US1383176A - Edged tool - Google Patents
Edged tool Download PDFInfo
- Publication number
- US1383176A US1383176A US332796A US33279619A US1383176A US 1383176 A US1383176 A US 1383176A US 332796 A US332796 A US 332796A US 33279619 A US33279619 A US 33279619A US 1383176 A US1383176 A US 1383176A
- Authority
- US
- United States
- Prior art keywords
- cadmium
- article
- coating
- solution
- electro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052793 cadmium Inorganic materials 0.000 description 22
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 22
- 239000011248 coating agent Substances 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/26—Electroplating: Baths therefor from solutions of cadmium
- C25D3/28—Electroplating: Baths therefor from solutions of cadmium from cyanide baths
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9265—Special properties
- Y10S428/932—Abrasive or cutting feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S76/00—Metal tools and implements, making
- Y10S76/08—Razor blade manufacturing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/27—Cutters, for shaping comprising tool of specific chemical composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12389—All metal or with adjacent metals having variation in thickness
- Y10T428/12403—Longitudinally smooth and symmetrical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
Definitions
- the present invention relates to implements and instruments of all descriptions containing one or more cutting edges.
- the coat is applied by electro-deposition and preferably by electro-deposition and subsequent heat treatment, as described in my copending applications Ser. N 0. 304,020,
- the treatment of the edged articles to be protected may be as follows:
- lic cadmium is weighed and dissolved in as small amount of water as possible. If metallic cadmium is used, it may be dissolved in hydrochloric acid to form a neutral solution or it may be dissolved in nitric acid and evaporated to dryness with hydrochloric acid to remove the nitric acid. After the cadmium is dissolved and is in a neutral or nearly neutral solution, a solution of sodlum or potassium hydroxid is slowly added until the cadmium is precipitated and the solution is red to phenolphthalein. Sodium or potassium cyanid is now slowly. added until the precipitated cadmium oxid is all dissolved, an excess of cyanid being avoided. The solution is then diluted to one liter.
- the solution as thus prepared constitutes the bath used for electroplating the article.
- Other strengths of solution may of course be used but a solution of 25 grams cadmium per liter we find preferable for use.
- the anode is metallic cadmium.
- a current density of 7 amperes to 50 amperes per square foot of cathode area can be used. About 7 amperes per square foot are preferred. Lower and higher current densities have been used and in fact the current density does not seem to affect the deposit.
- the article Before plating, the article is cleaned ofall rust and dirt by polishing with a very fine grade of emery cloth. If necessary, it may also be cleaned by dipping in dilute sulfuric acid or other chemical solutions and finally in water.
- the article After the article has received its coating, it is washed in water and laced in an oven and heated to about 150 to 200 C. The maximum in an ordinary oven is about 200 C. The duration of the heating is not very material, but ordinarily it should be several hours. The temperature should be such that there is only a slight coating of cadmium oxid formed on the surface of the article. Excessive oxidation must be avoided. By burying the article in calcium hydroxid, the temperature may be raised to about, 250 C. without-excessive oxidation.
- the degree of oxidation of course is gov- 1 erned by the temperature employed and the atmosphere in which the heating takes place.
- the heat treatment has the pur ose to alloy the cadmium with the metal 0 which the article is composed and also to harden the coating. It also serves the purpose of removing an excess of the coating metal by burning it to oxid. After the heat treatment the coating is very resistant to wear.
- the article is polished in any usual or preferred manner.
- T e.purpose of protecting an edged steel article against rusting which consists in electro-platlng the article with cadmium and L their ubjecting the coated article to heat to alloy thecadmium thereto.
- An edged steel article having a coating of cadmium alloyed thereto.
- a steel tool depending for its function upon a fine cutting edge having a coating of cadmium alloyed thereto.
- a razor blade having a coating of cadmium alloyed thereto.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Description
UNITED STATES PATENT OFFICE.
MARVIN J. UDY AND FRANK c. NICHOLSON, or xoxomo, INDIANA, ASSIGNQRS 1m 'rnn UDYLI'IE rnocnss COMPANY, or xoxomo, INDIANA, A CORPORATION OF Patented June 28, 1921.
INDIANA.
EDGED TOOL.
1,383 1 76 Specification of Letters Patent.
No Drawing.
To all whom it may concern:
Be it known that We, (1) MARVIN J. UDY and (2) FRANK C. NICHOLSON, citizens of the United States, residing at Kokomo, in the county of Howard and State of Indiana, have invented certain new and usefulImprovements in Edged Tools, of which the following is a specification.
The present invention relates to implements and instruments of all descriptions containing one or more cutting edges.
We have discovered that the cutting edges of tools, knives, scissors or other implements can be effectively protected against rusting by coating them with a metal which is electro-positive to the metal of which the article is made. We refer in particular to the coating of articles made of steel with cadmium. We have found that although thefedge of a coated article has been sharpened and the coating removed from it, the
exposed steel edge is protected by the cadmium coating adjoining it.
For instance, in the case of a razor, it is first given a complete coat of cadmium. It is then honed and by this honing the cadmium is removed from the edge and a narrow strip backward of the edge which also bears on the hone. Thusthe razor when in condition for use has a bare steel edge identical, in respect to all physical properties, with the edge it would have if it had not been treated. Our experiments have shown that this bare edge does not rust and that the coating need not be continuous to afford protection. We attribute this fact, as above suggested, to the electro-positive properties of cadmium in its'relation to steel.
