[go: up one dir, main page]

US1383176A - Edged tool - Google Patents

Edged tool Download PDF

Info

Publication number
US1383176A
US1383176A US332796A US33279619A US1383176A US 1383176 A US1383176 A US 1383176A US 332796 A US332796 A US 332796A US 33279619 A US33279619 A US 33279619A US 1383176 A US1383176 A US 1383176A
Authority
US
United States
Prior art keywords
cadmium
article
coating
solution
electro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US332796A
Inventor
Marvin J Udy
Frank C Nicholson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UDYLITE PROCESS Co
Original Assignee
UDYLITE PROCESS Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UDYLITE PROCESS Co filed Critical UDYLITE PROCESS Co
Priority to US332796A priority Critical patent/US1383176A/en
Application granted granted Critical
Publication of US1383176A publication Critical patent/US1383176A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/26Electroplating: Baths therefor from solutions of cadmium
    • C25D3/28Electroplating: Baths therefor from solutions of cadmium from cyanide baths
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/932Abrasive or cutting feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/934Electrical process
    • Y10S428/935Electroplating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/08Razor blade manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/27Cutters, for shaping comprising tool of specific chemical composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12389All metal or with adjacent metals having variation in thickness
    • Y10T428/12403Longitudinally smooth and symmetrical
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12785Group IIB metal-base component

Definitions

  • the present invention relates to implements and instruments of all descriptions containing one or more cutting edges.
  • the coat is applied by electro-deposition and preferably by electro-deposition and subsequent heat treatment, as described in my copending applications Ser. N 0. 304,020,
  • the treatment of the edged articles to be protected may be as follows:
  • lic cadmium is weighed and dissolved in as small amount of water as possible. If metallic cadmium is used, it may be dissolved in hydrochloric acid to form a neutral solution or it may be dissolved in nitric acid and evaporated to dryness with hydrochloric acid to remove the nitric acid. After the cadmium is dissolved and is in a neutral or nearly neutral solution, a solution of sodlum or potassium hydroxid is slowly added until the cadmium is precipitated and the solution is red to phenolphthalein. Sodium or potassium cyanid is now slowly. added until the precipitated cadmium oxid is all dissolved, an excess of cyanid being avoided. The solution is then diluted to one liter.
  • the solution as thus prepared constitutes the bath used for electroplating the article.
  • Other strengths of solution may of course be used but a solution of 25 grams cadmium per liter we find preferable for use.
  • the anode is metallic cadmium.
  • a current density of 7 amperes to 50 amperes per square foot of cathode area can be used. About 7 amperes per square foot are preferred. Lower and higher current densities have been used and in fact the current density does not seem to affect the deposit.
  • the article Before plating, the article is cleaned ofall rust and dirt by polishing with a very fine grade of emery cloth. If necessary, it may also be cleaned by dipping in dilute sulfuric acid or other chemical solutions and finally in water.
  • the article After the article has received its coating, it is washed in water and laced in an oven and heated to about 150 to 200 C. The maximum in an ordinary oven is about 200 C. The duration of the heating is not very material, but ordinarily it should be several hours. The temperature should be such that there is only a slight coating of cadmium oxid formed on the surface of the article. Excessive oxidation must be avoided. By burying the article in calcium hydroxid, the temperature may be raised to about, 250 C. without-excessive oxidation.
  • the degree of oxidation of course is gov- 1 erned by the temperature employed and the atmosphere in which the heating takes place.
  • the heat treatment has the pur ose to alloy the cadmium with the metal 0 which the article is composed and also to harden the coating. It also serves the purpose of removing an excess of the coating metal by burning it to oxid. After the heat treatment the coating is very resistant to wear.
  • the article is polished in any usual or preferred manner.
  • T e.purpose of protecting an edged steel article against rusting which consists in electro-platlng the article with cadmium and L their ubjecting the coated article to heat to alloy thecadmium thereto.
  • An edged steel article having a coating of cadmium alloyed thereto.
  • a steel tool depending for its function upon a fine cutting edge having a coating of cadmium alloyed thereto.
  • a razor blade having a coating of cadmium alloyed thereto.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Description

