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TWI908386B - Semiconductor circuit structure with direct die heat removal structure - Google Patents

Semiconductor circuit structure with direct die heat removal structure

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Publication number
TWI908386B
TWI908386B TW113138511A TW113138511A TWI908386B TW I908386 B TWI908386 B TW I908386B TW 113138511 A TW113138511 A TW 113138511A TW 113138511 A TW113138511 A TW 113138511A TW I908386 B TWI908386 B TW I908386B
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TW
Taiwan
Prior art keywords
heat dissipation
shallow groove
groove isolation
circuit structure
semiconductor circuit
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Application number
TW113138511A
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Chinese (zh)
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TW202516731A (en
Inventor
盧超群
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日日新半導體架構股份有限公司
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Priority claimed from US18/662,141 external-priority patent/US20250006584A1/en
Application filed by 日日新半導體架構股份有限公司 filed Critical 日日新半導體架構股份有限公司
Publication of TW202516731A publication Critical patent/TW202516731A/en
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Publication of TWI908386B publication Critical patent/TWI908386B/en

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Abstract

A semiconductor circuit structure. The semiconductor circuit structure includes a semiconductor substrate with an original semiconductor surface; a set of active regions within the semiconductor substrate; and a first shallow trench isolation (STI) region neighboring to the set of active regions and extending along a first direction. Wherein the first STI region includes a heat removing layer, and the material of the heat removing layer is different from SiO2.

Description

具有直接晶粒排熱結構的半導體電路結構Semiconductor circuit structure with direct grain heat dissipation

本揭露書是有關於一種半導體結構,特別是有關於一種具有直接晶粒排熱結構的半導體電路結構。This disclosure relates to a semiconductor structure, and more particularly to a semiconductor circuit structure having a direct grain heat dissipation structure.

矽晶片的單晶片整合能力已經從巨大規模積體電路(Giga Scale Integration (GSI):單一晶片(粒)上超過數十億個電晶體)發展到兆級規模積體電路(Tera Scale Integration (TSI):單一晶片(粒)上超過兆個電晶體),而運作如此大量的電晶體會導致電力消耗急劇增加。受限於現有技術有限的散熱能力,所增加的功耗會不利地提高電晶體的接面溫度(junction temperature),從而提高整個晶片(粒)的溫度。由於二氧化矽的導熱係數很低,矽本身的導熱係數也不是很高。這種材料和元件的結構問題會導致負循環效應(negative cyclic effect),意即:晶片(粒)溫度的升高會減慢電晶體的速度。然後不可避免地增強設計以提高電路的功率,以加速電晶體的效能,但這種機制會使晶片(粒)溫度急遽升高,導致散熱問題變得更嚴重。這種散熱不足導致晶片(粒)操作溫度升高的問題是整個晶片產業急需要解決的最嚴重的問題之一,是要更多元件整合至晶片(粒)時所要避免的主要障礙。然而,降低巨大規模積體電路(GSI)晶片溫度的進展並沒有得到應有的改善。Silicon wafer integration capabilities have evolved from gigascale integration (GSI: billions of transistors on a single chip) to terascale integration (TSI: trillions of transistors on a single chip). Operating such a large number of transistors leads to a dramatic increase in power consumption. Limited by current technology's heat dissipation capabilities, the increased power consumption adversely raises the transistor junction temperature, thereby increasing the overall chip temperature. Furthermore, silicon dioxide has a very low thermal conductivity, and silicon itself is not particularly thermally conductive. This material and component structural issue results in a negative cyclic effect, meaning that the increase in chip temperature slows down the transistor operation. Then, inevitably, designs are enhanced to increase circuit power and accelerate transistor performance, but this mechanism causes a sharp rise in chip temperature, exacerbating heat dissipation problems. This problem of insufficient heat dissipation leading to elevated chip operating temperatures is one of the most critical issues that the entire chip industry urgently needs to address, and a major obstacle to avoid when integrating more components onto the chip. However, progress in reducing the temperature of massive scalability integrated circuit (GSI) chips has not been as good as it should be.

實際上,隨著製程技術節點(technology node)進一步的微縮,電晶體尺寸必定變得更小(例如,最小特徵尺寸(minimum feature size)從 7nm 縮小到 5nm,再縮小到 3nm 等等),氧化物覆蓋率佔總電晶體的百分比尺寸也越來越大,導致通過元件接面散熱的能力進一步聚集。雖然業界以創造出很多散熱方法,例如在晶片(粒)外部用較高的散熱墊覆蓋整個晶片,或者在封裝晶片外部使用液冷循環等,但這些方法的成本都很高,但有效降低電晶體接面溫度的回報效率卻很低。In reality, as process technology nodes continue to shrink, transistor sizes inevitably become smaller (for example, the minimum feature size shrinks from 7nm to 5nm, then to 3nm, and so on). The percentage of the total transistor size covered by oxides also increases, leading to a further concentration of heat dissipation capabilities through the device junctions. Although the industry has created many heat dissipation methods, such as covering the entire chip with a taller thermal pad or using liquid cooling circulation outside the packaged chip, these methods are very expensive, but their return on investment in effectively reducing transistor junction temperatures is very low.

本發明聚焦在製造電晶體的單晶粒製程(monolithic processes)中,在半導體晶粒中特別創建出一種排熱(heat remover,HR)結構。這種排熱結構有點像是一種連接在晶粒上使整體成為單一構件(single piece),以盡可能地擴大散熱面積。此外,這種排熱結構可以連接到晶粒的整體邊緣,以便可以更輕鬆地連接到半導體晶粒外部的某些散熱器,從而為晶粒創造出更大的散熱路徑,以連接到晶粒的外部環境,從而連接到封裝晶片上。這種新型的排熱結構被認為是能與單一電晶體整直接合,以實現非常有效散熱功能的最接近路徑。而且,所有這些排熱結構可以連接在一起並跨越整個晶粒,作為內建於晶粒中優化散熱網絡的一部分。This invention focuses on creating a heat remover (HR) structure within the semiconductor die during monolithic processes of transistor manufacturing. This HR structure acts as a single-piece component attached to the die, maximizing the heat dissipation area. Furthermore, this HR structure can be connected to the entire edge of the die, allowing for easier connection to external heatsinks and creating a larger heat dissipation path to the external environment and ultimately to the packaged chip. This novel HR structure is considered the closest approach to achieving highly efficient heat dissipation when integrated with a single transistor. Moreover, all these heat dissipation structures can be connected together and span the entire grain as part of an optimized heat dissipation network built into the grain.

本發明的實施例提供一種半導體電路結構。此半導體電路結構包括具有原始半導體表面(original semiconductor surface,OSS)的半導體基材、位於半導體基材中的一組主動區、以及與此組主動區相鄰並且沿著第一方向延伸的第一淺溝隔離區(STI)。其中,第一淺溝隔離區包括一個排熱層,且排熱層的材料不同於二氧化矽(SiO2)。Embodiments of the present invention provide a semiconductor circuit structure. This semiconductor circuit structure includes a semiconductor substrate having an original semiconductor surface (OSS), a set of active regions located within the semiconductor substrate, and a first shallow groove isolation region (STI) adjacent to the set of active regions and extending along a first direction. The first shallow groove isolation region includes a heat dissipation layer, and the material of the heat dissipation layer is different from silicon dioxide ( SiO2 ).

根據本說明書的一個面向,排熱層的導熱率高於二氧化矽。According to one aspect of this manual, the thermal conductivity of the heat dissipation layer is higher than that of silicon dioxide.

根據本說明書的一個面向,排熱層在半導體電路結構的操作期間是一種電性絕緣體。According to one aspect of this specification, the heat dissipation layer is an electrical insulator during the operation of the semiconductor circuit structure.

根據本說明書的一個面向,排熱層延伸進入此組主動區之一者中。According to one aspect of this manual, the heat dissipation layer extends into one of the active zones of this assembly.

根據本說明書的一個面向,排熱層包括金屬層和絕緣薄層,絕緣薄層位於金屬層和此組主動區之間。According to one aspect of this specification, the heat dissipation layer comprises a metal layer and an insulating thin layer, which is located between the metal layer and this set of active regions.

根據本說明書的一個面向,排熱層包括一種複合材料。According to one aspect of this specification, the heat dissipation layer comprises a composite material.

根據本說明書的一個面向,第一淺溝隔離區更包括位於排熱層下方的二氧化矽層。According to one aspect of this specification, the first shallow groove isolation zone further includes a silicon dioxide layer located below the heat dissipation layer.

根據本說明書的一個面向,排熱層位於半導體電路結構的前端製程(front end of line,FEOL)區內。According to one aspect of this specification, the heat dissipation layer is located within the front end of line (FEOL) region of the semiconductor circuit structure.

根據本說明書的一個面向,第一淺溝隔離區圍繞此組主動區。According to one aspect of this instruction manual, the first shallow groove isolation zone surrounds this group of active zones.

根據本說明書的一個面向,排熱層位於第一淺溝隔離區中,且位於原始半導體表面下方,且排熱層圍繞此組主動區。According to one aspect of this specification, the heat dissipation layer is located in the first shallow groove isolation region and below the original semiconductor surface, and the heat dissipation layer surrounds this set of active regions.

根據本說明書的一個面向,更包括一個備用淺溝隔離區(spare STI region),連接至第一淺溝隔離區,且排熱層沿著第一方向延伸至備用淺溝隔離區。According to one aspect of this instruction manual, a spare shallow groove isolation region is also included, which is connected to the first shallow groove isolation region, and the heat dissipation layer extends into the spare shallow groove isolation region along the first direction.

根據本說明書的一個面向,備用淺溝隔離區靠近半導體基材的中心,或靠近半導體基材的邊緣部分。According to one aspect of this specification, the alternative shallow groove isolation region is located near the center of the semiconductor substrate or near the edge of the semiconductor substrate.

根據本說明書的一個面向,更包括一個排熱銲墊位於備用淺溝隔離區內,且排熱層連接至排熱銲墊。According to one aspect of this instruction manual, a heat dissipation pad is located within the spare shallow groove isolation area, and the heat dissipation layer is connected to the heat dissipation pad.

根據本說明書的一個面向,包括一個熱通孔插塞(thermal via)位於備用淺溝隔離區上方,並連接至備用淺溝隔離區內的排熱銲墊。According to one aspect of this specification, a thermal via is located above the spare shallow groove isolation area and connected to a heat dissipation solder pad within the spare shallow groove isolation area.

根據本說明書的一個面向,更包括一個散熱板(heat dissipation plate)位於熱通孔插塞上方,並連接至熱通孔插塞。According to one aspect of this manual, a heat dissipation plate is also included, located above the heat port plug and connected to the heat port plug.

根據本說明書的一個面向,更包括多個絕緣體位於此組主動區​​上方,其中熱通孔插塞穿透多個絕緣體並連接至位於備用淺溝隔離區中的排熱銲墊。According to one aspect of this instruction manual, multiple insulators are located above this active area, with heat-perforated plugs penetrating the multiple insulators and connecting to heat-dissipating solder pads located in the backup shallow groove isolation area.

根據本說明書的一個面向,多個絕緣體和熱通孔插塞位於半導體電路結構的後端製程(back end of line,BEOL)區內。According to one aspect of this specification, multiple insulators and thermal via plugs are located within the back end of line (BEOL) region of the semiconductor circuit structure.

根據本說明書的一個面向,更包括一個半導體通孔插塞(through semiconductor via,TSV)從半導體基材的背側表面延伸至位於備用淺溝隔離區中的排熱銲墊的底表面,其中背側表面與原始半導體表面分別位於相反二側。According to one aspect of this specification, a through semiconductor via (TSV) extends from the back surface of the semiconductor substrate to the bottom surface of the heat dissipation pad located in the standby shallow groove isolation area, wherein the back surface and the original semiconductor surface are located on opposite sides.

根據本說明書的一個面向,散熱板位於半導體基材的背側表面下方並連接至半導體通孔插塞。According to one aspect of this specification, the heatsink is located below the back surface of the semiconductor substrate and connected to the semiconductor via plug.

根據本說明書的一個面向,第一淺溝隔離區圍繞此組主動區之一者的四個側壁。According to one aspect of this instruction manual, the first shallow groove isolation zone surrounds the four side walls of one of the active zones in this group.

本發明的另一個實施例提供一種半導體電路結構,包括具有原始半導體表面的半導體基材、形成於半導體基材內的一組電晶體、鄰近此組電晶體並沿第一方向延伸至半導體基材邊緣部分的複合材料淺溝隔離區。其中,複合材料淺溝隔離區位於半導體電路結構的前端製程(front end of line,FEOL)區內。Another embodiment of the present invention provides a semiconductor circuit structure, including a semiconductor substrate having a raw semiconductor surface, a group of transistors formed within the semiconductor substrate, and a composite material shallow groove isolation region adjacent to the group of transistors and extending along a first direction to the edge portion of the semiconductor substrate. The composite material shallow groove isolation region is located within the front end of line (FEOL) region of the semiconductor circuit structure.

根據本說明書的一個面向,複合材料淺溝隔離區包括一排熱層,與此組電晶體相鄰,並沿著第一方向延伸至半導體基材的邊緣部分。According to one aspect of this specification, the composite shallow groove isolation region includes a row of thermal layers adjacent to the group of transistors and extending along a first direction to the edge portion of the semiconductor substrate.

根據本說明書的一個面向,排熱層上方或下方設有熱通孔插塞,其中熱通孔插塞連接至排熱層。According to one aspect of this specification, a heat dissipation hole plug is provided above or below the heat dissipation layer, wherein the heat dissipation hole plug is connected to the heat dissipation layer.

根據本說明書的一個面向,散熱板位於半導體基材的上方或下方,其中半導體基材連接至熱通孔插塞。According to one aspect of this specification, the heatsink is located above or below the semiconductor substrate, wherein the semiconductor substrate is connected to the thermal via plug.

根據本說明書的一個面向,熱通孔插塞位於半導體電路結構的後端製程區內。According to one aspect of this specification, the thermal via plug is located in the back-end process area of the semiconductor circuit structure.

本發明的又一實施例提供一種半導體電路結構,包括具有原始半導體表面的半導體基材、位於半導體基材中並沿著第一方向延伸的第一組主動區;位於半導體基材中,並沿著第一方向延伸的第二組主動區、位於第一組主動區與第二組主動區之間的第一淺溝隔離區,第一淺溝隔離區沿著第一方向延伸;其中,第一淺溝隔離區包括沿著第一方向延伸的排熱層,且排熱層的導熱率高於二氧化矽的導熱率。Another embodiment of the present invention provides a semiconductor circuit structure, including a semiconductor substrate having a raw semiconductor surface, a first set of active regions located in the semiconductor substrate and extending along a first direction, a second set of active regions located in the semiconductor substrate and extending along the first direction, and a first shallow groove isolation region located between the first set of active regions and the second set of active regions, the first shallow groove isolation region extending along the first direction; wherein the first shallow groove isolation region includes a heat dissipation layer extending along the first direction, and the thermal conductivity of the heat dissipation layer is higher than that of silicon dioxide.

