.
- the peripheral area of the slots can be made equal to or greater than the cross-sectional area of the slots by either increasing the perimeter of the slots or increasing the distance d.
- Increasing distance d requires more magnetic force to achieve the desired flow rate.
- increasing the perimeter of the slots which can be done by increasing the length of the slots and decreasing the width of the slots, allows the peripheral area of the slots to be increased without changing the cross-sectional area of the slots. Consequently, the back pressure is not adversely increased or affected.
- the same effect cannot be realized by using holes instead of slots because increasing the perimeter or circumference of the holes also increases the cross-sectional area of the holes.
- FIG. 8 shows another embodiment of the present invention, in which bypass assembly 317 is made of a magneto-restrictive material, instead of a ferromagnetic material described above.
- the end of bypass assembly 317 facing output magnetic flux plate 315 is secured to a sealing device 800 having holes 805 for fluid to flow through and a sealing area 810 that abuts orifice plate 329 to prevent fluid from flowing through opening 610 in orifice plate 329 .
- sealing device 800 In the normal biased position, sealing device 800 abuts orifice plate 329 when sufficient magnetic flux is generated to seal opening 610 .
- Magnetic flux travels from input magnetic flux plate 312 toward output magnetic flux plate 315 through bypass assembly 317 and sealing device 800 .
- the magnetic flux travels through bypass assembly 317 .
- the magnetic flux path travels through the body of the mass flow controller.
- the magnetic flux path (shown as a solid black line) travels through core 342 , along input magnetic flux plate 312 , through mass controller block 320 , which in this embodiment is typically made of a ferromagnetic material, through plunger button assembly 327 and back up through output magnetic flux plate 315 .
- a magnetic flux separator plate or washer 910 is located between mass controller block 320 and output magnetic flux plate 315 so that the magnetic flux travels through plunger button assembly 327 to control the fluid flow through orifice plate 329 .
- coil 341 is wound around mass controller block 320 .
- Mass controller block 320 typically made of a ferromagnetic material, encloses bypass assembly 317 .
- An outer cover 100 typically made of a ferromagnetic material, encloses coil 341 and block 320 .
- magnetic flux separator plate or washer 910 separates mass controller block 320 from output magnetic flux plate 315 . Accordingly, as shown in FIG.
- the generated magnetic flux travels through block 320 to plunger button assembly 327 , up through output magnetic flux plate 315 , along outer cover 100 , and down through input magnetic flux plate 312 .
- fluid flows through sensor section 20 (FIGS. 1A and 1B) parallel to the flow of fluid through bypass assembly 317 .
- sensor unit 322 FIGGS. 3A and 5 that allows fluid to flow perpendicular to the flow of fluid through bypass assembly 317 .
- FIGS. 11 - 19 show an assembled mass flow controller 920 according to another embodiment of the present invention, with FIG. 14 showing an exploded view of parts of mass flow controller 920 , rotated 90° , from FIG. 11.
- mass flow controller 920 has three main sections: a controller block section 921 , a bypass/valve section 922 , and a sensor section 923 .
- Bypass/valve section 922 with a solenoid core 924 and a solenoid coil 925 are contained within block section 921 .
- a cover 926 encloses an electronic control printed circuit board (PCB) 927 and sensor section 923 .
- Mass flow controller 920 is attached and sealed-to a surface mount block, such as by screws 928 (FIG. 13) and fluid input/output seals 929 .
- fluid enters through an input port 930 and flows through a channel 931 into an input plenum 932 located within block 921 , which is typically made of a non-ferromagnetic material.
- the fluid is split, with a majority of the fluid flowing along longitudinal grooves/channels 933 (FIGS. 14 - 16 ) formed in the generally cylindrical outer surface of a bypass/valve body 934 , typically made from a ferromagnetic material.
- grooves/channels 933 can be formed directly on bypass/valve body 934 (FIG. 14), on a sleeve 935 (FIG.
- bypass/valve assembly 922 which includes bypass/valve body 934 , is attached to block 921 , such as by screws 936 (FIG. 13) and seals 937 and 967 (FIGS. 11 and 14).
- bypass/valve assembly 922 within block 921 , the fluid flows from fluid input port 930 to fluid input plenum 932 to an output plenum 938 .
- sensor section 923 is attached to bypass/valve assembly 922 , such as by screws 939 and seals 940 , and can be mounted in any 360° orientation substantially perpendicular to the flux path, as shown in FIG. 19.
- Sensor section 923 includes conventionally known and used thermal mass flow sensors. Referring to FIG. 12, the smaller portion of the split fluid flows through channel 941 located within bypass/valve body 934 into a sensor tube 942 and exits from sensor tube 942 into channel 943 located in bypass/valve body 934 and flows through channel 944 located within block 921 , finally meeting the major portion of the split fluid at the output end of the bypass/valve assembly 922 at output plenum 938 .
- Sensor tube 942 has wrapped around its outside a first heater/sensor coil 945 and connected to terminals 946 .
- first coil 945 Passing current through first coil 945 heats the fluid as it passes through sensor tube 942 in the vicinity of first coil 945 .
- Current is also passed through a second coil 947 wrapped around sensor tube 942 in the downstream flow direction of the fluid, i.e., towards channel 943 .
- second coil 947 As the fluid passes second coil 947 , it gets hotter.
- the amount of heat transferred from coils 945 and 947 to the fluid is different because the fluid temperature is different at coils 945 and 947 .
- This voltage differential corresponds to the mass flow amount of fluid passing through sensor tube 942 , and proportionally through bypass/valve assembly 922 .
- Mass flow controller 920 includes electronic control PCB 927 to calculate the mass flow based upon the sensed change in voltage.
- Bypass/valve assembly 922 contains core 924 , typically made from a ferromagnetic material, surrounded by solenoid coil 925 .
- core 924 typically made from a ferromagnetic material, surrounded by solenoid coil 925 .
- One end of core 924 is in intimate contact with a valve pole 948 , typically made from a ferromagnetic material.
- the other end of core 924 is in intimate contact with a solenoid cap 949 , typically made from a ferromagnetic material.
- Cap 949 is in intimate contact with bypass/valve body 934 .
- Valve pole 948 is separated from bypass/valve body 934 by a flux isolation ring 950 , typically made from a non-ferromagnetic material.
- An electronic servo control section on PCB 927 generates a current signal (depending upon the actual flow and the desired flow) for solenoid coil 925 , which in turn generates magnetic flux proportional to the signal to move a plunger button assembly 951 (shown in greater detail in FIG. 17) to control the flow, as discussed in more detail below.
- the servo control system generates current through coil 925 to generate sufficient magnetic flux until the error signal(difference between the desired flow and actual flow) is minimized or approximately zero.
