TWI892299B - Thermoplastic composite induction welding method and monocoque structure manufacturing method - Google Patents
Thermoplastic composite induction welding method and monocoque structure manufacturing methodInfo
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Abstract
Description
本發明是有關於一種熱塑性纖維複合材料的感應銲接方法,且特別是有關於一種利用熱塑性纖維複合材料的感應銲接方法的硬殼式中空結構體的製造方法。The present invention relates to a method for induction welding of thermoplastic fiber composite materials, and more particularly to a method for manufacturing a hard-shell hollow structure using the induction welding method of thermoplastic fiber composite materials.
碳纖維複材等熱塑性纖維複合材料,具有可回收利用、高溫使用性能佳及抗衝擊韌性高等優勢,因此,被大量使用於自行車及航空等產業,使成為低成本化和高性能化的重要方向。Thermoplastic fiber composites, such as carbon fiber composites, have advantages such as recyclability, excellent high-temperature performance, and high impact toughness. Therefore, they are widely used in industries such as bicycles and aviation, making them an important direction for low-cost and high-performance.
目前,熱塑性複合材料常用的幾種銲接技術中,感應銲接(Induction Welding)由於具有成本低、可連續自動化及可同質介面銲接等眾多優勢。因此,感應銲接特別適合於熱塑性纖維複合材料構件的接合,該感應銲接的原理為:透過一感應線圈對要進行結合的兩工件(例如碳纖維複合材料)升溫,使該兩工件之間的接觸面產生熔融,進而使該兩工件相互接合。Among the several welding techniques currently used for thermoplastic composites, induction welding (IW) offers numerous advantages, including low cost, continuous automation, and the ability to weld homogeneous interfaces. Therefore, IW is particularly well-suited for joining thermoplastic fiber composite components. The principle of IW is to heat the two workpieces (e.g., carbon fiber composites) to be joined using an induction coil, causing the contact surfaces between the two workpieces to melt, thereby bonding the two workpieces.
碳纖維複合材料作為結構件,其中碳纖維管應用面廣闊,具有高強度、低密度、壽命長等特性,製品已被許多行業所接受,包括自行車架、汽車防撞架、飛機管道、小機翼結構、襟翼、翅片等。這些具有硬殼式(monocoque)中空結構體的部件,可以將浸漬纖維片被稱為預浸布,通常可以在模具中,加熱和加壓下固化成形。中空部分可使用充氣囊來提供壓實壓力,常常會因壓力分佈不均勻而導致皺紋,進一步導致樹脂不均和高空隙區域。Carbon fiber composites, particularly carbon fiber tubes, have a wide range of applications as structural components. Their high strength, low density, and long lifespan have led to their widespread adoption across numerous industries, including bicycle frames, automotive crash bars, aircraft ducting, small wing structures, flaps, and fins. These components, with their monocoque hollow structures, can be formed by impregnating fiber sheets, known as prepregs, which are typically cured in a mold under heat and pressure. Inflatable bladders can be used to provide compaction pressure within the hollow portion, but this often results in wrinkles due to uneven pressure distribution, which can lead to uneven resin deposition and high-void areas.
因此,便有需要提供一種熱塑性纖維複合材料的感應銲接方法及硬殼式中空結構體的製造方法,能夠解決前述的問題。Therefore, there is a need to provide an induction welding method for thermoplastic fiber composites and a method for manufacturing a hard shell hollow structure that can solve the aforementioned problems.
本發明之一目的是提供一種熱塑性纖維複合材料的感應銲接方法,其具有預熱之感應銲接的接合強度較大於無預熱之感應銲接的接合強度。An object of the present invention is to provide a method for induction welding of thermoplastic fiber composites, wherein the bonding strength of the induction welding with preheating is greater than the bonding strength of the induction welding without preheating.
依據上述之目的,本發明提供一種熱塑性纖維複合材料的感應銲接方法,包括下列步驟:提供一第一碳纖維複材層,其包括一第一熱塑性樹脂及至少一第一碳纖維布,該至少一第一碳纖維布位於該第一熱塑性樹脂內;提供一第二碳纖維複材層,其包括一第二熱塑性樹脂及至少一第二碳纖維布,該至少一第二碳纖維布位於該第二熱塑性樹脂內;提供一感應片及一第三熱塑性樹脂,其中該感應片位於該第三熱塑性樹脂內,且該感應片為一種受到電磁場感應發熱之材料;將該第一碳纖維複材層、含有該感應片之該第三熱塑性樹脂及該第二碳纖維複材層依序疊放而形成一疊層;以對該疊層進行感應銲接前之預熱,其中該預熱之一預熱溫度小於或等於該第三熱塑性樹脂的玻璃轉化溫度,且大於或等於該第三熱塑性樹脂之60%的玻璃轉化溫度;以及控制一感應線圈對該至少一第一碳纖維布、該感應片、及該至少一第二碳纖維布加熱,直到該感應片升溫至超過該第三熱塑性樹脂的熔點,並使位於該至少一第一碳纖維布與該感應片之間的該第一熱塑性樹脂,以及位於該至少一第二碳纖維布與該感應片之間的該第二熱塑性樹脂,分別形成熔融狀態,而讓該第一及第二熱塑性樹脂分別與該第三熱塑性樹脂相互接合,以完成該熱塑性纖維複合材料的感應銲接。In accordance with the above-mentioned object, the present invention provides a method for induction welding of thermoplastic fiber composite materials, comprising the following steps: providing a first carbon fiber composite layer, which comprises a first thermoplastic resin and at least one first carbon fiber cloth, wherein the at least one first carbon fiber cloth is located in the first thermoplastic resin; providing a second carbon fiber composite layer, which comprises a second thermoplastic resin and at least one second carbon fiber cloth; cloth, the at least one second carbon fiber cloth is located in the second thermoplastic resin; providing a sensing sheet and a third thermoplastic resin, wherein the sensing sheet is located in the third thermoplastic resin and the sensing sheet is a material that generates heat when subjected to an electromagnetic field; stacking the first carbon fiber composite layer, the third thermoplastic resin containing the sensing sheet, and the second carbon fiber composite layer in sequence to form a stack; The stack is preheated before induction welding, wherein a preheating temperature of the preheating is less than or equal to the glass transition temperature of the third thermoplastic resin and greater than or equal to 60% of the glass transition temperature of the third thermoplastic resin; and a sensing coil is controlled to heat the at least one first carbon fiber cloth, the sensing sheet, and the at least one second carbon fiber cloth until the sensing sheet is heated to a temperature exceeding the third thermoplastic resin. The melting point of the thermoplastic resin is controlled, and the first thermoplastic resin located between the at least one first carbon fiber cloth and the sensing sheet, and the second thermoplastic resin located between the at least one second carbon fiber cloth and the sensing sheet are respectively molten, so that the first and second thermoplastic resins are respectively bonded to the third thermoplastic resin to complete the induction welding of the thermoplastic fiber composite material.
