US1942937A - Process of heat treating ferrous metals - Google Patents
Process of heat treating ferrous metals Download PDFInfo
- Publication number
- US1942937A US1942937A US618297A US61829732A US1942937A US 1942937 A US1942937 A US 1942937A US 618297 A US618297 A US 618297A US 61829732 A US61829732 A US 61829732A US 1942937 A US1942937 A US 1942937A
- Authority
- US
- United States
- Prior art keywords
- ferrous metals
- metal
- penetration
- heat treating
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 25
- 239000002184 metal Substances 0.000 title description 25
- -1 ferrous metals Chemical class 0.000 title description 9
- 238000000034 method Methods 0.000 title description 6
- 230000035515 penetration Effects 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- 229910021538 borax Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000004328 sodium tetraborate Substances 0.000 description 7
- 235000010339 sodium tetraborate Nutrition 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 235000010582 Pisum sativum Nutrition 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 241000219843 Pisum Species 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 239000011121 hardwood Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000677 High-carbon steel Inorganic materials 0.000 description 1
- 241000219729 Lathyrus Species 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C12/00—Solid state diffusion of at least one non-metal element other than silicon and at least one metal element or silicon into metallic material surfaces
- C23C12/02—Diffusion in one step
Definitions
- the principal objects of this invention are to enable the conversion of low carbon ferrous metals such as iron or soft steels into high carbon steel with an increased tensile strength and hard- 5 ness in a remarkably short period and at very moderate cost.
- the principal feature of the invention consists in the novel admixture of materials in which the metal to be treated is packed to be heat treated whereby the grain of the metal is affected to increase porosity and a high percentage of silicon content of the metal is removed and a remarkable degree of'penetration of other metals and carbon are effected in the minimum of time.
- the flasks are then placed in a suitable furnace and are brought to a temperature of from 1850 F. to 1950 F. and retained under such temperature for a period sufficient to obtain the desired penetration, it being found that treatment at the above temperature obtains approximately 1%" of penetration in two hours and the admixture of materials is such that any degree of penetration up to complete penetration may be obtained.
- borax with the manganese and chromium salts is found to produce an extremely desirable result in effecting deep penetration of the foreign metal substances into the iron or mild steel being treated and the penetration is assisted by the continued supply of carbon effected by the presence of the pea chop and hardwood saw dust following the initial application of carbon supplied by the charcoal.
- the pea chop which consists of pea vines, pods and peas finely chopped, with the hardwood sawdust, provides a solid base for the metal to 50 be treated and prevents warping.
- the pea chop Under the heat-treatment the pea chop has the effect of opening the grain of the metal thereby assisting the penetration of the borax which acting as a purifier removes corrosion in the metal 5 and eliminates a portion of the silicon.
- the opening of the grain permits the ready penetration of the manganese and chromium and also the carbon produced by the charcoal and sawdust.
- the use of sawdust maintains the production of carbon beyond the period of the production of carbon from the charcoal in the mixture.
- Ferrous metals heat treated in the manner described have a hard but not brittle surface and a very desirable quality of steel is produced.
- a process of heat treating ferrous metals consisting in first preparing a mixture of finely ground carbonizable materials, manganese, chromium and borax, then packing the metal articles to be treated in such mixture, then raising the temperature of the entire body of materials to from 1850 F. to 1950 F. and maintaining such temperature for a period to effect the desired penetration of the resultant substances into the grain of the metal.
- a process of heat treating ferrous metals consisting in preparing a mixture of finely ground materials in or about the following proportions:
- a process ofheat treating ferrous metals consisting in first preparing a mixture of finely the desired penetration of the carbon, manganese and chromium into the grain of the metal.
- a compound for use in the heat treating of ferrous metals containing manganese, chromium, borax and a carbonizable material 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Carbon And Carbon Compounds (AREA)
Description
Patented Jan. 9, 1934 UNITED STATES PROCESS OF HEAT TREATING FERROUS METALS V James A. Robertson and David Robertson, To-
ronto, Ontario, Canada, assignors of one-half to George F. McCandless, Toronto, Canada No Drawing. Application June 20, 1932 Serial No. 618,297
Claims.
The principal objects of this invention are to enable the conversion of low carbon ferrous metals such as iron or soft steels into high carbon steel with an increased tensile strength and hard- 5 ness in a remarkably short period and at very moderate cost.
