[go: up one dir, main page]

US20010036447A1 - Cosmetic composition having fluorosilane coated particulates - Google Patents

Cosmetic composition having fluorosilane coated particulates Download PDF

Info

Publication number
US20010036447A1
US20010036447A1 US09/467,442 US46744299A US2001036447A1 US 20010036447 A1 US20010036447 A1 US 20010036447A1 US 46744299 A US46744299 A US 46744299A US 2001036447 A1 US2001036447 A1 US 2001036447A1
Authority
US
United States
Prior art keywords
cosmetic composition
fluorosilane
cosmetic
composition according
person
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US09/467,442
Other versions
US6315990B1 (en
Inventor
Alan Farer
Shari R. Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avon Products Inc
Original Assignee
Avon Products Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avon Products Inc filed Critical Avon Products Inc
Assigned to AVON PRODUCTS, INC. reassignment AVON PRODUCTS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FARER, ALAN, MARTIN, SHARI R.
Priority to US09/467,442 priority Critical patent/US6315990B1/en
Priority to PCT/US2000/028338 priority patent/WO2001045643A1/en
Priority to JP2001546384A priority patent/JP2003518024A/en
Priority to EP00970876A priority patent/EP1239810A4/en
Priority to AU80194/00A priority patent/AU8019400A/en
Publication of US20010036447A1 publication Critical patent/US20010036447A1/en
Publication of US6315990B1 publication Critical patent/US6315990B1/en
Application granted granted Critical
Assigned to CITIBANK, N.A. reassignment CITIBANK, N.A. SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AVON PRODUCTS, INC.
Assigned to AVON PRODUCTS, INC. reassignment AVON PRODUCTS, INC. RELEASE OF SECURITY INTEREST IN PATENTS Assignors: CITIBANK, N.A.
Assigned to CITIBANK, N.A., LONDON BRANCH reassignment CITIBANK, N.A., LONDON BRANCH SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AVON PRODUCTS, INC.
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/04—Compounds of zinc
    • C09C1/043—Zinc oxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/22—Compounds of iron
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/3081—Treatment with organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3684—Treatment with organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating

Definitions

  • the present invention relates to cosmetic compositions. More particularly, the present invention relates to cosmetic compositions having fluorosilane-coated particulates.
  • the cosmetic composition may be a blush, a concealer, an eye shadow, a lipstick, a lip liner, an eye liner, a liquid or cream compact make-up, a mascara, a moisturizer, a face powder or pressed powder. It is believed that the particulates coated with fluorosilane according to the present invention can be incorporated into any composition intended for any cosmetic use.
  • the present invention further relates to methods of reducing (a) color drift in a pigmented cosmetic, especially a pigmented face powder or blush cosmetic during wear; (b) staining potential of a lipstick on a person; and (c) oil breakthrough in facial products.
  • the present invention also relates to methods of improving or increasing (a) comfort of cosmetic products; and (b) water resistance in cosmetic products, especially in a mascara. cosmetic products; and (b) water resistance in cosmetic products, especially in a mascara.
  • U.S. Pat. No. 5,482,547 to Bugnon et al. is directed to a paint or varnish containing an organic pigment coated with a silicate.
  • Japan Patent No. 7053326 is directed to a makeup cosmetic material that contains modified powder prepared by coating powder with methylhydrogensiloxane and heat-treating and blending modified powder coated with a fluorine containing compound.
  • Fluorosilanes have been used in construction and for coating glass.
  • tridecafluorooctyltriethoxy silane-coated cosmetic pigments are not known.
  • Some cosmetic products suffer from stability problems that lead to an aesthetically unattractive appearance. These problems include settling, migration and floatation of colorants in nail enamel, color drift in a face powder or blush cosmetic during wear, oil breakthrough in facial products, and staining of a lipstick on a person.
  • the present invention provides cosmetic compositions that employ particulates, such as pigments, that are coated with fluorosilane.
  • compositions of the present invention are stable for an extended period of time, and have enhanced wear resistance due to the oil and water resistant nature of the fluorosilane coated cosmetic particulates.
  • the compositions of the present invention will not be affected by moisture or oil from the skin, they will not intensify the color of the product (known as “blooming” of the product). Accordingly, truer color of the product is maintained.
  • the present invention provides cosmetic compositions having particulates or particulate material coated with fluorosilane.
  • fluorosilane in the present invention refers to a silicon-containing compound having a hydrocarbyl group substituted by at least one fluorine atom and a reactive hydrocarbyloxy group capable of displacement by a nucleophile.
  • hydrocarbyl in the present invention refers to a linear, branched and cyclic group containing carbon and hydrogen such as an alkane, an alkene, an alkyne and an aryl group.
  • the hydrocarbyl group may be additionally interrupted and/or substituted by one or more of the following: a halogen, a cyano, a keto, an ester, hydroxyl, carboxyl, oxygen, sulfur, or nitrogen.
  • perfluro hydrocarbyl in the present invention refers to a fully fluorinated hydrocarbyl group.
  • the fluorosilane is represented by the formula:
  • R f is a C 4 -C 16 hydrocarbyl group having at least one fluorine atom, and wherein R is a C 1 -C 6 hydrocarbyl group.
  • the preferred fluorosilane is represented by the formula:
  • R f ′ is a C 4 -C 14 perfluoro hydrocarbyl group, and wherein R is methyl or ethyl.
  • Tridecafluorooctyltriethoxy silane is available from Sivento, Piscataway, N.J., under the trade name DYNASILANE® F 8261.
  • the particulates coated with fluorosilane according to the present invention can be organic pigments, inorganic pigments, organic fillers, inorganic fillers, or any combination thereof.
  • Examples of the organic particulate pigments include azo, xanthene, quinone, lakes, especially aluminum lakes, strontium lakes, barium lakes, FD&C and D&C Red 6, Red 7, Red 30, Red 34, Yellow 5, Blue 1, or derivatives thereof, or mixtures thereof.
  • Examples of the inorganic particulate pigments are iron oxide, especially red, yellow and black iron oxides, titanium dioxide, zinc oxide, potassium ferricyanide (K 3 Fe(CN) 6 ), potassium ferrocyanide (K 4 Fe(CN) 6 ), potassium ferrocyanide trihydrate (K 4 Fe(CN) 6 . 3H 2 O), and mixtures thereof.
  • Examples of the organic fillers include starch.
  • Examples of the inorganic fillers include talc, mica, silica, and mixtures thereof.
  • a preferred tridecafluorooctyltriethoxy silane-coated pigment includes tridecafluorooctyltriethoxy silane-coated black ore iron oxide, and tridecafluorooctyltriethoxy silane-coated red iron oxide.
  • Tridecafluorooctyltriethoxy silane-coated red iron oxide (Fe 2 O 3 ) is available from Cardre Pigment Technologies, Inc., South Plainfield, N.J.
