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US1684131A - Alloy - Google Patents

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Publication number
US1684131A
US1684131A US92584A US9258426A US1684131A US 1684131 A US1684131 A US 1684131A US 92584 A US92584 A US 92584A US 9258426 A US9258426 A US 9258426A US 1684131 A US1684131 A US 1684131A
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US
United States
Prior art keywords
boron
alloy
titanium
aluminum
alloys
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US92584A
Inventor
Franks Russell
Burnham E Field
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAYNES STELLITE Co
Original Assignee
HAYNES STELLITE CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US1305A external-priority patent/US1675798A/en
Application filed by HAYNES STELLITE CO filed Critical HAYNES STELLITE CO
Priority to US92584A priority Critical patent/US1684131A/en
Application granted granted Critical
Publication of US1684131A publication Critical patent/US1684131A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/007Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel

Definitions

  • Our new alloys contain as essential components nickel or cobalt. in preponderatin proportion, usually substantialamounts 0 tungsten, small amounts of boron up to about 1%, and substantial amounts of ti- Ytanium. .minum are usually present and have more or less effect onthe. properties of the alloy.
  • Molybdenum or uranium may be present,- 7 replacing part or all of the tungsten.
  • the desired hardnesjr has been obtained by adding a consid able amount of aluminum over and above that contained ,in the alloys used as raw materials. A great deal of trouble was encountered through oxidation of this excess aluminum and in addition the tungsten segregated very rapidly as soon as the aluminum was added. We have now producedalloys.
  • Alloys made inaccordance with our invention have a preferred composition range of 5 to 12% tungsten, 6 to. 12% titanium, 3.5 to 6% silicon, 3 to 5% aluminum, up to 1% boron, with the balance principally nickel or cobalt.
  • the boron may be added in the form of" ferro-boron, chromiumboron, boron carbide or any other "suitable alloy of boron. mium-boron-is used, small am'o'untsof iron or chromium will be introduced into; the
  • the other raw materlals frequently contain small amounts of iron -so that the iron 'content of. the final Y boroncontaining materials together in a graphite cruclble in any suitable type oi"- furnace, raising the temperature of the molten bath to .1600-1800 C., and then stlrring the titanium in the form. ofsome' suitable titanium alloy into the melt.
  • the other raw materlals frequently contain small amounts of iron -so that the iron 'content of. the final Y boroncontaining materials together in a graphite cruclble in any suitable type oi"- furnace, raising the temperature of the molten bath to .1600-1800 C., and then stlrring the titanium in the form. ofsome' suitable titanium alloy into the melt.
  • titanium alloy will dissolve quite readily if vlgorous stirring "is employed.
  • the melt may be poured at once into sand, carbon, or
  • a titanium alloy whichhas given good results in this work contains 64.8% tltanium, 27.3% aluminum, 2.2% silicon, 21% iron and 1.0% carbon. It is friable and ma *be'crushed to a powder. The best results ave been obtained .when it was crushed to approximately 40 mesh. No aluminum except that contained in the titanium .alloy is added to the melt.
  • One melt of this cutting tool alloy which has the proper hardness and good cutting quality had the following composition: tungsten 7.23%,titanium 7.20%, aluminum 3.90%,
  • All the alloys comprised within the invention are suitable for tools for the high--' of cast iron, steel and" semithey are also useful for'other, high-speed is here used in the same sense as in the common expression speed cutting steel, though purposes.
  • the term high-speed steel, and imports conditions 10f such (severity carbon steels subjected to them would be Serial No. 1,305, filed I January 8, 1925, of which this application,
  • a cutting tool composed ofan alloy containing from 3 to 5% aluminum, 3.5 to 6% silicon, 5 to' 12% tungsten, 6 to 12% titanium, boron in substantial and effective amounts up to 1%, cipally nickel.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Description