- An orifice plate 952 is generally flat on both faces, with the face towards plunger button assembly 951 having a frusto-conical portion 953 .
- Frusto-conical portion 953 has an opening 954 extending through orifice plate 952 , such that fluid can flow through orifice plate 952 to a fluid output channel 955 into an output port 956 .
- Plunger button assembly 951 as shown in FIG. 17, has a smooth flat sealing surface 957 that sits on to frusto-conical portion 953 .
- a spring pretension spacer 958 is positioned between plunger button assembly 951 and orifice plate 952 , as shown in FIGS. 11 and 14.
- Spacer 958 is intended for the purpose of creating an appropriate amount of compression between plunger button assembly 951 and frusto-conical portion 953 by allowing a spring 959 in plunger button assembly 951 to bend to a desired extent by a plunger button capture spacer 960 .
- the thinner the spacer 958 the greater the bending of spring 959 in plunger button assembly 951 , consequently creating greater compression between plunger button assembly 951 and frusto-conical portion 953 .
- fluid flows through grooves/channels 961 (FIG. 18) formed into orifice plate 952 and into opening 954 .
- the amount of fluid flowing into opening 954 depends on the positioning of plunger button assembly 951 in relation to orifice plate 952 .
- plunger button assembly 951 As the attractive force to plunger button assembly 951 , which is created by the magnetic flux, increases, plunger button assembly 951 is moved away from orifice plate 952 , thereby increasing the amount of fluid flowing into opening 954 .
- spring 959 pushes plunger button assembly 951 towards orifice plate 952 , thereby decreasing the fluid flow into opening 954 .
- the regulated fluid from opening 954 then flows through a fluid output channel 955 and exits from output port 956 .
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Abstract
A mass flow controller has a sensor section that generates an electrical signal, dependent on the measured flow rate. The controller sends a control signal to a magnetic field generating unit, dependent upon the actual flow rate and the desired flow rate, which in response, generates a magnetic flux in the direction of the fluid input to the fluid output through the body of the controller. This means that the magnetic flux is concurrent with the fluid flow within the mass flow controller body. The magnetic flux alters the position of a plunger button assembly, located between the bypass chamber and the fluid output, relative to an orifice plate to control the flow rate to obtain the desired output flow. By incorporating the proportional control valve within the mass flow controller body, the need for a separate and large valve section is eliminated, reducing the size and cost of the controller.
Description
- This is a continuation-in-part application of commonly-owned U.S. patent application Ser. No. 09/517,391, filed Mar. 2, 2000.
- The present invention relates to mass flow controllers.
- Mass flow controllers are known in the art for controlling the specific amount of flow of a fluid, necessary for a particular process, e.g., in semiconductor manufacturing processes, such as chemical vapor deposition or the like. Mass flow controllers are known to be capable of sensing the flow occurring through the controller and modifying or controlling that flow as necessary to achieve the required control of the mass of the fluid delivered to the particular process.
- Sensing the flow is a function of the type of fluid utilized and the physical effect used to sense the amount of flow. One typical type of physical effect to sense mass flow is to measure the temperature differential between the upstream and downstream heater/sensor coils exposed to the fluid flow. Other systems may use absolute and/or differential pressure changes, light-absorption, or the momentum change (e.g., paddle wheel) to measure the flow.
- Modifying or controlling the flow is typically made in response to the sensed flow as it relates to the desired flow by modifying a cross-sectional opening area available to the fluid for flowing. The smaller the area available for flow, the smaller the mass flow, and vice-versa. In the past, this has been accomplished with a typical plunger/diaphragm/orifice system. An orifice provides the variable cross sectional opening area for flow, where the flow control is dictated by the positioning and motion of a plunger/diaphragm or needle stem in the orifice in response to a flow control signal. The flow control signal is generated in response to the measurement of the flow sensor.
- A servo control section generates a control signal that drives the positioning of the plunger/diaphragm or needle stem, typically through the use of a solenoid type of driver. The solenoid driver has a ferromagnetic core surrounded by a coil. The plunger/diaphragm, typically made of ferromagnetic material, is held close to the orifice by a spring. The energizing of the coil generates a magnetic field that pulls the plunger/diaphragm away from the orifice while the spring pulls it toward the orifice. The distance between the orifice and the plunger/diaphragm is dependent upon the relative strengths of the magnetic field and the spring. The proportional control valve by its nature is not an open and shut valve. The closer the needle stem or plunger/diaphragm is to the orifice, the more restricted the flow becomes, until the flow is shut off, and the more it is withdrawn the more the flow increases, until it no longer affects the amount of flow.
- For precision control, complex and expensive controller circuitry is needed to control the positioning and movement of the needle stem or plunger/diaphragm as the flow is regulated. The valve parts themselves must be manufactured with high precision, and are therefore expensive. In addition, prior art proportional controlled solenoid valve mass flow controllers require the needle stem or plunger/diaphragm to be mounted at right angles to the fluid flow direction. Consequently, the orifice is also mounted at right angles to the fluid flow path, and the fluid has to change direction to go through the orifice, which generates turbulence in the fluid.
- Often the mass flow controller, particularly when used in high precision semiconductor manufacturing processes and the like, is part of a tool that has limited space available for the flow controllers, particularly if there are multiple mass flow controllers that are positioned in the immediate area of the actual discharge of the fluid into the tool's process chamber.
- There is a need in the art, therefore, for a mass flow controller that is simpler, less expensive, smaller, and easier to manufacture and control.
- The present invention, according to one embodiment, utilizes a closed loop magnetic flux path passing through the body of the controller in the direction of flow from its input to its output to magnetically operate a flexible plunger button valve assembly that is normally spring biased into the shut position. A current generated from a servo control section of a mass flow controller generates magnetic flux to pull the plunger valve assembly away from an orifice and allow more fluid to flow through. By controlling the amount of flux generated, and thereby the positioning of the button valve assembly relative to the orifice, the flow through the orifice can be controlled. Consequently, a large separate proportional control valve section is no longer necessary, which results in a more compact, less expensive and more reliable mass flow controller that is less costly to manufacture and has fewer components than the conventional mass flow controllers discussed above.
- The present invention will be more fully understood upon consideration of the detailed description below, taken together with the accompanying drawings.
