US1662299A - Road binder - Google Patents
Road binder Download PDFInfo
- Publication number
- US1662299A US1662299A US539032A US53903222A US1662299A US 1662299 A US1662299 A US 1662299A US 539032 A US539032 A US 539032A US 53903222 A US53903222 A US 53903222A US 1662299 A US1662299 A US 1662299A
- Authority
- US
- United States
- Prior art keywords
- bitumen
- acid
- asphalt
- sulphite liquor
- road binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011230 binding agent Substances 0.000 title description 3
- 239000010426 asphalt Substances 0.000 description 15
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 10
- 239000002253 acid Substances 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000011280 coal tar Substances 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- NGWKGSCSHDHHAJ-YPFQVHCOSA-N Liquoric acid Chemical compound C1C[C@H](O)C(C)(C)C2CC[C@@]3(C)[C@]4(C)C[C@H]5O[C@@H]([C@](C6)(C)C(O)=O)C[C@@]5(C)[C@@H]6C4=CC(=O)C3[C@]21C NGWKGSCSHDHHAJ-YPFQVHCOSA-N 0.000 description 1
- NGWKGSCSHDHHAJ-UHFFFAOYSA-N Liquoric acid Natural products C1CC(O)C(C)(C)C2CCC3(C)C4(C)CC5OC(C(C6)(C)C(O)=O)CC5(C)C6C4=CC(=O)C3C21C NGWKGSCSHDHHAJ-UHFFFAOYSA-N 0.000 description 1
- 229920002253 Tannate Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
Definitions
- bituminous substances such as asphalt, coal tar and wax tailings.
- bitumen which is preferably but not necessarily rendered basic by the addition, if necessary, of an alkali.
- Coal tar may be used for this purpose and does not require the addition of any alkaline 'substance. If liquid asphalt is used, this being acid in its natural state, I add caustic soda, calcium hydroxide or ammonia in the proportion of from 2% to 5 per cent.' Wax tailings may be used in place of asphalt or coal tar but requires to-be neutralized by the use of alkali. It Will be understood of course that mixtures of various bitumens may be employed, suflicient alkali being employed to render the whole somewhat alkaline in reaction.
- the acid employed has the effect of reducmg the viscosity of .the final product, whether tar, asphalt or wax tailings be used as a base, so that it distributes" itself through the gravel, stone or sand with which it is used, more readily and permeates much more quickly than the, ordinary bitumens alone. I also find that it affords morebond and, when-incorporated with aggregates, setsmore firmly.
- the sulphite liquor increases the bond and, being extremely hygroscopic, pievents the volatilization of the bitumen, thus acting as a preservative, greatly increasing the life of the bitumen.
- the acetate of lime or lactic tannate, which are believed to be formed, also-prevent the oil in the tar or asphalt from being volatilized and in some way cause the sulphite liquor to amalgamate with the bitumen.
- the road inder which comprises a basic bituminous substance, sulphite liquor, and lactic acid.
- the road binder which comprises five parts of'(a) asphalt and lime 2 to 5 per cent of the asphalt and (b) one part of sulphite liquor of about 30 Baum to which has been added lactic acid in the proportion of four to eight ounces of acid to each gallon of the sulphite liquor.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Working-Up Tar And Pitch (AREA)
Description
Patented Mar. 13, 1928.
UNITED sures PATENT orica.
MICHAEL H. 'COUGHLIN, OF STOUGH'I'ON, MASSACHUSETTS.
ROAD BINDER.
Ho Drawing.
ing qualities of bituminous substances such as asphalt, coal tar and wax tailings.
In practising my invention, I use as one element, a bitumen which is preferably but not necessarily rendered basic by the addition, if necessary, of an alkali. Coal tar may be used for this purpose and does not require the addition of any alkaline 'substance. If liquid asphalt is used, this being acid in its natural state, I add caustic soda, calcium hydroxide or ammonia in the proportion of from 2% to 5 per cent.' Wax tailings may be used in place of asphalt or coal tar but requires to-be neutralized by the use of alkali. It Will be understood of course that mixtures of various bitumens may be employed, suflicient alkali being employed to render the whole somewhat alkaline in reaction.
The bitumen, after being rendered alkaline if necessary, is mixedwith a. solution which is made as follows :-I take sulphite liquor of approximately 30 Baum or a liquid made by dissolving eight (8.) pounds of sulphite powder in one ('1) gallon of water which gives a practically equivalent solution, and to this I add an'organic acid as, for instance, lactic or acetic acid, using from four (4). to eight (8) ounces of aci for each gallonof sulphite liquor. In the case of either acid, the strength is -44= Baum.
The alkaline bitumen is then mixed with Application filed February 24, 1922. Serial No. 539,032.
The acid employed has the effect of reducmg the viscosity of .the final product, whether tar, asphalt or wax tailings be used as a base, so that it distributes" itself through the gravel, stone or sand with which it is used, more readily and permeates much more quickly than the, ordinary bitumens alone. I also find that it affords morebond and, when-incorporated with aggregates, setsmore firmly.
The sulphite liquor increases the bond and, being extremely hygroscopic, pievents the volatilization of the bitumen, thus acting as a preservative, greatly increasing the life of the bitumen. The acetate of lime or lactic tannate, which are believed to be formed, also-prevent the oil in the tar or asphalt from being volatilized and in some way cause the sulphite liquor to amalgamate with the bitumen.
I find that when mingled with a proper proportion of suitable aggregates such as fine gravel, sand or broken stone, the composition may be laid cold, and when so laid, will set satisfactorily and have excellent wearing qualities due chiefly, I believe, to the factthat the oils contained in the bitumen do not volatilize readily owing to the presence of the reaction products of the acids employed. Organic acid as used in the appended claims includes any capable of performing those functions outlined to provide a satisfactory final product of the type described.
What I claim is '1. The road inder which comprises a basic bituminous substance, sulphite liquor, and lactic acid.
2. The road binder which comprises five parts of'(a) asphalt and lime 2 to 5 per cent of the asphalt and (b) one part of sulphite liquor of about 30 Baum to which has been added lactic acid in the proportion of four to eight ounces of acid to each gallon of the sulphite liquor.
the sulphite liquor and acid at the ratio oh In testimony whereof I aflix my signature.
five (5) parts of bitumen to one (1) of sulphite liquor and the whole thoroughly stirred to render it-homogeneous.
MICHAEL F. CQUGHLIN;
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US539032A US1662299A (en) | 1922-02-24 | 1922-02-24 | Road binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US539032A US1662299A (en) | 1922-02-24 | 1922-02-24 | Road binder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1662299A true US1662299A (en) | 1928-03-13 |
Family
ID=24149473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US539032A Expired - Lifetime US1662299A (en) | 1922-02-24 | 1922-02-24 | Road binder |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1662299A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2693424A (en) * | 1951-12-28 | 1954-11-02 | Bennett Inc | Sized paper product, size and method of making the same |
| US2978342A (en) * | 1957-08-27 | 1961-04-04 | Exxon Research Engineering Co | Anti-stripping additive for asphalts |
| US3817643A (en) * | 1971-11-17 | 1974-06-18 | Roadway Int Corp | Roadway base and composition therefor |
-
1922
- 1922-02-24 US US539032A patent/US1662299A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2693424A (en) * | 1951-12-28 | 1954-11-02 | Bennett Inc | Sized paper product, size and method of making the same |
| US2978342A (en) * | 1957-08-27 | 1961-04-04 | Exxon Research Engineering Co | Anti-stripping additive for asphalts |
| US3817643A (en) * | 1971-11-17 | 1974-06-18 | Roadway Int Corp | Roadway base and composition therefor |
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