TWM498197U - Energy-saving glass - Google Patents
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- TWM498197U TWM498197U TW103218997U TW103218997U TWM498197U TW M498197 U TWM498197 U TW M498197U TW 103218997 U TW103218997 U TW 103218997U TW 103218997 U TW103218997 U TW 103218997U TW M498197 U TWM498197 U TW M498197U
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- multilayer film
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- 239000011521 glass Substances 0.000 title claims abstract description 102
- 239000000758 substrate Substances 0.000 claims abstract description 116
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 45
- 238000009413 insulation Methods 0.000 claims description 21
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 16
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 16
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 14
- 229910001887 tin oxide Inorganic materials 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- 230000003287 optical effect Effects 0.000 claims description 13
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 12
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 8
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 8
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000005083 Zinc sulfide Substances 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 4
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- DLCRXTYMOCAMIQ-UHFFFAOYSA-N [O].[Sn].[Bi] Chemical compound [O].[Sn].[Bi] DLCRXTYMOCAMIQ-UHFFFAOYSA-N 0.000 claims description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- -1 polyethylene terephthalate Polymers 0.000 claims description 2
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910021392 nanocarbon Inorganic materials 0.000 claims 1
- 239000000075 oxide glass Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 102
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 28
- 230000000052 comparative effect Effects 0.000 description 10
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 8
- 230000000903 blocking effect Effects 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000004566 building material Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000003618 dip coating Methods 0.000 description 3
- 230000000873 masking effect Effects 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229910006561 Li—F Inorganic materials 0.000 description 1
- 206010052143 Ocular discomfort Diseases 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
Description
本新型創作是有關於一種節能玻璃，且特別是有關於一種節能膠合玻璃。The novel creation is related to an energy-saving glass, and in particular to an energy-saving glued glass.
目前因全球暖化效應造成世界各地的氣候產生極大改變，寒冬與酷暑的頻率愈來愈頻繁。現代化建築物的門窗、外牆，或交通工具的窗戶等除了導入更多環保建材與再生能源之外，建築師們也積極運用更多高科技的節能建材與綠建築空間設計。在建築的設計上為達透光性及美觀的需求，玻璃建材已大幅被運用於建築物，然除了考慮太陽光的紫外線輻射外，其紅外線的輻射熱亦會經由玻璃傳入室內，增加室內空調系統的負荷，徒增能源消耗及電費支出，故選用具有隔熱功效的節能玻璃作為建材便應運而生，以達節省能源的目的並提供舒服的生活環境。At present, the climate around the world has changed dramatically due to the global warming effect, and the frequency of cold winters and hot summers has become more frequent. In addition to introducing more environmentally-friendly building materials and renewable energy, doors and windows, exterior walls, or windows of vehicles in modern buildings are also actively using more high-tech energy-saving building materials and green building space design. In the design of the building, in order to meet the requirements of light transmission and aesthetics, glass building materials have been widely used in buildings. Besides considering the ultraviolet radiation of sunlight, the infrared radiant heat will also be introduced into the room through the glass to increase the indoor air conditioner. The load of the system increases energy consumption and electricity expenses. Therefore, the use of energy-saving glass with heat insulation as a building material has emerged to save energy and provide a comfortable living environment.
市面上常見的節能玻璃可為鍍膜玻璃或於玻璃表面黏貼一片隔熱膜，然而鍍膜玻璃上的金屬層不僅容易氧化，其製作工序繁雜且真空鍍膜設備成本高，導致鍍膜玻璃售價居高不下，降低其產業競爭力；至於在玻璃上黏貼隔熱膜的作法，易於加工過 程中有皺摺不平或產生氣泡等問題，且長期使用下恐會產生黏膠變質劣化、隔熱膜局部刮傷、剝落、風化等問題，大幅影響玻璃的耐用性、透光度及美觀，加上夜晚於室內開燈時，室內的人會看到該玻璃的反射鏡面，而看不清室外景色，著實降低其實用性。另外，上述金屬膜或隔熱膜的反射率高，容易造成環境光害污染，影響用路人的視線，因此現階段的節能玻璃的製作及設計仍有待改善。The common energy-saving glass on the market can be coated glass or a film on the surface of the glass. However, the metal layer on the coated glass is not only easy to oxidize, the manufacturing process is complicated, and the cost of the vacuum coating equipment is high, resulting in high price of coated glass. , to reduce its industrial competitiveness; as for the practice of sticking a heat-insulating film on glass, it is easy to process There are problems such as wrinkles or bubbles in the process, and long-term use may cause problems such as deterioration of adhesive deterioration, partial scratching, peeling and weathering of the heat-insulating film, which greatly affects the durability, transparency and appearance of the glass. In addition, when the lights are turned on indoors at night, people in the room will see the mirror surface of the glass, and the outdoor scenery will not be seen, which will actually reduce its practicability. In addition, the above-mentioned metal film or heat-insulating film has high reflectance, is likely to cause environmental pollution, and affects the line of sight of the passers-by. Therefore, the production and design of the energy-saving glass at this stage still needs to be improved.
本揭露實施例提出提供一種節能玻璃，包括第一基板、第一氧化物多層膜、第二氧化物多層膜、第二基板、第一結合層、以及紅外線反射層。第一氧化物多層膜設置於第一基板的第一表面上，第二氧化物多層膜設置於第一基板的第二表面上。第二基板與第一基板相對設置。第一結合層設置於第二基板的第一表面與第二氧化物多層膜之間。紅外線反射層設置於第二基板的第二表面上。The present disclosure proposes to provide an energy-saving glass comprising a first substrate, a first oxide multilayer film, a second oxide multilayer film, a second substrate, a first bonding layer, and an infrared reflecting layer. The first oxide multilayer film is disposed on the first surface of the first substrate, and the second oxide multilayer film is disposed on the second surface of the first substrate. The second substrate is disposed opposite to the first substrate. The first bonding layer is disposed between the first surface of the second substrate and the second oxide multilayer film. The infrared reflective layer is disposed on the second surface of the second substrate.