- FIG. 1A shows a mass flow controller of the prior art;
- FIG. 1B shows magnetic flux path through a mass flow controller of FIG. 1A;
- FIG. 2 shows an exploded view of the mass flow controller of FIG. 1A;
- FIG. 3A shows a mass flow controller according to one embodiment of the present invention;
- FIG. 3B shows a bypass assembly of FIG. 3A according to one embodiment;
- FIGS. 3C-3G show various embodiments of a bypass assembly;
- FIG. 3H shows magnetic flux path through a mass flow controller of FIG. 3A;
- FIG. 4 shows an exploded view of the mass flow controller of FIG. 3A;
- FIG. 5 shows a sectional view of the mass flow controller of FIG. 3A along sectional line A-A′;
- FIG. 6A shows a side view of the button assembly and orifice plate shown in FIGS. 3A and 4;
- FIG. 6B shows a side view of the button assembly and orifice plate according to another embodiment;
- FIGS. 7A and 7B show different configurations of an orifice plate; and
- FIG. 7C shows a side view of an orifice plate and button plunger assembly;
- FIG. 8 shows an exploded view of a mass flow controller according to another embodiment of the present invention;
- FIG. 9 shows magnetic flux path through a mass flow controller according to another embodiment of the present invention;
- FIG. 10 shows magnetic flux path through a mass flow controller according to yet another embodiment of the present invention;
- FIG. 11 shows a mass flow controller according to another embodiment of the present invention;
- FIG. 12 shows the mass flow controller of FIG. 11, rotated 90° about the vertical axis;
- FIG. 13 shows the mass flow controller of FIG. 11 with securing screws;
- FIG. 14 shows an exploded view of a portion of the mass flow controller of FIG. 11, rotated 90° about the axis perpendicular to the vertical axis;
- FIGS. 15 and 16 show a portion of the bypass assembly according to two embodiments of the present invention;
- FIG. 17 shows a plunger button assembly according to one embodiment;
- FIG. 18 shows an orifice plate according to one embodiment; and
- FIG. 19 shows the magnetic flux path through the mass flow controller of FIGS. 11 and 12.
- Use of the same reference symbols in different figures indicates similar or identical items.
- FIGS. 1A and 2 show a conventional
mass flow controller 10. FIG. 1A shows an assembledcontroller 10, while FIG. 2 shows an exploded view of parts ofcontroller 10.Mass flow controller 10 has three main sections: asensor section 20, avalve section 30, and a masscontroller block section 40. A fluid input fitting 11 and a fluid output fitting 12 are sealed to respective input and output ends ofblock section 40 through metal O-rings 13. Note that other seals are also suitable, such as knife edge, O-ring, C-ring, and flat gasket, made of materials such as metal, polymer, and elastomer. Acover 14enclosing sensor section 20 andvalve section 30 is secured to input and 11 and 12 byoutput fittings screws 15. - Gas or fluid enters input fitting 11 through an
opening 16 in input fitting 11. The flow of fluid throughmass flow controller 10 is shown in the dark lines in FIG. 1A.Opening 16 opens into abypass assembly 17, which has aninput plenum 18 and anoutput plenum 19, and which is located withinblock section 40.Sensor section 20 is secured to blocksection 40 via appropriate seals 22. While a majority of the fluid passes alongbypass assembly 17, a portion of the fluid travels throughsensor section 20 along asensor tube 23.Bypass assembly 17 restricts the flow of fluid along one of a plurality of channels or grooves formed in the generally cylindrical outer surface ofbypass assembly 17 and intooutput plenum 19. As is known in the art, this is for the purpose of generating a laminar flow such that a portion of the fluid passing frominput plenum 18 into asensor bypass line 21 and intosensor portion 20 is linearly proportional to the fluid passing frominput plenum 18 tooutput plenum 19 through the plurality of channels or grooves inbypass assembly 17. -
Sensor section 20 typically includesmultiple coils 24 wrapped aroundsensor tube 23. When fluid flows insidesensor tube 23 from a heated upstream coil to a heated downstream coil that are electrically balanced, thermal energy is transferred from the coils to the flowing fluid. The amount of thermal energy transferred from the coils to the fluid is inversely proportional to the fluid temperature. Thermal energy transfer from the upstream coil and the downstream coil to the fluid is disproportionate because the fluid temperature is different at the upstream coil than at the downstream coil. This difference in heat transfer from the upstream coil and the downstream coil results in a temperature differential between the coils which manifests as a change in the relative resistance of the two coils. This change in resistance is directly proportional to the amount of fluid flowing throughsensor tube 23. Typically, a resistor circuit (not shown), which is coupled to the upstream and downstream coils, is configured to form a balanced bridge network when there is no fluid flow. When the fluid flows, the resistance in the coils changes. The bridge network measures the change of the resistance in the coils and generates a signal corresponding to the flow of fluid throughsensor tube 23. - Fluid from
bypass assembly 17 andsensor tube 23 converge and flow into afluid flow path 25. Fluid travels alongfluid flow path 25, throughvalve section 30, and out through anopening 26 inoutput fitting 12.Valve section 30 includes anupper housing 31 enclosing awound coil assembly 32 of a solenoid valve, which consists of a pole assembly or plug 33.Pole assembly 33 has alower housing 34, which together withupper housing 31, are secured to blocksection 40 and sealed with an O-ring 35 or other appropriate seal. Aplunger button assembly 37, having aflat sealing surface 46, is held in a cavity inlower housing 34 ofpole assembly 33 by a plungerbutton capture ring 36. Plungerbutton capture ring 36,plunger button assembly 37, and a plunger buttonassembly pre-tensioning ring 38 are in abutting relation to anorifice plate 39, which is sealed to blockportion 40 by an O-ring 41 or other appropriate seal. -
Orifice plate 39 has anopening 42 into which fluid flows fromfluid flow path 25, where the flow of the fluid is controlled by the position of theplunger button assembly 37, relative toorifice opening 42. The relative position ofplunger button assembly 37 is controlled by magnetic flux generated incore 33 in response to the signal generated fromsensor block 20.Coil 32 is held in place by atop cap 43 and apole nut 44.Top cap 43 is sealed with an O-ring 45. FIG. 1B shows the magnetic flux path ofcontroller 10. As seen from FIG. 1B, the magnetic flux only travels throughvalve section 30 to control the position ofplunger button assembly 37, and not through eithersensor section 20,bypass assembly 17, or block 40. - FIGS. 3A and 4 show a
mass flow controller 300 according to one embodiment of the present invention. FIG. 3A shows an assembledcontroller 300, while FIG. 4 shows an exploded view of parts ofcontroller 300.Mass flow controller 300 includes an input fitting 311 attached to an inputmagnetic flux plate 312, typically made of ferromagnetic material, where both input fitting 311 and inputmagnetic flux plate 312 have anopening 313 through which fluid enters and anoutput fitting 314 attached to an outputmagnetic flux plate 315, typically made of ferromagnetic material, where bothoutput fitting 314 and outputmagnetic flux plate 315 have anopening 316 through which fluid exits. Amass controller block 320, typically made of non-ferromagnetic material, is sealed between inputmagnetic flux plate 312 and outputmagnetic flux plate 315 by O-rings 321 or other appropriate seals, which can be metal, plated metal, polymeric, or elastomeric material. - Fluid flows through
