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TWI864126B - Semiconductor device and method for manufacturing the same - Google Patents

Semiconductor device and method for manufacturing the same Download PDF

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Publication number
TWI864126B
TWI864126B TW109134353A TW109134353A TWI864126B TW I864126 B TWI864126 B TW I864126B TW 109134353 A TW109134353 A TW 109134353A TW 109134353 A TW109134353 A TW 109134353A TW I864126 B TWI864126 B TW I864126B
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dielectric
semiconductor
fin
layer
gate structure
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TW109134353A
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Chinese (zh)
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TW202129768A (en
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林志昌
蘇煥傑
江國誠
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台灣積體電路製造股份有限公司
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/80Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
    • H10D84/82Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
    • H10D84/83Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
    • H10D84/834Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET] comprising FinFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/014Manufacture or treatment of FETs having zero-dimensional [0D] or one-dimensional [1D] channels, e.g. quantum wire FETs, single-electron transistors [SET] or Coulomb blockade transistors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/40FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
    • H10D30/43FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 1D charge carrier gas channels, e.g. quantum wire FETs or transistors having 1D quantum-confined channels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/62Fin field-effect transistors [FinFET]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • H10D30/6729Thin-film transistors [TFT] characterised by the electrodes
    • H10D30/673Thin-film transistors [TFT] characterised by the electrodes characterised by the shapes, relative sizes or dispositions of the gate electrodes
    • H10D30/6735Thin-film transistors [TFT] characterised by the electrodes characterised by the shapes, relative sizes or dispositions of the gate electrodes having gates fully surrounding the channels, e.g. gate-all-around
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/67Thin-film transistors [TFT]
    • H10D30/6757Thin-film transistors [TFT] characterised by the structure of the channel, e.g. transverse or longitudinal shape or doping profile
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/113Isolations within a component, i.e. internal isolations
    • H10D62/115Dielectric isolations, e.g. air gaps
    • H10D62/116Dielectric isolations, e.g. air gaps adjoining the input or output regions of field-effect devices, e.g. adjoining source or drain regions
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/117Shapes of semiconductor bodies
    • H10D62/118Nanostructure semiconductor bodies
    • H10D62/119Nanowire, nanosheet or nanotube semiconductor bodies
    • H10D62/121Nanowire, nanosheet or nanotube semiconductor bodies oriented parallel to substrates
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/0123Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
    • H10D84/0126Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
    • H10D84/0151Manufacturing their isolation regions
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/0123Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
    • H10D84/0126Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
    • H10D84/0158Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including FinFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/02Manufacture or treatment characterised by using material-based technologies
    • H10D84/03Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
    • H10D84/038Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/80Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
    • H10D84/82Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
    • H10D84/83Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic

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  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)

Abstract

Various embodiments of the present disclosure are directed towards a semiconductor device. The semiconductor device includes a semiconductor fin projecting from a substrate. Semiconductor nanostructures are disposed over the semiconductor fin. A gate electrode is disposed over the semiconductor fin and around the semiconductor nanostructures. A dielectric fin is disposed over the substrate. A dielectric structure is disposed over the dielectric fin. An upper surface of the dielectric structure is disposed over the upper surface of the gate electrode. A dielectric layer is disposed over the substrate. The dielectric fin laterally separates both the gate electrode and the semiconductor nanostructures from the dielectric layer. An upper surface of the dielectric layer is disposed over the upper surface of the gate electrode structure and the upper surface of the dielectric structure. A lower surface of the dielectric layer is disposed below the upper surface of the dielectric fin.

Description

半導體裝置與其形成方法 Semiconductor device and method for forming the same

本發明實施例關於形成奈米結構場效電晶體之間的空間減少之半導體裝置之方法。 The present invention relates to a method for forming a semiconductor device with reduced space between nanostructured field effect transistors.

積體電路製造產業在過去數十年已經歷指數成長。隨著積體電路發展,可持續減少最小結構尺寸以改善多種電子構件(如電晶體、二極體、電阻、電容、或類似物)的積體密度,使更多電子構件可整合至給定面積中。尺寸縮小的製程可提供許多優點,比如增加產能、降低製作成本、增加裝置效能、或類似優點。積體電路產業縮小半導體裝置的進展之一為多閘極場效電晶體。多閘極場效電晶體的一些例子包括雙閘極場效電晶體、三閘極場效電晶體、Ω閘極場效電晶體、或全繞式閘極場效電晶體。 The integrated circuit manufacturing industry has experienced exponential growth over the past several decades. As integrated circuits develop, the minimum structural dimensions can be continuously reduced to improve the integration density of various electronic components (such as transistors, diodes, resistors, capacitors, or the like), so that more electronic components can be integrated into a given area. The process of shrinking dimensions can provide many advantages, such as increased throughput, reduced manufacturing costs, increased device performance, or the like. One of the advances in the integrated circuit industry to shrink semiconductor devices is the multi-gate field effect transistor. Some examples of multi-gate field effect transistors include bi-gate field effect transistors, tri-gate field effect transistors, Ω-gate field effect transistors, or fully wound gate field effect transistors.

本發明一些實施例提供半導體裝置。半導體裝置包括半導體鰭狀物,自半導體基板垂直凸起。多個半導體奈米結構,直接位於半導體鰭狀物上並垂直堆疊。閘極結構,位於半導體鰭狀物上並圍繞半導體奈米結構。介電鰭狀物,位於半導體基板上,其中閘極結構與半導體奈米結構位於介電鰭狀物的第一側上,且其中介電鰭狀物的上表面低於閘極結構的上表面。介電結構,直 接位於介電鰭狀物上,其中介電結構的第一上表面高於閘極結構的上表面。介電層,至少部分地位於半導體基板上,其中介電層位於介電鰭狀物的第二側上,且介電鰭狀物的第一側與第二側相對,其中介電層的上表面高於閘極結構的上表面與介電結構的第一上表面,且其中介電層的下表面低於介電鰭狀物的上表面。 Some embodiments of the present invention provide a semiconductor device. The semiconductor device includes a semiconductor fin protruding vertically from a semiconductor substrate. A plurality of semiconductor nanostructures are directly located on the semiconductor fin and stacked vertically. A gate structure is located on the semiconductor fin and surrounds the semiconductor nanostructure. A dielectric fin is located on the semiconductor substrate, wherein the gate structure and the semiconductor nanostructure are located on a first side of the dielectric fin, and wherein the upper surface of the dielectric fin is lower than the upper surface of the gate structure. A dielectric structure is directly located on the dielectric fin, wherein the first upper surface of the dielectric structure is higher than the upper surface of the gate structure. A dielectric layer is at least partially disposed on a semiconductor substrate, wherein the dielectric layer is disposed on the second side of the dielectric fin, and the first side and the second side of the dielectric fin are opposite to each other, wherein the upper surface of the dielectric layer is higher than the upper surface of the gate structure and the first upper surface of the dielectric structure, and wherein the lower surface of the dielectric layer is lower than the upper surface of the dielectric fin.

本發明一些實施例提供半導體裝置。半導體裝置包括第一半導體鰭狀物與第二半導體鰭狀物,自半導體基板垂直凸起,其中第二半導體鰭狀物與第一半導體鰭狀物在第一方向中橫向分開,其中第一半導體鰭狀物與第二半導體鰭狀物在第二方向中橫向延伸並彼此平行,且其中第二方向實質上垂直於第一方向。第一閘極結構,位於第一半導體鰭狀物上。第二閘極結構,位於第二半導體鰭狀物上,並與第一閘極結構在第一方向中橫向分開。第一介電鰭狀物,位於半導體基板上,其中第一介電鰭狀物位於第一半導體鰭狀物與第二半導體鰭狀物之間,以及第一閘極結構與第二閘極結構之間。第二介電鰭狀物,位於半導體基板上,並在第一方向中與第一介電鰭狀物橫向分開,其中第二介電鰭狀物位於第一半導體鰭狀物與第二半導體鰭狀物之間,以及第一閘極結構與第二閘極結構之間。第一介電結構,位於第一介電鰭狀物上。第二介電結構,位於第二介電鰭狀物上,並在第一方向中與第一半導體鰭狀物橫向分開。介電層,至少部分地位於半導體基板上,其中第一介電結構橫向分開介電層與第一閘極結構的第一部分,且第二介電結構橫向分開介電層與第二閘極結構的第一部分。 Some embodiments of the present invention provide a semiconductor device. The semiconductor device includes a first semiconductor fin and a second semiconductor fin, which protrude vertically from a semiconductor substrate, wherein the second semiconductor fin is laterally separated from the first semiconductor fin in a first direction, wherein the first semiconductor fin and the second semiconductor fin extend laterally in a second direction and are parallel to each other, and wherein the second direction is substantially perpendicular to the first direction. A first gate structure is located on the first semiconductor fin. A second gate structure is located on the second semiconductor fin and is laterally separated from the first gate structure in the first direction. A first dielectric fin is disposed on the semiconductor substrate, wherein the first dielectric fin is disposed between the first semiconductor fin and the second semiconductor fin, and between the first gate structure and the second gate structure. A second dielectric fin is disposed on the semiconductor substrate and is laterally separated from the first dielectric fin in a first direction, wherein the second dielectric fin is disposed between the first semiconductor fin and the second semiconductor fin, and between the first gate structure and the second gate structure. A first dielectric structure is disposed on the first dielectric fin. A second dielectric structure is disposed on the second dielectric fin and is laterally separated from the first semiconductor fin in the first direction. A dielectric layer is at least partially disposed on a semiconductor substrate, wherein a first dielectric structure laterally separates the dielectric layer from a first portion of a first gate structure, and a second dielectric structure laterally separates the dielectric layer from a first portion of a second gate structure.

本發明一些實施例提供半導體裝置的形成方法。方法包括接收工件。工件包括第一介電鰭狀物,位於半導體基板上並橫向地位於第一多個半導體奈米結構與第二多個半導體奈米結構之間;第二介電鰭狀物,位於半導體基板上並橫向地位於第三多個半導體奈米結構與第二多個半導體奈米結構之間; 第一導電閘極結構,位於半導體基板上並圍繞第一多個半導體奈米結構;第二導電閘極結構,位於半導體基板上並圍繞第二多個半導體奈米結構;第三導電閘極結構,位於半導體基板上並圍繞第三多個半導體奈米結構,其中第二導電閘極結構位於第一導電閘極結構與第三導電閘極結構之間,並與第一導電閘極結構及第三導電閘極結構橫向分開;第一介電結構,直接位於第一介電鰭狀物上,其中第一介電結構與第一介電鰭狀物橫向分開第一導電閘極結構與第二導電閘極結構;以及第二介電結構,直接位於第二介電鰭狀物上,其中第二介電結構與第二介電鰭狀物橫向分開第三導電閘極結構與第二導電閘極結構。形成第一介電層於第一介電鰭狀物、第二介電鰭狀物、第一多個半導體奈米結構、第二多個半導體奈米結構、第三多個半導體奈米結構、第一介電結構、第二介電結構、第一導電閘極結構、第二導電閘極結構、與第三導電閘極結構上。形成第一開口於第一介電層中,其中第一開口與第一介電結構、第二介電結構、與第二導電閘極結構至少部分重疊。移除第二導電閘極結構。移除第一開口下的第一介電結構之一部分,以形成直接位於第一介電鰭狀物上的第三介電結構。移除第一開口下的第二介電結構之一部分,以形成直接位於第二介電鰭狀物上的第四介電結構。移除第二多個半導體奈米結構,以形成第二開口於第一開口下。形成第二介電層於第一開口與第二開口中,並至少部分地覆蓋第三介電結構與第四介電結構。 Some embodiments of the present invention provide a method for forming a semiconductor device. The method includes receiving a workpiece. The workpiece includes a first dielectric fin, located on a semiconductor substrate and laterally located between a first plurality of semiconductor nanostructures and a second plurality of semiconductor nanostructures; a second dielectric fin, located on the semiconductor substrate and laterally located between a third plurality of semiconductor nanostructures and the second plurality of semiconductor nanostructures; a first conductive gate structure, located on the semiconductor substrate and surrounding the first plurality of semiconductor nanostructures; a second conductive gate structure, located on the semiconductor substrate and surrounding the second plurality of semiconductor nanostructures; a third conductive gate structure, located on the semiconductor substrate and surrounding A third plurality of semiconductor nanostructures, wherein the second conductive gate structure is located between the first conductive gate structure and the third conductive gate structure and is laterally separated from the first conductive gate structure and the third conductive gate structure; a first dielectric structure is directly located on the first dielectric fin, wherein the first dielectric structure and the first dielectric fin laterally separate the first conductive gate structure from the second conductive gate structure; and a second dielectric structure is directly located on the second dielectric fin, wherein the second dielectric structure and the second dielectric fin laterally separate the third conductive gate structure from the second conductive gate structure. A first dielectric layer is formed on a first dielectric fin, a second dielectric fin, a first plurality of semiconductor nanostructures, a second plurality of semiconductor nanostructures, a third plurality of semiconductor nanostructures, a first dielectric structure, a second dielectric structure, a first conductive gate structure, a second conductive gate structure, and a third conductive gate structure. A first opening is formed in the first dielectric layer, wherein the first opening at least partially overlaps with the first dielectric structure, the second dielectric structure, and the second conductive gate structure. The second conductive gate structure is removed. A portion of the first dielectric structure under the first opening is removed to form a third dielectric structure directly on the first dielectric fin. A portion of the second dielectric structure under the first opening is removed to form a fourth dielectric structure directly on the second dielectric fin. The second plurality of semiconductor nanostructures are removed to form a second opening under the first opening. A second dielectric layer is formed in the first opening and the second opening, and at least partially covers the third dielectric structure and the fourth dielectric structure.

