US1877915A - Process for pumping vapors under high vacuum - Google Patents
Process for pumping vapors under high vacuum Download PDFInfo
- Publication number
- US1877915A US1877915A US296006A US29600628A US1877915A US 1877915 A US1877915 A US 1877915A US 296006 A US296006 A US 296006A US 29600628 A US29600628 A US 29600628A US 1877915 A US1877915 A US 1877915A
- Authority
- US
- United States
- Prior art keywords
- gas
- vapors
- pump
- under high
- high vacuum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 20
- 238000005086 pumping Methods 0.000 title description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000007789 gas Substances 0.000 description 17
- 230000006835 compression Effects 0.000 description 12
- 238000007906 compression Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 7
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003129 oil well Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/06—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/78—Processes of molding using vacuum
Definitions
- the drawing is a semi-diagrammatic view in sectional elevation of an apparatus ar' ranged for the extraction of oil vapors from gas or oil wells operated under high vacua.
- the present method finds a ready and valuable appli- 20 cation for the same purpose, namely for obtaining an increased yield of'natural gas and naphtha from gas wells, although my present method is of great value in other processes.
- numeral 1 denotes the casinghead of a gas or oil well which is being operated at a high vacuum, for example, 28.5 to 29 inches of mercury below atmospheric pressure or higher. It will be understood that operation at such high vacua has not been heretofore practical.
- a pipe 2 conducts the vaporous mixture from the Well to a vacuum pump 3 which may be of v10 to storage (not shown).
- a pipe 4 is shown connected to pipe 2 for introduction of inert gas.
- the drawing shows only the compression cylinder which is provided with valve chest 3a.
- the compressed mixture is discharged through a pipe 7 to cooler 8 and thence to separator drum 9 from which the condensate is 'removed by line
- the uncondensed gas is removed by line 11 to a suitable apparatus or removing the remaining gasoline or low boiling liquid hydrocarbons from the gas.
- the extraction system is shown generally at 12 and may be a compression and coollng process, an absorption'process, an adsorption process or, indeed, any known method for removing'the normally liquid constituents from the gas.
- the extracted gasoline is removed by line 13 to storage (not shown) and the ducted back by pipe 4 or recirculation through thecompressor. Gas may be bled from the system for fuel or for other uses by line 14.
- the vaporous mixture is removed from the well under high vacuum, for example 1/;, inch of mercury absolute pressure or less, and is fed to the vacuum pump ⁇ together with a regulated quantity of non-condensible gas, such as nitrogen, CO2 or hydrocarbon gas.
- non-condensible gas such as nitrogen, CO2 or hydrocarbon gas.
- Inert gases are preferred-to air, although the latter could be used.
- the Volume of gas is from 10 to 100% of the volume of the vapor and the amount may be regulated so that substantially no condensation occurs within the pump, although the cylinders are as may be concooled according to the present practice.
- a pump which is capable of reducing the pressure in a closed air filled vessel to 0.7 inches of mercury absolute pressure, is tested pumping air at approximately 1.0 inch of mercury pressure and the volumetric efficiency was found to be 8.8%.
- the same pump is then tested pumping toluene vapor substantially free of air or inert gas under the same pressure and it is found to have an efficiency of 1.75%. That is to say, the pump handles about five times as much air as toluene under the same pressure conditions.
- the method of compressing through a vacuum pump vapors which condense on adiabatic compression which comprises actuating the vacuum pump adiabatically to draw the vapors from a body thereof in' a confined stream under less than atmospheric pressure, adding to the confined stream on the intake side of the pump gas which does not condense on adiabatic compression whereby condensation is lessened at pressures greater than the pressure in the intake, and delivering the mixture from the pump under said increased pressure.
- the method of compressin through a vacuum pump vapors which con ense an adiabatic compression which comprises actuating the vacuum pump adiabatically to draw the vapors ⁇ in a confined stream from a body thereof under less than atmospheric pressure, adding to the confined stream on the intake side of the pump at least 10 percent by v olume of gas which does not condense on adiabatic compression to lessen condensation at atmospheric pressure, and delivering the mixture from the pumping operation under at' least atmospheric pressure.
- the method of increasing the flow of vapors from a well which comprises mecha-nically drawing vapors from the well under vless than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to lessen condensation at pressures greater' than the pressures on the intake of the pump, and discharging the mixture from the pump under said increased pressure.
