US1767764A - Mold wash - Google Patents
Mold wash Download PDFInfo
- Publication number
- US1767764A US1767764A US356299A US35629929A US1767764A US 1767764 A US1767764 A US 1767764A US 356299 A US356299 A US 356299A US 35629929 A US35629929 A US 35629929A US 1767764 A US1767764 A US 1767764A
- Authority
- US
- United States
- Prior art keywords
- mold
- nickel
- wash
- molds
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 38
- 229910052759 nickel Inorganic materials 0.000 description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
- 229910052710 silicon Inorganic materials 0.000 description 14
- 239000010703 silicon Substances 0.000 description 14
- 238000005266 casting Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 229920001800 Shellac Polymers 0.000 description 11
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 11
- 229940113147 shellac Drugs 0.000 description 11
- 235000013874 shellac Nutrition 0.000 description 11
- 239000004208 shellac Substances 0.000 description 11
- 229910000990 Ni alloy Inorganic materials 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/02—Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
- B22D21/027—Casting heavy metals with low melting point, i.e. less than 1000 degrees C, e.g. Zn 419 degrees C, Pb 327 degrees C, Sn 232 degrees C
Definitions
- This invention relates generally to the casting of nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy,
- molten metal is poured into molds, and particularly when molten metals of high melting point, such, for example, as nickel or nickel alloys, are poured into ingot molds from a considerable height, splashing will occur regardless of the amount of care exercised in the pouring. This splashing results in the formation of pellets or waves of metal as the molten material comes into contact with the inside surfaces of the mold.
- Ingot molds ordinarily are made out of cast iron which readily transmit heat. If a high melting point metal such as nickel or Monel metal is being poured, the pellets or Waves of metal splashing onto the surface of the mold become cool. As the pouring continues these pellets may become loosened from the surfaces of the mold and either float to the top of the ingot or become lodged at some other place along the surface of the mold. The resultant ingot therefore, has a rough surface which must be milled off. It usually is necessary to mill off from to inch of the metal in order to remove this rough surface.
- a high melting point metal such as nickel or Monel metal
- our invention provides a method of casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which a mold wash is utilized.
- the utilization of our mold wash results in a casting having a much improved surface.
- Our mold Wash is of a character such that it can be easily applied to the interior of the mold, either b a brush or a spray gun.
- the application 0 the mold wash to the surface of the mold eliminates or decreases the amount of splashing. In case a slight amount of splashing does occur, it decreases the bad effects of such splashing.
- ⁇ Ve have found that very good results are obtained by using a mold wash comprising 50 a deoxidizer, preferably a metallic deoxi- Application filed April 18,
- dizer such as silicon, magnesium, zinc or aluminum, with an organic vehicle such as shellac or tar, or with an inorganic vehicle, such as boraX.
- a mixture of an organic and an inorganic vehicle may be employed with the deoxidizer.
- our preferred mold wash we employ powdered silicon in a shellac vehicle.
- the wash because of its relatively soft nature as compared with the metal of a mold, decreases the amount of splashing during pouring.
- the powdered silicon acts to deoxidize the metal as the latter comes in contact with the mold, as well as to give a smoothing mechanical effect.
- the shellac not only acts as a vehicle to carry the powdered silicon, but it is also a sufficiently good binder so that the use of a bonding material such, for example, as water glass or molasses, is not required.
- the wash acts as an insulating medium for the mold, thereby causing any pellets Which may splash onto the surfaces of the mold to retain their heat longer than they would if they contacted with an iron mold. This de creases the tendency toward segregation on the surfaces of the mold because the pellets tend to melt when the main charge of metal 30 is poured into the mold.
- the surface of an ingot produced in a mold which has been coated with this wash is decidedly superior to that of an ingot made in the same mold without the coating.
- the practice of this invention has resulted in a 50% reduction of milling scrap losses.
- the invention is particularly applicable to the casting of high melting point metals in ingot molds, since in such a process there is a great tendency for splashing of the metal and segregation of the pellets of material which contact with the mold surfaces.
- the invention is also applicable to the casting of lower melting point metals, either in ingot molds or sand molds.
- Our mold wash may also be used in connection with the production of chilled castings.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
Description
Patented June 24, 1930 UNITED STATES PATENT OFFICE AUGUSTUS E. KAYES AND FRITZ MOEHLING, F HUNTINGTON, WEST VIRGINIA, AS-
SIGNORS TO THE INTERNATIONAL NICKEL COMPANY, INC., OF NEW YORK, N. Y.,
A CORPORATION OF DELAWARE MOLD No Drawing.
This invention relates generally to the casting of nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy,
and more particularly to a mold wash and the method of making the same whereby the process of casting nickel or nickel alloys may be efficiently carried out.
Whenever molten metal is poured into molds, and particularly when molten metals of high melting point, such, for example, as nickel or nickel alloys, are poured into ingot molds from a considerable height, splashing will occur regardless of the amount of care exercised in the pouring. This splashing results in the formation of pellets or waves of metal as the molten material comes into contact with the inside surfaces of the mold.
Ingot molds ordinarily are made out of cast iron which readily transmit heat. If a high melting point metal such as nickel or Monel metal is being poured, the pellets or Waves of metal splashing onto the surface of the mold become cool. As the pouring continues these pellets may become loosened from the surfaces of the mold and either float to the top of the ingot or become lodged at some other place along the surface of the mold. The resultant ingot therefore, has a rough surface which must be milled off. It usually is necessary to mill off from to inch of the metal in order to remove this rough surface.
