TWI885666B - Shallow etching process chamber - Google Patents
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Abstract
本發明涉及一種淺蝕刻處理腔室。淺蝕刻處理腔室包含:基座,其設置在腔室空間的內部;升降環,其形成在基座的兩側;以及移動裝置,其用於使升降環上下移動,透過升降環的上下移動,晶圓在基座上部能夠上下移動。The present invention relates to a shallow etching processing chamber, which comprises: a susceptor arranged inside the chamber space; a lifting ring formed on both sides of the susceptor; and a moving device used to move the lifting ring up and down, through which the lifting ring moves up and down, the wafer can move up and down on the upper part of the susceptor.
Description
本發明涉及一種淺蝕刻處理腔室(shallow etching process chamber),具體地,涉及一種可以在蝕刻製程過程中調節蝕刻製程空間的淺蝕刻處理腔室。 The present invention relates to a shallow etching process chamber, and more specifically, to a shallow etching process chamber capable of adjusting an etching process space during an etching process.
隨著半導體製造製程的微細化以及三維(3D)結構的立體化,需要一種在部分蝕刻製程中移除薄氧化膜或者以非常高的縱橫比來移除薄膜的技術。此外,為了最小化相對較寬圖案(pattern)與較窄圖案之間的蝕刻量差異,即負載效應,正在開發在原子層水準(level)上緩慢地反複蝕刻而沒有負載效應的技術。關於這種高縱橫比的原子層蝕刻技術,正在開發諸如原子層蝕刻(Atomic Layer Etch,ALE)、原子層移除(Atomic Layer Removal,ALR)、或者乾式清洗(Dry Cleaning)的技術。這種淺蝕刻(shallow etching)製程的共同點是包含在80℃以下的低溫下透過自限性改性(Self Limited Modification)反應來進行的吸附步驟以及在120℃以上的高溫下移除改性(Modification)的原子層水準的薄膜的移除步驟。已知的用於淺蝕刻的設備的吸附步驟以及移除步驟都是透過熱處理製程(Thermal Process)進行,這種設備的缺點是需要大量的製程時間,從而限制了生產率。此外,已經開發了利用電漿能(Plasma energy)進行吸附步驟並且利用熱能 進行移除步驟的設備,嘗試透過各種方法逐步改變低溫以及高溫。關於原子層蝕刻(ALE),韓國專利公開號10-2017-0124087公開了一種用於處理半導體基板的方法以及裝置。此外,韓國專利公開號10-2020-0116273揭露了一種包含在微電子工件上形成圖案化結構的微電子工件的製造方法。然而,現有技術並未揭露能夠同時滿足高效率以及生產率的原子層蝕刻(ALE)、或者乾式清洗(Dry Cleaning)技術。 With the miniaturization of semiconductor manufacturing processes and the stereoization of three-dimensional (3D) structures, a technology is needed to remove thin oxide films in a partial etching process or to remove thin films with a very high aspect ratio. In addition, in order to minimize the difference in etching amount between relatively wide patterns and narrow patterns, that is, the loading effect, a technology is being developed to slowly and repeatedly etch at the atomic layer level without the loading effect. Regarding this high aspect ratio atomic layer etching technology, technologies such as atomic layer etching (ALE), atomic layer removal (ALR), or dry cleaning are being developed. The common point of this shallow etching process is that it includes an adsorption step performed by a self-limited modification reaction at a low temperature below 80°C and a removal step of removing the modified atomic layer level film at a high temperature above 120°C. The adsorption step and the removal step of the known shallow etching equipment are both performed by a thermal process. The disadvantage of this equipment is that a large amount of process time is required, thereby limiting productivity. In addition, equipment that uses plasma energy for the adsorption step and thermal energy for the removal step has been developed, and attempts have been made to gradually change the low temperature and high temperature through various methods. Regarding atomic layer etching (ALE), Korean Patent Publication No. 10-2017-0124087 discloses a method and apparatus for processing a semiconductor substrate. In addition, Korean Patent Publication No. 10-2020-0116273 discloses a method for manufacturing a microelectronic workpiece including forming a patterned structure on the microelectronic workpiece. However, the prior art does not disclose an atomic layer etching (ALE) or dry cleaning technology that can simultaneously meet high efficiency and productivity.
本發明旨在解決現有技術的問題,其目的如下所述。 The present invention aims to solve the problems of the prior art, and its purpose is as follows.