A-A,B-B:剖線 A-A, B-B: section line

D1:第一距離 D 1 : First distance

D2:第二距離 D 2 : Second distance

H1:第一高度 H 1 : First height

H2:第二高度 H 2 : Second height

H3:第三高度 H 3 : The third height

H4:第四高度 H 4 : Fourth height

H5:第五高度 H 5 : Fifth height

H6:第六高度 H 6 : Sixth height

W1:第一寬度 W 1 : First width

W2:第二寬度 W 2 : Second width

102:基底半導體結構 102: Base semiconductor structure

104:半導體層的堆疊 104: Stacking of semiconductor layers

106:第一半導體層 106: First semiconductor layer

108:第二半導體層 108: Second semiconductor layer

110:硬遮罩層 110: Hard mask layer

202:第一硬遮罩結構 202: First hard mask structure

204:半導體結構的第一堆疊 204: The first stack of semiconductor structures

206:第一半導體結構 206: First semiconductor structure

208:第二半導體結構 208: Second semiconductor structure

210:鰭狀物 210: Fins

210a:第一鰭狀物 210a: First fin

210b:第二鰭狀物 210b: Second fin

210c:第三鰭狀物 210c: Third fin

210d:第四鰭狀物 210d: Fourth fin

210e:第五鰭狀物 210e: Fifth fin

210f:第六鰭狀物 210f: Sixth fin

212:基板 212: Substrate

214:第一溝槽 214: First groove

302:襯墊層 302: Pad layer

304:第一介電層 304: First dielectric layer

402:隔離結構 402: Isolation structure

404:蓋結構 404: Cover structure

406:第二溝槽 406: Second groove

502:介電鰭狀物 502: Dielectric fins

502a:第一介電鰭狀物 502a: first dielectric fin

502b:第二介電鰭狀物 502b: Second dielectric fin

502c:第三介電鰭狀物 502c: Third dielectric fin

502d:第四介電鰭狀物 502d: Fourth dielectric fin

502e:第五介電鰭狀物 502e: Fifth dielectric fin

504:介電帶 504: Dielectric tape

602:虛置閘極結構 602: Virtual gate structure

604:虛置閘極介電結構 604: Virtual gate dielectric structure

606:虛置閘極材料結構 606: Virtual gate material structure

608:第二硬遮罩結構 608: Second hard mask structure

610:第三硬遮罩結構 610: The third hard mask structure

612:第四硬遮罩結構 612: Fourth hard mask structure

702:第一側壁間隔物 702: First side wall spacer

704:第一多個介電結構 704: The first plurality of dielectric structures

704a:第一介電結構 704a: first dielectric structure

704b:第二介電結構 704b: Second dielectric structure

704b/704d:保留的介電結構 704b/704d: Retained dielectric structure

704c:第三介電結構 704c: The third dielectric structure

704d:第四介電結構 704d: Fourth dielectric structure

704e:第五介電結構 704e: Fifth dielectric structure

705:半導體結構的第二堆疊 705: Second stack of semiconductor structures

706:第三半導體結構 706: The third semiconductor structure

708:第四半導體結構 708: Fourth semiconductor structure

802:第二側壁間隔物 802: Second side wall spacer

902:第一源極/汲極區 902: First source/drain region

902a:第一對 902a: The first pair

902b:第二對 902b: Second pair

902c:第五對 902c: The fifth pair

902d:第六對 902d: The sixth pair

904:第二源極/汲極區 904: Second source/drain region

904a:第三對 904a: The third pair

904b:第四對 904b: The fourth pair

1002:第一蝕刻停止層 1002: First etching stop layer

1004:層間介電層 1004: Interlayer dielectric layer

1102:第三溝槽 1102: The third groove

1104:第一遮罩結構 1104: First mask structure

1106:第五硬遮罩結構 1106: Fifth hard mask structure

1302:奈米結構堆疊 1302: Nanostructure stacking

1302a:第一奈米結構堆疊 1302a: First nanostructure stacking

1302b:第二奈米結構堆疊 1302b: Second nanostructure stacking

1302c:第三奈米結構堆疊 1302c: The third nanostructure stack

1302d:第四奈米結構堆疊 1302d: The fourth nanostructure stack

1302e:第五奈米結構堆疊 1302e: The fifth nanostructure stack

1302f:第六奈米結構堆疊 1302f: The sixth nanostructure stack

1304:奈米結構 1304:Nanostructure

1402:界面層 1402: Interface layer

1404:閘極介電層 1404: Gate dielectric layer

1406:閘極層 1406: Gate layer

1502:閘極結構 1502: Gate structure

1502a:第一閘極結構 1502a: First gate structure

1502b:第二閘極結構 1502b: Second gate structure

1502c:第三閘極結構 1502c: Third gate structure

1504:第二蝕刻停止層 1504: Second etch stop layer

1506:第四介電層 1506: Fourth dielectric layer

1602:第一開口 1602: First opening

1604:第二遮罩結構 1604: Second mask structure

1801:第二開口 1801: Second opening

1802:凹陷的介電鰭狀物 1802: Recessed dielectric fins

1804a:第一凹陷的半導體鰭狀物 1804a: First recessed semiconductor fin

1804b:第二凹陷的半導體鰭狀物 1804b: Second recessed semiconductor fin

1806:第二多個介電結構 1806: Second dielectric structure

1806a:第六介電結構 1806a: Sixth dielectric structure

1806b:第七介電結構 1806b: The seventh dielectric structure

1808:閘極介電結構 1808: Gate dielectric structure

1808a:第一閘極介電結構 1808a: First gate dielectric structure

1808b:第二閘極介電結構 1808b: Second gate dielectric structure

1810:奈米結構場效電晶體 1810:Nanostructure Field Effect Transistor

1810a:第一奈米結構場效電晶體 1810a: The first nanostructured field effect transistor

1810b:第二奈米結構場效電晶體 1810b: The second nanostructure field effect transistor

1902:第五介電層 1902: Fifth dielectric layer

1904:半導體裝置 1904: Semiconductor devices

2002:第一內側側壁 2002: First medial sidewall

2004:第二內側側壁 2004: Second medial sidewall

2102:垂直部分 2102: Vertical section

2102a:第一垂直部分 2102a: First vertical section

2102b:第二垂直部分 2102b: Second vertical section

2104:橫向部分 2104: Horizontal part

2104a:第一橫向部分 2104a: First horizontal part

2104b:第二橫向部分 2104b: Second horizontal part

2106:區域 2106: Region

2202:第一周邊部分 2202: The first peripheral part

2204:第二周邊部分 2204: Second peripheral part

2208:第一上表面 2208: First upper surface

2210:第二上表面 2210: Second upper surface

2300:流程圖 2300: Flowchart

2302,2304,2306,2308,2310,2312,2314,2316:步驟 2302,2304,2306,2308,2310,2312,2314,2316: Steps

圖1至19係一些實施例中,形成奈米結構場效電晶體之間的空間減少的半導體裝置所用的方法之多種圖式。 Figures 1 to 19 are various diagrams of methods used to form a semiconductor device with reduced spacing between nanostructured field effect transistors in some embodiments.

圖20A至20C係一些實施例中,奈米結構場效電晶體之間的空間減少之半導 體裝置的多種圖式。 Figures 20A to 20C are various diagrams of semiconductor devices with reduced spacing between nanostructured field effect transistors in some embodiments.

圖21係一些實施例中,圖20A至20C的半導體裝置沿著圖20A的剖線B-B的剖視圖。 FIG. 21 is a cross-sectional view of the semiconductor device of FIGS. 20A to 20C along the section line B-B of FIG. 20A in some embodiments.

圖22係一些實施例中,半導體裝置的區域透視圖。 FIG. 22 is a perspective view of a region of a semiconductor device in some embodiments.

圖23係一些實施例中,形成奈米結構場效電晶體之間的空間減少的半導體裝置所用的方法之流程圖。 FIG. 23 is a flow chart of a method for forming a semiconductor device with reduced spacing between nanostructured field effect transistors in some embodiments.

以下內容參考圖式說明本發明實施例,類似標記用於標示類似單元,且圖示的結構不必依比例繪製。應將理解的是,詳細說明與對應圖式不侷限本發明實施例的範疇,且詳細說明與圖式僅提供一些例子說明實施本發明概念的一些方式。 The following content refers to the drawings to illustrate the embodiments of the present invention. Similar labels are used to mark similar units, and the structures shown in the drawings are not necessarily drawn to scale. It should be understood that the detailed description and the corresponding drawings do not limit the scope of the embodiments of the present invention, and the detailed description and drawings only provide some examples to illustrate some ways to implement the concepts of the present invention.

下述內容提供的不同實施例或實例可實施本發明的不同結構。特定構件與配置的實施例用以簡化本發明內容而非侷限本發明。舉例來說,形成第一構件於第二構件上的敘述包含兩者直接接觸的實施例,或兩者之間隔有其他額外構件而非直接接觸的實施例。此外,本發明之多個實例可重複採用相同標號以求簡潔,但多種實施例及/或設置中具有相同標號的元件並不必然具有相同的對應關係。 The different embodiments or examples provided below can implement different structures of the present invention. The embodiments of specific components and configurations are used to simplify the content of the present invention but are not intended to limit the present invention. For example, the description of forming a first component on a second component includes an embodiment in which the two are in direct contact, or an embodiment in which the two are separated by other additional components but not in direct contact. In addition, multiple embodiments of the present invention may repeatedly use the same number for simplicity, but components with the same number in multiple embodiments and/or configurations do not necessarily have the same corresponding relationship.

此外,空間性的相對用語如「下方」、「其下」、「較下方」、「上方」、「較上方」、或類似用語可用於簡化說明某一元件與另一元件在圖示中的相對關係。空間性的相對用語可延伸至以其他方向使用之元件,而非侷限於圖示方向。元件亦可轉動90°或其他角度,因此方向性用語僅用以說明圖示中的方向。 In addition, spatially relative terms such as "below", "beneath", "below", "above", "above", or similar terms can be used to simplify the relative relationship of one component to another component in the diagram. Spatially relative terms can be extended to components used in other orientations, not limited to the orientation of the diagram. Components can also be rotated 90° or other angles, so directional terms are only used to describe the orientation in the diagram.

在一些實施例中,半導體裝置(如積體電路)可包含第一奈米結構 場效電晶體(如全繞式場效電晶體),以及與第一奈米結構場效電晶體橫向分開的第二奈米結構場效電晶體。第一奈米結構場效電晶體包括第一金屬閘極,其延伸圍繞第一多個奈米結構,其橫向延伸於一對第一源極/汲極區之間。第二奈米結構場效電晶體包括第二金屬閘極,其延伸圍繞第二多個奈米結構,其橫向延伸於一對第二源極/汲極區之間。 In some embodiments, a semiconductor device (such as an integrated circuit) may include a first nanostructure field effect transistor (such as a fully wound field effect transistor), and a second nanostructure field effect transistor laterally separated from the first nanostructure field effect transistor. The first nanostructure field effect transistor includes a first metal gate extending around a first plurality of nanostructures and extending laterally between a pair of first source/drain regions. The second nanostructure field effect transistor includes a second metal gate extending around a second plurality of nanostructures and extending laterally between a pair of second source/drain regions.

一般而言,形成上述半導體裝置的方法包括形成金屬層,其連續地延伸於第一多個奈米結構與第二多個奈米結構上。之後可選擇性蝕刻金屬層,以形成分開的金屬閘極,進而形成第一金屬閘極與第二金屬閘極。選擇性蝕刻金屬層的步驟移除第一金屬閘極與第二金屬閘極之間的金屬層的一部分,進而形成橫向位於第一金屬閘極與第二金屬閘極之間的開口。接著沉積介電層於開口中。介電層設置為改善半導體裝置的裝置效能(比如降低第一奈米結構場效電晶體與第二奈米結構場效電晶體之間的漏電流),及/或降低製作成本(比如後續可採用自對準接點製程)。 Generally, the method of forming the semiconductor device includes forming a metal layer that extends continuously over the first plurality of nanostructures and the second plurality of nanostructures. The metal layer may then be selectively etched to form separate metal gates, thereby forming a first metal gate and a second metal gate. The step of selectively etching the metal layer removes a portion of the metal layer between the first metal gate and the second metal gate, thereby forming an opening laterally located between the first metal gate and the second metal gate. A dielectric layer is then deposited in the opening. The dielectric layer is provided to improve the device performance of the semiconductor device (e.g., to reduce the leakage current between the first nanostructure field effect transistor and the second nanostructure field effect transistor) and/or to reduce the manufacturing cost (e.g., a self-aligned contact process can be used later).

上述方法的挑戰之一為隨著最小結構尺寸持續縮小(比如3奈米技術節點或更小),上述方法無法提供充足的控制以可信地形成分開的金屬閘極。舉例來說,隨著第一奈米結構場效電晶體與第二奈米結構場效電晶體之間的空間縮小(比如第一多個奈米結構與第二多個奈米結構之間的橫向空間減少至小於40nm),上述方法不足以確保選擇性蝕刻金屬層的部分而只移除金屬層的預先定義的部分。多種圖案化製程的疊對控制不良,可能造成選擇性蝕刻金屬層的步驟非刻意地移除非預先定義移除金屬層的部分。換言之,上述方法會非刻意地移除金屬層的其他部分。由於上述方法非刻意地移除金屬層的部分,隨著最小結構尺寸持續縮小,上述方法會造成電性短路(比如第一金屬閘極與第二金屬閘極之間的電性短路)、不良地影響裝置效能(因為非刻意地減少第一金屬閘極與第二金屬閘極的尺寸)、或類似問題,因此降低產能。 One of the challenges of the above methods is that as the minimum structure size continues to shrink (e.g., to the 3 nm technology node or below), the above methods do not provide sufficient control to reliably pattern separate metal gates. For example, as the spacing between a first nanostructure field effect transistor and a second nanostructure field effect transistor shrinks (e.g., the lateral spacing between the first plurality of nanostructures and the second plurality of nanostructures decreases to less than 40 nm), the above methods are insufficient to ensure that portions of the metal layer are selectively etched to remove only predefined portions of the metal layer. Poor overlay control of multiple patterning processes may cause the step of selectively etching the metal layer to unintentionally remove portions of the metal layer other than the predefined removal. In other words, the above methods may unintentionally remove other portions of the metal layer. Since the above method unintentionally removes part of the metal layer, as the minimum structure size continues to shrink, the above method may cause electrical short circuits (such as electrical short circuits between the first metal gate and the second metal gate), adversely affect device performance (due to unintentional reduction of the size of the first metal gate and the second metal gate), or similar problems, thereby reducing production capacity.

本發明多種實施例關於形成奈米結構場效電晶體之間的空間減少之半導體裝置(如積體電路)之方法。方法包括形成第一介電結構於第一介電鰭狀物上,並形成第二介電結構於第二介電鰭狀物上。第一介電結構與第一介電鰭狀物橫向分開第一導電結構與第二導電結構。第二介電結構與第二介電鰭狀物橫向分開第二導電結構與第三導電結構。第一導電結構延伸於第一多個半導體奈米結構周圍,第二導電結構延伸於第二多個半導體奈米結構周圍,且第三導電結構延伸於第三多個半導體奈米結構周圍。第二導電結構位於第一導電結構與第三導電結構之間,並與第一導電結構與第三導電結構橫向分開。 Various embodiments of the present invention relate to methods for forming a semiconductor device (e.g., an integrated circuit) with reduced spacing between nanostructured field effect transistors. The method includes forming a first dielectric structure on a first dielectric fin and forming a second dielectric structure on a second dielectric fin. The first dielectric structure and the first dielectric fin laterally separate a first conductive structure from a second conductive structure. The second dielectric structure and the second dielectric fin laterally separate the second conductive structure from a third conductive structure. The first conductive structure extends around a first plurality of semiconductor nanostructures, the second conductive structure extends around a second plurality of semiconductor nanostructures, and the third conductive structure extends around a third plurality of semiconductor nanostructures. The second conductive structure is located between the first conductive structure and the third conductive structure, and is laterally separated from the first conductive structure and the third conductive structure.

形成第一介電層於第一介電鰭狀物、第二介電鰭狀物、第一多個半導體奈米結構、第二多個半導體奈米結構、第三多個半導體奈米結構、第一介電結構、第二介電結構、第一導電結構、第二導電結構、與第三導電結構上。之後選擇性蝕刻第一介電層以形成第一開口於第一介電層中,其至少部分覆蓋第二導電結構、第一介電結構、與第二介電結構。接著經由第一開口進行第一蝕刻製程以移除第二導電結構。之後經由第一開口進行第二蝕刻製程以移除第二多個半導體奈米結構,以形成第二開口於第一開口之下。此外,第二蝕刻製程移除第一介電結構的一部分以形成第三介電結構於第一介電鰭狀物上,並移除第二介電結構的一部分已形成第四介電結構於第二介電鰭狀物上。接著形成第二介電層於第一開口與第二開口中,並部分地覆蓋第三介電結構與第四介電結構。由於第一介電結構形成於第一介電鰭狀物上,且第二介電結構形成於第二介電鰭狀物上,因此可增加形成第一開口的蝕刻製程容許範圍。舉例來說,第一介電結構與第二介電結構會形成較大寬度的第一開口(由於微影中的解析度限制),及/或自預先定義的位置橫向偏移第一開口(由於疊對控制不佳),但仍確保第一開口只覆蓋所需結構(比如第二導電結構)。 A first dielectric layer is formed on the first dielectric fin, the second dielectric fin, the first plurality of semiconductor nanostructures, the second plurality of semiconductor nanostructures, the third plurality of semiconductor nanostructures, the first dielectric structure, the second dielectric structure, the first conductive structure, the second conductive structure, and the third conductive structure. The first dielectric layer is then selectively etched to form a first opening in the first dielectric layer, which at least partially covers the second conductive structure, the first dielectric structure, and the second dielectric structure. A first etching process is then performed through the first opening to remove the second conductive structure. A second etching process is then performed through the first opening to remove the second plurality of semiconductor nanostructures to form a second opening below the first opening. In addition, the second etching process removes a portion of the first dielectric structure to form a third dielectric structure on the first dielectric fin, and removes a portion of the second dielectric structure to form a fourth dielectric structure on the second dielectric fin. Then, a second dielectric layer is formed in the first opening and the second opening, and partially covers the third dielectric structure and the fourth dielectric structure. Since the first dielectric structure is formed on the first dielectric fin and the second dielectric structure is formed on the second dielectric fin, the etching process tolerance for forming the first opening can be increased. For example, the first dielectric structure and the second dielectric structure may form a first opening of greater width (due to resolution limitations in lithography) and/or laterally offset the first opening from a predefined position (due to poor overlay control), but still ensure that the first opening only covers the desired structure (such as the second conductive structure).