opening 313 into abypass assembly 317, typically formed with a ferromagnetic material, via distribution holes 318.Bypass assembly 317 can be a single part with longitudinal grooves orchannels 350 formed directly thereon, or in other embodiments, bypass assembly can be formed from more than one part, as shown in FIG. 3B. For example,bypass assembly 317 can be formed from aninner core 355 and anouter sleeve 360 havinggrooves 350 formed along the outer perimeter.Inner core 355 can be of a ferromagnetic material, whileouter sleeve 360 can be of a non-magnetic material. In another embodiment,inner core 355 is made of a non-magnetic material, andouter sleeve 360 is made of a ferromagnetic material. - Other embodiments of
bypass assembly 317 are shown in FIGS. 3C-3G. In each of these embodiments, abypass assembly 317 includes a ferromagnetic core and pathways along the longitudinal direction of the bypass assembly that allow fluid to flow from one end of the assembly to the other. In FIG. 3C,ferromagnetic core 355 is surrounded byconcentric tubes 361 held in place byribs 362. Fluid flows along channels created byconcentric tubes 361 andribs 363. In FIG. 3D,ferromagnetic core 355 is surrounded bylongitudinal tubes 363 in one or more layers, enclosed by anon-magnetic body 364. Fluid flows throughtubes 363. In FIG. 3E,ferromagnetic core 355 is surrounded by one or morelaminated sheets 365 havingchannels 366, which can be formed by laminating a channeledsheet 367 to aflat sheet 368.Laminated sheet 365 is then wound aroundferromagnetic core 355. Additional sheets can be wound around an inner sheet to provide multiple channels through which fluid can flow. In FIG. 3F,ferromagnetic core 355 is surrounded by aporous material 369, which allows fluid to flow through. In FIG. 3G,core 355 is made of a ferromagnetic porous (sintered) material. Thus,core 355 functions as the path for both the magnetic flux as well as the fluid flow throughbypass assembly 317. - Going back to the embodiment of FIG. 3B, the fluid flows along longitudinal flow groves along the outer circumference of
bypass assembly 317. Fluid also flows throughdistribution holes 318 to a flowsensor input line 319 formed withinblock 320.Input line 319 directs the flow to asensor unit 322, which is secured to block 320 byscrews 323 and two O-rings 324 or other appropriate seals. One O-ring 324 seals the interface betweensensor unit 322 andinput line 319 ofblock 320 and second O-ring 324 seals the interface betweensensor unit 322 and anoutput line 325 formed withinblock 320. Fluid fromoutput line 325 andbypass assembly 317 travels through a plunger buttonassembly capture spacer 326, typically made of ferromagnetic material, aplunger button assembly 327, (which includes a plunger made of ferromagnetic material, a spring, and a sealing surface), a plungerbutton pre-tension spacer 328, anorifice plate 329 typically made of non-magnetic material, and an orifice metal O-ring 330 or other seal, and out throughopening 316 inoutput fitting 314.Plunger button assembly 327 andorifice plate 329 are shown in greater detail in FIG. 6A. Plunger buttonassembly capture spacer 326 securesplunger button assembly 327,spacer 328,orifice plate 329, and O-ring 330 within a cavity in outputmagnetic flux plate 315. - In addition,
mass flow controller 300 of the present invention includes a magneticfield generating unit 340. Magneticfield generating unit 340 includes acoil 341 and acore 342 inserted into a cylindrical opening withincoil 341.Core 342 is a cylindrical plug, typically made of a ferromagnetic material, which is inserted into openings in the upper portion of inputmagnetic flux plate 312 and outputmagnetic flux plate 315. Magnetic flux generated byunit 340 is directed down through inputmagnetic flux plate 312, to bypassassembly 317, toplunger button assembly 327, and back up through outputmagnetic flux plate 315. FIG. 3H shows the magnetic flux path ofcontroller 300. As seen in FIG. 3H, the magnetic flux travels substantially with the fluid flow within the body ofcontroller 300, i.e., from inputmagnetic flux plate 312 and throughbypass assembly 317 to outputmagnetic flux plate 315. This is contrasted with the magnetic flux path of conventional controllers, such as shown in FIG. 1B. - FIG. 5 is a sectional view of
mass flow controller 300 along sectional line A-A′ of FIG. 3A. FIG. 5 shows thatsensor unit 322 is rotated approximately 90° from the orientation of conventionalmass flow controller 10 shown in FIGS. 1A and 2. In other words, fluid flowing throughsensor unit 322 is orthogonal to the flow direction of the fluid throughbypass assembly 317 according to the present invention, whereas the flow directions are parallel with the controller shown in FIGS. 1A and 2.Sensor unit 322 is a conventionally known and used thermal mass flow sensor. The majority of the fluid flows throughbypass assembly 317 alongflow grooves 350 formed longitudinally on the outer surface ofbypass assembly 317. Some of the fluid flows fromdistribution holes 318 to flowsensor input line 319 and into aflow sensor tube 344.Sensor tube 344 has wrapped around its outside a first heater/sensor coil 345 and a second heater/sensor coil 346, which are connected toterminals 347. - Passing current through
first coil 345 heats the fluid as it passes throughsensor tube 344 in the vicinity offirst coil 345. Current is also passed throughsecond coil 346 wrapped aroundsensor tube 344 in the downstream flow direction of the fluid, i.e., towardsoutput line 325. As the fluid passessecond coil 346, it gets hotter. However, the amount of heat transferred from 345 and 346 to the fluid is different because the fluid temperature is different atcoils 345 and 346. This in turn changes the relative resistance ofcoils 345 and 346, which is measured as a voltage differential in an electrical bridge (i.e., a Wheatstone bridge). This voltage differential corresponds to the mass flow amount of fluid passing throughcoils sensor tube 344, and, proportionately, throughbypass assembly 317.Controller unit 300 includes electronic circuitry, not shown, to calculate the mass flow based upon the sensed change in voltage. A servo control section ofcontroller 300 then generates a current signal for magneticfield generating unit 340, which in turn generates magnetic flux proportional to the signal to moveplunger button assembly 327 to control the flow. The servo control system generates current through the coil to generate sufficient magnetic flux until the error signal is minimized or approximately zero. Such systems are conventional and known to those skilled in the art. - FIG. 6A shows, in more detail,
plunger button assembly 327 andorifice plate 329 according to one embodiment.Orifice plate 329 is generally flat on both faces, with the face towardbutton assembly 327 having a frusto-conical portion 600. Frusto-conical portion 600 has anopening 610 extending throughorifice plate 329 such that fluid can flow throughorifice plate 329 to opening 316 inoutput fitting 314.Plunger button assembly 327 has a smoothflat sealing surface 620 that sits on to frusto-conical portion 600.Plunger button assembly 327 also hasopenings 331 located outside sealingsurface 620 for fluid to pass through. A spacer 328 (shown in FIG. 4) is positioned betweenplunger button assembly 327 andorifice plate 329.Spacer 328 is intended for the purpose of creating an appropriate amount of compression betweenplunger button assembly 327 and frusto-conical portion 600 by allowing aspring 625 inplunger button assembly 327 to bend to a desired extent by plunger buttonassembly capture spacer 326. The thinner thespacer 328, the greater the bending ofspring 625 inplunger button assembly 327, consequently creating greater compression betweenplunger button assembly 327 and frusto-conical portion 600. - Fluid flows through