現有技術文獻 Existing technical literature
專利文獻1:韓國專利公開號10-2017-0124087(Lam Research Corporation,2017年11月9日公開),使用原子層蝕刻以及選擇性沉積蝕刻基板。 Patent document 1: Korean Patent Publication No. 10-2017-0124087 (Lam Research Corporation, published on November 9, 2017), using atomic layer etching and selective deposition to etch substrates.
專利文獻2:韓國專利公開號10-2020-0116273(Tokyo Electron Co., Ltd.,2020年10月7日公開),鎢或其他金屬層的原子層蝕刻。 Patent document 2: Korean Patent Publication No. 10-2020-0116273 (Tokyo Electron Co., Ltd., published on October 7, 2020), atomic layer etching of tungsten or other metal layers.
本發明的目的在於提供一種淺蝕刻處理腔室,此淺蝕刻處理腔室在進行利用電漿能的低溫吸附步驟時可以同時滿足高效率以及生產率。 The purpose of the present invention is to provide a shallow etching processing chamber, which can simultaneously meet high efficiency and productivity when performing a low-temperature adsorption step using plasma energy.
根據本發明的適當的實施方式,淺蝕刻處理腔室包含:基座,其設置在腔室空間的內部;升降環,其形成在基座的兩側;以及移動裝置,其用於使升降環上下移動,透過升降環的上下移動,晶圓在基座上部能夠上下移動。 According to a suitable implementation of the present invention, the shallow etching processing chamber includes: a susceptor, which is arranged inside the chamber space; a lifting ring, which is formed on both sides of the susceptor; and a moving device, which is used to move the lifting ring up and down, and through the up and down movement of the lifting ring, the wafer can move up and down on the top of the susceptor.
根據本發明的另一適當的實施方式,淺蝕刻處理腔室進一步包含:內部噴頭以及外部噴頭,其設置在腔室空間的上部,在內部噴頭中設置有噴頭加熱器。 According to another suitable implementation of the present invention, the shallow etching processing chamber further comprises: an internal nozzle and an external nozzle, which are arranged at the upper part of the chamber space, and a nozzle heater is arranged in the internal nozzle.
根據本發明的另一適當的實施方式,淺蝕刻處理腔室進一步包含:擋板,其設置在內部噴頭與外部噴頭之間。 According to another suitable embodiment of the present invention, the shallow etching processing chamber further comprises: a baffle disposed between the inner nozzle and the outer nozzle.
根據本發明的又一適當的實施方式,升降環上升並與擋板接觸。 According to another suitable embodiment of the present invention, the lifting ring rises and contacts the baffle.
根據本發明的又一適當的實施方式,透過上升的升降環,在內部噴頭與晶圓之間形成製程空間。 According to another suitable implementation of the present invention, a process space is formed between the inner nozzle and the wafer by means of a rising lifting ring.
根據本發明的又一適當的實施方式,淺蝕刻處理腔室進一步包含:升降環加熱器,其設置在升降環的內部。 According to another suitable implementation of the present invention, the shallow etching processing chamber further comprises: a lifting ring heater, which is arranged inside the lifting ring.
根據本發明的又一適當的實施方式,移動裝置包含:線性齒輪;以及,升降軸,其能夠沿線性齒輪移動。 According to another suitable embodiment of the present invention, the moving device includes: a linear gear; and a lifting shaft capable of moving along the linear gear.
根據本發明的又一適當的實施方式,淺蝕刻處理腔室進一步包含:移動氣體壁,其圍繞內部噴頭的上部並且能夠上下移動。 According to another suitable embodiment of the present invention, the shallow etching processing chamber further comprises: a moving gas wall which surrounds the upper part of the inner nozzle and can move up and down.
根據本發明的又一適當的實施方式,擋板中形成有流動路徑。 According to another suitable embodiment of the present invention, a flow path is formed in the baffle.
根據本發明的又一適當的實施方式,升降環與擋板的底面接觸,或者與擋板的底面的一部分接觸,又或者與擋板的底面以及內側面接觸。 According to another suitable embodiment of the present invention, the lifting ring contacts the bottom surface of the baffle, or contacts a part of the bottom surface of the baffle, or contacts the bottom surface and inner side surface of the baffle.
