US1531324A - Detergent - Google Patents
Detergent Download PDFInfo
- Publication number
- US1531324A US1531324A US495760A US49576021A US1531324A US 1531324 A US1531324 A US 1531324A US 495760 A US495760 A US 495760A US 49576021 A US49576021 A US 49576021A US 1531324 A US1531324 A US 1531324A
- Authority
- US
- United States
- Prior art keywords
- cymene
- detergent
- salts
- sulphoacids
- soaps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title description 12
- 229930007927 cymene Natural products 0.000 description 23
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 11
- 239000000344 soap Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003925 fat Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000352 p-cymenyl group Chemical class C1(=C(C=C(C=C1)C)*)C(C)C 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- -1 sodium Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/32—Organic compounds, e.g. vitamins containing sulfur
Definitions
- cymene and the salts of the sulphoacids of cymene may be incorporated with saponaceous bodies, either after, or during, their emulsification, producing resulting compounds, or mixtures, possessing high detergent, antiseptic and germicidal properties.
- cymene we mean either the chemically, or commercially, pure cymene, or the crude cymene-of the waste sulphite turpentine, obtained as a by-product in the production of paper.
- salts of the sulphoacids of cymene we mean those salts of the mono-, or multi-, sulphoacids of cymene which are dissolvable, or miscible, with the particular saponaceous body with which they are employed, producing results having detergent powers greater than the employed saponaceous body.
- alkali salts such as sodium
- potassium and ammonium salts of the sulphoacids although other salts have valuable properties for particular uses.
- a soap containing an alkali salt of a sulphoacid of cymene ROBERT WOTHERSPOON.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Patented Mar. 31, 1925.
UNITED STATES PATENT OFFICE.
JOSEF HANS WEISS, OF BROOKLYN, AND ROBERT WOTHERSPOON, OF JAMAICA, NEW
YORK, ASSIGNORS T ORBIS PRODUCTS TRADING- CO., INC., 01! NEW YORK, N. Y.
DETERGENT.
No Drawing.
New York, and State of New York, have invented new and useful Improvements in Detergents, of which the following is a full, clear, and exact specification. Our invention relates to detergents and refers particularly to detergent soaps.
We have found that cymene and the salts of the sulphoacids of cymene possess extraordinary and highly valuable detergent properties capable of practical application in the production of soaps and similar products. The value of these products for detergent purposes is enhanced by our discovery that they are soluble in saponaceous bodies, thus making them suitable for incorporation with saponified fat and saponified oil soaps with the production of products having detergent values greatly in excess of the soaps not so incorporated. I i
Without entering into a discussion of the several theories regarding the chemical and physical conditions and reactions incident to detergent bodies and their use, we,would state that cymene and these cymene compounds have the characteristics of colloids, possessing high viscosity and low surface tension, in addition to which they possess strong emulsifying properties. i
We have found that cymene and the salts of the sulphoacids of cymene may be incorporated with saponaceous bodies, either after, or during, their emulsification, producing resulting compounds, or mixtures, possessing high detergent, antiseptic and germicidal properties. e
We have further found that cymene and 41 the salts of the sulphoacids of cymene have strong odor destroyin properties and that their use in conjunctlon with odoriferous saponaceous bodies will destroy the odors, thus producin odorless, or practically odorless, compoun s. 7
Application filed August 26, 1921.
Serial No. 495,760.
We have found, for example, that when 2% of sodium cymene sulphonic acid are added to a soap composed of saponified fat, the detergent properties of the original saponified fatshave been increased 65% and that, at the same time, the resulting product is odorless, antiseptic and ermicldal, thus possessing greatly increased value over the original saponified fats.
The addition of cymene and the salts of the sulphoacids of cymene will convert soft soaps, such as oleic acid soaps, into hard soaps, irrespective of whether the cymene or the salt of the sulphoacid of cymene is added during, or after, the production of the soap. This is a most valuable attribute of these chemicals.
By cymene we mean either the chemically, or commercially, pure cymene, or the crude cymene-of the waste sulphite turpentine, obtained as a by-product in the production of paper. 1
By salts of the sulphoacids of cymene we mean those salts of the mono-, or multi-, sulphoacids of cymene which are dissolvable, or miscible, with the particular saponaceous body with which they are employed, producing results having detergent powers greater than the employed saponaceous body.
Among the salts of the sulphoacids of cymene which we have found particularly valuable are the alkali salts, such as sodium,
potassium and ammonium salts of the sulphoacids, although other salts have valuable properties for particular uses.
For clearness of definition and classification, we employ the words cymene bodies in our claims to mean cymene and salts of the sulphoacids of cymene, as described A above.
. or one salt of a su phoacid of cymene, or'a mixture of several, may be employed and a singlesaponaceous body, or a mixture. of several, may also be employed WVe do not limit ourselves to the particular 2. A soap containing sodium salt of a chemicals and steps of process particularly sulphoacid of cymene. described, all of which may be Varied with- Signed at New York, in the county of out going beyond the scope of our invention New York and State of New York, this 24th 5 as described and claimed. day of August, 1921.
lVhat We claim is J OSEF HANS \VEISS.
1. A soap containing an alkali salt of a sulphoacid of cymene. ROBERT WOTHERSPOON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US495760A US1531324A (en) | 1921-08-26 | 1921-08-26 | Detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US495760A US1531324A (en) | 1921-08-26 | 1921-08-26 | Detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1531324A true US1531324A (en) | 1925-03-31 |
Family
ID=23969891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US495760A Expired - Lifetime US1531324A (en) | 1921-08-26 | 1921-08-26 | Detergent |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1531324A (en) |
-
1921
- 1921-08-26 US US495760A patent/US1531324A/en not_active Expired - Lifetime
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