US1549615A - Hard-metal alloy and the process of making same - Google Patents
Hard-metal alloy and the process of making same Download PDFInfo
- Publication number
- US1549615A US1549615A US672014A US67201423A US1549615A US 1549615 A US1549615 A US 1549615A US 672014 A US672014 A US 672014A US 67201423 A US67201423 A US 67201423A US 1549615 A US1549615 A US 1549615A
- Authority
- US
- United States
- Prior art keywords
- metal
- hard
- alloy
- metal alloy
- making same
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 6
- 229910001092 metal group alloy Inorganic materials 0.000 title description 4
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 229910045601 alloy Inorganic materials 0.000 description 12
- 239000000956 alloy Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 8
- 239000010937 tungsten Substances 0.000 description 8
- 229910052721 tungsten Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 101710148054 Ketol-acid reductoisomerase (NAD(+)) Proteins 0.000 description 1
- 101710099070 Ketol-acid reductoisomerase (NAD(P)(+)) Proteins 0.000 description 1
- 101710151482 Ketol-acid reductoisomerase (NADP(+)) Proteins 0.000 description 1
- 235000013382 Morus laevigata Nutrition 0.000 description 1
- 244000278455 Morus laevigata Species 0.000 description 1
- MEOSMFUUJVIIKB-UHFFFAOYSA-N [W].[C] Chemical compound [W].[C] MEOSMFUUJVIIKB-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S76/00—Metal tools and implements, making
- Y10S76/05—Electric welding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S76/00—Metal tools and implements, making
- Y10S76/11—Tungsten and tungsten carbide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S76/00—Metal tools and implements, making
- Y10S76/12—Diamond tools
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/27—Cutters, for shaping comprising tool of specific chemical composition
Definitions
- -My invention relates tohard metal alloys. More particularly, it relates to alloyed tun stic' carbide which alloy is suitable for making working implements-of various sorts and hones.
- auxil'ia metalof a considerably lower melting p'omt as, for instance, iron, cobalt or nickel, in quantitles' up to a maximum of p 10- per cent.
- a tungstic' metal thus consti- To make the new allo s,--'it carbide. containing from 3 to 10 per cent carif. occurs .at t'emperaturesjwhichd-ie in the neighborhood of 1000 degrees belowjthe. 9:
- the new alloy is not interior fin res eat to hardness to the known tiihgstic carbi e alloys and is quiteconsiderably sir-- to press into a body' oi pulvcrized-rtungstic "together with' a'nflauxiliary' metal? in 'a divided state and in a quantity-within sinteringjtemperature.
- the alloy of invention difiers from" 's advantageous.
- iron, cobaltor nickel. base metals may be m a'finely divided form.
- the tem'- perature at which the sinterin occurs, is. affected by the quantity oi the. a 'xed'aux'-' iliary metal, which can be'pm ade as high as 10 cent of the alloy.
- admixture of 5 per cent cobalt has proved- 7o two or several of the auxiliary metalsma 76 be addedv toe-the tungstic powder-in whic case'the auxil ary, metals can be taken-in- -any suitable ratio to each.
- b t 5 3 must not, all told, make up more than 10, 1 per cent of the total qggntity 'of thefalloy 'Iihe sintering of the dies, wh chibodies areiormedv for instance by hydraulicipressure, can be efiected' by heating'them--in- ⁇ a h protective atmosphere such as'a-n atmosphere" of hydrogen, nitrogen, argon, illuminating 88 gas, carbonic oxide, or an admixture ofsuch gases, or the sintering can be-e'fi'ecte'd by embedding 1: e'bodies in carboni-graphiteand; the like.
- Siiitable- 1 temperature ay be found between 1 500. andf gqq v grees'C-.fa
- a hard-metal allo comprising a ca'r alloy having, inaddition, a metalgofa con:
- H ranges from 3 to 10% of the tungsten, said: alloy having iron, the latter forming not more than 10% of the content.
