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TWI887343B - Device and method for repairing a defect of an optical component for the extreme ultraviolet wavelength range - Google Patents

Device and method for repairing a defect of an optical component for the extreme ultraviolet wavelength range Download PDF

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TWI887343B
TWI887343B TW110103628A TW110103628A TWI887343B TW I887343 B TWI887343 B TW I887343B TW 110103628 A TW110103628 A TW 110103628A TW 110103628 A TW110103628 A TW 110103628A TW I887343 B TWI887343 B TW I887343B
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defect
optical component
euv
photon beam
repair
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TW202134780A (en
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康瑞德 沃克
馬汀 迪耶左
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德商卡爾蔡司Smt有限公司
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/22Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof
    • G03F1/24Reflection masks; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/68Preparation processes not covered by groups G03F1/20 - G03F1/50
    • G03F1/72Repair or correction of mask defects

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  • General Physics & Mathematics (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)

Abstract

The present invention relates to a device (700) for repairing at least one defect (150, 350, 550, 1450) of an optical component (100, 300, 500) for the extreme ultraviolet (EUV) wavelength range, wherein the optical component (100, 300, 500) comprises a substrate (110) and a multilayer structure (120) arranged on the substrate (110) and wherein the device comprises: (a) at least one light source (610, 1010, 1020) designed to generate a photon beam (605, 1030, 1130) in the EUV wavelength range and/or in the wavelength range of soft x-ray radiation; and (b) wherein the at least one light source (610, 1010, 1020) is furthermore designed to repair the at least one defect (150, 350, 550, 1450) by locally altering the optical component (100, 300, 500).

Description

在極紫外線波長範圍內修復光學組件缺陷之裝置及方法Device and method for repairing defects in optical components in the extreme ultraviolet wavelength range

本案主張於2020年2月6日向德國專利商標局申請之德國第DE 10 2020 201 482.5號專利申請案之優先權。在此將德國優先權申請案以引用方式整個併入本案。This case claims priority to German patent application No. DE 10 2020 201 482.5 filed with the German Patent and Trademark Office on February 6, 2020. The German priority application is hereby incorporated by reference in its entirety into this case.

本發明係關於在極紫外線(EUV)波長範圍內修復光學組件的至少一缺陷之裝置及方法,其中用於EUV波長範圍的光學組件包含一基材及一配置在基材上的多層結構。The present invention relates to an apparatus and a method for repairing at least one defect of an optical component in the extreme ultraviolet (EUV) wavelength range, wherein the optical component for the EUV wavelength range comprises a substrate and a multi-layer structure disposed on the substrate.

由於半導體產業中的積體密度不斷提高,光刻光罩(Photolithography mask)必須在晶圓上成像越來越小的結構。關於光刻,藉由將光刻設備之曝光波長轉變成越來越短的波長來解決積體密度不斷提高的趨勢。目前在光刻設備或微影設備中經常用作光源是發射約193 nm之波長的氬氟(Argon fluoride,ArF)準分子雷射。As the semiconductor industry continues to increase in density, photolithography masks must image smaller and smaller structures on the wafer. In photolithography, the trend of increasing density is addressed by changing the exposure wavelength of the photolithography equipment to shorter and shorter wavelengths. Currently, the light source commonly used in photolithography equipment or lithography equipment is the argon fluoride (ArF) excimer laser, which emits a wavelength of about 193 nm.

現今,正在開發的微影系統係使用EUV(極紫外線)波長範圍內(較佳地在10 nm至15 nm範圍內)的電磁輻射。由於目前沒有在所述EUV範圍內為光學透明的可用材料,因此前述EUV微影系統係基於使用反射光學元件的全新之光束導引概念。開發EUV系統的技術挑戰相當龐大,必須付出極大開發努力才能將前述系統提升至就緒可進行工業應用的層級。Today, lithography systems are being developed that use electromagnetic radiation in the EUV (extreme ultraviolet) wavelength range, preferably in the range of 10 nm to 15 nm. Since there are currently no available materials that are optically transparent in the EUV range, EUV lithography systems are based on completely new beam guidance concepts using reflective optics. The technical challenges in developing EUV systems are considerable and a huge development effort is required to bring such systems to a level that is ready for industrial applications.

顯著有助於配置在晶圓上的光阻中成像越來越小的結構,係由於光刻光罩、曝光光罩、光罩、或僅僅光罩。隨著積體密度的每次進一步提高,減小曝光光罩之最小結構大小變得越來越重要。因此,光刻光罩之生產製程變得越來越複雜,且因此更耗時且最終也更昂貴。由於圖案元件之微小結構大小,無法在光罩生產期間排除缺陷。此些必須盡可能加以修復。Significantly contributing to the imaging of smaller and smaller structures in the photoresist arranged on the wafer is the lithography mask, exposure mask, photomask, or just the mask. With each further increase in integration density, it becomes increasingly important to reduce the minimum structure size of the exposure mask. As a result, the production process of the lithography mask becomes increasingly complex and therefore more time-consuming and ultimately more expensive. Due to the tiny structure size of the patterned elements, defects cannot be excluded during the mask production. These must be repaired whenever possible.

目前,光罩缺陷經常係藉由電子束引致的局部沉積及/或蝕刻製程而加以修復。以下舉例所示的文獻係關於修復EUV光罩:L. Pang等人:「藉由吸收劑圖案修飾而補償任意佈局內的EUV多層缺陷(Compensation of EUV multilayer defects within arbitrary layout by absorber pattern modification)」,「極紫外線微影(Extreme Ultraviolet Lithography)」,B.M.o Fontaine和P.P. Naulleau編輯,《國際光學工程學會論文集》(Proc. of SPIE),第7969卷,第79691E-1 – 79691E-14頁;WO 2016 / 037 851 A1;M. Waiblinger等人:「用於EUV光罩修復的大門開啟者(The door opener for EUV mask repair)」,「光罩及下一代微影光罩技術XIV(Photomask and Next Generation Lithography Mask Technology XIV)」,K. Kato編輯,《國際光學工程學會論文集》(Proc. of SPIE),第84441卷,第84410F-1 – 84410F-10頁;WO 2011 / 161 243 A1;WO 2013 / 010 976 A1;WO 2015 / 144 700 A1;G. McIntyre等人:「採用微機械加工的離焦EUV多層缺陷修復(Through-focus EUV multilayer defect repair with micromachining)」,「極紫外線(EUV)微影IV(Extreme Ultraviolet(EUV)Lithography IV)」,P.P. Naulleau編輯,《國際光學工程學會論文集》(Proc. of SPIE),第8679卷,第86791I-1至86791I-4頁。Currently, mask defects are often repaired by electron beam induced local deposition and/or etching processes. The following are examples of literature on EUV mask repair: L. Pang et al.: “Compensation of EUV multilayer defects within arbitrary layout by absorber pattern modification”, Extreme Ultraviolet Lithography, B.M.o Fontaine and P.P. Naulleau, eds., Proc. of SPIE, vol. 7969, pp. 79691E-1 – 79691E-14; WO 2016/037 851 A1; M. Waiblinger et al.: “The door opener for EUV mask repair”, Photomask and Next Generation Lithography XIV. K. Kato, ed., “Lithography Mask Technology XIV”, Proc. of SPIE, vol. 84441, pp. 84410F-1 – 84410F-10; WO 2011 / 161 243 A1; WO 2013 / 010 976 A1; WO 2015 / 144 700 A1; G. McIntyre et al., “Through-focus EUV multilayer defect repair with micromachining”, in “Extreme Ultraviolet (EUV) Lithography IV”, P.P. Naulleau, ed., Proc. of SPIE, vol. 84441, pp. 84410F-1 – 84410F-10. SPIE, vol. 8679, pp. 86791I-1–86791I-4.

由於圖案元件之不斷減小的結構大小,控制局部沉積及/或蝕刻製程變得越來越富有挑戰性。再者,修復策略必須個別調適於個別製造環境之要求。EUV光罩之每項技術驅動的調適(例如其材料組成、尺寸、或構造)皆需要重新評估確立的修復製程,此在一些情況下會導致其採耗時方式重新建置。Due to the ever-decreasing structure size of patterned elements, controlling the local deposition and/or etching processes becomes increasingly challenging. Furthermore, the repair strategy must be individually adapted to the requirements of the individual manufacturing environment. Every technology-driven adaptation of the EUV mask (e.g. its material composition, dimensions, or structure) requires a re-evaluation of the established repair process, which in some cases leads to its reconstruction in a time-consuming manner.

以下引用示例性文獻說明用於EUV波長範圍的同調光源:S. Hädrich等人:「高光子通量臺上型同調極紫外線來源(High photon flux table-top coherent extreme ultraviolet source)」,DOI: 10.1038/nphoton.2014.214,arXiv: 1403.4631;https://kmlabs.com/wp-content/uploads/2017/02/KML_XUUSTM.pdf;H. Carstens等人:「在250 MHz以光子能量超過100 eV的高諧波產生(High-harmonic generation at 250 MHz with photon energies exceeding 100 eV)」,《光學設計》(Optica),第4卷,第3期,2016年4月,第366-369頁;《自然光子學》(Nature Photonics),第8卷,第779-783頁(2014年)。The following references illustrate coherent light sources for the EUV wavelength range: S. Hädrich et al.: “High photon flux table-top coherent extreme ultraviolet source”, DOI: 10.1038/nphoton.2014.214, arXiv: 1403.4631; https://kmlabs.com/wp-content/uploads/2017/02/KML_XUUSTM.pdf; H. Carstens et al.: “High-harmonic generation at 250 MHz with photon energies exceeding 100 eV”, DOI: 10.1038/nphoton.2014.214, arXiv: 1403.4631; https://kmlabs.com/wp-content/uploads/2017/02/KML_XUUSTM.pdf; H. Carstens et al.: “High-harmonic generation at 250 MHz with photon energies exceeding 100 eV”, DOI: 10.1038/nphoton.2014.214, arXiv: 1403.4631; https://kmlabs.com/wp-content/uploads/2017/02/KML_XUUSTM.pdf eV), Optica, Vol. 4, No. 3, April 2016, pp. 366-369; Nature Photonics, Vol. 8, pp. 779-783 (2014).

在技術文章「理解薄膜雷射剝蝕:有效穿透深度和膜厚度的作用(Understanding thin film laser ablation: The role of the effective penetration depth and film thickness)」,《物理學學報》(Physics Procedia),第56卷,第1007-1014頁(2014年)中,作者M. Domke等人研究借助於雷射脈衝從光學透明材料剝蝕薄金屬層。在技術文章「應用於製備具有無缺陷光罩的HVM EUV微影之光化光罩檢測系統(Application of actinic mask review system for the preparation of HVM EUV lithography with defect free mask)」,《BACUS》,第33卷,2017年7月,第1-8頁中,作者J. Na等人說明使用高諧波產生(High Harmonic Generation,HHG)雷射系統檢驗EUV光罩。In the technical article “Understanding thin film laser ablation: The role of the effective penetration depth and film thickness,” Physics Procedia, Vol. 56, pp. 1007-1014 (2014), M. Domke et al. study the ablation of thin metal layers from optically transparent materials with the aid of laser pulses. In the technical article “Application of actinic mask review system for the preparation of HVM EUV lithography with defect free mask,” BACUS, Vol. 33, July 2017, pp. 1-8, J. Na et al. describe the use of a High Harmonic Generation (HHG) laser system to inspect EUV masks.

本發明解決了明確說明一裝置和一方法,其使得可改良在極紫外線波長範圍內修復光學組件缺陷的之問題。The present invention solves the problem of specifying a device and a method which allow improved repair of defects in optical components in the extreme ultraviolet wavelength range.

根據本發明之一示例性具體實例,此問題係藉由如申請專利範圍第1項之裝置並藉由如申請專利範圍第15項之方法而加以解決。在一具體實例中,一種在極紫外線(EUV)波長範圍內修復光學組件至少一缺陷之裝置,其中光學組件包含一基材及一配置在基材上的多層結構,其包含:(a)至少一光源,其設計成產生EUV波長範圍內及/或軟x光輻射之波長範圍內的一光子束;及(b)其中至少一光源更設計成藉由局部更改光學組件,以修復至少一缺陷。According to an exemplary embodiment of the present invention, this problem is solved by a device as in claim 1 and by a method as in claim 15. In one embodiment, a device for repairing at least one defect of an optical component in the extreme ultraviolet (EUV) wavelength range, wherein the optical component comprises a substrate and a multilayer structure disposed on the substrate, comprising: (a) at least one light source, which is designed to generate a photon beam in the EUV wavelength range and/or in the wavelength range of soft x-ray radiation; and (b) wherein the at least one light source is further designed to repair at least one defect by locally modifying the optical component.

根據本發明的裝置呈現在EUV波長範圍內修復組件方面的實施例變更。在先前間接製程之情況下,電子束藉由在反應部位處提供前驅氣體,而啟動用於沉積遺漏材料的局部沉積製程或用於去除過剩材料的局部蝕刻製程。相較之下,為了直接修復缺陷,根據本發明的裝置使用EUV波長範圍內及/或軟x光輻射之波長範圍內的光子束。因此,根據本發明的裝置克服使用前驅氣體造成的習知修復裝置之側向解析度限制。由於EUV範圍內的電磁輻射之短波長,使得根據本發明的裝置在用於EUV波長範圍的光學組件之缺陷修復期間進展為側向空間解析度之新尺寸。而且,在缺陷修復期間,防止光學組件受到前驅氣體及/或其成分污染。The device according to the invention presents an embodiment variation in the repair of components in the EUV wavelength range. In the case of previous indirect processes, an electron beam initiates a local deposition process for depositing missing material or a local etching process for removing excess material by providing a precursor gas at the reaction site. In contrast, for the direct repair of defects, the device according to the invention uses a photon beam in the EUV wavelength range and/or in the wavelength range of soft X-ray radiation. Thus, the device according to the invention overcomes the lateral resolution limitations of known repair devices caused by the use of precursor gases. Due to the short wavelength of electromagnetic radiation in the EUV range, the device according to the invention allows new dimensions of lateral spatial resolution during defect repair of optical components for the EUV wavelength range. Furthermore, during defect repair, the optical components are protected from contamination by the precursor gas and/or its components.

EUV光譜範圍涵蓋10 nm至121 nm之波長。此對應於124電子伏特(electron Volt,eV)與10.3 eV之間之光子能量。在本案中,軟x光輻射之範圍應可理解為意指0.1 nm至10 nm之波長範圍。相關聯光子能量範圍從12400 eV或12.4 keV至124 eV皆包含在內。光化波長(即操作光學組件所在波長)較佳地涵蓋10 nm至15 nm之波長範圍或124 eV至82.7 eV之能量範圍。The EUV spectral range covers a wavelength of 10 nm to 121 nm. This corresponds to a photon energy between 124 electron Volt (eV) and 10.3 eV. In the present case, the range of soft x-ray radiation should be understood to mean a wavelength range of 0.1 nm to 10 nm. The associated photon energy range is from 12400 eV or 12.4 keV to 124 eV. The actinic wavelength (i.e. the wavelength at which the optical components are operated) preferably covers a wavelength range of 10 nm to 15 nm or an energy range of 124 eV to 82.7 eV.

至少一光源可產生具有光化波長範圍內波長的光子束。At least one light source can generate a photon beam having a wavelength in the actinic wavelength range.

首先,光化波長範圍內的聚焦光子束具有高側向空間解析度,由此使其可執行非常精確的缺陷修復,並同時降低修復製程期間損壞光學組件之風險。其次,可使用產生光化波長範圍內光子束的光源,記錄缺陷位置及/或經修復位置之空間影像(Aerial image)。First, a focused photon beam in the actinic wavelength range has a high lateral spatial resolution, which makes it possible to perform very precise defect repair while reducing the risk of damaging the optical component during the repair process. Second, a light source that generates a photon beam in the actinic wavelength range can be used to record an aerial image of the defect location and/or the repaired location.

局部更改光學組件可包含光學組件在光化波長範圍內反射率的局部變更。Locally modifying an optical component may include locally modifying the reflectivity of the optical component within an actinic wavelength range.

用於EUV波長範圍的反射光學組件之缺陷,通常係表現為反射光學強度之不均勻分佈。在此種情況下,如設計所設想,可能有或多或少的光從光學組件的區域反射。憑藉用於局部變更光學組件之反射率的EUV光子束,可消除或至少顯著減少從光學組件反射光學強度之不均勻分佈。The defects of reflective optical components for the EUV wavelength range usually manifest themselves as an uneven distribution of the reflected optical intensity. In this case, more or less light may be reflected from areas of the optical component, as envisioned by the design. By means of an EUV photon beam used to locally change the reflectivity of the optical component, the uneven distribution of the reflected optical intensity from the optical component can be eliminated or at least significantly reduced.

局部更改光學組件可包含藉助光子束從光學組件局部去除材料。Locally modifying an optical component may comprise locally removing material from the optical component by means of a photon beam.

借助於光子束藉由蒸發從光學組件去除材料。為了蒸發材料,首先必須將光學組件加熱至特定材料的蒸發溫度;針對此,需要依材料之密度和熱容量而定的能量。其次,必須向材料提供同樣的特定材料蒸發熱。聚焦EUV光子束可局部施加此些特定能量密度,即每體積的能量。此基本上係基於EUV光子束之兩種性質。首先,可將EUV光子束聚焦到非常小的繞射有限面積,且其次,可產生次飛秒(sub-femtosecond)範圍內的EUV光子束之脈衝,其具有非常高功率密度。Material is removed from an optical component by evaporation with the aid of a photon beam. In order to evaporate the material, firstly the optical component must be heated to the material-specific evaporation temperature; for this, an amount of energy that depends on the density and heat capacity of the material is required. Secondly, the material must be supplied with the same material-specific heat of evaporation. Focusing the EUV photon beam makes it possible to apply these specific energy densities, i.e. the energy per volume, locally. This is essentially based on two properties of the EUV photon beam. Firstly, the EUV photon beam can be focused to a very small, diffraction-limited area and, secondly, pulses of the EUV photon beam in the sub-femtosecond range can be generated, which have a very high power density.

光學組件可包含一用於EUV波長範圍的光刻光罩、或者一用於EUV波長範圍的反射鏡。The optical assembly may include a lithography mask for EUV wavelength range, or a reflective mirror for EUV wavelength range.

局部去除材料可包含以下群組之至少一者:去除一光刻光罩之一吸收劑圖案之至少一元件之過剩材料、去除光學組件之多層結構之材料、並從光學組件去除至少一顆粒。The local removal of material may include at least one of the following: removing excess material from at least one element of an absorber pattern of a lithography mask, removing material from a multi-layer structure of an optical component, and removing at least one particle from an optical component.

根據本發明的裝置之光源使其可修復或校正過剩材料之缺陷、及遺漏材料之缺陷。光刻光罩之一或多個圖案元件之遺漏吸收劑材料之缺陷,係藉由局部去除多層結構之一部分而加以補償。因此,實質上沒有光子再從光刻光罩之經處理部分及在空間影像中或光阻中的影像中反射,經修復位置係與無缺陷位置無法區別。The light source of the device according to the invention makes it possible to repair or correct defects of excess material and defects of missing material. Defects of missing absorber material of one or more pattern elements of the lithography mask are compensated by locally removing a portion of the multilayer structure. As a result, substantially no photons are reflected from the processed portion of the lithography mask and in the spatial image or in the image in the photoresist, and the repaired locations are indistinguishable from defect-free locations.

EUV反射鏡之不均勻反射可根據相同原理加以修復。此外,存在於光學組件上並在光學組件之空間影像中可見的顆粒,可藉由藉助聚焦EUV光子束的蒸發而從光學組件之表面去除。The uneven reflection of EUV mirrors can be repaired according to the same principle. In addition, particles present on the optical component and visible in the spatial image of the optical component can be removed from the surface of the optical component by evaporation with the help of a focused EUV photon beam.

此處,如亦在本案中其他地方,若使用根據先前技術的測量儀器進行測量,則措辭「實質上」意指物理變量在其誤差限值內之測量。Here, as elsewhere in this case, the expression "substantially" means the measurement of the physical variable within its error limits if the measurement is carried out using a measuring instrument according to the prior art.

至少一光源可更設計成設定用於修復光學組件至少一缺陷的光子束之能量密度。The at least one light source may be further configured to set an energy density of the photon beam for repairing at least one defect of the optical component.

光子束之能量密度可藉助至少兩參數進行設定。首先,可設定聚焦條件,並因此設定光源之光子束入射在缺陷或光學組件上的光點大小。其次,可變化光子束之平均功率及因此可變化脈衝功率。The energy density of the photon beam can be set by means of at least two parameters. Firstly, the focusing conditions and thus the spot size of the photon beam of the light source incident on the defect or optical component can be set. Secondly, the average power of the photon beam and thus the pulse power can be varied.

根據本發明的裝置可更包含一偵測器,用於偵測從光學組件反射的光子;及/或一能量感測器,用於在一修復期間供監控修復之目的而偵測從光學組件及/或從至少一缺陷反射的光子。The device according to the invention may further comprise a detector for detecting photons reflected from the optical component and/or an energy sensor for detecting photons reflected from the optical component and/or from at least one defect during a repair for the purpose of monitoring the repair.

若裝置包含一偵測器,則為了檢驗缺陷或缺陷之剩餘部分之效果,而可在缺陷修復製程之前、期間、和之後使用偵測器。特別是,可結合光子束使用偵測器檢查缺陷修復是否成功。If the device includes a detector, the detector can be used before, during, and after the defect repair process in order to verify the effect of the defect or the remaining part of the defect. In particular, the detector can be used in conjunction with a photon beam to check whether the defect repair was successful.

在修復製程期間,可使用能量感測器偵測從經修復位置反射的光子,並由此判定光子通量密度之變更,特別是光子通量密度在修復製程期間之減小。During the repair process, an energy sensor may be used to detect photons reflected from the repaired location and thereby determine changes in photon flux density, particularly a decrease in photon flux density during the repair process.

偵測器可包含一用於EUV波長範圍的電荷耦合裝置(Charge Coupled Device,CCD)攝影機。能量感測器可為一CCD攝影機之元件或偵測器元件。The detector may include a charge coupled device (CCD) camera for the EUV wavelength range. The energy sensor may be a CCD camera element or a detector element.

再者,根據本發明的裝置可包含一能量分散x光偵測器。能量分散x光偵測器可偵測由於用光子束照射之結果,由光學組件產生的光子以及/或光學組件之缺陷。因此,其變成可判定由光子束所處理材料之材料組成。Furthermore, the device according to the invention may comprise an energy dispersive x-ray detector. The energy dispersive x-ray detector can detect photons generated by the optical component as a result of irradiation with the photon beam and/or defects in the optical component. It thus becomes possible to determine the material composition of the material treated by the photon beam.

根據本發明的裝置可設計成在閉反饋迴路中操作至少一光源和能量感測器。The device according to the present invention can be designed to operate at least one light source and an energy sensor in a closed feedback loop.

因此,其變成可即時監控修復製程。修復製程出錯之機率可顯著降低。特別是,可在很大程度上防止光學組件受到損壞,且確實可即時確定缺陷或光學組件之材料是否被剝蝕。Therefore, it becomes possible to monitor the repair process in real time. The probability of error in the repair process can be significantly reduced. In particular, damage to the optical component can be prevented to a large extent, and defects or whether the material of the optical component is eroded can be determined in real time.

根據本發明的裝置可更包含至少一第一反射鏡,用於在光學組件的至少一缺陷上方掃描光子束,並可包含至少一第二反射鏡,用於將光子束引導到光學組件含有至少一缺陷之區域。The device according to the invention may further comprise at least one first mirror for scanning the photon beam over at least one defect of the optical component, and may comprise at least one second mirror for directing the photon beam to a region of the optical component containing the at least one defect.

根據本發明之裝置包含兩反射鏡的之一具體實例,使得更容易將裝置從光學組件及/或光學組件之缺陷之一檢驗模式切換成用於修復缺陷的一修復模式,反之亦然。According to a specific embodiment of the device of the invention comprising two reflectors, it is easier to switch the device from an inspection mode of optical components and/or defects of optical components to a repair mode for repairing defects, and vice versa.

至少一第一反射鏡可設計成將光子束聚焦在光學組件之至少一缺陷上。再者,至少一第一反射鏡可設計成在光學組件及/或光學組件之至少一缺陷上方掃描聚焦光子束。The at least one first reflector can be designed to focus the photon beam on at least one defect of the optical component. Furthermore, the at least one first reflector can be designed to scan and focus the photon beam over the optical component and/or at least one defect of the optical component.

至少一光源可設計成產生EUV波長範圍內及/或軟x光輻射之波長範圍內的同調光子束。At least one light source may be designed to generate a coherent photon beam in the EUV wavelength range and/or in the wavelength range of soft x-ray radiation.

至少一光源可包含一高諧波產生(HHG)雷射。聚焦飛秒雷射系統之高諧波光譜直接延伸到EUV波長範圍內,且部分超出到甚至更短波長之光譜範圍內。HHG雷射產生具有微小光束發散的超短EUV或x光脈衝。At least one light source may include a high harmonic generation (HHG) laser. The high harmonic spectrum of a focused femtosecond laser system extends directly into the EUV wavelength range and partially beyond to even shorter wavelengths. HHG lasers generate ultrashort EUV or x-ray pulses with a small beam divergence.

光子束可具有0.5 nm至200 nm、較佳地1 nm至100 nm、更好是1 nm至50 nm、且最佳是1 nm至20 nm之光點直徑。光點直徑表示光子束之全寬半高值(Full Width Half Maximum,FWHM)。The photon beam may have a spot diameter of 0.5 nm to 200 nm, preferably 1 nm to 100 nm, more preferably 1 nm to 50 nm, and most preferably 1 nm to 20 nm. The spot diameter represents the Full Width Half Maximum (FWHM) of the photon beam.

光子束可包含多個脈衝,脈衝其具有0.5 fs至200 fs、較佳地1 fs至100 fs、更好是2 fs至50 fs、且最佳是3 fs至30 fs範圍內的脈衝長度。縮寫「fs」代表飛秒(Femtosecond)。The photon beam may include a plurality of pulses having a pulse length in the range of 0.5 fs to 200 fs, preferably 1 fs to 100 fs, more preferably 2 fs to 50 fs, and most preferably 3 fs to 30 fs. The abbreviation "fs" stands for femtosecond.

光子束之脈衝可具有0.5 nW至2 nW、較佳地0.2 nW至5 nW、更好是0.1 nW至10 nW、且最佳是0.05 nW至20 nW範圍內的脈衝功率。The pulse of the photon beam may have a pulse power in the range of 0.5 nW to 2 nW, preferably 0.2 nW to 5 nW, more preferably 0.1 nW to 10 nW, and most preferably 0.05 nW to 20 nW.

根據本發明的裝置可更包含一控制裝置,其設計成將至少一第一反射鏡及/或至少一第二反射鏡移動越過一目視(Macroscopic)距離。The device according to the invention may further comprise a control device, which is designed to move the at least one first reflector and/or the at least one second reflector over a macroscopic distance.

憑藉將至少一第一或至少一第二反射鏡帶到至少一光源之光子束中,可在修復模式與檢驗模式之間來回切換,而無需移動光學組件。By bringing at least one first or at least one second reflector into the photon beam of at least one light source, it is possible to switch back and forth between repair mode and inspection mode without moving the optical components.

根據本發明的裝置可包含一菲涅耳(Fresnel)波帶片,及/或控制裝置可設計成將菲涅耳波帶片移入光子束並移出光子束。The device according to the invention may comprise a Fresnel zone plate and/or the control device may be designed to move the Fresnel zone plate into and out of the photon beam.

在一第二具體實例中,以上定義裝置包含一菲涅耳波帶片,其使得可在一修復操作模式與一檢驗操作模式之間變更。In a second specific example, the above defined device comprises a Fresnel zone plate which enables changing between a repair mode of operation and a test mode of operation.

控制裝置可更設計成建置裝置為使用光子束的檢驗模式,及/或控制裝置可另外設計成在檢驗模式與修復模式之間切換裝置。The control device may be further configured to set the device to a test mode using a photon beam, and/or the control device may be further configured to switch the device between a test mode and a repair mode.

根據本發明的裝置之關鍵優勢在於,此裝置首先使其可檢驗光學組件及/或光學組件之缺陷,且其次允許修復缺陷,而不必將光學組件從修復工具移動到檢測工具並與之重新對準。而且,將光學組件從一第一工具轉移到一第二工具通常使真空受到破壞,此外此會減慢製程序列。為了所提原因,根據本發明的裝置與先前技術相比急劇加速修復製程。The key advantage of the device according to the invention is that it firstly makes it possible to inspect optical components and/or defects of optical components and secondly allows to repair defects without having to move the optical components from a repair tool to a test tool and realign them therewith. Moreover, transferring the optical components from a first tool to a second tool usually causes the vacuum to be broken, which in addition slows down the process sequence. For the reasons mentioned, the device according to the invention drastically speeds up the repair process compared to the prior art.

根據本發明的裝置可更包含一用於固定光學組件之樣品夾,樣品夾係設計成將光學組件繞著至少一軸旋轉,及/或樣品夾可更設計成為了用光子束檢驗光學組件之一實質無缺陷區域,而將光學組件在至少一側向方向移置。The device according to the present invention may further comprise a sample holder for fixing the optical component, the sample holder being designed to rotate the optical component around at least one axis, and/or the sample holder may be further designed to displace the optical component in at least one lateral direction in order to inspect a substantially defect-free area of the optical component using a photon beam.

缺陷之修復可藉助光子束之實質上垂直入射在光學組件上而執行。為了檢驗光學組件之目的,例如為了檢查修復製程是否成功之目的,有必要將光子束以相對於法線方向的角度入射在光學組件上,前述角度係為了此目的而由設計所設想。此條件可藉由旋轉光學組件而確立。因此,光學組件之經修復區域之最佳可能的空間影像可在檢驗模式下獲得。The repair of defects can be performed by means of a substantially normal incidence of the photon beam on the optical component. For the purpose of testing the optical component, for example for the purpose of checking whether the repair process has been successful, it is necessary that the photon beam is incident on the optical component at an angle relative to the normal direction, which is provided by the design for this purpose. This condition can be established by rotating the optical component. Thus, the best possible spatial image of the repaired area of the optical component can be obtained in the test mode.

在第二具體實例之一替代示例性具體實例中,為了滿足用於光學組件的布拉格條件,移動裝置之至少一反射鏡而非光學組件。In an alternative exemplary embodiment of the second embodiment, in order to satisfy the Bragg condition for the optical component, at least one reflector of the moving device is moved instead of the optical component.

至少一光源可包含一第一光源,其設計成為了修復至少一缺陷之目的而在至少一缺陷上方掃描一聚焦光子束,並可包含一第二光源,其設計成將一光子束引導到光學組件包含至少至少一缺陷之區域上。The at least one light source may include a first light source configured to scan a focused photon beam over the at least one defect for the purpose of repairing the at least one defect, and may include a second light source configured to direct a photon beam onto a region of the optical component that includes at least one defect.

在一第三具體實例中,根據本發明的裝置包含兩分開光源,其係為了其各自任務而最佳化。兩光源之設置可選擇,使得無需為了在修復模式與檢驗模式之間切換而將任何部分移動越過目視距離。In a third embodiment, the device according to the invention comprises two separate light sources which are optimized for their respective tasks. The arrangement of the two light sources can be selected so that no part needs to be moved beyond visual distance in order to switch between the repair mode and the inspection mode.

第一與第二光源可產生光學組件之光化波長範圍內的光子束。第一光源可產生光化波長範圍外的光子束,而第二光源可產生光化波長範圍內的光子束。The first and second light sources can generate a beam of photons within the actinic wavelength range of the optical component. The first light source can generate a beam of photons outside the actinic wavelength range, and the second light source can generate a beam of photons within the actinic wavelength range.

在修復期間及/或在檢驗期間,光學組件可包含一薄膜,光子束透過其輻射。During repair and/or during inspection, the optical component may include a thin film through which the photon beam is radiated.

根據本發明的裝置之一優勢在於,裝置可執行光學組件之修復製程和檢驗製程兩者,其中光學組件包含一薄膜。因此,缺陷係採用其在光學組件之操作期間表現出的方式進行檢驗。再者,修復製程係在類似於其使用光學組件的條件之條件下執行。一進一步優勢在於,修復可透過薄膜執行,其中在修復製程之結束之後,薄膜維持全功能,並因此不必變更。而且,安裝在光學組件上的薄膜防止從光學組件去除的材料沉積在裝置中或光學組件之遠端位置上並由此污染光學組件。沉降光罩去除的材料在薄膜上並無不利於或僅在很小程度上不利於即將由光罩執行的曝光製程。One advantage of the device according to the invention is that the device can perform both a repair process and an inspection process of an optical component, wherein the optical component comprises a film. Thus, defects are inspected in the way they manifest themselves during operation of the optical component. Furthermore, the repair process is performed under conditions similar to those under which the optical component is used. A further advantage is that the repair can be performed through the film, wherein after the end of the repair process, the film remains fully functional and therefore does not have to be changed. Moreover, the film mounted on the optical component prevents material removed from the optical component from being deposited in the device or at a remote location of the optical component and thereby contaminating the optical component. Material removed by the deposited mask on the film does not adversely affect or only adversely affects to a very small extent the exposure process to be performed by the mask.

一種在極紫外線(EUV)波長範圍內修復光學組件的至少一缺陷之方法,其中光學組件包含一基材及一配置在基材上的多層結構,方法包含下列步驟:(a)產生EUV波長範圍內及/或軟x光輻射之波長範圍內的一光子束;及(b)設定光子束,使得至少一缺陷係藉由局部更改光學組件而加以修復。A method for repairing at least one defect of an optical component in the extreme ultraviolet (EUV) wavelength range, wherein the optical component comprises a substrate and a multilayer structure arranged on the substrate, the method comprising the following steps: (a) generating a photon beam in the EUV wavelength range and/or in the wavelength range of soft x-ray radiation; and (b) configuring the photon beam so that the at least one defect is repaired by locally modifying the optical component.

設定光子束可包含以下群組之至少一者:聚焦光子束、變更光子束之一脈衝功率、變更光子束之一偏極、並變更光子束相對於光學組件之一法線方向之一入射角。Setting the photon beam may include at least one of the following groups: focusing the photon beam, changing a pulse power of the photon beam, changing a polarization of the photon beam, and changing an incident angle of the photon beam relative to a normal direction of the optical component.

根據本發明的方法可更包含下列步驟:在用光子束修復光學組件的至少一缺陷與用光子束檢驗光學組件及/或光學組件的至少一缺陷之間切換。The method according to the present invention may further comprise the step of switching between repairing at least one defect of the optical component with a photon beam and inspecting the optical component and/or at least one defect of the optical component with a photon beam.

根據本發明的方法可更包含下列步驟之至少一者:(a)用光子束檢驗至少一缺陷,及/或用光子束檢驗一實質無缺陷參考定位;(b)若至少一檢驗到缺陷超過一預定閾值,則針對至少一檢驗到缺陷判定一修復形式;(c)用光子束修復至少一缺陷;(d)用光子束檢驗光學組件之一經修復位置;及(e)若至少一缺陷之一剩餘殘留超過預定閾值,則重複步驟a.和b.。The method according to the present invention may further include at least one of the following steps: (a) inspecting at least one defect with a photon beam and/or inspecting a substantially defect-free reference position with a photon beam; (b) determining a repair form for at least one detected defect if at least one detected defect exceeds a predetermined threshold; (c) repairing at least one defect with a photon beam; (d) inspecting a repaired position of an optical component with a photon beam; and (e) repeating steps a. and b. if a remaining residue of at least one defect exceeds a predetermined threshold.

根據以上所說明態樣中任一者的裝置可設計成執行以上所明確說明方法中任一者之方法步驟。An apparatus according to any of the above described aspects may be designed to perform the method steps of any of the above explicitly described methods.

最後,一種電腦程式,其包含指令,當由一電腦系統執行時,指令使得電腦系統執行以上所說明態樣之方法步驟。Finally, a computer program comprises instructions which, when executed by a computer system, cause the computer system to perform the method steps described above.

以下更詳細解說根據本發明之用於極紫外線(EUV)波長範圍內修復光刻光罩的一或多個缺陷之裝置及方法的目前較佳具體實例。然而,根據本發明的裝置及方法不受限於以下討論的多個實施例。而是,一般來說可將其用於在極紫外線(EUV)波長範圍內修復光學組件缺陷。除了EUV光罩之外,用於EUV波長範圍的光學組件之多個實施例包括EUV反射鏡,即用於EUV波長範圍的反射鏡。The following is a more detailed description of currently preferred embodiments of the apparatus and method for repairing one or more defects of a lithography mask in the extreme ultraviolet (EUV) wavelength range according to the present invention. However, the apparatus and method according to the present invention are not limited to the embodiments discussed below. Rather, they can generally be used to repair defects of optical components in the extreme ultraviolet (EUV) wavelength range. In addition to EUV masks, embodiments of optical components for the EUV wavelength range include EUV mirrors, i.e., mirrors for the EUV wavelength range.

圖1在上部影像105中示意性呈現用於EUV波長範圍的光刻光罩100之區段之側視圖。以下用於EUV波長範圍的光刻光罩100也稱為EUV光罩100。圖1中的示例性EUV光罩100係設計用於13.5 nm之區域中的曝光波長或光化波長。EUV光罩100具有由熱膨脹係數低的材料(例如石英)製成的基材110。其他介電體、玻璃材料、或半導體材料同樣可用作用於EUV光罩的基材,例如ZERODUR® 、ULE® 、或CLEARCERAM® 等。EUV光罩100之基材110之後側或後側表面用於在EUV光罩100之生產期間以及在EUV光罩100在EUV光刻設備中的操作期間托住基材110。較佳地,用於將基材托住在靜電夾盤(Electrostatic Chuck,ESC)上的薄導電層係施加到基材110之後側(圖1中未繪示)。在替代具體實例中,EUV光罩100在光罩基材110之後側上沒有導電層,且EUV光罩100係在其在EUV光刻設備中的操作期間借助於真空吸盤(Vacuum Chuck,VC)進行固定。FIG. 1 schematically presents a side view of a section of a lithography mask 100 for the EUV wavelength range in the upper image 105. Hereinafter, the lithography mask 100 for the EUV wavelength range is also referred to as EUV mask 100. The exemplary EUV mask 100 in FIG. 1 is designed for exposure wavelengths or actinic wavelengths in the region of 13.5 nm. The EUV mask 100 has a substrate 110 made of a material with a low coefficient of thermal expansion, such as quartz. Other dielectrics, glass materials, or semiconductor materials can also be used as substrates for EUV masks, such as ZERODUR® , ULE® , or CLEARCERAM® . The back side or back side surface of the substrate 110 of the EUV mask 100 is used to hold the substrate 110 during production of the EUV mask 100 and during operation of the EUV mask 100 in an EUV lithography apparatus. Preferably, a thin conductive layer for holding the substrate on an electrostatic chuck (ESC) is applied to the back side of the substrate 110 (not shown in FIG. 1 ). In an alternative embodiment, the EUV mask 100 has no conductive layer on the back side of the mask substrate 110 and the EUV mask 100 is fixed by means of a vacuum chuck (VC) during its operation in the EUV lithography apparatus.

含有20至80成對之交替鉬(Mo)與矽(Si)層(以下也稱為MoSi層)的多層膜或多層結構120係沉積在基材110之前側上。Mo層之厚度為4.15 nm,而Si層具有2.80 nm之厚度。為了保護多層結構120,通常具有約7 nm之厚度的覆蓋層130(例如由二氧化矽製成)係施加在最上方矽層上。其他材料(例如釕(Ru))同樣可用於形成覆蓋層130。代替鉬,也可將由具有高質量數的其他元素構成的層用於MoSi層,例如鈷(Co)、鎳(Ni)、鎢(W)、錸(Re)、鋯(Zn)、或銥(Ir)。舉例來說,多層結構120之沉積可藉由離子束沉積(Ion Beam Deposition,IBD)而執行。A multilayer film or multilayer structure 120 containing 20 to 80 pairs of alternating molybdenum (Mo) and silicon (Si) layers (hereinafter also referred to as MoSi layers) is deposited on the front side of the substrate 110. The Mo layer has a thickness of 4.15 nm, while the Si layer has a thickness of 2.80 nm. To protect the multilayer structure 120, a capping layer 130 (e.g. made of silicon dioxide) having a thickness of typically about 7 nm is applied on the topmost silicon layer. Other materials, such as ruthenium (Ru), can also be used to form the capping layer 130. Instead of molybdenum, layers composed of other elements with high mass numbers, such as cobalt (Co), nickel (Ni), tungsten (W), rhodium (Re), zirconium (Zn), or iridium (Ir), may also be used for the MoSi layer. For example, the deposition of the multilayer structure 120 may be performed by ion beam deposition (IBD).

一吸收層係沉積在EUV光罩100之覆蓋層130上。適用於吸收層的材料尤其係Cr、氮化鈦(TiN)、及/或氮化鉭(TaN)。例如由氮氧化鉭(TaON)構成的抗反射層可施加到吸收層(圖1中未繪示)。吸收層係借助於例如電子束或雷射束進行構造化,使得吸收圖案元件之結構係從整個面積吸收層生成。圖1中的區段繪示比設計所設想更寬的圖案元件140。過剩材料150係EUV光罩100之缺陷150。由於缺陷150,無EUV光子或至少比設計所設想更少許多的EUV光子係從過剩材料150之區域反射。An absorption layer is deposited on the cover layer 130 of the EUV mask 100. Suitable materials for the absorption layer are in particular Cr, titanium nitride (TiN), and/or tantalum nitride (TaN). An antireflection layer, for example of tantalum oxynitride (TaON), can be applied to the absorption layer (not shown in FIG. 1 ). The absorption layer is structured, for example by means of an electron beam or a laser beam, so that the structure of the absorption pattern element is generated from the entire area of the absorption layer. The section in FIG. 1 shows a pattern element 140 that is wider than envisaged by the design. Excess material 150 is a defect 150 of the EUV mask 100. Due to the defect 150, no EUV photons or at least many fewer EUV photons than envisaged by the design are reflected from the area of the excess material 150.

過剩吸收劑材料之缺陷150可借助於EUV雷射束160或EUV光子束160進行去除。EUV光子束可例如藉由在焦點處或焦點附近聚焦並暴露於氣體流動的泵浦雷射之超短脈衝而產生。使用的泵浦雷射可為例如鈦藍寶石雷射,其較佳在800 nm之波長處發射飛秒光脈衝。舉例來說,氪或氙等惰性氣體目前較佳用作用於產生EUV光子束160的氣體。從泵浦雷射光束之約1014 W/cm2 之二維功率密度或約1014 J/(cm2 ·s)之光子通量密度開始,高諧波係在氣體流動中產生。高諧波之產生係在技術領域中稱為高諧波產生(HHG)。在以上指出極高強度處,泵浦束之電場到達相當於個別原子中的電場的場強度。原子內電場係受到泵浦雷射束之焦點處的電場變形或干擾,使得電子可克服其到原子的鍵結並可穿隧到連續體(Continuum)中。然後,自由電子係透過複數或大量(多達數百個)光子之吸收而在雷射場中進行加速。在雷射之電場變更記號後,電子之一些立即係在電子所源自的原子之電場中進行減速,並以一高能光子或幾個高能光子之形式發射其能量。可藉由此原理而產生的最高光子能量,係受到電子在加速階段中吸收到的最大光子數量限制。在泵浦雷射光之振盪持續時間期間,產生光束發散小的兩個同調超短次飛秒脈衝。The defect 150 of excess absorber material can be removed by means of an EUV laser beam 160 or an EUV photon beam 160. The EUV photon beam can be generated, for example, by ultrashort pulses of a pump laser that are focused at or near the focus and exposed to a gas flow. The pump laser used can be, for example, a titanium sapphire laser, which preferably emits femtosecond light pulses at a wavelength of 800 nm. For example, noble gases such as krypton or xenon are currently preferably used as gases for generating the EUV photon beam 160. Starting from a two-dimensional power density of the pump laser beam of about 10 14 W/cm 2 or a photon flux density of about 10 14 J/(cm 2 ·s), high harmonics are generated in the gas flow. The generation of high harmonic waves is known in the technical field as high harmonic generation (HHG). At the extremely high intensities indicated above, the electric field of the pump beam reaches field strengths that are equivalent to the electric field in individual atoms. The electric field inside the atom is deformed or disturbed by the electric field at the focus of the pump laser beam, so that the electron can overcome its bond to the atom and can tunnel into the continuum. The free electrons are then accelerated in the laser field by the absorption of multiple or large numbers (up to hundreds) of photons. Immediately after the electric field of the laser changes sign, some of the electrons are decelerated in the electric field of the atom from which they originated and emit their energy in the form of one or several high-energy photons. The highest photon energy that can be generated by this principle is limited by the maximum number of photons absorbed by the electrons during the acceleration phase. During the oscillation duration of the pump laser light, two coherent ultrashort sub-femtosecond pulses with small beam divergence are generated.

從產生的諧波之多樣性(Multiplicity),可借助於EUV光譜儀以選擇在例如在13.5 nm處的光化波長範圍內或最接近於光化波長範圍的諧波。在光化波長範圍內,HHG雷射系統目前達成約1 µW之平均功率,給定每個光子100 eV之假設光子能量,此對應於約7·1010 光子/秒之光子通量。From the diversity of the generated harmonics, it is possible to select harmonics in or closest to the actinic wavelength range, for example at 13.5 nm, with the aid of an EUV spectrometer. In the actinic wavelength range, HHG laser systems currently achieve average powers of about 1 µW, which, given an assumed photon energy of 100 eV per photon, corresponds to a photon flux of about 7·10 10 photons/second.

然後,假設EUV光子之10%可集中在100 nm之光點直徑中。此對應於約7·106 光子/(nm2 ·s)之光子通量密度。此對應於約103 J/cm2 之能量通量密度,並因此係非常明顯高於用於飛秒雷射脈衝的閾值能量密度。如以上已解說,兩個相互增強因子有助於例如HHG雷射系統之EUV雷射之光子束之相當龐大的能量通量密度。首先,由於EUV光子之波長非常短,可將其聚焦在小面積上。其次,相較於來自可見光譜範圍的光子,單一EUV光子攜帶大量能量。Then, assume that 10% of the EUV photons can be concentrated in a spot diameter of 100 nm. This corresponds to a photon flux density of about 7·10 6 photons/(nm 2 ·s). This corresponds to an energy flux density of about 10 3 J/cm 2 and is therefore very significantly higher than the threshold energy density for femtosecond laser pulses. As already explained above, two mutually reinforcing factors contribute to the rather large energy flux density of the photon beam of an EUV laser, such as an HHG laser system. Firstly, due to the very short wavelength of EUV photons, they can be focused on a small area. Secondly, a single EUV photon carries a lot of energy compared to photons from the visible spectrum.

在文獻「用短與超短雷射脈衝的金屬剝蝕(Metal Ablation with Short and Ultrashort Laser Pulses)」,《物理學學報》(Physics Procedia)12(2011)第230-238頁,作者K.H. Leitz等人研究借助於微秒、奈秒、皮秒、和飛秒雷射脈衝的材料剝蝕。對於飛秒雷射脈衝,此些作者指出用於接近可見光譜範圍的雷射輻射的1.25 J/cm2 之閾值能量密度。In the article "Metal Ablation with Short and Ultrashort Laser Pulses", Physics Procedia 12 (2011), pp. 230-238, KH Leitz et al. study material ablation with the aid of microsecond, nanosecond, picosecond, and femtosecond laser pulses. For femtosecond laser pulses, the authors indicate a threshold energy density of 1.25 J/cm 2 for laser radiation close to the visible spectrum.

EUV光子束160之交互作用區係如圖1中的元件符號170所示。飛秒脈衝之光子與物質之間的交互作用係不再可由傳統剝蝕模型(其考慮熱傳導、熔化、蒸發、和電漿形成之製程)加以說明。說明光子束與物質之間的超快交互作用的非傳統剝蝕模型係基於以下假設:當超短雷射脈衝作用在物質上時,金屬中的電子或電子雲(Electron gas)係不再處於與原子核的熱平衡。在飛秒時間尺度上,電子雲無法立刻將其能量發射到原子核之晶格。局部非常高的壓力、密度、和溫度在飛秒雷射脈衝之作用下發生,並將缺陷150之離子化材料加速至高速。由於交互作用時間短,缺陷150之材料無法連續蒸發,而是係轉變成過熱液體之狀態。過熱液體聚結為液滴和迅速擴散的蒸汽之高壓混合物。液滴係如圖1中的元件符號180所示。The interaction region of the EUV photon beam 160 is shown as component symbol 170 in Figure 1. The interaction between the photons of the femtosecond pulse and the matter can no longer be explained by the traditional erosion model (which takes into account the processes of heat conduction, melting, evaporation, and plasma formation). The non-traditional erosion model that explains the ultrafast interaction between the photon beam and the matter is based on the following assumption: When the ultrashort laser pulse acts on the matter, the electrons or electron gas in the metal are no longer in thermal equilibrium with the atomic nuclei. On the femtosecond time scale, the electron cloud cannot immediately emit its energy to the lattice of the atomic nuclei. Locally very high pressures, densities, and temperatures occur under the action of the femtosecond laser pulse and accelerate the ionized material of the defect 150 to high speeds. Due to the short interaction time, the material of defect 150 cannot continue to evaporate, but is transformed into a superheated liquid state. The superheated liquid coalesces into a high-pressure mixture of droplets and rapidly expanding vapor. The droplets are shown as component symbol 180 in FIG. 1 .

EUV光子束160之超短脈衝係在缺陷150上方進行掃描。在此種情況下,可在將光子束160聚焦在缺陷150之新定位上之前,一個、複數個、或大量(例如數百個)脈衝可引導到缺陷150之相同位置上。為了能夠更佳處理缺陷150,如有必要可將光子束160及/或EUV光罩100從法線方向傾斜。An ultra-short pulse of the EUV photon beam 160 is scanned over the defect 150. In this case, one, a plurality, or a large number (e.g., hundreds) of pulses may be directed to the same location of the defect 150 before focusing the photon beam 160 on the new location of the defect 150. To better address the defect 150, the photon beam 160 and/or the EUV mask 100 may be tilted from the normal direction if necessary.

圖2示意性顯示從EUV光罩100之缺陷150之區域反射EUV光子增加。將具有圖案元件140之等同設置但沒有缺陷位置150或缺陷定位150的EUV光罩100之位置視為參考。EUV光罩100之含缺陷區域係與此參考定位相關。憑藉借助於EUV光子束160從EUV光罩之覆蓋層130去除的缺陷150之過剩吸收劑材料,從EUV光罩反射的光學強度局部上升。一旦從缺陷150之區域反射的輻射到達參考區域之層級,即藉由將EUV光子束160關閉或中斷而停止修復製程。FIG. 2 schematically shows an increase in the reflection of EUV photons from the area of a defect 150 of an EUV mask 100. A position of an EUV mask 100 with an identical arrangement of pattern elements 140 but without a defect location 150 or a defect position 150 is considered as a reference. The defect-containing area of the EUV mask 100 is related to this reference position. Due to the excess absorber material of the defect 150 being removed from the cover layer 130 of the EUV mask by means of the EUV photon beam 160, the optical intensity reflected from the EUV mask increases locally. As soon as the radiation reflected from the area of the defect 150 reaches the level of the reference area, the repair process is stopped by switching off or interrupting the EUV photon beam 160.

修復製程可採用多種方式進行監控。首先,從含缺陷區域反射的EUV波長範圍內的光學強度可藉助能量感測器在修復製程期間持久進行測量。此是繪示在圖2中。然而,也可能不時中斷修復製程,並借助於大面積EUV光子束和偵測器監控來自缺陷150之區域的光學反射。最後,為了分析能量選擇性的x光光子(在修復製程期間由缺陷150產生),也可使用能量分散x光偵測器。由此可分析缺陷150之材料組成,並確定EUV光子束160何時到達EUV光罩之覆蓋層130。The repair process can be monitored in a number of ways. Firstly, the optical intensity in the EUV wavelength range reflected from the defect-containing area can be measured permanently during the repair process by means of energy sensors. This is illustrated in FIG. 2 . However, it is also possible to interrupt the repair process from time to time and monitor the optical reflection from the area of the defect 150 by means of a large-area EUV photon beam and a detector. Finally, in order to analyse the energy-selective x-ray photons generated by the defect 150 during the repair process, an energy-dispersive x-ray detector can also be used. This allows the material composition of the defect 150 to be analysed and it can be determined when the EUV photon beam 160 reaches the cover layer 130 of the EUV mask.

圖3中的上部影像305顯示具有圖案元件340之遺漏吸收劑材料之缺陷350的EUV光罩300之區段之側視圖。下部影像355呈現相關聯俯視圖。缺陷350的特色在於事實上,EUV光子係從EUV光罩300應顯得深色(dark)之區域反射。遺漏吸收劑材料之缺陷350可以各種方式加以修復。首先,可藉助聚焦EUV光子束360剝蝕缺陷區域350下方的多層結構120。此確保無EUV光子可再從缺陷350之區域反射。元件符號370繪示EUV光子束360與EUV光罩300之多層結構120之材料之局部交互作用區。The upper image 305 in FIG. 3 shows a side view of a section of an EUV mask 300 having a defect 350 of missing absorber material of a pattern element 340. The lower image 355 presents an associated top view. The defect 350 is characterized by the fact that EUV photons are reflected from areas of the EUV mask 300 that should appear dark. The defect 350 of missing absorber material can be repaired in various ways. First, the multi-layer structure 120 below the defect area 350 can be etched by means of a focused EUV photon beam 360. This ensures that no EUV photons can be reflected from the area of the defect 350 anymore. Element symbol 370 shows the local interaction area of the EUV photon beam 360 with the material of the multi-layer structure 120 of the EUV mask 300.

為了修復缺陷350,也可僅去除缺陷350之區域中的多層結構120之一部分即為足夠。多層結構120之最上層通常主要有助於EUV光子之反射。再者,特別是對於遺漏吸收劑材料之小面積缺陷350,可局部熔化缺陷之區域中的多層結構120之表面即已足夠,使得覆蓋層130之平整度及(若適當時)多層結構120之最上層之平整度局部受到干擾或破壞。In order to repair the defect 350, it may also be sufficient to remove only a portion of the multilayer structure 120 in the region of the defect 350. The uppermost layer of the multilayer structure 120 usually contributes primarily to the reflection of EUV photons. Furthermore, in particular for small-area defects 350 with missing absorber material, it may be sufficient to locally melt the surface of the multilayer structure 120 in the region of the defect, so that the planarity of the cover layer 130 and, if appropriate, the uppermost layer of the multilayer structure 120 is locally disturbed or destroyed.

參考圖3解說的修復製程也可用於修復用於EUV波長範圍的反射鏡(圖3中未繪示)之光學強度之局部過剩。EUV反射鏡之局部提高反射率可藉由多層結構120及/或基材110之缺陷而引起。3 can also be used to repair local excesses of optical intensity in mirrors for the EUV wavelength range (not shown in FIG3 ). Locally increased reflectivity of EUV mirrors can be caused by defects in the multilayer structure 120 and/or the substrate 110 .

圖4示意性繪示由於執行圖3中所說明的修復製程之結果,EUV光罩300之局部反射光學強度之變更。採用類似於圖2的方式,從缺陷350之區域反射的強度係用等同圖案正規化到EUV光罩300之無缺陷區域。由於遺漏吸收劑材料之缺陷350,EUV光子係從EUV光罩300實際上應為深色之區域反射。因此,缺陷350導致EUV光罩300之局部提高反射率。使用EUV光子束360修復缺陷350減少光學強度之局部過剩。從缺陷之區域反射的輻射到達參考層級後,立即結束EUV光罩300之修復製程。FIG. 4 schematically illustrates the change in the local reflected optical intensity of the EUV mask 300 as a result of performing the repair process illustrated in FIG. 3 . In a manner similar to FIG. 2 , the intensity reflected from the area of the defect 350 is normalized to the defect-free area of the EUV mask 300 using an equivalent pattern. Due to the defect 350 of missing absorber material, EUV photons are reflected from areas of the EUV mask 300 that should actually be dark. Therefore, the defect 350 causes a local increase in reflectivity of the EUV mask 300. Repairing the defect 350 using an EUV photon beam 360 reduces the local excess of optical intensity. The repair process of the EUV mask 300 is terminated immediately after the radiation reflected from the area of the defect reaches the reference level.

圖5中上部影像505呈現在多層結構120之覆蓋層130上具有顆粒550的EUV光罩500之區段之剖面之側視圖。下部影像555進而呈現相關聯俯視圖。顆粒550遮蔽用於入射EUV光子的多層結構120之一部分,此具有效果在於,相較於從無缺陷參考區域,EUV光罩500從缺陷550(即顆粒550)之區域反射較少光子。顆粒550可藉助聚焦光子束560而從EUV光罩500之覆蓋層130進行剝蝕。元件符號570進而繪示EUV光子束560與顆粒550之交互作用區。The upper image 505 in FIG. 5 presents a side view of a cross section of a section of an EUV reticle 500 having particles 550 on a capping layer 130 of a multi-layer structure 120. The lower image 555 further presents a related top view. The particles 550 shield a portion of the multi-layer structure 120 from incident EUV photons, which has the effect that the EUV reticle 500 reflects fewer photons from the area of the defect 550 (i.e., the particle 550) than from a non-defective reference area. The particles 550 can be etched from the capping layer 130 of the EUV reticle 500 by means of a focused photon beam 560. Element symbol 570 further illustrates the interaction region of the EUV photon beam 560 and the particles 550.

為了原位分析顆粒550之材料組成(圖5中未繪示),當去除顆粒550時,在剝蝕製程期間使用能量分散x光偵測器具優勢。由此,針對顆粒550可監控剝蝕製程之結束。而且,顆粒550之來源時常可從其材料組成推斷出。若達成此點,則可消除或至少急劇減少污染之來源,使得可避免未來修復製程。In order to analyze the material composition of the particle 550 in situ (not shown in FIG. 5 ), an energy dispersive x-ray detector is used during the stripping process to advantage when removing the particle 550. Thus, the end of the stripping process can be monitored for the particle 550. Moreover, the source of the particle 550 can often be inferred from its material composition. If this is achieved, the source of contamination can be eliminated or at least drastically reduced, so that future repair processes can be avoided.

圖6中的示意圖695顯示EUV光罩600之區段之側視圖。EUV光罩600可為含缺陷EUV光罩100、300、或500之一。亦即,光罩600之缺陷650可為缺陷150、350、或550之一,且吸收劑圖案640可包含EUV光罩100、300、或500之圖案元件140、340、540之一。再者,交互作用區670可為交互作用區170、370、或570之一。再者,圖6繪示用於修復缺陷650並檢驗EUV光罩600(或一般來說用於EUV波長範圍的光學組件100、300、500)的裝置700之一第一示例性具體實例。Schematic diagram 695 in FIG. 6 shows a side view of a section of EUV reticle 600. EUV reticle 600 can be one of defective EUV reticle 100, 300, or 500. That is, defect 650 of reticle 600 can be one of defects 150, 350, or 550, and absorber pattern 640 can include one of pattern elements 140, 340, 540 of EUV reticle 100, 300, or 500. Furthermore, interaction region 670 can be one of interaction regions 170, 370, or 570. Furthermore, FIG. 6 shows a first exemplary embodiment of an apparatus 700 for repairing defect 650 and inspecting EUV reticle 600 (or, in general, optical components 100, 300, 500 for use in the EUV wavelength range).

圖6示意性繪示修復缺陷650之部分製程。裝置700包含一用於EUV波長範圍的光源610,其產生一準直EUV光子束605。再者,裝置700包含一經由連接710連接到EUV光源610的控制裝置750。由EUV光源610產生的EUV光子束605係藉由一第一成像EUV反射鏡620而聚焦在EUV光罩600之缺陷650上。第一成像EUV反射鏡620係經由連接730連接到裝置700之控制裝置750。FIG6 schematically shows a part of the process for repairing a defect 650. The device 700 comprises a light source 610 for the EUV wavelength range, which generates a collimated EUV photon beam 605. Furthermore, the device 700 comprises a control device 750 connected to the EUV light source 610 via a connection 710. The EUV photon beam 605 generated by the EUV light source 610 is focused on the defect 650 of the EUV mask 600 by a first imaging EUV mirror 620. The first imaging EUV mirror 620 is connected to the control device 750 of the device 700 via a connection 730.

在聚焦EUV光子束630係藉由控制裝置750而在缺陷650上方進行掃描的同時,能量感測器690偵測從缺陷650之區域反射EUV光子680。能量感測器690同樣經由連接720連接到裝置700之控制裝置750。借助於能量感測器690,控制裝置750可在閉反饋迴路中操作EUV雷射系統610或EUV光源610。如圖2和圖4中示意性繪示,缺陷消除方面的進展可基於能量感測器690偵測到為時間之函數的反射光學強度之變更而推斷出。While the focused EUV photon beam 630 is scanned over the defect 650 by the control device 750, the energy sensor 690 detects EUV photons 680 reflected from the region of the defect 650. The energy sensor 690 is also connected to the control device 750 of the device 700 via a connection 720. With the aid of the energy sensor 690, the control device 750 can operate the EUV laser system 610 or the EUV light source 610 in a closed feedback loop. As schematically shown in Figures 2 and 4, progress in defect elimination can be inferred based on changes in the reflected optical intensity detected by the energy sensor 690 as a function of time.

圖7示意性顯示藉助裝置700檢驗圖6中繪示第一示例性具體實例的EUV光罩600之部分製程之實作。為了檢驗EUV光罩600之缺陷區域650之目的,裝置700之控制裝置750將第一成像EUV反射鏡620移出EUV光源610之準直EUV光子束605。因此,EUV光子束605可入射在第二成像EUV反射鏡660上。第二成像EUV反射鏡660將作為擴展光子束760的EUV光子束605引導到EUV光罩600之區域上,EUV光罩600包含內含缺陷650的區域。在圖6和圖7中繪示的示例性具體實例中,缺陷650包含顆粒550。EUV光罩600之多層結構120在偵測器780之方向上反射光束760之入射EUV光子之一部位。在圖7中繪示的示例性具體實例中,偵測器780包含一CCD攝影機。FIG. 7 schematically shows an implementation of a portion of a process for inspecting the EUV mask 600 of the first exemplary embodiment shown in FIG. 6 by means of the apparatus 700. For the purpose of inspecting the defect region 650 of the EUV mask 600, the control device 750 of the apparatus 700 moves the first imaging EUV mirror 620 out of the collimated EUV photon beam 605 of the EUV light source 610. Thus, the EUV photon beam 605 can be incident on the second imaging EUV mirror 660. The second imaging EUV mirror 660 directs the EUV photon beam 605 as an expanded photon beam 760 onto the region of the EUV mask 600, which includes the region containing the defect 650. In the exemplary embodiments shown in FIGS. 6 and 7, the defect 650 includes a particle 550. The multi-layer structure 120 of the EUV mask 600 reflects a portion of the incident EUV photons of the light beam 760 in the direction of a detector 780. In the exemplary embodiment illustrated in Figure 7, the detector 780 comprises a CCD camera.

圖8呈現根據本發明的裝置700之一第二示例性具體實例。第二示例性具體實例係基於修復EUV光罩600之缺陷650之一者之實施例而進行解說。用於修復缺陷650的裝置700包含第一示例性具體實例之EUV光源610。前述光源進而經由連接710連接到控制裝置750。再者,控制裝置750經由連接810連接到一非成像EUV反射鏡820、經由連接855連接到一菲涅耳波帶片850、並經由連接865連接到一能量感測器690。由EUV光源產生的EUV光子束605係藉由EUV反射鏡820而作為EUV光子束830引導到菲涅耳波帶片850上。菲涅耳波帶片850將通過其的EUV光子束840聚焦在EUV光罩600之缺陷650上。在修復期間,從EUV光罩600之缺陷區域650反射的EUV光860係由能量感測器690進行偵測。基於能量感測器偵測到的EUV輻射860(採用類似於第一示例性具體實例的方式),裝置700之控制裝置750可在閉反饋迴路(圖8中未繪示)中操作EUV光源610。FIG8 presents a second exemplary embodiment of an apparatus 700 according to the present invention. The second exemplary embodiment is explained based on an embodiment of repairing one of the defects 650 of an EUV mask 600. The apparatus 700 for repairing the defect 650 comprises the EUV light source 610 of the first exemplary embodiment. The aforementioned light source is in turn connected to the control device 750 via the connection 710. Furthermore, the control device 750 is connected to a non-imaging EUV mirror 820 via the connection 810, to a Fresnel zone plate 850 via the connection 855, and to an energy sensor 690 via the connection 865. The EUV photon beam 605 generated by the EUV light source is guided as the EUV photon beam 830 onto the Fresnel zone plate 850 by the EUV mirror 820. The Fresnel zone plate 850 focuses the EUV photon beam 840 passing therethrough onto the defect 650 of the EUV mask 600. During the repair, EUV light 860 reflected from the defect region 650 of the EUV mask 600 is detected by the energy sensor 690. Based on the EUV radiation 860 detected by the energy sensor (in a manner similar to the first exemplary embodiment), the control device 750 of the device 700 may operate the EUV light source 610 in a closed feedback loop (not shown in FIG. 8 ).

圖9顯示第二示例性具體實例之第二部分製程,亦即用EUV光源610之EUV光子束605檢驗EUV光罩600。為了檢驗EUV光罩600之目的,控制裝置750將菲涅耳波帶片850從EUV光子束之光束路徑移出920。不再聚焦的光子束830照射在EUV光罩600之多層結構120上缺陷650之區域中。為了入射的EUV光子束830盡可能滿足EUV光罩600之多層結構120之布拉格反射條件,控制裝置750使其上配置EUV光罩600的樣品夾旋轉。EUV光罩600之旋轉係如圖9中的元件符號910繪示。圖9中未繪示樣品夾(稱為:載台)。FIG9 shows the second part of the process of the second exemplary embodiment, namely, the inspection of the EUV mask 600 using the EUV photon beam 605 of the EUV light source 610. For the purpose of inspecting the EUV mask 600, the control device 750 moves the Fresnel zone plate 850 out of the beam path of the EUV photon beam 920. The photon beam 830, which is no longer focused, irradiates the region of the defect 650 on the multi-layer structure 120 of the EUV mask 600. In order for the incident EUV photon beam 830 to satisfy the Bragg reflection condition of the multi-layer structure 120 of the EUV mask 600 as much as possible, the control device 750 rotates the sample holder on which the EUV mask 600 is arranged. The rotation of the EUV mask 600 is shown as the component symbol 910 in FIG9. The sample holder (referred to as: carrier) is not shown in FIG9.

如圖9中的剩餘缺陷殘留650所示,若需要進一步修復步驟,則控制裝置750再次將EUV光罩600旋轉回到其初始定位上,並再次將菲涅耳波帶片850引入EUV光子830之光束路徑,使得可繼續修復剩餘缺陷殘留650。As shown by the remaining defect residues 650 in FIG. 9 , if further repair steps are required, the control device 750 rotates the EUV mask 600 back to its initial position again and introduces the Fresnel zone plate 850 into the beam path of the EUV photons 830 again so that the remaining defect residues 650 can continue to be repaired.

圖10中的示意圖1000繪示根據本發明的裝置700之一第三示例性具體實例。圖10中的第三示例性具體實例包含一第一EUV光源1010和一第二EUV光源1020,此兩者係經由連接1015和1025連接到控制裝置750。再者,控制裝置750係經由連接695連接到偵測器690。第三示例性具體實例同樣基於修復EUV光罩600之缺陷650而進行解說。The schematic diagram 1000 in FIG10 shows a third exemplary embodiment of the apparatus 700 according to the present invention. The third exemplary embodiment in FIG10 comprises a first EUV light source 1010 and a second EUV light source 1020, which are connected to the control device 750 via connections 1015 and 1025. Furthermore, the control device 750 is connected to the detector 690 via connection 695. The third exemplary embodiment is also explained based on repairing the defect 650 of the EUV mask 600.

根據本發明的裝置700之第三示例性具體實例之修復部分係在圖10中示意性呈現。為了修復缺陷650之目的,第二EUV光源1020在EUV光罩600之缺陷650上輻射聚焦光子束1030,或在缺陷650上方掃描聚焦光子束1030。The repairing portion of the third exemplary embodiment of the apparatus 700 according to the present invention is schematically presented in Fig. 10. For the purpose of repairing the defect 650, the second EUV light source 1020 radiates the focused photon beam 1030 on the defect 650 of the EUV mask 600 or scans the focused photon beam 1030 over the defect 650.

在預定時間之後,中斷修復製程並檢驗EUV光罩600之經處理或經修復位置650。為此目的(如圖11中示意性繪示),停止第二EUV光源之聚焦光子束1030。之後,啟動第一EUV光源1010,其將準直EUV光子束1130引導到EUV光罩600內含缺陷650之區域上。在此種情況下,採用未到達用於熔化EUV光罩600之多層結構120的閾值密度之量值,以選擇光束光點之面積。根據以上指出的估計,此需要約5 µm或更大之光點直徑。After a predetermined time, the repair process is interrupted and the processed or repaired position 650 of the EUV mask 600 is inspected. For this purpose (as schematically shown in FIG. 11 ), the focused photon beam 1030 of the second EUV light source is stopped. Afterwards, the first EUV light source 1010 is activated, which directs a collimated EUV photon beam 1130 onto the region of the EUV mask 600 containing the defect 650. In this case, the area of the beam spot is selected with a value that does not reach the threshold density for melting the multi-layer structure 120 of the EUV mask 600. According to the estimates indicated above, this requires a spot diameter of about 5 μm or more.

在圖10、圖11、和後續的圖12中,第一EUV光源1010和偵測器690係相對於EUV光罩600之法線方向配置,使得盡可能滿足針對EUV光罩600之光化波長範圍的布拉格反射條件。第三具體實例具有特別優勢:裝置700之任何部分皆不必為了在裝置700之修復模式與檢驗模式之間切換而移動越過目視距離。第一EUV光源1010和第二EUV光源可設計成使得單一EUV光源同時產生聚焦EUV光子束1030和EUV光子束1130兩者。在此具體實例中,第一EUV光源1010和第二EUV光源1020僅提供一光束塑形裝置及/或一光束導引裝置。In Figures 10, 11, and the subsequent Figure 12, the first EUV light source 1010 and the detector 690 are arranged relative to the normal direction of the EUV mask 600 so as to meet the Bragg reflection conditions for the actinic wavelength range of the EUV mask 600 as much as possible. The third embodiment has a particular advantage: no part of the device 700 needs to be moved beyond the visual distance in order to switch between the repair mode and the inspection mode of the device 700. The first EUV light source 1010 and the second EUV light source can be designed so that a single EUV light source simultaneously generates both the focused EUV photon beam 1030 and the EUV photon beam 1130. In this embodiment, the first EUV light source 1010 and the second EUV light source 1020 only provide a beam shaping device and/or a beam guiding device.

圖12顯示裝置700之示例性具體實例,其中兩光源1010和1020同時將光子1030和1130輻射到缺陷650上或缺陷650周圍的區域中。在此示例性具體實例中,若第一EUV光源1010將光化波長範圍內的EUV光子束1130輻射到EUV光罩600上,且第二EUV光源1020產生EUV光罩600之光化波長範圍外的光子則具優勢。此確保實質上沒有第二EUV光源1020之EUV光子能到達偵測器690。此防止偵測器690偵測到的局部反射光學強度受到破壞。12 shows an exemplary embodiment of the apparatus 700, wherein two light sources 1010 and 1020 simultaneously radiate photons 1030 and 1130 onto the defect 650 or into the area around the defect 650. In this exemplary embodiment, it is advantageous if the first EUV light source 1010 radiates a beam of EUV photons 1130 within the actinic wavelength range onto the EUV reticle 600, and the second EUV light source 1020 generates photons outside the actinic wavelength range of the EUV reticle 600. This ensures that substantially no EUV photons from the second EUV light source 1020 can reach the detector 690. This prevents the local reflected optical intensity detected by the detector 690 from being corrupted.

圖13重現圖6,其不同之處在於薄膜1310安裝在EUV光罩600上。EUV薄膜1310與EUV光罩之覆蓋層130之間的距離係在2至3 mm範圍內。EUV光罩600之修復製程和檢驗製程兩者係透過薄膜1310進行。因此,可在實際操作EUV光罩600之期間普遍存在的條件下,檢驗EUV光罩600之缺陷650之效果。再者,可避免為了缺陷校正而卸除薄膜1310,及在缺陷修復之後重新安裝薄膜1310,及可能損壞隨其結合的光罩600。FIG. 13 reproduces FIG. 6 , with the difference that the pellicle 1310 is mounted on the EUV mask 600. The distance between the EUV pellicle 1310 and the cover layer 130 of the EUV mask is in the range of 2 to 3 mm. Both the repair process and the inspection process of the EUV mask 600 are performed through the pellicle 1310. Therefore, the effect of the defect 650 of the EUV mask 600 can be inspected under the conditions that prevail during the actual operation of the EUV mask 600. Furthermore, the removal of the pellicle 1310 for defect correction and the reinstallation of the pellicle 1310 after defect repair and the possible damage to the mask 600 bonded thereto can be avoided.

如參考圖8至圖12所說明的EUV光罩600之修復製程及/或檢驗製程同樣可用安裝在EUV光罩上的薄膜1310執行。此具有兩個優勢。首先,修復可在光罩之操作條件下執行,且其次,可防止修復裝置之光學組件之污染。相較之下,從光罩去除並沉降在安裝在光罩上的薄膜上的材料幾乎不會干擾即將由光罩執行的曝光製程。The repair process and/or inspection process of the EUV mask 600 as described with reference to FIGS. 8 to 12 can also be performed with the pellicle 1310 mounted on the EUV mask. This has two advantages. First, the repair can be performed under the operating conditions of the mask, and second, contamination of the optical components of the repair device can be prevented. In contrast, the material removed from the mask and deposited on the pellicle mounted on the mask will hardly interfere with the exposure process to be performed by the mask.

以下參考圖14至圖16解說將藉助裝置700執行的修復製程嵌入EUV光罩100、300、500之缺陷分析和缺陷校正之工作序列中。在缺陷150、350、550可進行修復之前,必須先進行確認,然後進行分析。舉例來說,EUV-AIMSTM (空間影像測量系統)可用於分析缺陷150、350、550。圖14在左部影像1410中顯示條帶結構1420具有缺陷1450之區段之俯視圖。圖14中的右部影像1415呈現有關無缺陷參考條帶結構1425的區段之俯視圖。此兩影像皆由EUV-AIMSTM 進行記錄。從左部影像,可詳細分析缺陷1450。缺陷1450之分析可包含將含缺陷條帶結構1420與無缺陷參考條帶結構1425進行比較。針對缺陷1450的修復形式係從對缺陷1450之詳細分析建立。修復形式提供例如缺陷類型、缺陷大小、相對於一或多個圖案元件之缺陷定位、EUV光罩之圖案類型、及在光罩之操作期間之掃描器曝光設定。再者,修復形式說明EUV光罩上缺陷之尺寸之坐標,並相對於缺陷坐標指出即將為了修復缺陷而施加的能量劑量。針對缺陷1450所判定的修復形式係傳送到用於修復缺陷的裝置700。The following explanation of embedding the repair process performed by means of the device 700 into the work sequence of defect analysis and defect correction of the EUV mask 100, 300, 500 is explained with reference to Figures 14 to 16. Before the defects 150, 350, 550 can be repaired, they must first be confirmed and then analyzed. For example, EUV-AIMS TM (Aerial Image Measurement System) can be used to analyze the defects 150, 350, 550. Figure 14 shows a top view of a section of the strip structure 1420 with a defect 1450 in the left image 1410. The right image 1415 in Figure 14 presents a top view of a section of a defect-free reference strip structure 1425. Both images are recorded by EUV-AIMS TM . From the left image, the defect 1450 can be analyzed in detail. Analysis of defect 1450 may include comparing defect-containing strip structure 1420 to defect-free reference strip structure 1425. A repair profile for defect 1450 is established from a detailed analysis of defect 1450. The repair profile provides, for example, defect type, defect size, defect location relative to one or more pattern elements, pattern type of EUV mask, and scanner exposure settings during operation of the mask. Furthermore, the repair profile specifies the coordinates of the size of the defect on the EUV mask and indicates the energy dose to be applied to repair the defect relative to the defect coordinates. The repair profile determined for defect 1450 is transmitted to device 700 for repairing the defect.

圖15示意性呈現藉助裝置700之一具體實例以修復圖14的缺陷1450。圖15中的左上部影像1510實質上顯示圖14中的左部影像之區段,例如係在檢驗模式下由裝置700之EUV光子束760、830、1130成像。裝置700在檢驗或成像模式下「看到」圖14中的缺陷1450。右上部影像1515顯示圖14中的參考條帶結構1525,係用裝置700之EUV光子束760、830、1130記錄。FIG15 schematically presents a repair of the defect 1450 of FIG14 by means of one specific example of the apparatus 700. The upper left image 1510 of FIG15 substantially shows a section of the left image of FIG14, imaged, for example, by the EUV photon beam 760, 830, 1130 of the apparatus 700 in the inspection mode. The apparatus 700 "sees" the defect 1450 of FIG14 in the inspection or imaging mode. The upper right image 1515 shows the reference stripe structure 1525 of FIG14, recorded by the EUV photon beam 760, 830, 1130 of the apparatus 700.

藉助裝置之EUV光子束630、840、1030對缺陷1450之修復製程係如圖15中的箭頭1580所示。如以上已解說,裝置700從缺陷檢測工具(例如EUV-AIMSTM )獲得針對缺陷1450的修復形式。為了修復缺陷1450之目的,EUV光子束630、840、1030(如修復形式所預定)係在缺陷150、350、550、1450上方進行掃描。The repair process of the defect 1450 by means of the EUV photon beam 630, 840, 1030 of the apparatus is shown by arrow 1580 in FIG15. As explained above, the apparatus 700 obtains a repair pattern for the defect 1450 from a defect inspection tool (e.g., EUV-AIMS ). For the purpose of repairing the defect 1450, the EUV photon beam 630, 840, 1030 (as predetermined by the repair pattern) is scanned over the defect 150, 350, 550, 1450.

為了分析剩餘缺陷殘留,可時常中斷對缺陷1450之修復。對修復之中斷可週期性進行或由修復形式所預定。In order to analyze the remaining defect residues, the repair of defect 1450 may be interrupted from time to time. The interruption of the repair may be performed periodically or predetermined by the repair form.

圖15中的左下部影像1550顯示在結束缺陷修復之後,左上部影像1510之條帶結構1530之區段。經修復位置係由局部影像1550之條帶結構1530中的參考符號1560繪示。右下部影像1555再次重現右上部影像1515之參考條帶結構1525。15 shows a section of the stripe structure 1530 of the upper left image 1510 after defect repair has been completed. The repaired location is indicated by reference symbol 1560 in the stripe structure 1530 of the partial image 1550. The lower right image 1555 reproduces the reference stripe structure 1525 of the upper right image 1515 again.

圖16顯示圖15中的左下部影像1550之經修復區段1530之影像之空間影像,係藉助EUV-AIMSTM 記錄。在局部影像1610中,確認經修復位置1560、經修復定位1560、或經修復區域1560。為了比較目的,右部影像1615呈現局部影像1415之參考條帶結構1425。圖16中併置視圖顯露裝置700已將缺陷1450修復至一定程度,使得缺陷係在EUV-AIMSTM 之空間影像中不再可見。FIG16 shows an aerial image of an image of the repaired section 1530 of the lower left image 1550 in FIG15, recorded by means of EUV-AIMS . In the local image 1610, the repaired position 1560, the repaired location 1560, or the repaired area 1560 is identified. For comparison purposes, the right image 1615 presents the reference stripe structure 1425 of the local image 1415. The juxtaposed view in FIG16 reveals that the apparatus 700 has repaired the defect 1450 to a certain extent, such that the defect is no longer visible in the aerial image of EUV-AIMS .

圖17表示用於EUV波長範圍的光學組件100、300、500之缺陷修復之整體序列之流程圖1700。方法開始於區塊1705。第一步驟1710在於記錄光學EUV組件100、300、500之缺陷150、350、550、1450或缺陷定位150、350、550、1450之影像。此步驟通常係藉助檢測工具(例如EUV-AIMSTM 等)而執行。在替代具體實例中,檢測工具使用帶電粒子束(例如電子束)。然後,在步驟1715,無缺陷參考定位之參考影像同樣藉助檢驗工具進行記錄。步驟1715為一選擇性步驟。此是如圖17的虛線外框所示。FIG. 17 shows a flow chart 1700 of an overall sequence for defect repair of an optical component 100, 300, 500 for the EUV wavelength range. The method starts at block 1705. A first step 1710 consists in recording an image of a defect 150, 350, 550, 1450 or a defect location 150, 350, 550, 1450 of the optical EUV component 100, 300, 500. This step is typically performed with the aid of an inspection tool (e.g., EUV-AIMS TM , etc.). In an alternative embodiment, the inspection tool uses a charged particle beam (e.g., an electron beam). Then, in step 1715, a reference image of a defect-free reference location is also recorded with the aid of an inspection tool. Step 1715 is an optional step. This is shown in the dashed box in Figure 17.

然後,決策區塊1720關於基於缺陷150、350、550、1450所判定影像(視需要借助於參考影像而定),而判定是否有必要修復缺陷150、350、550、1450。若不必修復,則方法跳到區塊1775,其中針對EUV光罩100、300、500是否具有進一步缺陷150、350、550、1450做出決策。若情況並非如此,則方法結束於步驟1780,且光學EUV組件100、300、500就可使用。若光學EUV組件100、300、500包含一EUV光罩100、300、500,則EUV光罩就可在一掃描器中使用。若進一步缺陷150、350、550、1450存在EUV光罩100、300、500上,則方法跳到區塊1710,其中下一缺陷150、350、550、1450之影像係藉助EUV-AIMSTM 記錄。Then, decision block 1720 is made as to whether it is necessary to repair the defect 150, 350, 550, 1450 based on the image determined by the defect 150, 350, 550, 1450 (optionally with the aid of a reference image). If it is not necessary, the method jumps to block 1775 where a decision is made as to whether the EUV reticle 100, 300, 500 has further defects 150, 350, 550, 1450. If this is not the case, the method ends at step 1780 and the optical EUV assembly 100, 300, 500 can be used. If the optical EUV assembly 100, 300, 500 includes an EUV reticle 100, 300, 500, the EUV reticle can be used in a scanner. If a further defect 150, 350, 550, 1450 is present on the EUV reticle 100, 300, 500, the method jumps to block 1710, where an image of the next defect 150, 350, 550, 1450 is recorded by EUV-AIMS .

若有必要修復缺陷定位150、350、550、1450,則方法跳到區塊1725,其中缺陷定位150、350、550、1450或缺陷150、350、550、1450之影像係藉助裝置700或修復裝置700而在檢驗模式下進行記錄。然後,針對缺陷定位150、350、550、1450的修復形式係在區塊1730中進行判定。針對缺陷150、350、550、1450的修復形式可使用在步驟1710中由檢測工具記錄的影像(視需要與參考影像結合而定)進行判定。或者,修復形式可從裝置700或修復裝置700在檢驗模式下記錄的一或多個影像進行判定。或者,也可從組合考慮在步驟1710和1725中測量到的缺陷定位150、350、550、1450之影像,以判定針對缺陷150、350、550、1450的修復形式。If repair of the defect location 150, 350, 550, 1450 is necessary, the method jumps to block 1725, where the defect location 150, 350, 550, 1450 or an image of the defect 150, 350, 550, 1450 is recorded by the device 700 or the repair device 700 in the inspection mode. Then, the type of repair for the defect location 150, 350, 550, 1450 is determined in block 1730. The type of repair for the defect 150, 350, 550, 1450 can be determined using the image recorded by the inspection tool in step 1710 (optionally combined with a reference image). Alternatively, the type of repair can be determined from one or more images recorded by the device 700 or the repair device 700 in the inspection mode. Alternatively, the images of the defect locations 150, 350, 550, 1450 measured in steps 1710 and 1725 may be considered in combination to determine the type of repair for the defect 150, 350, 550, 1450.

在決策區塊1735,針對處理或修復缺陷150、350、550、1450是否預期導致EUV光罩100、300、500在反射率的局部提高1740或局部降低1745而做出決策。若缺陷150、350、550、1450係過剩材料之缺陷150、550,則在區塊1750,一或多個圖案元件140之過剩吸收劑材料或顆粒550之過剩材料係藉助使用光子束630、840、1030的剝蝕,而從EUV光罩100、500進行去除。At decision block 1735, a decision is made as to whether treating or repairing the defect 150, 350, 550, 1450 is expected to result in a local increase 1740 or a local decrease 1745 in reflectivity of the EUV reticle 100, 300, 500. If the defect 150, 350, 550, 1450 is an excess material defect 150, 550, then at block 1750, excess absorber material of one or more pattern elements 140 or excess material of particles 550 is removed from the EUV reticle 100, 500 by stripping using a photon beam 630, 840, 1030.

若缺陷修復之預期變更係在反射光學強度的局部降低,則在區塊1755,為了剝蝕EUV光罩100、300、500之多層結構120之一部分或至少減小平面度,EUV光罩300之多層結構120係使用光子束630、840、1030進行處理。If the desired change in defect repair is a local decrease in reflected optical intensity, then at block 1755, the multi-layer structure 120 of the EUV mask 300 is processed using the photon beam 630, 840, 1030 in order to strip a portion of the multi-layer structure 120 of the EUV mask 100, 300, 500 or at least reduce the planarity.

兩處理製程1750和1755將方法引導至區塊1765,其關於用裝置700之檢驗模式記錄EUV光罩100、300、500之經修復定位150、350、550、1450之影像。在決策區塊1770中,對於修復缺陷150、350、550、1450是否得出結論而做出決策。若情況並非如此,則方法跳到區塊1725,其中剩餘缺陷殘留之影像係在檢驗模式下由修復裝置700進行記錄。若修復缺陷150、350、550、1450得出結論的事實係在決策區塊1770中進行判定,則方法跳到決策區塊1775。決策區塊1775在於確定EUV光罩100、300、500是否具有進一步缺陷150、350、550、1450。若情況如此,則方法跳到區塊1710並測量下一缺陷之影像。若無進一步缺陷150、350、550、1450存在光罩100、300、500上,則方法結束於區塊1780。Two processes 1750 and 1755 direct the method to block 1765, which involves recording images of the repaired positions 150, 350, 550, 1450 of the EUV masks 100, 300, 500 using the inspection mode of the device 700. In decision block 1770, a decision is made as to whether to conclude repairing defects 150, 350, 550, 1450. If this is not the case, the method jumps to block 1725 where images of the remaining defect residues are recorded by the repair device 700 in inspection mode. If the fact that the conclusion of repairing defects 150, 350, 550, 1450 is determined in decision block 1770, the method jumps to decision block 1775. Decision block 1775 is to determine whether the EUV mask 100, 300, 500 has further defects 150, 350, 550, 1450. If so, the method jumps to block 1710 and measures the image of the next defect. If no further defects 150, 350, 550, 1450 exist on the mask 100, 300, 500, the method ends at block 1780.

最後,圖18中的流程圖1800顯示根據本發明之方法在極紫外線波長範圍內修復光學組件100、300、500的至少一缺陷150、350、550、1450之必要步驟,光學組件包含一基材110和一多層結構120。方法開始於步驟1810。第一步驟1820在於產生EUV波長範圍內及/或軟x光輻射之波長範圍內的光子束605、1030、1130。區塊1830在於設定光子束605、1030、1130,使得至少一缺陷150、350、550、1450係藉助局部更改光學組件100、300、500而進行修復。最後,方法結束於區塊1840。Finally, the flowchart 1800 in FIG. 18 shows the necessary steps for repairing at least one defect 150, 350, 550, 1450 of an optical component 100, 300, 500 in the extreme ultraviolet wavelength range according to the method of the present invention, the optical component comprising a substrate 110 and a multilayer structure 120. The method starts at step 1810. The first step 1820 consists in generating a photon beam 605, 1030, 1130 in the EUV wavelength range and/or in the wavelength range of soft x-ray radiation. Block 1830 consists in setting the photon beam 605, 1030, 1130 so that at least one defect 150, 350, 550, 1450 is repaired by locally modifying the optical component 100, 300, 500. Finally, the method ends at block 1840.

100,300,500,600:EUV光罩 105,305,505:上部影像 110:基材 120:多層結構 130:覆蓋層 140,340,540:圖案元件 150:過剩材料之缺陷 160,360,560:EUV光子束 170,370,570,670:交互作用區 180:液滴 350:遺漏材料之缺陷 355,555:下部影像 550:顆粒之缺陷 605:準直EUV光子束 610:EUV光源 620:第一成像EUV反射鏡 630:聚焦EUV光子束 640:吸收劑圖案 650:缺陷 660:第二成像EUV反射鏡 680:EUV光子 690:能量感測器 695:示意圖 700:修復裝置 710,720,730,810,855,865,1015,1025:連接 750:控制裝置 760:擴展光子束 780:偵測器 820:非成像EUV反射鏡 830,840:EUV光子束 850:菲涅耳波帶片 860:EUV光 910:旋轉 920:移出 1000:示意圖 1010:第一EUV光源 1020:第二EUV光源 1030:聚焦EUV光子束 1130:準直EUV光子束 1310:薄膜 1410:左部影像 1415:右部影像 1420:含缺陷條帶結構 1425:無缺陷參考條帶結構 1450:缺陷 1510:左上部影像 1515:右上部影像 1525:參考條帶結構 1530:條帶結構 1550:左下部影像 1555:右下部影像 1560:經修復位置 1580:箭頭 1610:局部影像 1615:右部影像 1700,1800:流程圖 1705,1710,1715,1725,1730,1750,1755,1765,1780,1810,1820,1830,1840:區塊/步驟 1720,1735,1770,1775:決策區塊 1740:局部提高 1745:局部降低100,300,500,600:EUV mask 105,305,505:Upper image 110:Substrate 120:Multi-layer structure 130:Coating layer 140,340,540:Pattern element 150:Defect of excess material 160,360,560:EUV photon beam 170,370,570,670:Interaction zone 180:Droplets 350:Defect of missing material 355,555:Lower image 550:Defect of particles 605:Collimated EUV photon beam 610:EUV Light source 620: First imaging EUV mirror 630: Focusing EUV photon beam 640: Absorber pattern 650: Defect 660: Second imaging EUV mirror 680: EUV photons 690: Energy sensor 695: Schematic diagram 700: Repair device 710,720,730,810,855,865,1015,1025: Connection 750: Control device 760: Expanding photon beam 780: Detector 820: Non-imaging EUV mirror 830,840: EUV photon beam 850 :Fresnel zone plate 860:EUV light 910:Rotation 920:Move out 1000:Schematic diagram 1010:First EUV light source 1020:Second EUV light source 1030:Focused EUV photon beam 1130:Collimated EUV photon beam 1310:Thin film 1410:Left image 1415:Right image 1420:Defective strip structure 1425:Defect-free reference strip structure 1450:Defect 1510:Upper left image 1515:Upper right image 1525:Reference strip structure 1530 : Strip structure 1550: Lower left image 1555: Lower right image 1560: Repaired position 1580: Arrow 1610: Partial image 1615: Right image 1700,1800: Flowchart 1705,1710,1715,1725,1730,1750,1755,1765,1780,1810,1820,1830,1840: Block/step 1720,1735,1770,1775: Decision block 1740: Local increase 1745: Local decrease

以下詳細說明係參考圖式說明本發明之目前較佳示例性具體實例,在附圖中: 圖1: 在上部影像中示意性顯示用於極紫外線波長範圍(EUV)的光罩之側視圖之剖面之一區段,其中圖案元件具有形式為過剩吸收劑材料的缺陷,並在下部影像中呈現上部影像之側視圖之俯視圖; 圖2: 示意性繪示圖1中在修復EUV光罩之過剩吸收劑材料之缺陷期間之正規化(Normalized)強度之變更; 圖3: 在上部影像中示意性繪示EUV光罩之側視圖之剖面之一區段,其中圖案元件具有形式為遺漏吸收劑材料的缺陷,並在下部影像中呈現上部影像之側視圖之俯視圖; 圖4: 示意性繪示圖3中在修復EUV光罩之遺漏吸收劑材料之缺陷期間之正規化強度之變更; 圖5: 在上部影像中示意性顯示具有形式為顆粒的缺陷的EUV光罩之側視圖之剖面之一區段,並在下部影像中呈現上部影像之側視圖之俯視圖; 圖6: 示意性呈現穿越具有缺陷的EUV光罩的剖面,及用於修復缺陷的裝置之一第一示例性具體實例,其中裝置在修復模式下操作; 圖7: 重現圖6,但其中裝置在檢驗模式下操作; 圖8: 繪示圖6中EUV光罩具有用於修復缺陷的裝置之一第二示例性具體實例,其中裝置在修復模式下操作; 圖9: 重現圖8,但其中裝置在檢驗模式下操作; 圖10: 繪示圖6中EUV光罩具有用於修復缺陷的裝置之一第三示例性具體實例,其中裝置在修復模式下操作; 圖11: 重現圖10,但其中裝置在檢驗模式下操作; 圖12: 呈現圖10和圖11中裝置,其中裝置同時在修復模式及在檢驗模式下操作; 圖13: 顯示圖6中配置,其中薄膜係在修復製程期間安裝在EUV光罩上; 圖14: 呈現EUV光罩之條帶結構,其中缺陷在左部影像中而無缺陷參考條帶結構在右部影像中,其中此兩局部影像皆使用EUV-AIMSTM 進行記錄; 圖15: 在上部影像中繪示圖14中局部影像之EUV光罩之條帶結構(當其出現在修復裝置在檢驗模式下產生的影像中),左下部影像呈現結束缺陷修復製程之後的左上部影像,而右下部影像重現右上部影像之參考條帶結構; 圖16: 呈現在缺陷修復之後圖14中影像; 圖17: 顯示用於EUV波長範圍的光學組件之修復製程之流程圖;及 圖18: 繪示根據本發明之用於在EUV波長範圍內修復光學組件缺陷的方法之流程圖。The following detailed description is a currently preferred exemplary embodiment of the present invention with reference to the drawings, in which: FIG1: schematically shows a section of a cross-section of a side view of a mask for use in the extreme ultraviolet wavelength range (EUV) in the upper image, wherein the pattern element has a defect in the form of excess absorber material, and presents a top view of the side view of the upper image in the lower image; FIG2: schematically shows the change of the normalized intensity during the repair of the defect of the excess absorber material of the EUV mask in FIG1; FIG3: schematically shows a section of a cross-section of a side view of an EUV mask in the upper image, wherein the pattern element has a defect in the form of missing absorber material, and presents a top view of the side view of the upper image in the lower image; FIG4: Schematic illustration of the change in normalized intensity during the repair of a defect of missing absorber material of an EUV mask in FIG3; FIG5: schematically showing a section of a side view of an EUV mask with a defect in the form of a particle in the upper image, and presenting a top view of the side view of the upper image in the lower image; FIG6: schematically presenting a section through an EUV mask with a defect and a first exemplary embodiment of an apparatus for repairing a defect, wherein the apparatus is operated in a repair mode; FIG7: a reproduction of FIG6, but wherein the apparatus is operated in an inspection mode; FIG8: a second exemplary embodiment of an EUV mask with an apparatus for repairing a defect in FIG6, wherein the apparatus is operated in a repair mode; FIG9: a reproduction of FIG8, but wherein the apparatus is operated in an inspection mode; FIG10: FIG. 6 shows a third exemplary embodiment of an EUV mask having an apparatus for repairing defects, wherein the apparatus is operated in a repair mode; FIG. 11: a reproduction of FIG. 10, but wherein the apparatus is operated in an inspection mode; FIG. 12: presents the apparatus of FIG. 10 and FIG. 11, wherein the apparatus is operated in a repair mode and in an inspection mode simultaneously; FIG. 13: shows the configuration of FIG. 6, wherein a pellicle is mounted on an EUV mask during a repair process; FIG. 14: presents a stripe structure of an EUV mask, wherein a defect is in the left image and a defect-free reference stripe structure is in the right image, wherein both local images were recorded using EUV-AIMS TM ; FIG. 15: The upper image shows the stripe structure of the EUV mask in the partial image of Figure 14 (as it appears in the image generated by the repair device in the inspection mode), the lower left image shows the upper left image after the defect repair process is completed, and the lower right image reproduces the reference stripe structure of the upper right image; Figure 16: shows the image in Figure 14 after the defect repair; Figure 17: shows a flow chart of the repair process for optical components in the EUV wavelength range; and Figure 18: shows a flow chart of the method for repairing defects of optical components in the EUV wavelength range according to the present invention.

110:基材 110: Base material

120:多層結構 120:Multi-layer structure

130:覆蓋層 130: Covering layer

600:EUV光罩 600:EUV mask

605:準直EUV光子束 605: Collimated EUV photon beam

610:EUV光源 610:EUV light source

620:第一成像EUV反射鏡 620: The first imaging EUV mirror

630:聚焦EUV光子束 630: Focusing EUV photon beam

640:吸收劑圖案 640:Absorbent pattern

650:缺陷 650: Defects

660:第二成像EUV反射鏡 660: Second imaging EUV mirror

670:交互作用區 670: Interaction zone

680:EUV光子 680:EUV Photons

690:能量感測器 690:Energy sensor

695:示意圖 695: Schematic diagram

700:修復裝置 700:Repair device

710,720,730:連接 710,720,730:Connection

750:控制裝置 750: Control device

Claims (19)

一種在極紫外線波長範圍內修復光學組件(100、300、500)的至少一缺陷(150、350、550、1450)之裝置(700),其中該光學組件(100、300、500)包含一基材(110)及一配置在該基材(110)上的多層結構(120),其包含: a.  至少一光源(610、1010、1020),其設計成產生該EUV波長範圍內及/或軟x光輻射之該波長範圍內的一光子束(605、1030、1130); b.  其中該至少一光源(610、1010、1020)更設計成藉由局部更改該光學組件(100、300、500)以修復該至少一缺陷(150、350、550、1450);及 c.  一偵測器(780),用於偵測從該光學組件(100、300、500)反射的光子。 A device (700) for repairing at least one defect (150, 350, 550, 1450) of an optical component (100, 300, 500) within the extreme ultraviolet wavelength range, wherein the optical component (100, 300, 500) comprises a substrate (110) and a multilayer structure (120) disposed on the substrate (110), comprising: a. At least one light source (610, 1010, 1020) designed to generate a photon beam (605, 1030, 1130) within the EUV wavelength range and/or within the wavelength range of soft x-ray radiation; b. wherein the at least one light source (610, 1010, 1020) is further designed to repair the at least one defect (150, 350, 550, 1450) by partially changing the optical component (100, 300, 500); and c. a detector (780) for detecting photons reflected from the optical component (100, 300, 500). 如請求項1之裝置(700),其中局部更改該光學組件(100、300、500)包含該光學組件(100、300、500)在一光化波長範圍內之一反射率之局部變更。A device (700) as claimed in claim 1, wherein locally changing the optical component (100, 300, 500) comprises locally changing a reflectivity of the optical component (100, 300, 500) within a range of actinic wavelengths. 如請求項1之裝置(700),其中局部更改該光學組件(100、300、500)包含藉助該光子束(630、840、1030)從該光學組件(100、300、500)局部去除材料。A device (700) as claimed in claim 1, wherein locally altering the optical component (100, 300, 500) comprises locally removing material from the optical component (100, 300, 500) by means of the photon beam (630, 840, 1030). 如請求項3之裝置(700),其中局部去除材料包含以下群組之至少一者:去除一光刻光罩(100)之吸收劑圖案(140)之至少一元件之過剩材料、去除該光學組件(300)之該多層結構(120)之材料、及從該光學組件(500)去除至少一顆粒(550)。A device (700) as claimed in claim 3, wherein the local removal of material includes at least one of the following groups: removing excess material from at least one element of an absorber pattern (140) of a lithography mask (100), removing material from the multi-layer structure (120) of the optical component (300), and removing at least one particle (550) from the optical component (500). 如請求項1之裝置(700),其中該至少一光源(610、1010、1020)更設計成設定用於修復該光學組件(100、300、500)的該至少一缺陷(150、350、550、1450)之該光子束(605、1030、1130)的能量密度。A device (700) as claimed in claim 1, wherein the at least one light source (610, 1010, 1020) is further designed to set the energy density of the photon beam (605, 1030, 1130) for repairing the at least one defect (150, 350, 550, 1450) of the optical component (100, 300, 500). 如請求項1之裝置(700),其更包含一能量感測器(690),用於在一修復期間供監控修復之目的而偵測從該光學組件(100、300、500)及/或從該至少一缺陷(150、350、550、1450)反射的光子。A device (700) as claimed in claim 1, further comprising an energy sensor (690) for detecting photons reflected from the optical component (100, 300, 500) and/or from the at least one defect (150, 350, 550, 1450) during a repair period for the purpose of monitoring the repair. 如請求項6之裝置(700),其中該裝置(700)係設計成在一閉反饋迴路中操作該至少一光源(610、1010、1020)和該能量感測器(690)。A device (700) as claimed in claim 6, wherein the device (700) is configured to operate the at least one light source (610, 1010, 1020) and the energy sensor (690) in a closed feedback loop. 如請求項1之裝置(700),其更包含至少一第一反射鏡(620),用於在該光學組件(100、300、500)的該至少一缺陷(150、350、550、1450)上方掃描該光子束(630);及至少一第二反射鏡(660),用於將該光子束(760)引導到該光學組件(100、300、500)含有該至少一缺陷(150、350、500、1450)之區域。The device (700) of claim 1 further comprises at least one first reflector (620) for scanning the photon beam (630) over the at least one defect (150, 350, 550, 1450) of the optical component (100, 300, 500); and at least one second reflector (660) for guiding the photon beam (760) to the area of the optical component (100, 300, 500) containing the at least one defect (150, 350, 500, 1450). 如請求項1之裝置(700),其更包含一控制裝置(750),設計成將該至少一第一反射鏡(620)及/或該至少一第二反射鏡(660)移動越過一目視距離。The device (700) of claim 1 further comprises a control device (750) configured to move the at least one first reflector (620) and/or the at least one second reflector (660) beyond a visual distance. 如請求項1之裝置(700),其中該裝置(700)包含一菲涅耳波帶片(850),及/或其中該控制裝置(750)係設計成將該菲涅耳波帶片(850)移入該光子束(830)並移出該光子束(830)。A device (700) as claimed in claim 1, wherein the device (700) comprises a Fresnel zone plate (850), and/or wherein the control device (750) is designed to move the Fresnel zone plate (850) into and out of the photon beam (830). 如請求項10之裝置(700),其中該控制裝置(750)更設計成建置裝置(700)為使用該光子束(760、830、1130)的一檢驗模式,及/或其中該控制裝置(750)係另外設計成在該檢驗模式與一修復模式之間切換該裝置(700)。A device (700) as claimed in claim 10, wherein the control device (750) is further designed to configure the device (700) for a test mode using the photon beam (760, 830, 1130), and/or wherein the control device (750) is further designed to switch the device (700) between the test mode and a repair mode. 如請求項1之裝置(700),其更包含一樣品夾,用於固定該光學組件(100、300、500),該樣品夾係設計成將該光學組件(100、300、500)繞著至少一軸旋轉,及/或其中該樣品夾更設計成為了用該光子束(760、830、1130)檢驗該光學組件(100、300、500)之一實質無缺陷區域之目的,而在至少一側向方向上移置該光學組件(100、300、500)。As in claim 1, the device (700) further comprises a sample clamp for fixing the optical component (100, 300, 500), the sample clamp being designed to rotate the optical component (100, 300, 500) around at least one axis, and/or the sample clamp being further designed to displace the optical component (100, 300, 500) in at least one lateral direction for the purpose of inspecting a substantially defect-free area of the optical component (100, 300, 500) using the photon beam (760, 830, 1130). 如請求項1之裝置(700),其中該至少一光源(610、1010、1020)包含一第一光源(1020),其設計成為了修復該至少一缺陷(150、350、550、1450)之目的而在該至少一缺陷(150、350、550、1450)上方掃描一聚焦光子束(1030),並包含一第二光源(1010),其設計成將該光子束(1130)引導到該光學組件(100、300、500)包含至少該至少一缺陷(150、350、550、1450)之該區域上。A device (700) as claimed in claim 1, wherein the at least one light source (610, 1010, 1020) includes a first light source (1020) designed to scan a focused photon beam (1030) over the at least one defect (150, 350, 550, 1450) for the purpose of repairing the at least one defect (150, 350, 550, 1450), and includes a second light source (1010) designed to guide the photon beam (1130) to the area of the optical component (100, 300, 500) including at least the at least one defect (150, 350, 550, 1450). 如請求項1之裝置(700),其中在該修復期間及/或在一檢驗期間,該光學組件包含一薄膜(1310),該光子束(630、760、830、840、1030、1130)透過其輻射。A device (700) as claimed in claim 1, wherein during the repair and/or during an inspection, the optical component includes a film (1310) through which the photon beam (630, 760, 830, 840, 1030, 1130) is radiated. 一種使用如請求項1之裝置以在極紫外線(EUV)波長範圍內修復光學組件(100、300、500)的至少一缺陷(150、350、550、1450)之方法(1800),其中該光學組件(100、300、500)包含一基材(110)及一配置在該基材(110)上的多層結構(120),該方法包含下列步驟: a. 產生該EUV波長範圍內及/或軟x光輻射之該波長範圍內的一光子束(605、1030、1130);及 b.  設定該光子束(605、1030、1130),使得該至少一缺陷(150、350、550、1450)係藉由局部更改該光學組件(100、300、500)而加以修復。 A method (1800) for repairing at least one defect (150, 350, 550, 1450) of an optical component (100, 300, 500) within an extreme ultraviolet (EUV) wavelength range using a device as claimed in claim 1, wherein the optical component (100, 300, 500) comprises a substrate (110) and a multilayer structure (120) disposed on the substrate (110), the method comprising the following steps: a. generating a photon beam (605, 1030, 1130) within the EUV wavelength range and/or soft x-ray radiation within the wavelength range; and b. The photon beam (605, 1030, 1130) is configured so that the at least one defect (150, 350, 550, 1450) is repaired by locally modifying the optical component (100, 300, 500). 如請求項15之方法(1800),其中設定該光子束(605、1030、1130)包含以下群組之至少一者:聚焦該光子束(605、1030、1130)、變更該光子束(605、1030、1130)之一脈衝功率、變更該光子束(605、1030、1130)之一偏極、並變更該光子束(605、1030、1130)關於該光學組件(100、300、500)之一法線方向之一入射角。A method (1800) as claimed in claim 15, wherein setting the photon beam (605, 1030, 1130) includes at least one of the following groups: focusing the photon beam (605, 1030, 1130), changing a pulse power of the photon beam (605, 1030, 1130), changing a polarization of the photon beam (605, 1030, 1130), and changing an incident angle of the photon beam (605, 1030, 1130) with respect to a normal direction of the optical component (100, 300, 500). 如請求項15之方法(1800),其更包含下列步驟:在用該光子束(630、840、1030)修復該光學組件(100、300、500)的該至少一缺陷(150、350、550、1450)與用該光子束(760、830、1130)檢驗該光學組件(100、300、500)及/或該光學組件(100、300、500)的該至少一缺陷(150、350、550、1450)之間切換。The method (1800) of claim 15 further comprises the following step: switching between repairing the at least one defect (150, 350, 550, 1450) of the optical component (100, 300, 500) using the photon beam (630, 840, 1030) and inspecting the optical component (100, 300, 500) and/or the at least one defect (150, 350, 550, 1450) of the optical component (100, 300, 500) using the photon beam (760, 830, 1130). 如請求項15之方法(1800),其更包含下列步驟之至少一者: a.  用該光子束(760、830、1130)檢驗該至少一缺陷(150、350、550、1450),及/或用該光子束(760、830、1130)檢驗一實質無缺陷參考定位; b.  若該至少一檢驗到缺陷(150、350、550、1450)超過一預定閾值,則針對該至少一檢驗到缺陷(150、350、550、1450)判定一修復形式; c.  用該光子束(630、840、1030)修復該至少一缺陷(150、350、550、1450); d.  用該光子束(760、830、1130)檢驗該光學組件(100、300、500)之一經修復位置;及 e.  若該至少一缺陷(150、350、550、1450)之一剩餘殘留超過該預定閾值,則重複步驟a.和b.。 The method (1800) of claim 15 further comprises at least one of the following steps: a. Inspecting the at least one defect (150, 350, 550, 1450) with the photon beam (760, 830, 1130), and/or inspecting a substantially defect-free reference position with the photon beam (760, 830, 1130); b. Determining a repair form for the at least one detected defect (150, 350, 550, 1450) if the at least one detected defect (150, 350, 550, 1450) exceeds a predetermined threshold; c. Repairing the at least one defect (150, 350, 550, 1450) with the photon beam (630, 840, 1030); d. Inspecting a repaired position of the optical component (100, 300, 500) with the photon beam (760, 830, 1130); and e. If a remaining residue of the at least one defect (150, 350, 550, 1450) exceeds the predetermined threshold, repeating steps a. and b.. 一種電腦程式,其包含指令,當由一電腦系統執行時,指令使得該電腦系統執行如請求項15至18之該等方法步驟。A computer program comprising instructions which, when executed by a computer system, cause the computer system to perform the method steps of claims 15 to 18.
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