US1953908A - Method of treating textile material and product - Google Patents
Method of treating textile material and product Download PDFInfo
- Publication number
- US1953908A US1953908A US511643A US51164331A US1953908A US 1953908 A US1953908 A US 1953908A US 511643 A US511643 A US 511643A US 51164331 A US51164331 A US 51164331A US 1953908 A US1953908 A US 1953908A
- Authority
- US
- United States
- Prior art keywords
- goods
- dyed
- fluoride
- sulphur
- sulphur black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 7
- 238000000034 method Methods 0.000 title description 5
- 239000004753 textile Substances 0.000 title description 2
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 16
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 10
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 5
- 235000013024 sodium fluoride Nutrition 0.000 description 5
- 239000011775 sodium fluoride Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 238000007280 thionation reaction Methods 0.000 description 3
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 2
- -1 nitro-phenol compound Chemical class 0.000 description 2
- 235000003270 potassium fluoride Nutrition 0.000 description 2
- 239000011698 potassium fluoride Substances 0.000 description 2
- MHKBMNACOMRIAW-UHFFFAOYSA-N 2,3-dinitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O MHKBMNACOMRIAW-UHFFFAOYSA-N 0.000 description 1
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Definitions
- This invention relates to the prevention of tendering of dyed goods and in particular goods dyed with sulphur dyes. It especially contemplates the treatment of sulphur black dyed goods 5 with soluble fluorides.
- Sulphur black dyes are extensively used for the production of very desirable fast black shades on various grades of cotton goods.
- the advantages of these dyes are somewhat overshadowed and the use of the dyes somewhat limited by the fact that under certain conditions of storage, such as for example, in awarm humid atmosphere there is a tendency for a material dyed with these dyes to tender.
- This invention has for an object the stabilization or goods dyed with sulphur blacks.
- Other objects are the inhibition of tendering of goods dyed with sulphur blacks and in general an advancement of the art. Other objects will appear hereinafter.
- Example II Cotton goods dyed with 12% (based on the weight of the goods) Sulfogene Carbon HXX (a sulphur black dye made by the thionation of a dinitrophenol) were thoroughly rinsed with a 2% solution of sodium fluoride, wrung out under such conditions that 2% of the dried agent (based on the weight of the dyed goods) remained thereon and dried in air. Samples of the dyed goods that had no fluoride after-treatment and samples impregnated with the 2% sodium fluoride solu- Example III Cotton goods were dyed with the dye resulting from the thionation of di-nitro-phenol, under such conditions that approximately 12% (based on the weight of the goods) of the dye remained thereon.
- Sulfogene Carbon HXX a sulphur black dye made by the thionation of a dinitrophenol
- any soluble salt of hydrofluoric acid may be used in carrying out this invention, the alkali metal and the like salts are particularly valuable. For reasons of economy the sodium and potassium salts are preferred.
- the concentration of the fluoride solution may be varied within wide limits as desired. A 2% solution has been found very effective but higher concentrations may be used.
- the presence of the small quantity of the hydrofluoric acid salt on sulphur black dyed material so stabilizes the goods and inhibits the tendering that they may be considered as essentially unaltered.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Description
Patented Apr. 3, 1934 UNITED STATES PATENT OFFICE METHOD OF TREATING TEXTILE MATERIAL AND PRODUCT No Drawing. Application January 2'7, 1931, Serial N 511,643
16 Claims.
This invention relates to the prevention of tendering of dyed goods and in particular goods dyed with sulphur dyes. It especially contemplates the treatment of sulphur black dyed goods 5 with soluble fluorides.
Sulphur black dyes are extensively used for the production of very desirable fast black shades on various grades of cotton goods. The advantages of these dyes are somewhat overshadowed and the use of the dyes somewhat limited by the fact that under certain conditions of storage, such as for example, in awarm humid atmosphere there is a tendency for a material dyed with these dyes to tender.
This invention has for an object the stabilization or goods dyed with sulphur blacks. Other objects are the inhibition of tendering of goods dyed with sulphur blacks and in general an advancement of the art. Other objects will appear hereinafter.
These objects are accomplished by passing goods, dyed with a sulphur black by the usual methods, through an aqueous solution of a soluble salt of hydrofluoric acid. Where convenient or necessary the goods are squeezed or wrung out beforedrying.
The invention will be readily understood from a consideration of the following examples in which the parts are given by weight.