根據本發明的淺蝕刻處理腔室,利用電漿能的以晶圓溫度為基準的低溫吸附步驟以及高溫移除步驟可以在一個腔室中進行,且快速改變晶圓的溫度,從而高效地進行吸附步驟。因此,提高了生產率並提高了以高縱橫比移 除薄膜的製程效率。根據本發明的淺蝕刻處理腔室可以應用於包含原子層蝕刻(ALE)製程在內的各種微細製程,並且本發明不限定於此。 According to the shallow etching processing chamber of the present invention, a low-temperature adsorption step based on the wafer temperature and a high-temperature removal step using plasma energy can be performed in one chamber, and the temperature of the wafer can be changed quickly, thereby efficiently performing the adsorption step. Therefore, the productivity is improved and the process efficiency of removing thin films with a high aspect ratio is improved. The shallow etching processing chamber according to the present invention can be applied to various micro processes including atomic layer etching (ALE) processes, and the present invention is not limited thereto.
11:腔室空間 11: Chamber space
12:靜電吸盤 12: Electrostatic suction cup
13:升降環 13: Lifting ring
14a,14b:線性齒輪 14a,14b: Linear gears
15a,15b:升降軸 15a,15b: lifting shaft
16a,16b,16c,19:電纜 16a,16b,16c,19: Cables
17a:內部噴頭 17a: Internal nozzle
17b:外部噴頭 17b: External nozzle
18:擋板 18: Baffle
41a,41b:齒輪單元 41a,41b: Gear unit
42:移動氣體壁 42: Moving gas wall
121,131,171:加熱器 121,131,171: Heater
RPS:遠程電漿源 RPS: Remote Plasma Source
B:基座塊 B: Base block
C:蓋 C: Cover
P:流入路徑 P: Inflow path
P1,P2,P3,P4:電力供應裝置 P1,P2,P3,P4: Power supply device
M1,M2,M3:馬達 M1,M2,M3: Motor
W:晶圓 W: Wafer
P51,P52,P53,P54,P55:步驟 P51,P52,P53,P54,P55: Steps
圖1示出根據本發明的淺蝕刻處理腔室的實施例。 FIG. 1 shows an embodiment of a shallow etching processing chamber according to the present invention.
圖2示出根據本發明的淺蝕刻處理腔室的操作結構的實施例。 FIG. 2 shows an embodiment of the operating structure of the shallow etching processing chamber according to the present invention.
圖3示出根據本發明的淺蝕刻處理腔室中的擋板(baffle)與升降環(lift ring)之間的相互位置關係的實施例。 FIG. 3 shows an embodiment of the relative positional relationship between a baffle and a lift ring in a shallow etching processing chamber according to the present invention.
圖4示出根據本發明的淺蝕刻處理腔室的另一實施例。 FIG. 4 shows another embodiment of a shallow etching processing chamber according to the present invention.
圖5示出在根據本發明的淺蝕刻處理腔室中進行原子層蝕刻(ALE)製程的流程的實施例。 FIG. 5 shows an embodiment of a flow chart of an atomic layer etching (ALE) process in a shallow etching processing chamber according to the present invention.
在下文中將參照附圖所示的實施例對本發明進行詳細說明,但這些實施例僅用於清楚地理解本發明,本發明並不限定於這些實施例。在下文的說明中,不同的附圖中具有相同元件符號的元件具有類似的功能,因此除非為了理解本發明所必需的,否則將不會重複說明,已知的組件將被簡要說明或省略,但是不應理解為其被排除在本發明的實施例之外。 The present invention will be described in detail below with reference to the embodiments shown in the accompanying drawings, but these embodiments are only used to clearly understand the present invention, and the present invention is not limited to these embodiments. In the following description, components with the same component symbols in different drawings have similar functions, so unless necessary for understanding the present invention, they will not be repeated. Known components will be briefly described or omitted, but it should not be understood that they are excluded from the embodiments of the present invention.
圖1示出根據本發明的淺蝕刻處理腔室的實施例。 FIG. 1 shows an embodiment of a shallow etching processing chamber according to the present invention.
