TWM638339U - Wastewater treatment system with descaling function - Google Patents
Wastewater treatment system with descaling function Download PDFInfo
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- TWM638339U TWM638339U TW111212081U TW111212081U TWM638339U TW M638339 U TWM638339 U TW M638339U TW 111212081 U TW111212081 U TW 111212081U TW 111212081 U TW111212081 U TW 111212081U TW M638339 U TWM638339 U TW M638339U
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- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 95
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 104
- 239000011737 fluorine Substances 0.000 claims abstract description 104
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 103
- 239000002351 wastewater Substances 0.000 claims abstract description 82
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 21
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- -1 fluoride ions Chemical class 0.000 claims abstract description 12
- 239000010802 sludge Substances 0.000 claims description 82
- 239000007788 liquid Substances 0.000 claims description 69
- 238000000926 separation method Methods 0.000 claims description 67
- 238000006243 chemical reaction Methods 0.000 claims description 44
- 230000008719 thickening Effects 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 230000018044 dehydration Effects 0.000 claims description 13
- 238000006297 dehydration reaction Methods 0.000 claims description 13
- 229940043430 calcium compound Drugs 0.000 claims description 8
- 150000001674 calcium compounds Chemical class 0.000 claims description 8
- 239000003814 drug Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 16
- 230000007774 longterm Effects 0.000 abstract description 4
- 238000010586 diagram Methods 0.000 description 5
- 150000004760 silicates Chemical class 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 150000002221 fluorine Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
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Abstract
本創作公開一種具有除垢功能的廢水處理系統,包括一含氟廢水處理設施以及一除垢設施。含氟廢水處理設施經配置以將含氟廢水中的氟離子轉化為氟化鈣,除垢設施連通於含氟廢水處理設施,且除垢設施經配置以將一除垢劑導入含氟廢水處理設施內,並以循環流動於含氟廢水處理設施與除垢設施之間的方式進行除垢。因此,能降低結垢物質對於廢水處理效能的負面影響,確保系統的連續長時間穩定運行。The invention discloses a wastewater treatment system with descaling function, which includes a fluorine-containing wastewater treatment facility and a descaling facility. The fluorine-containing wastewater treatment facility is configured to convert fluoride ions in the fluoride-containing wastewater into calcium fluoride, the descaling facility is connected to the fluoride-containing wastewater treatment facility, and the descaling facility is configured to introduce a descaling agent into the fluorine-containing wastewater treatment In the facility, descaling is carried out by circulating between the fluorine-containing wastewater treatment facility and the descaling facility. Therefore, the negative impact of fouling substances on the wastewater treatment efficiency can be reduced, and the continuous and long-term stable operation of the system can be ensured.
Description
本創作涉及一種廢水處理系統,特別是涉及一種具有除垢功能的廢水處理系統,適於處理含有氟鹽、硫酸鹽或矽酸鹽等容易與鈣離子形成結垢物質的廢水。The invention relates to a wastewater treatment system, in particular to a wastewater treatment system with scale removal function, which is suitable for treating wastewater containing fluorine salts, sulfates or silicates and other substances that easily form scales with calcium ions.
在各種工業製程中常見氟化物的使用,隨之也衍生出了含氟廢水的處理問題。為了避免廢水中的氟離子對環境造成汙染,並使流放水符合政府所訂定之排放標準,業界對於含氟廢水之處理已發展出許多技術。舉例來說,大部分高科技廠對於利用氫氟酸後產生之含氟廢水的處理方式,是先將廢水經由管線收集至廢水處理系統,再向廢水添加鈣鹽如氯化鈣、氫氧化鈣等,使存在於廢水中的氟離子與鈣離子反應形成氟化鈣顆粒,然後將氟化鈣顆粒從廢水中分離出來。The use of fluoride is common in various industrial processes, and the treatment of fluoride-containing wastewater has also been derived. In order to prevent the fluorine ions in the wastewater from polluting the environment and make the discharged water meet the discharge standards set by the government, the industry has developed many technologies for the treatment of fluoride-containing wastewater. For example, most high-tech factories treat the fluorine-containing wastewater generated after using hydrofluoric acid, first collecting the wastewater through pipelines to the wastewater treatment system, and then adding calcium salts such as calcium chloride and calcium hydroxide to the wastewater etc., react fluoride ions present in wastewater with calcium ions to form calcium fluoride particles, and then separate calcium fluoride particles from wastewater.