UNITED STATES PATENT OFFICE.
MARVIN J. UDY AND FRANK c. NICHOLSON, or xoxomo, INDIANA, ASSIGNQRS 1m 'rnn UDYLI'IE rnocnss COMPANY, or xoxomo, INDIANA, A CORPORATION OF Patented June 28, 1921.
INDIANA.
EDGED TOOL.
1,383 1 76 Specification of Letters Patent.
No Drawing.
To all whom it may concern:
Be it known that We, (1) MARVIN J. UDY and (2) FRANK C. NICHOLSON, citizens of the United States, residing at Kokomo, in the county of Howard and State of Indiana, have invented certain new and usefulImprovements in Edged Tools, of which the following is a specification.
The present invention relates to implements and instruments of all descriptions containing one or more cutting edges.
We have discovered that the cutting edges of tools, knives, scissors or other implements can be effectively protected against rusting by coating them with a metal which is electro-positive to the metal of which the article is made. We refer in particular to the coating of articles made of steel with cadmium. We have found that although thefedge of a coated article has been sharpened and the coating removed from it, the
exposed steel edge is protected by the cadmium coating adjoining it.
For instance, in the case of a razor, it is first given a complete coat of cadmium. It is then honed and by this honing the cadmium is removed from the edge and a narrow strip backward of the edge which also bears on the hone. Thusthe razor when in condition for use has a bare steel edge identical, in respect to all physical properties, with the edge it would have if it had not been treated. Our experiments have shown that this bare edge does not rust and that the coating need not be continuous to afford protection. We attribute this fact, as above suggested, to the electro-positive properties of cadmium in its'relation to steel.
The coat is applied by electro-deposition and preferably by electro-deposition and subsequent heat treatment, as described in my copending applications Ser. N 0. 304,020,
filed June 13, 1919 and Ser. No. 332,795, filed Oct. 23, 1919.
The treatment of the edged articles to be protected may be as follows:
1. Preparation of plating solution.
A solution containing about 25 grams of cadmium per liter of solution, we have found, is most convenient for the purpose. Enough of a salt of cadmium such as the sulfate or chlorid to yield 25 grams of metal- Application filed October 23, 1919. Serial No. 332,796.
lic cadmium is weighed and dissolved in as small amount of water as possible. If metallic cadmium is used, it may be dissolved in hydrochloric acid to form a neutral solution or it may be dissolved in nitric acid and evaporated to dryness with hydrochloric acid to remove the nitric acid. After the cadmium is dissolved and is in a neutral or nearly neutral solution, a solution of sodlum or potassium hydroxid is slowly added until the cadmium is precipitated and the solution is red to phenolphthalein. Sodium or potassium cyanid is now slowly. added until the precipitated cadmium oxid is all dissolved, an excess of cyanid being avoided. The solution is then diluted to one liter. The solution as thus prepared constitutes the bath used for electroplating the article. Other strengths of solution may of course be used but a solution of 25 grams cadmium per liter we find preferable for use. The anode is metallic cadmium. A current density of 7 amperes to 50 amperes per square foot of cathode area can be used. About 7 amperes per square foot are preferred. Lower and higher current densities have been used and in fact the current density does not seem to affect the deposit.
2. Gleam'ng of article.
Before plating, the article is cleaned ofall rust and dirt by polishing with a very fine grade of emery cloth. If necessary, it may also be cleaned by dipping in dilute sulfuric acid or other chemical solutions and finally in water.
3. Electroplating.
After the article is cleaned it is immediately electroplated in the usual. manner.
4. After the article has received its coating, it is washed in water and laced in an oven and heated to about 150 to 200 C. The maximum in an ordinary oven is about 200 C. The duration of the heating is not very material, but ordinarily it should be several hours. The temperature should be such that there is only a slight coating of cadmium oxid formed on the surface of the article. Excessive oxidation must be avoided. By burying the article in calcium hydroxid, the temperature may be raised to about, 250 C. without-excessive oxidation.
The degree of oxidation of course is gov- 1 erned by the temperature employed and the atmosphere in which the heating takes place.
The heat treatment has the pur ose to alloy the cadmium with the metal 0 which the article is composed and also to harden the coating. It also serves the purpose of removing an excess of the coating metal by burning it to oxid. After the heat treatment the coating is very resistant to wear.
5. After the heat treatment the article is polished in any usual or preferred manner.
' in coating the article with cadmium and then subjecting the coated article to heat to allo the cadmium thereto.
2. T e.purpose of protecting an edged steel article against rusting, which consists in electro-platlng the article with cadmium and L their ubjecting the coated article to heat to alloy thecadmium thereto.
.3. The process of protectingan edged steel article against rusting, which consists in electro-plating the article with a metal which is electro-positive to the metal of which the article is made and subjecting the coated article to heat under conditions preventing excessive oxidation of the coating metal.
4. The process of protecting an edged steel article against rustin which conslsts in electro-platlng the article with cadmium and subjecting the coated article to heat under conditions preventing excessive oxidation of the cadmium coating.
5. An edged steel article having a coating of cadmium alloyed thereto.
6. A steel tool depending for its function upon a fine cutting edge having a coating of cadmium alloyed thereto.
7. A razor blade having a coating of cadmium alloyed thereto.
In testimony whereof we aflix our signatures.
MARVIN J UDY. FRANK C. NICHOLSON.
US332796A 1919-10-23 1919-10-23 Edged tool Expired - Lifetime US1383176A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US332796A US1383176A (en) 1919-10-23 1919-10-23 Edged tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US332796A US1383176A (en) 1919-10-23 1919-10-23 Edged tool

