US20020033332A1 - Water Electrolytic system - Google Patents
Water Electrolytic system Download PDFInfo
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- US20020033332A1 US20020033332A1 US09/950,825 US95082501A US2002033332A1 US 20020033332 A1 US20020033332 A1 US 20020033332A1 US 95082501 A US95082501 A US 95082501A US 2002033332 A1 US2002033332 A1 US 2002033332A1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 99
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention relates to a water electrolytic system designed so that a water electrolyzer is operated by an output from a photovoltaic generator.
- a photovoltaic generator has an optimal point of operation, namely, an operating current and an operating voltage at the time when the output from the photovoltaic generator assumes a maximum value. If the optimal point of operation is matched with an IV characteristic (I: current, V: voltage) of a water electrolyzer, the water electrolyzer can be operated with a good efficiency. However, the optimal point of operation is varied depending on the temperature of the photovoltaic generator, an insolation amount to the photovoltaic generator and the like and as a result, the optimal point of operation is not matched with the IV characteristic of the water electrolyzer. When the photovoltaic generator and the water electrolyzer have been connected in series to each other, namely, connected directly to each other, it is difficult to operate the water electrolytic system with a good efficiency at all times.
- I current, V: voltage
- a water electrolytic system which includes a water electrolyzer, a photovoltaic generator, and a high-output type DC/DC converter adapted to convert all of the maximum output from the photovoltaic generator into a current and a voltage corresponding to an IV characteristic of the water electrolyzer to input them to the water electrolyzer.
- the high-output type DC/DC converter is large in size with a weight of about 60 kg and moreover, is of a high cost and has an efficiency of 80 to 90% and hence, a loss of 10 to 20% is produced. For this reason, the conventional system has a problem that it lacks in economy.
- a water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for the water electrolyzer, and a DC/DC converter adapted to convert the maximum output from the photovoltaic generator into a current and a voltage corresponding to an IV characteristic of the water electrolyzer by carrying out the conversion of current and voltage for a portion of the maximum output and to input the current and the voltage to the water electrolyzer.
- the water electrolyzer when the maximum output from the photovoltaic generator has been varied, the water electrolyzer can be operated with a good efficiency by utilizing the varied maximum output. Moreover, the conversion of current and voltage is carried out for a portion of the maximum output from the photovoltaic generator by the DC/DC converter and hence, a loss in the entire system can be suppressed to a small level, and a low-output type of a DC/DC converter made in a small size and at a low cost can be employed, leading to an increase in economy.
- a water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for the water electrolyzer, and a DC power source adapted to add an external output to the maximum output from the photovoltaic generator in order to provide a current and a voltage corresponding to an IV characteristic of the water electrolyzer.
- FIG. 1 is a graph showing a first example of an IV characteristic for a photovoltaic generator and a water electrolyzer
- FIG. 2A is a diagram of an electric circuit of example 1 of a first embodiment of the present invention.
- FIG. 2B is an equivalent circuit of the electric circuit shown in FIG. 2A;
- FIG. 3 is a graph showing a second example of the IV characteristic for a photovoltaic generator and a water electrolyzer
- FIG. 4A is a diagram of an electric circuit of example 2 of the first embodiment of the present invention.
- FIG. 4B is an equivalent circuit of the electric circuit shown in FIG. 4A;
- FIG. 5 is a diagram of an electric circuit of example 1 of a second embodiment of the present invention.
- FIG. 6 is a graph showing a third example of the IV characteristic for a photovoltaic generator and a water electrolyzer.
- FIG. 7 is a diagram of an electric circuit of example 2 of the second embodiment.
- FIGS. 1 to 4 B show a first embodiment of a water electrolytic system 1 .
- the first embodiment includes example 1 and example 2.
- FIGS. 1, 2A and 2 B show example 1
- FIGS. 3, 4A and 4 B show example 2.
- FIG. 1 shows a mode when the maximum output from a photovoltaic generator 2 has been varied.
- a line L 1 indicates an IV characteristic of the photovoltaic generator 2 at 28° C. (an insolation amount: 1040 W/m 2 ), and a line L 2 indicates an output characteristic of the photovoltaic generator 2 .
- an optimal point P 1 of operation of the photovoltaic generator 2 is a point at which the output is a maximum value.
- Such maximum output Emax is 1506 W.