此外,在移除第二導電結構時,第一介電結構與第二介電結構可 作為擋牆,使第一蝕刻製程可選擇性地移除第二導電結構。舉例來說,由於第一介電結構橫向分開第一導電結構與第二導電結構,且第二介電結構橫向分開第二導電結構與第三導電結構,因此第一介電結構與第二介電結構作為擋牆,以避免第一蝕刻製程非刻意地移除第一導電結構的部分及/或第二導電結構的部分。 In addition, when removing the second conductive structure, the first dielectric structure and the second dielectric structure can serve as a barrier so that the first etching process can selectively remove the second conductive structure. For example, since the first dielectric structure separates the first conductive structure from the second conductive structure laterally, and the second dielectric structure separates the second conductive structure from the third conductive structure laterally, the first dielectric structure and the second dielectric structure serve as a barrier to prevent the first etching process from unintentionally removing a portion of the first conductive structure and/or a portion of the second conductive structure.

此外,由於第二蝕刻製程移除第一介電結構的部分(比如形成第三介電結構),並移除第二介電結構的部分(比如形成第四介電結構),因此可由自對準方式形成第二介電層。舉例來說,在第二蝕刻製程之後,第三介電結構可位於第三鰭狀物上,且第四介電結構可位於第四鰭狀物上。因此在形成第二介電層時,第二介電層可自對準第三介電結構與第四介電結構的側壁。綜上所述,隨著結構尺寸持續縮小,方法可形成奈米結構場效電晶體之間的空間縮小的半導體裝置(第一多個奈米結構與第三多個奈米結構之間的橫向空間小於40nm),進而增加產能、改善裝置效能、與避免電性短路等等。 In addition, since the second etching process removes a portion of the first dielectric structure (e.g., to form the third dielectric structure) and removes a portion of the second dielectric structure (e.g., to form the fourth dielectric structure), the second dielectric layer can be formed in a self-aligned manner. For example, after the second etching process, the third dielectric structure can be located on the third fin, and the fourth dielectric structure can be located on the fourth fin. Therefore, when the second dielectric layer is formed, the second dielectric layer can be self-aligned to the sidewalls of the third dielectric structure and the fourth dielectric structure. In summary, as the structure size continues to shrink, the method can form a semiconductor device with a reduced space between nanostructure field effect transistors (the lateral space between the first plurality of nanostructures and the third plurality of nanostructures is less than 40nm), thereby increasing production capacity, improving device performance, and avoiding electrical short circuits, etc.

圖1至19係一些實施例中,形成奈米結構場效電晶體1810之間的空間減少之半導體裝置1904的方法之多種圖式。圖1至11所示的一系列透視圖,係形成奈米結構場效電晶體1810之間的空間減少之半導體裝置1904的方法之多種階段。圖12至19所示的一系列剖視圖,係形成奈米結構場效電晶體1810之間的空間減少之半導體裝置1904的方法之多種階段。圖12至19的剖視圖沿著圖11的剖線A-A,並接續圖11所示的階段。舉例來說,圖12顯示圖11所示的階段之後的第一階段,並沿著圖11的剖線A-A。圖13顯示圖12所示的第一階段之後的第二階段,並沿著圖11的剖線A-A。圖14顯示圖13所示的第二階段之後的第三階段,並沿著圖11的剖線A-A,以此類推。 FIGS. 1-19 are various diagrams of methods of forming a semiconductor device 1904 with reduced spacing between nanostructured field effect transistors 1810 in some embodiments. FIGS. 1-11 are a series of perspective views showing various stages of a method of forming a semiconductor device 1904 with reduced spacing between nanostructured field effect transistors 1810. FIGS. 12-19 are a series of cross-sectional views showing various stages of a method of forming a semiconductor device 1904 with reduced spacing between nanostructured field effect transistors 1810. The cross-sectional views of FIGS. 12-19 are along the section line A-A of FIG. 11 and continue from the stage shown in FIG. 11. For example, FIG. 12 shows a first stage after the stage shown in FIG. 11 and along the section line A-A of FIG. 11. FIG. 13 shows the second stage after the first stage shown in FIG. 12 and along the section line A-A of FIG. 11. FIG. 14 shows the third stage after the second stage shown in FIG. 13 and along the section line A-A of FIG. 11, and so on.

如圖1所示,提供基底半導體結構102。基底半導體結構102包括任何種類的半導體主體(如單晶矽、互補式金氧半基體、矽鍺、絕緣層上矽、或類 似物),其可摻雜(比如摻雜n型或p型摻質)或未摻雜。基底半導體結構102可為半導體晶圓(如碟狀矽晶圓)或半導體晶圓的一部分。 As shown in FIG. 1 , a base semiconductor structure 102 is provided. The base semiconductor structure 102 includes any type of semiconductor body (such as single crystal silicon, complementary metal oxide semiconductor substrate, silicon germanium, silicon on an insulating layer, or the like), which may be doped (such as doped with n-type or p-type doping) or undoped. The base semiconductor structure 102 may be a semiconductor wafer (such as a disk-shaped silicon wafer) or a portion of a semiconductor wafer.

如圖1所示,半導體層的堆疊104形成於基底半導體結構102上。半導體層的堆疊104包括交錯的第一半導體層106與第二半導體層108。半導體層104的堆疊可包含任何數目的第一半導體層106與任何數目的第二半導體層108。 As shown in FIG. 1 , a stack of semiconductor layers 104 is formed on a base semiconductor structure 102. The stack of semiconductor layers 104 includes alternating first semiconductor layers 106 and second semiconductor layers 108. The stack of semiconductor layers 104 may include any number of first semiconductor layers 106 and any number of second semiconductor layers 108.

第一半導體層106可為或包括第一半導體材料如矽、矽鍺、鍺、砷化鎵、砷化銦、磷化銦、或類似物。第二半導體層108可為或包括第二半導體材料如矽、矽鍺、鍺、砷化鎵、砷化銦、磷化銦、或類似物,且第二半導體材料與第一半導體材料不同。舉例來說,第一半導體材料為矽鍺,而第二半導體材料為矽。在這些實施例中,半導體層的堆疊104包括交錯的矽鍺層與矽層。第一半導體層106可或可不摻雜,端視半導體裝置1904的設計而定。第二半導體層108可或可不摻雜,端視半導體裝置1904的設計而定。第一半導體材料與基底半導體結構102的半導體材料可不同。舉例來說,基底半導體結構102的半導體材料可為矽,且第一半導體材料可為矽鍺。 The first semiconductor layer 106 may be or include a first semiconductor material such as silicon, silicon germanium, germanium, gallium arsenide, indium arsenide, indium phosphide, or the like. The second semiconductor layer 108 may be or include a second semiconductor material such as silicon, silicon germanium, germanium, gallium arsenide, indium arsenide, indium phosphide, or the like, and the second semiconductor material is different from the first semiconductor material. For example, the first semiconductor material is silicon germanium and the second semiconductor material is silicon. In these embodiments, the stack of semiconductor layers 104 includes alternating silicon germanium layers and silicon layers. The first semiconductor layer 106 may or may not be doped, depending on the design of the semiconductor device 1904. The second semiconductor layer 108 may or may not be doped, depending on the design of the semiconductor device 1904. The first semiconductor material may be different from the semiconductor material of the base semiconductor structure 102. For example, the semiconductor material of the base semiconductor structure 102 may be silicon, and the first semiconductor material may be silicon germanium.

在一些實施例中,半導體層的堆疊104的形成製程包括磊晶形成第一半導體層106與第二半導體層108。舉例來說,第一半導體層106的第一者成長於基底半導體結構102上的方法可為第一磊晶製程,比如氣相磊晶、液相磊晶、分子束磊晶、一些其他磊晶製程、或上述之組合。之後成長第二半導體層108的第一者於第一半導體層106的第一者上,其成長方法可為第二磊晶製程如氣相磊晶、液相磊晶、分子束磊晶、一些其他磊晶製程、或上述之組合。以交錯方式重複第一磊晶製程與第二磊晶製程,直到半導體層的堆疊104具有預定數目的第一半導體層106與預定數目的第二半導體層108。在一些實施例中,形成半導體層的堆疊104之後,可進行平坦化製程如化學機械研磨、回蝕刻製程、或類似製程,以平坦化半導體層的堆疊104之最上側的半導體層之上表面(比如最上側的第 一半導體層106)。 In some embodiments, the formation process of the stack of semiconductor layers 104 includes epitaxially forming a first semiconductor layer 106 and a second semiconductor layer 108. For example, the method of growing the first of the first semiconductor layers 106 on the base semiconductor structure 102 can be a first epitaxial process, such as vapor phase epitaxy, liquid phase epitaxy, molecular beam epitaxy, some other epitaxial process, or a combination thereof. Thereafter, the first of the second semiconductor layers 108 is grown on the first of the first semiconductor layers 106, and the growth method can be a second epitaxial process such as vapor phase epitaxy, liquid phase epitaxy, molecular beam epitaxy, some other epitaxial process, or a combination thereof. The first epitaxial process and the second epitaxial process are repeated in an alternating manner until the semiconductor layer stack 104 has a predetermined number of first semiconductor layers 106 and a predetermined number of second semiconductor layers 108. In some embodiments, after the semiconductor layer stack 104 is formed, a planarization process such as chemical mechanical polishing, an etching back process, or a similar process may be performed to planarize the upper surface of the uppermost semiconductor layer of the semiconductor layer stack 104 (such as the uppermost first semiconductor layer 106).

在一些實施例中,可在相同的製程腔室(比如磊晶成長腔室)中進行第一磊晶製程與第二磊晶製程。在這些實施例中,可將成長第一半導體層106所用的第一組前驅物與成長第二半導體層108所用的第二組前驅物循環泵入製程腔室。第一組前驅物包括形成第一半導體材料(如矽鍺)所用的前驅物,且第二組前驅物包括形成第二半導體材料(如矽)所用的前驅物。在一些實施例中,第一組前驅物包括矽前驅物(如矽烷)與鍺前驅物(如鍺烷),且第二組前驅物包括矽前驅物而無鍺前驅物。因此可將矽前驅物流入製程腔室,接著週期性地進行下述步驟:(1)在成長第一半導體層106時使鍺前驅物流入製程腔室;以及(2)在成長第二半導體層108時禁止鍺前驅物流入製程腔室。應理解的是一些實施例中,在形成半導體層的堆疊104時可進行一或多個淨化步驟(比如在成長第一半導體層106與第二半導體層108之間的製程腔室進行淨化)。 In some embodiments, the first epitaxial process and the second epitaxial process may be performed in the same process chamber (e.g., an epitaxial growth chamber). In these embodiments, a first set of precursors used to grow the first semiconductor layer 106 and a second set of precursors used to grow the second semiconductor layer 108 may be circulated and pumped into the process chamber. The first set of precursors includes precursors used to form a first semiconductor material (e.g., silicon germanium), and the second set of precursors includes precursors used to form a second semiconductor material (e.g., silicon). In some embodiments, the first set of precursors includes a silicon precursor (e.g., silane) and a germanium precursor (e.g., gerane), and the second set of precursors includes a silicon precursor without a germanium precursor. Therefore, a silicon precursor may be flowed into the process chamber, and then the following steps may be performed periodically: (1) the germanium precursor is allowed to flow into the process chamber when the first semiconductor layer 106 is grown; and (2) the germanium precursor is prohibited from flowing into the process chamber when the second semiconductor layer 108 is grown. It should be understood that in some embodiments, one or more purge steps may be performed when forming the stack of semiconductor layers 104 (e.g., purging the process chamber between the growth of the first semiconductor layer 106 and the second semiconductor layer 108).

如圖1所示,硬遮罩層110形成於半導體層堆疊104上。硬遮罩層110覆蓋半導體層堆疊104。舉例來說,硬遮罩層110可為或包含氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他硬遮罩材料、或上述之組合。在一些實施例中,形成硬遮罩層110的製程之一包含沉積或成長硬遮罩層110於半導體層堆疊104的上表面上。硬遮罩層110的沉積或成長方法可為化學氣相沉積、物理氣相沉積、原子層沉積、熱氧化、一些其他沉積或成長製程、或上述之組合。在其他實施例中,硬遮罩層110可包含多層。舉例來說,硬遮罩層110可包含氧化物層(如氧化矽),以及氧化物層上的氮化物層(如氮化矽)。 As shown in FIG. 1 , a hard mask layer 110 is formed on the semiconductor layer stack 104. The hard mask layer 110 covers the semiconductor layer stack 104. For example, the hard mask layer 110 may be or include an oxide (e.g., silicon oxide), a nitride (e.g., silicon nitride), an oxynitride (e.g., silicon oxynitride), some other hard mask material, or a combination thereof. In some embodiments, one of the processes for forming the hard mask layer 110 includes depositing or growing the hard mask layer 110 on the upper surface of the semiconductor layer stack 104. The deposition or growth method of the hard mask layer 110 may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, thermal oxidation, some other deposition or growth process, or a combination thereof. In other embodiments, the hard mask layer 110 may include multiple layers. For example, the hard mask layer 110 may include an oxide layer (such as silicon oxide) and a nitride layer (such as silicon nitride) on the oxide layer.

如圖2所示,形成第一硬遮罩結構202、多個半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、與半導體的鰭狀物210。為了使圖式清楚,只特別標示一些半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、與半導體的鰭狀物210。如圖2所示,使基底半導體 結構102凹陷,以形成半導體的基板212。半導體的基板212之後可視作基板。 As shown in FIG2 , a first hard mask structure 202, a first stack 204 of multiple semiconductor structures, a first semiconductor structure 206, a second semiconductor structure 208, and a semiconductor fin 210 are formed. For the sake of clarity, only some of the first stacks 204, the first semiconductor structure 206, the second semiconductor structure 208, and the semiconductor fin 210 are specifically marked. As shown in FIG2 , the base semiconductor structure 102 is recessed to form a semiconductor substrate 212. The semiconductor substrate 212 can be regarded as a substrate later.

半導體的鰭狀物210自基板212垂直凸起。半導體的鰭狀物210橫向分開(延著z軸)。舉例來說,第一體鰭狀物210a、第二鰭狀物210b、第三鰭狀物210c、第四鰭狀物210d、第五鰭狀物210e、與第六鰭狀物210f彼此橫向分開(沿著z軸)。半導體的鰭狀物210橫向延伸(沿著x軸)於基板212上並彼此平行。 The semiconductor fins 210 protrude vertically from the substrate 212. The semiconductor fins 210 are separated laterally (along the z-axis). For example, the first body fin 210a, the second fin 210b, the third fin 210c, the fourth fin 210d, the fifth fin 210e, and the sixth fin 210f are separated laterally (along the z-axis) from each other. The semiconductor fins 210 extend laterally (along the x-axis) on the substrate 212 and are parallel to each other.