然而,含氟廢水中除了氟鹽之外,往往還含有其他物質也會與所添加的鈣鹽反應形成結垢物,例如硫酸鹽、矽酸鹽等。廢水處理系統在長期運轉下容易出現管線、設備、儀表或桶槽等的結垢堵塞問題,導致廢水無法以原本設計的流量進入系統,最壞的情況是只能藉由更換管線或設備來使系統恢復。However, in addition to fluorine salts, fluorine-containing wastewater often contains other substances that will react with the added calcium salts to form scales, such as sulfates and silicates. The wastewater treatment system is prone to fouling and clogging of pipelines, equipment, instruments or tanks under long-term operation, resulting in the inability of wastewater to enter the system at the originally designed flow rate. In the worst case, it can only be used by replacing pipelines or equipment. system recovery.
因此,現有的廢水處理系統仍存有實作上亟待解決的問題與瓶頸。Therefore, there are still practical problems and bottlenecks that need to be solved urgently in the existing wastewater treatment system.
本創作所要解決的技術問題在於,針對現有技術的不足提供一種具有除垢功能的廢水處理系統,其具有申請專利範圍第1項的特色,而可以有效地將結垢物質溶解後排出系統外,並維持在設計的處理流量範圍下運行。The technical problem to be solved in this creation is to provide a wastewater treatment system with descaling function in view of the deficiencies of the existing technology, which has the characteristics of the first item in the scope of the patent application, and can effectively dissolve the scaling substances and discharge them out of the system. And maintain the operation under the designed processing flow range.
為了解決上述的技術問題,本創作所採用的其中一技術方案是提供一種具有除垢功能的廢水處理系統,包括一含氟廢水處理設施以及一除垢設施。所述含氟廢水處理設施經配置以將含氟廢水中的氟離子轉化為氟化鈣。所述除垢設施連通於所述含氟廢水處理設施,且所述除垢設施經配置以將一除垢劑導入所述含氟廢水處理設施內,並以循環流動於所述含氟廢水處理設施與所述除垢設施之間的方式進行除垢。In order to solve the above technical problems, one of the technical solutions adopted in this creation is to provide a wastewater treatment system with descaling function, including a fluorine-containing wastewater treatment facility and a descaling facility. The fluorine-containing wastewater treatment facility is configured to convert fluoride ions in the fluoride-containing wastewater into calcium fluoride. The descaling facility is connected to the fluorine-containing wastewater treatment facility, and the descaling facility is configured to introduce a descaling agent into the fluorine-containing wastewater treatment facility, and circulate through the fluorine-containing wastewater treatment facility Descaling is carried out in a way between the facility and the descaling facility.
在本創作的一實施例中,所述除垢設施包括至少一除垢裝置,至少一所述除垢裝置包括一儲存容器及一加藥管線,所述加藥管線接設於所述儲存容器與所述含氟廢水處理設施之間,且所述加藥管線上裝設有一過濾器及一位於所述過濾器後方的輸送泵。In one embodiment of the present creation, the descaling facility includes at least one descaling device, at least one of the descaling devices includes a storage container and a dosing pipeline, and the dosing pipeline is connected to the storage container Between the fluorine-containing wastewater treatment facility and on the dosing pipeline, a filter and a delivery pump behind the filter are installed.
在本創作的一實施例中,所述含氟廢水處理設施包括一含氟廢水反應裝置以及一第一固液分離裝置。所述含氟廢水反應裝置經配置以接收所述含氟廢水,並向所述含氟廢水添加一鈣化合物,以與所述氟離子反應形成所述氟化鈣。所述第一固液分離裝置連通於所述含氟廢水反應裝置,以對反應後的所述含氟廢水進行固液分離處理。In an embodiment of the present invention, the fluorine-containing wastewater treatment facility includes a fluorine-containing wastewater reaction device and a first solid-liquid separation device. The fluorine-containing wastewater reaction device is configured to receive the fluoride-containing wastewater, and add a calcium compound to the fluoride-containing wastewater to react with the fluoride ions to form the calcium fluoride. The first solid-liquid separation device is connected to the fluorine-containing wastewater reaction device to perform solid-liquid separation treatment on the reacted fluorine-containing wastewater.