- the proportions of the tungsten carbon and of the metal being respectively not more than 80% of tungsten, 10% of carbon and 10% of the metal.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Description
' Aug-1 11",: l
. NITEDf ESTATE-S.
sc'n n'ogmn'br 15mm, 01mm, 'nssrenon roommat- M1329 0011mm, A-conrom'nouon NEW 2031:. p I
m i na I i ibima ma mmam Be it known that PI, KARI: '8"
citizen: qt thefGerman Realm, residingat Lichtenberg, near Berlin, Germany, have-1nin Hardf Metal Alloys and the Processes of vented certain new and useful Improvements Making T'Same, of which the following is a which is {particularly suitablefor making known alloys primarily'by'consisting of a" tungstic carbide with a carbon content of from 4: to 10 percent, in combination with specification. 1-
-My invention relates tohard metal alloys. More particularly, it relates to alloyed tun stic' carbide which alloy is suitable for making working implements-of various sorts and hones.
an auxil'ia metalof a considerably lower melting; p'omt as, for instance, iron, cobalt or nickel, in quantitles' up to a maximum of p 10- per cent. A tungstic' metal thus consti- To make the new allo s,--'it carbide. containing from 3 to 10 per cent carif. occurs .at t'emperaturesjwhichd-ie in the neighborhood of 1000 degrees belowjthe. 9:
-- perioi" to: these for strength.
Q -fin'ely J thelimits specified, and to heat this Body to .j 35. auxih 'e.
tutes the .pr'edominating element amounting I te at least '80 per cent of the total content -'of'the alloy.- The new alloy is not interior fin res eat to hardness to the known tiihgstic carbi e alloys and is quiteconsiderably sir-- to press into a body' oi pulvcrized-rtungstic "together with' a'nflauxiliary' metal? in 'a divided state and in a quantity-within sinteringjtemperature. -The effect of the 7 ;metal is to" reducethe' sintering point o body to such' an extent that it '-;.:1;, going method is considerably cheaper easier and simpler than the methods used hereto: :iore inthe prior methodsiand: a temperature of them 2500degrees must ,be. obtained." Another ob'ect of 'myjinvention-"is' that inasmuch-as tehody maybe pr, sintered in a manner well known,"itii;-os j" sible'to make the-'bodyintoany desired'form, such" as. is obtained. onlyjwith. greatflifliv v h a e p d d .ei Powder from h m hw; q y
when other processes are used.
- and ear-bide can be i sed as the main-materia carbl fri'zingtung Applicationflled emb r-en; was. Serial no. 072.014.
The alloy of invention difiers from" 's advantageous.
ing-point'ofthe purecarbide. The-forc v p v bide of-tungstemthe'car oncontent of which. ranges from 3 to;10%T;'f' the tu'n gsten, said 91;
ofo-the tungsten content.
'2.- A hard metal all y comprising I akm'g the new. na pnlverizedjtungi t 1,549,615 PATENT. OFFICE-. 3,
J nan-gnu, nil-pox Ann me mom or MAKING sum Ra'ssuw 1 ing the tnngstic powder with carbon; --The 56 carbon may .be 'of' soot, sugar 'of carbon," graphite and the like, A carbon content. of
'7' 'per cent has proved especially favorable, 1
but it can be varied home to 10' "er c'enti A.met'al which can be reduce by. h dromelting point than 'the tungstie @enbide is suitable for use'as the auxilia' metal, for
example, iron, cobaltor nickel. base metals may be m a'finely divided form. The tem'- perature at which the sinterin occurs, is. affected by the quantity oi the. a 'xed'aux'-' iliary metal, which can be'pm ade as high as 10 cent of the alloy. For instance, admixture of 5 per cent cobalt has proved- 7o two or several of the auxiliary metalsma 76 be addedv toe-the tungstic powder-in whic case'the auxil ary, metals can be taken-in- -any suitable ratio to each. other, b t 5 3 must not, all told, make up more than 10, 1 per cent of the total qggntity 'of thefalloy 'Iihe sintering of the dies, wh chibodies areiormedv for instance by hydraulicipressure, can be efiected' by heating'them--in-}a h protective atmosphere such as'a-n atmosphere" of hydrogen, nitrogen, argon, illuminating 88 gas, carbonic oxide, or an admixture ofsuch gases, or the sintering can be-e'fi'ecte'd by embedding 1: e'bodies in carboni-graphiteand; the like. Siiitable- 1 temperature ay be found between 1 500. andf gqq v grees'C-.fa
, Wh t I claim as new and desire to secure by-Letters Patent'of the'UnjitedfStates, :isf'z' 1. A hard-metal allo comprising a ca'r alloy having, inaddition, a metalgofa con:
bide, said metal forming'not more the bide of tungsten,- the carbon content ciwhich es fiamat 10% of the tungsten',l.said.- alloy having ametal 'of the iron group, the.