半導體結構的第一堆疊204分別覆蓋半導體的鰭狀物210。半導體結構的第一堆疊204橫向分開(沿著z軸)。半導體結構的第一堆疊204橫向延伸(沿著x軸)於半導體的鰭狀物210上並彼此平行。半導體結構的第一堆疊204之每一者可包含交錯的第一半導體結構206與第二半導體結構208。第一硬遮罩結構202覆蓋半導體結構的第一堆疊204。 The first stacks 204 of semiconductor structures respectively cover the fins 210 of the semiconductor. The first stacks 204 of semiconductor structures are separated laterally (along the z-axis). The first stacks 204 of semiconductor structures extend laterally (along the x-axis) on the fins 210 of the semiconductor and are parallel to each other. Each of the first stacks 204 of semiconductor structures may include staggered first semiconductor structures 206 and second semiconductor structures 208. The first hard mask structure 202 covers the first stacks 204 of semiconductor structures.

在一些實施例中,形成第一硬遮罩結構202的製程包括形成第一圖案化遮罩層(未圖示,比如正光阻及/或負光阻)於硬遮罩層110上。第一圖案化遮罩層的形成方法可為形成遮罩層(未圖示)於硬遮罩層110上、顯影遮罩層至一圖案(比如經由微影製程如光微影、極紫外線微影、或類似微影)、並顯影遮罩層以形成第一圖案化遮罩層。之後可採用第一圖案化遮罩層,並在硬遮罩層110上進行第一蝕刻製程以移除硬遮罩層110的未遮罩部分。進而保留硬遮罩層110的遮罩部分作為第一遮罩結構202。第一蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。之後可剝除第一圖案化遮罩層。 In some embodiments, the process of forming the first hard mask structure 202 includes forming a first patterned mask layer (not shown, such as positive photoresist and/or negative photoresist) on the hard mask layer 110. The first patterned mask layer may be formed by forming a mask layer (not shown) on the hard mask layer 110, developing the mask layer to a pattern (such as by a lithography process such as photolithography, extreme ultraviolet lithography, or the like), and developing the mask layer to form the first patterned mask layer. The first patterned mask layer may then be used and a first etching process may be performed on the hard mask layer 110 to remove the unmasked portion of the hard mask layer 110. The masked portion of the hard mask layer 110 is then retained as the first mask structure 202. The first etching process may be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof. The first patterned mask layer may then be stripped off.

接著採用第一硬遮罩結構202作為蝕刻遮罩,並蝕刻形成半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、半導體的鰭狀物210、與基板212。搭配第一硬遮罩結構202,可在半導體層的堆疊104與基底半導體結構上進行第二蝕刻製程(見圖1)。第二蝕刻製程可移除半導體層的堆疊104之未遮罩部分,以保留半導體層的遮罩部分以作為半導體結構的第一堆疊204。 換言之,第二蝕刻製程移除第一半導體層106與第二半導體層108的未遮罩部分,以保留第一半導體層106的遮罩部分作為第一半導體結構206,並保留第二半導體層108的遮罩部分作為第二半導體結構208。第二蝕刻製程亦可使基底半導體結構102的未遮罩部分凹陷,以保留基底半導體結構102的部分(如遮罩部分與凹陷部分)作為基板212與半導體的鰭狀物210。第二蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 Then, the first hard mask structure 202 is used as an etching mask, and the first stack 204 of the semiconductor structure, the first semiconductor structure 206, the second semiconductor structure 208, the semiconductor fin 210, and the substrate 212 are etched. With the first hard mask structure 202, a second etching process can be performed on the semiconductor layer stack 104 and the base semiconductor structure (see FIG. 1). The second etching process can remove the unmasked portion of the semiconductor layer stack 104 to retain the masked portion of the semiconductor layer as the first stack 204 of the semiconductor structure. In other words, the second etching process removes the unmasked portions of the first semiconductor layer 106 and the second semiconductor layer 108 to retain the masked portion of the first semiconductor layer 106 as the first semiconductor structure 206, and retain the masked portion of the second semiconductor layer 108 as the second semiconductor structure 208. The second etching process can also recess the unmasked portion of the base semiconductor structure 102 to retain a portion of the base semiconductor structure 102 (such as the masked portion and the recessed portion) as the substrate 212 and the semiconductor fin 210. The second etching process can be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof.

此外,形成第一硬遮罩結構202、半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、半導體的鰭狀物210、與基板212的製程,可形成第一溝槽214於基板212上。為了使圖式清楚,只特別標示一些第一溝槽214。第一溝槽214橫向分開(沿著z軸)。半導體的鰭狀物210可橫向分開(沿著z軸)第一溝槽214。換言之,第一溝槽214位於半導體的鰭狀物210的兩側上。第一溝槽214橫向(沿著x軸)延伸於基板212上並彼此平行。 In addition, the process of forming the first hard mask structure 202, the first stack of semiconductor structures 204, the first semiconductor structure 206, the second semiconductor structure 208, the semiconductor fin 210, and the substrate 212 can form first trenches 214 on the substrate 212. For the sake of clarity of the figure, only some of the first trenches 214 are specifically marked. The first trenches 214 are separated laterally (along the z-axis). The semiconductor fin 210 can separate the first trenches 214 laterally (along the z-axis). In other words, the first trenches 214 are located on both sides of the semiconductor fin 210. The first trenches 214 extend laterally (along the x-axis) on the substrate 212 and are parallel to each other.

應理解的是,第一硬遮罩結構202、半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、半導體的鰭狀物210、與基板212的形成方法可為任何合適方法。舉例來說,第一硬遮罩結構202、半導體結構的第一堆疊204、第一半導體結構206、第二半導體結構208、半導體的鰭狀物210、與基板212的形成方法可採用一或多道光微影製程,比如雙重圖案化製程、多重圖案化製程、或類似製程。半導體的鰭狀物210之後可視作鰭狀物。 It should be understood that the first hard mask structure 202, the first stack of semiconductor structures 204, the first semiconductor structure 206, the second semiconductor structure 208, the semiconductor fin 210, and the substrate 212 may be formed by any suitable method. For example, the first hard mask structure 202, the first stack of semiconductor structures 204, the first semiconductor structure 206, the second semiconductor structure 208, the semiconductor fin 210, and the substrate 212 may be formed by one or more photolithography processes, such as a double patterning process, a multi-patterning process, or the like. The semiconductor fin 210 may then be considered a fin.

如圖3所示,沿著第一溝槽214的側壁與第一溝槽214的下表面(見圖2)形成襯墊層302。換言之,可沿著鰭狀物210的側壁、基板212的上表面(比如鰭狀物210之間的上表面)、半導體結構的第一堆疊204之側壁、與第一硬遮罩結構202的側壁形成襯墊層302。在一實施例中,襯墊層302可形成於第一硬遮罩結構202的上表面上。在其他實施例中,襯墊層302的形成製程包括成長或沉積襯墊層302,比如化學氣相沉積、物理氣相沉積、原子層沉積、磊晶製程、一些其 他沉積或成長製程、或上述之組合。 As shown in FIG3 , the liner layer 302 is formed along the sidewalls of the first trench 214 and the lower surface (see FIG2 ) of the first trench 214. In other words, the liner layer 302 may be formed along the sidewalls of the fins 210, the upper surface of the substrate 212 (e.g., the upper surface between the fins 210), the sidewalls of the first stack 204 of semiconductor structures, and the sidewalls of the first hard mask structure 202. In one embodiment, the liner layer 302 may be formed on the upper surface of the first hard mask structure 202. In other embodiments, the formation process of the liner layer 302 includes growing or depositing the liner layer 302, such as chemical vapor deposition, physical vapor deposition, atomic layer deposition, epitaxial process, some other deposition or growth process, or a combination thereof.

襯墊層302可為或包括半導體材料(如矽、矽鍺、或類似物)。在一些實施例中,襯墊層302的半導體材料與鰭狀物210的半導體材料(如基底半導體結構102的半導體材料)可相同。在其他實施例中,襯墊層302的半導體材料與第一半導體結構206的半導體材料可相同(比如第一半導體材料)。在其他實施例中,襯墊層302為順應性層狀物。 The liner layer 302 may be or include a semiconductor material (such as silicon, silicon germanium, or the like). In some embodiments, the semiconductor material of the liner layer 302 may be the same as the semiconductor material of the fin 210 (such as the semiconductor material of the base semiconductor structure 102). In other embodiments, the semiconductor material of the liner layer 302 may be the same as the semiconductor material of the first semiconductor structure 206 (such as the first semiconductor material). In other embodiments, the liner layer 302 is a compliant layer.

如圖3所示,形成第一介電層304於基板212、第一硬遮罩結構202、與襯墊層302上。在形成襯墊層302之後形成第一介電層304。形成第一介電層304以填入第一溝槽214(見圖2)。第一介電層304可具有平坦化上表面。舉例來說,第一介電層304可為或包括氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、碳氮化矽、碳氮氧化矽、金屬氧化物(如氧化鋁、氧化鉿、氧化鋯、或氧化釔)、一些其他介電材料、或上述之組合。在一些實施例中,更具體的第一介電層304為具有第一碳氮氧化矽組成的碳氮氧化矽。在其他實施例中,形成第一介電層304的製程包括沉積第一介電層304於第一溝槽214中、襯墊層302上、與第一硬遮罩結構202上,比如化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 As shown in FIG3 , a first dielectric layer 304 is formed on the substrate 212, the first hard mask structure 202, and the liner layer 302. The first dielectric layer 304 is formed after the liner layer 302 is formed. The first dielectric layer 304 is formed to fill the first trench 214 (see FIG2 ). The first dielectric layer 304 may have a planarized upper surface. For example, the first dielectric layer 304 may be or include a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), silicon carbonitride, silicon carbonitride, a metal oxide (such as aluminum oxide, yttrium oxide, zirconium oxide, or yttrium oxide), some other dielectric material, or a combination thereof. In some embodiments, the more specific first dielectric layer 304 is a carbon nitride silicon oxide having a first carbon nitride silicon oxide composition. In other embodiments, the process of forming the first dielectric layer 304 includes depositing the first dielectric layer 304 in the first trench 214, on the liner layer 302, and on the first hard mask structure 202, such as chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

如圖4所示,形成隔離結構402於基板212之上與鰭狀物210之間。為了使圖式清楚,只特別標示一些隔離結構402。隔離結構402可視作淺溝槽隔離結構。隔離結構402橫向分開(沿著z軸)。鰭狀物210橫向分開(沿著z軸)隔離結構402。在一些實施例中,隔離結構402橫向延伸(沿著x軸)於基板212上並彼此平行。在其他實施例中,隔離結構402可為橫向圍繞一或多個鰭狀物210的一或多個連續隔離結構的部分(比如較大的淺溝槽隔離結構的一些部分沿著x軸橫向延伸,而一些其他部分沿著z軸橫向延伸,使較大的淺溝槽隔離結構橫向圍繞一或多個鰭狀物210)。 As shown in FIG. 4 , isolation structures 402 are formed on substrate 212 and between fins 210. For clarity of the drawing, only some of the isolation structures 402 are specifically labeled. The isolation structures 402 can be considered as shallow trench isolation structures. The isolation structures 402 are separated laterally (along the z-axis). The fins 210 separate the isolation structures 402 laterally (along the z-axis). In some embodiments, the isolation structures 402 extend laterally (along the x-axis) on substrate 212 and are parallel to each other. In other embodiments, the isolation structure 402 may be part of one or more continuous isolation structures that laterally surround one or more fins 210 (e.g., some portions of the larger shallow trench isolation structure extend laterally along the x-axis, while some other portions extend laterally along the z-axis, so that the larger shallow trench isolation structure laterally surrounds one or more fins 210).

隔離結構402的上表面可實質上平坦。在其他實施例中,隔離結構402可具有凸起或凹陷的上表面。隔離結構402的上表面實質上對準(比如齊平)鰭狀物210的上表面。在其他實施例中,隔離結構402的上表面可高於或低於鰭狀物210的上表面。 The upper surface of the isolation structure 402 may be substantially flat. In other embodiments, the isolation structure 402 may have a convex or concave upper surface. The upper surface of the isolation structure 402 is substantially aligned with (e.g., flush with) the upper surface of the fin 210. In other embodiments, the upper surface of the isolation structure 402 may be higher or lower than the upper surface of the fin 210.

在一些實施例中,形成隔離結構402的製程包括使第一介電層304凹陷(見圖3)。使第一介電層304凹陷的方法可為在第一介電層304上進行第三蝕刻製程。因此,第三蝕刻製程使第一介電層304凹陷至預先定義的高度,以保留第一介電層304的下側部分作為隔離結構402。在一些實施例中,第三蝕刻製程亦移除襯墊層302的上側部分,以沿著鰭狀物210的側壁與基板212的上表面保留襯墊層302的下側部分,如圖4所示。在其他實施例中,第三蝕刻製程對第一介電層304的選擇性大於對襯墊層302的選擇性,以沿著半導體結構的第一堆疊204的側壁、第一硬遮罩結構202的側壁、與第一硬遮罩結構202的上表面保留襯墊層302。舉例來說,第三蝕刻製程可為乾蝕刻製程、溼蝕刻製程、一些其他蝕刻製程、或上述之組合。在一些實施例中,第三蝕刻製程可視作第一回蝕刻製程。 In some embodiments, the process of forming the isolation structure 402 includes recessing the first dielectric layer 304 (see FIG. 3 ). The method of recessing the first dielectric layer 304 may be to perform a third etching process on the first dielectric layer 304. Therefore, the third etching process recesses the first dielectric layer 304 to a predetermined height to retain a lower portion of the first dielectric layer 304 as the isolation structure 402. In some embodiments, the third etching process also removes an upper portion of the liner layer 302 to retain the lower portion of the liner layer 302 along the sidewall of the fin 210 and the upper surface of the substrate 212, as shown in FIG. 4 . In other embodiments, the third etching process has a greater selectivity to the first dielectric layer 304 than to the liner layer 302, so as to retain the liner layer 302 along the sidewalls of the first stack 204 of the semiconductor structure, the sidewalls of the first hard mask structure 202, and the upper surface of the first hard mask structure 202. For example, the third etching process can be a dry etching process, a wet etching process, some other etching process, or a combination thereof. In some embodiments, the third etching process can be regarded as the first etching process.

如圖4所示,蓋結構404分別形成於半導體結構的第一堆疊204上。蓋結構404亦形成於隔離結構402、襯墊層302、與第一硬遮罩結構202上。為了使圖式清楚,只特別標示一些蓋結構404。蓋結構404可為或包含半導體材料如矽、矽鍺、或類似物。在一些實施例中,蓋結構404的半導體材料與第一半導體結構206的半導體材料相同(比如第一半導體材料)。舉例來說,蓋結構404為矽鍺,且第一半導體結構206為矽鍺。 As shown in FIG. 4 , the capping structures 404 are formed on the first stack 204 of semiconductor structures. The capping structures 404 are also formed on the isolation structure 402, the liner layer 302, and the first hard mask structure 202. For the sake of clarity, only some of the capping structures 404 are specifically marked. The capping structure 404 may be or include a semiconductor material such as silicon, silicon germanium, or the like. In some embodiments, the semiconductor material of the capping structure 404 is the same as the semiconductor material of the first semiconductor structure 206 (such as the first semiconductor material). For example, the capping structure 404 is silicon germanium, and the first semiconductor structure 206 is silicon germanium.

在一些實施例中,形成蓋結構404的製程包括成長或沉積蓋結構404於半導體結構的第一堆疊204與第一硬遮罩結構202上。舉例來說,蓋結構404的成長或沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、磊晶製程、一些其他沉積或成長製程、或上述之組合。在其他實施例中,蓋結構404自襯墊 層302的露出表面選擇性成長(比如由磊晶製程),因此隔離結構402的上表面不含蓋結構404。 In some embodiments, the process of forming the cap structure 404 includes growing or depositing the cap structure 404 on the first stack 204 of the semiconductor structure and the first hard mask structure 202. For example, the growth or deposition method of the cap structure 404 can be chemical vapor deposition, physical vapor deposition, atomic layer deposition, epitaxial process, some other deposition or growth process, or a combination thereof. In other embodiments, the cap structure 404 is selectively grown from the exposed surface of the liner layer 302 (for example, by an epitaxial process), so that the upper surface of the isolation structure 402 does not contain the cap structure 404.