在本創作的一實施例中,所述含氟廢水反應裝置包括一反應槽及一設置於所述反應槽內的攪拌器。In an embodiment of the present creation, the fluorine-containing wastewater reaction device includes a reaction tank and an agitator arranged in the reaction tank.
在本創作的一實施例中,所述含氟廢水處理設施還包括一第一汙泥濃縮裝置,且所述第一汙泥濃縮裝置連通於所述第一固液分離裝置。In an embodiment of the present creation, the fluorine-containing wastewater treatment facility further includes a first sludge thickening device, and the first sludge thickening device is communicated with the first solid-liquid separation device.
在本創作的一實施例中,所述含氟廢水處理設施還包括一汙泥脫水裝置,且所述汙泥脫水裝置連通於所述第一汙泥濃縮裝置。In an embodiment of the present creation, the fluorine-containing wastewater treatment facility further includes a sludge dewatering device, and the sludge dewatering device is connected to the first sludge thickening device.
在本創作的一實施例中,所述含氟廢水反應裝置與所述第一固液分離裝置之間接設有一第一輸送管線及一第一回流管線。又,所述第一固液分離裝置與所述第一汙泥濃縮裝置之間接設有一第二輸送管線,且所述第一固液分離裝置通過一第一排放管線排出處理水。另外,所述第一汙泥濃縮裝置與所述汙泥脫水裝置之間接設有一第三輸送管線。In an embodiment of the present invention, a first delivery pipeline and a first return pipeline are connected between the fluorine-containing wastewater reaction device and the first solid-liquid separation device. In addition, a second delivery pipeline is connected between the first solid-liquid separation device and the first sludge thickening device, and the first solid-liquid separation device discharges the treated water through a first discharge pipeline. In addition, a third delivery pipeline is indirectly provided between the first sludge thickening device and the sludge dewatering device.
在本創作的一實施例中,至少一所述除垢裝置還包括一循環管線,且所述加藥管線、所述循環管線與所述第一至第三輸送管線、所述第一回流管線及所述第一排放管線中的至少一者構成除垢處理迴路。In an embodiment of the present creation, at least one of the descaling devices further includes a circulation line, and the dosing line, the circulation line, the first to the third delivery lines, and the first return line and at least one of the first discharge lines constitute a descaling treatment circuit.
在本創作的一實施例中,所述含氟廢水處理設施還包括一第二固液分離裝置以及一第二汙泥濃縮裝置。所述第二固液分離裝置連通於所述含氟廢水反應裝置,以對反應後的所述含氟廢水進行固液分離處理,且所述第二固液分離裝置設置為與所述第一固液分離裝置並聯運行。所述第二汙泥濃縮裝置連通於所述第二固液分離裝置與所述汙泥脫水裝置之間。In an embodiment of the present creation, the fluorine-containing wastewater treatment facility further includes a second solid-liquid separation device and a second sludge thickening device. The second solid-liquid separation device is connected to the fluorine-containing wastewater reaction device to perform solid-liquid separation treatment on the reacted fluorine-containing wastewater, and the second solid-liquid separation device is set to be connected with the first The solid-liquid separation devices operate in parallel. The second sludge thickening device is connected between the second solid-liquid separation device and the sludge dehydration device.
在本創作的一實施例中,所述含氟廢水反應裝置與所述第二固液分離裝置之間接設有一第四輸送管線及一第二回流管線。又,所述第二固液分離裝置與所述第二汙泥濃縮裝置之間接設有一第五輸送管線,且所述第二固液分離裝置通過一第二排放管線排出處理水。另外,所述第二汙泥濃縮裝置與所述汙泥脫水裝置之間接設有一第六輸送管線。In an embodiment of the present invention, a fourth delivery pipeline and a second return pipeline are connected between the fluorine-containing wastewater reaction device and the second solid-liquid separation device. In addition, a fifth delivery pipeline is connected between the second solid-liquid separation device and the second sludge thickening device, and the second solid-liquid separation device discharges the treated water through a second discharge pipeline. In addition, a sixth delivery pipeline is indirectly provided between the second sludge thickening device and the sludge dehydration device.