- a line L 3 indicates an IV characteristic of a water electrolyzer (number of water electrolytic cells: 8) 4 .
- a point of intersection between the line L 1 indicating the IV characteristic of the photovoltaic generator 2 and the line L 3 indicating the IV characteristic of the water electrolyzer 4 is a point P 2 of operation of the water electrolyzer 4 .
- This point P 2 of operation is at a location displaced from the optimal point P 1 of operation of the photovoltaic generator 2 toward a lower current and higher voltage side and hence, the highly efficient operation of the water electrolytic system 1 cannot be desired.
- a peak power tracking is carried out, which comprises controlling a low-output type DC/DC converter 5 , so that the operating current Imax at the optimal point P 1 of operation of the photovoltaic generator 2 is decreased, and the operating voltage Vmax is increased, measuring a current Imax ⁇ dI and a voltage Vmax+dV lying on the line L 3 indicating the IV characteristic of the water electrolyzer 4 , and determining these current and voltage as an operating current and an operating voltage for the water electrolyzer 4 .
- the low-output type DC/DC converter 5 is connected in series between the photovoltaic generator 2 and the water electrolyzer 4 .
- the low-output type DC/DC converter 5 has a function to conduct the conversion of current and voltage for a portion of the maximum output from the photovoltaic generator 2 , thereby converting the maximum output into a current and a voltage corresponding to the IV characteristic of the water electrolyzer 4 and inputting the current and the voltage to the water electrolyzer 4 , in order to carry out the peak power tracking.
- FIG. 2B shows an equivalent circuit shown in FIG. 2A.
- the operating current Imax (92.4 A) and the operating voltage Vmax (16.3 V) at the optimal point P 1 of operation of the photovoltaic generator 2 are first determined.
- the point P 2 of operation of the water electrolyzer 4 is a point at which the operating current is 80 A and the operating voltage is 17.8 V.
- an output of (Vmax+dV).(Imax ⁇ dI) is supplied from the photovoltaic generator 2 to the water electrolyzer 4 .
- a portion Vmax.dI of the maximum output Imax.Vmax from the photovoltaic generator 2 has been converted into (Imax ⁇ dI).dV at the supplied output (Vmax+dV).(Imax ⁇ dI), wherein (Imax ⁇ dI).dV is a value resulting from the subtraction of a loss due to the conversion from Vmax.dI.
- the weight of the low-output type DC/DC converter 5 was about 8 kg, which is about 13% of the weight of a high-output type DC/DC converter, and the efficiency was equal to or higher than 94%.
- FIG. 3 shows a mode when the maximum output from the photovoltaic generator 2 has been varied.
- a line L 1 indicates an IV characteristic of the photovoltaic generator 2 at 28° C. (an insolation amount: 1040 W/m 2 ), and a line L 2 indicates an output characteristic of the photovoltaic generator 2 , as in example 1.
- an optimal point P 1 of operation of the photovoltaic generator 2 is a point at which the output is a maximum value.
- Such maximum output Emax is 1506 W.
- a line L 3 indicates an IV characteristic of a water electrolyzer (number of water electrolytic cells: 6) 4 .
- a point of intersection between the line L 1 indicating the IV characteristic of the photovoltaic generator 2 and the line L 3 indicating the IV characteristic of the water-electrolyzing device 4 is a point P 2 of operation of the water electrolyzer 4 .
- This point P 2 of operation is at a location displaced from the optimal point P 1 of operation of the photovoltaic generator 2 toward a higher current and lower voltage side and hence, the highly efficient operation of the water electrolytic system 1 cannot be desired.
- a peak power tracking is carried out, which comprises controlling a low-output type DC/DC converter 5 , so that the operating current Imax at the optimal point P 1 of operation of the photovoltaic generator 2 is increased, and the operating voltage Vmax is decreased, measuring a current Imax+dI and a voltage Vmax ⁇ dV lying on the line L 3 indicating the IV characteristic of the water electrolyzer 4 , and determining these current and voltage as an operating current and an operating voltage for the water electrolyzer 4 .
- the low-output type DC/DC converter 5 is connected in parallel between the photovoltaic generator 2 and the water electrolyzer 4 .