Publications (1)

Publication Number Publication Date
US1383176A true US1383176A (en) 1921-06-28

Family

ID=23299884

Family Applications (1)

Application Number Title Priority Date Filing Date
US332796A Expired - Lifetime US1383176A (en) 1919-10-23 1919-10-23 Edged tool

Country Status (1)

Country Link
US (1) US1383176A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2563119A (en) * 1948-03-03 1951-08-07 Otis Pressure Control Inc Recorder chart for oil or gas well recording instruments
US2781308A (en) * 1945-04-12 1957-02-12 Edward C Creutz Neutronic reactor control
US3345202A (en) * 1963-06-10 1967-10-03 Eversharp Inc Method of making razor blades
US3402468A (en) * 1963-06-10 1968-09-24 Eversharp Inc Polytetrafluoroethylene coated razor blade

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2781308A (en) * 1945-04-12 1957-02-12 Edward C Creutz Neutronic reactor control
US2563119A (en) * 1948-03-03 1951-08-07 Otis Pressure Control Inc Recorder chart for oil or gas well recording instruments
US3345202A (en) * 1963-06-10 1967-10-03 Eversharp Inc Method of making razor blades
US3402468A (en) * 1963-06-10 1968-09-24 Eversharp Inc Polytetrafluoroethylene coated razor blade

Similar Documents

Publication Publication Date Title
Mandich et al. Electrodeposition of chromium
US2746915A (en) Electrolytic metal treatment and article
US2313756A (en) Method of electroplating magnesium
US1971761A (en) Protection of metals
US2334698A (en) Polished metal and a method of making the same
US1383176A (en) Edged tool
US4412892A (en) Pretreatment of superalloys and stainless steels for electroplating
GB2030596A (en) Combined method of electroplating and deplating electroplated ferrous based wire
US2457060A (en) Method for bonding a nickel electrodeposit to a nickel surface
US2526544A (en) Method of producing a metallic coating on magnesium and its alloys
US4356069A (en) Stripping composition and method for preparing and using same
US1776603A (en) Tin-coated chromium iron alloy and method of making the same
US2462870A (en) Electrodeposition of copper
US2946728A (en) Adherent electroplating on titanium
US2464168A (en) Electrolytic iron for powder metallurgy purposes
EP0260301A1 (en) Particulate diamond-coated metal article with high resistance to stress cracking and process therefor
US2095519A (en) Method for producing galvanic coatings on aluminum or aluminum alloys
US2355505A (en) Electrodeposition of bright zinc
US3490314A (en) Cutting instruments
US2092130A (en) Anodic cleaning process
US1383175A (en) Spring
US1211218A (en) Process for plating metals.
US2702785A (en) Process of producing hard chromium platings on light metals
US1902676A (en) Hardening alloy steels
US242338A (en) Constant laval