本發明更提供一種硬殼式中空結構體的製造方法,包括下列步驟:提供一第一碳纖維複材層,其包括一第一熱塑性樹脂及至少一第一碳纖維布,該至少一第一碳纖維布位於該第一熱塑性樹脂內;將該第一碳纖維複材層熱壓成形製作成一第一半殼結構體,該第一半殼結構體具有兩個第一端緣;提供一第二碳纖維複材層,其包括一第二熱塑性樹脂及至少一第二碳纖維布,該至少一第二碳纖維布位於該第二熱塑性樹脂內;將該第二碳纖維複材層熱壓成形製作成一第二半殼結構體,該第二半殼結構體具有兩個第二端緣;提供一第一感應片及一第三熱塑性樹脂,其中該第一感應片位於該第三熱塑性樹脂內,且該第一感應片為一種受到電磁場感應發熱之材料;將該第一半殼結構之該第一端緣、含有該第一感應片之該第三熱塑性樹脂、及該第二半殼結構之該第二端緣依序疊放而形成一第一疊層;對該第一疊層進行一第一預熱,該第一預熱之一預熱溫度小於或等於該第三熱塑性樹脂的玻璃轉化溫度,且大於或等於該第三熱塑性樹脂之60%的玻璃轉化溫度;以及控制一感應線圈將位於該第一端緣之該至少一第一碳纖維布、該第一感應片、及位於該第二端緣之該至少一第二碳纖維布加熱,直到該第一感應片升溫至超過該第三熱塑性樹脂的熔點,並使位於該至少一第一碳纖維布與該第一感應片之間的該第一熱塑性樹脂,以及位於該至少一第二碳纖維布與該第一感應片之間的該第二熱塑性樹脂,分別形成熔融狀態,而讓該第一及第二熱塑性樹脂分別與該第三熱塑性樹脂相互接合,以完成該第一及第二半殼結構體之端緣的第一次感應銲接。The present invention further provides a method for manufacturing a hard shell type hollow structure, comprising the following steps: providing a first carbon fiber composite material layer, which comprises a first thermoplastic resin and at least one first carbon fiber cloth, wherein the at least one first carbon fiber cloth is located in the first thermoplastic resin; hot pressing the first carbon fiber composite material layer to form a first half shell structure, wherein the first half shell structure has two first end edges; providing a second carbon fiber composite material layer, which comprises a second thermoplastic resin and at least one second carbon fiber cloth; fiber cloth, the at least one second carbon fiber cloth is located in the second thermoplastic resin; the second carbon fiber composite material layer is hot-pressed to form a second half shell structure, the second half shell structure having two second end edges; a first sensor sheet and a third thermoplastic resin are provided, wherein the first sensor sheet is located in the third thermoplastic resin, and the first sensor sheet is a material that generates heat when subjected to an electromagnetic field; the first end edge of the first half shell structure, the third thermoplastic resin containing the first sensor sheet, and the second half shell structure are hot-pressed to form a second half shell structure; The invention relates to a method for controlling a sensing coil to connect the at least one first carbon fiber cloth at the first end, the first sensing sheet, and the at least one second carbon fiber cloth at the second end. The method comprises the steps of: stacking the first stack of the thermoplastic resin and the second end of the second half shell structure in sequence to form a first stack; performing a first preheating on the first stack, wherein a preheating temperature of the first preheating is less than or equal to the glass transition temperature of the third thermoplastic resin and greater than or equal to 60% of the glass transition temperature of the third thermoplastic resin; and controlling a sensing coil to connect the at least one first carbon fiber cloth at the first end, the first sensing sheet, and the at least one second carbon fiber cloth at the second end. The cloth is heated until the temperature of the first sensing sheet rises to a temperature exceeding the melting point of the third thermoplastic resin, and the first thermoplastic resin located between the at least one first carbon fiber cloth and the first sensing sheet, and the second thermoplastic resin located between the at least one second carbon fiber cloth and the first sensing sheet, are respectively molten, and the first and second thermoplastic resins are respectively bonded to the third thermoplastic resin to complete the first induction welding of the end edges of the first and second half shell structures.
