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US1083007A - Process of detaching wall-paper. - Google Patents

Process of detaching wall-paper. Download PDF

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Publication number
US1083007A
US1083007A US41654408A US1908416544A US1083007A US 1083007 A US1083007 A US 1083007A US 41654408 A US41654408 A US 41654408A US 1908416544 A US1908416544 A US 1908416544A US 1083007 A US1083007 A US 1083007A
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US
United States
Prior art keywords
wallpaper
paper
solution
water
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US41654408A
Inventor
Carleton Ellis
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CHADELOID CHEMICAL CO
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CHADELOID CHEMICAL CO
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Publication date
Application filed by CHADELOID CHEMICAL CO filed Critical CHADELOID CHEMICAL CO
Priority to US41654408A priority Critical patent/US1083007A/en
Application granted granted Critical
Publication of US1083007A publication Critical patent/US1083007A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/032Organic insulating material consisting of one material
    • H05K1/0346Organic insulating material consisting of one material containing N
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10S156/918Delaminating processes adapted for specified product, e.g. delaminating medical specimen slide
    • Y10S156/929Delaminating component from building, e.g. wall paper, shingle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/11Methods of delaminating, per se; i.e., separating at bonding face
    • Y10T156/1168Gripping and pulling work apart during delaminating

Definitions

  • Patented'D ec. 30, 1913 Patented'D ec. 30, 1913.
  • Ihis invention relates to .an improved process of removing old wallpaper from the walls to which it 13 attached, and has for its object the speedy removal of a wallpaper without injury to the plaster, wood or other surface'to which said wallaper may have been attached, all as more ully hereinafter set forth.
  • My invention comprises the use of neutral salts which are placed in suitable solution, which solution when applied to wallpaper readily retains moisture, or in fact even absorbs from the moisture of the air an additional amount of water thereby maintaining the wallpaper in a damp condition until the paste or other adhesive is so softened that the paper may be readily detached from its support. 4
  • I preferably employ such-hygroscopic salts as the chlorids of calcium, magnesium, and zinc, these being cheap, readily available and highl eflicient for the purpose.
  • the chlorid of zinc solutions have the additional advantage, when c'oncentrated, of parchmentizing the paper, rendering 1t capable of being stripped fromthe' wall asa firm sheet.
  • I may, however, use hygroscopic salts such as acetate of pot-ash and the like. I dissolve the salt or salts in water or water and glycerin or other suitable solvent to form preferably a rather concentrated solution and apply this solution to the walls with a brush or sponge and allow the composition to remain thereon until the wallpaper is detachable.
  • the rapi lty of action is generally enhanced'by applying the composition in a heated condition. This may be accomplished by simply warming before use, or by using a spraying device which is adapted to handle such hot. applications.
  • Some very highly sized or water-proofed papers, or papers containing designs imprinted with waterproof ink, are occasionally somewhat resistant and I have observed that the addition to the composition of a moderate amount of alcohol, acetone and the like, is occasionally an aid in accelerating the penetration ofthe solution. In extremely dry weather the action of the solution may be slightly accelerated by placing in the room where the .wallpapeneven in the driest weather.
  • a suitable composition for carrying out my process is made by dissolving two pounds of zlnc chlorid and two pounds of calcium chlorid in one gallon of water. This may be applied hot or cold, but preferably by hot spraying, or by means of a hollow brush appliance. 7
  • composition useful in treating wallpaper of a somewhat water-proof character is made by dissolving eight pounds of zinc chlorid in one gallon of water and in adding thereto. one-half gallon of wood alcohol or denatured alcohol.
  • Another formula comprises ten pounds zinc chlorid and five-'eighths of a gallon"? each of wood alcohol and water.
  • a composition useful for paper which has been exposed for a long time is made by dissolving eight pounds of magnesium chlorid chlorid solutions.
  • Casein pastes which are not readily softened by an entirely neutral or slightly acid composition are more easily softened by a solution which is slightly "alkaline, and to effect suitable alkalinity of the solution I prefer to employ for such applications a hygroscopic metallic chlo-rid whichis slightly basic; aresult which may be brought about by the treatment of neutral solutions of the c lorid with a basis body or hydrate in regulated quantities. Ammonia sometimes may be used to advantage in these compositions. When an especially resistant wall-' paper is to be detached it is sometimes desirable to thicken the composition either with a soluble or insoluble thickener; as, for instance, whiting or other mineral or yegetable filler. Irish moss solution or pectinous matter may alsobe used for thickening,
  • a formula illustrating such a composition comprises 7 5% granulated calcium chlorid, two pounds, Irish moss, 1 ounce and water, 1 quart. A little alcohol or ammonia may be introduced.
  • What I claim as my invention is 1.
  • the process of detaching wallpaper which consists in applying thereto an aqueous solution of a hygroscopic salt having a substantial solvent action on cellulose fiber, in allowing said solution to remain in contact with said wallpaper and thereby distend and dissolve the fiber thereof, in simultaneously softening and loosening the adhesive securing the wall paper in position and .in thereupon removing said wallpaper from its support. 2.
  • detaching wallpaper which consists in applying thereto a hot solution of a hygroscopic salt having a substantial, solvent action on cellulose fiber, in allowing said solution to remainin contact with said wallpaper and thereby distend and dissolve the fiber thereof, in simultane ously softening and loosening theadhesive CARLETON ELLIS.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Paper (AREA)