根據本說明書的一個面向,此半導體電路結構還包括遠離第一組主動區和第二組主動區的備用淺溝隔離區,此備用淺溝隔離區接到第一淺溝隔離區,並且包括位於備用淺溝隔離區中的一個排熱銲墊,其中排熱層連接至排熱銲墊。According to one aspect of this specification, this semiconductor circuit structure also includes a backup shallow groove isolation region located away from the first set of active regions and the second set of active regions. This backup shallow groove isolation region is connected to the first shallow groove isolation region and includes a heat dissipation pad located in the backup shallow groove isolation region, wherein the heat dissipation layer is connected to the heat dissipation pad.

根據本說明書的一個面向,排熱銲墊的寬度大於排熱層的寬度。According to one aspect of this manual, the width of the heat dissipation pad is greater than the width of the heat dissipation layer.

藉由以下非限制性實施例的詳細描述,並參考以下所附圖式進行說明,將更能理本說明書上述和其他實施例。The above and other embodiments of this specification will be better understood through a detailed description of the following non-limiting embodiments and with reference to the accompanying diagrams.

以下將參考所附圖式更全面地描述各種實施例,其中圖式只是為了說明和解釋技術內容,並非用以限制本發明。為了清楚起見,圖式中的元件可能未按比例繪製。另外,有些圖式中可能省略一些元件和/或元件標號。 可以預期的是,一個實施例的元件和特徵可以被併入另一個實施例中,而無需進一步敘述。在下述用於製造半導體元件的方法中,所描述的步驟之間可以存在一個或多個附加的步驟,並且這些步驟的順序是可以變更的。在各個圖式中可以使用相同/相似的元件標號來指示相同/相似的元件。The various embodiments will be described more fully below with reference to the accompanying drawings, which are for illustrative and explanatory purposes only and are not intended to limit the invention. For clarity, the components in the drawings may not be drawn to scale. Additionally, some components and/or component designations may be omitted in some drawings. It is expected that the components and features of one embodiment can be incorporated into another embodiment without further description. In the methods for manufacturing semiconductor components described below, one or more additional steps may exist between the described steps, and the order of these steps can be varied. The same/similar component designations may be used in the various drawings to indicate the same/similar components.

如說明書和所申請專利範圍請求項中用於描述元件的序數詞,例如如「第一」、「第二」等,並不暗示或代表結構中的特定位置、或佈置的順序、或製造順序。序數詞僅用於清楚地區分具有相同名稱的多個組件。如說明書和所附申請專利範圍請求項中所使用的,空間關係術語,例如「上」、「上方」、「之上」、「上部」、「頂部」、「下」、「下方」、「之下」、「下部」、「底部」等,僅係用來描述圖式中一個或多個元件與另一元件之間的相對空間關係或位置關係,並且這些空間關係或位置關係,除非另有說明,可以是直接的還是間接的。除了圖式中描繪的方向之外,空間關係術語旨在涵蓋結構的不同方向。該結構可以倒置或旋轉各種角度,並且可以相應地解釋本說明書中使所用的各種空間關係的描述。Ordinal numbers used to describe elements in the specification and claims, such as "first," "second," etc., do not imply or represent a specific location in the structure, or the order of arrangement, or the order of manufacture. Ordinal numbers are used only to clearly distinguish multiple components with the same name. Spatial relation terms used in the specification and claims, such as "above," "above," "on top," "upper part," "top," "below," "below," "under," "lower part," "bottom," etc., are used only to describe the relative spatial or positional relationships between one or more elements in the drawing, and these spatial or positional relationships, unless otherwise stated, can be direct or indirect. Spatial relation terms are intended to cover different directions of the structure, in addition to the directions depicted in the drawing. The structure can be inverted or rotated at various angles, and can correspondingly explain the descriptions of various spatial relationships used in this manual.

另外,說明書和請求項中所使用的「電性連接」和「電性耦合」等術語,可以指元件之間的歐姆接觸、或者是指電流能通過所述元件、或者是指元件之間的操作關係。例如,所述操作關係可以是指以一個元件來驅動另一個元件,但電流可能不會直接在這兩個元件之間流動。Additionally, terms such as "electrical connection" and "electrical coupling" used in the specification and request can refer to ohmic contact between components, the passage of current through the components, or the operational relationship between components. For example, the operational relationship could mean that one component drives another component, but current may not flow directly between the two components.

在傳統半導體電路結構中,有許多電晶體或電路元件位於半導體基材中的主動區或主動區(active areas,AA)內,且有許多淺溝隔離區圍繞著這些主動區,如第1a圖所繪示。 第 1b圖係繪示第1a圖部分區域的結構俯視圖;第1c圖係繪示第1a圖的結構剖面示意圖。其中,在製造電晶體之前,主動區中的矽島會被氧化物層和氮化物層所覆蓋,這些氧化物層和氮化物層均沉積在半導體基材的原始半導體表面上方。淺溝隔離區從原始半導體表面向下延伸的深度通常為250奈米(nm)至300奈米,且淺溝隔離區的材料通常為二氧化矽,其熱導率相當低,為1.3至1.5 W/m×K。因此,淺溝隔離區可能會讓晶粒溫度提高,並且降低電晶體的速度。更糟的是,半導體基板中的淺溝隔離區可能佔據半導體基材總面積的40%或更多,而這些淺溝隔離區除了隔離目的之外沒有任何特殊功能。In traditional semiconductor circuit structures, numerous transistors or circuit components reside within active areas (AA) of the semiconductor substrate, surrounded by shallow groove isolation regions, as illustrated in Figure 1a. Figure 1b is a top view showing a portion of the structure in Figure 1a; Figure 1c is a cross-sectional view of the structure in Figure 1a. Prior to transistor fabrication, silicon islands in the active areas are covered by oxide and nitride layers, which are deposited above the original semiconductor surface of the semiconductor substrate. Shallow groove isolation regions typically extend downwards from the original semiconductor surface to a depth of 250 to 300 nanometers, and the material used is usually silicon dioxide, which has a relatively low thermal conductivity of 1.3 to 1.5 W/m×K. Therefore, shallow groove isolation regions can increase grain temperature and reduce transistor speed. Worse still, shallow groove isolation regions in semiconductor substrates can occupy 40% or more of the total semiconductor substrate area, and these shallow groove isolation regions have no special function other than isolation.

以下內容係根據本發明的實施例描述如何在基材或晶粒中製造排熱結構。請參考圖1。請參照第2a圖和第2b圖。首先,在原始半導體表面的頂部熱生長出墊氧化矽薄層101,然後在墊氧化矽薄層(thin pad-oxide layer)101上方沉積第一墊氮化矽層(pad-nitride-1 layer)102。使用微影蝕刻技術來定義出主動區103,其中電晶體的主體1031或鰭片結構係位於由第一墊氮化矽層102和墊氧化矽薄層101所構成的複合層下方。在主動區103的外側形成連接在晶粒內部的凹形溝槽區104(其深度t1,從原始半導體表面開始計算為250奈米至300奈米)。然後沉積厚矽氧化物層,並利用化學機械研磨 (Chemical-Mechanical-Polishing,CMP)技術製作淺溝隔離區201,使其頂面與第一墊氮化矽層102的頂面齊平(其中頂面俯視圖和結構剖面示意圖分別如第2a圖和第2b圖所繪示)。The following describes how a heat dissipation structure is fabricated in a substrate or grain according to embodiments of the present invention. Please refer to Figure 1. Please refer to Figures 2a and 2b. First, a thin pad-oxide layer 101 is thermally grown on top of the original semiconductor surface, and then a first pad-nitride layer 102 is deposited on top of the thin pad-oxide layer 101. An active region 103 is defined using a photolithography technique, wherein the transistor body 1031 or fin structure is located beneath the composite layer consisting of the first pad-nitride layer 102 and the thin pad-oxide layer 101. A concave groove region 104 (with a depth t1, calculated from the original semiconductor surface to be 250 nm to 300 nm) is formed on the outer side of the active region 103, connecting to the inside of the grain. Then, a thick silicon oxide layer is deposited, and a shallow groove isolation region 201 is fabricated using chemical-mechanical-polishing (CMP) technology, so that its top surface is flush with the top surface of the first pad silicon nitride layer 102 (wherein the top view and structural cross-sectional schematic diagram are shown in Figures 2a and 2b, respectively).

請參照第3a圖和第3b圖,沉積第二墊氮化矽層(pad-Nitride-2 layer)301,並利用微影光罩技術,在主動區103的中心留下一部分的第二墊氮化矽層301。其中,第3a圖和第3b圖係分別繪示該製程結構的俯視圖和剖面示意圖。之後,請參照第4a圖和第4b圖(第4a圖和第4b圖係分別繪示該製程結構的俯視圖和剖面示意圖),以蝕刻移除淺溝隔離區201中暴露於外的一部分矽氧化物至深度t2 (例如,深t2度為70奈米,或100奈米至150奈米);維持第二墊氮化矽層301和位於第二墊氮化矽層301下方的淺溝隔離區201中的矽氧化物不受影響。藉以使位於原始半導體表面下方的矽質側壁暴露出來。然後利用熱氧化製程,在這些側壁上生長出一層矽氧化物薄層401(例如,厚度約為1.5奈米至3奈米)。然後,沉積第三墊氮化矽層(pad-nitride-3 layer)403。使用非等向性蝕刻(anisotropic etching)技術蝕刻第三墊氮化矽層403,使其作為垂直側壁上的間隙壁。在適當有意的設計下,第二墊氮化矽層301雖然仍保留在平坦表面上,但由於製作第三墊氮化矽層403間隙壁所進行的非等向性蝕刻而使其變得更薄。Referring to Figures 3a and 3b, a second pad-nitrogen nitride layer 301 is deposited, and a portion of the second pad-nitrogen nitride layer 301 is left in the center of the active region 103 using photolithography. Figures 3a and 3b respectively show the top view and cross-sectional view of the fabrication structure. Next, referring to Figures 4a and 4b (Figures 4a and 4b respectively show a top view and a cross-sectional view of the fabrication structure), a portion of the exposed silicon oxide in the shallow groove isolation region 201 is etched away to a depth t2 (e.g., a depth t2 of 70 nm, or 100 nm to 150 nm); the silicon oxide in the second pad silicon nitride layer 301 and the shallow groove isolation region 201 located below the second pad silicon nitride layer 301 remains unaffected. This exposes the silicon sidewalls located below the original semiconductor surface. Then, using a thermal oxidation process, a thin silicon oxide layer 401 (e.g., approximately 1.5 nm to 3 nm thick) is grown on these sidewalls. Then, a third pad-nitride layer 403 is deposited. The third pad-nitride layer 403 is etched using anisotropic etching to serve as a gap wall on the vertical sidewalls. With proper intentional design, the second pad-nitride layer 301 remains on a flat surface, but is made thinner due to the anisotropic etching used to create the gap wall of the third pad-nitride layer 403.

請參照第5a圖和第5b圖,第5a圖和第5b圖係分別繪示該製程結構的俯視圖和剖面示意圖,使用非等向性蝕刻技術移除淺溝隔離區201中暴露於外的一部分矽氧化物層,蝕刻厚度t3約為8奈米,藉以形成平坦的矽氧化物表面,從暴露於外的矽氧化物表面頂部到原始半導體表面的距離為距離(t2+t3)約為78奈米。使用非等向性蝕刻技術移除暴露的矽氧化物薄層401,從而露出側壁上的矽。Please refer to Figures 5a and 5b, which are top and cross-sectional views of the fabrication structure, respectively. Anisotropic etching is used to remove a portion of the exposed silicon oxide layer in the shallow groove isolation region 201. The etching thickness t3 is approximately 8 nanometers, thereby forming a flat silicon oxide surface. The distance from the top of the exposed silicon oxide surface to the original semiconductor surface is approximately 78 nanometers (t2+t3). Anisotropic etching is then used to remove the exposed silicon oxide thin layer 401, thereby exposing the silicon on the sidewalls.

請參照第6a圖、第6b圖和第6c圖,其中第6a圖係繪示該製程結構的俯視圖;第6b圖係沿著第6a圖中的切線6b-6b’所繪示的結構剖面示意圖;第6c圖係沿著第6a圖中的切線6c-6c’所繪示的結構剖面示意圖。採用等向蝕刻技術移除一部分暴露在外的矽表面,較佳是可以調整晶格排列方向(1,1,0)上的蝕刻速率,使其比晶格排列方向(1,0,0)上的刻蝕速率快得多。因此,可以將暴露在外的矽質層移除,進而形成鏤空隧道區601。其中,矽的移除製程是可以很好地控制的,可藉由調整使其在適當的時間終止,以使一段垂直距離的矽質受到第三墊氮化矽層403間隙壁的保護。Please refer to Figures 6a, 6b, and 6c, where Figure 6a is a top view of the fabrication structure; Figure 6b is a cross-sectional view of the structure drawn along tangent 6b-6b' in Figure 6a; and Figure 6c is a cross-sectional view of the structure drawn along tangent 6c-6c' in Figure 6a. A portion of the exposed silicon surface is removed using isotropic etching, preferably by adjusting the etching rate along the lattice alignment direction (1,1,0) to be much faster than the etching rate along the lattice alignment direction (1,0,0). Therefore, the exposed silicon layer can be removed, thereby forming the etched tunnel region 601. The silicon removal process is well controlled and can be stopped at the appropriate time to ensure that a vertical distance of silicon is protected by the gap walls of the third silicon nitride layer 403.

值得注意的是,可以使用不同的製程來完成類似於第6a圖、第6b圖和第6c圖所繪示的結構。例如在形成如第5a圖和第5b圖所繪示的結構之後,可以不使用前述的非等向性蝕刻技術來移除一部分暴露在外的矽質表面,而是使用熱氧化製程,生長矽氧化物取代掉曝露於外的矽質區。由於暴露於外的矽質區其水平距離可能較窄,因此在矽島頂表面下方所生長的矽氧化物層(例如,熱氧化矽)可以快速填充水平空隙,具有良好的平滑的閉合(close-up)形狀,而被第三墊氮化矽層403所覆蓋的矽塊體材料,則可以受到很好地保護以作為強柱,用來將電晶體的半導體本體區連接到晶圓基材區,而不會被過度氧化。然後使用非等向性蝕刻技術移除此熱氧化矽以產生如類似於第6a圖、第6b圖和第6c圖所繪示的結構。.It is worth noting that different processes can be used to achieve structures similar to those shown in Figures 6a, 6b, and 6c. For example, after forming the structures shown in Figures 5a and 5b, instead of using the aforementioned anisotropic etching technique to remove a portion of the exposed silicon surface, a thermal oxidation process can be used to grow silicon oxide to replace the exposed silicon region. Because the exposed silicon regions may have narrow horizontal spacing, the silicon oxide layer (e.g., thermally oxidized silicon) grown beneath the top surface of the silicon islands can quickly fill the horizontal gaps, exhibiting a smooth, closed-up shape. The bulk silicon material covered by the third pad silicon nitride layer 403 is well protected as a strong pillar to connect the semiconductor body region of the transistor to the wafer substrate region without being over-oxidized. This thermally oxidized silicon is then removed using anisotropic etching techniques to produce a structure similar to that shown in Figures 6a, 6b, and 6c.