openings 331 around the outer edges ofsurface 620 as well as around the outer edges ofplunger button assembly 327 so that fluid can flow frombypass assembly 317 to opening 610 oforifice plate 329. The amount of fluid flowing intoopening 610 depends on the positioning ofplunger button assembly 327 in relation toorifice plate 329. As the attractive force toplunger button assembly 327, which is created by the magnetic flux, increases,plunger button assembly 327 is moved away fromorifice plate 329, thereby increasing the amount of fluid flowing intoopening 610. However, as the force decreases, the spring pushesbutton assembly 327 towardsorifice plate 329, thereby decreasing the fluid flow intoopening 610. The spring force of the spring should be as small as possible, yet sufficient to sealopening 610 to give a zero flow throughopening 610. Zero flow means less than 0.5% of the mass flow controller range. - FIG. 6B shows another embodiment of
plunger button assembly 327 in which amagnet 626 is attached to the side of plunger button assembly opposite sealingsurface 620. By changing the flux direction and magnitude throughbypass assembly 317,plunger button assembly 327 can be moved either away from or towardsorifice plate 329, thereby controlling the flow of fluid throughorifice plate 329. For example, if the magnetic flux creates a pole on the end ofbypass assembly 317 that is opposite in polarity tomagnet 626, the attractive force betweenbypass assembly 317 and plunger button assembly 327 (via magnet 626) will pullplunger button assembly 327 away fromorifice plate 329, which allows fluid to flow. If the magnetic flux creates a pole that is the same in polarity asmagnet 626,bypass assembly 317 will forceplunger button assembly 327 intoorifice plate 329, which will shut off the fluid flow. Thus, depending on the magnitude and direction of the flux and the strength ofmagnet 626, a desired fluid flow can be obtained. - In the above described embodiments, opening 610 in
orifice plate 329 is a central through hole. However, in other embodiments, opening 610 can be an annular ring of slots 700 (shown in FIG. 7A) or holes 710 (shown in FIG. 7B), or a combination of both. In these embodiments, the annular ring of holes or slots extend through protrudedportions 720 oforifice plate 329, shown in FIG. 7C.Plunger button assembly 327 has acentral hole 730 or slots (not shown) and sealingsurface 740, which abuts against protrudedportions 720 oforifice plate 329. Without any magnetic flux, protrudedportions 720 are sealed against sealingsurface 740, thereby preventing fluid from flowing through the holes or slots inorifice plate 329. When magnetic flux is generated,plunger button assembly 327 is pulled away fromorifice plate 329 to allow fluid flow throughorifice plate 329. Fluid flows throughhole 730 ofplunger button assembly 327 and holes orslots 750 on the outer edge of sealingsurface 740 as well as from the outer perimeter ofplunger button assembly 327 to the openings oforifice plate 329. - The size and number of
slots 700 orholes 710 can be chosen to make the mass flow controller for a desired flow rate. For a given flow rate, the area of the slots (FIG. 7A) or holes (FIG. 7B) should be minimized to reduce the back pressure, resulting in less force required (less magnetic flux and therefore less current required) to moveplunger button assembly 327. However, this area must not be minimized to the extent that choking occurs when fluid is attempting to pass throughorifice plate 329. Choking can also occur in the peripheral area of the slots or holes. Therefore, the peripheral area of the slots or holes should be greater than or equal to the cross-sectional area of the slots or holes. Referring to FIGS. 7A-7C, the peripheral area can be defined as the perimeter of the slots or holes times a displacement distance d. Distance d is the maximum distance betweenplunger button assembly 327 and the end of protrudedportions 720 for a given flow rate, as shown in FIG. 7C. - Therefore, for a given flow rate and cross-sectional area of
slots 700, the peripheral area of the slots can be made equal to or greater than the cross-sectional area of the slots by either increasing the perimeter of the slots or increasing the distance d. Increasing distance d requires more magnetic force to achieve the desired flow rate. On the other hand, increasing the perimeter of the slots, which can be done by increasing the length of the slots and decreasing the width of the slots, allows the peripheral area of the slots to be increased without changing the cross-sectional area of the slots. Consequently, the back pressure is not adversely increased or affected. However, the same effect cannot be realized by using holes instead of slots because increasing the perimeter or circumference of the holes also increases the cross-sectional area of the holes. - FIG. 8 shows another embodiment of the present invention, in which bypass
assembly 317 is made of a magneto-restrictive material, instead of a ferromagnetic material described above. The end ofbypass assembly 317 facing outputmagnetic flux plate 315 is secured to asealing device 800 havingholes 805 for fluid to flow through and asealing area 810 that abutsorifice plate 329 to prevent fluid from flowing throughopening 610 inorifice plate 329. In the normal biased position, sealingdevice 800 abutsorifice plate 329 when sufficient magnetic flux is generated to sealopening 610. Magnetic flux travels from inputmagnetic flux plate 312 toward outputmagnetic flux plate 315 throughbypass assembly 317 and sealingdevice 800. When the magnetic flux is reduced, the magneto-restrictive material constricts, which allows fluid to flow throughopening 610 inorifice plate 329. Then, when the magnetic flux is increased,bypass assembly 317 expands until sealingdevice 800 seals opening 610. This allowsplunger button assembly 327 and plunger buttonassembly pre-tension spacer 328 of FIG. 4 to be eliminated. - In the above described embodiments, the magnetic flux travels through
bypass assembly 317. In other embodiments, shown in FIGS. 9 and 10, the magnetic flux path travels through the body of the mass flow controller. In FIG. 9, the magnetic flux path (shown as a solid black line) travels throughcore 342, along inputmagnetic flux plate 312, throughmass controller block 320, which in this embodiment is typically made of a ferromagnetic material, throughplunger button assembly 327 and back up through outputmagnetic flux plate 315. A magnetic flux separator plate orwasher 910, typically made of a non-magnetic material, is located betweenmass controller block 320 and outputmagnetic flux plate 315 so that the magnetic flux travels throughplunger button assembly 327 to control the fluid flow throughorifice plate 329. In FIG. 10,coil 341 is wound aroundmass controller block 320.Mass controller block 320, typically made of a ferromagnetic material, enclosesbypass assembly 317. Anouter cover 100, typically made of a ferromagnetic material, enclosescoil 341 and block 320. Similar to FIG. 9, magnetic flux separator plate orwasher 910 separatesmass controller block 320 from outputmagnetic flux plate 315. Accordingly, as shown in FIG. 10, the generated magnetic flux (shown as a solid black line) travels throughblock 320 toplunger button assembly 327, up through outputmagnetic flux plate 315, alongouter cover 100, and down through inputmagnetic flux plate 312. Note that in the embodiments shown in FIGS. 9 and 10, fluid flows through sensor section 20 (FIGS. 1A and 1B) parallel to the flow of fluid throughbypass assembly 317. However, the embodiments shown in FIGS. 9 and 10 are also suitable with sensor unit 322 (FIGS. 3A and 5) that allows fluid to flow perpendicular to the flow of fluid throughbypass assembly 317. - FIGS. 11-19 show an assembled