本揭露實施例還提出一種節能玻璃用之基板結構，包括基板、第一氧化物多層膜以及第二氧化物多層膜。第一氧化物多層膜設置於所述基板的第一表面上。第二氧化物多層膜設置於所述基板的第二表面上。The disclosed embodiment further provides a substrate structure for energy-saving glass, comprising a substrate, a first oxide multilayer film, and a second oxide multilayer film. A first oxide multilayer film is disposed on the first surface of the substrate. A second oxide multilayer film is disposed on the second surface of the substrate.
本揭露的節能玻璃裝置在基板的兩面設置氧化物多層膜，可調整可見光區的反射特性，使得可見光區反射小於25%， 以減少熱能穿透。The energy-saving glass device of the present disclosure is provided with an oxide multilayer film on both sides of the substrate, which can adjust the reflection characteristics of the visible light region, so that the visible light region reflects less than 25%. To reduce the penetration of heat.
本揭露的節能玻璃裝置在室內側的基板的表面設置紅外線反射層，可有效反射紅外線，減少紅外線進入室內，因此可以避免室內溫度提高。The energy-saving glass device of the present invention is provided with an infrared reflecting layer on the surface of the substrate on the indoor side, which can effectively reflect infrared rays and reduce infrared rays from entering the room, thereby avoiding an increase in indoor temperature.
本揭露實施例的節能玻璃裝置，在兩片基板之間設置隔熱結構，可達到更佳的隔熱效果。In the energy-saving glass device of the embodiment, the heat insulating structure is disposed between the two substrates to achieve better heat insulation effect.
以下係藉由特定的具體實施例說明本揭露的實施方式，熟習此技藝之人士可由本說明書所揭示之內容瞭解本揭露之其他優點與功效。本揭露也可藉由其他不同的具體實施例加以施行或應用，本說明書中的各項細節亦可基於不同觀點與應用，在不悖離本創作之精神下進行各種修飾與變更。The embodiments of the present disclosure are described by way of specific examples, and those skilled in the art can understand the other advantages and advantages of the disclosure. The present disclosure may also be implemented or applied by other different embodiments. The details of the present specification can also be modified and changed without departing from the spirit and scope of the present invention.
10、20、30‧‧‧節能玻璃10, 20, 30‧ ‧ energy-saving glass
100‧‧‧第一基板100‧‧‧First substrate
101‧‧‧第一基板的第一表面101‧‧‧ First surface of the first substrate
102‧‧‧第一基板的第二表面102‧‧‧Second surface of the first substrate
120‧‧‧第一氧化物多層膜120‧‧‧First oxide multilayer film
121a、121c‧‧‧第一氧化層121a, 121c‧‧‧ first oxide layer
122a、122b‧‧‧第二氧化層122a, 122b‧‧‧Second oxide layer
121b、121d‧‧‧另一第一氧化層121b, 121d‧‧‧ another first oxide layer
140‧‧‧第二氧化物多層膜140‧‧‧Second oxide multilayer film
160‧‧‧光學調整層160‧‧‧Optical adjustment layer
180‧‧‧第一結合層180‧‧‧First bonding layer
200‧‧‧第二基板200‧‧‧second substrate
201‧‧‧第二基板的第一表面201‧‧‧ First surface of the second substrate
202‧‧‧第二基板的第二表面202‧‧‧Second surface of the second substrate
220‧‧‧紅外線反射層220‧‧‧Infrared reflective layer
240‧‧‧隔熱結構240‧‧‧Insulation structure
260‧‧‧第二結合層260‧‧‧second bonding layer
280‧‧‧隔熱紙280‧‧‧Insulation paper
圖1為依照本揭露實施例1所繪示的一種節能玻璃的剖面示意圖。1 is a schematic cross-sectional view of an energy-saving glass according to Embodiment 1 of the present disclosure.
圖2為依照本揭露第一氧化物多層膜及第二氧化物多層膜的詳細結構示意圖。2 is a schematic view showing the detailed structure of the first oxide multilayer film and the second oxide multilayer film in accordance with the present disclosure.
圖3繪示各種厚度的第一氧化物多層膜及第二氧化物多層膜的反射圖譜。3 is a reflection spectrum of a first oxide multilayer film and a second oxide multilayer film of various thicknesses.
圖4為依照本揭露實施例2所繪示的一種節能玻璃的剖面示意圖。4 is a cross-sectional view of an energy-saving glass according to Embodiment 2 of the present disclosure.
圖5為依照本揭露實施例3所繪示的一種節能玻璃的剖面示意 圖。FIG. 5 is a schematic cross-sectional view of an energy-saving glass according to Embodiment 3 of the disclosure. Figure.
圖1為依照本揭露實施例1所繪示的一種節能玻璃的剖面示意圖。為簡化起見，在說明書與圖式中，相同的元件以相同的符號來表示之。圖2為第一氧化物多層膜及第二氧化物多層膜的結構。1 is a schematic cross-sectional view of an energy-saving glass according to Embodiment 1 of the present disclosure. For the sake of simplicity, the same elements are denoted by the same symbols in the description and the drawings. 2 is a view showing the structure of a first oxide multilayer film and a second oxide multilayer film.