請參照第7a圖和第7b圖,採用等向刻蝕技術移除第三墊氮化矽層403間隙壁。採用熱氧化製程生長非常薄(例如1奈米至3奈米)的矽氧化物層701,以很好地保護剛形成並暴露於外的矽質表面。然後選擇合適的具有非常高導熱係數的材料(例如,氮化硼(BN),它是電絕緣體,但具有非常高的導熱係數,例如600W/m×K,而矽材料的導熱係數為149W/m×K;氮化鋁(AlN),為導熱係數高達321W/m×K的材料;或其他具有適當導熱係數的任何材料,其中任一種都可以稱為Z材料702)。接著利用化學氣相沉積(CVD)製程,例如選擇氮化硼(BN),來填補先前製程所形成的鏤空隧道區601。當然,淺溝隔離區內部的空隙也由氮化硼(BN)材料填滿(第7a圖和第7b圖係分別繪示該製程結構的俯視圖和剖面示意圖)。Referring to Figures 7a and 7b, the interstitial walls of the third pad silicon nitride layer 403 are removed using isotropic etching. A very thin (e.g., 1 nm to 3 nm) silicon oxide layer 701 is grown using a thermal oxidation process to effectively protect the newly formed and exposed silicon surface. A suitable material with a very high thermal conductivity is then selected (e.g., boron nitride (BN), which is an electrical insulator but has a very high thermal conductivity, such as 600 W/m × K, compared to silicon's 149 W/m × K; aluminum nitride (AlN), a material with a thermal conductivity up to 321 W/m × K; or any other material with a suitable thermal conductivity, any of which can be referred to as material Z 702). Next, a chemical vapor deposition (CVD) process, for example, boron nitride (BN), is used to fill the hollow tunnel region 601 formed in the previous process. Of course, the voids inside the shallow groove isolation region are also filled with boron nitride (BN) material (Figures 7a and 7b are top views and cross-sectional schematic diagrams of the process structure, respectively).

在另一實施例中,Z材料702的熱導率高於矽,或高於氮化矽,或高於10W/mK或30W/mK。當然,可能作為Z材料702的其他材料可以是石墨烯或金屬(例如銅、鎢或複合金屬等)。並且較佳在鎢層上覆蓋一層氮化鈦(TiN)阻障層或其他合適的材質層。當Z材料702的材料為金屬時,主動區和Z材料702之間可以存在絕緣體薄層,例如熱氧化矽層。此外,Z材料702的材料可以是包括兩種或多種上述材料所組成的複合材料層。顯然,Z材料702與淺溝隔離區的原始材料(二氧化矽)不同。在另一實施例中,Z材料702也不同於氮化矽。Z材料702可以包括導熱率高於淺溝隔離區之原始材料 (例如矽氧化物)的材料,例如氮化鋁、氮化硼、碳化矽(SiC)、矽(Si)、沉積鑽石(deposited diamond)或矽鍺(SiGe)等。In another embodiment, the thermal conductivity of material Z 702 is higher than that of silicon, or higher than that of silicon nitride, or higher than 10 W/mK or 30 W/mK. Of course, other materials that could be used as material Z 702 could be graphene or metals (e.g., copper, tungsten, or composite metals). Preferably, a titanium nitride (TiN) barrier layer or other suitable material layer is coated on the tungsten layer. When the material of material Z 702 is metal, an insulating thin layer, such as a thermally oxidized silicon layer, can exist between the active region and material Z 702. Furthermore, the material of material Z 702 can be a composite material layer comprising two or more of the aforementioned materials. Clearly, material Z 702 is different from the original material (silicon dioxide) of the shallow groove isolation region. In another embodiment, material Z 702 is also different from silicon nitride. Material Z 702 may include materials with higher thermal conductivity than the original material (e.g., silicon oxide) of the shallow groove isolation region, such as aluminum nitride, boron nitride, silicon carbide (SiC), silicon (Si), deposited diamond, or silicon-germanium (SiGe).

之後,可使用化學機械研磨技術移除位於第一墊氮化矽層102上方的氮化硼材料或Z材料702,以形成平坦的表面,並進一步使用非等向性蝕刻技術移除一部分氮化硼材料或Z材料702,使Z材料702的頂部與原始半導體表面對齊,或低於原始半導體表面。接著,在剩餘的Z材料702的頂部沉積一層矽氧化物801,直到其與第一墊氮化矽層102的頂面齊平。在移除第二墊氮化矽層301之後,矽質表面會被第一墊氮化矽層102和淺溝隔離區上方的矽氧化物所覆蓋,並且可以在剩餘的半導體主動區中進行熟悉的製程,以完成電晶體(例如,平面電晶體、鰭式場效電晶體或環繞式閘極 (gate-all-around;GAA)電晶體,等)的製備(參見第8圖,其中第8a圖和第8b圖係分別繪示該製程結構的俯視圖和剖面示意圖)。Subsequently, chemical mechanical polishing (CMP) can be used to remove the boron nitride material or Z material 702 located above the first silicon nitride layer 102 to form a flat surface. Anisotropic etching is then used to remove a portion of the boron nitride material or Z material 702, aligning the top of the Z material 702 with or below the original semiconductor surface. Next, a layer of silicon oxide 801 is deposited on top of the remaining Z material 702 until it is flush with the top surface of the first silicon nitride layer 102. After the second silicon nitride layer 301 is removed, the silicon surface is covered by silicon oxide above the first silicon nitride layer 102 and the shallow groove isolation region, and familiar processes can be performed in the remaining active semiconductor region to complete the fabrication of a transistor (e.g., a planar transistor, a fin field-effect transistor, or a gate-all-around (GAA) transistor, etc.) (see Figure 8, where Figures 8a and 8b are top and cross-sectional views of the fabrication structure, respectively).

由於將氮化硼材料或Z材料702填充在主動區(或鰭式場效電晶體/三閘極元件(Tri-gate device))下方的鏤空隧道區中,因此其可稱為水平散熱板。如第8圖所繪示,填充在淺溝隔離區的垂直空隙的一些Z材料702,可稱之為垂直散熱柱。在主動區中形成電晶體之後,可以將電晶體的源極/汲極區定位在靠近具有比傳統設計包圍電晶體的二氧化矽(或矽)材料更高導熱率的水平散熱板和垂直散熱柱的位置。實際上,電晶體在全面運作時最熱的區域分別集中在與電晶體通道區連接的汲極區和源極區二者之間的p/n接面區,這些水平散熱板和垂直散熱柱結構可以非常有效地分散這些p/n接面區所產生的熱能。Since boron nitride or Z material 702 is filled in the hollowed-out tunnel region beneath the active region (or finned field-effect transistor/tri-gate device), it can be referred to as a horizontal heatsink. Some Z material 702 filling the vertical voids in the shallow groove isolation region, as illustrated in Figure 8, can be referred to as vertical heatsink pillars. After the transistor is formed in the active region, the source/drain regions of the transistor can be positioned close to the horizontal heatsink and vertical heatsink pillars, which have a higher thermal conductivity than the silicon dioxide (or silicon) material conventionally used to surround the transistor. In fact, the hottest areas of a transistor during full operation are concentrated in the p/n junction region between the drain region and the source region, which are connected to the transistor channel region. These horizontal heat dissipation plates and vertical heat dissipation pillars can very effectively disperse the heat generated in these p/n junction regions.

另一種可能性是使用與前述的類似方法來創建距離原始矽表面更深的水平散熱板結構,增加更多的水平散熱板來擴大散熱面積。例如,在藉由化學氣相沉積製程完成氮化硼材料或Z材料702的沉積之後,可以使用非等向性蝕刻技術移除垂直位於淺溝隔離區201內部的氮化硼材料或Z材料702。然後,也可以採用非等向性蝕刻技術將淺溝隔離區201底部的矽氧化物材料去除或刻蝕掉(例如,僅在淺溝隔離區201內部保留20奈米至50奈米厚的矽氧化物,而不會傷害到已經水平插入鏤空隧道區601的氮化硼材料)。然後第二次將氮化硼材料或Z材料702沉積到淺溝隔離區21中的空隙中。形成氮化硼材料或Z材料702的兩段步驟,第一步是用於形成水平散熱板,然後第二步則用於優化淺溝隔離區21內部所有氮化硼或Z材料702的體積(參見第9圖,其中第9a圖和第9b圖係分別繪示該製程結構的俯視圖和剖面示意圖)。當然,在第二次沉積Z材料702之前,可以應用額外的步驟來形成薄垂直隔離層(例如,矽氧化物薄層401),使得垂直隔離層位於成水平散熱板下方,並且位於矽基材的側壁和Z材料702之間。Another possibility is to use a similar method to create a horizontal heatsink structure deeper than the original silicon surface, increasing the heat dissipation area by adding more horizontal heatsinks. For example, after the deposition of boron nitride material or Z material 702 by chemical vapor deposition, anisotropic etching can be used to remove the boron nitride material or Z material 702 vertically located inside the shallow groove isolation region 201. Then, anisotropic etching can also be used to remove or etch away the silicon oxide material at the bottom of the shallow groove isolation region 201 (e.g., leaving only 20 to 50 nanometers thick silicon oxide inside the shallow groove isolation region 201 without damaging the boron nitride material that has been horizontally inserted into the hollow tunnel region 601). Then, boron nitride material or Z material 702 is deposited a second time into the voids in the shallow groove isolation region 21. The two-step process of forming boron nitride material or Z material 702 involves forming a horizontal heat dissipation plate in the first step and optimizing the volume of all boron nitride or Z material 702 within the shallow groove isolation region 21 (see Figure 9, where Figures 9a and 9b are top and cross-sectional views of the process structure, respectively). Of course, before the second deposition of Z material 702, an additional step can be applied to form a thin vertical isolation layer (e.g., a silicon oxide layer 401) such that the vertical isolation layer is located below the horizontal heat dissipation plate and between the sidewall of the silicon substrate and the Z material 702.

另外值得注意的是,如第1a圖所繪示,淺溝隔離區遍佈整個晶圓基材。由於水平散熱板材料全部位於 金屬氧化物半導體場效電晶體(MOSFET)/電晶體的本體區(或主動區)下方,並且連接到淺溝隔離區內部的所有垂直散熱柱材料,因此所建構的高散熱材料網路,可以作為連接電晶體之工作P/N接面的散熱片(heat-dissipation sink)。藉由在單晶片(粒單晶(monolithic die))中設計Z材質,並利用熟悉的單晶片(粒)製程參數(配方),可以讓所有Z材質都連接到晶片或晶粒的邊緣環。而且位於淺溝隔離區內的Z材料702可以透過打開其頂面而形成接觸,使得整個晶粒的Z材料702可以熱連接到晶片/晶粒的外邊緣,以更直接和更有效地散熱。參見第10圖,其中第10a圖和第10b圖係分別繪示該製程結構的俯視圖和剖面示意圖。因此,淺溝隔離區中的水平散熱片(和/或主動區中的水平散熱片)可以稱為一種晶粒直接排散熱器(Direct Die Heat Remover,DDHR)。本發明提供了一種基於上述垂直散熱柱(和/或水平散熱板)的晶粒直接冷卻技術(Direct Die Cooling Technology,DDCT)。It is also worth noting that, as shown in Figure 1a, the shallow groove isolation region covers the entire wafer substrate. Since the horizontal heat dissipation plate material is entirely located below the body region (or active region) of the metal-oxide-semiconductor field-effect transistor (MOSFET)/transistor and connected to all the vertical heat dissipation pillar materials within the shallow groove isolation region, the constructed high-heat-dissipation material network can serve as a heat-dissipation sink connecting the working P/N junction of the transistor. By designing Z-materials in a monolithic die and utilizing familiar monolithic die process parameters (formulas), all Z-materials can be connected to the edge ring of the die or chip. Furthermore, the Z material 702 located within the shallow groove isolation region can form contact by opening its top surface, allowing the entire Z material 702 of the die to be thermally connected to the outer edge of the wafer/die for more direct and efficient heat dissipation. See Figure 10, where Figures 10a and 10b respectively illustrate the top view and cross-sectional schematic of the fabrication structure. Therefore, the horizontal heat sink in the shallow groove isolation region (and/or the horizontal heat sink in the active region) can be termed a Direct Die Heat Remover (DDHR). This invention provides a Direct Die Cooling Technology (DDCT) based on the aforementioned vertical heat sink (and/or horizontal heat sink).

半導體基材中存在多個主動區,在本發明中,主動區(或多個主動區)可以被Z材料702所包圍。Z材料702從一個主動區延伸到另一個主動區,並且進一步延伸到晶片/晶粒的邊緣。每個主動區可以容納一電路元件,例如電晶體。在另一個實施例中,具有垂直散熱柱(和/或水平散熱板)的晶片/晶粒可以先薄化,然後再通過開孔藉以露出垂直散熱柱(和/或水平散熱板),這樣可以使得具有熱通孔插塞(thermal vias)或散熱器(heat sink)的另一個基板,可以從晶片/晶粒的底部連接到垂直散熱柱(和/或水平散熱板) 。The semiconductor substrate contains multiple active regions, which in this invention can be surrounded by a Z material 702. The Z material 702 extends from one active region to another and further to the edge of the wafer/die. Each active region can accommodate a circuit element, such as a transistor. In another embodiment, the wafer/die with vertical heat dissipation pillars (and/or horizontal heat dissipation plates) can be thinned first, and then exposed through openings, so that another substrate with thermal vias or heat sinks can be connected from the bottom of the wafer/die to the vertical heat dissipation pillars (and/or horizontal heat dissipation plates).