在本創作的一實施例中,至少一所述除垢裝置還包括一循環管線,且所述加藥管線、所述循環管線與所述第一至第六輸送管線、所述第一和第二回流管線及所述第一和第二排放管線中的至少一者構成除垢處理迴路。In an embodiment of the present invention, at least one of the descaling devices further includes a circulation line, and the dosing line, the circulation line and the first to sixth delivery lines, the first and the second Two return lines and at least one of said first and second discharge lines constitute a descaling treatment circuit.
總結來說,本創作的具有除垢功能的廢水處理系統適於處理含有氟鹽、硫酸鹽或矽酸鹽等容易與鈣離子形成結垢物質的廢水,且其能通過“所述除垢設施連通於所述含氟廢水處理設施”以及“所述除垢設施經配置以將一除垢劑導入所述含氟廢水處理設施內,並以循環流動於所述含氟廢水處理設施與所述除垢設施之間的方式進行除垢”的技術特徵,以降低結垢物質對於廢水處理效能的負面影響,確保系統的連續長時間穩定運行。更進一步來說,當含氟廢水處理設施中有裝置或管線發生結垢堵塞問題時,除垢劑可以循環擾動的方式將沉積在裝置或管線的任何部分上的結垢物質溶解、沖刷後排出至外部。To sum up, the waste water treatment system with descaling function of this creation is suitable for treating waste water containing fluorine salts, sulfates or silicates, etc., which are easy to form scaling substances with calcium ions, and it can Connected to the fluorine-containing wastewater treatment facility" and "the descaling facility is configured to introduce a descaling agent into the fluorine-containing wastewater treatment facility, and circulate between the fluorine-containing wastewater treatment facility and the The technical feature of descaling between descaling facilities" is to reduce the negative impact of scaling substances on wastewater treatment efficiency and ensure the continuous and long-term stable operation of the system. Furthermore, when there is fouling and clogging of equipment or pipelines in the fluorine-containing wastewater treatment facilities, the descaling agent can dissolve and wash away the scaling substances deposited on any part of the equipment or pipelines in a cyclic and disturbed manner. to the outside.
為使能更進一步瞭解本創作的特徵及技術內容,請參閱以下有關本創作的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並非用來對本創作加以限制。In order to further understand the characteristics and technical content of this creation, please refer to the following detailed description and drawings about this creation. However, the provided drawings are only for reference and explanation, and are not used to limit this creation.
以下是通過特定的具體實施例來說明本創作所公開有關“具有除垢功能的廢水處理系統”的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本創作的優點與效果。本創作可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不背離本創作的構思下進行各種修改與變更。另外,本創作的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本創作的相關技術內容,但所公開的內容並非用以限制本創作的保護範圍。另外,本文中所使用的術語“或”,應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。The following are specific examples to illustrate the implementation of the "wastewater treatment system with descaling function" disclosed in this creation. Those skilled in the art can understand the advantages and effects of this creation from the content disclosed in this specification. This creation can be implemented or applied through other different specific embodiments, and the details in this specification can also be modified and changed based on different viewpoints and applications without departing from the idea of this creation. In addition, the drawings of this creation are only for simple illustration, not according to the actual size of the depiction, prior statement. The following embodiments will further describe the relevant technical content of this creation in detail, but the disclosed content is not intended to limit the protection scope of this creation. In addition, the term "or" used herein may include any one or a combination of more of the associated listed items depending on the actual situation.
在沒有另行定義的情況下,本文中所使用的術語具有與本領域技術人員的通常理解相同的含義。各實施例中所涉及的材料,如無特別說明則為市售或根據現有技術製得的材料。各實施例中所涉及的操作或儀器,如無特別說明則為本領域常規的操作或儀器。Unless otherwise defined, terms used herein have the same meaning as commonly understood by those skilled in the art. The materials involved in each embodiment are commercially available or prepared according to the prior art unless otherwise specified. The operations or instruments involved in each embodiment are conventional operations or instruments in the art unless otherwise specified.