- the method of increasing the flow of vapors from a Well which comprises mechanically drawing vapors from the Well under less than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to prevent condensation at atmospheric pressure, and discharging the mixture from the pumping operation under at least atmospheric pressure.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compressors, Vaccum Pumps And Other Relevant Systems (AREA)
Description
Sept. ZO, 1932. w. K. L Ewls PROCESS FOR PUMPING VAPORS UNDER HIGH VACUUM Filed July 28, 1928 NUYWOK QR nSnNQ bbb @imm UZNU Patented Sept. 20, 129.."2
UNITED STATES PATENT OFFICE WARREN K. LEWIS, OF NEWTON, MASSACHUSETTS, ASSIGNOR TO STANDARD OIL DEVELOPMENT COMPANY, A CORPORATION 0F DELAWARE PROCESS FOR PUMPING VAPORS UNDER HIGH VACUUM Application med my as, 1928. semi No. 296,006.
10 drawing which illustrates the invention.
The drawing is a semi-diagrammatic view in sectional elevation of an apparatus ar' ranged for the extraction of oil vapors from gas or oil wells operated under high vacua.
15 In my copending applications Serial Nos.
296,007 and 296,008, filed July 28, 1928, methods for obtaining high vacua in oil wells, gas wells and the like were disclosed. The present method finds a ready and valuable appli- 20 cation for the same purpose, namely for obtaining an increased yield of'natural gas and naphtha from gas wells, although my present method is of great value in other processes.
I have observed that certain vapors unlike steam do not, on adiabatic compression, become superheated, but on the contrary condense and the vapor of normally liquid hydrocarbons, such as pentane, hexane, benzene, toluene and the like are of this nature. It is needless to say that cooling of the pump cylinders increases the condensation. I have further observed that vacuum pumps when pumping such vapors, particularly at high vacua, operate with avolumetric eihciency greatly below that obtained when operating on non-condensible gases under the same pressure. My present method greatly increases the capacity of any given pump and makes it possible to obtain higher'vacua than are now commercially realized.
Referring to the drawing, numeral 1 denotes the casinghead of a gas or oil well which is being operated at a high vacuum, for example, 28.5 to 29 inches of mercury below atmospheric pressure or higher. It will be understood that operation at such high vacua has not been heretofore practical. A pipe 2 conducts the vaporous mixture from the Well to a vacuum pump 3 which may be of v10 to storage (not shown).
one or more stages, although a single stage unit is shown on the drawing for simplicity. A pipe 4 is shown connected to pipe 2 for introduction of inert gas. The drawing shows only the compression cylinder which is provided with valve chest 3a. The compressed mixture is discharged through a pipe 7 to cooler 8 and thence to separator drum 9 from which the condensate is 'removed by line The uncondensed gas is removed by line 11 to a suitable apparatus or removing the remaining gasoline or low boiling liquid hydrocarbons from the gas. The extraction system is shown generally at 12 and may be a compression and coollng process, an absorption'process, an adsorption process or, indeed, any known method for removing'the normally liquid constituents from the gas. The extracted gasoline is removed by line 13 to storage (not shown) and the ducted back by pipe 4 or recirculation through thecompressor. Gas may be bled from the system for fuel or for other uses by line 14.
In the operation of my process the vaporous mixture is removed from the well under high vacuum, for example 1/;, inch of mercury absolute pressure or less, and is fed to the vacuum pump `together with a regulated quantity of non-condensible gas, such as nitrogen, CO2 or hydrocarbon gas. Inert gases are preferred-to air, although the latter could be used. Ordinarily the Volume of gas is from 10 to 100% of the volume of the vapor and the amount may be regulated so that substantially no condensation occurs within the pump, although the cylinders are as may be concooled according to the present practice. Ad-
for each case.
As an example of my process, a pump, which is capable of reducing the pressure in a closed air filled vessel to 0.7 inches of mercury absolute pressure, is tested pumping air at approximately 1.0 inch of mercury pressure and the volumetric efficiency was found to be 8.8%. The same pump is then tested pumping toluene vapor substantially free of air or inert gas under the same pressure and it is found to have an efficiency of 1.75%. That is to say, the pump handles about five times as much air as toluene under the same pressure conditions. When air is admixed with the toluene vapor in a proportion of .4 volumes of air per volume of toluene vapor, the efficiency rises to 7.65%, and if the efficiency is based on the vapor alone, neglecting the volume of air, the value is found to be 5.4%; or in other words, the volume of toluene vapor handled is increased about threefold by the addition of the air.