在通過部分前端製程完成垂直散熱柱(和/或水平散熱板)的結構之後,可用剩餘的前端代工製程在主動區中形成電晶體,如第11圖所繪示。電晶體的擴散區(或源極/汲極區)可以與垂直散熱柱(和/或水平散熱板)接觸或幾乎接觸。因此,可以說垂直散熱柱(和/或水平散熱板)是在半導體前端代工製程期間所形成的,或者是形成在半導體晶粒的前端製程區之內。After the structure of the vertical heat pillar (and/or horizontal heat plate) is completed through a portion of the front-end fabrication process, the transistor can be formed in the active region using the remaining front-end foundry processes, as illustrated in Figure 11. The diffusion region (or source/drain region) of the transistor can be in contact with or nearly in contact with the vertical heat pillar (and/or horizontal heat plate). Therefore, it can be said that the vertical heat pillar (and/or horizontal heat plate) is formed during the semiconductor front-end foundry process, or within the front-end fabrication region of the semiconductor die.

在第11圖中,此電晶體包括閘極結構,該閘極結構包括閘極金屬區1101和高介電係數(Hi-K)介電層1102。此電晶體還包括源極區1103,源極區1103包括從基材的側壁橫向延伸的輕摻雜區和從輕摻雜區的側壁橫向延伸的重摻雜區。這些輕摻雜區和重摻雜區是採用選擇性生長方法(y selective growth methods)(例如磊晶生長方法(epitaxial growth methods))所形成。在源極區1104的頂部上方。在電晶體的閘極結構和淺溝隔離區(上方的矽氧化物801)之間存在有金屬接觸件1105。值得注意的是,淺溝隔離區(上方的矽氧化物801)的頂面高於原始半導體表面(例如,與閘極結構的頂部齊平),因此會自動形成接觸孔,病不需要使用微影製程來形成接觸孔。故而,金屬接觸1105會與源極區1103自對準(self-aligned with)。此外,在另一實施例中,金屬接觸件1105不僅可以連接至源極區1103的頂部,還可連接至源極區1103的最橫向的側壁。此電晶體也包括汲極區1104,由於其結構與源極區1103相同或基本相同,故在此不再贅述。第11圖所繪示的最終電晶體結構具有垂直散熱柱(和/或水平散熱板)的微結構,用於製作一種新的「電晶體冷卻 (CQT)」結構,這是描述本發明實施例的最佳術語。這種電晶體冷卻 (CQT)結構可以實現從現在的巨大規模積體電路(GSI) 時代到不久的將來的兆級規模積體電路(TSI)時代的效能放大(更多電晶體)和尺寸微縮(更小的電晶體尺寸)策略。為晶片或晶粒所創建的新散熱路徑,是從電晶體層級(transistor level) 直接形成散熱路徑至整個晶粒層級(entire die level)。有一些設計可以將晶粒層級的散熱路徑連接到晶片層級(chip-level thermal path)的熱路徑。在目前的晶片和封裝/異質機體模組(heterogeneous integration module)所用的冷卻方法下,其當然可以做為晶片和封裝/異質機體模組(例如,通過穿矽通孔插塞(TSV)或絕緣體通孔(TIV),等)有效的散熱裝置。In Figure 11, this transistor includes a gate structure comprising a gate metal region 1101 and a high-k dielectric layer 1102. The transistor also includes a source region 1103 comprising lightly doped regions extending laterally from the sidewalls of the substrate and heavily doped regions extending laterally from the sidewalls of the lightly doped regions. These lightly doped and heavily doped regions are formed using selective growth methods (e.g., epitaxial growth methods). The source region 1104 is located above the top of the source region 1104. A metal contact 1105 exists between the gate structure of the transistor and the shallow groove isolation region (the upper silicon oxide 801). Notably, the top surface of the shallow groove isolation region (the upper silicon oxide 801) is higher than the original semiconductor surface (e.g., flush with the top of the gate structure), thus automatically forming a contact via, eliminating the need for a photolithography process. Therefore, the metal contact 1105 is self-aligned with the source region 1103. Furthermore, in another embodiment, the metal contact 1105 can be connected not only to the top of the source region 1103 but also to the outermost lateral sidewall of the source region 1103. This transistor also includes a drain region 1104, whose structure is the same as or substantially the same as that of the source region 1103, and will not be described further here. The final transistor structure illustrated in Figure 11 has a microstructure with vertical heat dissipation pillars (and/or horizontal heat dissipation plates) for fabricating a new "transistor cooling (CQT)" structure, which is the best term to describe embodiments of the invention. This transistor cooling (CQT) structure enables performance scaling (more transistors) and size miniaturization (smaller transistor size) strategies from the current era of massive scalar integrated circuits (GSI) to the near future era of mega scalar integrated circuits (TSI). The new heat dissipation path created for a chip or die is a direct heat dissipation path formed from the transistor level to the entire die level. Some designs can connect the die-level heat dissipation path to the chip-level thermal path. Under current cooling methods used in chips and heterogeneous integration modules, it can certainly serve as an effective heat dissipation device for chips and heterogeneous integration modules (e.g., through through-silicon vias (TSVs) or through-insulator vias (TIVs), etc.).

此外,在另一實施例中,可以省略形成水平散熱板的製程,而僅建構垂直散熱柱。例如請參照第12圖,可以先將淺溝隔離區201向下刻蝕,將矽基材的側壁暴露於外,使得淺溝隔離區剩餘材料的深度約為150奈米至200奈米,然後沿著矽基材的側壁暴露於外的側壁形成矽氧化物(熱氧化矽)薄層401。然後,沉積Z材料702並回蝕100奈米至150奈米的深度以形成垂直散熱柱,並在垂直散熱柱上沉積額外的矽氧化物801或其他隔離材料,如第12a圖所繪示。In another embodiment, the process of forming a horizontal heat sink can be omitted, and only a vertical heat sink pillar can be constructed. For example, referring to Figure 12, the shallow groove isolation region 201 can be etched downwards to expose the sidewalls of the silicon substrate, such that the depth of the remaining material in the shallow groove isolation region is approximately 150 nm to 200 nm. Then, a silicon oxide (thermal silicon oxide) thin layer 401 is formed along the exposed sidewalls of the silicon substrate. Then, Z material 702 is deposited and etched back to a depth of 100 nm to 150 nm to form a vertical heat sink pillar, and additional silicon oxide 801 or other isolation materials are deposited on the vertical heat sink pillar, as illustrated in Figure 12a.

第12b圖係根據本發明的另一實施例繪示位於淺溝隔離區中的垂直散熱柱的結構剖面示意圖。第12a圖和第12b圖的差異在於,淺溝隔離區中大部分的二氧化矽材質被垂直散熱柱所取代。傳統淺溝隔離區的深度,從晶片的原始半導體表面(OSS)起算,為250奈米至300奈米。在第12b圖中,淺溝隔離區的下部中僅餘留深度為20奈米至50奈米的二氧化矽材料;而在第12a圖所繪示的淺溝隔離區下部中則餘留下深度為150奈米至200奈米的二氧化矽材料。被垂直散熱柱所取代的二氧化矽越多,晶粒結構的導熱率越高。當然,垂直散熱柱的頂部可以低於或高於原始半導體表面。同樣地,第12a圖或第12b圖所繪示的垂直散熱柱結構也可以沿著半導體晶粒內部的所有淺溝隔離區延伸,如第12c圖所繪示。其中,第12c圖的下方子圖式是沿著第12c圖上方子圖式的切線12c所繪示的結構剖面示意圖。Figure 12b is a schematic cross-sectional view of the structure of a vertical heat dissipation pillar located in a shallow groove isolation region, according to another embodiment of the present invention. The difference between Figures 12a and 12b is that most of the silicon dioxide material in the shallow groove isolation region is replaced by the vertical heat dissipation pillar. The depth of a conventional shallow groove isolation region, measured from the original semiconductor surface (OSS) of the wafer, is 250 nm to 300 nm. In Figure 12b, only silicon dioxide material with a depth of 20 nm to 50 nm remains in the lower part of the shallow groove isolation region; while in the shallow groove isolation region shown in Figure 12a, silicon dioxide material with a depth of 150 nm to 200 nm remains in the lower part. The more silicon dioxide replaced by vertical heat dissipation pillars, the higher the thermal conductivity of the grain structure. Of course, the top of the vertical heat dissipation pillars can be lower or higher than the original semiconductor surface. Similarly, the vertical heat dissipation pillar structure illustrated in Figure 12a or 12b can also extend along all the shallow groove isolation regions inside the semiconductor grain, as illustrated in Figure 12c. The lower sub-figure of Figure 12c is a schematic cross-sectional view of the structure drawn along the tangent 12c of the upper sub-figure of Figure 12c.

第13圖係繪示另一種電晶體冷卻結構的結構示意圖,第13圖和第11圖的差異在於,第13圖的電晶體冷卻結構是基於第12b圖所繪示位於淺溝隔離區中的垂直散熱柱所形成。由於第13圖所繪示的電晶體冷卻結構的其他說明與第11圖所繪示的電晶體冷卻結構相同。為簡潔起見,跳過其細節的描述。Figure 13 is a schematic diagram illustrating another transistor cooling structure. The difference between Figure 13 and Figure 11 is that the transistor cooling structure in Figure 13 is based on the vertical heat dissipation column located in the shallow groove isolation region shown in Figure 12b. Since the other descriptions of the transistor cooling structure shown in Figure 13 are the same as those in Figure 11, detailed descriptions will be skipped for the sake of brevity.

如前所述,垂直散熱柱或Z材料可以由單一的高散熱材料所製成,也可以由複合結構製成。例如,垂直散熱柱包括一層第一高散熱材料(例如,氮化硼、氮化鋁等,未於第12a圖或第12b圖中繪示)以及被第一高散熱材料所覆蓋的另一個金屬或類金屬柱。由於垂直散熱柱位於淺溝隔離區之中,且類金屬材料被第一高散熱材料所包圍,該材料在晶片/晶粒中的電晶體工作期間不會導電(在這種情況下,可以省略矽氧化物薄層401),因此垂直散熱柱中的類金屬材料將不影響晶片/晶粒中電晶體管的運行。當然,第一高散熱材料和金屬或類金屬柱體都可以進一步延伸至晶片/晶粒的邊緣,並形成如前所述的散熱網絡。因此,因此,本發明的半導體結構中存在複合材料的淺溝隔離區(包括原始淺溝隔離區二氧化矽材料和垂直散熱柱;僅包括垂直散熱柱,它可以是具有兩個不同層的複合材料)或異質的淺溝隔離區 (Heterogeneous STI,HSTI)。As previously mentioned, the vertical heat dissipation pillar or Z-material can be made of a single high-heat-dissipation material or a composite structure. For example, the vertical heat dissipation pillar includes a first high-heat-dissipation material (e.g., boron nitride, aluminum nitride, etc., not shown in Figures 12a or 12b) and another metal or metal-like pillar covered by the first high-heat-dissipation material. Since the vertical heat dissipation pillar is located in a shallow groove isolation region and the metal-like material is surrounded by the first high-heat-dissipation material, which does not conduct electricity during the operation of the transistors in the wafer/die (in this case, the silicon oxide layer 401 can be omitted), the metal-like material in the vertical heat dissipation pillar will not affect the operation of the transistors in the wafer/die. Of course, the first high heat dissipation material and the metal or metal-like pillars can further extend to the edge of the wafer/grain and form a heat dissipation network as described above. Therefore, the semiconductor structure of the present invention contains a shallow groove isolation region of composite material (including the original shallow groove isolation region silicon dioxide material and vertical heat dissipation pillars; only the vertical heat dissipation pillars are included, which can be a composite material with two different layers) or a heterogeneous shallow groove isolation region (HSTI).

此外,在一個實施例中,第1a圖中的全部或大部分淺溝隔離區,都可以用複合材料的淺溝隔離區來加以代替。這種複合材料的淺溝隔離區可以從一個主動區延伸到另一個主動區,並且進一步延伸到晶片/晶粒的邊緣。在另一實施例中,第一組主動區的外圍邊界(peripheral border)被這種複合材料的淺溝隔離區所圍繞,並延伸到第二組主動區,且進一步延伸到晶片/晶粒的邊緣。Furthermore, in one embodiment, all or most of the shallow groove isolation regions in Figure 1a can be replaced by shallow groove isolation regions of a composite material. These composite material shallow groove isolation regions can extend from one active region to another, and further to the edge of the wafer/die. In another embodiment, the peripheral border of the first set of active regions is surrounded by these composite material shallow groove isolation regions, extending to the second set of active regions, and further to the edge of the wafer/die.

第14a圖係根據本說明書的一些實施例所繪示的半導體電路結構200俯視圖。半導體電路結構200可以形成在半導體晶片或基材中。第14a圖繪示了更多的主動區或主動區220A、淺溝隔離區220B以及可以容納半導體電路結構200之接觸銲墊的銲墊開口層(pad open layer)220C。淺溝隔離區220B中的一些大型淺溝隔離區224-1至224-4可以位於與半導體晶片的外圍/邊緣區域相鄰的角落區(corner area)中,或位於晶片的中心備用區(center spare area)中。大型垂直散熱柱結構(例如垂直散熱柱銲墊)209位於大型淺溝隔離區224-1至224-4內部,且位於半導體基材原始半導體表面的下方。另外,其他薄或長的垂直散熱柱結構(例如,垂直散熱柱線)205位於半導體基材的原始半導體表面下方,並且形成在淺溝隔離區220B中的那些薄或長的淺溝隔離區224-1至224-4內部。垂直散熱柱結構205和淺溝隔離區214-1至214-4可以沿著X軸方向(或沿著主動區的長軸方向)延伸。此外,垂直散熱柱結構205可以在兩個或更多個主動區220A之上延伸,例如,位於第14a圖右上方的垂直散熱柱結構205從鄰近於主動區220A-1的一個預定點延伸到大型淺溝隔離區224-1。Figure 14a is a top view of a semiconductor circuit structure 200 illustrated according to some embodiments of this specification. The semiconductor circuit structure 200 may be formed in a semiconductor wafer or substrate. Figure 14a illustrates additional active regions or active regions 220A, shallow groove isolation regions 220B, and pad open layers 220C that can accommodate the contact pads of the semiconductor circuit structure 200. Some large shallow groove isolation regions 224-1 to 224-4 in the shallow groove isolation regions 220B may be located in corner areas adjacent to the outer/edge areas of the semiconductor wafer, or in the center spare area of the wafer. Large vertical heat dissipation pillar structures (e.g., vertical heat dissipation pillar pads) 209 are located within large shallow groove isolation regions 224-1 to 224-4 and below the original semiconductor surface of the semiconductor substrate. Additionally, other thin or long vertical heat dissipation pillar structures (e.g., vertical heat dissipation pillar lines) 205 are located below the original semiconductor surface of the semiconductor substrate and are formed within those thin or long shallow groove isolation regions 224-1 to 224-4 in the shallow groove isolation region 220B. The vertical heat dissipation pillar structures 205 and the shallow groove isolation regions 214-1 to 214-4 may extend along the X-axis direction (or along the long axis of the active region). In addition, the vertical heat dissipation column structure 205 may extend over two or more active zones 220A. For example, the vertical heat dissipation column structure 205 located in the upper right of Figure 14a extends from a predetermined point near the active zone 220A-1 to a large shallow groove isolation zone 224-1.