  • the amount of fluorosilane is about 0.01 percentage by weight (wt %) to about 5 wt %, and the amount of particulates is about 95 wt % to about 99.99 wt %, of the total weight of the fluorosilane coated particulate.
  • the amount of fluorosilane is about 2 wt %, and the amount of particulates is about 98 wt % of the total weight of the fluorosilane coated particulate.
  • the particulates coated with fluorosilane are about 0.1 wt % to about 40 wt % of the total weight of the composition.
  • the particulate coated with fluorosilane is about 1 wt % to about 25 wt % of the total weight of the composition.
  • the fluorosilane is about 0.0005 wt % to about 1.5 wt % of the total weight of the cosmetic composition
  • the amount of fluorosilane varies within the range depending upon its intended product.
  • the fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight in a pressed face powder or blush.
  • the fluorosilane is about 0.01 wt % to about 0.5 wt % of the total weight in a mascara.
  • the fluorosilane is about 0.0015 wt % to about 0.30 wt % of the total weight of the composition in a lip product.
  • the fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight of the composition in an eye shadow.
  • a cosmetic composition of the present invention can be an unpigmented cosmetic composition having fluorosilane coated particulates.
  • Such unpigmented compositions include, for example, a skin treatment product, and a sunscreen.
  • the fluorosilane is about 0.01 wt % to about 0.50 wt % of the total weight of the unpigmented composition.
  • fluorine-treated particulates do not dissolve or disperse in water, hydrocarbon solvents or common organic solvents. Fluorosilanes are also insoluble in water and have limited solubility in hydrocarbon and other common organic solvents, but can be dispersed in ethanol. It has been surprisingly found that fluorosilane-containing water-based compositions can be easily prepared according to the present invention.
  • the lipsticks of the present invention can be prepared by dispersing particulate material coated with fluorosilane, such as pigments and/or fillers coated with fluorosilane, into a slurry. Thereafter, the slurry is added to a lipstick formulation.
  • the organic pigments such as common organic colorants
  • the organic pigment interacts with the moisture on the lips. Such interaction causes staining and dries the lips.
  • coating organic pigments with fluorosilane in a lipstick formulation produces a lipstick with reduced staining potential and improved moisturization.
  • the water repellent nature of the fluorosilane coating prevents and protects the pigments from interacting with moisture.
  • the lipstick of the present invention minimizes the staining of the lips and results in a greater amount of moisture being bound to the lips.
  • the lipstick of the present invention also has improved wear, moisturization, and reduced color drift.
  • a blush or face powder of the present invention can be prepared by coating pigment and/or filler particulates with fluorosilane in such powders and thereafter mixing together these ingredients to obtain a uniform composition.
  • the resulting blush or face powder has enhanced wear resistance.
  • Such powders during wear display enhanced water proofing and reduced color drift, which is otherwise caused by the blooming of shade during the day due to its interaction with skin lipids and with skin moisture vapor.
  • the blush or face powder formulations will preferably have filler particulates as well coated with fluorosilane.
  • the amount of pigments coated with fluorosilane are about 1 wt % to about 15 wt % of the total weight of the composition. As stated before, the amount of fluorosilane is about 0.01 wt % to about 1.5 wt %.
  • a moisturizer of the present invention can be prepared by dispersing particulates, such as pigments and/or fillers, coated with fluorosilane into a slurry and thereafter adding the slurry to a moisturizer formulation.
  • the coated particulates of the present invention when added to the moisturizer vehicle causes the formation of an oil and water repellent film, which produces a moisturizer that displays reduced oil breakthrough.
  • the most commonly used particulates in this case are talc, mica, silica, iron oxides and titanium dioxide.
  • fluorosilane coated particulates such as pigments, fillers or a combination of pigments and fillers, of the present invention in a cosmetic composition improve wear resistance and water proofing properties of blush, powder and lip cosmetics. In a face powder, it improves the color drift over time.
  • the cosmetic compositions can also include one or more of the following: a chelating agent, an emollient, an emulsifier, a film former, a fragrance, a humectant, a plasticizer, a preservative, a resin, a retinoid, a skin penetration enhancer, a solvent, a stabilizer, a sunscreen, a surfactant, a thickener, a vitamin and a wax.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