- the low-output type DC/DC converter 5 has a function to conduct the conversion of current and voltage for a portion of the maximum output from the photovoltaic generator 2 , thereby converting the maximum output into a current and a voltage corresponding to the IV characteristic of the water electrolyzer 4 and inputting the current and the voltage to the water electrolyzer 4 , in order to carry out the peak power tracking.
- FIG. 4B shows an equivalent circuit shown in FIG. 4A.
- the operating current Imax (92.4 A) and the operating voltage Vmax (16.3 V) at the optimal point P 1 of operation of the photovoltaic generator 2 are first determined.
- the point P 2 of operation of the water electrolyzer 4 is a point at which the operating current is 100 A and the operating voltage is 13.8 V.
- FIGS. 5 to 7 show a second embodiment of the present invention.
- a DC power source 6 is connected in series between a photovoltaic generator and a water electrolyzer 4 .
- the DC power source 6 has a function to add an external output to the maximum output from the photovoltaic generator 2 in order to provide a current and a voltage corresponding to the IV characteristic of the water electrolyzer 4 .
- a curve L 1 indicates an IV characteristic of the photovoltaic generator 2 at 80° C. (an insolation amount: 905 W/m 2 ), and a line L 2 indicates an output characteristic of the photovoltaic generator 2 .
- An optimal point of operation of the photovoltaic generator 2 is a point at which a relative output assumes a maximum value; an operating voltage is 13.3 V, and an operating current is 92 A (1224 W).
- a line L 3 indicates an IV characteristic of the water electrolyzer (number of water electrolytic cells: 7) 4
- a line L 4 indicates a power characteristic of the water electrolyzer 4 .
- a point of intersection between the line L 1 indicating the IV characteristic of the photovoltaic generator 2 and the line L 3 indicating the IV characteristic of the water electrolyzer 4 namely, a point of a lower current and higher voltage than those at the optimal point of operation, is a point P 2 of operation of the water electrolyzer 4 .
- the optimal point P 1 of operation when the optimal point P 1 of operation is shifted toward a higher voltage side in a state of a constant current (92 A), the optimal point P 1 is in accord with the line L 3 indicating the IV characteristic of the water electrolyzer 4 at a voltage of 15.6 V.
- a new optimal point P 3 of operation corresponding to such variation i.e., a point having an operating voltage of 15.6 V and an operating current of 92 A (1435 W) can be allowed to appear by adding an external output corresponding to such variation to the varied maximum output.
- Such optimal point P 3 can be matched with the IV characteristic of the water electrolyzer 4 and determined as a point of operation for the water electrolyzer 4 .
- the water electrolyzer 4 can be operated with a good efficiency by such peak power tracking.
- a power of 1435 W corresponding to the optimal point P 3 of operation in the water electrolyzer 4 is indicated by a point P 4 on the line L 4 .
- This power is a value provided by increasing, by 47%, a power of 976 W shown by a point P 5 on the line L 4 before addition of the external output in the water electrolyzer 4 .
- the details of the increase rate of 47% are as follows: If the maximum output from the photovoltaic generator 2 shown by a point P 6 on the line L 2 is 1223 W, a component A of the increase rate provided by a peak power tracking effect is 25.3%, and a component B provided by the external output is 21.7%. In this case, the efficiency is 94%.
- a DC power source 6 is connected in parallel between as a photovoltaic generator 2 and a water electrolyzer 4 . Even in example 2, a peak power tracking can be carried out.
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Abstract
A water electrolytic system includes a water electrolyzer, a photovoltaic generator which is a power source for the water electrolyzer, and a DC/DC converter adapted to convert the maximum output from the photovoltaic generator into a current and a voltage corresponding to an IV characteristic of the water electrolyzer by converting current and voltage for a portion of such maximum output, and to input the converted current and voltage to the water electrolyzer. With the water electrolytic system, even when an optimal point of operation of the photovoltaic generator, i.e., the maximum output from the photovoltaic generator has been varied, the efficient operation of the water electrolytic system can be carried out utilizing such maximum output.
Description
- 1. Field of the Invention
- The present invention relates to a water electrolytic system designed so that a water electrolyzer is operated by an output from a photovoltaic generator.