Although my specification has particularly described the process in relation to the removal of gas and oil vapor from wells, it will be understood that my invention finds application wherever it is desirable to pump vapors which, unlike steam, do not superheat on adiabatic compression or such compression as occurs in compression pumps cooled in any suitable manner.
My invention is not to be limited by any theory of the operation of the process, nor by any example which may have been given merely by way of illustration, but only by the following claims in which l Wish to claim all novelty inherent in the invention.
I claim:
1. The method of compressing through a vacuum pump vapors which condense on adiabatic compression, which comprises actuating the vacuum pump adiabatically to draw the vapors from a body thereof in' a confined stream under less than atmospheric pressure, adding to the confined stream on the intake side of the pump gas which does not condense on adiabatic compression whereby condensation is lessened at pressures greater than the pressure in the intake, and delivering the mixture from the pump under said increased pressure.
2. The method of compressin through a vacuum pump vapors which con ense an adiabatic compression, which comprises actuating the vacuum pump adiabatically to draw the vapors `in a confined stream from a body thereof under less than atmospheric pressure, adding to the confined stream on the intake side of the pump at least 10 percent by v olume of gas which does not condense on adiabatic compression to lessen condensation at atmospheric pressure, and delivering the mixture from the pumping operation under at' least atmospheric pressure.
4. The method of increasing the flow of vapors from a well, which comprises mecha-nically drawing vapors from the well under vless than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to lessen condensation at pressures greater' than the pressures on the intake of the pump, and discharging the mixture from the pump under said increased pressure.
5. The method of increasing the flow of vapors from a Well which comprises mechanically drawing vapors from the Well under less than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to prevent condensation at atmospheric pressure, and discharging the mixture from the pumping operation under at least atmospheric pressure.
WARREN K. LEWIS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US296006A US1877915A (en) | 1928-07-28 | 1928-07-28 | Process for pumping vapors under high vacuum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US296006A US1877915A (en) | 1928-07-28 | 1928-07-28 | Process for pumping vapors under high vacuum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1877915A true US1877915A (en) | 1932-09-20 |
Family
ID=23140183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US296006A Expired - Lifetime US1877915A (en) | 1928-07-28 | 1928-07-28 | Process for pumping vapors under high vacuum |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1877915A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4369839A (en) * | 1981-08-17 | 1983-01-25 | F & P Production Co., Inc. | Casing vacuum system |
| US4593760A (en) * | 1984-01-04 | 1986-06-10 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| US4660639A (en) * | 1984-01-04 | 1987-04-28 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| USRE33102E (en) * | 1984-01-04 | 1989-10-31 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| US5554290A (en) * | 1995-04-11 | 1996-09-10 | Geraghty & Miller, Inc. | Insitu anaerobic reactive zone for insitu metals precipitation and to achieve microbial de-nitrification |
| US5575589A (en) * | 1995-04-11 | 1996-11-19 | Geraghty & Miller, Inc. | Apparatus and method for removing volatile contaminants from phreatic water |
| US5588490A (en) * | 1995-05-31 | 1996-12-31 | Geraghty & Miller, Inc. | Method and system to achieve two dimensional air sparging |
| US5664911A (en) * | 1991-05-03 | 1997-09-09 | Iit Research Institute | Method and apparatus for in situ decontamination of a site contaminated with a volatile material |
| US6007274A (en) * | 1997-05-19 | 1999-12-28 | Arcadis Geraghty & Miller | In-well air stripping, oxidation, and adsorption |
| US6116816A (en) * | 1998-08-26 | 2000-09-12 | Arcadis Geraghty & Miller, Inc. | In situ reactive gate for groundwater remediation |
| US6143177A (en) * | 1995-04-11 | 2000-11-07 | Arcadis Geraghty & Miller, Inc. | Engineered in situ anaerobic reactive zones |
| US20060290197A1 (en) * | 2005-06-10 | 2006-12-28 | See Jackie R | Oil extraction system and method |