mass flow controller 920 according to another embodiment of the present invention, with FIG. 14 showing an exploded view of parts ofmass flow controller 920, rotated 90° , from FIG. 11. Referring to FIGS. 11 and 14,mass flow controller 920 has three main sections: acontroller block section 921, a bypass/valve section 922, and asensor section 923. Bypass/valve section 922 with asolenoid core 924 and asolenoid coil 925 are contained withinblock section 921. Acover 926 encloses an electronic control printed circuit board (PCB) 927 andsensor section 923.Mass flow controller 920 is attached and sealed-to a surface mount block, such as by screws 928 (FIG. 13) and fluid input/output seals 929. - Referring to FIG. 11, fluid enters through an
input port 930 and flows through achannel 931 into aninput plenum 932 located withinblock 921, which is typically made of a non-ferromagnetic material. There, the fluid is split, with a majority of the fluid flowing along longitudinal grooves/channels 933 (FIGS. 14-16) formed in the generally cylindrical outer surface of a bypass/valve body 934, typically made from a ferromagnetic material. In various embodiments, grooves/channels 933 can be formed directly on bypass/valve body 934 (FIG. 14), on a sleeve 935 (FIG. 15), within a sleeve when the sleeve is a porous material that acts as grooves/channels 933, or on the inner surface of block 921 (FIG. 16). Bypass/valve assembly 922, which includes bypass/valve body 934, is attached to block 921, such as by screws 936 (FIG. 13) and seals 937 and 967 (FIGS. 11 and 14). Thus, in bypass/valve assembly 922 withinblock 921, the fluid flows fromfluid input port 930 tofluid input plenum 932 to anoutput plenum 938. - Referring to FIGS. 11-14 and 19,
sensor section 923 is attached to bypass/valve assembly 922, such as byscrews 939 and seals 940, and can be mounted in any 360° orientation substantially perpendicular to the flux path, as shown in FIG. 19.Sensor section 923 includes conventionally known and used thermal mass flow sensors. Referring to FIG. 12, the smaller portion of the split fluid flows throughchannel 941 located within bypass/valve body 934 into asensor tube 942 and exits fromsensor tube 942 intochannel 943 located in bypass/valve body 934 and flows throughchannel 944 located withinblock 921, finally meeting the major portion of the split fluid at the output end of the bypass/valve assembly 922 atoutput plenum 938.Sensor tube 942 has wrapped around its outside a first heater/sensor coil 945 and connected toterminals 946. - Passing current through
first coil 945 heats the fluid as it passes throughsensor tube 942 in the vicinity offirst coil 945. Current is also passed through asecond coil 947 wrapped aroundsensor tube 942 in the downstream flow direction of the fluid, i.e., towardschannel 943. As the fluid passessecond coil 947, it gets hotter. However, the amount of heat transferred from 945 and 947 to the fluid is different because the fluid temperature is different atcoils 945 and 947. This in turn changes the relative resistance ofcoils 945 and 947, which is measured as a voltage differential in an electrical bridge (e.g., a Wheatstone bridge). This voltage differential corresponds to the mass flow amount of fluid passing throughcoils sensor tube 942, and proportionally through bypass/valve assembly 922.Mass flow controller 920 includeselectronic control PCB 927 to calculate the mass flow based upon the sensed change in voltage. - Bypass/
valve assembly 922 containscore 924, typically made from a ferromagnetic material, surrounded bysolenoid coil 925. One end ofcore 924 is in intimate contact with avalve pole 948, typically made from a ferromagnetic material. The other end ofcore 924 is in intimate contact with asolenoid cap 949, typically made from a ferromagnetic material.Cap 949, in turn, is in intimate contact with bypass/valve body 934.Valve pole 948 is separated from bypass/valve body 934 by aflux isolation ring 950, typically made from a non-ferromagnetic material. - An electronic servo control section on
PCB 927 generates a current signal (depending upon the actual flow and the desired flow) forsolenoid coil 925, which in turn generates magnetic flux proportional to the signal to move a plunger button assembly 951 (shown in greater detail in FIG. 17) to control the flow, as discussed in more detail below. The servo control system generates current throughcoil 925 to generate sufficient magnetic flux until the error signal(difference between the desired flow and actual flow) is minimized or approximately zero. - An
orifice plate 952, as shown in FIG. 18, typically made of non ferromagnetic material, is generally flat on both faces, with the face towardsplunger button assembly 951 having a frusto-conical portion 953. Frusto-conical portion 953 has anopening 954 extending throughorifice plate 952, such that fluid can flow throughorifice plate 952 to afluid output channel 955 into anoutput port 956.Plunger button assembly 951, as shown in FIG. 17, has a smoothflat sealing surface 957 that sits on to frusto-conical portion 953. Aspring pretension spacer 958 is positioned betweenplunger button assembly 951 andorifice plate 952, as shown in FIGS. 11 and 14.Spacer 958 is intended for the purpose of creating an appropriate amount of compression betweenplunger button assembly 951 and frusto-conical portion 953 by allowing aspring 959 inplunger button assembly 951 to bend to a desired extent by a plungerbutton capture spacer 960. The thinner thespacer 958, the greater the bending ofspring 959 inplunger button assembly 951, consequently creating greater compression betweenplunger button assembly 951 and frusto-conical portion 953. - From
output plenum 938, fluid flows through grooves/channels 961 (FIG. 18) formed intoorifice plate 952 and intoopening 954. The amount of fluid flowing intoopening 954 depends on the positioning ofplunger button assembly 951 in relation toorifice plate 952. As the attractive force toplunger button assembly 951, which is created by the magnetic flux, increases,plunger button assembly 951 is moved away fromorifice plate 952, thereby increasing the amount of fluid flowing intoopening 954. However, as the force decreases,spring 959 pushesplunger button assembly 951 towardsorifice plate 952, thereby decreasing the fluid flow intoopening 954. The regulated fluid from opening 954 then flows through afluid output channel 955 and exits fromoutput port 956. - Although the invention has been described with reference to particular embodiments, the description is only an example of the invention's application and should not be taken as a limitation. For example, the above description describes magnetic flux traveling from the input to the output. However, the magnetic flux can also travel from the output to the input along the direction of the bypass assembly for controlling the fluid flow. The concepts described above can then be modified to open or close the path of the fluid in response to the presence of the magnetic flux. Consequently, various adaptations and combinations of features of the embodiments disclosed are within the scope of the invention as defined by the following claims.