- 2. Description of the Related Art
- A photovoltaic generator has an optimal point of operation, namely, an operating current and an operating voltage at the time when the output from the photovoltaic generator assumes a maximum value. If the optimal point of operation is matched with an IV characteristic (I: current, V: voltage) of a water electrolyzer, the water electrolyzer can be operated with a good efficiency. However, the optimal point of operation is varied depending on the temperature of the photovoltaic generator, an insolation amount to the photovoltaic generator and the like and as a result, the optimal point of operation is not matched with the IV characteristic of the water electrolyzer. When the photovoltaic generator and the water electrolyzer have been connected in series to each other, namely, connected directly to each other, it is difficult to operate the water electrolytic system with a good efficiency at all times.
- Therefore, in order to ensure that even when the optimal point of operation of the photovoltaic generator, i.e., the maximum output from the photovoltaic generator, has been varied, the water electrolyzer is operated efficiently by utilizing such maximum output, a water electrolytic system has been developed (for example, see Japanese Patent Application Laid-open No. 7-233493), which includes a water electrolyzer, a photovoltaic generator, and a high-output type DC/DC converter adapted to convert all of the maximum output from the photovoltaic generator into a current and a voltage corresponding to an IV characteristic of the water electrolyzer to input them to the water electrolyzer.
- However, the high-output type DC/DC converter is large in size with a weight of about 60 kg and moreover, is of a high cost and has an efficiency of 80 to 90% and hence, a loss of 10 to 20% is produced. For this reason, the conventional system has a problem that it lacks in economy.
- Accordingly, it is an object of the present invention to provide an economical water electrolytic system designed so that even when the optimal point of operation of the photovoltaic generator, i.e., the maximum output from the photovoltaic generator has been varied, the water electrolyzer can be operated with a good efficiency by utilizing such maximum output.
- To achieve the above object, according to the present invention, there is provided a water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for the water electrolyzer, and a DC/DC converter adapted to convert the maximum output from the photovoltaic generator into a current and a voltage corresponding to an IV characteristic of the water electrolyzer by carrying out the conversion of current and voltage for a portion of the maximum output and to input the current and the voltage to the water electrolyzer.
- With such arrangement, when the maximum output from the photovoltaic generator has been varied, the water electrolyzer can be operated with a good efficiency by utilizing the varied maximum output. Moreover, the conversion of current and voltage is carried out for a portion of the maximum output from the photovoltaic generator by the DC/DC converter and hence, a loss in the entire system can be suppressed to a small level, and a low-output type of a DC/DC converter made in a small size and at a low cost can be employed, leading to an increase in economy.
- According to the present invention, there is provided a water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for the water electrolyzer, and a DC power source adapted to add an external output to the maximum output from the photovoltaic generator in order to provide a current and a voltage corresponding to an IV characteristic of the water electrolyzer.
- With such arrangement, when the maximum output from the photovoltaic generator has been varied, a new optimal point of operation corresponding to such variation can be allowed to appear by adding an external output corresponding to the variation to the varied maximum output, and can be matched with the IV characteristic of the water electrolyzer and determined as a point of operation for the water electrolyzer. Thus, the water electrolytic system can be operated with a good efficiency.
- The above and other objects, features and advantages of the invention will become apparent from the following description of the preferred embodiment taken in conjunction with the accompanying drawings.
- FIG. 1 is a graph showing a first example of an IV characteristic for a photovoltaic generator and a water electrolyzer;
- FIG. 2A is a diagram of an electric circuit of example 1 of a first embodiment of the present invention;
- FIG. 2B is an equivalent circuit of the electric circuit shown in FIG. 2A;
- FIG. 3 is a graph showing a second example of the IV characteristic for a photovoltaic generator and a water electrolyzer;
- FIG. 4A is a diagram of an electric circuit of example 2 of the first embodiment of the present invention;
- FIG. 4B is an equivalent circuit of the electric circuit shown in FIG. 4A;
- FIG. 5 is a diagram of an electric circuit of example 1 of a second embodiment of the present invention;
- FIG. 6 is a graph showing a third example of the IV characteristic for a photovoltaic generator and a water electrolyzer; and
- FIG. 7 is a diagram of an electric circuit of example 2 of the second embodiment.