本發明之熱塑性纖維複合材料可透過預浸碳纖維布疊層熱壓方式製作而成,並透過熱壓成形製作一半殼結構體,將該半殼結構體之端緣加工後,可以與另一半殼結構體進行接合。然後,透過容易感應發熱之材料埋入二個碳纖維複材層之界面,並控制感應銲接製程參數,搭配感應銲接設備使二個碳纖維複材層可被連續性的熔接,以完成一個硬殼式中空結構體。再者,透過二段式程式控制進行預熱後再進行感應銲接,此時具有預熱之感應銲接的接合強度較大於無預熱之感應銲接的接合強度。The thermoplastic fiber composite material of the present invention can be manufactured by hot pressing a pre-impregnated carbon fiber layer, and then forming a half shell structure by hot pressing. After the end edge of the half shell structure is processed, it can be joined to the other half shell structure. Then, a material that easily senses heat is embedded in the interface of the two carbon fiber composite layers, and the induction welding process parameters are controlled. In combination with induction welding equipment, the two carbon fiber composite layers can be continuously welded to complete a hard shell hollow structure. Furthermore, preheating is performed through two-stage program control before induction welding. At this time, the bonding strength of the preheated induction welding is greater than the bonding strength of the induction welding without preheating.
為讓本發明之上述目的、特徵和特點能更明顯易懂,茲配合圖式將本發明相關實施例詳細說明如下。In order to make the above-mentioned objects, features and characteristics of the present invention more clearly understood, the relevant embodiments of the present invention are described in detail below with reference to the drawings.
茲配合圖式將本發明實施例詳細說明如下,其所附圖式主要為簡化之示意圖,僅以示意方式說明本發明之基本結構,因此在該等圖式中僅標示與本發明有關之元件,且所顯示之元件並非以實施時之數目、形狀、尺寸比例等加以繪製,其實際實施時之規格尺寸實為一種選擇性之設計,且其元件佈局形態有可能更為複雜。The following is a detailed description of an embodiment of the present invention with reference to the accompanying drawings. The accompanying drawings are primarily simplified schematic diagrams that illustrate the basic structure of the present invention. Therefore, only components relevant to the present invention are labeled in these drawings, and the components shown are not drawn in the same number, shape, or size ratio as in an actual implementation. The specifications and dimensions of the actual implementation are actually a selective design, and the component layout may be more complex.
圖1為本發明之一實施例之熱塑性纖維複合材料的感應銲接方法的步驟流程圖。圖2為本發明之一實施例之第一碳纖維複材層、含有感應片之第三熱塑性樹脂及第二碳纖維複材層之疊層的剖面示意圖。圖3為本發明之一實施例之感應銲接設備的立體示意圖。請參考圖1,該熱塑性纖維複合材料的感應銲接方法包括下列步驟:FIG1 is a flow chart of the steps of an induction welding method for thermoplastic fiber composites according to an embodiment of the present invention. FIG2 is a schematic cross-sectional view of a stack of a first carbon fiber composite layer, a third thermoplastic resin containing a sensing sheet, and a second carbon fiber composite layer according to an embodiment of the present invention. FIG3 is a schematic three-dimensional view of an induction welding apparatus according to an embodiment of the present invention. Referring to FIG1 , the induction welding method for thermoplastic fiber composites includes the following steps:
請參考圖2,在步驟S11中,提供一第一碳纖維複材層1,其包括一第一熱塑性樹脂11及至少一第一碳纖維布12,該第一碳纖維布12位於該第一熱塑性樹脂11內。該第一碳纖維複材層1可藉由預浸碳纖維布疊層製作而成。舉例,該第一碳纖維複材層1可為使用聚碸(PSU)碳纖維複合材料,是以單方向 (Unidirectinal, UD)纖維預浸布。Referring to Figure 2, in step S11, a first carbon fiber composite layer 1 is provided. The layer comprises a first thermoplastic resin 11 and at least one first carbon fiber cloth 12, with the first carbon fiber cloth 12 disposed within the first thermoplastic resin 11. The first carbon fiber composite layer 1 can be fabricated by laminating pre-impregnated carbon fiber cloths. For example, the first carbon fiber composite layer 1 can be made of polysulfone sulfide (PSU) carbon fiber composite material, which is a unidirectional (UD) fiber pre-impregnated cloth.
請再參考圖2,在步驟S12中,提供一第二碳纖維複材層2,其包括一第二熱塑性樹脂21及至少一第二碳纖維布22,該第二碳纖維布22位於該第二熱塑性樹脂21內。同樣地,該第二碳纖維複材層2可藉由預浸碳纖維布疊層製作而成。舉例,該第二碳纖維複材層2可為使用聚碸(PSU)碳纖維複合材料,也是以單方向 (Unidirectinal, UD)單方向纖維預浸布。Referring again to Figure 2, in step S12, a second carbon fiber composite layer 2 is provided. The layer comprises a second thermoplastic resin 21 and at least one second carbon fiber cloth 22. The second carbon fiber cloth 22 is disposed within the second thermoplastic resin 21. Similarly, the second carbon fiber composite layer 2 can be fabricated by laminating pre-impregnated carbon fiber cloths. For example, the second carbon fiber composite layer 2 can be made of polysulfone sulfide (PSU) carbon fiber composite material, also using unidirectional (UD) fiber pre-impregnation.