In accordance with our invention, we provide a method of casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which a mold wash is utilized. The utilization of our mold wash results in a casting having a much improved surface. Our mold Wash is of a character such that it can be easily applied to the interior of the mold, either b a brush or a spray gun. The application 0 the mold wash to the surface of the mold eliminates or decreases the amount of splashing. In case a slight amount of splashing does occur, it decreases the bad effects of such splashing.
\Ve have found that very good results are obtained by using a mold wash comprising 50 a deoxidizer, preferably a metallic deoxi- Application filed April 18,
WASH
1929. Serial No. 356,299.
dizer such as silicon, magnesium, zinc or aluminum, with an organic vehicle such as shellac or tar, or with an inorganic vehicle, such as boraX.
If desired, a mixture of an organic and an inorganic vehicle may be employed with the deoxidizer. In our preferred mold wash, we employ powdered silicon in a shellac vehicle. The wash, because of its relatively soft nature as compared with the metal of a mold, decreases the amount of splashing during pouring. The powdered silicon acts to deoxidize the metal as the latter comes in contact with the mold, as well as to give a smoothing mechanical effect. The shellac not only acts as a vehicle to carry the powdered silicon, but it is also a sufficiently good binder so that the use of a bonding material such, for example, as water glass or molasses, is not required.
In addition to decreasing the amount of splashing and also acting as a deoxidizer, the wash acts as an insulating medium for the mold, thereby causing any pellets Which may splash onto the surfaces of the mold to retain their heat longer than they would if they contacted with an iron mold. This de creases the tendency toward segregation on the surfaces of the mold because the pellets tend to melt when the main charge of metal 30 is poured into the mold. The surface of an ingot produced in a mold which has been coated with this wash is decidedly superior to that of an ingot made in the same mold without the coating. The practice of this invention has resulted in a 50% reduction of milling scrap losses.
In preparing the preferred mold wash of silicon and shellac, from two to five parts of commercial powdered silicon are mixed produced combines the deoxidizing properties of silicon with the reducing and bind ing properties of shellac. Both the silicon and the shellac produce a repellant action to the splashing of the metal against the mold surfaces.
The invention is particularly applicable to the casting of high melting point metals in ingot molds, since in such a process there is a great tendency for splashing of the metal and segregation of the pellets of material which contact with the mold surfaces. However, the invention is also applicable to the casting of lower melting point metals, either in ingot molds or sand molds. Our mold wash may also be used in connection with the production of chilled castings.
e have described the present preferred method of practicing our invention and have set forth the proportions which we prefer to use in preparing the mold wash. The inventions may be otherwise practiced and variations in the proportions of the materials making up the mold wash may be employed within the scope of the following claims.
WVe claim:
1. A coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy, comprising a mixture of powdered silicon and a vehicle therefor.
2. A coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% ofthe alloy, comprising a mixture of powdered silicon and an organic vehicle therefor.
3. A coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy, comprising a mixture of powdered silicon and a shellac vehicle.
4. A coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy, comprising a mixture of from two to five parts powdered silicon and from eight to sixteen parts shellac.
5. The process of making a coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or man-- ganese, in which the nickel constitutes at least 30% of the alloy, comprising mixing powdered silicon, shellac and a solvent for the shellac.
6. The process of making a coating or wash for molds for casting nickel or nickel alloys with copper, chromium, iron, or manganese, in which the nickel constitutes at least 30% of the alloy, comprising mixing powdered silicon, shellac and alcohol, and
set our hands.
AUGUSTUS E. KAYES. FRITZ MOEHLIN G.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US356299A US1767764A (en) | 1929-04-18 | 1929-04-18 | Mold wash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US356299A US1767764A (en) | 1929-04-18 | 1929-04-18 | Mold wash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1767764A true US1767764A (en) | 1930-06-24 |
Family
ID=23400907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US356299A Expired - Lifetime US1767764A (en) | 1929-04-18 | 1929-04-18 | Mold wash |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1767764A (en) |
-
1929
- 1929-04-18 US US356299A patent/US1767764A/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2527829A (en) | Foundry additives | |
| US2662820A (en) | Method for producing cast iron | |
| US2197660A (en) | Ferro-alloys and method of producing them | |
| US1767764A (en) | Mold wash | |
| JPS6125454B2 (en) | ||
| US2510155A (en) | Process for treatment of molten stainless steel | |
| US2578794A (en) | Magnesium-treated malleable iron | |
| US2007008A (en) | Copper zinc alloy containing silicon and iron | |
| US1871315A (en) | Casting readily oxidizable metals | |
| US2716604A (en) | Process for producing nodular iron | |
| US2603563A (en) | Prealloy for the production of cast iron and method for producing the prealloy | |
| US1727088A (en) | Method of making rimming steel | |
| US2132276A (en) | Metal mold | |
| US1156093A (en) | White-metal casting and the method of making same. | |
| US1764034A (en) | Alloy | |
| US1965949A (en) | Mold for casting ferrous metals | |
| US1566420A (en) | Mold composition | |
| US1551418A (en) | Process op making heat-resisting alloys | |
| US3744997A (en) | Metallurgical grain refinement process | |
| US283311A (en) | William wilmington | |
| US1753904A (en) | Acid-resistant alloy | |
| US3239898A (en) | Production of high-quality ingots | |
| US1975742A (en) | Composite metal article | |
| US1860852A (en) | Ferrous alloys | |
| US1572382A (en) | Metallic alloy |