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US1580444A - Metallic alloy - Google Patents

Metallic alloy Download PDF

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Publication number
US1580444A
US1580444A US31671A US3167125A US1580444A US 1580444 A US1580444 A US 1580444A US 31671 A US31671 A US 31671A US 3167125 A US3167125 A US 3167125A US 1580444 A US1580444 A US 1580444A
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US
United States
Prior art keywords
alloy
gold
silver
chromium
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US31671A
Inventor
Thomas P Shields
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Shields & Moore
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Shields & Moore
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Publication date
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Priority to US31671A priority Critical patent/US1580444A/en
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Publication of US1580444A publication Critical patent/US1580444A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/02Alloys based on gold

Definitions

  • I employ about 58.3% of fine golo, silver, 13% of zinc and 25.2 2 of copper. This produces an alloy which is relatively low in gold, but possesses the property of not readily tarnishing, and this alloy will be found to have the desired green gold color, and. will have good working properies. lhis alloy is very cheap to produce, and can be readily worked. with ordinary goldsmiths tools, and also can be readily enameled.
  • the amount of silver can be great-- end if desired can be omitted ly reduced
  • i0% of w ⁇ tine gold, of chromium, 30 of copper, 20% of zinc and no silver are employed.
  • the amount of gold is relatively low so that the alloy is cheaply produced, and is very suitable for making up jewelry.
  • the proportions 7 1 oi. cnromiuni, 2% of tiuc' it is preferable to inthe constituents can Application sacs May 20, 1925. Bass No. 31,671.
  • the final alloys do not contain any of the ,metals of the platinum group, which have heretofore been used in alloys of this general class, for the prevention of tarnishing.
  • the metals of this group however are extremely expensive, and l find that the alloys produced in accord ance with the present invention arqisubstan tially free from tendency to tarnish, even in the form of jewelry about 10 tov14 carat.
  • the final alloy can of course contain smell and somewhat immaterial amounts of other substances, which do not materially alter the properties of the final alloy. Thus, in commercial practice, using metals of commercial qualities, some minor amounts of" impurities may be introduced.
  • An intermediate alloy consisting of 1 to 10 parts of chromium, 24 to ports of eoppcn lO to 30 purts of zinc, together with some silver but not substantially above 15 parts thereof. 4 2.
  • An intermediate alloy consisting esseni ially of 8 to 10 parts of chromium, 24 to *ter together amounting to at least 8% of 50 parts of copper, and 10 to 13 parts of the total alloy. zinc. 4;.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Adornments (AREA)