此外,形成隔離結構402與蓋結構404的製程亦形成第二溝槽406於基板212上。第二溝槽406亦分別形成於隔離結構402上。為了使圖式清楚,只特別標示一些第二溝槽406。第二溝槽406橫向分開(沿著z軸)。蓋結構404橫向分開(沿著z軸)第二溝槽406。換言之,第二溝槽406位於蓋結構404的兩側與隔離結構402上。第二溝槽406橫向延伸(沿著x軸)於隔離結構402上並彼此平行。 In addition, the process of forming the isolation structure 402 and the cover structure 404 also forms second trenches 406 on the substrate 212. The second trenches 406 are also formed on the isolation structure 402. For the sake of clarity, only some of the second trenches 406 are specifically marked. The second trenches 406 are separated laterally (along the z-axis). The cover structure 404 separates the second trenches 406 laterally (along the z-axis). In other words, the second trenches 406 are located on both sides of the cover structure 404 and the isolation structure 402. The second trenches 406 extend laterally (along the x-axis) on the isolation structure 402 and are parallel to each other.

如圖5所示,介電鰭狀物502形成於基板212與鰭狀物210上。介電鰭狀物502分別形成於(比如直接形成於)隔離結構402上。介電鰭狀物502橫向分開(沿著z軸)。舉例來說,第一介電鰭狀物502a、第二介電鰭狀物502b、第三介電鰭狀物502c、第四介電鰭狀物502d、與第五介電鰭狀物502e彼此橫向分開(沿著z軸)。蓋結構404橫向分開(沿著z軸)介電鰭狀物502。換言之,介電鰭狀物502位於蓋結構404的兩側與隔離結構402上。介電鰭狀物502橫向延伸(沿著x軸)於隔離結構402上並彼此平行。 As shown in FIG. 5 , dielectric fins 502 are formed on substrate 212 and fins 210. Dielectric fins 502 are formed on (e.g., directly on) isolation structures 402. Dielectric fins 502 are separated laterally (along the z-axis). For example, first dielectric fin 502a, second dielectric fin 502b, third dielectric fin 502c, fourth dielectric fin 502d, and fifth dielectric fin 502e are separated laterally (along the z-axis) from each other. Cover structure 404 separates dielectric fins 502 laterally (along the z-axis). In other words, the dielectric fins 502 are located on both sides of the cap structure 404 and on the isolation structure 402. The dielectric fins 502 extend laterally (along the x-axis) on the isolation structure 402 and are parallel to each other.

介電鰭狀物502的上表面低於半導體結構的第一堆疊204的上表面。具體而言,介電鰭狀物502的上表面低於半導體結構的第一堆疊204的最上側半導體結構的上表面(比如半導體結構的第一堆疊204之最上側的第一半導體結構206的上表面)。在一些實施例中,介電鰭狀物502的上表面實質上對準半導體結構的第一堆疊204之最上側的第二半導體結構208的上表面。在其他實施例中,介電鰭狀物502的上表面低於或高於半導體結構的第一堆疊204之最上側的第二半導體結構208的上表面。在其他實施例中,介電鰭狀物502的上表面可實質上平坦。在其他實施例中,介電鰭狀物502的上表面可凸起或凹陷。 The upper surface of the dielectric fin 502 is lower than the upper surface of the first stack of semiconductor structures 204. Specifically, the upper surface of the dielectric fin 502 is lower than the upper surface of the uppermost semiconductor structure of the first stack of semiconductor structures 204 (e.g., the upper surface of the uppermost first semiconductor structure 206 of the first stack of semiconductor structures 204). In some embodiments, the upper surface of the dielectric fin 502 is substantially aligned with the upper surface of the uppermost second semiconductor structure 208 of the first stack of semiconductor structures 204. In other embodiments, the upper surface of the dielectric fin 502 is lower than or higher than the upper surface of the uppermost second semiconductor structure 208 of the first stack of semiconductor structures 204. In other embodiments, the upper surface of the dielectric fin 502 may be substantially flat. In other embodiments, the upper surface of the dielectric fin 502 may be convex or concave.

舉例來說,介電鰭狀物502可為或包含氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、碳氮化矽、碳氮氧化矽、金屬氧化物(如氧化鋁、氧化鉿、氧 化鋯、或氧化釔)、一些其他介電材料、或上述之組合。在一些實施例中,更具體的介電鰭狀物502為具有第二碳氮氧化矽組成的碳氮氧化矽。在一些實施例中,第二碳氮氧化矽組成與第一碳氮氧化矽組成不同。 For example, dielectric fin 502 may be or include a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), a silicon carbonitride, a silicon carbonitride oxide, a metal oxide (such as aluminum oxide, yttrium oxide, zirconium oxide, or yttrium oxide), some other dielectric material, or a combination thereof. In some embodiments, more specifically dielectric fin 502 is a silicon carbonitride oxide having a second silicon carbonitride oxide composition. In some embodiments, the second silicon carbonitride oxide composition is different from the first silicon carbonitride oxide composition.

在一些實施例中,形成介電鰭狀物502的製程包括形成第二介電層(未圖示)於基板212、隔離結構402、襯墊層302、蓋結構404、與第一硬遮罩結構202上。 In some embodiments, the process of forming the dielectric fin 502 includes forming a second dielectric layer (not shown) on the substrate 212, the isolation structure 402, the liner layer 302, the capping structure 404, and the first hard mask structure 202.

形成第二介電層以填入第二溝槽406(見圖4)。第二介電層可具有平坦上表面。舉例來說,第二介電層可為或包含氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、碳氮氧化矽、一些其他介電材料、或上述之組合。在一些實施例中,第二介電層為具有第二碳氮氧化矽組成的碳氮氧化矽。在一些實施例中,形成第二介電層的製程包括沉積第二介電層於第二溝槽406中、隔離結構402上、以及蓋結構404上,其形成方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 A second dielectric layer is formed to fill the second trench 406 (see FIG. 4 ). The second dielectric layer may have a flat upper surface. For example, the second dielectric layer may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), a carbon nitride silicon oxide, some other dielectric material, or a combination thereof. In some embodiments, the second dielectric layer is a carbon nitride silicon oxide having a second carbon nitride silicon oxide composition. In some embodiments, the process of forming the second dielectric layer includes depositing the second dielectric layer in the second trench 406, on the isolation structure 402, and on the cap structure 404, and the formation method thereof may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

之後使第二介電層凹陷至預先定義的高度。可由第四蝕刻製程始第二介電層凹陷。第四蝕刻製程對第二介電層的選擇性大於對第二介電層下的其他結構(比如蓋結構404與第一硬遮罩結構202)的選擇性。因此第四蝕刻製程可使第二介電層凹陷至預先定義的高度,以保留第二介電層的下側部分作為介電鰭狀物502。舉例來說,第四蝕刻製程可為乾蝕刻製程、溼蝕刻製程、一些其他蝕刻製程、或上述之組合。在一些實施例中,第四蝕刻製程可視作第二回蝕刻製程。 The second dielectric layer is then recessed to a predetermined height. The second dielectric layer may be recessed by a fourth etching process. The selectivity of the fourth etching process to the second dielectric layer is greater than the selectivity to other structures under the second dielectric layer (such as the cap structure 404 and the first hard mask structure 202). Therefore, the fourth etching process may recess the second dielectric layer to a predetermined height to retain the lower portion of the second dielectric layer as a dielectric fin 502. For example, the fourth etching process may be a dry etching process, a wet etching process, some other etching process, or a combination thereof. In some embodiments, the fourth etching process may be regarded as a second re-etching process.

如圖5所示,形成介電帶504於基板212上。介電帶504亦分別形成於(比如直接形成於)介電鰭狀物502上。為了使圖式清楚,只特別標示一些介電帶504。介電帶504橫向分開(沿著z軸)。蓋結構404橫向分開(沿著z軸)介電帶504。換言之,介電帶504位於蓋結構404的兩側與介電鰭狀物502上。介電帶504橫向 延伸(沿著x軸)於介電鰭狀物502上並彼此平行。 As shown in FIG. 5 , dielectric tapes 504 are formed on substrate 212. Dielectric tapes 504 are also formed on (e.g., directly on) dielectric fins 502. For clarity of the drawing, only some dielectric tapes 504 are specifically labeled. Dielectric tapes 504 are separated laterally (along the z-axis). Cover structure 404 separates dielectric tapes 504 laterally (along the z-axis). In other words, dielectric tapes 504 are located on both sides of cover structure 404 and on dielectric fins 502. Dielectric tapes 504 extend laterally (along the x-axis) on dielectric fins 502 and are parallel to each other.

介電帶504分別自介電鰭狀物502的上表面垂直延伸(沿著y軸)。換言之,介電帶504分別接觸介電鰭狀物502的上表面,並分別自介電鰭狀物502的上表面垂直延伸至介電帶504的上表面。介電帶504的上表面實質上平坦。介電帶504的上表面實質上對準蓋結構404的上表面與第一硬遮罩結構202的上表面。 The dielectric tape 504 extends vertically (along the y-axis) from the upper surface of the dielectric fin 502. In other words, the dielectric tape 504 contacts the upper surface of the dielectric fin 502 and extends vertically from the upper surface of the dielectric fin 502 to the upper surface of the dielectric tape 504. The upper surface of the dielectric tape 504 is substantially flat. The upper surface of the dielectric tape 504 is substantially aligned with the upper surface of the cover structure 404 and the upper surface of the first hard mask structure 202.

舉例來說,介電帶504可為或包括氧化物(如氧化矽)、高介電常數的介電層(如氧化鉿、氧化鋯、氧化鉿鋁、矽酸鉿、或介電常數大於3.9的一些其他介電材料)、碳氮化矽、金屬氧化物(如氧化鋁、氧化鉿、氧化鋯、或氧化釔)、一些其他介電材料、或上述之組合。介電帶504與介電鰭狀物502包括不同的介電材料。舉例來說,介電帶504為氧化鉿,且介電鰭狀物502為碳氮氧化矽。在一些實施例中,由於介電鰭狀物502包括第一介電材料(如碳氮氧化矽)且介電帶504包括不同於第一介電材料的第二介電材料(如氧化鉿),介電鰭狀物502與對應的介電帶504可一起視作混合鰭狀物。舉例來說,混合鰭狀物的第一者包括介電鰭狀物502的第一者,與位於介電鰭狀物502的第一者上對應之介電帶504的第一者。 For example, dielectric tape 504 may be or include an oxide (e.g., silicon oxide), a high dielectric constant dielectric layer (e.g., bismuth oxide, zirconium oxide, bismuth aluminum oxide, bismuth silicate, or some other dielectric material with a dielectric constant greater than 3.9), silicon carbonitride, a metal oxide (e.g., aluminum oxide, bismuth oxide, zirconia, or yttrium oxide), some other dielectric material, or a combination thereof. Dielectric tape 504 and dielectric fin 502 include different dielectric materials. For example, dielectric tape 504 is bismuth oxide, and dielectric fin 502 is silicon oxycarbonitride. In some embodiments, since the dielectric fin 502 includes a first dielectric material (such as silicon oxycarbon nitride) and the dielectric tape 504 includes a second dielectric material (such as bismuth oxide) different from the first dielectric material, the dielectric fin 502 and the corresponding dielectric tape 504 can be considered as a hybrid fin. For example, the first of the hybrid fins includes a first of the dielectric fin 502 and a first of the dielectric tape 504 located on the first of the dielectric fin 502.

在一些實施例中,形成介電帶504的製程包括形成第三介電層(未圖示)於基板212、介電鰭狀物502、蓋結構404、與第一硬遮罩結構202上。舉例來說,第三介電層可為或包含氧化物(如氧化矽)、高介電常數的介電層(如氧化鉿、氧化鋯、鋁酸鉿、矽酸鉿、或介電常數大於3.9的一些其他介電材料)、碳氮化矽、金屬氧化物(如氧化鋁、氧化鉿、氧化鋯、或氧化釔)、一些其他介電材料、或上述之組合。第三介電層與第二介電層包含不同的介電材料。舉例來說,第三介電層為氧化鉿,而第二介電層為碳氮氧化矽。在一些實施例中,形成第三介電層的方法包括沉積第三介電層於介電鰭狀物502、蓋結構404、與第一硬遮罩結構202上,其形成方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一 些其他沉積製程、或上述之組合。 In some embodiments, the process of forming the dielectric tape 504 includes forming a third dielectric layer (not shown) on the substrate 212, the dielectric fin 502, the capping structure 404, and the first hard mask structure 202. For example, the third dielectric layer can be or include an oxide (such as silicon oxide), a high dielectric constant dielectric layer (such as bismuth oxide, zirconia, bismuth aluminate, bismuth silicate, or some other dielectric material with a dielectric constant greater than 3.9), silicon carbonitride, a metal oxide (such as aluminum oxide, bismuth oxide, zirconia, or yttrium oxide), some other dielectric material, or a combination thereof. The third dielectric layer and the second dielectric layer include different dielectric materials. For example, the third dielectric layer is bismuth oxide, and the second dielectric layer is silicon oxycarbonitride. In some embodiments, the method of forming the third dielectric layer includes depositing the third dielectric layer on the dielectric fin 502, the cap structure 404, and the first hard mask structure 202, and the formation method thereof can be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

之後可在第三介電層上進行平坦化製程。平坦化製程移除第三介電層的上側部分,進而保留第三介電層的下側部分以分別作為介電帶504。在第一硬遮罩結構202與蓋結構404上亦進行平坦化製程。因此平坦化製程移除第一硬遮罩結構202與蓋結構404的上側部分,使介電帶504的上表面、第一硬遮罩結構202的上表面、與蓋結構404的上表面共平面。 A planarization process may then be performed on the third dielectric layer. The planarization process removes the upper portion of the third dielectric layer, thereby retaining the lower portion of the third dielectric layer to serve as the dielectric tape 504, respectively. A planarization process is also performed on the first hard mask structure 202 and the cap structure 404. Therefore, the planarization process removes the upper portion of the first hard mask structure 202 and the cap structure 404, so that the upper surface of the dielectric tape 504, the upper surface of the first hard mask structure 202, and the upper surface of the cap structure 404 are coplanar.

如圖6所示,形成虛置閘極結構602於基板212、鰭狀物210、半導體結構的第一堆疊204、隔離結構402、襯墊層302、蓋結構404、介電鰭狀物502、介電帶504、與第一硬遮罩結構202上。在一些實施例中,虛置閘極結構602分別包括虛置閘極介電結構604與虛置閘極材料結構606。虛置閘極材料結構606分別覆蓋虛置閘極介電結構604。為了使圖式清楚,只特別標示一些虛置閘極結構602、虛置閘極介電結構604、與虛置閘極材料結構606。 6 , a dummy gate structure 602 is formed on the substrate 212, the fin 210, the first stack of semiconductor structures 204, the isolation structure 402, the liner layer 302, the capping structure 404, the dielectric fin 502, the dielectric tape 504, and the first hard mask structure 202. In some embodiments, the dummy gate structure 602 includes a dummy gate dielectric structure 604 and a dummy gate material structure 606. The dummy gate material structure 606 covers the dummy gate dielectric structure 604. In order to make the diagram clear, only some dummy gate structures 602, dummy gate dielectric structures 604, and dummy gate material structures 606 are specifically marked.