A cosmetic composition having particulates coated with fluorosilane, such as a pigment and/or filler coated with fluorosilane is provided. The cosmetic composition can be a blush, a concealer, an eye shadow, a lipstick, a liquid make-up, a mascara, a moisturizer, or a powder. The present invention also provides methods of (a) reducing staining potential of a lipstick on a person, (b) improving water and/or oil resistance in cosmetic compositions, especially in a mascara, (c) reducing oil breakthrough in a facial product, and (d) reducing color drift in a powder cosmetic during wear.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention relates to cosmetic compositions. More particularly, the present invention relates to cosmetic compositions having fluorosilane-coated particulates. The cosmetic composition may be a blush, a concealer, an eye shadow, a lipstick, a lip liner, an eye liner, a liquid or cream compact make-up, a mascara, a moisturizer, a face powder or pressed powder. It is believed that the particulates coated with fluorosilane according to the present invention can be incorporated into any composition intended for any cosmetic use. [0002]
  • The present invention further relates to methods of reducing (a) color drift in a pigmented cosmetic, especially a pigmented face powder or blush cosmetic during wear; (b) staining potential of a lipstick on a person; and (c) oil breakthrough in facial products. The present invention also relates to methods of improving or increasing (a) comfort of cosmetic products; and (b) water resistance in cosmetic products, especially in a mascara. cosmetic products; and (b) water resistance in cosmetic products, especially in a mascara. [0003]
  • 2. Description of the Prior Art [0004]
  • U.S. Pat. No. 5,482,547 to Bugnon et al. is directed to a paint or varnish containing an organic pigment coated with a silicate. [0005]
  • Japan Patent No. 7053326 is directed to a makeup cosmetic material that contains modified powder prepared by coating powder with methylhydrogensiloxane and heat-treating and blending modified powder coated with a fluorine containing compound. [0006]
  • Fluorosilanes have been used in construction and for coating glass. However, heretofore, tridecafluorooctyltriethoxy silane-coated cosmetic pigments are not known. [0007]
  • Some cosmetic products, particularly cosmetic products having colored compositions, suffer from stability problems that lead to an aesthetically unattractive appearance. These problems include settling, migration and floatation of colorants in nail enamel, color drift in a face powder or blush cosmetic during wear, oil breakthrough in facial products, and staining of a lipstick on a person. [0008]
  • Despite the continuous efforts of the cosmetic industry to develop cosmetic compositions that are more stable and aesthetically pleasing under normal use conditions, the appearance of a cosmetic after application deteriorates rapidly leading to an aesthetically unattractive appearance of the wearer of the cosmetic. [0009]
  • To overcome the instability problem of certain cosmetics and to minimize or eliminate the aesthetic deterioration of certain cosmetics during normal use, the present invention provides cosmetic compositions that employ particulates, such as pigments, that are coated with fluorosilane. [0010]
  • The compositions of the present invention are stable for an extended period of time, and have enhanced wear resistance due to the oil and water resistant nature of the fluorosilane coated cosmetic particulates. Thus, since the compositions of the present invention will not be affected by moisture or oil from the skin, they will not intensify the color of the product (known as “blooming” of the product). Accordingly, truer color of the product is maintained. [0011]
    • SUMMARY OF THE INVENTION
  • It is an object of the present invention to provide cosmetic compositions having particulates, at least some of which, and preferably most of which, are coated with fluorosilane. [0012]
  • It is another object of the present invention to provide such cosmetic compositions that can be a blush, a concealer, an eye shadow, a lipstick, a liquid or cream compact make-up, a mascara, a moisturizer, or a powder, such as a face powder or a pressed powder. [0013]
  • It is still another object of the present invention to provide a method of reducing color drift in cosmetic compositions, such as a liquid or cream compact make-up or a face or blush powder, during wear. [0014]
  • It is a further object of the present invention to provide a method of reducing staining potential of a lipstick on a person. [0015]
  • It is still a further object of the present invention to provide a method of improving or increasing water resistance in cosmetic compositions, especially a mascara.[0016]
    • DETAILED DESCRIPTION OF THE INVENTION
  • The present invention provides cosmetic compositions having particulates or particulate material coated with fluorosilane. [0017]
  • The term “fluorosilane” in the present invention refers to a silicon-containing compound having a hydrocarbyl group substituted by at least one fluorine atom and a reactive hydrocarbyloxy group capable of displacement by a nucleophile. [0018]
  • The term “hydrocarbyl” in the present invention refers to a linear, branched and cyclic group containing carbon and hydrogen such as an alkane, an alkene, an alkyne and an aryl group. The hydrocarbyl group may be additionally interrupted and/or substituted by one or more of the following: a halogen, a cyano, a keto, an ester, hydroxyl, carboxyl, oxygen, sulfur, or nitrogen. [0019]
  • The term “perfluro hydrocarbyl” in the present invention refers to a fully fluorinated hydrocarbyl group. [0020]
  • The fluorosilane is represented by the formula:[0021]
  • RfSi (OR)3
  • wherein R[0022] f is a C4-C16 hydrocarbyl group having at least one fluorine atom, and wherein R is a C1-C6hydrocarbyl group.
  • The preferred fluorosilane is represented by the formula:[0023]
  • Rf′CH2CH2Si (OR)3
  • wherein R[0024] f′ is a C4-C14 perfluoro hydrocarbyl group, and wherein R is methyl or ethyl.
  • An example of the preferred fluorosilane is tridecafluorooctyltriethoxy silane represented by the formula:[0025]
  • CF3CF2CF2CF2CF2CF2CH2CH2Si (OCH2CH3)3
  • Tridecafluorooctyltriethoxy silane is available from Sivento, Piscataway, N.J., under the trade name DYNASILANE® F 8261. [0026]
  • The particulates coated with fluorosilane according to the present invention can be organic pigments, inorganic pigments, organic fillers, inorganic fillers, or any combination thereof. [0027]