請參照圖1，在一實施例中，節能玻璃10包括第一基板100、第一氧化物多層膜120、第二氧化物多層膜140、第一結合層180、第二基板200及紅外線反射層220。在另一實施例中，節能玻璃10還包括隔熱結構240。Referring to FIG. 1 , in an embodiment, the energy-saving glass 10 includes a first substrate 100 , a first oxide multilayer film 120 , a second oxide multilayer film 140 , a first bonding layer 180 , a second substrate 200 , and an infrared reflective layer 220. In another embodiment, the energy efficient glass 10 further includes a thermal insulation structure 240.
第一基板100與第二基板200為相對設置。第一基板100與第二基板200可以是相同材質，或相異材質。第一基板100及第二基板200可以分別包括含二氧化矽的玻璃、綠玻璃、鍍有氧化層膜的玻璃、低輻射(Low-E)玻璃、鍍銀玻璃、聚碳酸酯(PC)、聚對苯二甲酸乙二酯(PET)、聚酸甲酯(PMMA)或其組合。The first substrate 100 and the second substrate 200 are disposed opposite to each other. The first substrate 100 and the second substrate 200 may be the same material or different materials. The first substrate 100 and the second substrate 200 may respectively include ceria-containing glass, green glass, an oxide film-coated glass, low-emission (Low-E) glass, silver-plated glass, polycarbonate (PC), Polyethylene terephthalate (PET), polymethyl methacrylate (PMMA) or a combination thereof.
隔熱結構240具有可阻擋紅外線的功能。隔熱結構240位於第二基板200的第一表面201上。在一實施例中，隔熱結構240可為隔熱層，但不以此為限。在另一實施例中，隔熱結構240也可為隔熱紙與第二結合層，如圖4所示，其後再詳述。隔熱層例如是奈米陶瓷隔熱層、紅外線吸收層、光吸收層或紅外線阻隔層。奈米陶瓷隔熱層可為紅外線吸收材，其包括摻雜銫的奈米氧化鎢(CsWO3 )、奈米銻錫氧化物(ATO)、奈米六硼化鑭(LaB6 )、奈米碳黑隔熱塗料或其組合。奈米陶瓷隔熱層可藉噴塗或是刮塗 的方式來形成。在一實施例中，奈米陶瓷隔熱層可由奈米陶瓷粉體分散在樹脂中，再經由濕式旋塗法、噴塗法或刮塗法等方式製作在第二基板200的第一表面201上。奈米陶瓷隔熱層的厚度例如是4~10微米。在另一實施例中，隔熱結構240除了可以阻擋紅外線之外，還具有阻擋紫外線之功能。在一實施例中，隔熱結構240中還可包括紫外光吸收劑、耦合劑以及樹脂。The heat insulating structure 240 has a function of blocking infrared rays. The thermal insulation structure 240 is located on the first surface 201 of the second substrate 200. In an embodiment, the heat insulating structure 240 may be a heat insulating layer, but is not limited thereto. In another embodiment, the thermal insulation structure 240 can also be an insulating paper and a second bonding layer, as shown in FIG. 4, and will be described in detail later. The heat insulating layer is, for example, a nano ceramic heat insulating layer, an infrared absorbing layer, a light absorbing layer or an infrared ray blocking layer. The nano ceramic heat insulation layer may be an infrared absorbing material, which comprises cerium-doped nano tungsten oxide (CsWO 3 ), nano bismuth tin oxide (ATO), nano lanthanum hexaboride (LaB 6 ), nanometer. Carbon black insulation coating or a combination thereof. The nano ceramic insulation layer can be formed by spraying or scraping. In one embodiment, the nano ceramic thermal insulation layer is dispersed in the resin by the nano ceramic powder, and then formed on the first surface 201 of the second substrate 200 by wet spin coating, spray coating or doctor coating. on. The thickness of the nano ceramic insulation layer is, for example, 4 to 10 μm. In another embodiment, the heat insulating structure 240 has a function of blocking ultraviolet rays in addition to blocking infrared rays. In an embodiment, the heat insulating structure 240 may further include an ultraviolet light absorber, a coupling agent, and a resin.
紅外線反射層220位於第二基板的第二表面202上。紅外線反射層220的材料例如是低輻射(low-E)特性的金屬氧化物薄膜。紅外線反射層220可包括銦錫氧化物(ITO)、氟摻雜氧化錫(FTO)、氧化鋅(ZnO)或其組合。紅外線反射層220的厚度例如是0.3~1.5微米。紅外線反射層220可經由濺鍍法、蒸鍍法等方式製作在第二基板200的第二表面202上。The infrared reflective layer 220 is located on the second surface 202 of the second substrate. The material of the infrared reflective layer 220 is, for example, a metal oxide film having low-elow characteristics. The infrared reflective layer 220 may include indium tin oxide (ITO), fluorine-doped tin oxide (FTO), zinc oxide (ZnO), or a combination thereof. The thickness of the infrared ray reflection layer 220 is, for example, 0.3 to 1.5 μm. The infrared ray reflection layer 220 can be formed on the second surface 202 of the second substrate 200 by a sputtering method, a vapor deposition method, or the like.
第一結合層180設置於第一基板100的第二氧化物多層膜140與第二基板200的隔熱結構240之間。第一結合層180例如是聚乙烯醇縮丁醛(PVB)、乙烯醋酸乙烯酯(EVA)或其組合。第一結合層180可以透過熱及壓力與將具有第一氧化物多層膜120以及第二氧化物多層膜140的第一基板100，與具有隔熱結構240以及紅外線反射層220的第二基板200膠合成節能玻璃10。The first bonding layer 180 is disposed between the second oxide multilayer film 140 of the first substrate 100 and the heat insulating structure 240 of the second substrate 200. The first bonding layer 180 is, for example, polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), or a combination thereof. The first bonding layer 180 can transmit heat and pressure to the first substrate 100 having the first oxide multilayer film 120 and the second oxide multilayer film 140, and the second substrate 200 having the heat insulating structure 240 and the infrared reflecting layer 220. Glue synthetic energy-saving glass 10.