Claims (24)
1. A mass flow controller, comprising:
a flow input port located on a lower end of the controller;
a flow output port located on the lower end of the controller;
a sensor unit in fluid connection with the input port and the output port;
a first channel for carrying a first amount of fluid from the input port to the output port;
a second channel for carrying a second amount of fluid through the sensor unit, wherein the second amount is less than the first amount;
an orifice assembly coupled to the output port, wherein the orifice assembly has at least one orifice opening; and
a magnetic field generator coupled between the orifice assembly and the sensor, wherein the magnetic field generator, in response to the sensor unit, generates a magnetic flux in a direction from the sensor unit to the orifice assembly to allow flow through the at least one orifice opening.
2. The mass flow controller of claim 1 , wherein the flow direction through the sensor unit is approximately perpendicular to the flow direction of the magnetic flux.
3. The mass flow controller of claim 1 , further comprising a bypass assembly coupled between the sensor unit and the orifice assembly, wherein the bypass assembly comprises grooves to allow fluid to flow through.
4. The mass flow controller of claim 3 , further comprising a spring-biased sealing mechanism coupled between the bypass assembly and the orifice assembly and moveable along the flow direction.
5. The mass flow controller of claim 4 , wherein the orifice assembly comprises an orifice plate, and wherein the sealing mechanism is located between the bypass assembly and the orifice plate.
6. The mass flow controller of claim 4 , wherein the sealing mechanism has openings to allow flow to the orifice plate.
7. The mass flow controller of claim 1 , wherein the at least one orifice opening is a central hole.
8. The mass flow controller of claim 4 , wherein the spring-biased sealing mechanism seals the at least one orifice opening when no magnetic flux is generated.
9. The mass flow controller of claim 1 , wherein the magnetic field generator comprises:
a solenoid core; and
a solenoid coil surrounding the solenoid core, wherein the solenoid core comprises a ferromagnetic material.
10. The mass flow controller of claim 3 , wherein the magnetic flux travels through the bypass assembly.
11. A mass flow controller, comprising:
an input port;
a first input channel in fluid connection with the input port;
a second input channel in fluid connection with the first input channel, wherein the second input channel is smaller than the first input channel;
a sensor unit in fluid connection with the second input channel;
a magnetic field generator located between the sensor unit and the input port;
an output channel in fluid connection with the sensor unit;
an output port in fluid connection with the output channel; and
an orifice assembly located between the magnetic field generator and the output port, wherein the orifice assembly has at least one opening and, in response to magnetic flux generated by the generator from the sensor unit to the output port, the at least one opening opens to allow fluid flow to the output port.
12. The mass flow controller of claim 11 , wherein the magnetic field generator is located approximately parallel to and at least partially overlaps the first channel.
13. The mass flow controller of claim 11 , further comprising a bypass assembly located between the sensor unit and the output port.
14. The mass flow controller of claim 11 , wherein the at least one opening is sealed when no magnetic flux is generated by the magnetic field generator.
15. The mass flow controller of claim 11 , wherein fluid flow through the sensor unit is approximately perpendicular to the flow direction of the magnetic flux.
16. The mass flow controller of claim 11 , wherein the input port and the output port are located at the same end of the mass flow controller.
17. The mass flow controller of claim 13 , further comprising a spring-biased sealing mechanism located between the bypass assembly and the orifice assembly.
18. The mass flow controller of claim 17 , wherein the sealing mechanism comprises a ferromagnetic material.
19. A method for controlling flow through a mass flow controller having a flow input, a flow output, a sensor unit, and a bypass assembly and a magnetic field generator coupled between the sensor unit and the flow input and output, the method comprising:
introducing a fluid into the flow input;
generating an electrical signal, dependent upon a desired flow rate and a measured flow rate, to the magnetic field generator;
generating a magnetic flux, dependent on the electrical signal, traveling in a direction approximately parallel to the bypass assembly;
in response to the magnetic flux, adjusting the position of a sealing mechanism relative to an orifice to adjust the flow rate through the orifice; and
delivering the fluid out from the flow output in a direction opposite of the fluid introduction.
20. The method of claim 19 , further comprising directing a flow through the sensor unit approximately perpendicular to the flow direction through the bypass assembly.
21. The method of claim 19 , wherein the adjustment of the sealing mechanism is in a direction approximately parallel to the flow direction.
22. The method of claim 19 , wherein in the absence of the magnetic flux, the sealing mechanism seals the orifice.
23. The method of claim 19 , wherein the magnetic flux travels through the bypass assembly to pull the sealing mechanism away from the orifice.