- FIGS. 1 to 4B show a first embodiment of a water
electrolytic system 1. The first embodiment includes example 1 and example 2. FIGS. 1, 2A and 2B show example 1, and FIGS. 3, 4A and 4B show example 2. - In example 1, FIG. 1 shows a mode when the maximum output from a
photovoltaic generator 2 has been varied. A line L1 indicates an IV characteristic of thephotovoltaic generator 2 at 28° C. (an insolation amount: 1040 W/m2), and a line L2 indicates an output characteristic of thephotovoltaic generator 2. In this case, an optimal point P1 of operation of thephotovoltaic generator 2 is a point at which the output is a maximum value. Such maximum output Emax is 1506 W. On the other hand, a line L3 indicates an IV characteristic of a water electrolyzer (number of water electrolytic cells: 8) 4. When thephotovoltaic generator 2 and thewater electrolyzer 4 has been connected in series, a point of intersection between the line L1 indicating the IV characteristic of thephotovoltaic generator 2 and the line L3 indicating the IV characteristic of thewater electrolyzer 4 is a point P2 of operation of thewater electrolyzer 4. This point P2 of operation is at a location displaced from the optimal point P1 of operation of thephotovoltaic generator 2 toward a lower current and higher voltage side and hence, the highly efficient operation of the waterelectrolytic system 1 cannot be desired. - To deal with this, in example 1, a peak power tracking is carried out, which comprises controlling a low-output type DC/
DC converter 5, so that the operating current Imax at the optimal point P1 of operation of thephotovoltaic generator 2 is decreased, and the operating voltage Vmax is increased, measuring a current Imax−dI and a voltage Vmax+dV lying on the line L3 indicating the IV characteristic of thewater electrolyzer 4, and determining these current and voltage as an operating current and an operating voltage for thewater electrolyzer 4. - As in FIG. 2A, in example 1, the low-output type DC/
DC converter 5 is connected in series between thephotovoltaic generator 2 and thewater electrolyzer 4. The low-output type DC/DC converter 5 has a function to conduct the conversion of current and voltage for a portion of the maximum output from thephotovoltaic generator 2, thereby converting the maximum output into a current and a voltage corresponding to the IV characteristic of thewater electrolyzer 4 and inputting the current and the voltage to thewater electrolyzer 4, in order to carry out the peak power tracking. FIG. 2B shows an equivalent circuit shown in FIG. 2A. - To operate the
water electrolyzer 4 under a situation shown in FIG. 1, the operating current Imax (92.4 A) and the operating voltage Vmax (16.3 V) at the optimal point P1 of operation of thephotovoltaic generator 2 are first determined. When thephotovoltaic generator 2 and thewater electrolyzer 4 have been connected in series to each other, the point P2 of operation of thewater electrolyzer 4 is a point at which the operating current is 80 A and the operating voltage is 17.8 V. - When the low-output type DC/
DC converter 5 is then operated to decrease the resistance value of a variable resistor R, as shown in FIG. 2B, a current dI flows. Therefore, the current to thewater electrolyzer 4 is decreased into Imax−dI, while the voltage is increased into Vmax+dV. This is continued to measure a current Imax−dI (73.5 A) and a voltage Vmax+dV (17.7 V) lying on the line L3 indicating the IV characteristic of thewater electrolyzer 4. A point P3 having these current and voltage is determined as a point of operation of thewater electrolyzer 4. - Namely, an output of (Vmax+dV).(Imax−dI) is supplied from the
photovoltaic generator 2 to thewater electrolyzer 4. In this case, a portion Vmax.dI of the maximum output Imax.Vmax from thephotovoltaic generator 2 has been converted into (Imax−dI).dV at the supplied output (Vmax+dV).(Imax−dI), wherein (Imax−dI).dV is a value resulting from the subtraction of a loss due to the conversion from Vmax.dI. In this case, the weight of the low-output type DC/DC converter 5 was about 8 kg, which is about 13% of the weight of a high-output type DC/DC converter, and the efficiency was equal to or higher than 94%. - In example 2, FIG. 3 shows a mode when the maximum output from the