The coat is applied by electro-deposition and preferably by electro-deposition and subsequent heat treatment, as described in my copending applications Ser. N 0. 304,020,
filed June 13, 1919 and Ser. No. 332,795, filed Oct. 23, 1919.
The treatment of the edged articles to be protected may be as follows:
1. Preparation of plating solution.
A solution containing about 25 grams of cadmium per liter of solution, we have found, is most convenient for the purpose. Enough of a salt of cadmium such as the sulfate or chlorid to yield 25 grams of metal- Application filed October 23, 1919. Serial No. 332,796.
lic cadmium is weighed and dissolved in as small amount of water as possible. If metallic cadmium is used, it may be dissolved in hydrochloric acid to form a neutral solution or it may be dissolved in nitric acid and evaporated to dryness with hydrochloric acid to remove the nitric acid. After the cadmium is dissolved and is in a neutral or nearly neutral solution, a solution of sodlum or potassium hydroxid is slowly added until the cadmium is precipitated and the solution is red to phenolphthalein. Sodium or potassium cyanid is now slowly. added until the precipitated cadmium oxid is all dissolved, an excess of cyanid being avoided. The solution is then diluted to one liter. The solution as thus prepared constitutes the bath used for electroplating the article. Other strengths of solution may of course be used but a solution of 25 grams cadmium per liter we find preferable for use. The anode is metallic cadmium. A current density of 7 amperes to 50 amperes per square foot of cathode area can be used. About 7 amperes per square foot are preferred. Lower and higher current densities have been used and in fact the current density does not seem to affect the deposit.
2. Gleam'ng of article.
Before plating, the article is cleaned ofall rust and dirt by polishing with a very fine grade of emery cloth. If necessary, it may also be cleaned by dipping in dilute sulfuric acid or other chemical solutions and finally in water.
3. Electroplating.
After the article is cleaned it is immediately electroplated in the usual. manner.
4. After the article has received its coating, it is washed in water and laced in an oven and heated to about 150 to 200 C. The maximum in an ordinary oven is about 200 C. The duration of the heating is not very material, but ordinarily it should be several hours. The temperature should be such that there is only a slight coating of cadmium oxid formed on the surface of the article. Excessive oxidation must be avoided. By burying the article in calcium hydroxid, the temperature may be raised to about, 250 C. without-excessive oxidation.
The degree of oxidation of course is gov- 1 erned by the temperature employed and the atmosphere in which the heating takes place.
The heat treatment has the pur ose to alloy the cadmium with the metal 0 which the article is composed and also to harden the coating. It also serves the purpose of removing an excess of the coating metal by burning it to oxid. After the heat treatment the coating is very resistant to wear.
5. After the heat treatment the article is polished in any usual or preferred manner.
' in coating the article with cadmium and then subjecting the coated article to heat to allo the cadmium thereto.
2. T e.purpose of protecting an edged steel article against rusting, which consists in electro-platlng the article with cadmium and L their ubjecting the coated article to heat to alloy thecadmium thereto.
.3. The process of protectingan edged steel article against rusting, which consists in electro-plating the article with a metal which is electro-positive to the metal of which the article is made and subjecting the coated article to heat under conditions preventing excessive oxidation of the coating metal.
4. The process of protecting an edged steel article against rustin which conslsts in electro-platlng the article with cadmium and subjecting the coated article to heat under conditions preventing excessive oxidation of the cadmium coating.
5. An edged steel article having a coating of cadmium alloyed thereto.
6. A steel tool depending for its function upon a fine cutting edge having a coating of cadmium alloyed thereto.
7. A razor blade having a coating of cadmium alloyed thereto.
In testimony whereof we aflix our signatures.
MARVIN J UDY. FRANK C. NICHOLSON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US332796A US1383176A (en) | 1919-10-23 | 1919-10-23 | Edged tool |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US332796A US1383176A (en) | 1919-10-23 | 1919-10-23 | Edged tool |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1383176A true US1383176A (en) | 1921-06-28 |
Family
ID=23299884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US332796A Expired - Lifetime US1383176A (en) | 1919-10-23 | 1919-10-23 | Edged tool |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1383176A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2563119A (en) * | 1948-03-03 | 1951-08-07 | Otis Pressure Control Inc | Recorder chart for oil or gas well recording instruments |
| US2781308A (en) * | 1945-04-12 | 1957-02-12 | Edward C Creutz | Neutronic reactor control |
| US3345202A (en) * | 1963-06-10 | 1967-10-03 | Eversharp Inc | Method of making razor blades |
| US3402468A (en) * | 1963-06-10 | 1968-09-24 | Eversharp Inc | Polytetrafluoroethylene coated razor blade |
-
1919
- 1919-10-23 US US332796A patent/US1383176A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2781308A (en) * | 1945-04-12 | 1957-02-12 | Edward C Creutz | Neutronic reactor control |
| US2563119A (en) * | 1948-03-03 | 1951-08-07 | Otis Pressure Control Inc | Recorder chart for oil or gas well recording instruments |
| US3345202A (en) * | 1963-06-10 | 1967-10-03 | Eversharp Inc | Method of making razor blades |
| US3402468A (en) * | 1963-06-10 | 1968-09-24 | Eversharp Inc | Polytetrafluoroethylene coated razor blade |
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