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US20040014799A1 - Synergetic biocidal composition comprising 2-methylisothiazoline-3-on - Google Patents

Synergetic biocidal composition comprising 2-methylisothiazoline-3-on Download PDF

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Publication number
US20040014799A1
US20040014799A1 US10/362,326 US36232603A US2004014799A1 US 20040014799 A1 US20040014799 A1 US 20040014799A1 US 36232603 A US36232603 A US 36232603A US 2004014799 A1 US2004014799 A1 US 2004014799A1
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US
United States
Prior art keywords
active ingredient
biocidal active
biocide composition
mit
methylisothiazolin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/362,326
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English (en)
Inventor
Dagmar Antoni-Zimmermann
Rudiger Baum
Hans-Jurgen Schmidt
Thomas Wunder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thor GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7654500&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20040014799(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Assigned to THOR GMBH reassignment THOR GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ANTONI-ZIMMERMAN, DAGMAR, BAUM, RUDIGER, SCHMIDT, HANS-JURGEN, WUNDER, THOMAS
Publication of US20040014799A1 publication Critical patent/US20040014799A1/en
Priority to US12/319,828 priority Critical patent/US8323674B2/en
Abandoned legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Definitions

  • biocide composition according to the invention may also be combined simultaneously with a polar and an unpolar liquid medium.
  • the biocide composition according to the invention can be employed in very different fields.
  • it is suitable for use in paints, renderings, lignosulfonates, chalk suspensions, glues, photochemicals, casein-containing products, starch-containing products, bitumen emulsions, surfactant solutions, fuels, cleaners, cosmetic products, water circuits, polymer dispersions and cooling lubricants against attack by, for example, bacteria, filamentous fungi, yeasts and algae.
  • synergism which is present is shown in the form of figures using the calculations of the synergistic index shown in table II.
  • the synergistic index is calculated by the method of F. C. Kull et al., Applied Microbiology, vol. 9 (1961), p. 538.
  • the synergistic index is calculated using the following formula:
  • the MIC values of the biocide compositions tested can be seen from table V which follows.
  • the MIC value was 40 ppm when only MIT was employed and 30 ppm when only PMG was employed.
  • TABLE V Pseudomonas aeruginosa MIC values of MIT + PGM at an incubation time of 48 h/25° C.
  • MIT concentration PMG concentration (ppm) 100 75 50 40 30 20 10 0 50 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ 40 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ 30 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 20 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 15 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 10 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 7.5 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 5 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 0 ⁇ ⁇ ⁇ ⁇ + + + + + +
  • the MIC values of the biocide composition tested can be seen from table IX which follows. The MIC value was 40 ppm when only MIT was employed and over 100 ppm when only ZnPy was employed. TABLE IX Pseudomonas aeruginosa : MIC values of MIT + ZnPy at an incubation time of 72 h/25° C.
  • the experimental batches contained a Müller-Hinton broth as the nutrient medium.
  • the cell density was 10 6 cells/ml.
  • the incubation time was 72 hours at 25° C. Each sample was incubated in a shaker-incubator at 120 rpm.
  • MIT concentration BBIT concentration (ppm) 500 375 250 200 150 100 50 0 50 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ 40 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ 30 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 20 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 15 ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ + 10 ⁇ ⁇ ⁇ ⁇ ⁇ + + 5 + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
US10/362,326 2000-08-31 2001-05-23 Synergetic biocidal composition comprising 2-methylisothiazoline-3-on Abandoned US20040014799A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/319,828 US8323674B2 (en) 2000-08-31 2009-01-12 Synergistic biocide composition comprising 2-methylisothiazoline-3-one

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10042894.0 2000-08-31
DE10042894A DE10042894A1 (de) 2000-08-31 2000-08-31 Synergistische Biozidzusammensetzung mit 2-Methylisothiazolin-3-on
PCT/EP2001/005939 WO2002017716A1 (de) 2000-08-31 2001-05-23 Synergistische biozidzusammensetzung mit 2-methylisothiazolin-3-on

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/319,828 Division US8323674B2 (en) 2000-08-31 2009-01-12 Synergistic biocide composition comprising 2-methylisothiazoline-3-one

Publications (1)

Publication Number Publication Date
US20040014799A1 true US20040014799A1 (en) 2004-01-22

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
US10/362,326 Abandoned US20040014799A1 (en) 2000-08-31 2001-05-23 Synergetic biocidal composition comprising 2-methylisothiazoline-3-on
US12/319,828 Expired - Fee Related US8323674B2 (en) 2000-08-31 2009-01-12 Synergistic biocide composition comprising 2-methylisothiazoline-3-one

Family Applications After (1)

Application Number Title Priority Date Filing Date
US12/319,828 Expired - Fee Related US8323674B2 (en) 2000-08-31 2009-01-12 Synergistic biocide composition comprising 2-methylisothiazoline-3-one

Country Status (21)