24. The method of claim 19 , wherein the magnetic flux travels through the bypass assembly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/786,520 US20040163712A1 (en) | 2000-03-02 | 2004-02-24 | Mass flow controller and method of operation of mass flow controller |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/517,391 US6314991B1 (en) | 2000-03-02 | 2000-03-02 | Mass flow controller |
| US09/741,552 US6543466B2 (en) | 2000-03-02 | 2000-12-19 | Mass flow controller and method of operation of mass flow controller |
| US10/377,054 US6705341B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
| US10/786,520 US20040163712A1 (en) | 2000-03-02 | 2004-02-24 | Mass flow controller and method of operation of mass flow controller |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/377,054 Continuation US6705341B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
Publications (1)
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|---|---|
| US20040163712A1 true US20040163712A1 (en) | 2004-08-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/741,552 Expired - Fee Related US6543466B2 (en) | 2000-03-02 | 2000-12-19 | Mass flow controller and method of operation of mass flow controller |
| US10/377,039 Expired - Fee Related US6619315B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
| US10/377,054 Expired - Fee Related US6705341B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
| US10/786,520 Abandoned US20040163712A1 (en) | 2000-03-02 | 2004-02-24 | Mass flow controller and method of operation of mass flow controller |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/741,552 Expired - Fee Related US6543466B2 (en) | 2000-03-02 | 2000-12-19 | Mass flow controller and method of operation of mass flow controller |
| US10/377,039 Expired - Fee Related US6619315B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
| US10/377,054 Expired - Fee Related US6705341B2 (en) | 2000-03-02 | 2003-02-28 | Mass flow controller |
Country Status (4)
| Country | Link |
|---|---|
| US (4) | US6543466B2 (en) |
| AU (1) | AU2001247252A1 (en) |
| FR (1) | FR2805904B1 (en) |
| WO (1) | WO2001065326A2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080211510A1 (en) * | 2007-03-01 | 2008-09-04 | Michael John Zolock | Method and apparatus for measuring the temperature of a gas in a mass flow controller |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6543466B2 (en) | 2000-03-02 | 2003-04-08 | Rajinder S. Gill | Mass flow controller and method of operation of mass flow controller |
| US6782906B2 (en) * | 2000-12-28 | 2004-08-31 | Young-Chul Chang | Time based mass flow controller and method for controlling flow rate using it |
| US7232588B2 (en) * | 2004-02-23 | 2007-06-19 | Eastman Kodak Company | Device and method for vaporizing temperature sensitive materials |
| US7394639B2 (en) * | 2005-07-08 | 2008-07-01 | Advanced Energy Industries, Inc. | System and method for driving an industrial control device |
| GB0607851D0 (en) * | 2006-04-24 | 2006-05-31 | Johnson Matthey Plc | Particulate matter generator |
| EP2167824A4 (en) * | 2007-03-30 | 2013-03-13 | Fairchild Ind Products Company | High performance transducer |
| USD584179S1 (en) * | 2008-02-14 | 2009-01-06 | Brooks Instrument, Llc | Mass flow controller |
| USD590734S1 (en) * | 2008-02-14 | 2009-04-21 | Brooks Instrument, Llc | Mass flow controller |
| CN106948004A (en) * | 2009-09-02 | 2017-07-14 | Gtat公司 | Improved under adjusted pressure using the high-temperature technology of helium |
| JP5887188B2 (en) * | 2012-04-12 | 2016-03-16 | 株式会社堀場エステック | Fluid control equipment |
| CN102840356B (en) * | 2012-08-23 | 2013-11-13 | 杭州云谷科技有限公司 | Electromagnetic flow measurement and control integrated device |
| US10161060B2 (en) * | 2013-12-19 | 2018-12-25 | Taiwan Semiconductor Manufacturing Co., Ltd. | Gas-supply system and method |
| US9632516B2 (en) | 2013-12-19 | 2017-04-25 | Tawan Semiconductor Manufacturing Co., Ltd | Gas-supply system and method |
| ITUB20154584A1 (en) * | 2015-10-12 | 2017-04-12 | Elbi Int Spa | VALVE GROUP WITH ASSOCIATED MEASUREMENT DEVICE. |
| US10310521B2 (en) * | 2016-04-07 | 2019-06-04 | Hitachi Metals, Ltd. | Bypass unit, a base for a flow meter, a base for a flow controller, a flow meter, and a flow controller |
| US10648842B2 (en) * | 2016-06-22 | 2020-05-12 | Benoit & Cote Inc. | Fluid flow measuring and control devices and method |
| US9785154B2 (en) * | 2017-02-13 | 2017-10-10 | Robert M. McMillan | Reconfigurable modular fluid flow control system for liquids or gases |
| KR20240026083A (en) * | 2022-08-19 | 2024-02-27 | 가부시키가이샤 호리바 에스텍 | Fluid control valve and fluid control apparatus |
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| US6705341B2 (en) * | 2000-03-02 | 2004-03-16 | Rajinder S. Gill | Mass flow controller |
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| FR2739968B1 (en) | 1995-10-12 | 1998-01-02 | Aerospatiale | ELECTROMAGNETIC LINEAR ACTUATOR WITH MOBILE PLATES AND FLUID REGULATOR WITH VALVES DRIVEN BY SUCH AN ACTUATOR |
| US6314991B1 (en) | 2000-03-02 | 2001-11-13 | Rajinder S. Gill | Mass flow controller |
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- 2000-12-19 US US09/741,552 patent/US6543466B2/en not_active Expired - Fee Related
-
2001
- 2001-02-28 WO PCT/US2001/006671 patent/WO2001065326A2/en not_active Ceased
- 2001-02-28 AU AU2001247252A patent/AU2001247252A1/en not_active Abandoned
- 2001-03-02 FR FR0102878A patent/FR2805904B1/en not_active Expired - Fee Related
-
2003
- 2003-02-28 US US10/377,039 patent/US6619315B2/en not_active Expired - Fee Related
- 2003-02-28 US US10/377,054 patent/US6705341B2/en not_active Expired - Fee Related
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| US4794947A (en) * | 1986-11-29 | 1989-01-03 | Kabushiki Kaisha Nippon IC (also trading as Nippon IC, Inc.) | Mass flow controller |
| US6705341B2 (en) * | 2000-03-02 | 2004-03-16 | Rajinder S. Gill | Mass flow controller |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080211510A1 (en) * | 2007-03-01 | 2008-09-04 | Michael John Zolock | Method and apparatus for measuring the temperature of a gas in a mass flow controller |
| WO2008109339A3 (en) * | 2007-03-01 | 2008-11-06 | Advanced Energy Ind Inc | Method and apparatus for measuring the temperature of a gas in a mass flow controller |
| US7651263B2 (en) | 2007-03-01 | 2010-01-26 | Advanced Energy Industries, Inc. | Method and apparatus for measuring the temperature of a gas in a mass flow controller |
| TWI454671B (en) * | 2007-03-01 | 2014-10-01 | Hitachi Metals Ltd | Method and apparatus for measuring the temperature of a gas in a mass flow controller |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001065326A3 (en) | 2002-02-07 |
| AU2001247252A1 (en) | 2001-09-12 |
| WO2001065326A9 (en) | 2002-12-27 |
| US6705341B2 (en) | 2004-03-16 |
| FR2805904A1 (en) | 2001-09-07 |
| US20030127131A1 (en) | 2003-07-10 |
| WO2001065326A2 (en) | 2001-09-07 |
| US20030127139A1 (en) | 2003-07-10 |
| US6543466B2 (en) | 2003-04-08 |
| FR2805904B1 (en) | 2007-02-23 |
| US6619315B2 (en) | 2003-09-16 |
| US20010018927A1 (en) | 2001-09-06 |
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Legal Events
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| STCB | Information on status: application discontinuation |
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