請再參考圖2,在步驟S13中,提供一感應片32及一第三熱塑性樹脂31,其中該感應片32位於該第三熱塑性樹脂31內,且該感應片32為一種受到電磁場感應發熱之材料。該感應片32可選自碳鋼、不鏽鋼、鋁合金及碳纖維布之其中一者。該第三熱塑性樹脂31可使用與該第一及第二熱塑性樹脂11、21相同之高分子種類,例如聚碸(PSU)。當該感應片32為碳纖維布時,其纖維排列方式使用編織排列,例如平織(一上一下交織)或斜織(二上二下交織)方式,非UD單方向,使用的編織排列可提供界面有較高之溫度,使容易感應銲接且構件外觀不易受損。在本發明之一實施例中,當聚碸(PSU)預浸感應片32時,該感應片32可使用基重為220g/m 2的碳纖維,碳纖維使用3K絲束,以一上一下平織方式進行編織後,預浸聚碸(PSU)高分子。 Referring again to Figure 2 , in step S13, a sensor sheet 32 and a third thermoplastic resin 31 are provided. The sensor sheet 32 is located within the third thermoplastic resin 31 and is a material that generates heat when induced by an electromagnetic field. The sensor sheet 32 can be made from one of carbon steel, stainless steel, aluminum alloy, and carbon fiber cloth. The third thermoplastic resin 31 can be made from the same polymer as the first and second thermoplastic resins 11 and 21, such as polysulfone sulfide (PSU). When the sensor sheet 32 is a carbon fiber cloth, its fibers are arranged in a woven pattern, such as a plain weave (one-up, one-down interlaced) or a diagonal weave (two-up, two-down interlaced), rather than a unidirectional UD weave. This weave arrangement provides a higher interface temperature, facilitating inductive welding and minimizing damage to the component's appearance. In one embodiment of the present invention, when the sensor sheet 32 is pre-impregnated with polysulfide (PSU), the sensor sheet 32 may be made of carbon fiber with a basis weight of 220 g/ m² . The carbon fiber is 3K tow, woven in a plain weave pattern, and then pre-impregnated with polysulfide (PSU) polymer.
請再參考圖2,在步驟S14中,將該第一碳纖維複材層1、含有該感應片32之該第三熱塑性樹脂31及該第二碳纖維複材層2依序疊放而形成一疊層。Referring to FIG. 2 again, in step S14, the first carbon fiber composite layer 1, the third thermoplastic resin 31 containing the sensor sheet 32, and the second carbon fiber composite layer 2 are stacked in sequence to form a stack.
在步驟S15中,以一預熱器(圖未示)對該疊層進行感應銲接前之預熱,其中該預熱溫度(preheat temperature, TP)小於或等於該第三熱塑性樹脂的玻璃轉化溫度(glass transition temperature, TG ),且大於或等於該第三熱塑性樹脂之60%的玻璃轉化溫度,即 )。該玻璃轉化溫度(glass transition temperature, TG)是指玻璃態物質在玻璃態和高彈態之間相互可逆轉化的溫度。當該感應片為碳纖維布時,該預熱溫度可為120~190℃。舉例,一感應銲接設備包括該預熱器,該預熱器包括熱風槍,用以提供感應銲接前之預熱。該感應銲接之製程參數包括:預熱溫度與時間。 In step S15, a preheater (not shown) is used to preheat the laminate before induction welding, wherein the preheat temperature (TP) is less than or equal to the glass transition temperature (TG) of the third thermoplastic resin and greater than or equal to 60% of the glass transition temperature of the third thermoplastic resin, i.e. The glass transition temperature (TG) refers to the temperature at which a glassy material reversibly transitions between a glassy state and a highly elastic state. When the sensor sheet is a carbon fiber cloth, the preheating temperature can be 120-190°C. For example, an induction welding apparatus includes a preheater, which includes a hot air gun for preheating before induction welding. The process parameters of the induction welding include: preheating temperature and time.
請再參考圖2,在步驟S16中,控制一感應線圈對該第一碳纖維布12、該感應片32、及該第二碳纖維布22加熱,直到該感應片32升溫至超過該第三熱塑性樹脂31的熔點,並使位於該第一碳纖維布12與該感應片32之間的該第一熱塑性樹脂11,以及位於該第二碳纖維布22與該感應片32之間的該第二熱塑性樹脂21,分別形成熔融狀態,而讓該第一及第二熱塑性樹脂11、21分別與該第三熱塑性樹脂31相互接合,以完成該熱塑性纖維複合材料的感應銲接。在本發明之一實施例中,相較於第一碳纖維布12和第二碳纖維布22,感應片32於步驟S16時較易受到電磁場感應,而產生較多之熱能。舉例而言,當該感應片32為碳纖維布時,感應片32可具有不同的構型條件(例如:較高之基重、較易感磁的編織方式、其他可提升感磁加熱性能的方法,或所述方法的任意組合),以較第一碳纖維布12和第二碳纖維布22產生較多之熱能。舉例,請參考圖3,該感應銲接設備4更包括:該感應線圈40、下壓前滾輪41及下壓後滾輪42。該感應線圈40、下壓前滾輪41及下壓後滾輪42同時沿銲接方向44移動,其移動所對應之下方區域形成一銲接區域43,而該感應線圈40所對應之下方位置即為接合點45。此時銲接速度可為50~200mm/min。再者,該感應銲接設備4更可包括:感應主機、氣冷裝置、XY移動機構等,以進行感應銲接。該感應銲接之製程參數更包括:該熱塑性纖維複合材料之疊層與該感應線圈之間距、該下壓前滾輪及該下壓後滾輪的夾持壓力、預熱電流、預熱時間、感應頻率、感應電流、感應時間及氣冷風壓等。本發明之一實施例之控制感應銲接的實施參數如下表1及表2:
在本發明之一實施例中,該感應銲接設備可配置如下:第一、感應機工作頭及感應線圈,感應機工作頭下方配有X軸及Z軸的調整機構,可進行微調感應線圈與該熱塑性纖維複合材料疊層之間的距離,用以提供感應銲接之所需溫度。該感應機工作頭可調整輸出功率。第二、設置一馬達提供Y軸方向移動功能,可控制其移動速率,用以提供銲接時間。第三、設置另一馬達提供Z軸方向下壓力,與該熱塑性纖維複合材料疊層接觸為下壓前滾輪及下壓後滾輪,可控制其下壓力量,用以提供銲接壓力。第四、設置可調整位置之壓縮空氣噴嘴,對準銲接區域,並可調整風壓,用以冷卻該熱塑性纖維複合材料疊層之表面。In one embodiment of the present invention, the induction welding equipment can be configured as follows: First, an induction head and an induction coil. The induction head is equipped with an X-axis and Z-axis adjustment mechanism, which can fine-tune the distance between the induction coil and the thermoplastic fiber composite material stack to provide the required temperature for induction welding. The induction head can adjust the output power. Second, a motor is provided to provide a Y-axis movement function, and its movement rate can be controlled to provide welding time. Third, another motor is provided to provide a downward pressure in the Z-axis direction, and the front and rear downward pressure rollers in contact with the thermoplastic fiber composite material stack can control their downward pressure force to provide welding pressure. Fourth, a compressed air nozzle with adjustable position is installed, aimed at the welding area, and the air pressure can be adjusted to cool the surface of the thermoplastic fiber composite laminate.