在第14a圖中,在淺溝隔離區214-1的一側,具有沿著X軸方向延伸的第一組主動區;在淺溝隔離區214-1的另一側,具有沿著X軸方向延伸的第二組主動區。因此,淺溝隔離區214-1位於第一組主動區和第二組主動區之間,並且沿著X軸方向延伸。此外,淺溝隔離區214-1內部的垂直散熱柱結構205也位於第一組主動區和第二組主動區之間,並且沿著X軸方向延伸。在一個實施例中,位於第一組主動區和第二組主動區之間的垂直散熱柱結構205的最小寬度和/或最長寬度(例如,沿著Y軸方向),小於垂直散熱柱結構209(例如,沿著y方向)連接到直散熱柱結構205的寬度。In Figure 14a, on one side of the shallow groove isolation region 214-1, there is a first set of active regions extending along the X-axis; on the other side of the shallow groove isolation region 214-1, there is a second set of active regions extending along the X-axis. Therefore, the shallow groove isolation region 214-1 is located between the first and second sets of active regions and extends along the X-axis. Furthermore, the vertical heat dissipation column structure 205 inside the shallow groove isolation region 214-1 is also located between the first and second sets of active regions and extends along the X-axis. In one embodiment, the minimum width and/or maximum width (e.g., along the Y-axis) of the vertical heat dissipation column structure 205 located between the first set of active regions and the second set of active regions is less than the width of the vertical heat dissipation column structure 209 (e.g., along the y-direction) connected to the vertical heat dissipation column structure 205.

此外,淺溝隔離區214-1至214-4的每一者可以與複數個主動區220A中的一組電晶體相鄰,並且大型淺溝隔離區214-1遠離此組電晶體。垂直散熱柱結構205耦合到或直接連接到垂直散熱柱結構209。Furthermore, each of the shallow groove isolation regions 214-1 to 214-4 may be adjacent to one group of transistors in the plurality of active regions 220A, and the large shallow groove isolation region 214-1 is distanced from this group of transistors. The vertical heat dissipation pillar structure 205 is coupled to or directly connected to the vertical heat dissipation pillar structure 209.

垂直散熱柱結構209沿著Y軸方向的寬度,大於垂直散熱柱結構205沿著Y軸方向的寬度。垂直散熱柱結構209沿著Y軸方向的寬度,可以介於約2微米(μm)至8微米之間。垂直散熱柱結構205沿著Y軸方向的寬度,可以介於約10奈米至100奈米之間。垂直散熱柱結構209的面積可以以介於約4平方微米(μm2)至約50平方微米之間。垂直散熱柱結構205和 209的材料可以相同或不同。The width of the vertical heat dissipation pillar 209 along the Y-axis is greater than the width of the vertical heat dissipation pillar 205 along the Y-axis. The width of the vertical heat dissipation pillar 209 along the Y-axis can be between approximately 2 micrometers (μm) and 8 micrometers. The width of the vertical heat dissipation pillar 205 along the Y-axis can be between approximately 10 nanometers (nm) and 100 nanometers (nm). The area of the vertical heat dissipation pillar 209 can be between approximately 4 square micrometers ( μm² ) and approximately 50 square micrometers (nm²). The materials of the vertical heat dissipation pillars 205 and 209 can be the same or different.

備用或大型淺溝隔離區224可以形成用於從大型淺溝隔離區224的底部延伸到基材底側的背面穿矽通孔插塞(TSV)或熱通孔插塞的額外對準標記(extra alignment marks),如第14b圖所繪示。這些背面穿矽通孔插塞(TSV)或熱通孔插塞位於大型淺溝隔離區224內部之大尺寸垂直散熱柱銲墊正下方,並且與大尺寸垂直散熱柱銲墊連接。備用或大型淺溝隔離區224的面積夠大,使其可以容納一個或多個穿矽通孔插塞(TSV)或熱通孔插塞。當然,那些備用或大型淺溝隔離區224還可以形成用於從大型淺溝隔離區22的頂部延伸到基材頂側的頂側的穿矽通孔插塞(TSV)或熱通孔插塞的額外對準標記。這些熱通孔插塞位於備用淺溝隔離區內的大尺寸垂直散熱柱銲墊的正上方,並且連接到大尺寸垂直散熱柱銲墊。本發明的穿矽通孔插塞(TSV)或熱通孔插塞可以通過後端製程代工製造,並且連接到大尺寸垂直散熱柱銲墊。因此,可以說,穿矽通孔插塞(TSV)或熱通孔插塞是在後端製程代工製造期間形成的,或是在半導體晶粒的後端製程區內形成的。The spare or large shallow groove isolation area 224 may form additional alignment marks for back-through-silicon via (TSV) or hot-through-hole plugs extending from the bottom of the large shallow groove isolation area 224 to the bottom side of the substrate, as illustrated in Figure 14b. These back-through-silicon via (TSV) or hot-through-hole plugs are located directly below and connected to the large vertical heat dissipation pillar pads inside the large shallow groove isolation area 224. The spare or large shallow groove isolation area 224 is large enough to accommodate one or more TSVs or hot-through-hole plugs. Of course, the spare or large shallow groove isolation areas 224 can also form additional alignment marks for the through-silicon via (TSV) or hot-through-hole plugs extending from the top of the large shallow groove isolation area 22 to the top side of the substrate. These hot-through-hole plugs are located directly above and connected to the large vertical heat dissipation pillar pads within the spare shallow groove isolation areas. The through-silicon via (TSV) or hot-through-hole plugs of the present invention can be manufactured by back-end processing and connected to the large vertical heat dissipation pillar pads. Therefore, it can be said that through-silicon via (TSV) plugs or thermal via plugs are formed during back-end foundry manufacturing or within the back-end processing area of the semiconductor die.

在其他實施例中,垂直散熱柱結構可以沿著非X軸方向延伸,如第15a圖所繪示。第15a圖係根據本說明書的一些實施例所繪示的半導體電路結構300俯視圖。與第14a圖所繪示的半導體電路結構200相比,第15a圖繪示的半導體電路結構300更包括沿著Y軸方向延伸的淺溝隔離區314-1、314-2和314-3以及垂直散熱柱結構305-1、305-2和305-3。垂直散熱柱結構305-1、305-2和305-3位於半導體基材的原始半導體表面下方,並且分別形成在淺溝隔離區314-1、314-2和314-3的內部。垂直散熱柱結構305-1、305-2和305-3可以是垂直散熱柱線。垂直散熱柱結構305-1、305-2和305-3以及淺溝隔離區314-1、314-2和314-3可以沿著Y軸方向(或沿著主動區的寬度方向)延伸。此外,垂直散熱柱結構305-1、305-2和305-3可以在兩個或更多個主動區220A上方延伸。例如,位於第15圖左上部分的垂直散熱柱結構305-1從鄰近主動區220A-2的一個預定點延伸到水平淺溝隔離區214。淺溝隔離區314-1、314-2和314-3中的每一者,都可以鄰近位於主動區220A中的一組電晶體。In other embodiments, the vertical heat dissipation pillar structure may extend along a direction other than the X-axis, as illustrated in Figure 15a. Figure 15a is a top view of a semiconductor circuit structure 300 illustrated according to some embodiments of this specification. Compared to the semiconductor circuit structure 200 illustrated in Figure 14a, the semiconductor circuit structure 300 illustrated in Figure 15a further includes shallow groove isolation regions 314-1, 314-2, and 314-3 extending along the Y-axis, as well as vertical heat dissipation pillar structures 305-1, 305-2, and 305-3. Vertical heat dissipation pillar structures 305-1, 305-2, and 305-3 are located below the original semiconductor surface of the semiconductor substrate and are formed inside shallow groove isolation regions 314-1, 314-2, and 314-3, respectively. The vertical heat dissipation pillar structures 305-1, 305-2, and 305-3 can be vertical heat dissipation pillars. The vertical heat dissipation pillar structures 305-1, 305-2, and 305-3, as well as the shallow groove isolation regions 314-1, 314-2, and 314-3, can extend along the Y-axis direction (or along the width direction of the active region). Furthermore, the vertical heat dissipation pillar structures 305-1, 305-2, and 305-3 can extend above two or more active regions 220A. For example, the vertical heat dissipation pillar structure 305-1 located in the upper left portion of Figure 15 extends from a predetermined point adjacent to the active region 220A-2 to the horizontal shallow groove isolation region 214. Each of the shallow groove isolation regions 314-1, 314-2, and 314-3 can be adjacent to a set of transistors located in the active region 220A.

在第15a圖中,沿著非X軸方向延伸的垂直散熱柱結構可以連接到(或電性耦合到)沿著X軸方向延伸的垂直散熱柱結構和/或位於大型淺溝隔離區內的垂直散熱柱銲墊。例如,垂直散熱柱結構305-1連接到(或電性耦合到)垂直散熱柱結構205;垂直散熱柱結構305-2連接到(或電性耦合到)兩個垂直散熱柱結構205,並且位於這兩個垂直散熱柱結構205之間;垂直散熱柱結構305-3連接到(或電性耦合到)位於大型淺溝隔離區224內的垂直散熱柱銲墊209。垂直散熱柱結構305-1、305-2和305-3的尺寸和材質,可以與垂直散熱柱結構205類似。In Figure 15a, vertical heat dissipation pillar structures extending along a non-X-axis direction can be connected to (or electrically coupled to) vertical heat dissipation pillar structures extending along the X-axis direction and/or vertical heat dissipation pillar pads located within a large shallow groove isolation zone. For example, vertical heat dissipation pillar structure 305-1 is connected to (or electrically coupled to) vertical heat dissipation pillar structure 205; vertical heat dissipation pillar structure 305-2 is connected to (or electrically coupled to) two vertical heat dissipation pillar structures 205 and is located between these two vertical heat dissipation pillar structures 205; vertical heat dissipation pillar structure 305-3 is connected to (or electrically coupled to) vertical heat dissipation pillar pads 209 located within a large shallow groove isolation zone 224. The dimensions and materials of the vertical heat dissipation column structures 305-1, 305-2 and 305-3 can be similar to those of the vertical heat dissipation column structure 205.

透過沿著X軸方向延伸的垂直散熱柱結構/線、沿Y軸方向(或X軸方向以外的方向)延伸的垂直散熱柱結構/線以及位於大型淺溝隔離區內的垂直散熱柱銲墊的佈置,可以在晶粒或半導體基材內部和半導體基材原始半導體表面下方提供一種垂直散熱柱網格(VHDC mesh)(或稱為「直接晶粒冷卻技術(Direct Die Cooling Technology)」)。沿著X軸方向延伸的垂直散熱柱結構(即水平的垂直散熱柱線)可用於連接位於大型淺溝隔離區內的垂直散熱柱結構(即垂直散熱柱銲墊);且沿著Y軸方向延伸的垂直散熱柱結構(即垂直的垂直散熱柱線)可用於連接垂直散熱柱銲墊或水平的垂直散熱柱線。A vertical heat dissipation column structure/line extending along the X-axis, a vertical heat dissipation column structure/line extending along the Y-axis (or in a direction other than the X-axis), and a vertical heat dissipation column pad located within a large shallow groove isolation area can provide a vertical heat dissipation column mesh (VHDC mesh) (or "Direct Die Cooling Technology") inside the grain or semiconductor substrate and below the original semiconductor surface of the semiconductor substrate. Vertical heat dissipation column structures extending along the X-axis (i.e., horizontal vertical heat dissipation column lines) can be used to connect vertical heat dissipation column structures (i.e., vertical heat dissipation column pads) located within large shallow trench isolation areas; and vertical heat dissipation column structures extending along the Y-axis (i.e., vertical vertical heat dissipation column lines) can be used to connect vertical heat dissipation column pads or horizontal vertical heat dissipation column lines.

在一些實施例中,沿著非X軸方向延伸的垂直散熱柱結構,如第15a圖中所繪示的垂直散熱柱結構305-1、305-2和305-3,可以透過以下步驟來製造。第15b圖至第15c圖係繪示在製作第15a圖之半導體電路結構300的不同階段中的製程結構俯視圖。 在半導體基材上依序沉積墊氧化矽層(未繪示)和墊氮化矽層3206。然後,先藉由微影蝕刻製程定義出臨時主動區,並在臨時主動區外側定義出臨時淺溝隔離區和大型淺溝隔離區(如第15b圖中所繪示的虛線)。然後在臨時淺溝隔離區和大型淺溝隔離區中形成Z材料。然後,可以藉由另一個微影蝕刻製程定義出真正的主動區150A,並且被移除臨時主動區被用來作為剩餘的淺溝隔離區域,如第15c圖中所繪示。In some embodiments, vertical heat dissipation pillar structures extending along a non-X-axis direction, such as the vertical heat dissipation pillar structures 305-1, 305-2, and 305-3 illustrated in Figure 15a, can be manufactured through the following steps. Figures 15b to 15c are top views illustrating the fabrication structure at different stages of manufacturing the semiconductor circuit structure 300 of Figure 15a. A silicon oxide layer (not shown) and a silicon nitride layer 3206 are sequentially deposited on the semiconductor substrate. Next, a temporary active region is defined using a photolithography process, and temporary shallow groove isolation regions and large shallow groove isolation regions are defined outside the temporary active region (as shown by the dashed lines in Figure 15b). Z material is then formed within the temporary shallow groove isolation regions and the large shallow groove isolation regions. The actual active region 150A can then be defined using another photolithography process, and the removed temporary active region is used as the remaining shallow groove isolation region, as shown in Figure 15c.

垂直散熱柱結構的位置、尺寸、數量並不以第14圖和第15a圖所繪示的內容為限。如上所述,對於散熱的應用,垂直散熱柱結構可以包括(或可以由下述材料所製成)高導熱率材料,例如鎢(具有約170W/mK的導熱率)、氮化硼(具有約600W/mK的導熱率)、氮化鋁(具有約321W/mK的導熱率)。也可以使用導熱率高於淺溝隔離區的原始材料(二氧化矽)的其他材料,例如碳化矽、矽鍺、未摻雜的矽或沉積鑽石。在一些實施例中,垂直散熱柱結構可以包括複合材料(或可以由複合材料所製成),此複合材料包括兩種或更多種高導熱率材料。本發明可以利用垂直散熱柱結構來取代原有淺溝隔離區中的部分二氧化矽,由於垂直散熱柱結構的材料導熱率高於二氧化矽和/或矽,從而可以提高散熱能力。The location, size, and number of vertical heat dissipation columns are not limited to those shown in Figures 14 and 15a. As mentioned above, for heat dissipation applications, the vertical heat dissipation column structure may include (or may be made of) high thermal conductivity materials, such as tungsten (with a thermal conductivity of about 170 W/mK), boron nitride (with a thermal conductivity of about 600 W/mK), and aluminum nitride (with a thermal conductivity of about 321 W/mK). Other materials with higher thermal conductivity than the original material (silicon dioxide) of the shallow groove isolation zone may also be used, such as silicon carbide, silicon germanium, undoped silicon, or deposited diamond. In some embodiments, the vertical heat dissipation column structure may include (or may be made of) a composite material comprising two or more high thermal conductivity materials. This invention can use a vertical heat dissipation column structure to replace part of the silicon dioxide in the original shallow groove isolation zone. Since the thermal conductivity of the material of the vertical heat dissipation column structure is higher than that of silicon dioxide and/or silicon, the heat dissipation capacity can be improved.