[第一實施例][first embodiment]
請參閱圖1至圖3,並配合圖5所示,本創作第一實施例提供一種具有除垢功能的廢水處理系統Z,其包括一含氟廢水處理設施1以及一除垢設施2,且除垢設施2連通於含氟廢水處理設施1。使用時,除垢設施2可向含氟廢水處理設施1中有結垢堵塞問題的裝置或管線通入除垢劑,使得結垢物質在除垢劑的作用下溶解、沖刷後排出系統外,從而降低結垢物質對於廢水處理效能的負面影響。因此,本創作的廢水處理系統Z可以在設計的處理流量範圍下連續長時間穩定運行。Please refer to Figures 1 to 3, and in conjunction with Figure 5, the first embodiment of the present invention provides a wastewater treatment system Z with descaling function, which includes a fluorine-containing
在本實施例中,含氟廢水處理設施1可經配置以將含氟廢水中的氟離子轉化為氟化鈣,除垢設施2可經配置以將除垢劑導入含氟廢水處理設施1,並以循環流動於含氟廢水處理設施1與除垢設施2之間的方式進行除垢。本文中提到的含氟廢水可為各種工業製程廢水、再生廢水或反洗廢水。然而,本創作不以上述所舉的例子為限。In this embodiment, the fluorine-containing
具體來說,如圖3所示,含氟廢水處理設施1主要包括一含氟廢水反應裝置11及一第一固液分離裝置12。含氟廢水反應裝置11可經配置以接收含氟廢水,並向含氟廢水添加一鈣化合物,其可與氟離子反應形成難溶性物質氟化鈣(氟化鈣汙泥)。第一固液分離裝置12連通於含氟廢水反應裝置11,以對反應後的含氟廢水進行固液分離處理,即將顆粒和泥狀物質從水體中分離出來,達到將廢水中所含的氟離子去除之目的。第一固液分離裝置12可包括一沉降槽或一浮除槽,但不限於此。Specifically, as shown in FIG. 3 , the fluorine-containing
實際應用時,含氟廢水反應裝置11可包括一反應槽111及一設置於反應槽111內的攪拌器112。反應槽111可連通於一廢水輸入管線P10,以將含氟廢水導入內部空間進行化學反應,且反應槽111可具有一加藥端,其主要功用是將所需量的鈣化合物投加到含氟廢水中。含氟廢水的化學反應可控制在鹼性條件(pH = 8.0~9.0)下進行,其中鈣化合物可採用鈣鹽如氯化鈣或氫氧化鈣,且可以溶液形式投加,但本創作不受限於此;而鈣化合物的投加量可根據廢水中的氟離子濃度和廢水的總量來決定。攪拌器112可充分攪動含氟廢水,以增加鈣化合物與氟離子的碰撞機率,儘可能地降低含氟廢水中的氟離子濃度。In practical application, the fluorine-containing
根據實際需要,含氟廢水處理設施1還可包括一原水槽13,用以存放待處理的含氟廢水,且廢水輸入管線P10可接設於原水槽13與含氟廢水反應裝置11之間。According to actual needs, the fluorine-containing
如圖2及圖5所示,除垢設施2可包括至少一個除垢裝置2a,且除垢裝置可包括一儲存容器21及一加藥管線22。儲存容器21用以存放除垢劑,其可為一儲存桶,但不限於此。加藥管線22接設於儲存容器21與含氟廢水處理設施1之間,且加藥管線22上裝設有一過濾器23及一位於過濾器23後方的輸送泵24。據此,當含氟廢水處理設施1中有裝置或管線發生結垢堵塞問題時,可控制輸送泵24開始工作(系統的送水/回水控制閥關閉,且進水泵停止工作),以將儲存容器21中的除垢劑導出至含氟廢水處理設施1,並以循環擾動的方式將沉積在裝置或管線的任何部分上的結垢物質溶解後排出至外部。As shown in FIG. 2 and FIG. 5 , the