| US20080164020A1 (en) * | 2007-01-04 | 2008-07-10 | Rock Well Petroleum, Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US20080169104A1 (en) * | 2007-01-11 | 2008-07-17 | Rock Well Petroleum, Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US20080314640A1 (en) * | 2007-06-20 | 2008-12-25 | Greg Vandersnick | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US20090183872A1 (en) * | 2008-01-23 | 2009-07-23 | Trent Robert H | Methods Of Recovering Hydrocarbons From Oil Shale And Sub-Surface Oil Shale Recovery Arrangements For Recovering Hydrocarbons From Oil Shale |
-
1928
- 1928-07-28 US US296006A patent/US1877915A/en not_active Expired - Lifetime
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4369839A (en) * | 1981-08-17 | 1983-01-25 | F & P Production Co., Inc. | Casing vacuum system |
| US4593760A (en) * | 1984-01-04 | 1986-06-10 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| US4660639A (en) * | 1984-01-04 | 1987-04-28 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| USRE33102E (en) * | 1984-01-04 | 1989-10-31 | The Upjohn Company | Removal of volatile contaminants from the vadose zone of contaminated ground |
| US5664911A (en) * | 1991-05-03 | 1997-09-09 | Iit Research Institute | Method and apparatus for in situ decontamination of a site contaminated with a volatile material |
| US6143177A (en) * | 1995-04-11 | 2000-11-07 | Arcadis Geraghty & Miller, Inc. | Engineered in situ anaerobic reactive zones |
| US5554290A (en) * | 1995-04-11 | 1996-09-10 | Geraghty & Miller, Inc. | Insitu anaerobic reactive zone for insitu metals precipitation and to achieve microbial de-nitrification |
| US5575589A (en) * | 1995-04-11 | 1996-11-19 | Geraghty & Miller, Inc. | Apparatus and method for removing volatile contaminants from phreatic water |
| US6632364B1 (en) | 1995-04-11 | 2003-10-14 | Arcadis G & M | Engineered in situ anaerobic reactive zones |
| US6322700B1 (en) | 1995-04-11 | 2001-11-27 | Arcadis Geraghty & Miller | Engineered in situ anaerobic reactive zones |
| US5588490A (en) * | 1995-05-31 | 1996-12-31 | Geraghty & Miller, Inc. | Method and system to achieve two dimensional air sparging |
| US6283674B1 (en) | 1997-05-19 | 2001-09-04 | Arcadis Geraghty & Miller | In-well air stripping, oxidation, and adsorption |
| US6102623A (en) * | 1997-05-19 | 2000-08-15 | Arcadis Geraghty & Miller, Inc. | In-well air stripping, oxidation, and adsorption |
| US6007274A (en) * | 1997-05-19 | 1999-12-28 | Arcadis Geraghty & Miller | In-well air stripping, oxidation, and adsorption |
| US6254310B1 (en) | 1997-05-19 | 2001-07-03 | Arcadis Geraghty & Miller, Inc. | In-well air stripping and adsorption |
| US6280118B1 (en) | 1998-08-26 | 2001-08-28 | Arcadis Geraghty & Miller, Inc. | In situ reactive gate |
| US6116816A (en) * | 1998-08-26 | 2000-09-12 | Arcadis Geraghty & Miller, Inc. | In situ reactive gate for groundwater remediation |
| US20060290197A1 (en) * | 2005-06-10 | 2006-12-28 | See Jackie R | Oil extraction system and method |
| US7568527B2 (en) | 2007-01-04 | 2009-08-04 | Rock Well Petroleum, Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US20080164020A1 (en) * | 2007-01-04 | 2008-07-10 | Rock Well Petroleum, Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US20080169104A1 (en) * | 2007-01-11 | 2008-07-17 | Rock Well Petroleum, Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US7543649B2 (en) | 2007-01-11 | 2009-06-09 | Rock Well Petroleum Inc. | Method of collecting crude oil and crude oil collection header apparatus |
| US20080314640A1 (en) * | 2007-06-20 | 2008-12-25 | Greg Vandersnick | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US7823662B2 (en) | 2007-06-20 | 2010-11-02 | New Era Petroleum, Llc. | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US8307918B2 (en) | 2007-06-20 | 2012-11-13 | New Era Petroleum, Llc | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US8474551B2 (en) | 2007-06-20 | 2013-07-02 | Nep Ip, Llc | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US8534382B2 (en) | 2007-06-20 | 2013-09-17 | Nep Ip, Llc | Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods |
| US20090183872A1 (en) * | 2008-01-23 | 2009-07-23 | Trent Robert H | Methods Of Recovering Hydrocarbons From Oil Shale And Sub-Surface Oil Shale Recovery Arrangements For Recovering Hydrocarbons From Oil Shale |
| US7832483B2 (en) | 2008-01-23 | 2010-11-16 | New Era Petroleum, Llc. | Methods of recovering hydrocarbons from oil shale and sub-surface oil shale recovery arrangements for recovering hydrocarbons from oil shale |
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