參照圖1,淺蝕刻處理腔室包含:基座(susceptor),其設置在腔室空間11的內部;升降環13,其形成在基座的兩側;以及移動裝置,其用於使升降環13上下移動,透過升降環13的上下移動,晶圓W在基座上部能夠上下移動。
Referring to FIG. 1 , the shallow etching processing chamber includes: a susceptor, which is disposed inside the
腔室空間11可以透過底面以及外周壁與外部分隔開,並且蓋C可以結合至腔室空間11的上部。腔室空間11可以形成為真空狀態,並且在腔室空間11中可以產生電漿,或者產生的電漿可以流入腔室空間11。腔室空間11可以具有能夠進行半導體製程或蝕刻製程的各種結構。可以在腔室空間11中形成基座塊(base block)B,並且可以在基座塊B的上部設置基座(susceptor)以固定晶圓W。基座可以為固定晶圓W的各種裝置,並且可以包含加熱器131或冷卻劑流動路徑。基座可以包含例如靜電吸盤12,在下文中將以使用靜電吸盤12的實施例進行說明,但是基座不限定於此。靜電吸盤12可以設置在基座塊B的上部,在靜電吸盤12的內部可以設置有加熱器121,並且用於蝕刻製程的晶圓W可以固定在靜電吸盤12的上表面。此外,在靜電吸盤12的外周面設置升降環13,升降環13用於固定固定在靜電吸盤12的上表面的晶圓W,且保持電漿密度均勻,以防止晶圓W受到污染。升降環13可以具有與邊緣環相同或相似的功能,並且邊緣環可以為升降環13。在升降環13的內部設置有加熱器131,從而可以控制升降環13的溫度。升降環13可以支撐晶圓W的外周部分,升降環13的彼此面對的兩側部分可以透過移動裝置上下移動。當支撐晶圓W的升降環13向上移動時,晶圓W可以隨之向上移動。如上所述,升降環13可以發揮向上或向下移動晶圓W的作用。移動裝置包含線性齒輪14a、14b以及能夠沿線性齒輪14a、14b移動的升降軸15a、15b。第一線性齒輪14a以及第二線性齒輪14b可以從腔室空間的底面垂直向上延伸,並且在第一線性齒輪14a以及第二線性齒輪14b的一側面可以沿第一線性齒輪14a以及第二線性齒輪14b的延伸方向形成嚙合齒。升降軸15a、15b可以分別結合至第一線性齒輪14a以及所述第二線性齒輪14b並且能夠上下移動。各升降軸15a、15b的上端可以結合至升降環13的彼此面對部分的下部,並且透過第一馬
達M1以及第二馬達M2的驅動,各升降軸15a、15b可以沿各線性齒輪14a、14b上下移動,從而使得升降環13上下移動。例如,升降軸15a、15b可以包含與線性齒輪14a、14b嚙合的小齒輪。升降軸15a、15b相對於線性齒輪14a、14b的上下移動可以透過各種方法實現,本發明不限定於此。可以向設置在靜電吸盤12中的加熱器121或者設置在升降環13中的加熱器131供應用於溫度控制的電力,第一電力供應裝置P1、第二電力供應裝置P2、以及第三電力供應裝置P3可以透過第一電纜16a、第二電纜16b、以及第三電纜16c向靜電吸盤加熱器121以及升降環加熱器131供應電力,以調節靜電吸盤12或升降環13的溫度。例如,靜電吸盤12的溫度可以調節為在20℃至80℃的溫度範圍內,升降環13的溫度可以調節為在150℃至300℃的溫度範圍內。可以向設置在升降環13的內部的加熱器131的彼此面對的兩側部分供應電力,以調節升降環13的溫度。升降環13的內部的加熱器131可以透過各種方法形成,例如可以在升降環13的內部設置整體呈圓形的加熱器131,也可以在兩側部分設置加熱器131,本發明並不限定於此。
The
蓋C可以結合至腔室空間11的上部,並且在蓋C的中心部分可以形成用於將電漿從遠程電漿源RPS引導至腔室空間的內部的流入路徑P。此外,在蓋C的下部可以設置有內部噴頭17a,在內部噴頭17a的外周外側可以設置有外部噴頭17b。內部噴頭17a或者外部噴頭17b可以由諸如鋁的材料製成,但不限定於此。內部噴頭17a可以具有圓形板或多邊形板的形狀並且具有平板形狀,並且在整個內部噴頭17a中可以形成有沿從上到下的方向貫通的通孔,以供電漿或氣體流入。此外,在內部噴頭17a的內部可以設置加熱器171,並且電力供應裝置P4可以透過電纜19供應電力,以將內部噴頭17a的溫度調節為在300℃至400℃的溫度範圍內。內部噴頭17a的邊緣可以呈向下傾斜的形狀,並且外部噴頭17b可以
設置在內部噴頭17a的外側。外部噴頭17b可以呈以內部噴頭17a的邊緣的傾斜度延伸的形態而向外側傾斜的形狀。與內部噴頭17a相似的,在外部噴頭17b中可以均勻地形成用於將電漿或者氣體引導至腔室空間11中的多個通孔。可以在內部噴頭17a與外部噴頭17b之間設置擋板18,並且在擋板18中可以沿水平方向或類似方向形成有至少一個狹縫或通孔。擋板18可以由水晶(quartz)或其相似材料製成,但不限定於此。擋板18可以包含傾斜的外表面,並且傾斜的外表面可以連接至內部噴頭17a的邊緣的傾斜面以及外部噴頭17b的傾斜面。擋板18可以具有能夠阻斷內部噴頭17a與外部噴頭17b之間的熱傳遞並且防止自由基(radical)的攻擊(attack)的各種結構,本發明不限定於此。在下文中將說明在具有這種結構的蝕刻處理腔室中有效地進行蝕刻製程的過程。
The cover C may be coupled to the upper portion of the
圖2示出根據本發明的淺蝕刻處理腔室的操作結構的實施例。 FIG. 2 shows an embodiment of the operating structure of the shallow etching processing chamber according to the present invention.