  • Examples of the organic particulate pigments include azo, xanthene, quinone, lakes, especially aluminum lakes, strontium lakes, barium lakes, FD&C and D&C Red 6, Red 7, Red 30, Red 34, Yellow 5, Blue 1, or derivatives thereof, or mixtures thereof. Examples of the inorganic particulate pigments are iron oxide, especially red, yellow and black iron oxides, titanium dioxide, zinc oxide, potassium ferricyanide (K[0028] 3Fe(CN)6), potassium ferrocyanide (K4Fe(CN)6), potassium ferrocyanide trihydrate (K4Fe(CN)6. 3H2O), and mixtures thereof. Examples of the organic fillers include starch. Examples of the inorganic fillers include talc, mica, silica, and mixtures thereof.
  • A preferred tridecafluorooctyltriethoxy silane-coated pigment includes tridecafluorooctyltriethoxy silane-coated black ore iron oxide, and tridecafluorooctyltriethoxy silane-coated red iron oxide. Tridecafluorooctyltriethoxy silane-coated red iron oxide (Fe[0029] 2O3) is available from Cardre Pigment Technologies, Inc., South Plainfield, N.J.
  • The amount of fluorosilane is about 0.01 percentage by weight (wt %) to about 5 wt %, and the amount of particulates is about 95 wt % to about 99.99 wt %, of the total weight of the fluorosilane coated particulate. Preferably, the amount of fluorosilane is about 2 wt %, and the amount of particulates is about 98 wt % of the total weight of the fluorosilane coated particulate. [0030]
  • The particulates coated with fluorosilane are about 0.1 wt % to about 40 wt % of the total weight of the composition. Preferably, the particulate coated with fluorosilane is about 1 wt % to about 25 wt % of the total weight of the composition. [0031]
  • While, in general, the fluorosilane is about 0.0005 wt % to about 1.5 wt % of the total weight of the cosmetic composition, the amount of fluorosilane varies within the range depending upon its intended product. For example, the fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight in a pressed face powder or blush. The fluorosilane is about 0.01 wt % to about 0.5 wt % of the total weight in a mascara. The fluorosilane is about 0.0015 wt % to about 0.30 wt % of the total weight of the composition in a lip product. It is about 0.01 wt % to about 0.5 wt % of the total weight in a liquid make-up. The fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight of the composition in an eye shadow. [0032]
  • A cosmetic composition of the present invention can be an unpigmented cosmetic composition having fluorosilane coated particulates. Such unpigmented compositions include, for example, a skin treatment product, and a sunscreen. In such cases, the fluorosilane is about 0.01 wt % to about 0.50 wt % of the total weight of the unpigmented composition. [0033]
  • In general, fluorine-treated particulates do not dissolve or disperse in water, hydrocarbon solvents or common organic solvents. Fluorosilanes are also insoluble in water and have limited solubility in hydrocarbon and other common organic solvents, but can be dispersed in ethanol. It has been surprisingly found that fluorosilane-containing water-based compositions can be easily prepared according to the present invention. For example, the lipsticks of the present invention can be prepared by dispersing particulate material coated with fluorosilane, such as pigments and/or fillers coated with fluorosilane, into a slurry. Thereafter, the slurry is added to a lipstick formulation. [0034]
  • Ordinarily, when organic pigments, such as common organic colorants, are used in a lipstick formulation, the organic pigment interacts with the moisture on the lips. Such interaction causes staining and dries the lips. According to the present invention, coating organic pigments with fluorosilane in a lipstick formulation produces a lipstick with reduced staining potential and improved moisturization. Specifically, the water repellent nature of the fluorosilane coating prevents and protects the pigments from interacting with moisture. Thus, the lipstick of the present invention minimizes the staining of the lips and results in a greater amount of moisture being bound to the lips. In addition to water proofing properties, the lipstick of the present invention also has improved wear, moisturization, and reduced color drift. [0035]
  • A blush or face powder of the present invention can be prepared by coating pigment and/or filler particulates with fluorosilane in such powders and thereafter mixing together these ingredients to obtain a uniform composition. The resulting blush or face powder has enhanced wear resistance. Such powders during wear display enhanced water proofing and reduced color drift, which is otherwise caused by the blooming of shade during the day due to its interaction with skin lipids and with skin moisture vapor. In addition to the coated pigments, the blush or face powder formulations will preferably have filler particulates as well coated with fluorosilane. [0036]
  • In a blush or a face powder composition, the amount of pigments coated with fluorosilane are about 1 wt % to about 15 wt % of the total weight of the composition. As stated before, the amount of fluorosilane is about 0.01 wt % to about 1.5 wt %. [0037]
  • A moisturizer of the present invention can be prepared by dispersing particulates, such as pigments and/or fillers, coated with fluorosilane into a slurry and thereafter adding the slurry to a moisturizer formulation. The coated particulates of the present invention when added to the moisturizer vehicle causes the formation of an oil and water repellent film, which produces a moisturizer that displays reduced oil breakthrough. The most commonly used particulates in this case are talc, mica, silica, iron oxides and titanium dioxide. To achieve these benefits, about 3 wt % to about 20 wt %, based on the total weight of the composition, of the fluorosilane-coated particulates are in the moisturizer composition, with the fluorosilane being about 0.05 wt % to about 0.5 wt %. [0038]
  • Thus, fluorosilane coated particulates, such as pigments, fillers or a combination of pigments and fillers, of the present invention in a cosmetic composition improve wear resistance and water proofing properties of blush, powder and lip cosmetics. In a face powder, it improves the color drift over time. [0039]
  • In addition to the coated particulates, the cosmetic compositions can also include one or more of the following: a chelating agent, an emollient, an emulsifier, a film former, a fragrance, a humectant, a plasticizer, a preservative, a resin, a retinoid, a skin penetration enhancer, a solvent, a stabilizer, a sunscreen, a surfactant, a thickener, a vitamin and a wax. [0040]
  • The present invention has been described with particular reference to the preferred embodiments thereof. It will be obvious that variations and modifications may be made therein without departing from the spirit and scope of the present invention as defined by the following claims. Also, singular used in the application can also mean plural of the same ingredient unless otherwise indicated. Also, improving means increasing unless otherwise indicated. [0041]

