US1446332A - Alloy and method of making same - Google Patents
Alloy and method of making same Download PDFInfo
- Publication number
- US1446332A US1446332A US337778A US33777819A US1446332A US 1446332 A US1446332 A US 1446332A US 337778 A US337778 A US 337778A US 33777819 A US33777819 A US 33777819A US 1446332 A US1446332 A US 1446332A
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- United States
- Prior art keywords
- alloy
- making same
- draft
- tin
- speed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title description 15
- 239000000956 alloy Substances 0.000 title description 15
- 238000004519 manufacturing process Methods 0.000 title description 7
- 238000000034 method Methods 0.000 description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 229910000906 Bronze Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000723368 Conium Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- MDPILPRLPQYEEN-UHFFFAOYSA-N aluminium arsenide Chemical compound [As]#[Al] MDPILPRLPQYEEN-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- -1 co-v bait Chemical compound 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/06—Sliding surface mainly made of metal
- F16C33/12—Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
- F16C33/121—Use of special materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/10—Alloys based on copper
- F16C2204/12—Alloys based on copper with tin as the next major constituent
Definitions
- One object of my invention is to provide a high grade bearing bronze inrod or tubu- 1o lar form, for use particularly in automatic screw machines for the economical production of bushings of various sizes and lengths,
- Another object of the invention to provide a method fortreating I, alloys of the above noted class, whereby 'thevaluable qualities inherent in what may be referred to as the raw material are .preservedin the improved product, so that vfor example, an
- apparatus suchgas is "shown in the accompanying-drawings, in which- 'The figure is a diagrammatic representa tion in vertical section of'a furnace, tank and rolling mill constituting apparatus 40 which may be employed in connection with my invention.
- T he. specimen is thereafter submitted with out further heating, to a rolling, drawing or .swaging process in a suitable rolling mill 3 ata speed not in excess of 15 feet per min 7 cessof .0625, and this process is repeated as occasionrequires depending upon the size and mass of the piece undergoing manipulation and upon the ultimate dimensions re- 55.
- alloy analyzing as above described can be successfully produced in rods, sheets and tubes of dimensions to; meet existing and In the preparation'lof"rollingequipment-9o fornthe, production of rods and tubes from thefl'alloy as described above, I have discovered the necessity of departure from wellequipment, for -ifthe grooves in such rolls be concentric,,a fin will be. produced on the specimen which will render it useless.- lf on the other hand the grooves be opened 4 as isthe common practice in the'rrolling of steel and other alloys, such opening will permit the specimento fracture.
- a yield point of approximately 22,500 pounds er s uare inch an elon 'ation in 2 of from 9% to 12% and a Brinell hardness number of about 90 can be improved so that the ultimate strength will be over 110,000 pounds per square inch, the elastic limit will be over 100,000 pounds per square inch, the elongationover 40% in two inches and the Brinell hardness number over 200.
- the ductility ofthe alloy can be ma terially increased and the specific gravity increased from 8.66 to 9.01; In short, the
- Iclaim: 1 The method which consists in heating a bronze alloy; containing more than 85% of copper, more than 9%% of tin and more than 2% of zinc, 932 F. to 1483"- F., immediately quenching said alloy 1n a cooling medium and there after compacting the alloy' as by rolling, drawing or swaging.
- the method which consists in heating a bronze alloy containing more than 85% of copper, more than 9%% of tin and more than 2% of zinc to a temperature below that at which it disintegrates and above that at which the eutectic fuses; and subjecting said alloy to a compacting operation at the speed and draft represented by the formula 4 izggeee 3.
- the method Which consists in heating an alloy containing more than 85% of copper, more than 9% of tin and more than 2% of zinc to a temperature of from 932 F to 1483 F and subjecting said alloy to a compacting operation between rolls hav- 2 ing a chamfer orradius of one sixty-fourth of an inch to three-sixteenths of an inch on of their grooves.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Rolling (AREA)
- Forging (AREA)
Description
Patented Feb, 2%, 1923;
Josnrn vviu. BRAMWELL, or BnieWYN, PENNSYLVANIA, AssisNon T AMERIcAN BRONZE oonronArro or nnnwvurnivnsvnvimm, A conronA'rIoN or PENN- SYLVALN 1A.
AIILQY AND METHOD OF MAKING SAEI E;
Application filed November 13, 1919. Serial Ito. 337,778.
To all whom it may concern;
a citizen of the United States, residing in Berwyn, Chester County, Pennsylvania,- 5 have invented ing Same, of which the following is a speciiication.
One object of my invention is to provide a high grade bearing bronze inrod or tubu- 1o lar form, for use particularly in automatic screw machines for the economical production of bushings of various sizes and lengths,
or in sheet form for the economical production by stamping of discs and washers. Another object of the invention ,to provide a method fortreating I, alloys of the above noted class, whereby 'thevaluable qualities inherent in what may be referred to as the raw material are .preservedin the improved product, so that vfor example, an
alloy of a certain composition particularly. adapting it for use as a be aring meta1-, Wh en subjected to my method of treatment not I only has no impairment of its qualities as'a hearing metal but in addition has given to -it other qualities adding materially to its value .as a material for the manufacture of machine elements or' parts ;+-the invention especially contemplating such a method of so procedure in the production of certain articles such as tubular bearlngs as Wlll terially reduce their cost both in material and labor. a f
In carrying out my inventio-nl may. use
as apparatus suchgas is "shown in the accompanying-drawings, in which- 'The figure is a diagrammatic representa tion in vertical section of'a furnace, tank and rolling mill constituting apparatus 40 which may be employed in connection with my invention.