如第15a圖所繪示,用於散熱的垂直散熱柱結構,可以從電晶體所在的主動區旁邊的一些淺溝隔離區,延伸到垂直散熱柱銲墊所在的大型淺溝隔離區(例如,垂直散熱柱銲墊的面積可以介於約4平方微米至50平方微米之間)。在另一個實施例中,所有的垂直散熱柱結構可以熱耦合在一起。例如,位於大型淺溝隔離區(即垂直散熱柱銲墊)中的垂直散熱柱結構,可以熱耦合到位於淺溝隔離區中的垂直散熱柱結構(即垂直散熱柱線)。 此外,可以採用大型淺溝隔離區來與一個或多個熱通孔插塞對準,如第14b圖所繪示。此外,半導體晶片中的全部或大部分(例如超過60%,甚至70%至90%)淺溝隔離區,可以被本發明所提供的垂直散熱柱結構填充,藉以達到散熱目的。As illustrated in Figure 15a, the vertical heat dissipation pillar structure for heat dissipation can extend from some shallow groove isolation regions adjacent to the active region where the transistor is located to a large shallow groove isolation region where the vertical heat dissipation pillar pads are located (e.g., the area of the vertical heat dissipation pillar pads can be between about 4 square micrometers and 50 square micrometers). In another embodiment, all the vertical heat dissipation pillar structures can be thermally coupled together. For example, the vertical heat dissipation pillar structure located in the large shallow groove isolation region (i.e., the vertical heat dissipation pillar pad) can be thermally coupled to the vertical heat dissipation pillar structure located in the shallow groove isolation region (i.e., the vertical heat dissipation pillar line). Furthermore, a large shallow groove isolation region can be used to align with one or more thermal via plugs, as illustrated in Figure 14b. Furthermore, all or most (e.g., more than 60%, or even 70% to 90%) of the shallow groove isolation areas in the semiconductor chip can be filled by the vertical heat dissipation pillar structure provided by the present invention to achieve heat dissipation.

第16a係根據本說明書的一些實施例所繪示的半導體電路結構700的剖面示意圖。 半導體電路結構700包括位於半導體基材400上方的上方內連線結構440。上方內連線結構440包括接觸結構441、金屬層Ml至M3、連接插塞(connecting vias)Vl和V2以及介電層(或一組絕緣層)442。接觸結構441、金屬層M1至M3、連接插塞V1和V2位於可包含多個子介電層的介電層442中。接觸結構441位於電晶體TS與金屬層M1之間。金屬層M1至M3沿Z軸方向依序位於半導體基材400的原始半導體表面上方。金屬層M1至M3彼此垂直分離。連接插塞V1和V2位於半導體基材400的原始半導體表面上方。連接插塞V1位於金屬層M1與M2之間。連接插塞 V2位於金屬層M2與M3之間。金屬層M1至M3與連接插塞V1和V2彼此電性連接。Figure 16a is a schematic cross-sectional view of a semiconductor circuit structure 700 illustrated according to some embodiments of this specification. The semiconductor circuit structure 700 includes an upper interconnect structure 440 located above a semiconductor substrate 400. The upper interconnect structure 440 includes contact structures 441, metal layers M1 to M3, connecting vias V1 and V2, and a dielectric layer (or a set of insulating layers) 442. Contact structures 441, metal layers M1 to M3, and connecting vias V1 and V2 are located within a dielectric layer 442, which may contain multiple sub-dielectric layers. Contact structure 441 is located between a transistor TS and metal layer M1. Metal layers M1 to M3 are sequentially located above the original semiconductor surface of the semiconductor substrate 400 along the Z-axis. Metal layers M1 to M3 are perpendicularly separated from each other. Connecting plugs V1 and V2 are located above the original semiconductor surface of the semiconductor substrate 400. Connecting plug V1 is located between metal layers M1 and M2. Connecting plug V2 is located between metal layers M2 and M3. Metal layers M1 to M3 are electrically connected to connecting plugs V1 and V2.

半導體電路結構700還包括背面穿矽通孔插塞(TSV) 733,其位於大型淺溝隔離區424內的第二垂直散熱柱結構209 (即包括如第16a圖所繪示之複合層的垂直散熱柱銲墊)正下方,並且連接至第二垂直散熱柱結構209;包括位於穿矽通孔插塞(TSV)733側壁上的散熱膜734、位於散熱膜734側壁上的阻障或隔離膜735、位於或靠近半導體基材400背側表面400B(或晶片背面)的散熱板737,以及位於上方內連線結構440上方的頂部散熱板739。穿矽通孔插塞(TSV)733係用於散熱,可以理解為(背面)熱通孔插塞。散熱板737可以是一種散熱器,其材料可以與散熱膜734或穿矽通孔插塞(TSV)733的材料相同。穿矽通孔插塞(TSV)733從第二垂直散熱柱結構209的底表面延伸到半導體基材400的背側表面400B。穿矽通孔插塞(TSV)733連接在第二垂直散熱柱結構209和散熱板737之間,以形成包含第二垂直散熱柱結構209、穿矽通孔插塞(TSV)733和散熱板737的散熱路徑。The semiconductor circuit structure 700 also includes a back-side through-silicon via (TSV) plug 733 located directly below and connected to the second vertical heat dissipation pillar structure 209 (i.e., the vertical heat dissipation pillar pad including the composite layer as shown in Figure 16a) within the large shallow groove isolation region 424; including a heat dissipation film 734 on the sidewall of the through-silicon via plug (TSV) 733, a barrier or isolation film 735 on the sidewall of the heat dissipation film 734, a heat dissipation plate 737 located on or near the back surface 400B of the semiconductor substrate 400 (or the back side of the wafer), and a top heat dissipation plate 739 located above the upper interconnect structure 440. The through-silicon via (TSV) 733 is used for heat dissipation and can be understood as a (backside) heat via plug. The heatsink 737 can be a heatsink made of the same material as the heatsink film 734 or the through-silicon via (TSV) 733. The through-silicon via (TSV) 733 extends from the bottom surface of the second vertical heatsink structure 209 to the back surface 400B of the semiconductor substrate 400. The through-silicon via (TSV) 733 connects the second vertical heatsink structure 209 and the heatsink 737 to form a heat dissipation path including the second vertical heatsink structure 209, the through-silicon via (TSV) 733, and the heatsink 737.

為了散熱,本實施例中的垂直散熱柱結構可以包括導熱率高於二氧化矽之導熱率的材料(或可以由導熱率高於二氧化矽的導熱率的材料所製成)。例如,垂直散熱柱結構可以包括鎢、銅、氮化硼、氮化鋁、碳化矽、矽鍺、或沉積鑽石、未摻雜的矽、或上述材料的任意組合。在一些實施例中,垂直散熱柱結構包括導熱率高於矽之導熱率的隔離材料。穿矽通孔插塞(TSV)733可以包括銅,散熱膜734可以是氮化硼或氮化鋁。For heat dissipation, the vertical heat dissipation column structure in this embodiment may include a material with a thermal conductivity higher than that of silicon dioxide (or may be made of a material with a thermal conductivity higher than that of silicon dioxide). For example, the vertical heat dissipation column structure may include tungsten, copper, boron nitride, aluminum nitride, silicon carbide, silicon germanium, or deposited diamond, undoped silicon, or any combination of the above materials. In some embodiments, the vertical heat dissipation column structure includes a insulating material with a thermal conductivity higher than that of silicon. The through-silicon via plug (TSV) 733 may include copper, and the heat dissipation film 734 may be boron nitride or aluminum nitride.

此外,穿矽通孔插塞(TSV)733直接連接到第二垂直散熱柱結構209,然後第二垂直散熱柱結構209連接到位於淺溝隔離區414中的第一垂直散熱柱結構205 (即包含如第16a圖所繪示的複合層的垂直散熱柱線)。第一垂直散熱柱結構205也可以透過對應的連接插塞431與電晶體(例如電晶體的源極/汲極區)連接。這樣,電晶體產生的熱量可以透過連接插塞431、第一垂直散熱柱結構205和第二垂直散熱柱結構209散發到穿矽通孔插塞(TSV)733,從而提供了一種高散熱效率的垂直散熱柱散熱網路。在另一實施例中,垂直散熱柱結構可以與電晶體隔離,但可以透過垂直散熱柱線、垂直散熱柱銲墊和穿矽通孔插塞(TSV)733來達到散熱目的。Furthermore, the through-silicon via (TSV) 733 is directly connected to the second vertical heat dissipation pillar structure 209, which in turn is connected to the first vertical heat dissipation pillar structure 205 (i.e., the vertical heat dissipation pillar containing the composite layer as shown in Figure 16a) located in the shallow groove isolation region 414. The first vertical heat dissipation pillar structure 205 can also be connected to the transistor (e.g., the source/drain region of the transistor) via a corresponding connecting plug 431. In this way, the heat generated by the transistor can be dissipated to the through-silicon via (TSV) 733 through the connecting plug 431, the first vertical heat dissipation pillar structure 205, and the second vertical heat dissipation pillar structure 209, thereby providing a vertical heat dissipation pillar heat dissipation network with high heat dissipation efficiency. In another embodiment, the vertical heat dissipation pillar structure can be isolated from the transistor, but can achieve heat dissipation through the vertical heat dissipation pillar lines, vertical heat dissipation pillar pads, and through-silicon via plugs (TSV) 733.

位於淺溝隔離區414內部並沿著淺溝隔離區414延伸的垂直散熱柱結構205,可以透過自對準或自構造的方法(self-aligned or self-constructed method)通過位於電晶體主動區內的連接插塞431連接至電晶體的源極端或汲極端。連接插塞431係連接至垂直散熱柱結構的側壁。The vertical heat dissipation pillar structure 205, located within and extending along the shallow groove isolation region 414, can be connected to the source or drain terminal of the transistor via a connection plug 431 located within the transistor's active region using a self-aligned or self-constructed method. The connection plug 431 is connected to the sidewall of the vertical heat dissipation pillar structure.

傳統的半導體電路結構僅包括上方內連線結構440中的上方熱通孔插塞,且不包括垂直散熱柱結構,尤其是不包括垂直散熱柱銲墊。因此,上方熱通孔插塞的對齊是一個關鍵問題。此外,傳統半導體電路結構的上方熱通孔插塞僅位於上方內連線結構440的介電層442內部,並被上方內連線結構440的介電層442所隔離,且這些上方熱通孔插塞遠離電晶體。因此,電晶體產生的熱量難以有效散發。本說明書所提供的半導體電路結構即通過垂直散熱柱銲墊的幫助,可以為熱通孔插塞提供更大的對準窗口。此外,藉由垂直散熱柱結構,使熱通孔插塞與電晶體的源極/汲極端之間的熱耦合路徑更短。 因此,藉由本說明書的配置可以有效地散發從電晶體產生的熱量。Traditional semiconductor circuit structures only include upper thermal via plugs in the upper interconnect structure 440, and do not include vertical heat dissipation pillar structures, especially vertical heat dissipation pillar pads. Therefore, the alignment of the upper thermal via plugs is a critical issue. Furthermore, in traditional semiconductor circuit structures, the upper thermal via plugs are located only inside the dielectric layer 442 of the upper interconnect structure 440 and are isolated by the dielectric layer 442 of the upper interconnect structure 440, and these upper thermal via plugs are far from the transistor. Therefore, the heat generated by the transistor is difficult to dissipate effectively. The semiconductor circuit structure provided in this specification provides a larger alignment window for the thermal via plugs with the help of vertical heat dissipation pillar pads. Furthermore, the vertical heat dissipation pillar structure shortens the thermal coupling path between the heat through-hole plug and the source/drain terminals of the transistor. Therefore, the configuration in this manual effectively dissipates the heat generated by the transistor.

第16b圖係根據本說明書的一些實施例所繪示的半導體電路結構800剖面示意圖。半導體電路結構800包括位於上方內連線結構440的介電層442內部的上方或頂側熱通孔插塞833。上方熱通孔插塞833從第二垂直散熱柱結構209的上表面向上延伸至頂部散熱板739並穿透上方內連線結構440的介電層442。Figure 16b is a schematic cross-sectional view of a semiconductor circuit structure 800 illustrated according to some embodiments of this specification. The semiconductor circuit structure 800 includes an upper or top thermal via plug 833 located inside the dielectric layer 442 of the upper interconnect structure 440. The upper thermal via plug 833 extends upward from the upper surface of the second vertical heat dissipation pillar structure 209 to the top heat dissipation plate 739 and penetrates the dielectric layer 442 of the upper interconnect structure 440.