' Example I Example II Cotton goods dyed with 12% (based on the weight of the goods) Sulfogene Carbon HXX (a sulphur black dye made by the thionation of a dinitrophenol) were thoroughly rinsed with a 2% solution of sodium fluoride, wrung out under such conditions that 2% of the dried agent (based on the weight of the dyed goods) remained thereon and dried in air. Samples of the dyed goods that had no fluoride after-treatment and samples impregnated with the 2% sodium fluoride solu- Example III Cotton goods were dyed with the dye resulting from the thionation of di-nitro-phenol, under such conditions that approximately 12% (based on the weight of the goods) of the dye remained thereon. Samples of this material were thereafter immersed in a 2% solution of sodium fluoride, wrung out and dried. After-treated and untreated samples of the dyed material were placed in atmosphere of air and steam in anoven maintained at about 130 C. for approximately four hours, the samples were then removed and tested whereby it was found that the untreated sample had lost about 75% of its tensile strength whereas the fluoride treated material was only approximately 10% weaker.
Although any soluble salt of hydrofluoric acid may be used in carrying out this invention, the alkali metal and the like salts are particularly valuable. For reasons of economy the sodium and potassium salts are preferred.
The action of these stabilizing agents is especially noticeable in sulphur dyes resulting from the thionation of nitro-phenolic bodies.
The concentration of the fluoride solution may be varied within wide limits as desired. A 2% solution has been found very effective but higher concentrations may be used. The presence of the small quantity of the hydrofluoric acid salt on sulphur black dyed material so stabilizes the goods and inhibits the tendering that they may be considered as essentially unaltered.
As many apparently widely different embodiments of this invention may be made without departing from the spirit and scope thereof, it is to be understood that we do not limit ourselves to the specific embodiments thereof except as defined in the appended claims.
, We claim:
- 1. Sulphur black dyed goods having 2% of sodium fluoride thereon.
2. Sulphur black dyed goods having sodium fluoride thereon.
3. Sulphur black dyed goods having 2% of potassium fluoride thereon.
4. Sulphur black dyed goods having potassium fluoride thereon.
5. Sulphur black dyed goods having a soluble fluoride thereon.
6. Sulphur black dyed goods having an alkali metal fluoride thereon.
'7. Sulphur black dyed goods having a fluoride thereon.
8. Sulphur black dyed goods having 2% of a soluble salt of hydrofluoric acid thereon.
9. Cotton goods dyed with a sulphur black produced by thionating a nitro-phenol compound, and having thereon a soluble fluoride.
10. Cotton goods dyed with a sulphur black produced by thionating a di-nitro-phenol compound, and having thereon a soluble fluoride.
11. The process of stabilizing sulphur black dyed goods comprising adding thereto a soluble salt of hydrofluoric acid.
12. The process of preventing or retarding the than 10% water solution of an alkali metal fluoride.
HERBERT A. LUBS. HERBERT WARREN WALKER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US511643A US1953908A (en) | 1931-01-27 | 1931-01-27 | Method of treating textile material and product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US511643A US1953908A (en) | 1931-01-27 | 1931-01-27 | Method of treating textile material and product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1953908A true US1953908A (en) | 1934-04-03 |
Family
ID=24035791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US511643A Expired - Lifetime US1953908A (en) | 1931-01-27 | 1931-01-27 | Method of treating textile material and product |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1953908A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0613975A3 (en) * | 1993-03-02 | 1994-09-28 | Hoechst Ag | Reactive ink-jet one-phase printing. |
| US20030154565A1 (en) * | 2000-04-20 | 2003-08-21 | The Procter & Gamble Company | Sulfur dye protection systems and compositions and methods employing same |
-
1931
- 1931-01-27 US US511643A patent/US1953908A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0613975A3 (en) * | 1993-03-02 | 1994-09-28 | Hoechst Ag | Reactive ink-jet one-phase printing. |
| US5443630A (en) * | 1993-03-02 | 1995-08-22 | Hoechst Aktiengesellschaft | Inkjet single-phase reactive printing |
| US20030154565A1 (en) * | 2000-04-20 | 2003-08-21 | The Procter & Gamble Company | Sulfur dye protection systems and compositions and methods employing same |
| US7018424B2 (en) * | 2000-04-20 | 2006-03-28 | The Board Of Regents Of The University Of Nebraska | Sulfur dye protection systems and compositions and methods employing same |
| US7101407B2 (en) | 2000-04-20 | 2006-09-05 | The Board Of Regents Of The University Of Nebraska | Sulfur dye protection systems and compositions and methods employing same |
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