Description

7 UNITED srnrns PATENT OFFICE.
GARLE'ION ELLIS, OF LARCHMONT, YORK, ASSIGNOR, BY MESNE ASSIGNMENTS,
TO CHADELOI'D CHEMICAL COMPANY, OF NEW YORK, N. 21, A CORPORATION OF WEST VIRGINIA.
No Drawing.
rnocnss or nnracnmo WALL-PAPER.
Patented'D ec. 30, 1913.
Serial No. 416,544.
To all whom. it may concern:
Be it known that I, CARLn'roN ELLIS, a citizen of the United States, and resident of Larchmont, in the county of Westchester and State of New York, have invented certain new and useful Improvements in Processes of Detaching WalLP-aper, of which the following is a specification.
Ihis invention relates to .an improved process of removing old wallpaper from the walls to which it 13 attached, and has for its object the speedy removal of a wallpaper without injury to the plaster, wood or other surface'to which said wallaper may have been attached, all as more ully hereinafter set forth.
The removal of wallpaper by scraping or J by steam treatment or by both conjoined,
offers. many difficulties, and is, generally speaking, laborious. I have found certain solutions of certain salts of a hygroscopic nature'to be of great utility in the softening of such old wallpaper preparatory to its removal and my improved process consists in y as the application to said wallpaper, of solutions of hygroscopic salts, which in the terms of this art may be described as substantially neutral that is to say, have no deleterious action on-varnish or wood or other materials with which they may accidentally come in contact. Highly acid solutions are dangerous to handle, and if they come in contact with woodwork or with ainted surfaces are liable to cause serious amage. Volatile solvents ordinarily act upon paint or varnish.
My invention comprises the use of neutral salts which are placed in suitable solution, which solution when applied to wallpaper readily retains moisture, or in fact even absorbs from the moisture of the air an additional amount of water thereby maintaining the wallpaper in a damp condition until the paste or other adhesive is so softened that the paper may be readily detached from its support. 4
I preferably employ such-hygroscopic salts as the chlorids of calcium, magnesium, and zinc, these being cheap, readily available and highl eflicient for the purpose. The chlorid of zinc solutions have the additional advantage, when c'oncentrated, of parchmentizing the paper, rendering 1t capable of being stripped fromthe' wall asa firm sheet. I may, however, use hygroscopic salts such as acetate of pot-ash and the like. I dissolve the salt or salts in water or water and glycerin or other suitable solvent to form preferably a rather concentrated solution and apply this solution to the walls with a brush or sponge and allow the composition to remain thereon until the wallpaper is detachable. From one to twenty-four hours may be required for this purpose, depending upon the number of sheets of wallpaper to be removed and u on the character of said paper. The rapi lty of action is generally enhanced'by applying the composition in a heated condition. This may be accomplished by simply warming before use, or by using a spraying device which is adapted to handle such hot. applications. Some very highly sized or water-proofed papers, or papers containing designs imprinted with waterproof ink, are occasionally somewhat resistant and I have observed that the addition to the composition of a moderate amount of alcohol, acetone and the like, is occasionally an aid in accelerating the penetration ofthe solution. In extremely dry weather the action of the solution may be slightly accelerated by placing in the room where the .wallpapeneven in the driest weather.
A suitable composition for carrying out my process is made by dissolving two pounds of zlnc chlorid and two pounds of calcium chlorid in one gallon of water. This may be applied hot or cold, but preferably by hot spraying, or by means of a hollow brush appliance. 7
Another composition useful in treating wallpaper of a somewhat water-proof character is made by dissolving eight pounds of zinc chlorid in one gallon of water and in adding thereto. one-half gallon of wood alcohol or denatured alcohol.