圖4為本發明之一實施例之剪切接合強度、電流、預熱溫度T1及銲接溫度T2的關係示意圖。請參考圖4,在實施例1中,無預熱,預熱溫度T1為室溫25˚C;銲接電流20A提供銲接溫度T2約為272˚C,該第一及第二碳纖維複材層之感應銲接的接合強度為9.3MPa。在實施例2、3及4中,固定銲接電流20A,提供銲接溫度T2約為220˚C、242˚C及256˚C;透過二段式程式控制進行預熱後再進行感應銲接,實施例2、3、4分別設定預熱溫度分別約為120˚C、168˚C、189˚C,預熱120˚C後之感應銲接的接合強度為13.9MPa,預熱168˚C後之感應銲接的接合強度為14.6MPa,預熱189˚C後之感應銲接的接合強度為13.1MPa,表示預熱過高,碳纖複材界面之高分子容易裂解,增加氣孔,導致接合強度下降。圖5顯示本發明之實施例1之銲接電流20A及無預熱之橫截面OM影像。請參考圖5,該OM影像出現未完全銲接之界面F1。圖6顯示本發明之實施例3之銲接電流20A及預熱168˚C之橫截面OM影像。請參考圖6,該OM影像出現良好銲接接合之界面F2。Figure 4 is a diagram showing the relationship between shear bond strength, current, preheating temperature T1, and welding temperature T2 for one embodiment of the present invention. Referring to Figure 4, in Example 1, no preheating was performed, and the preheating temperature T1 was room temperature (25°C). A welding current of 20A provided a welding temperature T2 of approximately 272°C. The induction weld strength between the first and second carbon fiber composite layers was 9.3 MPa. In Examples 2, 3, and 4, a fixed welding current of 20A was used to provide welding temperatures T2 of approximately 220°C, 242°C, and 256°C. Induction welding was performed after preheating using a two-stage program control. In Examples 2, 3, and 4, the preheating temperatures were set to approximately 120°C, 168°C, and 189°C, respectively. The joint strength of the induction weld after preheating at 120°C was 13.9 MPa, the joint strength after preheating at 168°C was 14.6 MPa, and the joint strength after preheating at 189°C was 13.1 MPa. This indicates that excessive preheating easily decomposes the polymer at the carbon fiber composite interface, increasing pores and resulting in a decrease in joint strength. Figure 5 shows a cross-sectional OM image of Example 1 of the present invention with a welding current of 20A and no preheating. Referring to Figure 5 , this OM image shows an incompletely welded interface F1. Figure 6 shows a cross-sectional OM image of Example 3 of the present invention with a welding current of 20A and preheating at 168°C. Referring to Figure 6 , this OM image shows a well-welded interface F2.
圖7為本發明一實施例之硬殼式中空結構體的製造方法的步驟流程圖。圖8為本發明之一實施例之第一碳纖維複材層的剖面示意圖及第一半殼結構體的立體示意圖。圖9為本發明之一實施例之第二碳纖維複材層的剖面示意圖及第二半殼結構體的立體示意圖。圖10A為本發明之一實施例之第一感應片及第三熱塑性樹脂的剖面示意圖。圖10B為本發明之一實施例之第二感應片及第四熱塑性樹脂的剖面示意圖。圖11為本發明之一實施例之第一半殼結構體、含有感應片之第三熱塑性樹脂、及該第一半殼結構體的立體示意圖。該硬殼式中空結構體的製造方法,包括下列步驟:Figure 7 is a step flow chart of a method for manufacturing a hard shell hollow structure according to an embodiment of the present invention. Figure 8 is a schematic cross-sectional view of a first carbon fiber composite layer and a three-dimensional schematic view of a first half shell structure according to an embodiment of the present invention. Figure 9 is a schematic cross-sectional view of a second carbon fiber composite layer and a three-dimensional schematic view of a second half shell structure according to an embodiment of the present invention. Figure 10A is a schematic cross-sectional view of a first sensor sheet and a third thermoplastic resin according to an embodiment of the present invention. Figure 10B is a schematic cross-sectional view of a second sensor sheet and a fourth thermoplastic resin according to an embodiment of the present invention. Figure 11 is a three-dimensional schematic view of a first half shell structure, a third thermoplastic resin containing a sensor sheet, and the first half shell structure according to an embodiment of the present invention. The manufacturing method of the hard shell hollow structure includes the following steps:
請參考圖8,在步驟S21中,提供一第一碳纖維複材層1,其包括一第一熱塑性樹脂11及至少一第一碳纖維布12,該第一碳纖維布12位於該第一熱塑性樹脂11內。在步驟S22中,將該第一碳纖維複材層1熱壓成形製作成一第一半殼結構體1’,該第一半殼結構體1’具有兩個第一端緣13。Referring to Figure 8 , in step S21, a first carbon fiber composite layer 1 is provided, comprising a first thermoplastic resin 11 and at least one first carbon fiber cloth 12. The first carbon fiber cloth 12 is disposed within the first thermoplastic resin 11. In step S22, the first carbon fiber composite layer 1 is hot-pressed to form a first half-shell structure 1′ having two first end edges 13.