photovoltaic generator 2 has been varied. A line L1 indicates an IV characteristic of thephotovoltaic generator 2 at 28° C. (an insolation amount: 1040 W/m2), and a line L2 indicates an output characteristic of thephotovoltaic generator 2, as in example 1. In this case, In this case, an optimal point P1 of operation of thephotovoltaic generator 2 is a point at which the output is a maximum value. Such maximum output Emax is 1506 W. On the other hand, a line L3 indicates an IV characteristic of a water electrolyzer (number of water electrolytic cells: 6) 4. - When the
photovoltaic generator 2 and thewater electrolyzer 4 has been connected in series, a point of intersection between the line L1 indicating the IV characteristic of thephotovoltaic generator 2 and the line L3 indicating the IV characteristic of the water-electrolyzingdevice 4 is a point P2 of operation of thewater electrolyzer 4. This point P2 of operation is at a location displaced from the optimal point P1 of operation of thephotovoltaic generator 2 toward a higher current and lower voltage side and hence, the highly efficient operation of the waterelectrolytic system 1 cannot be desired. - To deal with this, in example 2, a peak power tracking is carried out, which comprises controlling a low-output type DC/
DC converter 5, so that the operating current Imax at the optimal point P1 of operation of thephotovoltaic generator 2 is increased, and the operating voltage Vmax is decreased, measuring a current Imax+dI and a voltage Vmax−dV lying on the line L3 indicating the IV characteristic of thewater electrolyzer 4, and determining these current and voltage as an operating current and an operating voltage for thewater electrolyzer 4. - As in FIG. 4A, in example 2, the low-output type DC/
DC converter 5 is connected in parallel between thephotovoltaic generator 2 and thewater electrolyzer 4. The low-output type DC/DC converter 5 has a function to conduct the conversion of current and voltage for a portion of the maximum output from thephotovoltaic generator 2, thereby converting the maximum output into a current and a voltage corresponding to the IV characteristic of thewater electrolyzer 4 and inputting the current and the voltage to thewater electrolyzer 4, in order to carry out the peak power tracking. FIG. 4B shows an equivalent circuit shown in FIG. 4A. - To operate the
water electrolyzer 4 under a situation shown in FIG. 3, the operating current Imax (92.4 A) and the operating voltage Vmax (16.3 V) at the optimal point P1 of operation of thephotovoltaic generator 2 are first determined. When thephotovoltaic generator 2 and thewater electrolyzer 4 have been connected in series to each other, the point P2 of operation of thewater electrolyzer 4 is a point at which the operating current is 100 A and the operating voltage is 13.8 V. - When the low-output type DC/
DC converter 5 is then operated to increase the resistance value of a variable resistor R, as shown in FIG. 2B, a current dI flows. Therefore, the current to thewater electrolyzer 4 is decreased into Imax+dI, while the voltage is increased into Vmax−dV. This is continued to measure a current Imax+dI (108.2 A) and a voltage Vmax−dV (13.9 V) lying on the line L3 indicating the IV characteristic of thewater electrolyzer 4. A point P3 having these current and voltage is determined as a point of operation of thewater electrolyzer 4. - Namely, an output of (Vmax−dV).(Imax+dI) is supplied from the
photovoltaic generator 2 to thewater electrolyzer 4. In this case, a portion Imax.dV of the maximum output Imax.Vmax from thephotovoltaic generator 2 has been converted into (Vmax−dV).dI at the supplied output (Vmax−dV).(Imax+dI), wherein (Vmax−dV).dI is a value resulting from the subtraction of a loss due to the conversion from Imax.dV. - FIGS. 5 to 7 show a second embodiment of the present invention. In example 1 of the second embodiment shown in FIG. 5, a
DC power source 6 is connected in series between a photovoltaic generator and awater electrolyzer 4. TheDC power source 6 has a function to add an external output to the maximum output from thephotovoltaic generator 2 in order to provide a current and a voltage corresponding to the IV characteristic of thewater electrolyzer 4. - In FIG. 6, a curve L 1 indicates an IV characteristic of the
photovoltaic generator 2 at 80° C. (an insolation amount: 905 W/m2), and a line L2 indicates an output characteristic of thephotovoltaic generator 2. An optimal point of operation of thephotovoltaic generator 2 is a point at which a relative output assumes a maximum value; an operating voltage is 13.3 V, and an operating current is 92 A (1224 W). On the other hand, a line L3 indicates an IV characteristic of the water electrolyzer (number of water electrolytic cells: 7) 4, and a line L4 indicates a power characteristic of thewater electrolyzer 4. - When the