Description

letented Apr. l 3.5326.
STATES PATENT OFFICE.
TEQZi'IXl-E P. SHIELDS, 035 NEW YGRK, N. Y., ASSIGNOR TO SHIELD & MQORE, A FIRM CQNSEQTHTG OI" TEOEAE Ti. SHIELDS AND A. MOORE, OF NEW YORK, N. Y.
METALLIC ALLOY.
Ito Brewing.
To all whom may concern:
tie it known that I THOMAS P. Sinmns a i 1r itizen of the Bolted btetes, residing at New York Git New York have invented certain tion with-several. specific examples but it is 15 to he understood that the invention is not restricted to these specific examples.
In s first example, I employ about 58.3% of fine golo, silver, 13% of zinc and 25.2 2 of copper. This produces an alloy which is relatively low in gold, but possesses the property of not readily tarnishing, and this alloy will be found to have the desired green gold color, and. will have good working properies. lhis alloy is very cheap to produce, and can be readily worked. with ordinary goldsmiths tools, and also can be readily enameled.
In this example, as in several of the other 30 examples, the amount of silver can be great-- end if desired can be omitted ly reduced,
and if it 18 desired, to decrease altogether, the amount silver, crease the amount 0t chromium proportionand an alloy to form a good substitute for old, from which silver is entirely absent, would contain about 8% of chr0- mium as a minimum. I
in another particular example, i0% of w {tine gold, of chromium, 30 of copper, 20% of zinc and no silver are employed. In this alloy it isnoted that the amount of gold is relatively low so that the alloy is cheaply produced, and is very suitable for making up jewelry.
The proportions 7 1 oi. cnromiuni, 2% of tiuc' it is preferable to inthe constituents can Application sacs May 20, 1925. Bass No. 31,671.
be varied substantially, and the following table illustrates in a general Way the amount of variation which csnbe had, While still giving very satisfactory products Percent. Gold 4012060 Copper 24m Zinc 10 to 30 Silver 0 to 15 Chromium i 1 to 10 In making up the alloy, I preferably mix together the chromium, copper and zinc (and silver if it is-to be used) in the proportion in which they are toaexist in the final alloy. These'metals can be mixed together, melted and granulated, to form a. stock alloy, and the desired amount of this is added to the desired amount of fine gold, to give the percentage of gold desired, and again melted and stirred, to give the desired tine product.
The final alloys, as will be noted, do not contain any of the ,metals of the platinum group, which have heretofore been used in alloys of this general class, for the prevention of tarnishing. The metals of this group however are extremely expensive, and l find that the alloys produced in accord ance with the present invention arqisubstan tially free from tendency to tarnish, even in the form of jewelry about 10 tov14 carat.
The final alloy can of course contain smell and somewhat immaterial amounts of other substances, which do not materially alter the properties of the final alloy. Thus, in commercial practice, using metals of commercial qualities, some minor amounts of" impurities may be introduced.
1 claim v 1. An intermediate alloy consisting of 1 to 10 parts of chromium, 24 to ports of eoppcn lO to 30 purts of zinc, together with some silver but not substantially above 15 parts thereof. 4 2. An intermediate alloy consisting esseni ially of 8 to 10 parts of chromium, 24 to *ter together amounting to at least 8% of 50 parts of copper, and 10 to 13 parts of the total alloy. zinc. 4;. A gold alloy consisting essentially of 3. A gold alloy "consisting of 40 to 60% 4:0 to 60% of gold, 8 to 10% of chromium,
efgold, 24110 30% of Copper, to 30% of to of copper, and 10 to 30% o'fzinc. zinc, 1 to 10% ofchmmium, and some silver, In testimony whereof I aflix my signature. but not more than 15% thereof, the two lat- I THOMAS P. SHIELDS.
US31671A 1925-05-20 1925-05-20 Metallic alloy Expired - Lifetime US1580444A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE750343C (en) * 1937-04-24 1945-01-09 Heraeus Gmbh W C Gold alloys for wedding rings
US2654146A (en) * 1949-04-02 1953-10-06 Wilson H A Co Gold base alloy
US4266973A (en) * 1979-12-14 1981-05-12 The J. M. Ney Company Tarnish-resistant gold color alloy and dental restorations employing same
US4464213A (en) * 1982-09-30 1984-08-07 Nielsen John P Nobleization of beta brass
FR2579624A1 (en) * 1985-04-02 1986-10-03 G C Dental Ind Corp DENTAL ALLOY AU-CU-ZN SUPERELASTIC
US5045411A (en) * 1990-01-10 1991-09-03 P.M. Refining, Inc. Alloy compositions

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE750343C (en) * 1937-04-24 1945-01-09 Heraeus Gmbh W C Gold alloys for wedding rings
US2654146A (en) * 1949-04-02 1953-10-06 Wilson H A Co Gold base alloy
US4266973A (en) * 1979-12-14 1981-05-12 The J. M. Ney Company Tarnish-resistant gold color alloy and dental restorations employing same
US4464213A (en) * 1982-09-30 1984-08-07 Nielsen John P Nobleization of beta brass
FR2579624A1 (en) * 1985-04-02 1986-10-03 G C Dental Ind Corp DENTAL ALLOY AU-CU-ZN SUPERELASTIC
US4690799A (en) * 1985-04-02 1987-09-01 G-C Dental Industrial Corp. Superelastic dental Au-Cu-Zn alloys
US5045411A (en) * 1990-01-10 1991-09-03 P.M. Refining, Inc. Alloy compositions

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