參照圖2,在蝕刻製程過程中,如圖2的(A)部分所示,可以在晶圓W位於靜電吸盤12上部的狀態下進行吸附製程,並且如圖2的(B)部分所示,可以在晶圓W向上移動的狀態下進行移除製程。遠程電漿源RPS可以通過流入路徑P流入腔室空間11的內部,並且由於腔室空間11的內部存在有氨氣(NH3)、三氟化氮(NF3)、或者氬氣(Ar),因此可以透過流入的電漿形成用於吸附製程(modification step)的離子或自由基。晶圓W可以固定在靜電吸盤12的上部。具體地,晶圓W可以固定在基座上,基座由鋁材料製成並且包含加熱器(heater)或者冷卻器(cooler)。形成在靜電吸盤12上方的內部噴頭17a可以具有使得形成的離子以及自由基均勻地流動至固定在基座上的晶圓W的上部的功能。電力供應裝置可以透過電纜19向加熱器171供應電力,以將內部噴頭17a的溫度保持在300℃至400℃的溫度範圍內。外部噴頭17b可以具有控制內部噴頭17a的側面與腔室空間
11的外周壁之間的製程均勻性(uniformity)的功能。氣體可以通過在擋板18中沿水平方向形成的狹縫或通孔向內部噴頭17a或外部噴頭17b的側面方向流動。擋板18可以具有阻斷熱從內部噴頭17a傳遞至外部噴頭17b的功能,並且可以由水晶或類似材料製成以預防自由基的攻擊。此外,內部噴頭17a、外部噴頭17b、以及腔室空間11的外周壁或者蓋C可以由鋁或其相似材料製成。此外,晶圓基座可以由鋁或其相似材料製成,並且可以透過電力供應裝置透過電纜向加熱器121供應的電力或者透過冷卻裝置而保持在20℃至80℃的溫度範圍內。升降環13可以呈由鋁或水晶材料製成的環形,並且如上所述可以在升降環13的內部設置有加熱器131。此外,電力供應裝置可以透過電纜16b、16c向加熱器131供應電力,以將升降環13保持在150℃至300℃的溫度範圍內。在此狀態下,從500W至3000W功率的遠程電漿源RPS供應電漿,並且在存在有氨氣(NH3)、三氟化氮(NF3)、以及氬氣(Ar)的狀態下進行吸附製程。在腔室空間11的內部,內部噴頭17a的區域溫度可以約為400℃,外部噴頭17b的區域溫度可以約為150℃,與晶圓W相鄰的區域溫度可以約為200℃,晶圓W的下部區域溫度可以約為100℃,並且基座的區域溫度可以約為50℃。在這樣的製程條件下,在吸附步驟完成後,升降環13可以透過包含線性齒輪14a、14b、升降軸15a、15b、或者馬達M1、M2的移動裝置向上移動。升降環13可以接觸至距離晶圓W的外圓周約2mm的點,並且升降環13可以上升並與擋板18接觸。因此,可以由內部噴頭17a、擋板18、升降環13、以及晶圓W形成進行移除製程(removal step)的狹小的移除製程空間。在此狀態下,來自遠程電漿源RPS的電漿的流入被阻斷,並且如圖2的(B)部分所示,可以透過移除製程空間中的氬氣(Ar)移除形成在晶圓W上的薄膜。進行移除製程所需的氬氣(Ar)可以通過形成在內部噴頭17a中的通孔流入移除製程空間的
內部。在移除製程完成後,剩餘的氬氣(Ar)可以通過形成在擋板18中的通孔或狹縫排出至外部。可以適當地調節高溫內部噴頭17a的設定溫度、晶圓W與內部噴頭17a之間的距離、或者晶圓W的溫度。此外,可以在移除製程空間中控制內部噴頭17a與晶圓W之間的距離、擋板18的氣體流動容量(Gas Flow Capacity)以及氣體流量,因此,可以控制移除製程空間的內部壓力。內部噴頭17a以及升降環13可以具有形成移除製程空間、控制溫度、或者控制壓力所需的各種結構,例如,可以具有透過限制氣體的流動來控制氣體流動以及壓力的各種結構。此外,如將在下文中說明的,可以在內部噴頭17a的上部設置移動氣體壁,以透過控制移除製程空間中的氣體流量以及壓力來提高製程均勻性。內部噴頭17a、升降環13、或者擋板18可以具有能夠控制移除製程空間內部的溫度、壓力、空間大小、或者氣體流動的各種結構,本發明不限定於此。
2 , during the etching process, as shown in part (A) of FIG. 2 , the wafer W can be placed on the