值得一提的是,含氟廢水中往往還會有其他物質也會與所添加的鈣化合物反應形成結垢物,例如硫酸鹽、矽酸鹽等,而除垢裝置2a可以有效地去除在含氟廢水處理設施1中造成堵塞的結垢物質。較佳地,除垢裝置2a中的除垢劑可採用草酸、乙二胺四乙酸(EDTA)、液鹼或硫代硫酸鹽,但不限於此。It is worth mentioning that there are often other substances in fluorine-containing wastewater that will react with the added calcium compounds to form scales, such as sulfates, silicates, etc., and the
在一些實施例中,含氟廢水反應裝置11與第一固液分離裝置12之間接設有一第一輸送管線P11及一第一回流管線P21。第一輸送管線P11可經配置以將反應後的含氟廢水從含氟廢水反應裝置11送至第一固液分離裝置12進行固液分離處理,第一回流管線P21可經配置以將第一固液分離裝置12所分離出來的氟化鈣汙泥返回至含氟廢水反應裝置11進行化學反應。又,第一固液分離裝置12可連通於一第一排放管線P31,且第一排放管線P31可經配置以將第一固液分離裝置12所分離出來的處理水從預定的位置排出,以便於進行後續處理、回收或排放。In some embodiments, a first delivery pipeline P11 and a first return pipeline P21 are indirectly provided between the fluorine-containing
請複參閱圖3,並配合圖5所示,在本創作中,含氟廢水處理設施1還可包括一第一汙泥濃縮裝置14及一汙泥脫水裝置15。第一汙泥濃縮裝置14連通於第一固液分離裝置12,且第一汙泥濃縮裝置14可經配置以接收從反應後的含氟廢水中分離出來的氟化鈣汙泥,並通過延長汙泥沉澱時間的方式來降低汙泥的含水率。第一汙泥濃縮裝置14可為一重力濃縮裝置,但不限於此。汙泥脫水裝置15連通於第一汙泥濃縮裝置14,且汙泥脫水裝置15可經配置以對濃縮後的氟化鈣汙泥進行脫水,以進一步降低汙泥的含水率,同時減少汙泥的體積。因此,汙泥產出量會有明顯的減少,從而達到汙泥清運費用更加節省之目的。Please refer to FIG. 3 again, and as shown in FIG. 5 , in this invention, the fluorine-containing
在一些實施例中,第一固液分離裝置12與第一汙泥濃縮裝置14之間接設有一第二輸送管線P12,且第一汙泥濃縮裝置14與汙泥脫水裝置15之間接設有一第三輸送管線P13。第二輸送管線P12可經配置以將第一固液分離裝置12所分離出來的氟化鈣汙泥送至第一汙泥濃縮裝置14進行濃縮脫水,第三輸送管線P13可經配置以將濃縮後的汙泥送至汙泥脫水裝置15進行深度脫水。In some embodiments, a second delivery pipeline P12 is indirectly provided between the first solid-
實際應用時,除垢裝置2a還可包括一循環管線25,且除垢裝置2a的加藥管線22及循環管線25可與第一至第三輸送管線P11-P13、第一回流管線P21及第一排放管線P31中的至少一者構成除垢處理迴路;在除垢處理過程中,系統的送水/回水控制閥關閉,且進水泵停止工作。在此基礎上,就可以實現除垢劑以循環流動於含氟廢水處理設施1與除垢設施2之間的方式進行除垢。值得一提的是,伴隨除垢劑流動的雜物可被加藥管線22上的過濾器23攔截住,確保除垢過程不會受到干擾。In actual application, the
[第二實施例][Second embodiment]
請參閱圖4,並配合圖1及圖5所示,本創作第二實施例提供一種具有除垢功能的廢水處理系統Z,其包括一含氟廢水處理設施1以及一除垢設施2,且除垢設施2連通於含氟廢水處理設施1。含氟廢水處理設施1可經配置以將含氟廢水中的氟離子轉化為氟化鈣,除垢設施2可經配置以將除垢劑導入含氟廢水處理設施1,並以循環流動於含氟廢水處理設施1與除垢設施2之間的方式進行除垢。Please refer to Fig. 4, and as shown in Fig. 1 and Fig. 5, the second embodiment of the present invention provides a wastewater treatment system Z with descaling function, which includes a fluorine-containing
