US1770794A - Tennis string - Google Patents
Tennis string Download PDFInfo
- Publication number
- US1770794A US1770794A US204667A US20466727A US1770794A US 1770794 A US1770794 A US 1770794A US 204667 A US204667 A US 204667A US 20466727 A US20466727 A US 20466727A US 1770794 A US1770794 A US 1770794A
- Authority
- US
- United States
- Prior art keywords
- string
- strings
- glue
- silk
- gut
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003292 glue Substances 0.000 description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000004902 Softening Agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229940107218 chromium Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229960004011 methenamine Drugs 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229940069002 potassium dichromate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B51/00—Stringing tennis, badminton or like rackets; Strings therefor; Maintenance of racket strings
- A63B51/02—Strings; String substitutes; Products applied on strings, e.g. for protection against humidity or wear
Definitions
- steel strings are less lively than gut and steel strung rackets have a difierent feel.
- the silk string offers the best solution provided it can be improved as to resiliency and as to waterproof properties.
- the strands of silk are twisted and drawn under desirable tension through an appropriate glue mixture which is held at a carefully regulated temperature.
- the temperature is regulatedaccording to the fluidity of the glue and the appearance of the twisted string.
- the finished string is essential, otherwise the string will almost certainly break at the frame in the stringing process.
- the desired flexibility may be obtained by the use of a satisfactory softening agent in the glue mixture.
- the use of such agent in the required amount tends to confer uponthe string a resin-like surface so that when the string is pulled through a racket form it. slips at intervals as though it were treated with pine resin. Obviously, this condition is altogether undesirable inasmuch as it makes for non-uniformity of tension.
- I add a good lubricant such as castor oil, lard or other vegetable or animal product; Good results have also been had with petroleum oils.
- compositionpf the glue mixture or emulsion may bevaried over rather wide limits according to the characteristics desired in the product.
- Other softening agents such ,as glycol, diethyleine glycerins, etc'., may be substituted for the glycerin used in the present process, and various oils of almost any stituted for the lard.
- a string containing glue as: such is not waterproof. By vproper treatment, however, the glue may be rendered very resistant to the action of moisture.
- the common tanning agents for leather are in general capable of rendering glue moisture-proof. Amon these are formaldehyde, other aldehydes, hexamethylene tetramine, tannic acid, potassium dichromate, and chromium and aluminum salts. .From the standpoint of ease of handling, low price and results obtained, formaldehyde has been most satisfactory. As carried out at present, curing is obtained orlgin may be substring de- A twisted by exposing the twisted string to the vapor of formaldehyde in a closed environment.
- any small surface irregularities may be removed by polishing with lard or other oil.
- a satisfactory string must possess a breakuse of between fifty or sixty strands of 22 thread 13/15 Japan tram.
- strings are wiped off with well qualified or may readily be qualified for other purposes by modifying the glue bath, by proper choice of caplllary bore or other trim, and/or by varying the number of strands. For example it maysreplace raw hide in hookless belt lacing.
- Strings ofa solid color may be providedby simply adding the emulsion or glue mixture. Where more than one color is required, the use .of two or more kinds of colored silk will insure the desired combination of colors.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
'No Drawing.
Patented July 15, 1 930 UNITED STATES PATENT, oFFicE GUSTAVE s. marnnmor ELIZABETH, NEW JERSEY, ASSIGNOR T0 JOHNSON & :ronnson, or NEW BRUNSWICK, NEW JERSEY, A conronnrrou on NEW JERSEY TENNIS STRING and disadvantages of steel strings'are similar to those of silk. Vhether covered or not,
steel strings are less lively than gut and steel strung rackets have a difierent feel.
There are on the market at present only a few synthetic strings. Braided strings are rapidly disappearing. A few special strings, combining gut and silk, have been offered, but their disadvantages over-shadow any apparent advantages.
The silk string offers the best solution provided it can be improved as to resiliency and as to waterproof properties.
After extended experimentation with many raw materials and divers methods of fabrication and treatment, I have devised a comparatively low cost strand which practically equals the resiliency of gut and for durability and over all efficiency is far superior to gut. It possesses the further merit that in appearance it is almost identical with gut in that it is substantially transparent, a
cross-section of the string revealing nofibrous structure. And the new strand may he untwisted with even more difiiculty than is the case with gut strings.
In-the practice of m invention, '1 start with silk in the boiled-o condition, i. e. free from the silk gum, ceresin. of ceresin is highly important for I have found that the presence of this substance is 'a deterrent to successful impregnation and accounts for past failures. A size of silk which has proven satisfactory is 22 thread 13/15 Japan tram.
Having, as stated, completely removed all traces of ceresin, the strands of silk are twisted and drawn under desirable tension through an appropriate glue mixture which is held at a carefully regulated temperature.
The elimination Application filed July 9, 1927. Serial No. 204,667.
In general, the higher the temperature, the better the impregnation. However, it is not desirable to raise the temperature of the glue appreciably beyond 7 0 (1., otherwise hydrolysis of the glue takes place and the finishedstring is likely to be decidedly brittle. The temperature is regulatedaccording to the fluidity of the glue and the appearance of the twisted string.