圖3示出根據本發明的淺蝕刻處理腔室中的擋板(baffle)與升降環(lift ring)之間的相互位置關係的實施例。 FIG. 3 shows an embodiment of the relative positional relationship between a baffle and a lift ring in a shallow etching processing chamber according to the present invention.
參照圖3,升降環13與擋板18的底面接觸,或者與擋板18的底面的一部分接觸,又或者與擋板18的底面以及內側面接觸。線性齒輪14a、14b以及升降軸15a、15b透過馬達M1、M2的驅動而操作,升降環13可以向上移動並與擋板18接觸。參照圖3的(B)部分,升降環13整體呈環形,內側部分可以呈平面形狀,並且可以向外向上傾斜後再次呈平面形狀。此外,擋板18可以呈上表面以平面形狀延伸後向下傾斜的形狀。此外,擋板18的下表面可以呈平面形狀。在這樣的升降環13以及擋板18的結構中,升降環13的外側平面可以與擋板18的底面接觸,因此移除製程空間的側面被密封,從而使得諸如氬氣(Ar)的氣體可以通過形成在擋板18中的通孔流動。
Referring to FIG3 , the lifting
參照圖3的(C)部分,擋板18可以向內部噴頭17a的內側方向延伸相對較長的長度,並且升降環13的外側平面可以與擋板18的底面的一部分接觸。此外,升降環13的內側平面與擋板18的未接觸平面之間可以形成有間隙。
Referring to part (C) of FIG. 3 , the
參照圖3的(D)部分,升降環13可以包含內側平面、向外側延伸的傾斜面、中間平面、以及形成在中間平面下方的臺階平面。晶圓W的邊緣部分可以與內側平面接觸,例如,內側平面的長度可以為2.0mm至3.0mm。擋板18可以包含內側垂直面以及底面,並且垂直面可以與由中間平面以及臺階平面形成的垂直邊界面接觸。此外,擋板18的底面可以與臺階平面接觸。在這樣的接觸結構中,升降環13中可以形成與擋板18的通孔連接的引導孔。如上所述,升降環13或擋板18可以具有能夠彼此接觸以密封移除製程空間的側面的各種結構,但是本發明不限定於此。
Referring to part (D) of FIG. 3 , the lifting
圖4示出根據本發明的淺蝕刻處理腔室的另一實施例。 FIG. 4 shows another embodiment of a shallow etching processing chamber according to the present invention.
參照圖4,蝕刻處理腔室可以進一步包含移動氣體壁42,移動氣體壁42圍繞內部噴頭17a的上部並且能夠上下移動。如圖4的(A)部分所示,在吸附製程步驟中,移動氣體壁42可以位於腔室的蓋C的上部。移動氣體壁42可以呈圍繞內部噴頭17a的中空缸體形狀或者中空多面體形狀。用於移動移動氣體壁42的齒輪單元41a、41b可以設置在移動氣體壁42的彼此面對的位置,並且如(B)部分所示,移動氣體壁42可以透過馬達M3的驅動沿齒輪單元41a、41b向下移動。此外,移動氣體壁42可以設置為圍繞內部噴頭17a的上部。因此,可以限制或調節氣體通過形成在內部噴頭17a中的通孔流入移除製程空間。移動氣體壁42可以根據內部噴頭17a的形狀具有與其相適應的結構,並且可以透過各種方法上下移動,本發明不限定於此。
4 , the etching processing chamber may further include a moving
圖5示出在根據本發明的淺蝕刻處理腔室中進行原子層蝕刻(ALE)製程的流程的實施例。 FIG. 5 shows an embodiment of a flow chart of an atomic layer etching (ALE) process in a shallow etching processing chamber according to the present invention.