Another formula comprises ten pounds zinc chlorid and five-'eighths of a gallon"? each of wood alcohol and water.
A composition useful for paper which has been exposed for a long time is made by dissolving eight pounds of magnesium chlorid chlorid solutions.
I in three quarts of water and one quart of Certain pastes are more readily softened" by a solution which is slightly acid and for such application I prefer to use weak acetic acid. in preference to a mineral acid, especially'the fixed mineral acids. 'To make a suitable weakly acid solution, I add about eight ounces of concentrated acetic acid to a gallon of the composition. Hydrochloric acid may be used to advantage with zinc An illustrative formula comprises ten pounds zinc chlorid, one pound hydrochloric acid, one gallon water and one-quarter gallon denatured alcohol.
Casein pastes which are not readily softened by an entirely neutral or slightly acid composition are more easily softened by a solution which is slightly "alkaline, and to effect suitable alkalinity of the solution I prefer to employ for such applications a hygroscopic metallic chlo-rid whichis slightly basic; aresult which may be brought about by the treatment of neutral solutions of the c lorid with a basis body or hydrate in regulated quantities. Ammonia sometimes may be used to advantage in these compositions. When an especially resistant wall-' paper is to be detached it is sometimes desirable to thicken the composition either with a soluble or insoluble thickener; as, for instance, whiting or other mineral or yegetable filler. Irish moss solution or pectinous matter may alsobe used for thickening,
the proportion, of course, being relatively small. A formula illustrating such a composition comprises 7 5% granulated calcium chlorid, two pounds, Irish moss, 1 ounce and water, 1 quart. A little alcohol or ammonia may be introduced.
What I claim as my invention is 1. The process of detaching wallpaper which consists in applying thereto an aqueous solution of a hygroscopic salt having a substantial solvent action on cellulose fiber, in allowing said solution to remain in contact with said wallpaper and thereby distend and dissolve the fiber thereof, in simultaneously softening and loosening the adhesive securing the wall paper in position and .in thereupon removing said wallpaper from its support. 2. The process of detaching wallpaper which consists in applying thereto a hot solution of a hygroscopic salt having a substantial, solvent action on cellulose fiber, in allowing said solution to remainin contact with said wallpaper and thereby distend and dissolve the fiber thereof, in simultane ously softening and loosening theadhesive CARLETON ELLIS.
Witnesses I FLETCHER P. Soormnn,
RICHARD WASTEOAT.
securing-the wallpaper in position and in
US41654408A 1908-02-18 1908-02-18 Process of detaching wall-paper. Expired - Lifetime US1083007A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4239832A (en) * 1978-11-30 1980-12-16 Eaton Allen Corp. Adhesively correctable transfer medium with delayed alteration resistance characteristics
US4979526A (en) * 1989-01-23 1990-12-25 Rudy Gus J Method and manufacture for removing wallpaper
US5858110A (en) * 1995-12-14 1999-01-12 Jackson; Richard L. Method of wallpaper removal
SE547633C2 (en) * 2024-06-14 2025-10-28 Smartax Byggmaterial Ab Method of reusing building boards

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4239832A (en) * 1978-11-30 1980-12-16 Eaton Allen Corp. Adhesively correctable transfer medium with delayed alteration resistance characteristics
US4979526A (en) * 1989-01-23 1990-12-25 Rudy Gus J Method and manufacture for removing wallpaper
US5858110A (en) * 1995-12-14 1999-01-12 Jackson; Richard L. Method of wallpaper removal
SE547633C2 (en) * 2024-06-14 2025-10-28 Smartax Byggmaterial Ab Method of reusing building boards
SE2450661A1 (en) * 2024-06-14 2025-10-28 Smartax Byggmaterial Ab Method of reusing building boards
WO2025257411A1 (en) * 2024-06-14 2025-12-18 Smartax Byggmaterial Ab Method of reusing building boards

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