photovoltaic generator 2 and thewater electrolyzer 4 have been connected in sires to each other, a point of intersection between the line L1 indicating the IV characteristic of thephotovoltaic generator 2 and the line L3 indicating the IV characteristic of thewater electrolyzer 4, namely, a point of a lower current and higher voltage than those at the optimal point of operation, is a point P2 of operation of thewater electrolyzer 4. - Therefore, when the optimal point P 1 of operation is shifted toward a higher voltage side in a state of a constant current (92 A), the optimal point P1 is in accord with the line L3 indicating the IV characteristic of the
water electrolyzer 4 at a voltage of 15.6 V. An operating voltage at the optimal point P1 of operation is 13.3 V, and 15.6 V−13.3 V=2.3 V. Therefore, when an external output of 2.3 V from theDC power source 6 is added to the IV characteristic of thephotovoltaic generator 2, a secondary IV characteristic provided by cooperation of thephotovoltaic generator 2 and theDC power source 6 with each other is as indicated by a line L5 shown by a dotted line, and a new optimal point of operation in such IV characteristic is a point of operation of thewater electrolyzer 4. - When the maximum output from the
photovoltaic generator 2 has been varied, as described above, a new optimal point P3 of operation corresponding to such variation, i.e., a point having an operating voltage of 15.6 V and an operating current of 92 A (1435 W) can be allowed to appear by adding an external output corresponding to such variation to the varied maximum output. Such optimal point P3 can be matched with the IV characteristic of thewater electrolyzer 4 and determined as a point of operation for thewater electrolyzer 4. Thewater electrolyzer 4 can be operated with a good efficiency by such peak power tracking. - In this case, a power of 1435 W corresponding to the optimal point P 3 of operation in the
water electrolyzer 4 is indicated by a point P4 on the line L4. This power is a value provided by increasing, by 47%, a power of 976 W shown by a point P5 on the line L4 before addition of the external output in thewater electrolyzer 4. The details of the increase rate of 47% are as follows: If the maximum output from thephotovoltaic generator 2 shown by a point P6 on the line L2 is 1223 W, a component A of the increase rate provided by a peak power tracking effect is 25.3%, and a component B provided by the external output is 21.7%. In this case, the efficiency is 94%. - In example 2 of the second embodiment shown in FIG. 7, a
DC power source 6 is connected in parallel between as aphotovoltaic generator 2 and awater electrolyzer 4. Even in example 2, a peak power tracking can be carried out.
Claims (2)
1. A water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for said water electrolyzer, and a DC/DC converter adapted to convert the maximum output from said photovoltaic generator into a current and a voltage corresponding to an IV characteristic of said water electrolyzer by converting current and voltage for a portion of said maximum output, and to input the converted current and voltage to said water electrolyzer.
2. A water electrolytic system comprising a water electrolyzer, a photovoltaic generator which is a power source for said water electrolyzer, and a DC power source adapted to add an external output to the maximum output from said photovoltaic generator in order to provide a current and a voltage corresponding to an IV characteristic of said water electrolyzer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000-285222 | 2000-09-14 | ||
| JP2000285222A JP2002088493A (en) | 2000-09-14 | 2000-09-14 | Water electrolysis system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20020033332A1 true US20020033332A1 (en) | 2002-03-21 |
Family
ID=18769327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/950,825 Abandoned US20020033332A1 (en) | 2000-09-14 | 2001-09-13 | Water Electrolytic system |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US20020033332A1 (en) |
| JP (1) | JP2002088493A (en) |
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| US20100114395A1 (en) * | 2008-10-30 | 2010-05-06 | Next Hydrogen Corporation | Power dispatch system for electrolytic production of hydrogen from wind power |