Claims (20)

Wherefore we claim:
1. A cosmetic composition comprising a plurality of particulates, at least some of which are coated with fluorosilane.
2. The cosmetic composition according to
claim 1
, wherein said fluorosilane is represented by the formula:
RISi (OR)3
wherein Rf is a C4-C16 hydrocarbyl having at least one fluorine atom and R is a C1-C6 a hydrocarbyl.
3. The cosmetic composition according to
claim 2
, wherein said fluorosilane is represented by the formula:
Rf′CH2CH2Si (OR)3
wherein Rf′ is a C4-C14 perfluoro hydrocarbyl and R is methyl or ethyl.
4. The cosmetic composition according to
claim 3
, wherein said fluorosilane is represented by the formula:
CF3CF2CF2CF2CF2CF2CH2CH2Si (OCH2CH3)3
5. The cosmetic composition according to
claim 1
, wherein said particulates are selected from the group consisting of pigments, fillers, and mixtures thereof.
6. The cosmetic composition according to
claim 5
, wherein said pigment is selected from the group consisting of organic pigments, inorganic pigments, and a combination thereof.
7. The cosmetic composition according to
claim 5
, wherein said pigment is an inorganic pigment selected from the group consisting of an iron oxide, titanium dioxide, zinc oxide, potassium ferricyanide (K3Fe(CN)6), potassium ferrocyanide (K4Fe(CN)6), potassium ferrocyanide trihydrate (K4Fe(CN)6.3H2O), and mixtures thereof, and wherein said filler is selected from the group consisting of mica, talc, silica, starch, and mixtures thereof.
8. The cosmetic composition according to
claim 1
, wherein the composition is a product selected from the group consisting of a blush, a concealer, an eye shadow, a lip product, a liquid make-up, a cream make-up, a mascara, a moisturizer, and a powder.
9. The cosmetic composition according to
claim 1
, wherein the composition is either a powder or blush, and wherein said fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight of the cosmetic composition.
10. The cosmetic composition according to
claim 1
, wherein the cosmetic composition is a mascara, and wherein said fluorosilane is about 0.01 wt % to about 0.5 wt % of the total weight of the cosmetic composition.
11. The cosmetic composition according to
claim 1
, wherein the cosmetic composition is a lip product, and wherein said fluorosilane is about 0.0015 wt % to about 0.30 wt % of the total weight of the cosmetic composition.
12. The cosmetic composition according to
claim 1
, wherein the cosmetic composition is a liquid make-up, and wherein said fluorosilane is about 0.01 wt % to about 0.5 wt % of the total weight of the cosmetic composition.
13. The cosmetic composition according to
claim 1
, wherein the cosmetic composition is an eye shadow, and wherein said fluorosilane is about 0.01 wt % to about 1.5 wt % of the total weight of the cosmetic composition.
14. A method of reducing staining potential of a lipstick on a person, comprising applying to the person a lipstick having the composition of
claim 1
.
15. A method of improving water and/or oil resistance in a mascara on a person, comprising applying to a person a mascara of the composition of
claim 1
.
16. A method of improving wear resistance of a cosmetic having a plurality of particulates comprising coating at least some of said particulates with fluorosilane.
17. A method of reducing oil breakthrough in a facial product on a person, comprising applying to the person a facial product of the composition of
claim 1
.
18. A method of reducing color drift in a powder cosmetic during wear on a person, comprising applying to the person a powder cosmetic of the composition of
claim 1
.
19. An unpigmented cosmetic composition comprising a fluorosilane.
20. A method of moisturizing skin comprising applying to the skin the composition of
claim 1
.
US09/467,442 1999-12-20 1999-12-20 Cosmetic composition having fluorosilane coated particulates Expired - Lifetime US6315990B1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US09/467,442 US6315990B1 (en) 1999-12-20 1999-12-20 Cosmetic composition having fluorosilane coated particulates
AU80194/00A AU8019400A (en) 1999-12-20 2000-10-13 Cosmetic composition having fluorosilane coated particulates
JP2001546384A JP2003518024A (en) 1999-12-20 2000-10-13 Cosmetics containing fluorosilane-coated particles
EP00970876A EP1239810A4 (en) 1999-12-20 2000-10-13 Cosmetic composition having fluorosilane coated particulates
PCT/US2000/028338 WO2001045643A1 (en) 1999-12-20 2000-10-13 Cosmetic composition having fluorosilane coated particulates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/467,442 US6315990B1 (en) 1999-12-20 1999-12-20 Cosmetic composition having fluorosilane coated particulates