high-speed cutting tools and'the like which" Patented Sept. 11,1928.
umrao ST A 1. .1 1 TES PATENT OFFICE.
:eUssELL FRANKS, or ELMIIUBST, Ann 11mm 11. HELD, or 'nouenns'romnnw YORK, assrenons 'ro mamas srnmrra COMPANY, A. conrdanrron or mnmmt l io nra'wing Original applieationfiled January. 8, 1925, Serial No. 1,305. Divided 'fl1ed March 5, 1926. Seria1 No. 92,584.
' Our invention relates to alloys for use as are similar in general physical properties and structural characteristics to those obtained by H. S. Cooper, U. S. Patents Nos. 1,221,769, 1,277,0ie, 1,278,304., 1,350,359 and 1,161,178. a
Our new alloys contain as essential components nickel or cobalt. in preponderatin proportion, usually substantialamounts 0 tungsten, small amounts of boron up to about 1%, and substantial amounts of ti- Ytanium. .minum are usually present and have more or less effect onthe. properties of the alloy.
Molybdenum or uranium may be present,- 7 replacing part or all of the tungsten. Heretofore in' preparing alloys such-as those. disclosed by Cooper in the patents above mentioned, the desired hardnesjrhas been obtained by adding a consid able amount of aluminum over and above that contained ,in the alloys used as raw materials. A great deal of trouble was encountered through oxidation of this excess aluminum and in addition the tungsten segregated very rapidly as soon as the aluminum was added. We have now producedalloys.
of this type in which, hardness and good cutting properties are secured by raising the titanium content and correspondingly decreasing the aluminum oxidation of aluminum and the segregation of tungsten are largely avoided.
We have found t at the-hardness of-the alloyis increased by the presence of boron therein, and that there is a marked refinement of grain. the boron seems to actin conjunction with the titanium ,in' producing a much better cutting tool than can be made from alloys of this type which do not contain boron.-
Alloys made inaccordance with our invention have a preferred composition range of 5 to 12% tungsten, 6 to. 12% titanium, 3.5 to 6% silicon, 3 to 5% aluminum, up to 1% boron, with the balance principally nickel or cobalt. The boron may be added in the form of" ferro-boron, chromiumboron, boron carbide or any other "suitable alloy of boron. mium-boron-is used, small am'o'untsof iron or chromium will be introduced into; the
final alloy, but these have no appreciable Minor amounts of silicon and alu-f boron 0.55%, nickel remainder.
content, whereby We have also found that When ferro-boron or chro.-
and um nimation efi'ect on-its properties. The other raw materlals frequently contain small amounts of iron -so that the iron 'content of. the final Y boroncontaining materials together in a graphite cruclble in any suitable type oi"- furnace, raising the temperature of the molten bath to .1600-1800 C., and then stlrring the titanium in the form. ofsome' suitable titanium alloy into the melt. The
titanium alloy will dissolve quite readily if vlgorous stirring "is employed. The melt may be poured at once into sand, carbon, or
graphite molds. A titanium alloy whichhas given good results in this work contains 64.8% tltanium, 27.3% aluminum, 2.2% silicon, 21% iron and 1.0% carbon. It is friable and ma *be'crushed to a powder. The best results ave been obtained .when it was crushed to approximately 40 mesh. No aluminum except that contained in the titanium .alloy is added to the melt. One melt of this cutting tool alloy which has the proper hardness and good cutting quality had the following composition: tungsten 7.23%,titanium 7.20%, aluminum 3.90%,
silicon 4.40%, iron 0.95%, carbon While in theexamples above given nickel has been specified as the principal.constituentof the alloy, itis to be understood that cobalt-may be. substituted for nickel or used with the same, and that nickel is useddn the claims-[to mean either nickel or cobalt 'or both. Y
In our application,
have somewhat broadly 1s a division, we
claimed alloys of thisclass containing boron and either titanium or zirconium, and we have also claimed specifically such of said alloys as are characterized by the. use of boron and zirconium.
All the alloys comprised within the invention are suitable for tools for the high--' of cast iron, steel and" semithey are also useful for'other, high-speed is here used in the same sense as in the common expression speed cutting steel, though purposes. The term high-speed steel, and imports conditions 10f such (severity carbon steels subjected to them would be Serial No. 1,305, filed I January 8, 1925, of which this application,
that ordmary .6 to 12% titanium,
for" the high-speed cutting of cast iron which contains 3% to 5% of aluminum, 3.5% to 6% of silicon, 5 to 12% of tungsten, -S to 12% or titanium, and approximately 0.5% of boron, with the balance principally nickel. v
3. A cutting tool composed ofan alloy containing from 3 to 5% aluminum, 3.5 to 6% silicon, 5 to' 12% tungsten, 6 to 12% titanium, boron in substantial and effective amounts up to 1%, cipally nickel.
In testimony whereof, We aflix our signatures.
the balance being prin- RUSSELL FRANKs. BURNHAM E. FIELD.
US92584A 1925-01-08 1926-03-05 Alloy Expired - Lifetime US1684131A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US92584A US1684131A (en) 1925-01-08 1926-03-05 Alloy

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1305A US1675798A (en) 1925-01-08 1925-01-08 Alloy and process for making same
US92584A US1684131A (en) 1925-01-08 1926-03-05 Alloy

Publications (1)

Publication Number Publication Date
US1684131A true US1684131A (en) 1928-09-11

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2515184A (en) * 1941-01-13 1950-07-18 Int Nickel Co Age hardenable nickel alloys
US2882190A (en) * 1954-07-19 1959-04-14 Gen Motors Corp Method of forming a sintered powdered metal piston ring
US2884687A (en) * 1959-05-05 Wear-resistant sintered powdered metal
US2887765A (en) * 1954-07-19 1959-05-26 Gen Motors Corp Sintered powdered copper base bearing
US2983602A (en) * 1957-09-24 1961-05-09 Armour Res Found Cobalt alloys

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2884687A (en) * 1959-05-05 Wear-resistant sintered powdered metal
US2515184A (en) * 1941-01-13 1950-07-18 Int Nickel Co Age hardenable nickel alloys
US2882190A (en) * 1954-07-19 1959-04-14 Gen Motors Corp Method of forming a sintered powdered metal piston ring
US2887765A (en) * 1954-07-19 1959-05-26 Gen Motors Corp Sintered powdered copper base bearing
US2983602A (en) * 1957-09-24 1961-05-09 Armour Res Found Cobalt alloys

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