請參考圖9,在步驟S23中,提供一第二碳纖維複材層2,其包括一第二熱塑性樹脂21及至少一第二碳纖維布22,該第二碳纖維布22位於該第二熱塑性樹脂21內。在步驟S24中,將該第二碳纖維複材層2熱壓成形製作成一第二半殼結構體2’,該第二半殼結構體2’具有兩個第二端緣23。Referring to Figure 9, in step S23, a second carbon fiber composite layer 2 is provided. The layer includes a second thermoplastic resin 21 and at least one second carbon fiber cloth 22. The second carbon fiber cloth 22 is disposed within the second thermoplastic resin 21. In step S24, the second carbon fiber composite layer 2 is hot-pressed to form a second half-shell structure 2'. The second half-shell structure 2' has two second end edges 23.
請參考圖10A,在步驟S25中,提供一第一感應片32’及一第三熱塑性樹脂31,其中該第一感應片32’位於該第三熱塑性樹脂31內,且該第一感應片32’為一種受到電磁場感應發熱之材料。該第一感應片32’可選自碳鋼、不鏽鋼、鋁合金及碳纖維布之其中一者。該第三熱塑性樹脂31可使用與該第一及第二熱塑性樹脂11、21相同之高分子種類,例如聚碸(PSU)。Referring to Figure 10A , in step S25, a first sensor sheet 32' and a third thermoplastic resin 31 are provided. The first sensor sheet 32' is located within the third thermoplastic resin 31 and is made of a material that generates heat when induced by an electromagnetic field. The first sensor sheet 32' can be selected from carbon steel, stainless steel, aluminum alloy, and carbon fiber cloth. The third thermoplastic resin 31 can be made of the same polymer as the first and second thermoplastic resins 11 and 21, such as polysulfone sulfide (PSU).
請參考圖11,在步驟S26中,將該第一半殼結構體1’之該第一端緣13、含有該第一感應片32’之該第三熱塑性樹脂31、及該第二半殼結構體2’之該第二端緣23依序疊放而形成一第一疊層。請參考圖12A~圖12D,其顯示該第一半殼結構體1’之該第一端緣13及該第二半殼結構體2’之該第二端緣23之間的四種搭接型態。較佳地,圖12B顯示該第一端緣13及該第二端緣23之間的搭接型態為階梯狀切齊的剖面,在感應銲接後,其銲接區域最為平滑而無凹凸狀。Referring to Figure 11 , in step S26, the first end edge 13 of the first half shell structure 1', the third thermoplastic resin 31 containing the first sensor sheet 32', and the second end edge 23 of the second half shell structure 2' are stacked in sequence to form a first stack. Referring to Figures 12A through 12D , four different overlap configurations are shown between the first end edge 13 of the first half shell structure 1' and the second end edge 23 of the second half shell structure 2'. Preferably, Figure 12B shows a stepped cross-section of the overlap between the first end edge 13 and the second end edge 23. After induction welding, the welded area is smoothest and free of unevenness.
在步驟S27中,以一預熱器(圖未示)對該第一疊層進行預熱,所需之預熱溫度小於或等於該第三熱塑性樹脂的玻璃轉化溫度(glass transition temperature,TG ),且大於或等於該第三熱塑性樹脂之60%的玻璃轉化溫度。In step S27, the first laminate is preheated using a preheater (not shown). The required preheating temperature is less than or equal to the glass transition temperature (TG) of the third thermoplastic resin and greater than or equal to 60% of the glass transition temperature of the third thermoplastic resin.
請再參考圖8、圖9及圖11,在步驟S28中,控制一感應線圈將位於該第一端緣13之該第一碳纖維布12、該第一感應片32’、及位於該第二端緣23之該第二碳纖維布22加熱,直到該第一感應片32’升溫至超過該第三熱塑性樹脂31的熔點,並使位於該第一碳纖維布12與該第一感應片32’之間的該第一熱塑性樹脂11,以及位於該第二碳纖維布22與該第一感應片32’之間的該第二熱塑性樹脂21,分別形成熔融狀態,而讓該第一及第二熱塑性樹脂11、21分別與該第三熱塑性樹脂31相互接合,以完成該第一及第二半殼結構體1’、2’之端緣的第一次感應銲接。Referring again to FIG8, FIG9 and FIG11, in step S28, a sensing coil is controlled to heat the first carbon fiber cloth 12 located at the first end 13, the first sensing sheet 32', and the second carbon fiber cloth 22 located at the second end 23 until the first sensing sheet 32' is heated to a temperature exceeding the melting point of the third thermoplastic resin 31, and the first carbon fiber cloth 12 and the first sensing sheet 32' are heated to a temperature exceeding the melting point of the third thermoplastic resin 31. The first thermoplastic resin 11 between the first and second sensing sheets 32', and the second thermoplastic resin 21 between the second carbon fiber cloth 22 and the first sensing sheet 32', are respectively molten, and the first and second thermoplastic resins 11, 21 are respectively bonded to the third thermoplastic resin 31 to complete the first induction welding of the end edges of the first and second half shell structures 1', 2'.