As a result of testing a number of types of cementing agents such as glass, resins, varnishes, lacquers, etc., I have found that a true colloid in solid form to the jelly form results in a true colloid jelly which shrinks uniformly and dries without any. separation from the strands. I
Inthose tests in which varnishes or lacquers were used, it was found that the resulting strings were quite large, poorly impregnated, slow in drying, and not at all satisfactoryas tennis strings.
F lexibilityinthe finished string is essential, otherwise the string will almost certainly break at the frame in the stringing process. The desired flexibility may be obtained by the use of a satisfactory softening agent in the glue mixture. However, the use of such agent in the required amount tends to confer uponthe string a resin-like surface so that when the string is pulled through a racket form it. slips at intervals as though it were treated with pine resin. Obviously, this condition is altogether undesirable inasmuch as it makes for non-uniformity of tension. To overcome this action of the softening agent, I add a good lubricant such as castor oil, lard or other vegetable or animal product; Good results have also been had with petroleum oils. The oil is stirred into the glue mixture until a uniform emulsion is formed "in which no trace of oil may be observed. Such an emulsion may be kept almost indefinitely with no separation into its components and glycol, triethylene glycol, the various p satisfactory products are given in the accompanying table,
It will be noted. that the compositionpf the glue mixture or emulsion may bevaried over rather wide limits according to the characteristics desired in the product. Other softening agents such ,as glycol, diethyleine glycerins, etc'., may be substituted for the glycerin used in the present process, and various oils of almost any stituted for the lard.
The properties of the finished pendlargely upon its structure. string having from two to four twists to the inch, and referably a twist of three turns to the inch, as proven eminently satisfactbry. A string containing glue as: such is not waterproof. By vproper treatment, however, the glue may be rendered very resistant to the action of moisture. The common tanning agents for leather are in general capable of rendering glue moisture-proof. Amon these are formaldehyde, other aldehydes, hexamethylene tetramine, tannic acid, potassium dichromate, and chromium and aluminum salts. .From the standpoint of ease of handling, low price and results obtained, formaldehyde has been most satisfactory. As carried out at present, curing is obtained orlgin may be substring de- A twisted by exposing the twisted string to the vapor of formaldehyde in a closed environment.
e use of solutions of formaldehyde containing the softening agent used in the glue mixture has also proved satisfactory.
After removal from the curing vessel the strings are stretched tightly and allowed to remain until dry. The quality of the strings is improved somewhat if the drying is conducted under considerable tension.
After the strings are thoroughly dried, any small surface irregularities may be removed by polishing with lard or other oil.
A satisfactory string must possess a breakuse of between fifty or sixty strands of 22 thread 13/15 Japan tram.
sand paper or equivalent, whereupon the strings are wiped off with well qualified or may readily be qualified for other purposes by modifying the glue bath, by proper choice of caplllary bore or other trim, and/or by varying the number of strands. For example it maysreplace raw hide in hookless belt lacing.
Having described my invention, I clann:
synthetic gut, comprising tw sted strands of degummed silk, and an emulsified colloidal bond having lubricating and water-proofing properties.
In testimony whereof I afiix my signature.
GUSTAVE S.MATHEY.
Strings ofa solid color may be providedby simply adding the emulsion or glue mixture. Where more than one color is required, the use .of two or more kinds of colored silk will insure the desired combination of colors.
While the present tended for use as a desired color to the product is mainly in substitute for gut itis
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US204667A US1770794A (en) | 1927-07-09 | 1927-07-09 | Tennis string |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US204667A US1770794A (en) | 1927-07-09 | 1927-07-09 | Tennis string |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1770794A true US1770794A (en) | 1930-07-15 |
Family
ID=22758910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US204667A Expired - Lifetime US1770794A (en) | 1927-07-09 | 1927-07-09 | Tennis string |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1770794A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1703132A1 (en) * | 1967-04-06 | 1972-02-17 | Osaka Gosen Co Ltd | Plastic strings and processes for their manufacture |
| US20080124546A1 (en) * | 2006-11-16 | 2008-05-29 | Nano-Proprietary, Inc. | Buffer Layer for Strings |
| US20080206559A1 (en) * | 2007-02-26 | 2008-08-28 | Yunjun Li | Lubricant enhanced nanocomposites |
| US8713906B2 (en) | 2006-11-16 | 2014-05-06 | Applied Nanotech Holdings, Inc. | Composite coating for strings |
-
1927
- 1927-07-09 US US204667A patent/US1770794A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1703132A1 (en) * | 1967-04-06 | 1972-02-17 | Osaka Gosen Co Ltd | Plastic strings and processes for their manufacture |
| US20080124546A1 (en) * | 2006-11-16 | 2008-05-29 | Nano-Proprietary, Inc. | Buffer Layer for Strings |
| US8713906B2 (en) | 2006-11-16 | 2014-05-06 | Applied Nanotech Holdings, Inc. | Composite coating for strings |
| US20080206559A1 (en) * | 2007-02-26 | 2008-08-28 | Yunjun Li | Lubricant enhanced nanocomposites |
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