US20040117915A1 - Multifunctional surface treatment for textiles - Google Patents
Multifunctional surface treatment for textiles Download PDFInfo
- Publication number
- US20040117915A1 US20040117915A1 US10/322,767 US32276702A US2004117915A1 US 20040117915 A1 US20040117915 A1 US 20040117915A1 US 32276702 A US32276702 A US 32276702A US 2004117915 A1 US2004117915 A1 US 2004117915A1
- Authority
- US
- United States
- Prior art keywords
- substrate
- curing
- coating
- coated substrate
- dried
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000004753 textile Substances 0.000 title claims abstract description 16
- 238000004381 surface treatment Methods 0.000 title description 3
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims abstract description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2400/00—Specific information on the treatment or the process itself not provided in D06M23/00-D06M23/18
- D06M2400/02—Treating compositions in the form of solgel or aerogel
Definitions
- the present invention relates to multifunctional nanostructural surface treatment for textiles. More particularly, although not exclusively, the invention relates to the surface treatment of textiles adopting a Sol-gel reaction scheme.
- the invention relates to a simple, fast and low-cost finishing process for textiles using a metal oxide matrix providing improved surface properties. Properties to be improved might be ultraviolet filtering, hydrophilicity, self-cleaning, antimicrobial and deodorising characteristics.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
A process for chemically bonding an oxide matrix to a textile surface, comprises providing a dry textile substrate, coating the substrate with a nanosol preparation, and curing the coated substrate.
Description
- The present invention relates to multifunctional nanostructural surface treatment for textiles. More particularly, although not exclusively, the invention relates to the surface treatment of textiles adopting a Sol-gel reaction scheme. The invention relates to a simple, fast and low-cost finishing process for textiles using a metal oxide matrix providing improved surface properties. Properties to be improved might be ultraviolet filtering, hydrophilicity, self-cleaning, antimicrobial and deodorising characteristics.
- Applications of the invention exist in the production of smart textiles with tailor-made end uses addressing environmental protection and hygienic aspects.
- Present technologies such as impregnation coating of dispersed nanoparticles suffer from low adhesion between the oxide coating and the textile surface and hence poor wash-fastness results. The present invention, on the other hand allows for chemical bonding between the oxide matrix and the textile surface leading to excellent wash fastness. Other advantages are in the simplicity of the process and the low processing temperatures
- The invention may have application to the treatment of cellulosic webs (such as paper, cotton, rayon and other regenerated cellulosic and cellulosic-containing materials such as Tencil and Lyocell, as well as linen, jute, ramie and industrial hemp or the like), wool which is proteinaceous animal fibre, as well as silk and regenerated proteins, other animal fibres, man-made or synthetic fibres that contain hydroxyls, amides, carboxyl and thiol groups.
- It is an object of the present invention to provide a simple process for coating textile surfaces with a continuous metal oxide without altering the appearance of the textile.
- There is disclosed herein a process for bonding an oxide matrix directly to a textile surface, comprising:
- providing a dry textile substrate,
- coating the substrate with a nanosol preparation, and
- drying/curing the coated substrate.
- Preferably the coated substrate is pressed and/or padded prior to drying/curing.
- Preferably the pressing/padding takes place at a pressure of about 2.7 kg per square cm.
- Preferably the coated substrate is dried at about 80° C. for about 10 minutes prior to curing.
- Typically curing is effected at about 150° C. for about 5 minutes.
- Preferably the nanosol preparation is prepared at room temperature by mixing titanium tetraisopropoxide, ethanol and acetic acid in a molar ratio of 1:100:0.05 respectively.
- The substrate is typically dried at about 100° C. for about 5-10 minutes prior to the coating step.
- Preferably the coating step comprises dip-coating the substrate in the nanosol preparation for about 30 seconds.
- Definition
- As used herein, the term “dry” is intended to mean that the surface of the textile is free of water to enable the nanosol preparation to coat and remain coated to the substrate.
- The General Sol-gel Reaction Scheme
- The general reaction,scheme adopted in the present invention is represented as follows:
- Titania Nanosol Preparation
- The nanosol can be prepared at room temperature by mixing titanium tetraisopropoxide, ethanol and acetic acid in a molar ratio of 1:100:0.05 respectively.