請參考圖10B,在步驟S29中,提供一第二感應片34及一第四熱塑性樹脂33,其中該第二感應片34位於該第四熱塑性樹脂33內,且該第二感應片34為一種受到電磁場感應發熱之材料。第二感應片34的材料可相同或不相同於第一感應片32’的材料。Referring to Figure 10B , in step S29, a second sensor sheet 34 and a fourth thermoplastic resin 33 are provided. The second sensor sheet 34 is located within the fourth thermoplastic resin 33 and is made of a material that generates heat when induced by an electromagnetic field. The material of the second sensor sheet 34 may be the same as or different from the material of the first sensor sheet 32′.
請再參考圖11,在步驟S30中,將該第一半殼結構體1’之該第一端緣13、該兩個含有該第二感應片34之該第四熱塑性樹脂33、及該第二半殼結構體2’之該第二端緣23分別依序疊放而形成一第二疊層。Referring to FIG. 11 , in step S30, the first end 13 of the first half shell structure 1′, the two fourth thermoplastic resins 33 containing the second sensor sheet 34, and the second end 23 of the second half shell structure 2′ are stacked in sequence to form a second stack.
在步驟S31中,以該預熱器對該第二疊層進行預熱,所需之預熱溫度小於或等於該第四熱塑性樹脂的玻璃轉化溫度(glass transition temperature,TG ),且大於或等於該第四熱塑性樹脂之60%的玻璃轉化溫度TG。In step S31, the second laminate is preheated by the preheater, and the required preheating temperature is less than or equal to the glass transition temperature (TG) of the fourth thermoplastic resin and greater than or equal to 60% of the glass transition temperature TG of the fourth thermoplastic resin.
請再參考圖8、圖9及圖11,在步驟S32中,控制該感應線圈將位於該第一端緣13之該第一碳纖維布11、該第二感應片34、及位於該第二端緣23之該第二碳纖維布21加熱,直到該第二感應片34升溫至超過該第四熱塑性樹脂33的熔點,並使位於該第一碳纖維布12與該第二感應片34之間的該第一熱塑性樹脂11,以及位於該第二碳纖維布22與該第二感應片34之間的該第二熱塑性樹脂21,分別形成熔融狀態,而讓該第一及第二熱塑性樹脂11、21分別與該第四熱塑性樹脂33相互接合,以完成該第一及第二半殼結構體1’、2’之端緣的第二次感應銲接,進而完成一硬殼式中空結構體。Referring again to FIG8, FIG9 and FIG11, in step S32, the sensing coil is controlled to heat the first carbon fiber cloth 11 located at the first end 13, the second sensing sheet 34, and the second carbon fiber cloth 21 located at the second end 23 until the temperature of the second sensing sheet 34 is raised to a temperature exceeding the melting point of the fourth thermoplastic resin 33, and the carbon fiber cloth 12 located between the first carbon fiber cloth 12 and the second sensing sheet 34 is heated. The first thermoplastic resin 11 and the second thermoplastic resin 21 located between the second carbon fiber cloth 22 and the second sensor sheet 34 are each molten, allowing the first and second thermoplastic resins 11, 21 to be bonded to the fourth thermoplastic resin 33, respectively, to complete the second induction welding of the end edges of the first and second half-shell structures 1', 2', thereby completing a hard shell hollow structure.
本發明之熱塑性纖維複合材料可透過預浸碳纖維布疊層熱壓方式製作而成,並透過熱壓成形製作一半殼結構體,將該半殼結構體之端緣加工後,可以與另一半殼結構體進行接合。然後,透過容易感應發熱之材料埋入二個碳纖維複材層之界面,並控制感應銲接製程參數,搭配感應銲接設備使二個碳纖維複材層可被連續性的熔接,以完成一個硬殼式中空結構體。再者,透過二段式程式控制進行預熱後再進行感應銲接,此時具有預熱之感應銲接的接合強度較大於無預熱之感應銲接的接合強度。The thermoplastic fiber composite material of the present invention can be manufactured by hot pressing a pre-impregnated carbon fiber layer, and then forming a half shell structure by hot pressing. After the end edge of the half shell structure is processed, it can be joined to the other half shell structure. Then, a material that easily senses heat is embedded in the interface of the two carbon fiber composite layers, and the induction welding process parameters are controlled. In combination with induction welding equipment, the two carbon fiber composite layers can be continuously welded to complete a hard shell hollow structure. Furthermore, preheating is performed through two-stage program control before induction welding. At this time, the bonding strength of the preheated induction welding is greater than the bonding strength of the induction welding without preheating.
綜上所述,乃僅記載本發明為呈現解決問題所採用的技術手段之較佳實施方式或實施例而已,並非用來限定本發明專利實施之範圍。即凡與本發明專利申請範圍文義相符,或依本發明專利範圍所做的均等變化與修飾,皆為本發明專利範圍所涵蓋。The foregoing merely describes preferred embodiments or examples of the technical means employed by this invention to solve the problem, and is not intended to limit the scope of implementation of this patent. In other words, all equivalent variations and modifications consistent with the scope of this patent application or based on the scope of this patent are covered by this patent.