第一氧化物多層膜120位於第一基板100的第一表面101上，第二氧化物多層膜140位於第一基板100的第二表面102上。第一氧化物多層膜120與第二氧化物多層膜140是由具有高折射率的第一氧化層與具有低折射率的第二氧化層相互堆疊而成。在一實施例中，具有高折射率的第一氧化層可選自折射率在2.2~2.9範圍，且厚度為110~140奈米，具有低折射率的第二氧化層可選 自折射率在1.4~1.5範圍，且厚度為150~180奈米。高折射率的第一氧化層例如是氧化鈦(TiO2 )、氧化錫(SnO2 )、氧化鋅(ZnO)或硫化鋅(ZnS)，具有低折射率的第二氧化層可為氧化矽(SiO2 )、氟化鎂(MgF2 )或氟化鋰(LiF)。在一實施例中，第一氧化物多層膜120與第二氧化物多層膜140例如是分別由至少一二氧化矽(SiO2 )層與至少一二氧化鈦(TiO2 )層所組合而成。在一實施例中，所述二氧化矽層與所述二氧化鈦層以所述第一基板100為對稱中心對稱排列。The first oxide multilayer film 120 is located on the first surface 101 of the first substrate 100, and the second oxide multilayer film 140 is located on the second surface 102 of the first substrate 100. The first oxide multilayer film 120 and the second oxide multilayer film 140 are formed by stacking a first oxide layer having a high refractive index and a second oxide layer having a low refractive index. In one embodiment, the first oxide layer having a high refractive index may be selected from the range of 2.2 to 2.9, and the thickness is 110 to 140 nm, and the second oxide layer having a low refractive index may be selected from the refractive index. The range of 1.4~1.5, and the thickness is 150~180 nm. The first refractive layer having a high refractive index is, for example, titanium oxide (TiO 2 ), tin oxide (SnO 2 ), zinc oxide (ZnO), or zinc sulfide (ZnS), and the second oxide layer having a low refractive index may be cerium oxide ( SiO 2 ), magnesium fluoride (MgF 2 ) or lithium fluoride (LiF). In one embodiment, the first oxide multilayer film 120 and the second oxide multilayer film 140 are each formed, for example, by combining at least one cerium oxide (SiO 2 ) layer and at least one titanium dioxide (TiO 2 ) layer. In one embodiment, the ruthenium dioxide layer and the titanium dioxide layer are symmetrically arranged in a center of symmetry of the first substrate 100.
請參照圖2，在一實施例中，第一氧化物多層膜120及第二氧化物多層膜140各僅需使用三層氧化層，堆疊方式為於第一基板100的兩個表面上先形成具有高折射率的第一氧化層121a、121c，接下來於第一氧化層121a、121c上形成具有低折射率的第二氧化層122a、122b，最後再於第二氧化層122a、122b上形成具有高折射率的另一第一氧化層121b、121d。第一氧化層121a、121c、另一第一氧化層121b、121d的折射率可介於2.2至2.9，厚度可為110至140奈米，第二氧化層122a、122b的折射率可介於1.4至1.5，厚度可為150至180奈米。第一氧化層的材料例如為二氧化鈦。第二氧化層的材料例如為二氧化矽。第一氧化物多層膜120與第二氧化物多層膜140形成於第一基板100第一表面101與第二表面102的方式可經由工業上常使用的噴塗、浸塗法(Dip-Coating)或濕式旋塗法(Spin-Coating)等方式製作。Referring to FIG. 2, in an embodiment, the first oxide multilayer film 120 and the second oxide multilayer film 140 only need to use three oxide layers in a stacking manner to form on both surfaces of the first substrate 100. The first oxide layers 121a, 121c having a high refractive index, and then the second oxide layers 122a, 122b having a low refractive index are formed on the first oxide layers 121a, 121c, and finally formed on the second oxide layers 122a, 122b. Another first oxide layer 121b, 121d having a high refractive index. The first oxide layers 121a, 121c and the other first oxide layers 121b, 121d may have a refractive index of 2.2 to 2.9, a thickness of 110 to 140 nm, and a refractive index of the second oxide layer 122a, 122b of 1.4. To 1.5, the thickness can range from 150 to 180 nm. The material of the first oxide layer is, for example, titanium dioxide. The material of the second oxide layer is, for example, cerium oxide. The manner in which the first oxide multilayer film 120 and the second oxide multilayer film 140 are formed on the first surface 101 and the second surface 102 of the first substrate 100 may be via a spray coating, dip coating method (Dip-Coating) commonly used in the industry or It is produced by a wet spin coating method (Spin-Coating).
圖3繪示各種厚度的第一氧化物多層膜及第二氧化物多層膜的反射圖譜。3 is a reflection spectrum of a first oxide multilayer film and a second oxide multilayer film of various thicknesses.