Publications (2)

Publication Number Publication Date
US20010036447A1 true US20010036447A1 (en) 2001-11-01
US6315990B1 US6315990B1 (en) 2001-11-13

Family

ID=23855720

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/467,442 Expired - Lifetime US6315990B1 (en) 1999-12-20 1999-12-20 Cosmetic composition having fluorosilane coated particulates

Country Status (5)

Country Link
US (1) US6315990B1 (en)
EP (1) EP1239810A4 (en)
JP (1) JP2003518024A (en)
AU (1) AU8019400A (en)
WO (1) WO2001045643A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060182698A1 (en) * 2002-09-19 2006-08-17 Serge Grizzo Preparation of chromium oxide pigment with reduced chromium (vi) content
US20060182772A1 (en) * 2002-09-17 2006-08-17 Martine Seu-Salerno Method for the extemporaneous preparation of cosmetic compositions having the texture of a cream and compositions for carrying out said method
US20110150793A1 (en) * 2009-12-17 2011-06-23 Avon Products, Inc. Clear or Translucent Composition
US20110182834A1 (en) * 2009-12-17 2011-07-28 Avon Products, Inc. Clear or Translucent Composition

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10233963A1 (en) * 2002-07-25 2004-02-12 Itn-Nanovation Gmbh Use of silanes in cosmetic products and methods for hair treatment
US7041278B2 (en) * 2002-07-31 2006-05-09 Coty Inc Cosmetic compositions with improved thermal stability and wear
US7387795B2 (en) * 2003-06-05 2008-06-17 Jane Hollenberg Cosmetic compositions organophosphonic acid coated particulates and methods for producing the same
EP1889598B1 (en) * 2006-07-18 2016-02-03 L'Oréal Cosmetic composition in powdered form
JP4874077B2 (en) * 2006-12-11 2012-02-08 ポーラ化成工業株式会社 Surface-treated powder and cosmetics containing the surface-treated powder
JP4931568B2 (en) * 2006-12-11 2012-05-16 ポーラ化成工業株式会社 Cosmetics containing surface-treated powder
JP4943128B2 (en) * 2006-12-11 2012-05-30 ポーラ化成工業株式会社 Powder-containing cosmetic
JP2008184399A (en) * 2007-01-29 2008-08-14 Shiseido Co Ltd Powdery cosmetic
JP4858977B2 (en) * 2007-02-08 2012-01-18 株式会社 資生堂 Powder cosmetic manufacturing method and powder cosmetic
EP2229132B1 (en) 2007-12-20 2019-02-27 Avon Products, Inc. Cosmetic compositions for imparting superhydrophobic films
JP5102070B2 (en) * 2008-02-29 2012-12-19 株式会社コーセー Eye makeup cosmetics
MX2010009771A (en) * 2008-03-04 2010-09-28 Avon Prod Inc Cosmetic compositions for imparting superhydrophobic fils.
JP5182865B2 (en) * 2008-03-21 2013-04-17 株式会社コーセー Oily salmon cosmetic
JP5497314B2 (en) * 2008-03-27 2014-05-21 株式会社コーセー Oily cosmetics
JP5166091B2 (en) * 2008-03-27 2013-03-21 株式会社コーセー Water-containing cosmetics
JP5128990B2 (en) * 2008-03-27 2013-01-23 株式会社コーセー Cosmetic for salmon
JP5270207B2 (en) * 2008-03-27 2013-08-21 株式会社コーセー Oily cosmetics
JP5356710B2 (en) * 2008-03-27 2013-12-04 株式会社コーセー Oily cosmetics
JP5226358B2 (en) * 2008-03-31 2013-07-03 株式会社コーセー Oil makeup cosmetics
US20100003290A1 (en) * 2008-09-28 2010-01-07 Kobo Products, Inc. Oil and water repellent cosmetic powder and methods of making and using same
JP2010095501A (en) * 2008-10-20 2010-04-30 Kose Corp Water-containing powder makeup cosmetic material
WO2010114112A1 (en) * 2009-03-30 2010-10-07 Daikin Industries, Ltd. Powder surface-treated with fluorine-modified aminosilane and cosmetics comprising the same
WO2010114110A1 (en) * 2009-03-30 2010-10-07 Daikin Industries, Ltd. Alkoxylated fluorine-modified siloxane polymer, surface treated powder and cosmetics comprising the same
WO2010114111A1 (en) * 2009-03-30 2010-10-07 Daikin Industries, Ltd. Fluorine-modified silicone polymer, surface treated powder and cosmetics comprising powder
BR112012008811B1 (en) 2009-11-06 2021-03-02 Avon Products, Inc method to prevent or reduce the appearance of frizzy hair
WO2011056547A1 (en) * 2009-11-06 2011-05-12 Avon Products, Inc. Methods and compositions for preventing or reducing frizzy appearance of hair
US9956432B2 (en) 2010-11-05 2018-05-01 Avon Products, Inc. Method for improving color retention in artificially colored hair
WO2014205113A1 (en) 2013-06-19 2014-12-24 Elc Management Llc Methods, compositions, and kit for whitening hyper pigmented spots on skin

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2597492B2 (en) * 1987-12-18 1997-04-09 ポーラ化成工業株式会社 Makeup cosmetics
JP2689569B2 (en) * 1989-02-01 1997-12-10 三菱マテリアル株式会社 Fluorine-based coating composition
FR2632962A1 (en) * 1988-06-17 1989-12-22 Pola Chem Ind Inc WATERPROOFING AND OLEOFUGE COATING POWDERS, PROCESS FOR THE PRODUCTION THEREOF AND COSMETIC PRODUCTS CONTAINING THEM
JPH06192594A (en) * 1992-01-29 1994-07-12 Teika Corp Water-repellent and oil-repellent pigment and powdery cosmetic containing the same
JP3280062B2 (en) * 1992-04-14 2002-04-30 花王株式会社 Water / oil repellent powder and cosmetics containing it
JPH06166611A (en) 1992-12-01 1994-06-14 Kose Corp Powdery cosmetic
DE59400199D1 (en) 1993-02-09 1996-05-23 Ciba Geigy Ag Organic pigments coated with silanes
JP2719303B2 (en) 1993-08-12 1998-02-25 鐘紡株式会社 Makeup cosmetics
JPH08208418A (en) * 1994-06-03 1996-08-13 Pola Chem Ind Inc Water-based manicure
US6471950B1 (en) * 1999-12-17 2002-10-29 Avon Products, Inc. Nail enamel composition having fluorosilane coated particulars