- A cotton substrate of 10×10 cm was dried at 100° C. for 10 minutes. The dried cotton substrate was then dip-coated in the prepared sol for 30 seconds, padded at 2,7 kg per square centimetre and dried at 80° C. for 10 minutes and then finally cured at 150° C. for five minutes.
Claims (8)
1. A process for bonding an oxide matrix directly to a textile surface, comprising:
providing a dry textile substrate,
coating the substrate with a nanosol preparation, and
drying/curing the coated substrate.
2. The process of claim 1 wherein the coated substrate is pressed and/or padded prior to drying/curing.
3. The process of claim 2 wherein the pressing/padding takes place at a pressure of about 2.7 kg per square cm.
4. The process of claim 1 wherein the coated substrate is dried at about 80° C. for about 10 minutes prior to curing.
5. The process of claim 1 wherein curing of the coated substrate is effected at about 150° C. for about 5 minutes.
6. The process of claim 1 wherein the nanosol preparation is prepared at room temperature by mixing titanium tetraisopropoxide, ethanol and acetic acid in a molar ratio of 1:100:0.05 respectively.
7. The process of claim 1 wherein the substrate is dried at about 110° C. for about 10 minutes prior to the coating step.
8. The process of claim 1 wherein the coating step comprises dip-coating the substrate in the nanosol preparation for about 30 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/322,767 US20040117915A1 (en) | 2002-12-19 | 2002-12-19 | Multifunctional surface treatment for textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/322,767 US20040117915A1 (en) | 2002-12-19 | 2002-12-19 | Multifunctional surface treatment for textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20040117915A1 true US20040117915A1 (en) | 2004-06-24 |
Family
ID=32593030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/322,767 Abandoned US20040117915A1 (en) | 2002-12-19 | 2002-12-19 | Multifunctional surface treatment for textiles |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US20040117915A1 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050260455A1 (en) * | 2004-05-20 | 2005-11-24 | Xin John H | Methods of coating titanium dioxide |
| WO2007137971A2 (en) | 2006-05-26 | 2007-12-06 | Cht R. Beitlich Gmbh | Water-dilutable concentrates for coating different substrates |
| US20080241405A1 (en) * | 2007-04-02 | 2008-10-02 | The Hong Kong Polytechnic University | Formulation coated self-cleaning wool |
| DE102007054627A1 (en) | 2007-11-15 | 2009-05-20 | Cht R. Beitlich Gmbh | Water-compatible brine for coating various substrates |
| WO2010029586A1 (en) * | 2008-09-11 | 2010-03-18 | Biotecnology Advice And Designer International S.R.L. | Surface treatment method, particularly for materials, fabrics and other laminar elements having similar properties, and product obtained with the method |
| DE102010030046A1 (en) | 2009-07-17 | 2011-02-03 | BSH Bosch und Siemens Hausgeräte GmbH | Photocatalytic treatment unit for use with laundry dryer to perform photocatalytic treatment of laundry item, has set of illuminants that are freely movable in container, where laundry item and illuminants are accommodated in container |
| KR101121575B1 (en) | 2009-10-26 | 2012-03-07 | 주식회사 블루폴리텍 | Preparation of transparent nano sol compositions with high refraction inoranic particle and epoxy acrylate oligomer, epoxy acrylate resin, organic or inorganic hybride resin including the same |
| CN104947411A (en) * | 2015-07-07 | 2015-09-30 | 安徽理工大学 | Multifunctional fabric slurry composite and preparation method thereof |
| CN105040426A (en) * | 2015-07-07 | 2015-11-11 | 安徽理工大学 | Antibacterial warming anti-electromagnetic radiation textile fabric and preparation method thereof |