請參照圖1與3，在一示範實施例中，第一氧化物多層膜 120及第二氧化物多層膜140分別包括110奈米的氧化鈦層/150奈米的氧化矽層/110奈米的氧化鈦層，其反射率曲線為50。在又一示範實施例中，第一氧化物多層膜120及第二氧化物多層膜140分別包括120奈米的氧化鈦層/160奈米的氧化矽層/120奈米的氧化鈦層，其反射率曲線為52。在另一示範實施例中，第一氧化物多層膜120及第二氧化物多層膜140分別包括130奈米的氧化鈦層/170奈米的氧化矽層/130奈米的氧化鈦層，其反射率曲線為54。在其他示範實施例中，第一氧化物多層膜120及第二氧化物多層膜140分別包括140奈米的氧化鈦層/180奈米的氧化矽層/140奈米的氧化鈦層，其反射率曲線為56。Referring to Figures 1 and 3, in an exemplary embodiment, a first oxide multilayer film The 120 and second oxide multilayer films 140 respectively include a 110 nm titanium oxide layer/150 nm yttria layer/110 nm titanium oxide layer having a reflectance curve of 50. In still another exemplary embodiment, the first oxide multilayer film 120 and the second oxide multilayer film 140 respectively include a 120 nm titanium oxide layer/160 nm yttria layer/120 nm titanium oxide layer, which The reflectance curve is 52. In another exemplary embodiment, the first oxide multilayer film 120 and the second oxide multilayer film 140 respectively include a 130 nm titanium oxide layer/170 nm yttria layer/130 nm titanium oxide layer, which The reflectance curve is 54. In other exemplary embodiments, the first oxide multilayer film 120 and the second oxide multilayer film 140 respectively include a 140 nm titanium oxide layer/180 nm yttria layer/140 nm titanium oxide layer, and the reflection thereof The rate curve is 56.
由圖3的結果顯示，第一氧化物多層膜120及第二氧化物多層膜140的設置可調整光線在可見光區的反射特性。由於可見光區的熱能佔太陽光譜的45%，因此，藉由調整可見光區的反射，可以減少熱能穿透。然而，若是反射太高，反而會造成視覺上的不舒服。本揭露實施例之節能玻璃可藉由第一氧化物多層膜120及第二氧化物多層膜140使可見光區的反射率小於25%。The results of FIG. 3 show that the arrangement of the first oxide multilayer film 120 and the second oxide multilayer film 140 can adjust the reflection characteristics of light in the visible light region. Since the heat energy in the visible light region accounts for 45% of the solar spectrum, thermal energy penetration can be reduced by adjusting the reflection in the visible light region. However, if the reflection is too high, it will cause visual discomfort. The energy-saving glass of the embodiment can make the reflectance of the visible light region less than 25% by the first oxide multilayer film 120 and the second oxide multilayer film 140.
在一實施例中，上述節能玻璃的第一基板100設置在較接近室外側；而第二基板200設置在較接近室內側。換言之，光線自第一基板100第一表面101上的第一氧化物多層膜120入射，經由第一基板100後，光線再通過第二氧化物多層膜140，藉由布拉格反射鏡膜原理，調整可見光區的反射，以減少熱能穿透。當光線繼續行進，隔熱結構240阻擋紫外線並隔絕91%以上的紅外線，而讓大部分的可見光穿透。最後於光線通過紅外線反射層220時，紅外線反射層220可反射紅外線。經由實驗結果顯示，本揭 露的節能玻璃的遮蔽係數低(SC小於0.41)且透光性佳。In an embodiment, the first substrate 100 of the energy-saving glass is disposed closer to the outdoor side; and the second substrate 200 is disposed closer to the indoor side. In other words, light is incident from the first oxide multilayer film 120 on the first surface 101 of the first substrate 100. After passing through the first substrate 100, the light passes through the second oxide multilayer film 140, and is adjusted by the principle of the Bragg mirror film. Reflection in the visible region to reduce thermal energy penetration. As the light continues to travel, the thermal barrier 240 blocks the ultraviolet light and isolates more than 91% of the infrared light, allowing most of the visible light to penetrate. Finally, when the light passes through the infrared reflecting layer 220, the infrared reflecting layer 220 can reflect infrared rays. Through the experimental results, this disclosure The exposed energy-saving glass has a low shielding coefficient (SC less than 0.41) and good light transmission.
圖4為依照本揭露實施例2所繪示的另一種節能玻璃的剖面示意圖。4 is a cross-sectional view of another energy-saving glass according to Embodiment 2 of the present disclosure.
請參照圖4，本實施例之節能玻璃20與上述節能玻璃10相似，除同樣包括第一基板100、第一氧化物多層膜120、第二氧化物多層膜140、第一結合層180、第二基板200與紅外線反射層220之外，隔熱結構240為隔熱紙280與第二結合層260。隔熱紙280的材料可以是PET，例如是市售的3M M70、V-kool V70或V-kool J60。第二結合層260的材料可包括聚乙烯醇縮丁醛、乙烯醋酸乙烯酯或其組合。隔熱紙280可藉由第二結合層260直接貼覆於第二基板200上。Referring to FIG. 4, the energy-saving glass 20 of the present embodiment is similar to the energy-saving glass 10 described above, except that the first substrate 100, the first oxide multilayer film 120, the second oxide multilayer film 140, the first bonding layer 180, and the first layer are also included. The heat insulating structure 240 is the heat insulating paper 280 and the second bonding layer 260, in addition to the second substrate 200 and the infrared reflecting layer 220. The material of the thermal insulation paper 280 may be PET, such as commercially available 3M M70, V-kool V70 or V-kool J60. The material of the second bonding layer 260 may include polyvinyl butyral, ethylene vinyl acetate, or a combination thereof. The heat insulating paper 280 can be directly attached to the second substrate 200 by the second bonding layer 260.
圖5為依照本揭露實施例3所繪示的一種節能玻璃的剖面示意圖。FIG. 5 is a cross-sectional view of an energy-saving glass according to Embodiment 3 of the present disclosure.