1 have discovered that by employing 'certain methods hereinafter described, I am ableto successfully roll, draw or swage a at non-ferrous alloy containing more than 85% 'scopper, more than 9%;% tinand more than 2% zinc and preferably containing 869 70 copper, 11%tin and 2-1 %.zinc'. The basic ternary alloy whose low limits are referred to as containing more than 85% of copper, more than 9 of tin, and more than 2% ofzinc, can, within the scope of my process, 7 my claims, and'my practice he made to include relatively small additions not to @X p ceed 2% each of each or several of the metals Be it known that L'JOSEPH 'lV. BRAMWELL,
Alloys and Methods of Malttanium, tungsten, uranium, vanadium, zir- 932 F. at which the eutectic fuses to 1483 F1 and preferably to 1250 ,F., in a furnace lute, simultaneously with a draft not in exquired. As a result of this treatment the future demands.
known and'commonly' used designsof such comprisedin the groups or families represented byz'aluminum arsenic, boron, co-v bait, magnesium, manganese, molybdenum, nickel, phosphorus, potassium, silicon, ti-
conium.
In carrying out my invention I heat an alloy of approximately the composition above specified to a temperature of from such as is indicated at 1 f0r a period of time (depending upon the size and mass of the piece under-going manipulation) sufficient to -enable such specimen to become thoroughly heated throughout to a temperature within the prescribed limits and then immediately subject the piece to treatment ina suitable cooling medium, preferably by plunging-it into a bath 2 of cold 'water.
T he. specimen is thereafter submitted with out further heating, to a rolling, drawing or .swaging process in a suitable rolling mill 3 ata speed not in excess of 15 feet per min 7 cessof .0625, and this process is repeated as occasionrequires depending upon the size and mass of the piece undergoing manipulation and upon the ultimate dimensions re- 55.
alloy analyzing as above described can be successfully produced in rods, sheets and tubes of dimensions to; meet existing and In the preparation'lof"rollingequipment-9o fornthe, production of rods and tubes from thefl'alloy as described above, I have discovered the necessity of departure from wellequipment, for -ifthe grooves in such rolls be concentric,,a fin will be. produced on the specimen which will render it useless.- lf on the other hand the grooves be opened 4 as isthe common practice in the'rrolling of steel and other alloys, such opening will permit the specimento fracture.
dius between the rolls d and 5. of fromg processga certain fixed relation should exist between the speed of rolls and theamount v loop I have discovered thatfa chamfer or m;
. integrate.
of my invention it I v 'k of reduction or draft of the material possessing the high tin content. For example,
at a roll speed of 15 feet per minute, the
maximum safe reduction or draft was found to be and any. greater draft at the same speed caused the material to dis In accordance with this'feature :reductibn or draft at each passmaximum' for any increased speed Szspeed ft. per min. at each pass;
S =any other increased speed;
R thedraft for any other increased speed will be inversely as the fourth powers of S and S then SX .0625 e- T s As a result of my method of treatment the physical properties of an alloy of the chemicalcomposition above noted and havingas originally cast an ultimatestrength of approximately 45,000-pounds per square inch,
a yield point of approximately 22,500 pounds er s uare inch an elon 'ation in 2 of from 9% to 12% and a Brinell hardness number of about 90, can be improved so that the ultimate strength will be over 110,000 pounds per square inch, the elastic limit will be over 100,000 pounds per square inch, the elongationover 40% in two inches and the Brinell hardness number over 200.
Also the ductility ofthe alloy can be ma terially increased and the specific gravity increased from 8.66 to 9.01; In short, the
wear resisting qualities and consequent desirability and adaptability of the metal as a bearing material are greatly. enhanced.
Iclaim: 1 1. The method which consists in heating a bronze alloy; containing more than 85% of copper, more than 9%% of tin and more than 2% of zinc, 932 F. to 1483"- F., immediately quenching said alloy 1n a cooling medium and there after compacting the alloy' as by rolling, drawing or swaging.
2. The method which consists in heating a bronze alloy containing more than 85% of copper, more than 9%% of tin and more than 2% of zinc to a temperature below that at which it disintegrates and above that at which the eutectic fuses; and subjecting said alloy to a compacting operation at the speed and draft represented by the formula 4 izggeee 3. The method Which consists in heating an alloy containing more than 85% of copper, more than 9% of tin and more than 2% of zinc to a temperature of from 932 F to 1483 F and subjecting said alloy to a compacting operation between rolls hav- 2 ing a chamfer orradius of one sixty-fourth of an inch to three-sixteenths of an inch on of their grooves.
the edges 7 JOSEPH WM. BRAMWELL' to a temperature of from
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US337778A US1446332A (en) | 1919-11-13 | 1919-11-13 | Alloy and method of making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US337778A US1446332A (en) | 1919-11-13 | 1919-11-13 | Alloy and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1446332A true US1446332A (en) | 1923-02-20 |
Family
ID=23321963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US337778A Expired - Lifetime US1446332A (en) | 1919-11-13 | 1919-11-13 | Alloy and method of making same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1446332A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1698707A3 (en) * | 2005-03-03 | 2010-10-13 | Miba Gleitlager GmbH | Sliding bearing with a lead free copper based bearing metal layer containing tin and zinc |
-
1919
- 1919-11-13 US US337778A patent/US1446332A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1698707A3 (en) * | 2005-03-03 | 2010-10-13 | Miba Gleitlager GmbH | Sliding bearing with a lead free copper based bearing metal layer containing tin and zinc |
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