參照圖5,在蝕刻處理腔室中進行原子層蝕刻(ALE)製程的流程包含以下步驟:將晶圓設置並固定在靜電吸盤的基座上(步驟P51);控制蝕刻處理腔室內部的溫度,電漿被引導至腔室內部,進行吸附製程步驟或自限性改性(self-limited modification)製程(步驟P52);吸附製程完成後,晶圓透過升降環的上升而上升,在製程腔室的上部形成移除製程空間(步驟P53);控制升降環的溫度、移除製程空間的壓力或者氣體流動條件(步驟P54);以及透過氬氣(Ar)進行移除製程(步驟P55)。 Referring to FIG. 5 , the flow of performing an atomic layer etching (ALE) process in an etching processing chamber includes the following steps: placing and fixing a wafer on a base of an electrostatic chuck (step P51); controlling the temperature inside the etching processing chamber, and guiding plasma into the chamber to perform an adsorption process step or a self-limited modification process (step P52); after the adsorption process is completed, the wafer is raised by the rise of the lifting ring, and a removal process space is formed at the upper part of the process chamber (step P53); controlling the temperature of the lifting ring, the pressure of the removal process space, or the gas flow conditions (step P54); and performing a removal process through argon (Ar) (step P55).
可以透過遠程電漿源(Remote Plasma Source)形成用於吸附製程的離子以及自由基,並且可以設置內部噴頭,使得形成的離子以及自由基向晶圓的方向均勻地流動。內部噴頭可以保持在300至400℃的溫度範圍內,並且可以在內部噴頭的側面與腔室壁之間設置用於調節製程均勻性的外部噴頭。可以在內部噴頭與外部噴頭之間設置允許氣體向側面流動的擋板。擋板可以由諸如水晶的材料製成,以阻斷熱的傳遞,並且預防自由基的攻擊(attack)。此外,內部噴頭、外部噴頭、以及腔室壁可以由鋁材料製成。此外,晶圓基座由鋁製成並且可以包含加熱器或者用於冷卻劑流動的冷卻劑路徑。晶圓側面的升降環可以由鋁或水晶材料製成,並且升降環內部可以設置有加熱器。具有這種結構的升降環可以保持在150至300℃的溫度範圍內。在這樣的條件下,電漿可以流入腔室內部以進行吸附製程(步驟P52)。升降環可以包含升降環上下移動裝置,升降環透過上下移動裝置可以上升至噴頭的位置,從而使得晶圓可以上升(步驟P53)。在吸附步驟中,在晶圓固定在基座上並保持在20至80℃的溫度範圍內,可 以透過由遠程電漿源形成的離子以及自由基進行自限性改性反應製程。因此,在晶圓上升並形成移除製程區域的狀態下進行的移除步驟中,晶圓透過處於150至300℃的高溫狀態的升降環向上移動,並且可以向上移動至升降環與擋板接觸的位置。因此,晶圓位於保持在300℃至400℃的溫度範圍內的噴頭附近。如上所述,可以由高溫內部噴頭、晶圓、擋板、以及升降環形成移除製程空間,並且可以控制移除製程空間的溫度、壓力、或者氣體流動條件(步驟P54)。在這樣形成的狹小的移除製程空間中,用於進行移除製程的氬氣(Ar)等氣體可以通過形成在噴頭中的通孔填充至移除製程空間中。此外,這種氣體可以通過形成在擋板中的通孔或狹縫排出至外部。可以透過調節高溫噴頭的設定溫度以及晶圓與噴頭之間的距離,在移除步驟中適當地控制晶圓的溫度,從而可以進行用於移除在改性製程中形成的薄膜的移除製程(步驟P55)。新形成的移除製程空間的壓力可以透過噴頭與晶圓之間的距離、擋板的氣體流動容量(capacity)、或者氣體流量來控制。可以透過各種形態的擋板或者升降環的形狀來控制移除製程空間的大小,或者控制氣體的流量或壓力,但是本發明不限定於此。較佳地,可以在噴頭上部形成移動氣體壁以提高均勻性。可以在移除製程空間中添加用於移除製程條件的各種配置,並且本發明不限定於此。 Ions and free radicals for adsorption process can be formed by remote plasma source, and an internal nozzle can be set so that the formed ions and free radicals flow uniformly in the direction of wafer. The internal nozzle can be maintained in the temperature range of 300 to 400°C, and an external nozzle for adjusting the uniformity of the process can be set between the side of the internal nozzle and the chamber wall. A baffle that allows gas to flow to the side can be set between the internal nozzle and the external nozzle. The baffle can be made of materials such as crystal to block the transfer of heat and prevent the attack of free radicals. In addition, the internal nozzle, the external nozzle, and the chamber wall can be made of aluminum material. In addition, the wafer base is made of aluminum and may include a heater or a coolant path for coolant flow. The lifting ring on the side of the wafer may be made of aluminum or a crystal material, and a heater may be provided inside the lifting ring. The lifting ring having such a structure can be maintained within a temperature range of 150 to 300°C. Under such conditions, plasma can flow into the interior of the chamber for an adsorption process (step P52). The lifting ring may include a lifting ring up and down moving device, and the lifting ring can be raised to