請參照圖5，本實施例之節能玻璃30與上述節能玻璃10相似。節能玻璃30除包括第一基板100、第一氧化物多層膜120、第二氧化物多層膜140、第一結合層180、第二基板200、隔熱結構240與紅外線反射層220之外，還包括光學調整層160。更具體地說，本實施例還可以在第一基板100的第一表面101的最外側設置光學調整層160，亦即設置在第一氧化物多層膜120的表面上。換言之，第一氧化物多層膜120位於光學調整層160與第一基板100之間。光學調整層160可用以降低可見光反射率，提升可見光穿透率，同時當作保護層。光學調整層160的材料可包括二氧化矽(SiO2 )、氟化鎂(MgF2 )、氧化鋁(Al2 O3 )或其組合。光學調整層160的厚度例如是0.1~0.2微米。光學調整層160可以 在第一氧化物多層膜120與第二氧化物多層膜140形成之後，利用噴塗、浸塗法(Dip-Coating)或濕式旋塗法(Spin-Coating)的方式，形成在第一氧化物多層膜120上。Referring to FIG. 5, the energy-saving glass 30 of the present embodiment is similar to the energy-saving glass 10 described above. The energy-saving glass 30 includes, in addition to the first substrate 100, the first oxide multilayer film 120, the second oxide multilayer film 140, the first bonding layer 180, the second substrate 200, the heat insulating structure 240, and the infrared reflecting layer 220, An optical adjustment layer 160 is included. More specifically, the present embodiment can also provide an optical adjustment layer 160 on the outermost side of the first surface 101 of the first substrate 100, that is, on the surface of the first oxide multilayer film 120. In other words, the first oxide multilayer film 120 is located between the optical adjustment layer 160 and the first substrate 100. The optical adjustment layer 160 can be used to reduce the visible light reflectance and enhance the visible light transmittance while serving as a protective layer. The material of the optical adjustment layer 160 may include cerium oxide (SiO 2 ), magnesium fluoride (MgF 2 ), aluminum oxide (Al 2 O 3 ), or a combination thereof. The thickness of the optical adjustment layer 160 is, for example, 0.1 to 0.2 μm. The optical adjustment layer 160 may be formed by spraying, dip-coating or spin-coating after the first oxide multilayer film 120 and the second oxide multilayer film 140 are formed. On the first oxide multilayer film 120.
實例1Example 1
實例1的節能玻璃結構如上述實施例1與圖1。第一氧化物多層膜120、第一基板100、第二氧化物多層膜140、第一結合層180、隔熱結構240、第二基板200及紅外線反射層220依序為氧化鈦(110nm)/氧化矽(150nm)/氧化鈦(110nm)/玻璃基板/氧化鈦(110nm)/氧化矽(150nm)/氧化鈦(110nm)/PVB/氧化鎢(40μm)/玻璃基板/氟摻雜氧化錫(800nm)。此節能玻璃的測試結果如表1所示。表1中遮蔽係數是指在相同環境下，節能玻璃的太陽因子與3毫米透明玻璃的太陽因子的比值。The energy-saving glass structure of Example 1 is as in the above-described Embodiment 1 and FIG. The first oxide multilayer film 120, the first substrate 100, the second oxide multilayer film 140, the first bonding layer 180, the heat insulating structure 240, the second substrate 200, and the infrared reflecting layer 220 are sequentially titanium oxide (110 nm)/ Cerium oxide (150 nm) / titanium oxide (110 nm) / glass substrate / titanium oxide (110 nm) / cerium oxide (150 nm) / titanium oxide (110 nm) / PVB / tungsten oxide (40 μm) / glass substrate / fluorine doped tin oxide ( 800nm). The test results of this energy-saving glass are shown in Table 1. The shielding factor in Table 1 refers to the ratio of the solar factor of the energy-saving glass to the solar factor of the 3 mm transparent glass under the same environment.
比較例1Comparative example 1
比較例1的節能玻璃結構與實例1以及圖1者相似，惟將做為紅外線反射層220的氟摻雜氧化錫設置位置更改在隔熱結構240與第二基板200的第一表面201之間，即，其結構為氧化鈦/氧化矽/氧化鈦/玻璃基板/氧化鈦/氧化矽/氧化鈦/PVB/氧化鎢/氟摻雜氧化錫/玻璃基板，此節能玻璃的穿透率、反射率、放射率以及遮蔽係數等測試結果如表1所示。The energy-saving glass structure of Comparative Example 1 is similar to that of Example 1 and FIG. 1, except that the position of the fluorine-doped tin oxide disposed as the infrared-ray reflective layer 220 is changed between the heat-insulating structure 240 and the first surface 201 of the second substrate 200. , that is, its structure is titanium oxide / cerium oxide / titanium oxide / glass substrate / titanium oxide / cerium oxide / titanium oxide / PVB / tungsten oxide / fluorine doped tin oxide / glass substrate, the penetration rate, reflection of this energy-saving glass The test results of rate, emissivity and shading coefficient are shown in Table 1.
比較例2Comparative example 2
比較例2的節能玻璃結構與實例1以及圖1者相似，惟省略第二氧化物多層膜140，即，其結構為氧化鈦/氧化矽/氧化鈦/玻璃基板/PVB/氧化鎢/玻璃基板/氟摻雜氧化錫。此節能玻璃的測試結果如表1所示。The energy-saving glass structure of Comparative Example 2 is similar to that of Example 1 and FIG. 1, except that the second oxide multilayer film 140 is omitted, that is, the structure is titanium oxide/yttria/titanium oxide/glass substrate/PVB/tungsten oxide/glass substrate. / fluorine doped tin oxide. The test results of this energy-saving glass are shown in Table 1.