因此,上方熱通孔插塞833連接到第二垂直散熱柱結構209(即位於淺溝隔離區424中的垂直散熱柱銲墊),然後第二垂直散熱柱結構209連接到第一垂直散熱柱結構205(即位於淺溝隔離區414中的垂直散熱柱線)。第一垂直散熱柱結構205通過對應的連接插塞431連接至電晶體(例如,電晶體的源極/汲極區)。因此,頂部散熱板739、上方熱通孔插塞833、第一垂直散熱柱結構205和第二垂直散熱柱結構209可以形成散熱路徑以發散電晶體所產生的熱。這樣,電晶體產生的熱量可以通過連接插塞431、第一垂直散熱柱結構205和第二垂直散熱柱結構209消散到上方熱通孔插塞833。根據本說明書所提供的熱直接冷卻技術,提供了一種高散熱效率的垂直散熱柱散熱網路。在另一個實施例中,即使垂直散熱柱結構205(即位於淺溝隔離區414中的垂直散熱柱線)與電晶體隔離,仍可達到散熱的目的。在其他實施例中,上方熱通孔插塞833可以從上方內連線結構440的上表面延伸到第一垂直散熱柱結構205。進一步地,構成上方熱通孔插塞833的材料可以是導熱係數高於矽或二氧化矽的Z材料,例如,銅。構成上方熱通孔插塞833的材料可以與構成頂部散熱板739的材料相同或不同。Therefore, the upper heat through-hole plug 833 is connected to the second vertical heat dissipation pillar structure 209 (i.e., the vertical heat dissipation pillar washer located in the shallow groove isolation region 424), and then the second vertical heat dissipation pillar structure 209 is connected to the first vertical heat dissipation pillar structure 205 (i.e., the vertical heat dissipation pillar located in the shallow groove isolation region 414). The first vertical heat dissipation pillar structure 205 is connected to the transistor (e.g., the source/drain region of the transistor) via a corresponding connecting plug 431. Thus, the top heat dissipation plate 739, the upper heat through-hole plug 833, the first vertical heat dissipation pillar structure 205, and the second vertical heat dissipation pillar structure 209 can form a heat dissipation path to dissipate the heat generated by the transistor. In this way, the heat generated by the transistor can be dissipated to the upper heat-through-hole plug 833 through the connecting plug 431, the first vertical heat-dissipating pillar structure 205, and the second vertical heat-dissipating pillar structure 209. A high-efficiency vertical heat-dissipating pillar heat dissipation network is provided according to the direct heat cooling technology provided in this specification. In another embodiment, heat dissipation can still be achieved even when the vertical heat-dissipating pillar structure 205 (i.e., the vertical heat-dissipating pillars located in the shallow groove isolation region 414) is isolated from the transistor. In other embodiments, the upper heat-through-hole plug 833 can extend from the upper surface of the upper interconnect structure 440 to the first vertical heat-dissipating pillar structure 205. Furthermore, the material constituting the upper heat-through-hole plug 833 can be a Z material with a thermal conductivity higher than silicon or silicon dioxide, such as copper. The material constituting the upper heat vent plug 833 may be the same as or different from the material constituting the top heat sink 739.

第16c圖係根據本說明書的一些實施例所繪示的半導體電路結構900剖面示意圖。第16c圖所繪示的半導體電路結構900與第16b圖所繪示的半導體電路結構800的差異在於,半導體電路結構900包括位於上方熱通孔插塞833側壁上的上方散熱膜934。上方散熱膜934可以包括導熱率高於矽或二氧化矽的Z材料 的材料,例如氮化硼或氮化鋁(或可以由該材料所製成)。在上方熱通孔插塞833上設置上方散熱膜934可以提高散熱效率。Figure 16c is a schematic cross-sectional view of a semiconductor circuit structure 900 illustrated according to some embodiments of this specification. The difference between the semiconductor circuit structure 900 shown in Figure 16c and the semiconductor circuit structure 800 shown in Figure 16b is that the semiconductor circuit structure 900 includes an upper heat dissipation film 934 located on the sidewall of the upper heat port plug 833. The upper heat dissipation film 934 may comprise a material with a thermal conductivity higher than silicon or silicon dioxide, such as boron nitride or aluminum nitride (or may be made of such material). Providing the upper heat dissipation film 934 on the upper heat port plug 833 can improve heat dissipation efficiency.

在一些實施例中,第16a圖所繪示的穿矽通孔插塞(TSV)733與第16b圖所繪示的上方熱通孔插塞833 (或第16c圖所繪示的上方散熱膜934和上方熱通孔插塞833)可以組合在一起,如第16d圖所繪示。一些上方熱通孔插塞833從上方內連線結構440的上表面延伸至第二垂直散熱柱結構209,並連接至頂部散熱板739。穿矽通孔插塞(TSV)733 (額外的熱通孔插塞)從半導體基材400的背側表面400B延伸到第二垂直散熱柱結構209(或其他垂直散熱柱結構),並且連接到位於半導體基材400背側表面400B上方或附近的散熱板737。這種三明治夾層結構(晶片內的中間垂直散熱柱結構、與中間垂直散熱柱結構連接的頂部散熱板,以及位於半導體基材背側表面並與中間垂直散熱柱結構連接的散熱板)可以大大提高IC晶片的散熱能力。In some embodiments, the through-silicon via (TSV) plug 733 illustrated in Figure 16a and the upper heat via plug 833 illustrated in Figure 16b (or the upper heat dissipation film 934 and upper heat via plug 833 illustrated in Figure 16c) may be combined together, as illustrated in Figure 16d. Some of the upper heat via plugs 833 extend from the upper surface of the upper interconnect structure 440 to the second vertical heat dissipation pillar structure 209 and are connected to the top heat dissipation plate 739. The through-silicon via plug (TSV) 733 (an additional heat via plug) extends from the back surface 400B of the semiconductor substrate 400 to the second vertical heat dissipation pillar structure 209 (or other vertical heat dissipation pillar structure) and is connected to the heat dissipation plate 737 located above or near the back surface 400B of the semiconductor substrate 400. This sandwich structure (a central vertical heat dissipation pillar structure within the chip, a top heat dissipation plate connected to the central vertical heat dissipation pillar structure, and a heat dissipation plate located on the back surface of the semiconductor substrate and connected to the central vertical heat dissipation pillar structure) can greatly improve the heat dissipation capability of IC chips.

先進的2.5代(2.5D)或第3代(3D)封裝結構,甚至是高頻寬記憶體(HBM)結構,都有兩個或多個IC/記憶體晶片堆疊在一起。因此,第16a圖至第16d圖所繪示的任何結構都可以應用於這些垂直堆疊在一起的IC晶片中。例如,如第16e圖所示,第16e圖中所繪示的垂直散熱柱結構可以應用於垂直堆疊在一起的晶片C1和晶片C2中。在另一實施例中,晶片C1(具有第16b圖中所繪示的垂直散熱柱結構)可以先翻轉,然後再堆疊在晶片C2(具有第16d圖中所繪示的垂直散熱柱結構)之上,如第16f圖所示。當然,可以在這兩個IC晶片之間設置另一個中介層(例如矽中介層或其他中介層),且第16a圖至第16d圖所繪示的任何結構都可以應用於用於中介層中。Advanced 2.5D or 3D package structures, and even high-bandwidth memory (HBM) structures, involve stacking two or more IC/memory chips together. Therefore, any structure illustrated in Figures 16a through 16d can be applied to these vertically stacked IC chips. For example, as shown in Figure 16e, the vertical heat pillar structure illustrated in Figure 16e can be applied to vertically stacked chips C1 and C2. In another embodiment, chip C1 (having the vertical heat pillar structure illustrated in Figure 16b) can be flipped and then stacked on top of chip C2 (having the vertical heat pillar structure illustrated in Figure 16d), as shown in Figure 16f. Of course, another interposer (such as a silicon interposer or other interposer) can be placed between these two IC chips, and any structure shown in Figures 16a to 16d can be applied to the interposer.

第17a圖係繪示具有鰭式場效電晶體和鄰近(或圍繞)鰭式場效電晶體之淺溝隔離區的半導體電路結構,其中有一部分的淺溝隔離區(由斜線標記)被由鎢所製成的垂直散熱柱結構取代。第17a圖更繪示由TCAD模擬軟體Sentaurus所建立的鰭式場效電晶體的溫度分佈圖。當一部分的淺溝隔離區被鎢所取代時,計算電晶體峰值溫度(熱點區域)與環境溫度(40℃)之間的溫差(∆T),如第17b圖更繪示。第17b圖中所述的用語「完全」表示所有的淺溝隔離區都未被鎢所取代。用語「1nm」至「15nm」表示淺溝隔離區尚未被鎢所取代的剩餘厚度。可明顯看出,淺溝隔離區的剩餘厚度越小,電晶體的峰值溫度與環境溫度的溫差越小(散熱性能越好)。因此,本發明可以有效地降低電晶體的峰值溫度。Figure 17a illustrates a semiconductor circuit structure with a finned field-effect transistor and shallow groove isolation regions adjacent to (or surrounding) the finned field-effect transistor, where a portion of the shallow groove isolation regions (marked by diagonal lines) is replaced by vertical heat dissipation pillars made of tungsten. Figure 17a further illustrates the temperature distribution of the finned field-effect transistor, generated by the TCAD simulation software Sentaurus. When a portion of the shallow groove isolation regions is replaced by tungsten, the temperature difference (∆T) between the transistor peak temperature (hot spot region) and the ambient temperature (40°C) is calculated, as further illustrated in Figure 17b. The term "completely" used in Figure 17b indicates that all shallow groove isolation regions are not replaced by tungsten. The terms "1nm" to "15nm" refer to the remaining thickness of the shallow groove isolation region before it is replaced by tungsten. It is clear that the smaller the remaining thickness of the shallow groove isolation region, the smaller the temperature difference between the transistor's peak temperature and the ambient temperature (the better the heat dissipation performance). Therefore, this invention can effectively reduce the peak temperature of the transistor.

本說明書提供了一種以複合材料淺溝隔離區為基底的直接晶粒冷卻技術(或稱排熱結構,例如位於原始半導體表面下方和淺溝隔離區內的垂直散熱柱線和垂直散熱柱銲墊)。根據需要,一些垂直散熱柱結構可以連接到電晶體,並且散熱結構可以在晶片或半導體基材內形成垂直散熱柱網格或散熱網絡。由於大型淺溝隔離區有足夠的空間容納垂直散熱柱銲墊,可提供更大的未對準容差,並縮短將背面穿矽通孔插塞(TSV)連接到垂直散熱柱網格的路徑,進而改善訊號傳輸的IR壓降(IR drop),並增強散熱效能。This specification provides a direct grain cooling technique (or heat dissipation structure, such as vertical heat dissipation pillars and vertical heat dissipation pillar pads located below the original semiconductor surface and within the shallow groove isolation region) based on a composite material shallow groove isolation region. Depending on requirements, some vertical heat dissipation pillar structures can be connected to the transistor, and the heat dissipation structure can be formed into a vertical heat dissipation pillar grid or heat dissipation network within the wafer or semiconductor substrate. Because the large shallow groove isolation region provides sufficient space to accommodate the vertical heat dissipation pillar pads, it offers greater misalignment tolerance and shortens the path for connecting back-side through-silicon via (TSV) plugs to the vertical heat dissipation pillar grid, thereby improving IR drop in signal transmission and enhancing heat dissipation performance.

值得注意的是,提供上述結構和方法僅係用於說明例示本發明的技術特徵。本說明書的技術內容並不限於上述結構和方法。可以應用具有配置不同已知元件的其他實施例。所例示的結構可以根據實際應用的需求進行調整和變更。當然,需要注意的是,所附圖示的配置僅用於例示,而非用以限制本發明。因此,本領域中具有通常知識者可知,半導體結構中的相關元件和層、元件的形狀或位置關係及製程細節,可以根據實際需要和/或實際應用進行調整或變更。It is worth noting that the above structures and methods are provided only to illustrate the technical features of the present invention. The technical content of this specification is not limited to the above structures and methods. Other embodiments with different configurations of known components can be applied. The illustrated structures can be adjusted and modified according to the needs of actual applications. Of course, it should be noted that the configurations shown in the accompanying figures are for illustration only and are not intended to limit the present invention. Therefore, those skilled in the art will understand that the relevant components and layers in a semiconductor structure, the shape or positional relationship of the components, and the process details can be adjusted or modified according to actual needs and/or actual applications.

雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何該技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed above with reference to preferred embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the art may make some modifications and refinements without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be determined by the appended patent claims.

101:墊氧化矽薄層 102:第一墊氮化矽層 103:主動區 201:淺溝隔離區 301:第二墊氮化矽層 401:矽氧化物薄層 403:第三墊氮化矽層 601:鏤空隧道區 701:矽氧化物層 702:Z材料 801:矽氧化物 1101:閘極金屬區 1102:高介電係數介電層 1103:源極區 1104:汲極區 200:半導體電路結構 205:垂直散熱柱結構 209:垂直散熱柱結構 214:水平淺溝隔離區 214-1至214-4:淺溝隔離區 220A-1主動區 220A:主動區 220B:淺溝隔離區 220C:銲墊開口層 224:大型淺溝隔離區 224-1至224-4:大型淺溝隔離區 300:半導體電路結構 314-1、314-2、314-3:淺溝隔離區 305-1、305-2、305-3:垂直散熱柱結構 400:半導體基材 400B:背側表面 414:淺溝隔離區 424:大型淺溝隔離區 431:連接插塞 440:上方內連線結構 441:接觸結構 442:介電層 700:半導體電路結構 733:穿矽通孔插塞 734:散熱膜 735:阻障或隔離膜 737:散熱板 739:頂部散熱板 800:半導體電路結構 833:上方熱通孔插塞 900:半導體電路結構 934:上方散熱膜 12c:切線 6b-6b’:切線 6c-6c’:切線 OSS:原始半導體表面 t1:深度 t2:深度 t3:厚度 Ml-M3:金屬層 Vl、V2:連接插塞 C1、C2:晶片101: Silicon oxide thin layer 102: First silicon nitride thin layer 103: Active region 201: Shallow groove isolation region 301: Second silicon nitride thin layer 401: Silicon oxide thin layer 403: Third silicon nitride thin layer 601: Hollow tunnel region 701: Silicon oxide layer 702: Z material 801: Silicon oxide 1101: Gate metal region 1102: High dielectric constant dielectric layer 1103: Source region 1104: Drain region 200: Semiconductor circuit structure 205: Vertical heat dissipation pillar structure 209: Vertical heat dissipation pillar structure 214: Horizontal shallow groove isolation area; 214-1 to 214-4: Shallow groove isolation area; 220A-1: Active area; 220A: Active area; 220B: Shallow groove isolation area; 220C: Solder pad opening layer; 224: Large shallow groove isolation area; 224-1 to 224-4: Large shallow groove isolation area; 300: Semiconductor circuit structure; 314-1, 314-2, 314-3: Shallow groove isolation area; 305-1, 305-2, 305-3: Vertical heat dissipation pillar structure; 400: Semiconductor substrate; 400B: Back side surface; 414: Shallow groove isolation area. 424: Large shallow groove isolation area; 431: Connector plug; 440: Upper internal interconnect structure; 441: Contact structure; 442: Dielectric layer; 700: Semiconductor circuit structure; 733: Through-silicon via plug; 734: Heat dissipation film; 735: Barrier or isolation film; 737: Heat dissipation plate; 739: Top heat dissipation plate; 800: Semiconductor circuit structure; 833: Upper heat via plug; 900: Semiconductor circuit structure; 934: Upper heat dissipation film; 12c: Tangent; 6b-6b’: Tangent; 6c-6c’: Tangent; OSS: Raw semiconductor surface; t1: Depth; t2: Depth; t3: Thickness; M1-M3: Metal layer; V1, V2: Connector plug; C1, C2: Wafer.