the position of the nozzle through the up and down moving device, so that the wafer can be raised (step P53). In the adsorption step, the wafer is fixed on the base and maintained in the temperature range of 20 to 80°C, and a self-limiting modification reaction process can be performed by ions and radicals formed by the remote plasma source. Therefore, in the removal step performed in a state where the wafer rises and forms a removal process area, the wafer moves upward through the lifting ring in a high temperature state of 150 to 300°C, and can move upward to a position where the lifting ring contacts the baffle. Therefore, the wafer is located near the nozzle maintained in the temperature range of 300 to 400°C. As described above, a removal process space can be formed by the high-temperature internal nozzle, the wafer, the baffle, and the lifting ring, and the temperature, pressure, or gas flow conditions of the removal process space can be controlled (step P54). In the narrow removal process space thus formed, a gas such as argon (Ar) used for the removal process can be filled into the removal process space through the through hole formed in the nozzle. In addition, such a gas can be discharged to the outside through the through hole or slit formed in the baffle. The temperature of the wafer can be appropriately controlled in the removal step by adjusting the set temperature of the high-temperature nozzle and the distance between the wafer and the nozzle, so that a removal process for removing the thin film formed in the modification process can be performed (step P55). The pressure of the newly formed removal process space can be controlled by the distance between the nozzle and the wafer, the gas flow capacity of the baffle, or the gas flow rate. The size of the removal process space can be controlled by various forms of baffles or the shape of the lifting ring, or the flow rate or pressure of the gas can be controlled, but the present invention is not limited thereto. Preferably, a moving gas wall can be formed on the upper part of the nozzle to improve uniformity. Various configurations for removing process conditions can be added to the removal process space, and the present invention is not limited thereto.
儘管尚文忠已參照實施例詳細說明了本發明,但是本領域具有通常知識者可以在不脫離本發明的技術思想的範圍內參照實施例進行各種變更以及修改。本發明不受這些變更以及修改的限制,而是由所附申請專利範圍限制。 Although Shang Wenzhong has described the present invention in detail with reference to the embodiments, a person with ordinary knowledge in the field can make various changes and modifications with reference to the embodiments without departing from the technical idea of the present invention. The present invention is not limited by these changes and modifications, but is limited by the scope of the attached patent application.
11:腔室空間 11: Chamber space
12:靜電吸盤 12: Electrostatic suction cup
13:升降環 13: Lifting ring
14a,14b:線性齒輪 14a,14b: Linear gears
15a,15b:升降軸 15a,15b: lifting shaft
16a,16b,16c,19:電纜 16a,16b,16c,19: Cables
17a:內部噴頭 17a: Internal nozzle
17b:外部噴頭 17b: External nozzle
18:擋板 18: Baffle
121,131,171:加熱器 121,131,171: Heater
RPS:遠程電漿源 RPS: Remote Plasma Source
C:蓋 C: Cover
P:流入路徑 P: Inflow path
P1,P2,P3,P4:電力供應裝置 P1,P2,P3,P4: Power supply device
M1,M2:馬達 M1,M2: Motor
W:晶圓 W: Wafer
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| TW202527024A (en) | 2025-07-01 |
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