虛置閘極結構602橫向分開(沿著x軸)。虛置閘極結構602橫向(沿著z軸)延伸於基板212、鰭狀物210、半導體結構的第一堆疊204、隔離結構402、襯墊層302、蓋結構404、介電鰭狀物502、介電帶504、與第一硬遮罩結構202上。舉例來說,虛置閘極材料結構606可為或包括多晶矽,但虛置閘極材料結構606可為或包括其他材料。舉例來說,虛置閘極介電結構604可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他介電材料、或上述之組合。 The dummy gate structure 602 is laterally separated (along the x-axis). The dummy gate structure 602 extends laterally (along the z-axis) over the substrate 212, the fin 210, the first stack of semiconductor structures 204, the isolation structure 402, the liner layer 302, the capping structure 404, the dielectric fin 502, the dielectric tape 504, and the first hard mask structure 202. For example, the dummy gate material structure 606 may be or include polysilicon, but the dummy gate material structure 606 may be or include other materials. For example, the virtual gate dielectric structure 604 may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other dielectric material, or a combination thereof.

在一些實施例中,形成虛置閘極結構602的製程包括沉積虛置閘極介電層(未圖示)於基板212、鰭狀物210、半導體結構的第一堆疊204、隔離結構402、襯墊層302、蓋結構404、介電鰭狀物502、介電帶504、與第一硬遮罩結構202上。虛置閘極介電層可沉積如順應層。舉例來說,虛置閘極介電層可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他介 電材料、或上述之組合。在一些實施例中,虛置閘極介電層的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 In some embodiments, the process of forming the dummy gate structure 602 includes depositing a dummy gate dielectric layer (not shown) on the substrate 212, the fin 210, the first stack of semiconductor structures 204, the isolation structure 402, the liner layer 302, the capping structure 404, the dielectric fin 502, the dielectric tape 504, and the first hard mask structure 202. The dummy gate dielectric layer can be deposited as a compliant layer. For example, the dummy gate dielectric layer can be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other dielectric material, or a combination thereof. In some embodiments, the deposition method of the dummy gate dielectric layer may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

接著沉積虛置閘極材料(未圖示)於虛置閘極介電層上並覆蓋虛置閘極介電層。舉例來說,虛置閘極介電材料可為或包括多晶矽,但虛置閘極介電材料可為或包括其他材料。舉例來說,虛置閘極材料的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 A dummy gate material (not shown) is then deposited on and covers the dummy gate dielectric layer. For example, the dummy gate dielectric material may be or include polysilicon, but the dummy gate dielectric material may be or include other materials. For example, the deposition method of the dummy gate material may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

之後沉積或成長第一硬遮罩層(未圖示)於虛置閘極材料上並覆蓋虛置閘極材料。舉例來說,第一硬遮罩層可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他硬遮罩材料、或上述之組合。舉例來說,第一硬遮罩層的沉積或成長方法可為化學氣相沉積、物理氣相沉積、原子層沉積、熱氧化、一些其他沉積或成長製程、或上述之組合。 A first hard mask layer (not shown) is then deposited or grown on the dummy gate material to cover the dummy gate material. For example, the first hard mask layer may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other hard mask material, or a combination thereof. For example, the deposition or growth method of the first hard mask layer may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, thermal oxidation, some other deposition or growth process, or a combination thereof.

之後沉積第二硬遮罩層(未圖示)於第一硬遮罩層上並覆蓋第一硬遮罩層。舉例來說,第二硬遮罩層可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他硬遮罩材料、或上述之組合。第二硬遮罩層與第一硬遮罩層可包含不同的硬遮罩材料。舉例來說,第一硬遮罩可為氧化矽,且第二硬遮罩可為氮化矽。第二硬遮罩層的沉積或成長方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 A second hard mask layer (not shown) is then deposited on the first hard mask layer and covers the first hard mask layer. For example, the second hard mask layer may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other hard mask material, or a combination thereof. The second hard mask layer and the first hard mask layer may include different hard mask materials. For example, the first hard mask may be silicon oxide, and the second hard mask may be silicon nitride. The deposition or growth method of the second hard mask layer may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

之後形成第二圖案化遮罩層(未圖示,比如正光阻及/或負光阻)於第二硬遮罩層上。在第二圖案化遮罩層的存在下,進行第五蝕刻製程以移除第二硬遮罩層的未遮罩部分,以保留第二硬遮罩層的遮罩部分作為第二硬遮罩結構608。在第二硬遮罩結構608位於第一硬遮罩層上的狀況下,接著進行第六蝕刻製程以移除第一硬遮罩層的未遮罩部分,以保留第一硬遮罩層的遮罩部分作為第三硬遮罩結構610。第二硬遮罩結構608與第三硬遮罩結構610可一起視作第四硬遮罩結構612。舉例來說,第五蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反 應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。舉例來說,第六蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 A second patterned mask layer (not shown, such as positive photoresist and/or negative photoresist) is then formed on the second hard mask layer. In the presence of the second patterned mask layer, a fifth etching process is performed to remove the unmasked portion of the second hard mask layer to retain the masked portion of the second hard mask layer as a second hard mask structure 608. In a state where the second hard mask structure 608 is located on the first hard mask layer, a sixth etching process is then performed to remove the unmasked portion of the first hard mask layer to retain the masked portion of the first hard mask layer as a third hard mask structure 610. The second hard mask structure 608 and the third hard mask structure 610 can be collectively regarded as a fourth hard mask structure 612. For example, the fifth etching process may be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof. For example, the sixth etching process may be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof.

之後在第四硬遮罩結構612位於虛置閘極材料層與虛置閘極介電層上的狀況下,在虛置閘極材料層與虛置閘極介電層上進行第七蝕刻製程以形成虛置閘極結構602。第七蝕刻製程移除虛置閘極材料層的未遮罩部分,以保留虛置閘極材料層的遮罩部分作為虛置閘極材料結構606。第七蝕刻製程亦移除虛置閘極介電層的未遮罩部分,以保留虛置閘極介電層的遮罩部分作為虛置閘極介電結構604。因此形成虛置閘極結構602。舉例來說,第七蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 Then, with the fourth hard mask structure 612 located on the dummy gate material layer and the dummy gate dielectric layer, a seventh etching process is performed on the dummy gate material layer and the dummy gate dielectric layer to form the dummy gate structure 602. The seventh etching process removes the unmasked portion of the dummy gate material layer to retain the masked portion of the dummy gate material layer as the dummy gate material structure 606. The seventh etching process also removes the unmasked portion of the dummy gate dielectric layer to retain the masked portion of the dummy gate dielectric layer as the dummy gate dielectric structure 604. Thus, the dummy gate structure 602 is formed. For example, the seventh etching process can be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof.

如圖7所示,沿著虛置閘極材料結構606的側壁形成第一側壁間隔物702。在一些實施例中,亦沿著第四硬遮罩結構612的側壁形成第一側壁間隔物702。為了使圖式清楚,只特別標示一些第一側壁間隔物702。 As shown in FIG. 7 , first sidewall spacers 702 are formed along the sidewalls of the dummy gate material structure 606. In some embodiments, first sidewall spacers 702 are also formed along the sidewalls of the fourth hard mask structure 612. For clarity of the drawings, only some first sidewall spacers 702 are specifically marked.

在一些實施例中,形成第一側壁間隔物702的製程包括沉積第一間隔物層於圖6所示的結構上。第一間隔物層可順應性地沉積於圖6所示的結構上。舉例來說,第一間隔物層可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他硬遮罩材料、或上述之組合。之後可在第一間隔物層上進行第八蝕刻製程,以移除第一間隔物層的水平部分(比如第四硬遮罩結構612、第一硬遮罩結構202、蓋結構404、與介電帶504上的部分),以保留第一間隔物層的垂直部分作為第一側壁間隔物702(比如沿著虛置閘極介電結構604、虛置閘極材料結構606、第三硬遮罩結構610、與第二硬遮罩結構608的側壁之部分)。舉例來說,第八蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 In some embodiments, the process of forming the first sidewall spacer 702 includes depositing a first spacer layer on the structure shown in Figure 6. The first spacer layer can be conformally deposited on the structure shown in Figure 6. For example, the first spacer layer can be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other hard mask material, or a combination thereof. An eighth etching process may then be performed on the first spacer layer to remove horizontal portions of the first spacer layer (e.g., portions on the fourth hard mask structure 612, the first hard mask structure 202, the capping structure 404, and the dielectric tape 504) to retain vertical portions of the first spacer layer as first sidewall spacers 702 (e.g., portions along the sidewalls of the dummy gate dielectric structure 604, the dummy gate material structure 606, the third hard mask structure 610, and the second hard mask structure 608). For example, the eighth etching process may be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof.

如圖7所示,移除第一側壁間隔物702的邊界之外(比如第一側壁間隔物702的外側側壁之外)的第一硬遮罩結構202的部分、半導體結構的第一堆疊204的部分、蓋結構404的部分、與介電帶504的部分(見圖6)。在一些實施例中,移除第一側壁間隔物702的邊界之外的第一硬遮罩結構202的部分、半導體結構的第一堆疊204的部分、蓋結構404的部分、與介電帶504的部分的製程,包括在第一硬遮罩結構202、半導體結構的第一堆疊204、蓋結構404、與介電帶504上進行第九蝕刻製程。 As shown in FIG. 7 , a portion of the first hard mask structure 202, a portion of the first stack 204 of the semiconductor structure, a portion of the cap structure 404, and a portion of the dielectric tape 504 outside the boundary of the first sidewall spacer 702 (e.g., outside the outer sidewall of the first sidewall spacer 702) are removed (see FIG. 6 ). In some embodiments, the process of removing a portion of the first hard mask structure 202, a portion of the first stack 204 of the semiconductor structure, a portion of the cap structure 404, and a portion of the dielectric tape 504 outside the boundary of the first sidewall spacer 702 includes performing a ninth etching process on the first hard mask structure 202, the first stack 204 of the semiconductor structure, the cap structure 404, and the dielectric tape 504.

第九蝕刻製程可為非等向蝕刻。舉例來說,第九蝕刻製程可為乾蝕刻製程、反應性離子蝕刻、一些其他蝕刻製程、或上述之組合。第九蝕刻製程採用的蝕刻劑對第一硬遮罩結構202、第一半導體結構206、第二半導體結構208、蓋結構404、與介電帶504具有選擇性(比如對這些材料的蝕刻速率,高於對介電鰭狀物502及/或隔離結構402的蝕刻速率)。 The ninth etching process may be anisotropic etching. For example, the ninth etching process may be a dry etching process, reactive ion etching, some other etching process, or a combination thereof. The etchant used in the ninth etching process is selective to the first hard mask structure 202, the first semiconductor structure 206, the second semiconductor structure 208, the cap structure 404, and the dielectric tape 504 (for example, the etching rate of these materials is higher than the etching rate of the dielectric fin 502 and/or the isolation structure 402).

在第九蝕刻製程時,虛置閘極結構602、第四硬遮罩結構612、與第一側壁間隔物一起作為蝕刻遮罩。因此,第九蝕刻製程移除第一側壁間隔物702的邊界之外的第一硬遮罩結構202的部分、半導體結構的第一堆疊204的部分、蓋結構404的部分、與介電帶504的部分。第九蝕刻製程露出鰭狀物210的上表面。在一些實施例中,第九蝕刻製程止於隔離結構402的上表面(或靠近上表面處)。 During the ninth etching process, the dummy gate structure 602, the fourth hard mask structure 612, and the first sidewall spacer together serve as an etching mask. Therefore, the ninth etching process removes the portion of the first hard mask structure 202 outside the boundary of the first sidewall spacer 702, the portion of the first stack 204 of the semiconductor structure, the portion of the cap structure 404, and the portion of the dielectric tape 504. The ninth etching process exposes the upper surface of the fin 210. In some embodiments, the ninth etching process stops at the upper surface (or near the upper surface) of the isolation structure 402.

第九蝕刻製程形成第一多個介電結構704。舉例來說,第九蝕刻製程形成第一介電結構704a、第二介電結構704b、第三介電結構704c、第四介電結構704d、與第五介電結構704e。第一多個介電結構704係第九蝕刻製程之後,保留的介電帶504的分開部分。第一多個介電結構704形成於(如直接形成於)介電鰭狀物502之上,並形成於(如直接形成於)第一側壁間隔物702與虛置閘極結構602之下。第一多個介電結構704彼此分開(沿著z軸及/或沿著x軸)。應理解的是,第 一多個介電結構704可包含的介電結構可比所列者更多(比如第一多個介電結構704可包括介電帶504的其他分開部分,其保留於其他虛置閘極結構602之下,但因透視視角而未圖示)。 The ninth etch process forms a first plurality of dielectric structures 704. For example, the ninth etch process forms a first dielectric structure 704a, a second dielectric structure 704b, a third dielectric structure 704c, a fourth dielectric structure 704d, and a fifth dielectric structure 704e. The first plurality of dielectric structures 704 are separated portions of the dielectric tape 504 remaining after the ninth etch process. The first plurality of dielectric structures 704 are formed on (e.g., directly on) the dielectric fins 502 and formed on (e.g., directly on) the first sidewall spacers 702 and the dummy gate structures 602. The first plurality of dielectric structures 704 are separated from each other (along the z-axis and/or along the x-axis). It should be understood that the first plurality of dielectric structures 704 may include more dielectric structures than those listed (e.g., the first plurality of dielectric structures 704 may include other separated portions of the dielectric tape 504 that remain below other dummy gate structures 602, but are not shown due to perspective).

第九蝕刻製程亦形成多個半導體結構的第二堆疊705。每一半導體結構的第二堆疊705包括交錯的第三半導體結構706與第四半導體結構708。第三半導體結構706係第九蝕刻製程之後,保留的第一半導體結構206的部分。第四半導體結構708係第九蝕刻製程之後,保留的第二半導體結構208的部分。為了使圖式清楚,只特別標示一些半導體結構的第二堆疊705、第三半導體結構706、與第四半導體結構708。 The ninth etching process also forms a second stack 705 of multiple semiconductor structures. The second stack 705 of each semiconductor structure includes a third semiconductor structure 706 and a fourth semiconductor structure 708 that are interlaced. The third semiconductor structure 706 is a portion of the first semiconductor structure 206 that is retained after the ninth etching process. The fourth semiconductor structure 708 is a portion of the second semiconductor structure 208 that is retained after the ninth etching process. In order to make the figure clear, only the second stack 705, the third semiconductor structure 706, and the fourth semiconductor structure 708 of some semiconductor structures are specially marked.

半導體結構的第二堆疊705形成於(比如直接形成於)鰭狀物210之上,並形成於(比如直接形成於)第一側壁間隔物702與虛置閘極結構602之下。具體而言,半導體結構的第二堆疊705形成於(比如直接形成於)鰭狀物210之上,並形成於(比如直接形成於)第一硬遮罩結構202的分開部分之下。以第九蝕刻製程形成第一硬遮罩結構202的分開部分。第一硬遮罩結構202的分開部分係第九蝕刻製程之後,保留的第一硬遮罩結構202的分開部分。第一硬遮罩結構202的分開部分橫向分開(沿著z軸)。第一硬遮罩結構202的分開部分橫向位於(沿著z軸)蓋結構404之間。第一硬遮罩結構202的分開部分分別位於(如直接位於)半導體結構的第二堆疊705上,以及位於(比如直接位於)第一側壁間隔物702與虛置閘極結構602之下。 The second stack of semiconductor structures 705 is formed on (e.g., directly on) the fin 210 and is formed on (e.g., directly on) the first sidewall spacer 702 and the dummy gate structure 602. Specifically, the second stack of semiconductor structures 705 is formed on (e.g., directly on) the fin 210 and is formed on (e.g., directly on) the separated portions of the first hard mask structure 202. The separated portions of the first hard mask structure 202 are formed by the ninth etching process. The separated portions of the first hard mask structure 202 are the separated portions of the first hard mask structure 202 that remain after the ninth etching process. The separated portions of the first hard mask structure 202 are separated laterally (along the z-axis). The separated portions of the first hard mask structure 202 are laterally located (along the z-axis) between the capping structures 404. The separated portions of the first hard mask structure 202 are respectively located on (such as directly located on) the second stack 705 of the semiconductor structure, and located under (such as directly located on) the first sidewall spacer 702 and the dummy gate structure 602.