1:第一碳纖維複材層 1’:第一半殼結構體 11:第一熱塑性樹脂 12:第一碳纖維布 13:第一端緣 2:第二碳纖維複材層 2’:第二半殼結構體 21:第二熱塑性樹脂 22:第二碳纖維布 23:第二端緣 31:第三熱塑性樹脂 32:感應片 32’:第一感應片 33:第四熱塑性樹脂 34:第二感應片 4:感應銲接設備 40:感應線圈 41:下壓前滾輪 42:下壓後滾輪 43:銲接區域 44:銲接方向 45:接合點 F1:介面 F2:介面 T1:預熱溫度 T2:銲接溫度 S11~S16:步驟 S21~S32:步驟 1: First carbon fiber composite layer 1': First shell half 11: First thermoplastic resin 12: First carbon fiber cloth 13: First end edge 2: Second carbon fiber composite layer 2': Second shell half 21: Second thermoplastic resin 22: Second carbon fiber cloth 23: Second end edge 31: Third thermoplastic resin 32: Sensor sheet 32': First sensor sheet 33: Fourth thermoplastic resin 34: Second sensor sheet 4: Inductive welding equipment 40: Inductive coil 41: Front pressure roller 42: Rear pressure roller 43: Welding area 44: Welding direction 45: Joint F1: Interface F2: Interface T1: Preheating Temperature T2: Soldering Temperature S11-S16: Steps S21-S32: Steps
圖1為本發明之一實施例之熱塑性纖維複合材料的感應銲接方法的步驟流程圖。 圖2為本發明之一實施例之第一碳纖維複材層、含有感應片之第三熱塑性樹脂及第二碳纖維複材層之疊層的剖面示意圖。 圖3為本發明之一實施例之感應銲接設備的立體示意圖。 圖4為本發明之一實施例之剪切接合強度、電流、預熱溫度T1及銲接溫度T2的關係示意圖。 圖5顯示本發明之實施例1之銲接電流20A及無預熱之橫截面OM影像。 圖6顯示本發明之實施例3之銲接電流20A及預熱168˚C之橫截面OM影像。 圖7為本發明一實施例之硬殼式中空結構體的製造方法的步驟流程圖。 圖8為本發明之一實施例之該第一碳纖維複材層的剖面示意圖。 圖9為本發明之一實施例之第二碳纖維複材層的剖面示意圖及第二半殼結構體的立體示意圖。 圖10A為本發明之一實施例之第一感應片及第三熱塑性樹脂的剖面示意圖。 圖10B為本發明之一實施例之第二感應片及第四熱塑性樹脂的剖面示意圖。 圖11為本發明之一實施例之第一半殼結構體、含有感應片之第三熱塑性樹脂、及該第一半殼結構體的立體示意圖。 圖12A~圖12D顯示第一半殼結構體之該第一端緣及第一半殼結構體之第二端緣之間的四種搭接型態。 Figure 1 is a flow chart of the steps of an induction welding method for thermoplastic fiber composites according to an embodiment of the present invention. Figure 2 is a schematic cross-sectional view of a stack of a first carbon fiber composite layer, a third thermoplastic resin containing a sensing sheet, and a second carbon fiber composite layer according to an embodiment of the present invention. Figure 3 is a schematic perspective view of an induction welding apparatus according to an embodiment of the present invention. Figure 4 is a schematic diagram showing the relationship between shear bond strength, current, preheating temperature T1, and welding temperature T2 according to an embodiment of the present invention. Figure 5 shows a cross-sectional OM image of Example 1 of the present invention at a welding current of 20A and without preheating. Figure 6 shows a cross-sectional OM image of Example 3 of the present invention at a welding current of 20A and preheating to 168°C. Figure 7 is a flow chart of the steps of a method for manufacturing a hardshell hollow structure according to an embodiment of the present invention. Figure 8 is a schematic cross-sectional view of the first carbon fiber composite layer according to an embodiment of the present invention. Figure 9 is a schematic cross-sectional view of the second carbon fiber composite layer and a three-dimensional schematic view of the second half-shell structure according to an embodiment of the present invention. Figure 10A is a schematic cross-sectional view of the first sensor sheet and the third thermoplastic resin according to an embodiment of the present invention. Figure 10B is a schematic cross-sectional view of the second sensor sheet and the fourth thermoplastic resin according to an embodiment of the present invention. Figure 11 is a schematic perspective view of a first half shell structure, a third thermoplastic resin containing a sensor sheet, and the first half shell structure according to one embodiment of the present invention. Figures 12A-12D illustrate four different types of overlaps between the first end edge of the first half shell structure and the second end edge of the first half shell structure.
S11~S16:步驟 S11~S16: Steps
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Citations (4)
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|---|---|---|---|---|
| WO1993002849A1 (en) * | 1991-07-30 | 1993-02-18 | E.I. Du Pont De Nemours And Company | Method for induction heating of composite materials |
| CN107433724A (en) * | 2016-05-25 | 2017-12-05 | 空客直升机 | Method and thermoplasticity blade |
| CN111655448A (en) * | 2017-11-21 | 2020-09-11 | 通用电气公司 | Method for manufacturing the outer skin of a rotor blade |
| CN116829340A (en) * | 2021-02-05 | 2023-09-29 | 阿科玛法国公司 | Method for preparing composite parts with high degree of consolidation |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993002849A1 (en) * | 1991-07-30 | 1993-02-18 | E.I. Du Pont De Nemours And Company | Method for induction heating of composite materials |
| CN107433724A (en) * | 2016-05-25 | 2017-12-05 | 空客直升机 | Method and thermoplasticity blade |
| CN111655448A (en) * | 2017-11-21 | 2020-09-11 | 通用电气公司 | Method for manufacturing the outer skin of a rotor blade |
| CN116829340A (en) * | 2021-02-05 | 2023-09-29 | 阿科玛法国公司 | Method for preparing composite parts with high degree of consolidation |
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