| WO2010069622A1 (en) * | 2008-12-18 | 2010-06-24 | Silicon Fire Ag | Method and plant for providing an energy carrier using carbon dioxide as a carbon supplier and using electricity |
| WO2011018124A1 (en) * | 2009-08-13 | 2011-02-17 | Silicon Fire Ag | Method and system for providing a hydrocarbon-based energy source using a portion of renewably produced methanol and a portion of methanol that is produced by means of direct oxidation, partial oxidation, or reforming |
| US20120175271A1 (en) * | 2009-09-18 | 2012-07-12 | Martin Alexander Goldmaier | Device for disinfecting water by means of anodic oxidation |
| CN104630815A (en) * | 2015-01-29 | 2015-05-20 | 湖北民族学院 | Photovoltaic hydrogen production system |
| US9133553B2 (en) | 2012-09-13 | 2015-09-15 | Next Hydrogen Corporation | Externally-reinforced water electrolyzer module |
| US9187833B2 (en) | 2012-09-13 | 2015-11-17 | Next Hydrogen Corporation | Internally-reinforced water electrolyser module |
| EP3533905A1 (en) * | 2018-03-01 | 2019-09-04 | Shell Internationale Research Maatschappij B.V. | Method of configuring a water electrolysis system |
| CN112226787A (en) * | 2020-10-21 | 2021-01-15 | 阳光电源股份有限公司 | Control method, device and system for startup and shutdown of hydrogen production system and storage medium |
| US20220389595A1 (en) * | 2021-06-03 | 2022-12-08 | Analog Devices, Inc. | Electrolyzer system converter arrangement |
| WO2026008367A1 (en) * | 2024-07-03 | 2026-01-08 | Aker Solutions As | Offshore hydrogen production systems and methods |
-
2000
- 2000-09-14 JP JP2000285222A patent/JP2002088493A/en active Pending
-
2001
- 2001-09-13 US US09/950,825 patent/US20020033332A1/en not_active Abandoned
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| US9249518B2 (en) | 2008-10-30 | 2016-02-02 | Next Hydrogen Corporation | Power dispatch system for electrolytic production of hydrogen from wind power |
| US20100114395A1 (en) * | 2008-10-30 | 2010-05-06 | Next Hydrogen Corporation | Power dispatch system for electrolytic production of hydrogen from wind power |
| US8288888B2 (en) * | 2008-10-30 | 2012-10-16 | Next Hydrogen Corporation | Power dispatch system for electrolytic production of hydrogen from wind power |
| US9303325B2 (en) | 2008-10-30 | 2016-04-05 | Next Hydrogen Corporation | Power dispatch system for electrolytic production of hydrogen from wind power |
| WO2010069622A1 (en) * | 2008-12-18 | 2010-06-24 | Silicon Fire Ag | Method and plant for providing an energy carrier using carbon dioxide as a carbon supplier and using electricity |
| EP2647596A3 (en) * | 2008-12-18 | 2014-08-27 | Silicon Fire AG | Method and apparatus for providing an energy source using carbon dioxide as a carbon source, and electric power |
| US9631287B2 (en) | 2008-12-18 | 2017-04-25 | Silicon Fire Ag | Method and facility system for providing an energy carrier by application of carbon dioxide as a carbon supplier of electric energy |
| WO2011018124A1 (en) * | 2009-08-13 | 2011-02-17 | Silicon Fire Ag | Method and system for providing a hydrocarbon-based energy source using a portion of renewably produced methanol and a portion of methanol that is produced by means of direct oxidation, partial oxidation, or reforming |
| US9701550B2 (en) * | 2009-09-18 | 2017-07-11 | Autarcon Gmbh | Device for disinfecting water by means of anodic oxidation |
| US20120175271A1 (en) * | 2009-09-18 | 2012-07-12 | Martin Alexander Goldmaier | Device for disinfecting water by means of anodic oxidation |
| US9187833B2 (en) | 2012-09-13 | 2015-11-17 | Next Hydrogen Corporation | Internally-reinforced water electrolyser module |
| US9133553B2 (en) | 2012-09-13 | 2015-09-15 | Next Hydrogen Corporation | Externally-reinforced water electrolyzer module |
| CN104630815A (en) * | 2015-01-29 | 2015-05-20 | 湖北民族学院 | Photovoltaic hydrogen production system |
| EP3533905A1 (en) * | 2018-03-01 | 2019-09-04 | Shell Internationale Research Maatschappij B.V. | Method of configuring a water electrolysis system |
| WO2019166539A1 (en) * | 2018-03-01 | 2019-09-06 | Shell Internationale Research Maatschappij B.V. | Method of configuring a water electrolysis system |
| CN112226787A (en) * | 2020-10-21 | 2021-01-15 | 阳光电源股份有限公司 | Control method, device and system for startup and shutdown of hydrogen production system and storage medium |
| US20220389595A1 (en) * | 2021-06-03 | 2022-12-08 | Analog Devices, Inc. | Electrolyzer system converter arrangement |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2002088493A (en) | 2002-03-27 |
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