latter 'formingnot f'more. than 10% of the tungsten content.
i wj u me a v a w if a gen and which has a considerably ower .3.;9A. hard metal alloy" comprising .a car? H ranges from 3 to 10% of the tungsten, said: alloy having iron, the latter forming not more than 10% of the content.
4;. The method of making an alloy of a carbide of tungsten and a metal which consists in bringing, together a pulverized tun'ge sten carbide and a quantity of finely divided metal, mixing said materiaIsand pressing them into forms and heating the forms to sintering temperature;
5.. The method of. making an alloy of a. carbide of'tungsten and a metal which conslsts in bringing together a pulverized tungsten carbide, said carbide having a carbon content within the ranges of from 3 to 10%,
- of thecarbide, the proportions of the tungsten carbon and of the metal being respectively not more than 80% of tungsten, 10% of carbon and 10% of the metal.
In Witness whereof, I have hereunto set my hand this 8th day of October, 1923.
KARL scHRoTER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US672014A US1549615A (en) | 1923-10-31 | 1923-10-31 | Hard-metal alloy and the process of making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US672014A US1549615A (en) | 1923-10-31 | 1923-10-31 | Hard-metal alloy and the process of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1549615A true US1549615A (en) | 1925-08-11 |
Family
ID=24696803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US672014A Expired - Lifetime US1549615A (en) | 1923-10-31 | 1923-10-31 | Hard-metal alloy and the process of making same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1549615A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2735421A (en) * | 1951-10-22 | 1956-02-21 | Shaping of bodies of crystalline carbon | |
| US2798474A (en) * | 1951-09-18 | 1957-07-09 | Deutsche Edelstahlwerke Ag | Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated |
| US4452325A (en) * | 1982-09-27 | 1984-06-05 | Conoco Inc. | Composite structure for cutting tools |
| US20050025657A1 (en) * | 2003-07-25 | 2005-02-03 | Sandvik Ab | Method of making a fine grained cemented carbide |
| US8778259B2 (en) | 2011-05-25 | 2014-07-15 | Gerhard B. Beckmann | Self-renewing cutting surface, tool and method for making same using powder metallurgy and densification techniques |
| US9640746B2 (en) | 2013-01-22 | 2017-05-02 | California Institute Of Technology | High performance high temperature thermoelectric composites with metallic inclusions |
-
1923
- 1923-10-31 US US672014A patent/US1549615A/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798474A (en) * | 1951-09-18 | 1957-07-09 | Deutsche Edelstahlwerke Ag | Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated |
| US2735421A (en) * | 1951-10-22 | 1956-02-21 | Shaping of bodies of crystalline carbon | |
| US4452325A (en) * | 1982-09-27 | 1984-06-05 | Conoco Inc. | Composite structure for cutting tools |
| US20050025657A1 (en) * | 2003-07-25 | 2005-02-03 | Sandvik Ab | Method of making a fine grained cemented carbide |
| US20060029511A1 (en) * | 2003-07-25 | 2006-02-09 | Sandvik Ab | Method of making a fine grained cemented carbide |
| US8778259B2 (en) | 2011-05-25 | 2014-07-15 | Gerhard B. Beckmann | Self-renewing cutting surface, tool and method for making same using powder metallurgy and densification techniques |
| US9640746B2 (en) | 2013-01-22 | 2017-05-02 | California Institute Of Technology | High performance high temperature thermoelectric composites with metallic inclusions |
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