The principal feature of the invention consists in the novel admixture of materials in which the metal to be treated is packed to be heat treated whereby the grain of the metal is affected to increase porosity and a high percentage of silicon content of the metal is removed and a remarkable degree of'penetration of other metals and carbon are effected in the minimum of time.
According to this process a thorough mechanical mixture of materials in finely ground or powdered form is prepared in or about the following proportions Percent Charcoal 40 Hardwood Sawdust 24 Chromium 5 Manganese 20 Borax 8 25 Pea chop 3 The metal to be treated is packed in suitable iron boxes or flasks, each piece being completely surrounded with the ground mixture as is the usual practice for pack treatment.
The flasks are then placed in a suitable furnace and are brought to a temperature of from 1850 F. to 1950 F. and retained under such temperature for a period sufficient to obtain the desired penetration, it being found that treatment at the above temperature obtains approximately 1%" of penetration in two hours and the admixture of materials is such that any degree of penetration up to complete penetration may be obtained.
It will of course be understod that the dimensions and volume of the metal pieces being treated will require widely varying periods of time to attain the furnace temperature and that the treatment is carried on in periods of time to attain the furnace temperature and that the treatment is carried on in periods, following complete heat penetration, in accordance with the desired carbon penetration.
The use of borax with the manganese and chromium salts is found to produce an extremely desirable result in effecting deep penetration of the foreign metal substances into the iron or mild steel being treated and the penetration is assisted by the continued supply of carbon effected by the presence of the pea chop and hardwood saw dust following the initial application of carbon supplied by the charcoal.
The pea chop, which consists of pea vines, pods and peas finely chopped, with the hardwood sawdust, provides a solid base for the metal to 50 be treated and prevents warping.
Under the heat-treatment the pea chop has the effect of opening the grain of the metal thereby assisting the penetration of the borax which acting as a purifier removes corrosion in the metal 5 and eliminates a portion of the silicon.
The opening of the grain permits the ready penetration of the manganese and chromium and also the carbon produced by the charcoal and sawdust. The use of sawdust maintains the production of carbon beyond the period of the production of carbon from the charcoal in the mixture.
Ferrous metals heat treated in the manner described have a hard but not brittle surface and a very desirable quality of steel is produced.
It will of course be understod that the proportions of the materials used may be varied in accordance with the quality of the metal being treated.
What we claim as our invention is:-
1. A process of heat treating ferrous metals, consisting in first preparing a mixture of finely ground carbonizable materials, manganese, chromium and borax, then packing the metal articles to be treated in such mixture, then raising the temperature of the entire body of materials to from 1850 F. to 1950 F. and maintaining such temperature for a period to effect the desired penetration of the resultant substances into the grain of the metal.
2. A process of heat treating ferrous metals, consisting in preparing a mixture of finely ground materials in or about the following proportions:
Per cent Charcoal 40 Hardwood sawdust 24 Manganese 20 Chromium 5 Borax 8 Pea chop 3 then packing the metal articles in such mixture, then heating the mass to attain a temperature of from 1850 F. to 1950" F. and maintaining such temperatures for a period of approximately two hours for each of carbon penetration of the metal desired.
3. A process ofheat treating ferrous metals, consisting in first preparing a mixture of finely the desired penetration of the carbon, manganese and chromium into the grain of the metal.
4. A compound for use in the heat treating of ferrous metals containing manganese, chromium, borax and a carbonizable material.
5. A compound for use in the heat-treating of ferrous metals containing manganese approximately 20%, chromium approximately 5%, borax approximately 8%, in combination with approximately 67% carbonizable material.
JAMES A. ROBERTSON. DAVID ROBERTSON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US618297A US1942937A (en) | 1932-06-20 | 1932-06-20 | Process of heat treating ferrous metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US618297A US1942937A (en) | 1932-06-20 | 1932-06-20 | Process of heat treating ferrous metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1942937A true US1942937A (en) | 1934-01-09 |
Family
ID=24477134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US618297A Expired - Lifetime US1942937A (en) | 1932-06-20 | 1932-06-20 | Process of heat treating ferrous metals |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1942937A (en) |
-
1932
- 1932-06-20 US US618297A patent/US1942937A/en not_active Expired - Lifetime
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