第1a圖係繪示具有淺溝隔離區和主動區的傳統半導體電路結構的結構俯視圖;第 1b圖係繪示第1a圖部分區域的結構俯視圖;第1c圖係繪示第1a圖的結構剖面示意圖; 第2圖 (包括第2a圖和第2b圖) 係分別繪示在形成主動區和淺溝隔離區之後的製程結構俯視圖和剖面示意圖; 第3圖 (包括第3a圖和第3b圖) 係分別繪示在主動區在中心上方形成氮化物保護區之後的製程結構俯視圖和剖面示意圖; 第4圖 (包括第4a圖和第4b圖) 係分別繪示在形成垂直間隙壁以覆蓋暴露的矽側壁之後的製程結構俯視圖和剖面示意圖; 第5圖 (包括第5a圖和第5b圖) 係分別繪示在將更深的矽側壁暴露於外之後的製程結構俯視圖和剖面示意圖; 第6圖 (包括第6a圖、第6b圖和第6c圖) 係分別繪示在形鏤空隧道區(vacant tunnel regions)之後的的製程結構俯視圖和二個區域的結構剖面示意圖; 第7圖 (包括第7a圖和第7b圖) 係分別繪示在沉積高散熱材料(high thermal dissipation material)之後的製程結構俯視圖和剖面示意圖; 第8圖 (包括第8a圖和第8b圖) 係分別繪示在形成水平散熱板(Horizontal Heat-Dissipation Plate,HHDP)和垂直散熱柱(Vertical Heat-Dissipation Column,VHDC) 之後的製程結構俯視圖和剖面示意圖; 第9圖 (包括第9a圖和第9b圖) 係根據另一實施例,分別繪示在形成水平散熱板和垂直散熱柱之後的製程結構俯視圖和剖面示意圖; 第10圖係繪示在將水平散熱板和垂直散熱柱連接並延伸至晶片/晶粒邊緣之後的結構示意圖; 第11圖係根據本發明所繪示的電晶體冷卻(Cool Transistor,CQT)結構示意圖; 第12a圖和第12b圖係根據本發明不同實施例所繪示的垂直散熱柱結構剖面示意圖;第12c圖係根據另一實施例繪示將第12b圖所示垂直散熱柱延伸到晶片/晶粒邊緣之後的結構示意圖; 第13圖係根據第12b圖所繪示的另一種電晶體冷卻結構示意圖; 第14a圖係根據本說明書的一些實施例所繪示的半導體電路結構俯視圖; 第14b圖係根據本說明書的另一些實施例所繪示的半導體電路結構俯視圖; 第15a圖係根據本說明書的一些實施例所繪示的半導體電路結構俯視圖;第15b圖至第15c圖係繪示在製作第15a圖之半導體電路結構的不同階段中的製程結構俯視圖; 第16a圖至第16f圖係根據本說明書的一些實施例所繪示的不同半導體電路結構剖面示意圖; 第17a圖係繪示由TCAD模擬軟體Sentaurus所建立的鰭式場效電晶體(FinFET)的溫度分佈圖;以及 第17b圖係繪示溫差與淺溝隔離區之厚度的關係圖。Figure 1a is a top view of a conventional semiconductor circuit structure with shallow groove isolation regions and active regions; Figure 1b is a top view of a portion of the structure in Figure 1a; Figure 1c is a cross-sectional view of the structure in Figure 1a; Figure 2 (including Figures 2a and 2b) are top and cross-sectional views of the fabrication structure after the formation of the active regions and shallow groove isolation regions, respectively; Figure 3 (including Figures 3a and 3b) are top and cross-sectional views of the fabrication structure after the formation of a nitride protection region above the center of the active region, respectively; Figure 4 (including Figures 4a and 4b) are top and cross-sectional views of the fabrication structure after the formation of vertical gap walls to cover the exposed silicon sidewalls, respectively; Figure 5 Figures 5a and 5b (including Figures 5a and 5b) show the top view and cross-sectional view of the process structure after the deeper silicon sidewalls are exposed, respectively; Figure 6 (including Figures 6a, 6b, and 6c) shows the top view and cross-sectional view of the process structure after the vacant tunnel regions are formed, respectively; Figure 7 (including Figures 7a and 7b) shows the top view and cross-sectional view of the process structure after the high thermal dissipation material is deposited, respectively; Figure 8 (including Figures 8a and 8b) shows the formation of the Horizontal Heat-Dissipation Plate (HHDP) and the Vertical Heat-Dissipation Column (VHDC), respectively. The following are top and cross-sectional views of the manufacturing process structure; Figure 9 (including Figures 9a and 9b) is a top and cross-sectional view of the manufacturing process structure after the formation of the horizontal heat dissipation plate and the vertical heat dissipation pillar, respectively, according to another embodiment; Figure 10 is a structural diagram after the horizontal heat dissipation plate and the vertical heat dissipation pillar are connected and extended to the edge of the wafer/die; Figure 11 is a structural diagram of a cool transistor (CQT) according to the present invention; Figures 12a and 12b are cross-sectional views of the vertical heat dissipation pillar structure according to different embodiments of the present invention; Figure 12c is a structural diagram after the vertical heat dissipation pillar shown in Figure 12b is extended to the edge of the wafer/die, according to another embodiment. Figure 13 is a schematic diagram of another transistor cooling structure illustrated in Figure 12b; Figure 14a is a top view of a semiconductor circuit structure illustrated in some embodiments of this specification; Figure 14b is a top view of a semiconductor circuit structure illustrated in some embodiments of this specification; Figure 15a is a top view of a semiconductor circuit structure illustrated in some embodiments of this specification; Figures 15b to 15c are top views of the fabrication structure at different stages of fabricating the semiconductor circuit structure of Figure 15a; Figures 16a to 16f are schematic cross-sectional views of different semiconductor circuit structures illustrated in some embodiments of this specification; Figure 17a shows the temperature distribution of a finned field-effect transistor (FinFET) created by the TCAD simulation software Sentaurus; and Figure 17b shows the relationship between temperature difference and the thickness of the shallow groove isolation region.

101:墊氧化矽薄層 102:第一墊氮化矽層 201:淺溝隔離區 401:矽氧化物薄層 801:矽氧化物 701:矽氧化物層 702:Z材料 t2:深度 t3:厚度101: Silicon oxide thin layer; 102: First silicon nitride layer; 201: Shallow groove isolation region; 401: Silicon oxide thin layer; 801: Silicon oxide; 701: Silicon oxide layer; 702: Z material; t2: Depth; t3: Thickness

Claims (23)

一種半導體電路結構,包括: 一半導體基材,具有一原始半導體表面(original semiconductor surface,OSS); 一組主動區,位於半導體基材中;以及 一第一淺溝隔離區(STI),鄰接該組主動區,並沿著一第一方向延伸至一備用淺溝隔離區(spare STI region);該備用淺溝隔離區遠離該組主動區; 其中,該第一淺溝隔離區包括一排熱層(heat removing layer),且該排熱層的材料不同於二氧化矽(SiO2)。A semiconductor circuit structure includes: a semiconductor substrate having an original semiconductor surface (OSS); a set of active regions located in the semiconductor substrate; and a first shallow groove isolation region (STI) adjacent to the set of active regions and extending along a first direction to a spare shallow groove isolation region; the spare shallow groove isolation region being remote from the set of active regions; wherein the first shallow groove isolation region includes a heat removing layer, and the material of the heat removing layer is different from silicon dioxide ( SiO2 ). 如請求項1所述之半導體電路結構,其中該排熱層的一導熱率高於二氧化矽的一導熱率。The semiconductor circuit structure as described in claim 1, wherein the thermal conductivity of the heat dissipation layer is higher than that of silicon dioxide. 如請求項2所述之半導體電路結構,其中該排熱層在該半導體電路結構的一操作期間是一電性絕緣體。The semiconductor circuit structure as described in claim 2, wherein the heat dissipation layer is an electrical insulator during an operation of the semiconductor circuit structure. 如請求項2所述之半導體電路結構,其中該排熱層延伸進入該組主動區之一者中。The semiconductor circuit structure as described in claim 2, wherein the heat dissipation layer extends into one of the active regions of the group. 如請求項2所述之半導體電路結構,其中該排熱層包括一金屬層和一絕緣薄層,該絕緣薄層位於該金屬層和該組主動區之間。The semiconductor circuit structure as described in claim 2, wherein the heat dissipation layer includes a metal layer and an insulating thin layer located between the metal layer and the set of active regions. 如請求項2所述之半導體電路結構,其中該排熱層包括一複合材料。The semiconductor circuit structure as described in claim 2, wherein the heat dissipation layer comprises a composite material. 如請求項2所述之半導體電路結構,其中該第一淺溝隔離區更包括位於該排熱層下方的一二氧化矽層。The semiconductor circuit structure as described in claim 2, wherein the first shallow groove isolation region further includes a silicon dioxide layer located below the heat dissipation layer. 如請求項1所述之半導體電路結構,其中該排熱層位於該半導體電路結構的一前端製程(front end of line ,FEOL)區內。The semiconductor circuit structure as described in claim 1, wherein the heat dissipation layer is located within a front end of line (FEOL) region of the semiconductor circuit structure. 如請求項1所述之半導體電路結構,其中該第一淺溝隔離區圍繞該組主動區。The semiconductor circuit structure as described in claim 1, wherein the first shallow groove isolation region surrounds the set of active regions. 如請求項9所述之半導體電路結構,其中該排熱層位於該第一淺溝隔離區中,且位於該原始半導體表面下方,且該排熱層圍繞該組主動區的一外圍邊界(peripheral border)。The semiconductor circuit structure as described in claim 9, wherein the heat dissipation layer is located in the first shallow groove isolation region and below the original semiconductor surface, and the heat dissipation layer surrounds a peripheral border of the set of active regions. 如請求項1所述之半導體電路結構,其中該備用淺溝隔離區連接至該第一淺溝隔離區,且該排熱層沿著該第一方向延伸至該備用淺溝隔離區。The semiconductor circuit structure as described in claim 1, wherein the backup shallow groove isolation region is connected to the first shallow groove isolation region, and the heat dissipation layer extends to the backup shallow groove isolation region along the first direction. 如請求項11所述之半導體電路結構,其中該備用淺溝隔離區靠近該半導體基材的一中心,或靠近該半導體基材的一邊緣部分。The semiconductor circuit structure as described in claim 11, wherein the backup shallow groove isolation region is located near a center of the semiconductor substrate or near a peripheral portion of the semiconductor substrate. 如請求項11所述之半導體電路結構,更包括一排熱銲墊(heat removing pad)位於該備用淺溝隔離區內,且該排熱層連接至該排熱銲墊。The semiconductor circuit structure as described in claim 11 further includes a row of heat removing pads located within the backup shallow groove isolation area, and the heat removal layer is connected to the row of heat removing pads. 如請求項13所述之半導體電路結構,更包括一熱通孔插塞(thermal via)位於備用該淺溝隔離區上方,並連接至位於該備用淺溝隔離區內的該排熱銲墊。The semiconductor circuit structure as described in claim 13 further includes a thermal via located above the standby shallow groove isolation area and connected to the heat sink located within the standby shallow groove isolation area. 如請求項14所述之半導體電路結構,更包括一散熱板(heat dissipation plate)位於該熱通孔插塞上方並連接至該熱通孔插塞。The semiconductor circuit structure as described in claim 14 further includes a heat dissipation plate located above and connected to the heat via plug. 如請求項14所述之半導體電路結構,更包括複數個絕緣體,位於該組主動區​​上方,其中該熱通孔插塞穿透該複數個絕緣體並連接至位於該備用淺溝隔離區中的該排熱銲墊。The semiconductor circuit structure as described in claim 14 further includes a plurality of insulators located above the set of active regions, wherein the thermal via plug penetrates the plurality of insulators and is connected to the row of thermally soldered pads located in the backup shallow groove isolation region. 如請求項16所述之半導體電路結構,其中該複數個絕緣體和該熱通孔插塞位於該半導體電路結構的一後端製程(back end of line,BEOL)區內。The semiconductor circuit structure as described in claim 16, wherein the plurality of insulators and the thermal via plug are located within a back end of line (BEOL) region of the semiconductor circuit structure. 如請求項13所述之半導體電路結構,更包括一半導體通孔插塞(through semiconductor via,TSV)從該半導體基材的一背側表面延伸至位於該備用淺溝隔離區內的該排熱銲墊的一底表面,其中該背側表面與該原始半導體表面分別位於相反二側。The semiconductor circuit structure as described in claim 13 further includes a through semiconductor via (TSV) extending from a back surface of the semiconductor substrate to a bottom surface of the heat sink located within the spare shallow groove isolation area, wherein the back surface and the original semiconductor surface are located on opposite sides. 如請求項18所述之半導體電路結構,更包括一散熱板,位於該半導體基材的該背側表面下方,並連接至該半導體通孔插塞。The semiconductor circuit structure as described in claim 18 further includes a heat dissipation plate located below the back surface of the semiconductor substrate and connected to the semiconductor via plug. 如請求項18所述之半導體電路結構,該第一淺溝隔離區圍繞該組主動區之一者的四個側壁。As described in claim 18, the first shallow groove isolation region surrounds the four sidewalls of one of the active regions. 一半導體電路結構,包括: 一半導體基材,具有一原始半導體表面; 一第一組主動區,位於該半導體基材中,並沿著一第一方向延伸; 一第二組主動區,位於該半導體基材中,並沿著該第一方向延伸;以及 一第一淺溝隔離區,位於該第一組主動區與該第二組主動區之間,沿著第一方向延伸至遠離該第一組主動區和該第二組主動區的一備用淺溝隔離區; 其中,該第一淺溝隔離區包括沿著該第一方向延伸的一排熱層,且該排熱層的一導熱率高於二氧化矽的一導熱率。A semiconductor circuit structure includes: a semiconductor substrate having a raw semiconductor surface; a first set of active regions located in the semiconductor substrate and extending along a first direction; a second set of active regions located in the semiconductor substrate and extending along the first direction; and a first shallow groove isolation region located between the first set of active regions and the second set of active regions, extending along the first direction to a backup shallow groove isolation region away from the first set of active regions and the second set of active regions; wherein the first shallow groove isolation region includes a row of heat-dissipating layers extending along the first direction, and the thermal conductivity of the heat-dissipating layers is higher than that of silicon dioxide. 如請求項21所述之半導體電路結構,其中該備用淺溝隔離區連接到該第一淺溝隔離區,並且包括位於該備用淺溝隔離區中的一排熱銲墊,其中該排熱層連接至該排熱銲墊。The semiconductor circuit structure as described in claim 21, wherein the backup shallow groove isolation region is connected to the first shallow groove isolation region, and includes a row of hot solder pads located in the backup shallow groove isolation region, wherein the row of hot solder pads is connected to the row of hot solder pads. 如請求項22所述之半導體電路結構,其中該排熱銲墊的一寬度大於該排熱層的一寬度。The semiconductor circuit structure as described in claim 22, wherein the width of the heat sink is greater than the width of the heat sink layer.
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