比較例3Comparative example 3
比較例3的節能玻璃結構與實例1以及圖1者相似，惟將做為紅外線反射層220的氟摻雜氧化錫的設置位置更改在隔熱結構240與第二基板200的第一表面201之間，且省略第二氧化物多層膜140，即，其結構為氧化鈦/氧化矽/氧化鈦/玻璃基板/PVB/氧化鎢/氟摻雜氧化錫/玻璃基板。此節能玻璃的測試結果如表1所示。The energy-saving glass structure of Comparative Example 3 is similar to that of Example 1 and FIG. 1, except that the position of the fluorine-doped tin oxide as the infrared reflective layer 220 is changed to the first surface 201 of the heat insulating structure 240 and the second substrate 200. The second oxide multilayer film 140 is omitted, that is, the structure thereof is a titanium oxide/yttria/titanium oxide/glass substrate/PVB/tungsten oxide/fluorine-doped tin oxide/glass substrate. The test results of this energy-saving glass are shown in Table 1.
實例2Example 2
實例2的節能玻璃結構如節能玻璃結構與實例1以及圖1者相似，其結構為氧化鈦/氧化矽/氧化鈦/玻璃基板/氧化鈦/氧化矽/氧化鈦/PVB/氧化鎢/玻璃基板/氟鋰共摻雜氧化錫。此節能玻璃的測試結果如表1所示。The energy-saving glass structure of Example 2, such as the energy-saving glass structure, is similar to that of Example 1 and FIG. 1, and its structure is titanium oxide/yttria/titanium oxide/glass substrate/titanium oxide/yttria/titanium oxide/PVB/tungsten oxide/glass substrate. / Fluoride lithium co-doped tin oxide. The test results of this energy-saving glass are shown in Table 1.
實例3Example 3
實例3的節能玻璃結構如節能玻璃結構與實例1者相似，惟更設置光學調整層160於第一氧化物多層膜120的表面上，其結構可參考圖5，依序為光學調整層160、第一氧化物多層膜120、第一基板100、第二氧化物多層膜140、第一結合層180、隔熱結構240、第二基板200以及紅外線反射層220，材料依序為二氧化矽/氧化鈦/氧化矽/氧化鈦/玻璃基板/氧化鈦/氧化矽/氧化鈦/PVB/氧化鎢/玻璃基板/氟摻雜氧化錫。此節能玻璃的測試結果如表1所示。The energy-saving glass structure of the example 3 is similar to that of the first embodiment, but the optical adjustment layer 160 is further disposed on the surface of the first oxide multilayer film 120. The structure thereof can be referred to FIG. The first oxide multilayer film 120, the first substrate 100, the second oxide multilayer film 140, the first bonding layer 180, the heat insulating structure 240, the second substrate 200, and the infrared reflecting layer 220 are sequentially made of cerium oxide/ Titanium oxide / cerium oxide / titanium oxide / glass substrate / titanium oxide / cerium oxide / titanium oxide / PVB / tungsten oxide / glass substrate / fluorine doped tin oxide. The test results of this energy-saving glass are shown in Table 1.
表1為光線由靠近第一基板的第一表面入射實例1至3及比較例1至3的節能玻璃，所得到之測量結果。由表1的結果顯示，相較於比較例1(將紅外線反射層設置在第一基板與第二基板之間)，實例1將紅外線反射層設置在第二基板的第二表面上(室內側)，其遮蔽係數較低，表示通過節能玻璃的熱量較低，對太陽能具有較佳的遮蔽效果。相較於比較例2(省略第二氧化物多層膜)，同時具有第一氧化物多層膜與第二氧化物多層膜的實例1的遮蔽係數較低。相較於比較例3(將紅外線反射層設置在第一基板與第二基板之間，且省略第二氧化物多層膜)，實例1的遮蔽係數較低。相較於實例1，將氟摻雜氧化錫(F：SnO2 )改變為氟鋰共摻雜氧化錫(Li-F：SnO2 )的實例2具有更低的遮蔽係數。相較於實例1，設置光學調整層的實例3具有更低的遮蔽係數。Table 1 shows the measurement results obtained by injecting the energy-saving glass of Examples 1 to 3 and Comparative Examples 1 to 3 from the first surface close to the first substrate. From the results of Table 1, it is shown that Example 1 has an infrared reflecting layer disposed on the second surface of the second substrate as compared with Comparative Example 1 (the infrared reflecting layer is disposed between the first substrate and the second substrate) (indoor side) ), the shielding coefficient is low, indicating that the heat passing through the energy-saving glass is low, and the solar energy has a better shielding effect. The masking factor of Example 1 having both the first oxide multilayer film and the second oxide multilayer film was lower than that of Comparative Example 2 (omitting the second oxide multilayer film). The masking factor of Example 1 was lower than that of Comparative Example 3 (the infrared reflecting layer was disposed between the first substrate and the second substrate, and the second oxide multilayer film was omitted). Example 2, which changed fluorine-doped tin oxide (F:SnO 2 ) to fluorolithium co-doped tin oxide (Li-F:SnO 2 ), had a lower masking factor than Example 1. Example 3, which sets the optical adjustment layer, has a lower shading coefficient than Example 1.