在本實施例中,除了在第一實施例中描述過的含氟廢水反應裝置11、第一固液分離裝置12、第一汙泥濃縮裝置14與汙泥脫水裝置15之外,含氟廢水處理設施1還可包括一第二固液分離裝置16及一第二汙泥濃縮裝置17,以提高廢水處理效能。第二固液分離裝置16可具有與第一固液分離裝置12相同的構造和功能,且第二汙泥濃縮裝置17可具有與第一汙泥濃縮裝置14相同的構造和功能。關於含氟廢水反應裝置11、第一固液分離裝置12、第一汙泥濃縮裝置14與汙泥脫水裝置15的技術細節,可參考第一實施例所述,故在此不加以贅述。In this embodiment, in addition to the fluorine-containing
具體來說,第二固液分離裝置16連通於含氟廢水反應裝置11,以對反應後的含氟廢水進行固液分離處理,且第二固液分離裝置16設置為與第一固液分離裝置12並聯運行。第二汙泥濃縮裝置17連通於第二固液分離裝置16與汙泥脫水裝置15之間,且第二汙泥濃縮裝置17可經配置以接收第二固液分離裝置16所分離出來的氟化鈣汙泥,並通過延長汙泥沉澱時間的方式來降低汙泥的含水率。然後,經第二汙泥濃縮裝置17濃縮後的汙泥也可送至汙泥脫水裝置15進行深度脫水。因此,即使除垢裝置2a正在對第一固液分離裝置12或接設於第一固液分離裝置12的管線進行除垢,含氟廢水反應裝置11所排出的反應後的含氟廢水仍可導入到第二固液分離裝置16內進行固液分離處理,且可繼續通過第二汙泥濃縮裝置17與汙泥脫水裝置15進行後續處理,以避免廢水處理流程停止於固液分離階段。Specifically, the second solid-
在一些實施例中,含氟廢水反應裝置11與第二固液分離裝置16之間接設有一第四輸送管線P14及一第二回流管線P22。第四輸送管線P14可經配置以將反應後的含氟廢水從含氟廢水反應裝置11送至第二固液分離裝置16進行固液分離處理,第二回流管線P22可經配置以將第二固液分離裝置16所分離出來的氟化鈣汙泥返回至含氟廢水反應裝置11進行化學反應。又,第二固液分離裝置16與第二汙泥濃縮裝置17之間接設有一第五輸送管線P15,且第二固液分離裝置16通過一第二排放管線P32排出處理水。第五輸送管線P15可經配置以將第二固液分離裝置16所分離出來的氟化鈣汙泥送至第二汙泥濃縮裝置17進行濃縮脫水,第二排放管線P32可經配置以將第二固液分離裝置16所分離出來的處理水從預定的位置排出,以便於進行後續處理、回收或排放。另外,第二汙泥濃縮裝置17與汙泥脫水裝置15之間接設有一第六輸送管線P16,且第六輸送管線P16可經配置以將濃縮後的汙泥送至汙泥脫水裝置15進行深度脫水。In some embodiments, a fourth delivery pipeline P14 and a second return pipeline P22 are indirectly provided between the fluorine-containing
實際應用時,除垢裝置2a的加藥管線22及循環管線25可與第一至第六輸送管線P11-P16、第一和第二回流管線P21、P22及第一和第二排放管線P31、P32中的至少一者構成除垢處理迴路;在除垢處理過程中,系統的送水/回水控制閥關閉,且水泵停止工作。在此基礎上,即可以實現除垢劑以循環流動於含氟廢水處理設施1與除垢設施2之間的方式進行除垢。In actual application, the
第一實施例中提到的相關技術細節在本實施例中依然有效,為了減少重複,這裡不再贅述。同樣地,本實施例中提到的相關技術細節也可以應用在第一實施例中。The relevant technical details mentioned in the first embodiment are still valid in this embodiment, and will not be repeated here to reduce repetition. Likewise, the related technical details mentioned in this embodiment can also be applied in the first embodiment.