由於第九蝕刻製程為非等向蝕刻製程,第一多個介電結構704的每一者、第一硬遮罩結構202的分開部分的每一者、第三半導體結構706的每一者、與第四半導體結構708的每一者之外側側壁(沿著x軸橫向分開),實質上對準第一側壁間隔物702的外側側壁(沿著x軸橫向分開)。此外,由於第九蝕刻製程為非等向蝕刻製程,在第九蝕刻製程之後保留的蓋結構404的部分亦具有外側側壁(沿著 x軸橫向分開),其實質上對準第一側壁間隔物702的外側側壁(在x軸中橫向分開)。在一些實施例中,第一多個介電結構704可視作第一多個介電鰭狀物蓋,因其在後續製程步驟中覆蓋並保護介電鰭狀物502的上表面之部分。 Since the ninth etching process is an anisotropic etching process, the outer sidewalls (separated laterally along the x-axis) of each of the first plurality of dielectric structures 704, each of the separated portions of the first hard mask structure 202, each of the third semiconductor structure 706, and each of the fourth semiconductor structure 708 are substantially aligned with the outer sidewalls (separated laterally along the x-axis) of the first sidewall spacers 702. In addition, since the ninth etching process is an anisotropic etching process, the portion of the capping structure 404 remaining after the ninth etching process also has outer sidewalls (separated laterally along the x-axis) that are substantially aligned with the outer sidewalls (separated laterally in the x-axis) of the first sidewall spacers 702. In some embodiments, the first plurality of dielectric structures 704 can be considered as first plurality of dielectric fin caps because they cover and protect portions of the upper surface of the dielectric fin 502 during subsequent process steps.

如圖8所示,第二側壁間隔物802沿著每一第三半導體結構706的外側側壁(沿著x軸橫向分開)形成。第二側壁間隔物802亦沿著蓋結構404的外側側壁(沿著z軸橫向分開)形成。此外,第二側壁間隔物802可部分地沿著第一硬遮罩結構202的分開部分之兩側側壁(沿著z軸橫向分開)形成。為了使圖式清楚,只特別標示一些第二側壁間隔物802。在一些實施例中,第二側壁間隔物802可視作內側側壁間隔物。 As shown in FIG. 8 , the second sidewall spacers 802 are formed along the outer sidewalls (separated laterally along the x-axis) of each third semiconductor structure 706. The second sidewall spacers 802 are also formed along the outer sidewalls (separated laterally along the z-axis) of the cover structure 404. In addition, the second sidewall spacers 802 may be partially formed along both sidewalls (separated laterally along the z-axis) of the separated portion of the first hard mask structure 202. For the sake of clarity of the figure, only some of the second sidewall spacers 802 are specifically marked. In some embodiments, the second sidewall spacers 802 may be regarded as inner sidewall spacers.

在一些實施例中,形成第二側壁間隔物802的製程包括進行第十蝕刻製程以橫向(沿著x方向)蝕刻第三半導體結構706與蓋結構404。第十蝕刻製程對第三半導體結構706與蓋結構404的材料(如第一半導體材料,比如矽鍺)具有選擇性,因此可使第三半導體結構706與蓋結構404橫向凹陷。在第十蝕刻製程之後,每一第三半導體結構706的外側側壁與每一蓋結構404的外側側壁,可相對於第一硬遮罩結構202的外側側壁、第一側壁間隔物702的外側側壁、與第一多個介電結構704的外側側壁凹陷。 In some embodiments, the process of forming the second sidewall spacer 802 includes performing a tenth etching process to laterally (along the x-direction) etch the third semiconductor structure 706 and the capping structure 404. The tenth etching process is selective to the material of the third semiconductor structure 706 and the capping structure 404 (e.g., the first semiconductor material, such as silicon germanium), and thus the third semiconductor structure 706 and the capping structure 404 may be laterally recessed. After the tenth etching process, the outer sidewalls of each third semiconductor structure 706 and the outer sidewalls of each capping structure 404 may be recessed relative to the outer sidewalls of the first hard mask structure 202, the outer sidewalls of the first sidewall spacer 702, and the outer sidewalls of the first plurality of dielectric structures 704.

之後可形成第二間隔物層(未圖式)以填入第十蝕刻製程所形成的凹陷。第二間隔物層的形成方法,可為沉積第二間隔物層於第十蝕刻製程所形成的凹陷之中,以及基板212、鰭狀物210、襯墊層302、隔離結構402、介電鰭狀物502、半導體結構的第二堆疊705、第一硬遮罩結構202、第一多個介電結構704、第一側壁間隔物702、虛置閘極結構602、與第四硬遮罩結構612之上。在一些實施例中,可沉積第二間隔物層如順應層。在其他實施例中,第二間隔物層可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他介電材料、或上述之組合。舉例來說,第二間隔物層的沉積方法可為 化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。 A second spacer layer (not shown) may then be formed to fill the recess formed by the tenth etching process. The second spacer layer may be formed by depositing the second spacer layer in the recess formed by the tenth etching process and on the substrate 212, the fin 210, the pad layer 302, the isolation structure 402, the dielectric fin 502, the second stack of semiconductor structures 705, the first hard mask structure 202, the first plurality of dielectric structures 704, the first sidewall spacer 702, the dummy gate structure 602, and the fourth hard mask structure 612. In some embodiments, the second spacer layer may be deposited as a compliant layer. In other embodiments, the second spacer layer may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other dielectric material, or a combination thereof. For example, the deposition method of the second spacer layer may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof.

接著在第二間隔物層上進行第十一蝕刻製程以部分移除第二間隔物層,可沿著第三半導體結構706的外側側壁與蓋結構404的外側側壁保留第二間隔物層的部分,以作為第二側壁間隔物802。具體而言,第十一蝕刻製程為非等向,其可修整第二間隔物層,因此只有第二間隔物層的部分保留於第十蝕刻製程所形成的凹陷中。因此第二側壁間隔物802的側壁可實質上對準第一硬遮罩結構202的外側側壁、第一側壁間隔物702的外側側壁、與第一多個介電結構704的外側側壁。舉例來說,第十一蝕刻製程可為電漿蝕刻製程、乾蝕刻製程、反應性離子蝕刻、一些其他蝕刻製程、或上述之組合。 Then, an eleventh etching process is performed on the second spacer layer to partially remove the second spacer layer, and a portion of the second spacer layer may be retained along the outer sidewalls of the third semiconductor structure 706 and the outer sidewalls of the capping structure 404 to serve as the second sidewall spacers 802. Specifically, the eleventh etching process is anisotropic, which may trim the second spacer layer, so that only a portion of the second spacer layer remains in the recess formed by the tenth etching process. Therefore, the sidewalls of the second sidewall spacers 802 may be substantially aligned with the outer sidewalls of the first hard mask structure 202, the outer sidewalls of the first sidewall spacers 702, and the outer sidewalls of the first plurality of dielectric structures 704. For example, the eleventh etching process may be a plasma etching process, a dry etching process, a reactive ion etching process, some other etching process, or a combination thereof.

如圖9所示,多對第一源極/汲極區902與多對第二源極/汲極區904形成於鰭狀物210上。為了使圖式清楚,僅特別標示一些第一源極/汲極區902與一些第二源極/汲極區904。第一源極/汲極區902分別形成於(比如直接形成於)一些鰭狀物210上,且第二源極/汲極區904分別形成於(比如直接形成於)一些其他鰭狀物210上。舉例來說,第一對902a的第一源極/汲極區902形成於(比如直接形成於)第一鰭狀物210a上,第二對902b的第一源極/汲極區902形成於(比如直接形成於)第二鰭狀物210b上,第三對904a的第二源極/汲極區904形成於(比如直接形成於)第三鰭狀物210c上,第四對904b的第二源極/汲極區904形成於(比如直接形成於)第四鰭狀物210d上,第五對902c的第一源極/汲極區902形成於(比如直接形成於)第五鰭狀物210e上,且第六對902d的第一源極/汲極區902形成於(比如直接形成於)第六鰭狀物210f上,多對第一源極/汲極區902的第一源極/汲極區902(比如第一對902a、第二對902b、第五對902c、與第六對902d)橫向分開(沿著x軸),並位於虛置閘極結構602的兩側上。多對第二源極/汲極區904的第二源極/汲極區904(比如 第三對904a與第四對904b)橫向分開(沿著x軸),並位於虛置閘極結構602的兩側上。多對第一源極/汲極區902與多對第二源極/汲極區904橫向分開(沿著z軸)。介電鰭狀物502橫向分開(沿著z軸)多對第一源極/汲極區902與多對第二源極/汲極區904。換言之,多對第一源極/汲極區902與多對第二源極/汲極區904位於介電鰭狀物502的兩側上。 As shown in FIG9 , a plurality of pairs of first source/drain regions 902 and a plurality of pairs of second source/drain regions 904 are formed on the fins 210. For clarity of the drawing, only some of the first source/drain regions 902 and some of the second source/drain regions 904 are specifically labeled. The first source/drain regions 902 are formed on (e.g., directly formed on) some of the fins 210, and the second source/drain regions 904 are formed on (e.g., directly formed on) some of the other fins 210. For example, the first source/drain region 902 of the first pair 902a is formed on (e.g., directly formed on) the first fin 210a, the first source/drain region 902 of the second pair 902b is formed on (e.g., directly formed on) the second fin 210b, the second source/drain region 904 of the third pair 904a is formed on (e.g., directly formed on) the third fin 210c, the second source/drain region 904 of the fourth pair 904b is formed on (e.g., directly formed on) the fourth fin 210d, The first source/drain regions 902 of the fifth pair 902c are formed on (e.g., directly on) the fifth fin 210e, and the first source/drain regions 902 of the sixth pair 902d are formed on (e.g., directly on) the sixth fin 210f. The first source/drain regions 902 of multiple pairs of first source/drain regions 902 (e.g., the first pair 902a, the second pair 902b, the fifth pair 902c, and the sixth pair 902d) are laterally separated (along the x-axis) and located on both sides of the dummy gate structure 602. The second source/drain regions 904 of the plurality of pairs of second source/drain regions 904 (e.g., the third pair 904a and the fourth pair 904b) are separated laterally (along the x-axis) and are located on both sides of the dummy gate structure 602. The plurality of pairs of first source/drain regions 902 are separated laterally (along the z-axis) from the plurality of pairs of second source/drain regions 904. The dielectric fins 502 separate laterally (along the z-axis) the plurality of pairs of first source/drain regions 902 from the plurality of pairs of second source/drain regions 904. In other words, multiple pairs of first source/drain regions 902 and multiple pairs of second source/drain regions 904 are located on both sides of the dielectric fin 502.

對應的鰭狀物210上的第四半導體結構708分別橫向延伸(沿著x軸)於對應的鰭狀物210上的多對源極/汲極區的源極/汲極區之間。舉例來說,第一鰭狀物210a上的半導體結構的第二堆疊705之一者位於第一對902a的第一源極/汲極區902之間,且第一鰭狀物210a上的半導體結構的第二堆疊705之一者的第四半導體結構708橫向延伸(沿著x軸)於第一對902a的第一源極/汲極區902之間。對應鰭狀物210上的第二側壁間隔物802分別位於對應鰭狀物210上的多對源極/汲極區之源極/汲極區之間。舉例來說,第二側壁間隔物802之一者沿著第一鰭狀物210a上的半導體結構的第二堆疊705之一者的第三半導體結構706之外側側壁,其位於第一對902a的第一源極/汲極區902之間。 The fourth semiconductor structures 708 on the corresponding fins 210 extend laterally (along the x-axis) between the source/drain regions of the multiple pairs of source/drain regions on the corresponding fins 210. For example, one of the second stacks 705 of semiconductor structures on the first fin 210a is located between the first source/drain regions 902 of the first pair 902a, and the fourth semiconductor structure 708 of one of the second stacks 705 of semiconductor structures on the first fin 210a extends laterally (along the x-axis) between the first source/drain regions 902 of the first pair 902a. The second sidewall spacers 802 on the corresponding fins 210 are respectively located between the source/drain regions of the multiple pairs of source/drain regions on the corresponding fins 210. For example, one of the second sidewall spacers 802 is along the outer sidewall of the third semiconductor structure 706 of one of the second stacks 705 of semiconductor structures on the first fin 210a, and is located between the first source/drain regions 902 of the first pair 902a.

舉例來說,第一源極/汲極區902可為或包括矽、鍺、矽鍺、碳化矽、一些其他半導體材料、或上述之組合。在一些實施例中,第一源極/汲極區902為磊晶的半導體材料,比如磊晶製程所形成的半導體材料如磊晶矽、磊晶鍺、磊晶矽鍺、磊晶碳化矽、或類似物。舉例來說,第二源極/汲極區904可為或包括矽、鍺、矽鍺、碳化矽、一些其他半導體材料、或上述之組合。在一些實施例中,第二源極/汲極區904為磊晶的半導體材料,比如磊晶製程所形成的半導體材料如磊晶矽、磊晶鍺、磊晶矽鍺、磊晶碳化矽、或類似物。 For example, the first source/drain region 902 can be or include silicon, germanium, silicon germanium, silicon carbide, some other semiconductor material, or a combination thereof. In some embodiments, the first source/drain region 902 is an epitaxial semiconductor material, such as a semiconductor material formed by an epitaxial process such as epitaxial silicon, epitaxial germanium, epitaxial silicon germanium, epitaxial silicon carbide, or the like. For example, the second source/drain region 904 can be or include silicon, germanium, silicon germanium, silicon carbide, some other semiconductor material, or a combination thereof. In some embodiments, the second source/drain region 904 is an epitaxial semiconductor material, such as a semiconductor material formed by an epitaxial process such as epitaxial silicon, epitaxial germanium, epitaxial silicon germanium, epitaxial silicon carbide, or the like.

在一些實施例中,第一源極/汲極區902與第二源極/汲極區904包含相同的半導體材料。在其他實施例中,第一源極/汲極區902與第二源極/汲極區904包含不同的半導體材料。在其他實施例中,第一源極/汲極區902具有第一摻 雜型態(如p型)。在其他實施例中,第二源極/汲極區904具有與第一摻雜型態相反的第二摻雜型態(如n型)。 In some embodiments, the first source/drain region 902 and the second source/drain region 904 include the same semiconductor material. In other embodiments, the first source/drain region 902 and the second source/drain region 904 include different semiconductor materials. In other embodiments, the first source/drain region 902 has a first doping type (e.g., p-type). In other embodiments, the second source/drain region 904 has a second doping type (e.g., n-type) opposite to the first doping type.

在一些實施例中,形成第一源極/汲極區902與第二源極/汲極區904的製程,包括磊晶形成第一源極/汲極區902與第二源極/汲極區904。進行第三磊晶製程以自對應鰭狀物210的上表面成長第一源極/汲極區902。舉例來說,可自第一鰭狀物210a的上表面成長第一對902a的第一源極/汲極區902,自第二鰭狀物210b的上表面成長第二對902b的第一源極/汲極區902,自第五鰭狀物210e的上表面成長第五對902c的第一源極/汲極區902,並自第六鰭狀物210f的上表面成長第六對902d的第一源極/汲極區902。在一些實施例中,第三磊晶製程可為氣相磊晶、液相磊晶、分子束磊晶、一些其他磊晶製程、或上述之組合。第三磊晶製程可原位摻雜第一摻雜型態的摻質(比如p型摻質如硼原子)至第一源極/汲極區902。 In some embodiments, the process of forming the first source/drain region 902 and the second source/drain region 904 includes epitaxially forming the first source/drain region 902 and the second source/drain region 904. A third epitaxial process is performed to grow the first source/drain region 902 from the upper surface corresponding to the fin 210. For example, the first source/drain regions 902 of the first pair 902a may be grown from the upper surface of the first fin 210a, the first source/drain regions 902 of the second pair 902b may be grown from the upper surface of the second fin 210b, the first source/drain regions 902 of the fifth pair 902c may be grown from the upper surface of the fifth fin 210e, and the first source/drain regions 902 of the sixth pair 902d may be grown from the upper surface of the sixth fin 210f. In some embodiments, the third epitaxial process may be vapor phase epitaxy, liquid phase epitaxy, molecular beam epitaxy, some other epitaxial process, or a combination thereof. The third epitaxial process can in-situ dope the first doping type dopant (e.g., p-type dopant such as boron atoms) into the first source/drain region 902.