| WO2020243889A1 (en) * | 2019-06-04 | 2020-12-10 | Lora & Festa Limited | Functional cashmere fiber and fabrication method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951941A (en) * | 1973-03-14 | 1976-04-20 | Sakai Chemical Industry Company, Limited | Trisazo compounds containing a diphenyl-tetrazinyl component |
| US4015037A (en) * | 1976-03-22 | 1977-03-29 | Michigan Chemical Corporation | Durable flame retardant finishes for textile materials |
| US6465088B1 (en) * | 1998-03-05 | 2002-10-15 | Saint-Gobain Glass France | Substrate with a photocatalytic coating |
-
2002
- 2002-12-19 US US10/322,767 patent/US20040117915A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951941A (en) * | 1973-03-14 | 1976-04-20 | Sakai Chemical Industry Company, Limited | Trisazo compounds containing a diphenyl-tetrazinyl component |
| US4015037A (en) * | 1976-03-22 | 1977-03-29 | Michigan Chemical Corporation | Durable flame retardant finishes for textile materials |
| US6465088B1 (en) * | 1998-03-05 | 2002-10-15 | Saint-Gobain Glass France | Substrate with a photocatalytic coating |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050260455A1 (en) * | 2004-05-20 | 2005-11-24 | Xin John H | Methods of coating titanium dioxide |
| US8309476B2 (en) | 2006-05-26 | 2012-11-13 | Cht R. Beitlich Gmbh | Water-dilutable concentrates for the coating of various substrates |
| WO2007137971A2 (en) | 2006-05-26 | 2007-12-06 | Cht R. Beitlich Gmbh | Water-dilutable concentrates for coating different substrates |
| US20100203312A1 (en) * | 2006-05-26 | 2010-08-12 | Cht R. Beitlich Gmbh | Water-dilutable concentrates for the coating of various substrates |
| US20080241405A1 (en) * | 2007-04-02 | 2008-10-02 | The Hong Kong Polytechnic University | Formulation coated self-cleaning wool |
| WO2008120088A3 (en) * | 2007-04-02 | 2008-12-04 | Univ Hong Kong Polytechnic | Formulation coated self-cleaning wool |
| US8679588B2 (en) * | 2007-04-02 | 2014-03-25 | The Hong Kong Polytechnic University | Formulation coated self-cleaning wool |
| US8926744B2 (en) | 2007-11-15 | 2015-01-06 | Cht R. Beitlich Gmbh | Water-compatible sols for coating various substrates |
| US20100311295A1 (en) * | 2007-11-15 | 2010-12-09 | Cht R. Beitlich Gmbh | Water-compatible sols for coating various substrates |
| DE102007054627A1 (en) | 2007-11-15 | 2009-05-20 | Cht R. Beitlich Gmbh | Water-compatible brine for coating various substrates |
| WO2010029586A1 (en) * | 2008-09-11 | 2010-03-18 | Biotecnology Advice And Designer International S.R.L. | Surface treatment method, particularly for materials, fabrics and other laminar elements having similar properties, and product obtained with the method |
| DE102010030046A1 (en) | 2009-07-17 | 2011-02-03 | BSH Bosch und Siemens Hausgeräte GmbH | Photocatalytic treatment unit for use with laundry dryer to perform photocatalytic treatment of laundry item, has set of illuminants that are freely movable in container, where laundry item and illuminants are accommodated in container |
| KR101121575B1 (en) | 2009-10-26 | 2012-03-07 | 주식회사 블루폴리텍 | Preparation of transparent nano sol compositions with high refraction inoranic particle and epoxy acrylate oligomer, epoxy acrylate resin, organic or inorganic hybride resin including the same |
| CN104947411A (en) * | 2015-07-07 | 2015-09-30 | 安徽理工大学 | Multifunctional fabric slurry composite and preparation method thereof |
| CN105040426A (en) * | 2015-07-07 | 2015-11-11 | 安徽理工大学 | Antibacterial warming anti-electromagnetic radiation textile fabric and preparation method thereof |
| WO2020243889A1 (en) * | 2019-06-04 | 2020-12-10 | Lora & Festa Limited | Functional cashmere fiber and fabrication method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: THE HONG KONG POLYTECHNIC UNIVERSITY, HONG KONG Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:XIN, JOHN HAOZHONG;DAOUD, WALID ABDELHAMID;TAO, XIAO MING;REEL/FRAME:013797/0268 Effective date: 20030117 |
|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |