TWI886916B - Manufacturing method for photonic crystal surface-emitting laser - Google Patents
Manufacturing method for photonic crystal surface-emitting laser Download PDFInfo
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Abstract
Description
本發明涉及一種面射型雷射結構,特別是涉及一種兩主動發光層之間具有光子晶體的面射型雷射結構。 The present invention relates to a surface-emitting laser structure, and in particular to a surface-emitting laser structure having a photonic crystal between two active light-emitting layers.
隨著科技發展,半導體雷射光源的應用逐漸在人類的生活扮演重要的角色,除了邊射型雷射及垂直共振腔面射型雷射外,近期還發展出光子晶體面射型雷射,其具有共振腔長及發光發散角度小,傳遞距離遠的優點。 With the development of technology, the application of semiconductor laser light sources has gradually played an important role in human life. In addition to edge-emitting lasers and vertical cavity surface-emitting lasers, photonic crystal surface-emitting lasers have also been developed recently. They have the advantages of long cavity length, small light divergence angle, and long transmission distance.
習知光子晶體面射型雷射器發出的雷射光時,只能利用到一部份的雷射能量,使得光電轉換的效率較低,造成能量上的浪費。 It is known that when a photonic crystal surface-emitting laser emits laser light, only a portion of the laser energy can be utilized, resulting in a low efficiency of photoelectric conversion and a waste of energy.
故,如何通過結構設計的改良,來提升光子晶體面射型雷射器的效率,來克服上述的缺陷,已成為該項事業所欲解決的重要課題之一。 Therefore, how to improve the efficiency of photonic crystal surface-emitting lasers by improving the structural design to overcome the above-mentioned defects has become one of the important issues that the industry wants to solve.
本發明所要解決的技術問題在於,針對現有技術的不足提供一種光子晶體面射型雷射結構,包括電路基板、第一電極層、歐姆接觸層、第一半導體層、第一主動層、光子晶體層、第二主動層、第三半導體層及第二電極層。第一電極層位於電路基板上,第一電極層具有容置槽。歐姆接觸層位於容置槽。第一半導體層位於第一電極層上,覆蓋歐姆接觸層。第一主動 層位於第一半導體層上,第一主動層包括至少一第一發光層。光子晶體層包括:第二半導體層及多個微結構物,每一微結構物為透光性導電體,第二半導體層包括頂部、基部及填充部,多個微結構物位於基部上且間隔排列,填充部填滿二相鄰微結構物之間的間隙,頂部連接填充部,覆蓋填充部及多個微結構物。第二主動層位於光子晶體層上,第二主動層包括至少一第二發光層。第三半導體層位於第二主動層上。第二電極層位於第三半導體層上,第二電極層具有槽口,第三半導體層的一部份表面顯露於槽口,定義出光面。 The technical problem to be solved by the present invention is to provide a photonic crystal surface-emitting laser structure in view of the shortcomings of the prior art, including a circuit substrate, a first electrode layer, an ohmic contact layer, a first semiconductor layer, a first active layer, a photonic crystal layer, a second active layer, a third semiconductor layer and a second electrode layer. The first electrode layer is located on the circuit substrate, and the first electrode layer has a receiving groove. The ohmic contact layer is located in the receiving groove. The first semiconductor layer is located on the first electrode layer and covers the ohmic contact layer. The first active layer is located on the first semiconductor layer, and the first active layer includes at least one first light-emitting layer. The photonic crystal layer includes: a second semiconductor layer and a plurality of microstructures, each microstructure being a light-transmitting conductor. The second semiconductor layer includes a top, a base and a filling portion. The plurality of microstructures are located on the base and arranged at intervals. The filling portion fills the gap between two adjacent microstructures. The top portion is connected to the filling portion, covering the filling portion and the plurality of microstructures. The second active layer is located on the photonic crystal layer, and the second active layer includes at least one second light-emitting layer. The third semiconductor layer is located on the second active layer. The second electrode layer is located on the third semiconductor layer, and the second electrode layer has a notch. A portion of the surface of the third semiconductor layer is exposed in the notch to define a light-emitting surface.
依據一可行的實施方案,第一發光層為多個,第二發光層為多個,第一主動層中最遠離光子晶體層的第一發光層之間的距離小於等於1μm;第二主動層中最遠離光子晶體層的第二發光層之間的距離小於等於1μm。 According to a feasible implementation scheme, there are multiple first light-emitting layers, multiple second light-emitting layers, and the distance between the first light-emitting layers farthest from the photonic crystal layer in the first active layer is less than or equal to 1μm; the distance between the second light-emitting layers farthest from the photonic crystal layer in the second active layer is less than or equal to 1μm.
依據一可行的實施方案,光子晶體面射型雷射結構還包括保護層,側向包覆第二電極層、第三半導體層、第二主動層、光子晶體層及第一主動層,保護層還覆蓋出光面。 According to a feasible implementation scheme, the photonic crystal surface-emitting laser structure also includes a protective layer, which laterally covers the second electrode layer, the third semiconductor layer, the second active layer, the photonic crystal layer and the first active layer, and the protective layer also covers the light-emitting surface.
依據一可行的實施方案,微結構物的形狀為柱體。 According to a feasible implementation scheme, the shape of the microstructure is a column.
本發明還提供一種光子晶體面射型雷射結構,其包括電路基板、第一電極層、歐姆接觸層、第一半導體層、第一主動層、穿隧接面、第二主動層、光子晶體層、第三半導體層及第二電極層。第一電極層位於電路基板上,第一電極層具有容置槽。歐姆接觸層位於容置槽。第一半導體層位於第一電極層上,覆蓋歐姆接觸層。第一主動層位於第一半導體層上,第一主動層包括至少一第一發光層。穿隧接面位於第一主動層上。第二主動層位於穿隧接面上,第二主動層包括至少一第二發光層。光子晶體層包括:第二半導體層及多個微結構物,每一微結構物為透光性導電體,第二半導體層包括頂部、基部及填充部,多個微結構物位於基部上且間隔排列,填充部填 滿二相鄰微結構物之間的間隙,頂部連接填充部,覆蓋填充部及多個微結構物。第三半導體層位於光子晶體層上。第二電極層位於第三半導體層上,第二電極層具有槽口,第三半導體層的一部份表面顯露於槽口,定義出光面。 The present invention also provides a photonic crystal surface-emitting laser structure, which includes a circuit substrate, a first electrode layer, an ohmic contact layer, a first semiconductor layer, a first active layer, a tunneling junction, a second active layer, a photonic crystal layer, a third semiconductor layer and a second electrode layer. The first electrode layer is located on the circuit substrate, and the first electrode layer has a receiving groove. The ohmic contact layer is located in the receiving groove. The first semiconductor layer is located on the first electrode layer and covers the ohmic contact layer. The first active layer is located on the first semiconductor layer, and the first active layer includes at least one first light-emitting layer. The tunneling junction is located on the first active layer. The second active layer is located on the tunneling junction, and the second active layer includes at least one second light-emitting layer. The photonic crystal layer includes: a second semiconductor layer and a plurality of microstructures, each microstructure is a light-transmitting conductor, the second semiconductor layer includes a top, a base and a filling part, a plurality of microstructures are located on the base and arranged at intervals, the filling part fills the gap between two adjacent microstructures, the top is connected to the filling part, and covers the filling part and the plurality of microstructures. The third semiconductor layer is located on the photonic crystal layer. The second electrode layer is located on the third semiconductor layer, and the second electrode layer has a notch, and a portion of the surface of the third semiconductor layer is exposed in the notch to define the light-emitting surface.
依據一可行的實施方案,光子晶體面射型雷射結構還包括保護層,側向包覆第二電極層、光子晶體層、第二主動層、穿隧接面及第一主動層,保護層還覆蓋出光面。 According to a feasible implementation scheme, the photonic crystal surface-emitting laser structure also includes a protective layer, which laterally covers the second electrode layer, the photonic crystal layer, the second active layer, the tunneling junction and the first active layer, and the protective layer also covers the light-emitting surface.
本發明更提供一種光子晶體面射型雷射結構的製造方法,其包括:提供複合發光層,複合發光層依序包括歐姆接觸層、第一半導體層、第一主動層、第二半導體層及透光導電層,第一主動層包括至少一第一發光層。對透光導電層進行蝕刻,形成多個微結構物,多個微結構物位在第二半導體層上且間隔排列。對第二半導體層進行再長晶(regrowth)步驟,形成頂部及填充部,填充部填滿二相鄰微結構物之間的間隙,頂部連接填充部,覆蓋填充部及多個微結構物,第二半導體層、多個微結構物、填充部及頂部形成光子晶體層。設置第二主動層於光子晶體層上,第二主動層包括至少一第二發光層。設置第三半導體層於第二主動層上。側向蝕刻第一主動層、光子晶體層、第二主動層及第三半導體層,使第一主動層的兩側與第一半導體層分別形成一斷差結構。設置上電極層於第三半導體層上,上電極層具有槽口,第三半導體層的一部份表面顯露於槽口,定義出光面。設置保護層,沿斷差結構包覆上電極層、第三半導體層、第二主動層、光子晶體層及第一主動層。設置下電極層於第一半導體層下方,下電極層具有容置槽,容置歐姆接觸層。 The present invention further provides a method for manufacturing a photonic crystal surface-emitting laser structure, which includes: providing a composite light-emitting layer, the composite light-emitting layer sequentially including an ohmic contact layer, a first semiconductor layer, a first active layer, a second semiconductor layer and a light-transmitting conductive layer, the first active layer including at least one first light-emitting layer. Etching the light-transmitting conductive layer to form a plurality of microstructures, the plurality of microstructures being located on the second semiconductor layer and arranged at intervals. The second semiconductor layer is subjected to a regrowth step to form a top portion and a filling portion, wherein the filling portion fills the gap between two adjacent microstructures, the top portion is connected to the filling portion, covers the filling portion and the plurality of microstructures, and the second semiconductor layer, the plurality of microstructures, the filling portion and the top portion form a photonic crystal layer. A second active layer is disposed on the photonic crystal layer, wherein the second active layer includes at least one second light-emitting layer. A third semiconductor layer is disposed on the second active layer. The first active layer, the photonic crystal layer, the second active layer and the third semiconductor layer are laterally etched so that the two sides of the first active layer and the first semiconductor layer respectively form a discontinuous structure. An upper electrode layer is arranged on the third semiconductor layer, the upper electrode layer has a notch, a portion of the surface of the third semiconductor layer is exposed in the notch, and a light-emitting surface is defined. A protective layer is arranged to cover the upper electrode layer, the third semiconductor layer, the second active layer, the photonic crystal layer, and the first active layer along the step structure. A lower electrode layer is arranged below the first semiconductor layer, the lower electrode layer has a receiving groove, and the ohmic contact layer is received.
本發明還另提供一種光子晶體面射型雷射結構的製造方法,其包括:提供複合發光層,複合發光層依序包括歐姆接觸層、第一半導體層、第一主動層、穿隧接面、第二主動層、第二半導體層及一透光導電層,第一主動層包括至少一第一發光層,第二主動層包括至少一第二發光層。對透光 導電層進行蝕刻,形成多個微結構物,多個微結構物位在第二半導體層上且間隔排列。對第二半導體層進行再長晶(regrowth)步驟,形成一頂部及一填充部,填充部填滿二相鄰微結構物之間的間隙,頂部連接填充部,覆蓋填充部及多個微結構物,第二半導體層、多個微結構物、填充部及頂部形成光子晶體層。設置第三半導體層於光子晶體層上。側向蝕刻第一主動層、穿隧接面、第二半導體層、光子晶體層及第三半導體層,使第一主動層的兩側與第一半導體層分別形成一斷差結構。設置上電極層,位於第三半導體層上,上電極層具有槽口,第三半導體層的一部份表面顯露於槽口,定義出光面。設置保護層,沿斷差結構包覆上電極層、第三半導體層、第二主動層、光子晶體層及第一主動層。設置下電極層,位於第一半導體層下,下電極層具有容置槽,容置歐姆接觸層。 The present invention also provides a method for manufacturing a photonic crystal surface-emitting laser structure, which includes: providing a composite light-emitting layer, the composite light-emitting layer sequentially including an ohmic contact layer, a first semiconductor layer, a first active layer, a tunneling junction, a second active layer, a second semiconductor layer and a light-transmitting conductive layer, the first active layer including at least one first light-emitting layer, and the second active layer including at least one second light-emitting layer. Etching the light-transmitting conductive layer to form a plurality of microstructures, the plurality of microstructures being located on the second semiconductor layer and arranged at intervals. The second semiconductor layer is subjected to a regrowth step to form a top portion and a filling portion, the filling portion fills the gap between two adjacent microstructures, the top portion is connected to the filling portion, covers the filling portion and the plurality of microstructures, and the second semiconductor layer, the plurality of microstructures, the filling portion and the top portion form a photonic crystal layer. The third semiconductor layer is disposed on the photonic crystal layer. The first active layer, the tunneling junction, the second semiconductor layer, the photonic crystal layer and the third semiconductor layer are laterally etched so that the two sides of the first active layer and the first semiconductor layer respectively form a discontinuous structure. An upper electrode layer is provided, located on the third semiconductor layer, and the upper electrode layer has a notch, and a portion of the surface of the third semiconductor layer is exposed in the notch to define the light-emitting surface. A protective layer is provided, and covers the upper electrode layer, the third semiconductor layer, the second active layer, the photonic crystal layer and the first active layer along the fault structure. A lower electrode layer is provided, and is located under the first semiconductor layer, and the lower electrode layer has a receiving groove to receive the ohmic contact layer.
本發明的其中一有益效果在於,本發明所提供的光子晶體面射型雷射器及其製造方法,其能通過“第一主動層與第二主動層之間具有光子晶體層”的技術方案,光線在最大範圍下於腔內共振,如此可增強出光面的出光量。 One of the beneficial effects of the present invention is that the photonic crystal surface-emitting laser and its manufacturing method provided by the present invention can achieve the maximum range of light resonance in the cavity through the technical solution of "having a photonic crystal layer between the first active layer and the second active layer", thereby enhancing the light output of the light-emitting surface.
依據一實施例,光子晶體面射型雷射結構具有歐姆接觸層,如此可使電流集中在出光區域。 According to one embodiment, the photonic crystal surface-emitting laser structure has an ohmic contact layer, so that the current can be concentrated in the light-emitting area.
另依據一些實施例,第一主動層及第二主動層之間具有穿隧接面。穿隧接面是高折射率介質層,設置穿隧接面有助於使通過雷射結構的電流均勻化,提升發光效率。 According to some embodiments, there is a tunneling junction between the first active layer and the second active layer. The tunneling junction is a high refractive index medium layer. The provision of the tunneling junction helps to make the current passing through the laser structure uniform and improve the luminescence efficiency.
綜合上述等技術功效,本發明的光子晶體面射型雷射器具有高的光電轉換效率。 Combining the above-mentioned technical effects, the photonic crystal surface-emitting laser of the present invention has a high photoelectric conversion efficiency.
為使能更進一步瞭解本發明的特徵及技術內容,請參閱以下有關本發明的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並 非用來對本發明加以限制。 In order to further understand the features and technical contents of the present invention, please refer to the following detailed description and drawings of the present invention. However, the drawings provided are only used for reference and description and are not used to limit the present invention.
100:製造方法 100: Manufacturing method
200:製造方法 200: Manufacturing method
1A-1B:光子晶體面射型雷射結構 1A-1B: Photonic crystal surface-emitting laser structure
11:電路基板 11: Circuit board
12:第一電極層,下電極層 12: First electrode layer, lower electrode layer
121:容置槽 121: Storage tank
13:歐姆接觸層 13: Ohm contact layer
14:第一半導體層 14: First semiconductor layer
15:第一主動層,第一發光層 15: First active layer, first light-emitting layer
16:光子晶體層 16: Photonic crystal layer
16A:透光導電層 16A: light-transmitting conductive layer
16B:透光導電層 16B: light-transmitting conductive layer
161:第二半導體層 161: Second semiconductor layer
1611:基部,第二半導體層 1611: Base, second semiconductor layer
1612:填充部 1612: Filling section
1613:頂部 1613: Top
162:微結構物 162: Microstructures
17:第二主動層,第二發光層 17: Second active layer, second light-emitting layer
18:第三半導體層 18: Third semiconductor layer
181:出光面 181: Bright surface
19:第二電極層,上電極層 19: Second electrode layer, upper electrode layer
191:槽口 191: Notch
20:保護層 20: Protective layer
21:斷差結構 21: Discontinuity structure
22:穿隧接面 22: Tunneling interface
S1-S9:步驟 S1-S9: Steps
P1-P8:步驟 P1-P8: Steps
圖1為本發明一實施例的光子晶體面射型雷射結構的截面示意圖。 Figure 1 is a schematic cross-sectional view of a photonic crystal surface-emitting laser structure according to an embodiment of the present invention.
圖2為本發明一實施例光子晶體面射型雷射結構的製造方法的流程示意圖。 Figure 2 is a schematic diagram of the process of manufacturing a photonic crystal surface-emitting laser structure according to an embodiment of the present invention.
圖3至圖11分別為對應圖2所示實施例的步驟示意圖。 Figures 3 to 11 are schematic diagrams of the steps corresponding to the embodiment shown in Figure 2.
圖12為本發明一實施例的光子晶體面射型雷射結構的截面示意圖。 Figure 12 is a cross-sectional schematic diagram of a photonic crystal surface-emitting laser structure according to an embodiment of the present invention.
圖13為本發明一實施例光子晶體面射型雷射結構的製造方法的流程示意圖。 Figure 13 is a schematic diagram of the process of manufacturing a photonic crystal surface-emitting laser structure according to an embodiment of the present invention.
圖14至圖22分別為對應圖13所示實施例的步驟示意圖。 Figures 14 to 22 are schematic diagrams of the steps corresponding to the embodiment shown in Figure 13.
以下是通過特定的具體實施例來說明本發明所公開有關“光子晶體面射型雷射結構及其製造方法”的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與效果。本發明可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不背離本發明的構思下進行各種修改與變更。另外,本發明的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本發明的相關技術內容,但所公開的內容並非用以限制本發明的保護範圍。 The following is a specific embodiment to illustrate the implementation of the "photonic crystal surface-emitting laser structure and its manufacturing method" disclosed in the present invention. Technical personnel in this field can understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can be implemented or applied through other different specific embodiments, and the details in this specification can also be modified and changed based on different viewpoints and applications without departing from the concept of the present invention. In addition, the attached figures of the present invention are only for simple schematic illustrations and are not depicted according to actual sizes. Please note in advance. The following implementation will further explain the relevant technical content of the present invention in detail, but the disclosed content is not used to limit the scope of protection of the present invention.
應當可以理解的是,雖然本文中可能會使用到“第一”、“第 二”、“第三”等術語來描述各種元件或者信號,但這些元件或者信號不應受這些術語的限制。這些術語主要是用以區分一元件與另一元件,或者一信號與另一信號。另外,本文中所使用的術語“或”,應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。 It should be understood that although the terms "first", "second", "third" and the like may be used in this article to describe various components or signals, these components or signals should not be limited by these terms. These terms are mainly used to distinguish one component from another component, or one signal from another signal. In addition, the term "or" used in this article may include any one or more combinations of the related listed items depending on the actual situation.
請參閱圖1,為本發明一實施例的光子晶體面射型雷射結構1A的截面示意圖。光子晶體面射型雷射結構1A包括電路基板11、第一電極層12、歐姆接觸層13、第一半導體層14、第一主動層15、光子晶體層16、第二主動層17、第三半導體層18及第二電極層19。第一電極層12位於電路基板11上,第一電極層12具有容置槽121。歐姆接觸層13位於容置槽121。第一半導體層14位於第一電極層12上,覆蓋歐姆接觸層13。第一主動層15位於第一半導體層14上,第一主動層15包括至少一第一發光層15。光子晶體層16包括第二半導體層161及多個微結構物162,每一微結構物162為透光性導電體,第二半導體層161包括頂部1613、基部1611及填充部1612,多個微結構物162位於基部1611上且間隔排列,填充部1612填滿二相鄰微結構物162之間的間隙,頂部1613連接填充部1612,覆蓋填充部1612及多個微結構物162。第二主動層17位於光子晶體層16上,第二主動層17包括至少一第二發光層17。第三半導體層18位於第二主動層17上。第二電極層19位於第三半導體層18上,第二電極層19具有一槽口191,第三半導體層18的一部份表面顯露於槽口191,定義出光面181。也就是說,第一主動層15與第二主動層17發出的光,在光子晶體層16內共振後由出光面181發射出。
Please refer to FIG. 1 , which is a schematic cross-sectional view of a photonic crystal surface-emitting
第一半導體層14、第二半導體層161及第三半導體層18為磊晶膜層,其所摻雜的材料可以是銦(In)、鎵(Ga)、鋁(Al)、砷(As)、磷(P)、氮(N)或銻(Sb),本發明並無限制。依據一些實施例,第一半導體層14無摻雜,第一半導體層14與第二半導體層161為不同電性,例如第一半導體層14為i型半導體
層,第二半導體層161為P型半導體層。另依據一些實施例,第三半導體層18為介電層。
The
依據一些實施例,第一電極層12及第二電極層19的材質可以是鈦(Ti)、鉑(Pt)、鎳(Ni)、鍺(Ge)、金(Au)、鋁(Al)、錫(Sn)或鋅(Zn),但並不以此為限制。
According to some embodiments, the materials of the
依據一些實施例,第一主動層15及第二主動層17的發光波段範圍在280-3000nm。所述的透光性導電物可以是氧化銦錫(ITO,Indium Tin Oxide)。然而,並不限於此,依據一些實施例,透光性導電物為銦鋅氧化物(IZO)。依據一些實施例,透光性導電物的厚度(即縱向方向的長度)範圍在140-160nm。優選的,為150nm。依據圖1所示的實施例,微結構物162為柱體形狀,相鄰的柱體之間具有間隙,由填充部1612所填滿。
According to some embodiments, the luminescent wavelength range of the first
在此實施例中,第一主動層15包括一第一發光層15,第二主動層17包括一第二發光層17。然而,本發明並不限於此。依據一些實施例,第一主動層15包括多個第一發光層15,第二主動層17包括多個第二發光層17,其中第一主動層15中最遠離光子晶體層16的第一發光層15之間的距離小於等於1μm。第二主動層17中最遠離光子晶體層16的第二發光層17之間的距離小於等於1μm。
In this embodiment, the first
在此實施例中,光子晶體面射型雷射結構1A還包括保護層20,保護層20側向包覆第二電極層19、第三半導體層18、第二主動層17、光子晶體層16及第一主動層15,保護層20還覆蓋出光面181。依據一些實施例,保護層20的材質由氧化矽(SiO2)製造。在此實施例中,第二電極層19的一部顯露於保護層20,以接收電流注入。
In this embodiment, the photonic crystal surface-emitting
依據圖1所示的實施例,第一主動層15與第二主動層17之間具有光子晶體層16,光線在最大範圍下於腔內共振,如此可增強出光面181的出光
量。
According to the embodiment shown in FIG. 1 , a
依據圖1所示的實施例,光子晶體面射型雷射結構1A具有歐姆接觸層13,如此可使電流集中在出光區域(對應出光面181)。
According to the embodiment shown in FIG. 1 , the photonic crystal surface-emitting
此外,依據此實施例,所使用的電路基板11為金屬-陶瓷基板或複合式金屬基板,搭配歐姆接觸層13使用,可以加強光子晶體面射型雷射結構1A的散熱效果。也可使光子晶體面射型雷射結構1A在高電流的注入下維持良好的發光效能。
In addition, according to this embodiment, the
請參閱圖2至圖12,圖2為本發明一實施例光子晶體面射型雷射結構的製造方法100的流程示意圖。圖3至圖12分別為對應圖2所示實施例的步驟示意圖。光子晶體面射型雷射結構的製造方法100包括:步驟S1至步驟S9。
Please refer to Figures 2 to 12. Figure 2 is a schematic diagram of the process of manufacturing a photonic crystal surface-emitting
步驟S1:提供複合發光層,複合發光層依序包括歐姆接觸層13、第一半導體層14、第一主動層15、第二半導體層161及透光導電層16A,如圖1所示,第一主動層15可包括一個或多個第一發光層15。歐姆接觸層13由金屬及半導體材料製成。例如由P型的氮化鋁鎵。第一半導體層14與第二半導體層161為不同電性。例如第一半導體層14為i型半導體,第二半導體層161為P型半導體。透光導電層16A如氮化矽(SiNx)或氧化銦錫(ITO,Indium Tin Oxide)。依據一些實施例,透光導電層16A包括多個橫置,且相鄰二者具有間隔的條狀結構。依據一些實施例,透光導電層16A的厚度為150nm。
Step S1: Provide a composite light-emitting layer, which includes an
步驟S2:對透光導電層16A進行蝕刻,形成多個微結構物162,多個微結構物162位在第二半導體層161上且間隔排列。對透光導電層16A進行蝕刻的方式有多種,如圖4及圖5所示,在透光導電層16A上設置PC板40(如PMMA)做為遮罩,以E-Beam在透光導電層16A上製作光阻圖案,並進一步對透光導電層16A進行蝕刻,相鄰的微結構物162具有間隙。依據一些實施例,也可通過奈米壓印(Nanoimprint Lithography,NIL)對透光導電層16A製作光阻
圖案。接著對透光導電層16A進行蝕刻,使透光導電層16A形成多個微結構物162。
Step S2: Etching the light-transmitting
步驟S3:對第二半導體層161進行再長晶(regrowth)步驟,例如以有機金屬化學氣相沉積法(Metal-organic Chemical Vapor Deposition,MOCVD)進行再長晶,形成頂部1613及填充部1612,填充部1612填滿二相鄰微結構物162之間的間隙,頂部1613連接填充部1612,覆蓋填充部1612及多個微結構物162,第二半導體層161、多個微結構物162、填充部1612及頂部1613形成光子晶體層16,如圖6所示。
Step S3: Perform a re-crystallization step on the
步驟S4:設置第二主動層17於光子晶體層16上,第二主動層17可包括一個或多個第二發光層17。步驟S5:設置第三半導體層18於第二主動層17上,如圖7所示。
Step S4: Dispose the second
步驟S6:側向蝕刻第一主動層15、光子晶體層16、第二主動層17及第三半導體層18,使第一主動層15的兩側與第一半導體層14分別形成斷差結構21,如圖8所示。
Step S6: Laterally etch the first
步驟S7:設置上電極層19於第三半導體層18上,上電極層19具有槽口191,第三半導體層18的一部份表面顯露於槽口191,所述部分表面定義出光面181,如圖9所示。
Step S7: An
步驟S8:設置保護層20,沿斷差結構21包覆上電極層19、第三半導體層18、第二主動層17、光子晶體層16及第一主動層15,如圖10所示。
Step S8: Set up a
步驟S9:設置下電極層12於第一半導體層14下方,下電極層12具有容置槽121,容置歐姆接觸層13,如圖11所示。設置下電極層12的方式具有多種,依據一些實施例,是通過覆晶接合技術(Flip Chip)、蝕刻歐姆接觸層13後,設置下電極層12並移除覆晶接合技術所使的載板及膠體(圖未繪示),即完成光子晶體面射型雷射結構的製作。此外,依據此實施例,進一步的在
下電極層12下方設置電路基板11,其結構類似圖1所示實施例。依據一些實施例,上電極層19及下電極層12的材質可以是鈦(Ti)、鉑(Pt)、鎳(Ni)、鍺(Ge)、金(Au)、鋁(Al)、錫(Sn)或鋅(Zn),但並不以此為限制。
Step S9: Set the
請參閱圖12,為本發明一實施例的光子晶體面射型雷射結構1B的截面示意圖。光子晶體面射型雷射結構1B包括電路基板11、第一電極層12、歐姆接觸層13、第一半導體層14、第一主動層15、穿隧接面22、第二主動層17、光子晶體層16、第三半導體層18及第二電極層19。圖12所示實施例與圖1所示的實施例差異在於第一主動層15及第二主動層17之間具有穿隧接面22,光子晶體位於第二主動層17上。第一主動層15包括一個或多個第一發光層15,第二主動層17包括一個或多個第二發光層17。
Please refer to FIG. 12, which is a schematic cross-sectional view of a photonic crystal surface-emitting laser structure 1B of an embodiment of the present invention. The photonic crystal surface-emitting laser structure 1B includes a
關於電路基板11、第一電極層12、歐姆接觸層13、第一半導體層14、第一主動層15、第二主動層17、光子晶體層16、第三半導體層18及第二電極層19請參閱上述說明。穿隧接面22是高折射率介質層,設置穿隧接面22有助於使通過雷射結構的電流均勻化,提升發光效率。
Please refer to the above description for the
請參閱圖13至圖22,圖13為本發明一實施例光子晶體面射型雷射結構的製造方法200的流程示意圖。圖14至圖22分別為對應圖13所示實施例的步驟示意圖。光子晶體面射型雷射結構的製造方法200包括:步驟P1至步驟P8。
Please refer to Figures 13 to 22. Figure 13 is a schematic diagram of the process of manufacturing a photonic crystal surface-emitting
步驟P1:提供複合發光層,複合發光層依序包括歐姆接觸層13、第一半導體層14、第一主動層15、穿隧接面22、第二主動層17、第二半導體層1611及透光導電層16B。依據一些實施例,透光導電層16B的厚度為150nm。透光導電層16B的材料為氮化矽(SiNx)或氧化銦錫(ITO,Indium Tin Oxide),如圖14所示。第一主動層15可包括一個或多個第一發光層15。第二主動層17可包括一個或多個第一發光層17。
Step P1: Provide a composite light-emitting layer, which includes an
步驟P2:對透光導電層16B進行蝕刻,形成多個微結構物162,多個微結構物162位在第二半導體層1611上且間隔排列。蝕刻的方式可參閱上述說明,參閱圖15及圖16,例如,在透光導電層16B上設置PC板40(如PMMA)做為遮罩,以E-Beam在透光導電層16B上製作光阻圖案,並進一步對透光導電層16B進行蝕刻,形成多個微結構物162相鄰的微結構物162具有間隙。依據一些實施例,也可通過奈米壓印(Nanoimprint Lithography,NIL)對透光導電層16B製作光阻圖案。接著對透光導電層16B進行蝕刻,使透光導電層16B形成多個微結構物162。
Step P2: Etching the light-transmitting
步驟P3:對第二半導體層1611進行再長晶(regrowth)步驟,形成頂部1613及填充部1612,填充部1612填滿二相鄰微結構物162之間的間隙,頂部1613連接填充部1612,覆蓋填充部1612及多個微結構物162,第二半導體層1611、多個微結構物162、填充部1612及頂部1613形成光子晶體層16,如圖17所示。
Step P3: Perform a re-crystallization step on the
步驟P4:設置第三半導體層18於光子晶體層16上,如圖18所示。步驟P5:側向蝕刻第一主動層15、穿隧接面22、第二半導體層1611、光子晶體層16及第三半導體層18,使第一主動層15的兩側與第一半導體層14分別形成斷差結構21,如圖19所示。
Step P4: Set the
步驟P6:設置上電極層19,位於第三半導體層18上,上電極層19具有槽口191,第三半導體層18的一部份表面顯露於槽口191,定義出光面181,如圖20所示。
Step P6: Set the
步驟P7:設置保護層20,沿斷差結構21包覆上電極層19、第三半導體層18、第二主動層17、光子晶體層16及第一主動層15,如圖21所示。
Step P7: Set up a
步驟P8:設置下電極層12,位於第一半導體層14下方,下電極層12具有容置槽121,容置歐姆接觸層13。設置下電極層12的方式具有多種,
依據一些實施例,是通過覆晶接合技術(Flip Chip)、蝕刻歐姆接觸層13後,設置下電極層12並移除覆晶接合技術所使的載板及膠體(圖未繪示),即完成光子晶體面射型雷射結構的製作。此外,依據此實施例,進一步的在下電極層12下方設置電路基板11,其結構請參考圖12所示實施例。
Step P8: Set the
在前述的光子晶體面射型雷射結構的製造方法中,依據一些實施例,第一發光層為多個,第二發光層為多個(圖未繪示),第一主動層15中最遠離光子晶體層16的第一發光層之間的距離小於等於1μm。第二主動層17中最遠離光子晶體層16的第二發光層之間的距離小於等於1μm。
In the aforementioned method for manufacturing the photonic crystal surface-emitting laser structure, according to some embodiments, there are multiple first light-emitting layers and multiple second light-emitting layers (not shown), and the distance between the first light-emitting layers farthest from the
[實施例的有益效果] [Beneficial effects of the embodiment]
本發明的其中一有益效果在於,本發明所提供的光子晶體面射型雷射器及其製造方法,其能通過“第一主動層與第二主動層之間具有光子晶體層”的技術方案,光線在最大範圍下於腔內共振,如此可增強出光面的出光量。 One of the beneficial effects of the present invention is that the photonic crystal surface-emitting laser and its manufacturing method provided by the present invention can achieve the maximum range of light resonance in the cavity through the technical solution of "having a photonic crystal layer between the first active layer and the second active layer", thereby enhancing the light output of the light-emitting surface.
依據一實施例,光子晶體面射型雷射結構具有歐姆接觸層,如此可使電流集中在出光區域。進一步的,依據一些實施例,電路基板為金屬-陶瓷基板或複合式金屬基板,搭配歐姆接觸層使用,可以加強光子晶體面射型雷射結構的散熱效果。也可使光子晶體面射型雷射結構在高電流的注入下維持良好的發光效能。 According to one embodiment, the photonic crystal surface emitting laser structure has an ohmic contact layer, so that the current can be concentrated in the light-emitting area. Furthermore, according to some embodiments, the circuit substrate is a metal-ceramic substrate or a composite metal substrate, and is used with an ohmic contact layer to enhance the heat dissipation effect of the photonic crystal surface emitting laser structure. It can also enable the photonic crystal surface emitting laser structure to maintain good luminescence performance under high current injection.
另依據一些實施例,第一主動層及第二主動層之間具有穿隧接面。穿隧接面是高折射率介質層,設置穿隧接面有助於使通過雷射結構的電流均勻化,提升發光效率。 According to some embodiments, there is a tunneling junction between the first active layer and the second active layer. The tunneling junction is a high refractive index medium layer. The provision of the tunneling junction helps to make the current passing through the laser structure uniform and improve the luminescence efficiency.
綜合上述等技術功效,本發明的光子晶體面射型雷射器具有高的光電轉換效率。 Combining the above-mentioned technical effects, the photonic crystal surface-emitting laser of the present invention has a high photoelectric conversion efficiency.
以上所公開的內容僅為本發明的優選可行實施例,並非因此侷 限本發明的申請專利範圍,所以凡是運用本發明說明書及圖式內容所做的等效技術變化,均包含於本發明的申請專利範圍內。 The above disclosed contents are only the preferred feasible embodiments of the present invention, and do not limit the scope of the patent application of the present invention. Therefore, all equivalent technical changes made by using the contents of the specification and drawings of the present invention are included in the scope of the patent application of the present invention.
1A:光子晶體面射型雷射結構 1A: Photonic crystal surface-emitting laser structure
11:電路基板 11: Circuit board
12:第一電極層 12: First electrode layer
121:容置槽 121: Storage tank
13:歐姆接觸層 13: Ohm contact layer
14:第一半導體層 14: First semiconductor layer
15:第一主動層,第一發光層 15: First active layer, first light-emitting layer
16:光子晶體層 16: Photonic crystal layer
161:第二半導體層 161: Second semiconductor layer
1611:基部 1611: Base
1612:填充部 1612: Filling section
1613:頂部 1613: Top
162:微結構物 162: Microstructures
17:第二主動層,第二發光層 17: Second active layer, second light-emitting layer
18:第三半導體層 18: Third semiconductor layer
181:出光面 181: Bright surface
19:第二電極層,上電極層 19: Second electrode layer, upper electrode layer
191:槽口 191: Notch
20:保護層 20: Protective layer
Claims (6)
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| TWM627209U (en) * | 2021-10-28 | 2022-05-21 | 鴻海精密工業股份有限公司 | Photonic crystal surface-emitting laser device and optical system |
| CN115868090A (en) * | 2020-07-14 | 2023-03-28 | 国立大学法人京都大学 | Photonic crystal surface emitting laser element |
| TW202315254A (en) * | 2021-09-29 | 2023-04-01 | 全新光電科技股份有限公司 | A semiconductor laser diode including multiple junctions and grating layer |
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| CN115868090A (en) * | 2020-07-14 | 2023-03-28 | 国立大学法人京都大学 | Photonic crystal surface emitting laser element |
| TW202315254A (en) * | 2021-09-29 | 2023-04-01 | 全新光電科技股份有限公司 | A semiconductor laser diode including multiple junctions and grating layer |
| TWM627209U (en) * | 2021-10-28 | 2022-05-21 | 鴻海精密工業股份有限公司 | Photonic crystal surface-emitting laser device and optical system |
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