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060182772A1 (en) * 2002-09-17 2006-08-17 Martine Seu-Salerno Method for the extemporaneous preparation of cosmetic compositions having the texture of a cream and compositions for carrying out said method
US8226961B2 (en) 2002-09-17 2012-07-24 Lcw Loose powders turning into liquids under cosmetic application
US8715703B2 (en) 2002-09-17 2014-05-06 Sensient Cosmetic Technologies Method for the extemporaneous preparation of cosmetic compositions having the texture of a cream and compositions for carrying out said method
US20060182698A1 (en) * 2002-09-19 2006-08-17 Serge Grizzo Preparation of chromium oxide pigment with reduced chromium (vi) content
US20110150793A1 (en) * 2009-12-17 2011-06-23 Avon Products, Inc. Clear or Translucent Composition
US20110182834A1 (en) * 2009-12-17 2011-07-28 Avon Products, Inc. Clear or Translucent Composition
TWI512049B (en) * 2011-04-05 2015-12-11 Avon Prod Inc Clear or translucent composition

Also Published As

Publication number Publication date
AU8019400A (en) 2001-07-03
JP2003518024A (en) 2003-06-03
WO2001045643A1 (en) 2001-06-28
US6315990B1 (en) 2001-11-13
EP1239810A1 (en) 2002-09-18
EP1239810A4 (en) 2008-04-09

Similar Documents

Publication Publication Date Title
US6315990B1 (en) Cosmetic composition having fluorosilane coated particulates
JP2898232B2 (en) Anhydrous water-resistant cosmetic composition
US5108736A (en) Method of incorporating cosmetic pigments and bases into products containing oil and water phases
US6346237B2 (en) Cosmetic compositions comprising liquid crystal coloring agents and their use
AU646690B2 (en) Coated cosmetic materials and method of coating cosmetic materials
EP3281623B1 (en) Hair coloring composition for providing a film on keratin fibers
DE69718430T2 (en) Composite particles of melanin pigment with a spherical wax core, manufacturing process and uses in cosmetics
EP3102639B1 (en) Surface-treated calcium carbonate, methods for making the same, and compositions including the same
CA2361144C (en) Nail enamel composition having fluorosilane coated particulates
KR102085801B1 (en) Lip make-up composition with superior color sustainability and flexibility
CN1525845A (en) spray beauty composition
EP1758550A2 (en) Cosmetic preparation containing a metallic pigment
KR20200144904A (en) Cosmetic composition capable of mixed using for adjusting chroma
JP2001158713A (en) Emulsified composition
KR20160061476A (en) Water in Oil Emulsion Type Make-up Cosmetic Composition With Low Viscosity
KR101684415B1 (en) Cosmetic composition of water-in-oil with liposome hexacarboxymethyl dipeptide-12 and menufacturing method thereof
KR102211786B1 (en) Composition for cosmetics having improved water absorbability and oil absorbability
JPH01172312A (en) Cosmetic
JP2001002524A (en) Cosmetic
JP3065375B2 (en) Makeup cosmetics
JP2004196740A (en) Oil-in-water makeup cosmetics
JP5485778B2 (en) Water-in-oil emulsified cosmetic
JPH10130126A (en) Foundation
JP2008169177A (en) Cosmetic pigment and cosmetics containing the same
KR960003935B1 (en) Preparation process of water-/oil-resistant composite pigment and color make-up composed of it

Legal Events

Date Code Title Description
AS Assignment

Owner name: AVON PRODUCTS, INC., NEW YORK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:FARER, ALAN;MARTIN, SHARI R.;REEL/FRAME:010474/0158

Effective date: 19991215

STCF Information on status: patent grant

Free format text: PATENTED CASE

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

RR Request for reexamination filed

Effective date: 20120815

FPAY Fee payment

Year of fee payment: 12

B1 Reexamination certificate first reexamination

Free format text: CLAIMS 2-4 AND 13 ARE CANCELLED.CLAIMS 1 AND 5-12 ARE DETERMINED TO BE PATENTABLE AS AMENDED.NEW CLAIMS 14-24 ARE ADDED AND DETERMINED TO BE PATENTABLE.

AS Assignment

Owner name: CITIBANK, N.A., NEW YORK

Free format text: SECURITY INTEREST;ASSIGNOR:AVON PRODUCTS, INC.;REEL/FRAME:035899/0776

Effective date: 20150605

AS Assignment

Owner name: AVON PRODUCTS, INC., NEW YORK

Free format text: RELEASE OF SECURITY INTEREST IN PATENTS;ASSIGNOR:CITIBANK, N.A.;REEL/FRAME:039690/0331

Effective date: 20160815

AS Assignment

Owner name: CITIBANK, N.A., LONDON BRANCH, NEW YORK

Free format text: SECURITY INTEREST;ASSIGNOR:AVON PRODUCTS, INC.;REEL/FRAME:051032/0210

Effective date: 20190212