從實例1~3的結果顯示，於第一基板的兩面對稱設置第一氧化物多層膜及第二氧化物多層膜，且將紅外線反射層設置在 第二基板的第二表面上的節能玻璃，具有阻擋紫外線並阻隔90%的紅外線(780~2500nm)，且能讓大部分的可見光(380~780nm)穿透，平均可見光穿透率約50%以上，且具有較小的遮蔽係數(0.41以下)，因此，可以有效阻擋輻射熱能進入室內。The results from the examples 1 to 3 show that the first oxide multilayer film and the second oxide multilayer film are symmetrically disposed on both sides of the first substrate, and the infrared reflective layer is disposed on The energy-saving glass on the second surface of the second substrate has ultraviolet rays blocking and blocking 90% of infrared rays (780~2500 nm), and can penetrate most of visible light (380-780 nm), and the average visible light transmittance is about 50%. Above, and with a small shielding factor (0.41 or less), it is effective to block radiant heat energy from entering the room.
本揭露的節能玻璃裝置在基板的兩面設置氧化物多層膜，可調整可見光區的反射特性。由於可見光區的熱能佔太陽光譜的45%，因此，可以藉由調整可見光區的反射減少熱能穿透。本揭露實施例設置高低折射率的氧化物疊層，可藉由氧化物布拉格反射鏡原理，使得可見光區反射小於25%。The energy-saving glass device of the present invention is provided with an oxide multilayer film on both surfaces of the substrate to adjust the reflection characteristics in the visible light region. Since the heat energy in the visible light region accounts for 45% of the solar spectrum, thermal energy penetration can be reduced by adjusting the reflection in the visible light region. The disclosed embodiments provide a high and low refractive index oxide stack which can reflect less than 25% of the visible light region by the principle of an oxide Bragg mirror.
本揭露的節能玻璃裝置在室內側的基板的表面設置紅外線反射層，可有效反射紅外線，減少紅外線進入室內，避免室內溫度提高。The energy-saving glass device of the present invention is provided with an infrared reflecting layer on the surface of the substrate on the indoor side, which can effectively reflect infrared rays and reduce infrared rays from entering the room to avoid an increase in indoor temperature.
本揭露實施例的節能玻璃裝置，還可以在兩片基板之間設置隔熱結構，以達到更佳的隔熱效果。隔熱結構不僅限於隔熱紙，也可以是隔熱層。當隔熱結構為隔熱層時，相較於隔熱紙的製作更為簡易便利，可大量減少製作工序，故可以大幅減輕本創作於隔熱、節能功能上的製作成本，有效提升本創作的產業競爭力。In the energy-saving glass device of the embodiment, the heat insulating structure can be disposed between the two substrates to achieve better heat insulation effect. The heat insulating structure is not limited to heat insulating paper, but may be a heat insulating layer. When the heat insulation structure is a heat insulation layer, it is easier and more convenient to manufacture than the heat insulation paper, and the production process can be greatly reduced, so that the production cost of the heat insulation and energy saving functions can be greatly reduced, and the creation is effectively improved. Industrial competitiveness.
雖然本新型創作已以實施例揭露如上，然其並非用以限定本新型創作，任何所屬技術領域中具有通常知識者，在不脫離本新型創作的精神和範圍內，當可作些許的更動與潤飾，故本新型創作的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the novel creation, and any person skilled in the art can make some changes without departing from the spirit and scope of the novel creation. Retouching, the scope of protection of this new creation is subject to the definition of the scope of the patent application attached.
10‧‧‧節能玻璃10‧‧‧Energy-saving glass
100‧‧‧第一基板100‧‧‧First substrate
101‧‧‧第一基板的第一表面101‧‧‧ First surface of the first substrate
102‧‧‧第一基板的第二表面102‧‧‧Second surface of the first substrate
120‧‧‧第一氧化物多層膜120‧‧‧First oxide multilayer film
140‧‧‧第二氧化物多層膜140‧‧‧Second oxide multilayer film
180‧‧‧第一結合層180‧‧‧First bonding layer
200‧‧‧第二基板200‧‧‧second substrate
201‧‧‧第二基板的第一表面201‧‧‧ First surface of the second substrate
202‧‧‧第二基板的第二表面202‧‧‧Second surface of the second substrate
220‧‧‧紅外線反射層220‧‧‧Infrared reflective layer
240‧‧‧隔熱結構240‧‧‧Insulation structure
Claims (20)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW103218997U TWM498197U (en) | 2014-10-27 | 2014-10-27 | Energy-saving glass |
| CN201420744137.3U CN204566817U (en) | 2014-10-27 | 2014-12-02 | Energy-saving glass and substrate structure for energy-saving glass |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW103218997U TWM498197U (en) | 2014-10-27 | 2014-10-27 | Energy-saving glass |
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| TWM498197U true TWM498197U (en) | 2015-04-01 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105235321A (en) * | 2015-08-14 | 2016-01-13 | 芜湖真空科技有限公司 | LOW-E glass and preparation method therefor |
| TWI585289B (en) * | 2015-09-15 | 2017-06-01 | 姜玉桂 | Structure of multilayer heat insulation window |
| TWI610804B (en) * | 2016-05-23 | 2018-01-11 | 國立成功大學 | Energy-saving Glass and Method of Manufacturing the Same |
-
2014
- 2014-10-27 TW TW103218997U patent/TWM498197U/en not_active IP Right Cessation
- 2014-12-02 CN CN201420744137.3U patent/CN204566817U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105235321A (en) * | 2015-08-14 | 2016-01-13 | 芜湖真空科技有限公司 | LOW-E glass and preparation method therefor |
| TWI585289B (en) * | 2015-09-15 | 2017-06-01 | 姜玉桂 | Structure of multilayer heat insulation window |
| TWI610804B (en) * | 2016-05-23 | 2018-01-11 | 國立成功大學 | Energy-saving Glass and Method of Manufacturing the Same |
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| Publication number | Publication date |
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| CN204566817U (en) | 2015-08-19 |
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