Country Link
US (2) US20040014799A1 (de)
EP (2) EP1676479A1 (de)
JP (1) JP2004507475A (de)
KR (1) KR100793444B1 (de)
CN (1) CN1234273C (de)
AT (1) ATE341939T1 (de)
AU (2) AU7241901A (de)
BR (1) BR0113575A (de)
CA (1) CA2420135A1 (de)
CZ (1) CZ2003653A3 (de)
DE (2) DE10042894A1 (de)
DK (1) DK1315419T3 (de)
ES (1) ES2276804T3 (de)
HU (1) HUP0301731A3 (de)
MX (1) MXPA03001626A (de)
NO (1) NO20030906L (de)
PL (1) PL361624A1 (de)
PT (1) PT1315419E (de)
RU (1) RU2269264C2 (de)
UA (1) UA74843C2 (de)
WO (1) WO2002017716A1 (de)

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JP2005281305A (ja) * 2004-03-05 2005-10-13 Rohm & Haas Co Ｎ−（ｎ−ブチル）−１，２−ベンズイソチアゾリン−３−オンを含有する抗微生物組成物
US20060106024A1 (en) * 2004-11-16 2006-05-18 Richard Levy Microbicidal composition
US20060124246A1 (en) * 2004-12-14 2006-06-15 Pitney Bowes Incorporated Moistening fluids that destroy and/or inhibit the growth of biological organisms
US20070078118A1 (en) * 2005-10-04 2007-04-05 Richard Levy Microbicidal composition
US20070275094A1 (en) * 2006-05-26 2007-11-29 Thompson Nicholas E Isothiazolinone biocides enhanced by zinc ions
US20080227766A1 (en) * 2005-09-02 2008-09-18 Thor Gmbh Synergistic, Silver-Containing Biocide Composition
US20080274154A1 (en) * 2007-05-04 2008-11-06 Werner Bussmann Water-based, antimicrobially active, dispersion concentrates
US20090035340A1 (en) * 2007-07-30 2009-02-05 Kimberly-Clark Worldwide, Inc. Preservative compositions for moist wipes
US20090053272A1 (en) * 2005-05-10 2009-02-26 Basf Se Method for producing polymer nanoparticles
US20090163445A1 (en) * 2007-12-20 2009-06-25 Diehl Megan A Synergistic microbicidal compositions
US20100099793A1 (en) * 2006-12-28 2010-04-22 Thor Gmbh Gluing and Sealing Compounds Having Antimicrobial Properties
EP2289335A2 (de) 2009-07-30 2011-03-02 Rohm and Haas Company Synergistische mikrobizide Zusammensetzungen enthaltend 2-Methyl-4-isothiazolin-3-on (MIT) oder 1,2-Benzisothiazolin-3-on (BIT)
EP1924140A4 (de) * 2005-07-08 2012-06-06 Isp Investiments Inc Mikrobizidzusammensetzung
EP2614710A1 (de) 2005-07-08 2013-07-17 Isp Investments Inc. Mikrobizidzusammensetzung
AU2012201220B2 (en) * 2005-10-04 2013-09-05 Rohm And Haas Company Microbicidal composition
AU2012201201B2 (en) * 2005-10-04 2013-09-05 Rohm And Haas Company Microbicidal composition
US9131683B2 (en) 2011-09-30 2015-09-15 The Sherwin-Williams Company High quality antimicrobial paint composition
EP2932852A1 (de) * 2012-05-24 2015-10-21 Dow Global Technologies LLC Mikrobizide zusammensetzung
WO2016196116A1 (en) * 2015-05-31 2016-12-08 Dow Global Technologies Llc Microbicidal composition containing ortophenylphenol and isothiazolinone
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ATE549922T1 (de) 2009-01-29 2012-04-15 Thor Gmbh Biozidzusammensetzungen enthaltend 2- methylisothiazolin-3-on und ein haloalkylsulfon
JP5356884B2 (ja) * 2009-03-31 2013-12-04 アクアス株式会社 微生物防除剤、及び、微生物防除方法
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BR122017008236B1 (pt) * 2009-10-20 2018-01-16 Dow Global Technologies Llc Composição antimicrobiana sinérgica compreendendo composto de fósforo substituído por hidroximetila e derivados de orto-fenilfenol
JP5431291B2 (ja) * 2009-12-18 2014-03-05 ダウ・イタリア・ディビジョン・コマーシャル・ソシエテ・ア・レスポンサビリテ・リミテ 低温での使用に適する消毒剤配合物
WO2011147558A1 (de) 2010-05-26 2011-12-01 Thor Gmbh Synergistische biozidzusammensetzung enthaltend wenigstens drei biozide komponenten
JP5643740B2 (ja) * 2010-12-27 2014-12-17 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ 安定化された殺微生物組成物
JP2013014619A (ja) * 2012-10-09 2013-01-24 Aquas Corp 藻類抑制剤、及び、藻類抑制方法
US20160106099A1 (en) * 2013-05-28 2016-04-21 Thor Gmbh Microbicidal composition comprising isothiazolone and an amine oxide
CN103535369B (zh) * 2013-10-25 2014-09-17 中国海洋石油总公司 一种生物粘泥抑制剂及其制备方法
ES2790679T5 (es) * 2013-12-06 2024-05-20 Thor Gmbh Procedimiento para la producción de un agente de revestimiento