[實施例的有益效果][Advantageous Effects of Embodiment]
總結來說,本創作的具有除垢功能的廢水處理系統適於處理含有氟鹽、硫酸鹽或矽酸鹽等容易與鈣離子形成結垢物質的廢水,且其能通過“所述除垢設施連通於所述含氟廢水處理設施”以及“所述除垢設施經配置以將一除垢劑導入所述含氟廢水處理設施內,並以循環流動於所述含氟廢水處理設施與所述除垢設施之間的方式進行除垢”的技術特徵,以降低結垢物質對於廢水處理效能的負面影響,確保系統的連續長時間穩定運行。更進一步來說,當含氟廢水處理設施中有裝置或管線發生結垢堵塞問題時,除垢劑可以循環擾動的方式將沉積在裝置或管線的任何部分上的結垢物質溶解、沖刷後排出至外部。To sum up, the waste water treatment system with descaling function of this creation is suitable for treating waste water containing fluorine salts, sulfates or silicates, etc., which are easy to form scaling substances with calcium ions, and it can Connected to the fluorine-containing wastewater treatment facility" and "the descaling facility is configured to introduce a descaling agent into the fluorine-containing wastewater treatment facility, and circulate between the fluorine-containing wastewater treatment facility and the The technical feature of descaling between descaling facilities" is to reduce the negative impact of scaling substances on wastewater treatment efficiency and ensure the continuous and long-term stable operation of the system. Furthermore, when there is fouling and clogging of equipment or pipelines in the fluorine-containing wastewater treatment facilities, the descaling agent can dissolve and wash away the scaling substances deposited on any part of the equipment or pipelines in a cyclic and disturbed manner. to the outside.
以上所公開的內容僅為本創作的優選可行實施例,並非因此侷限本創作的申請專利範圍,所以凡是運用本創作說明書及圖式內容所做的等效技術變化,均包含於本創作的申請專利範圍內。The content disclosed above is only the preferred feasible embodiment of this creation, and does not limit the scope of patent application for this creation. Therefore, all equivalent technical changes made by using the instructions and drawings of this creation are included in the application of this creation. within the scope of the patent.
Z:廢水處理系統
1:含氟廢水處理設施
11:含氟廢水反應裝置
111:反應槽
112:攪拌器
12:第一固液分離裝置
13:原水槽
14:第一汙泥濃縮裝置
15:汙泥脫水裝置
16:第二固液分離裝置
17:第二汙泥濃縮裝置
2:除垢設施
2a:除垢裝置
21:儲存容器
22:加藥管線
23:過濾器
24:輸送泵
25:循環管線
P10:廢水輸入管線
P11:第一輸送管線
P12:第二輸送管線
P13:第三輸送管線
P14:第四輸送管線
P15:第五輸送管線
P16:第六輸送管線
P21:第一回流管線
P22:第二回流管線
P31:第一排放管線
P32:第二排放管線
Z: Wastewater treatment system
1: Fluorine-containing wastewater treatment facilities
11: Fluorine-containing wastewater reaction device
111: Reaction tank
112: Stirrer
12: The first solid-liquid separation device
13: Original sink
14: The first sludge thickening device
15: Sludge dewatering device
16: The second solid-liquid separation device
17: The second sludge thickening device
2: Descaling
圖1為本創作的具有除垢功能的廢水處理系統的總體架構圖。Fig. 1 is the overall structure diagram of the wastewater treatment system with descaling function created by this invention.
圖2為本創作的具有除垢功能的廢水處理系統的具體架構圖。Fig. 2 is the specific architecture diagram of the waste water treatment system with descaling function created by this invention.
圖3為本創作的具有除垢功能的廢水處理系統的含氟廢水處理設施的其中一實施架構圖。FIG. 3 is an implementation framework diagram of the fluorine-containing wastewater treatment facility of the wastewater treatment system with descaling function of the present invention.
圖4為本創作的具有除垢功能的廢水處理系統的含氟廢水處理設施的另外一實施架構圖。Fig. 4 is another implementation framework diagram of the fluorine-containing wastewater treatment facility of the wastewater treatment system with descaling function in this invention.
圖5為本創作的具有除垢功能的廢水處理系統的除垢處理迴路的示意圖。Fig. 5 is a schematic diagram of the descaling treatment circuit of the waste water treatment system with descaling function of the present invention.
Z:廢水處理系統 Z: Wastewater treatment system
1:含氟廢水處理設施 1: Fluorine-containing wastewater treatment facilities
2:除垢設施 2: Descaling facilities
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