US20180036236A1 (en) * 2015-02-05 2018-02-08 Marc Selner Ionic nanovesicle suspension and biocide prepared therefrom
US12433856B2 (en) 2015-06-19 2025-10-07 Global Health Solutions Llc Petrolatum-based compositions and methods of treatment for onychomycosis
US11110071B2 (en) 2015-06-19 2021-09-07 Global Health Solutions Llc Petrolatum-based PHMB compositions and methods of treatment for onychomycosis
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AU2016278854A1 (en) 2015-06-19 2018-02-08 Global Health Solutions, LLC. Petrolatum-based delivery systems and for active ingredients
EP3439476A1 (de) * 2016-04-05 2019-02-13 THOR GmbH Synergistische biozidzusammensetzungen enthaltend 5-chlor-2-methylisothiazolin-3-on
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WO2018235269A1 (ja) * 2017-06-23 2018-12-27 ロンザ リミテッド 工業用防腐組成物
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AU2010246431B2 (en) * 2004-11-16 2011-08-11 Rohm And Haas Company Microbicidal composition
EP2289329A2 (de) 2004-11-16 2011-03-02 Rohm and Haas Company Mikrobizide Zusammensetzung
EP1665933A3 (de) * 2004-11-16 2006-08-16 Rohm and Haas Company Mikrobizide Zusammensetzung
EP2289328A3 (de) * 2004-11-16 2011-11-02 Rohm and Haas Company Mikrobizide Zusammensetzung
EP2289327A3 (de) * 2004-11-16 2011-10-26 Rohm and Haas Company Mikrobizide Zusammensetzung
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EP2289330A2 (de) 2004-11-16 2011-03-02 Rohm and Haas Company Mikrobizide Zusammensetzung
EP2289328A2 (de) 2004-11-16 2011-03-02 Rohm and Haas Company Mikrobizide Zusammensetzung
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EP2289334A2 (de) 2004-11-16 2011-03-02 Rohm and Haas Company Mikrobizide Zusammensetzung
US20060124246A1 (en) * 2004-12-14 2006-06-15 Pitney Bowes Incorporated Moistening fluids that destroy and/or inhibit the growth of biological organisms
US20090053272A1 (en) * 2005-05-10 2009-02-26 Basf Se Method for producing polymer nanoparticles
EP2614710A1 (de) 2005-07-08 2013-07-17 Isp Investments Inc. Mikrobizidzusammensetzung
EP1924140A4 (de) * 2005-07-08 2012-06-06 Isp Investiments Inc Mikrobizidzusammensetzung
US20080227766A1 (en) * 2005-09-02 2008-09-18 Thor Gmbh Synergistic, Silver-Containing Biocide Composition
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EP2865269A1 (de) 2005-10-04 2015-04-29 Rohm and Haas Company Synergistische mikrobizide Zusammensetzung enthaltend ein N-Alkyl Benzisothiazolinon und Hexetidin
AU2012201220B2 (en) * 2005-10-04 2013-09-05 Rohm And Haas Company Microbicidal composition
EP2865268A1 (de) 2005-10-04 2015-04-29 Rohm and Haas Company Synergistische mikrobizide Zusammensetzung enthaltend ein N-Alkylbenzisothiazolon und Dithio-2,2'-bis(N-methylbenzamid)
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EP1925202A2 (de) 2005-10-04 2008-05-28 Rohm and Haas Company Synergistische Mikrobizidzusammensetzungen enthaltend N-Alkyl-1,2-benzisothiazolin-3-on
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ATE341939T1 (de) 2006-11-15
EP1315419A1 (de) 2003-06-04
DE50111219D1 (de) 2006-11-23
JP2004507475A (ja) 2004-03-11
NO20030906D0 (no) 2003-02-26
KR100793444B1 (ko) 2008-01-11
KR20030029853A (ko) 2003-04-16
DE10042894A1 (de) 2002-03-14
CZ2003653A3 (cs) 2003-08-13
PT1315419E (pt) 2007-01-31
MXPA03001626A (es) 2004-09-10
CA2420135A1 (en) 2003-02-20
CN1449245A (zh) 2003-10-15
DK1315419T3 (da) 2007-02-19
HUP0301731A2 (hu) 2003-08-28
NO20030906L (no) 2003-04-24
AU2001272419B2 (en) 2006-03-02
EP1676479A1 (de) 2006-07-05
HUP0301731A3 (en) 2005-05-30
RU2269264C2 (ru) 2006-02-10
WO2002017716A1 (de) 2002-03-07
US20090156570A1 (en) 2009-06-18
ES2276804T3 (es) 2007-07-01
AU7241901A (en) 2002-03-13
US8323674B2 (en) 2012-12-04
BR0113575A (pt) 2003-07-22
UA74843C2 (en) 2006-02-15
CN1234273C (zh) 2006-01-04
PL361624A1 (en) 2004-10-04
EP1315419B1 (de) 2006-10-11

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