可進行第四磊晶製程以自對應鰭狀物210的上表面成長第二源極/汲極區904。舉例來說,可自第三鰭狀物210c的上表面形成第三對904a的第二源極/汲極區904,且可自第四鰭狀物210d的上表面形成第四對904b的第二源極/汲極區904。在一些實施例中,第四磊晶製程可為氣相磊晶、液相磊晶、分子束磊晶、一些其他磊晶製程、或上述之組合。第四磊晶製程可原位摻雜第二摻雜型態的摻質(比如n型摻質如磷原子)至第二源極/汲極區904。應理解的是,在第三磊晶製程時可由遮罩層遮罩鰭狀物210的上表面(其可成長第二源極/汲極區904)。應理解的是,在第四磊晶製程時可由遮罩層遮罩第一源極/汲極區902。 A fourth epitaxial process may be performed to grow the second source/drain regions 904 from the upper surface of the corresponding fin 210. For example, the second source/drain regions 904 of the third pair 904a may be formed from the upper surface of the third fin 210c, and the second source/drain regions 904 of the fourth pair 904b may be formed from the upper surface of the fourth fin 210d. In some embodiments, the fourth epitaxial process may be vapor phase epitaxy, liquid phase epitaxy, molecular beam epitaxy, some other epitaxial process, or a combination thereof. The fourth epitaxial process may in-situ dope the second source/drain regions 904 with a second doping type (e.g., an n-type dopant such as phosphorus atoms). It should be understood that in the third epitaxial process, the upper surface of the fin 210 (which can grow the second source/drain region 904) can be masked by the mask layer. It should be understood that in the fourth epitaxial process, the first source/drain region 902 can be masked by the mask layer.

如圖10所示,形成第一蝕刻停止層1002(如接點蝕刻停止層)於圖9所示的結構上,並形成第一層間介電層1004於第一蝕刻停止層1002上。舉例來說,第一蝕刻停止層1002可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他介電材料、或上述之組合。舉例來說,層間介電 層1004可為或包含低介電常數的介電層(如介電常數小於約3.9的介電材料)、氧化物(如氧化矽)、或類似物。 As shown in FIG. 10 , a first etch stop layer 1002 (such as a contact etch stop layer) is formed on the structure shown in FIG. 9 , and a first interlayer dielectric layer 1004 is formed on the first etch stop layer 1002. For example, the first etch stop layer 1002 may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other dielectric material, or a combination thereof. For example, the interlayer dielectric layer 1004 may be or include a low dielectric constant dielectric layer (such as a dielectric material having a dielectric constant less than about 3.9), an oxide (such as silicon oxide), or the like.

在一些實施例中,形成第一蝕刻停止層1002與層間介電層1004的製程包含沉積第一蝕刻停止層1002於圖9所示的結構上並覆蓋圖9所示的結構。在一些實施例中,沉積第一蝕刻停止層1002如順應層。舉例來說,第一蝕刻停止層1002的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。之後可沉積層間介電層1004於第一蝕刻停止層1002與圖9所示的結構上,並覆蓋第一蝕刻停止層1002與圖9所示的結構。接著在層間介電層1004、第一蝕刻停止層1002、第四硬遮罩結構612(見圖9)、與第一側壁間隔物702上進行平坦化製程,平坦化製程可移除層間介電層1004、第一蝕刻停止層1002、第四硬遮罩結構612、與第一側壁間隔物702的上側部分,以形成圖10所示的結構。因此平坦化製程可使層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上表面共平面。 In some embodiments, the process of forming the first etch stop layer 1002 and the interlayer dielectric layer 1004 includes depositing the first etch stop layer 1002 on and covering the structure shown in FIG. 9 . In some embodiments, the first etch stop layer 1002 is deposited as a conforming layer. For example, the deposition method of the first etch stop layer 1002 can be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof. Thereafter, the interlayer dielectric layer 1004 can be deposited on and covering the first etch stop layer 1002 and the structure shown in FIG. 9 . Then, a planarization process is performed on the interlayer dielectric layer 1004, the first etch stop layer 1002, the fourth hard mask structure 612 (see FIG. 9 ), and the first sidewall spacer 702. The planarization process can remove the interlayer dielectric layer 1004, the first etch stop layer 1002, the fourth hard mask structure 612, and the upper portion of the first sidewall spacer 702 to form the structure shown in FIG. 10 . Therefore, the planarization process can make the interlayer dielectric layer 1004, the first etch stop layer 1002, and the upper surface of the first sidewall spacer 702 coplanar.

如圖11所示,移除虛置閘極結構,以形成第三溝槽1102於第一側壁間隔物702的內側側壁之間。為了使圖式清楚,只特別標示一些第三溝槽1102。第三溝槽1102露出位於第一側壁間隔物702的內側側壁之間的第一多個介電結構704之部分與第一硬遮罩結構202的部分。在一些實施例中,移除虛置閘極結構602的製程包括進行第十二蝕刻製程(比如濕蝕刻製程、乾蝕刻製程、或類似製程),其選擇性移除虛置閘極介電結構604與虛置閘極材料結構606。應理解的是,可採用多道蝕刻製程移除虛置閘極結構602(比如在第十二蝕刻製程移除虛置閘極材料結構606之後,以後續的蝕刻製程移除虛置閘極介電結構604)。 As shown in FIG. 11 , the dummy gate structure is removed to form a third trench 1102 between the inner sidewalls of the first sidewall spacers 702. For clarity of the drawing, only some of the third trenches 1102 are specifically labeled. The third trenches 1102 expose portions of the first plurality of dielectric structures 704 and portions of the first hard mask structure 202 between the inner sidewalls of the first sidewall spacers 702. In some embodiments, the process of removing the dummy gate structure 602 includes performing a twelfth etching process (e.g., a wet etching process, a dry etching process, or the like) that selectively removes the dummy gate dielectric structure 604 and the dummy gate material structure 606. It should be understood that multiple etching processes may be used to remove the dummy gate structure 602 (for example, after the twelfth etching process removes the dummy gate material structure 606, a subsequent etching process removes the dummy gate dielectric structure 604).

如圖11所示,第一遮罩結構1104形成於第三溝槽1102中。第一遮罩結構1104的上表面可位於層間介電層1004的上表面之上。舉例來說,第一遮罩結構1104包括正光阻材料、負光阻材料、或類似物。第五硬遮罩結構1106形 成於第一遮罩結構1104上。舉例來說,第五硬遮罩結構1106可為或包括氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他硬遮罩材料、或上述之組合。 As shown in FIG. 11 , a first mask structure 1104 is formed in the third trench 1102. The upper surface of the first mask structure 1104 may be located above the upper surface of the interlayer dielectric layer 1004. For example, the first mask structure 1104 includes a positive photoresist material, a negative photoresist material, or the like. A fifth hard mask structure 1106 is formed on the first mask structure 1104. For example, the fifth hard mask structure 1106 may be or include an oxide (such as silicon oxide), a nitride (such as silicon nitride), an oxynitride (such as silicon oxynitride), some other hard mask material, or a combination thereof.

在一些實施例中,形成第一遮罩結構1104與第五硬遮罩結構1106的製程包括沉積光阻層(如正光阻材料及/或負光阻材料),其沉積方法可為化學氣相沉積、旋轉塗佈、或類似製程。光阻層沉積於第三溝槽1102中(比如填入第三溝槽1102)以及層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上表面上。之後可沉積硬遮罩層(未圖示)於光阻層上並覆蓋光阻層,且沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、或類似製程。之後可形成第三圖案化遮罩層於硬遮罩層上。採用第三圖案化的遮罩層,並在硬遮罩層上進行第十三蝕刻製程(比如濕蝕刻製程、乾蝕刻製程、反應性離子蝕刻製程、或類似製程),以移除硬遮罩層的未遮罩部分,進而保留硬遮罩層的遮罩部分作為第五硬遮罩結構1106。之後可剝除第三圖案化的遮罩層。 In some embodiments, the process of forming the first mask structure 1104 and the fifth hard mask structure 1106 includes depositing a photoresist layer (such as a positive photoresist material and/or a negative photoresist material), and the deposition method can be chemical vapor deposition, spin coating, or a similar process. The photoresist layer is deposited in the third trench 1102 (such as filling the third trench 1102) and on the upper surface of the interlayer dielectric layer 1004, the first etch stop layer 1002, and the first sidewall spacer 702. A hard mask layer (not shown) may then be deposited on the photoresist layer and cover the photoresist layer, and the deposition method may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, or a similar process. A third patterned mask layer may then be formed on the hard mask layer. The third patterned mask layer is used, and a thirteenth etching process (such as a wet etching process, a dry etching process, a reactive ion etching process, or a similar process) is performed on the hard mask layer to remove the unmasked portion of the hard mask layer, thereby retaining the masked portion of the hard mask layer as the fifth hard mask structure 1106. The third patterned mask layer may then be stripped off.

接著可在光阻層上進行第十四蝕刻製程(比如濕蝕刻製程、乾蝕刻製程、反應性離子蝕刻製程、或類似製程),以形成第一遮罩結構1104。在第十四蝕刻製程時,第五硬遮罩結構1106作為蝕刻遮罩。因此第十四蝕刻製程移除光阻層的未遮罩部分,並保留光阻層的保留部分作為第一遮罩結構1104。在一些實施例中,第一遮罩結構1104可視作切割金屬閘極遮罩。 Then, a fourteenth etching process (such as a wet etching process, a dry etching process, a reactive ion etching process, or a similar process) can be performed on the photoresist layer to form a first mask structure 1104. During the fourteenth etching process, the fifth hard mask structure 1106 serves as an etching mask. Therefore, the fourteenth etching process removes the unmasked portion of the photoresist layer and retains the remaining portion of the photoresist layer as the first mask structure 1104. In some embodiments, the first mask structure 1104 can be regarded as a cutting metal gate mask.

圖12至19顯示形成奈米結構場效電晶體1810減少的半導體裝置1904之方法的多種階段之一系列剖視圖。圖12至19的剖視圖沿著圖11的剖線A-A,並接續圖11所示的階段。舉例來說,圖12顯示圖11所示的階段之後的第一階段,並沿著圖11的剖線A-A。圖13顯示圖12所示的第一階段之後的第二階段,並沿著圖11的剖線A-A。圖14顯示圖13所示的第二階段之後的第三階段,並沿著圖11的剖線A-A,以此類推。由於圖12至19的剖視圖沿著圖11的剖線A-A,因此 圖12至19所示的形成奈米結構場效電晶體1810之間的空間減少之半導體裝置1904的方法之多種階段,只顯示可由圖11的剖線A-A所見的結構之製程(比如移除、形成、凹陷、或類似製程)。然而在一些實施例中,應理解可在圖12至19所示的多種階段對類似結構(比如與圖12至19中進行製程的結構類似)進行製程,比如以與圖12至19類似的方式對類似結構進行製程,但因沿著圖11的剖線A-A而未圖示。 12 to 19 show a series of cross-sectional views of various stages of a method of forming a semiconductor device 1904 with a reduced nanostructured field effect transistor 1810. The cross-sectional views of FIG12 to 19 are along the section line A-A of FIG11 and continue the stages shown in FIG11. For example, FIG12 shows a first stage after the stage shown in FIG11 and along the section line A-A of FIG11. FIG13 shows a second stage after the first stage shown in FIG12 and along the section line A-A of FIG11. FIG14 shows a third stage after the second stage shown in FIG13 and along the section line A-A of FIG11, and so on. Since the cross-sectional views of FIGS. 12 to 19 are along the section line A-A of FIG. 11 , the various stages of the method of forming the semiconductor device 1904 with reduced space between the nanostructure field effect transistors 1810 shown in FIGS. 12 to 19 only show the process (such as removal, formation, recessing, or similar process) of the structure that can be seen by the section line A-A of FIG. 11 . However, in some embodiments, it should be understood that similar structures (such as structures similar to those processed in FIGS. 12 to 19 ) can be processed at the various stages shown in FIGS. 12 to 19 , such as being processed in a manner similar to FIGS. 12 to 19 , but not shown because they are along the section line A-A of FIG. 11 .

如圖12所示,移除第三溝槽1102(見圖11)露出且第一遮罩結構1104未遮罩的第一多個介電結構704。舉例來說,第三溝槽1102露出且第一遮罩結構1104未遮罩第一介電結構704a、第三介電結構704c、與第五介電結構704e(見圖9),因此移除上述介電結構。雖然圖12顯示移除第一介電結構704a、第三介電結構704c、與第五介電結構704e,但應理解可移除第一多個介電結構704的介電結構之任何組合(比如形成預先定義圖案的第一遮罩結構1104)。在一些實施例中,移除(比如完全移除)第三溝槽1102露出且第一遮罩結構1104未遮罩的第一多個介電結構704的介電結構。在其他實施例中,只移除第三溝槽1102露出且第一遮罩結構1104未遮罩的第一多個介電結構704的介電結構的一部分,比如保留直接位於第一側壁間隔物702下的第一多個介電結構704之這些介電結構的其餘部分。 As shown in FIG12, the first plurality of dielectric structures 704 are removed, exposing the third trench 1102 (see FIG11) and not masked by the first mask structure 1104. For example, the third trench 1102 is exposed and the first mask structure 1104 does not mask the first dielectric structure 704a, the third dielectric structure 704c, and the fifth dielectric structure 704e (see FIG9), so the above dielectric structures are removed. Although FIG12 shows the removal of the first dielectric structure 704a, the third dielectric structure 704c, and the fifth dielectric structure 704e, it should be understood that any combination of dielectric structures of the first plurality of dielectric structures 704 may be removed (such as forming a first mask structure 1104 in a predefined pattern). In some embodiments, the dielectric structures of the first plurality of dielectric structures 704 exposed by the third trench 1102 and not covered by the first mask structure 1104 are removed (e.g., completely removed). In other embodiments, only a portion of the dielectric structures of the first plurality of dielectric structures 704 exposed by the third trench 1102 and not covered by the first mask structure 1104 is removed, such as retaining the remaining portions of the first plurality of dielectric structures 704 directly under the first sidewall spacer 702.

如圖12所示,移除第三溝槽1102露出且第一遮罩結構1104未遮罩的蓋結構404的部分,使蓋結構404的內側側壁傾斜。舉例來說,第三溝槽1102露出且第一遮罩結構1104未遮置沿著第一介電鰭狀物502a、第三介電鰭狀物502c、與第五介電鰭狀物502e的側壁之蓋結構404。因此移除沿著第一介電鰭狀物502a、第三介電鰭狀物502c、與第五介電鰭狀物502e的側壁之蓋結構404的部分,使沿著第一介電鰭狀物502a、第三介電鰭狀物502c、與第五介電鰭狀物502e的側壁之蓋結構404的內側側壁傾斜。蓋結構404的傾斜側壁可自對應的介電鰭 狀物502傾斜至半導體結構的第二堆疊705之對應堆疊。舉例來說,沿著第三介電鰭狀物502c的第一側壁之蓋結構404之一者的第一傾斜內側側壁,可自第三介電鰭狀物502c傾斜至第三介電鰭狀物502c與第二介電鰭狀物502b之間的半導體結構的第二堆疊705。沿著第三介電鰭狀物502c的第二側壁之蓋結構404之另一者的第二傾斜內側側壁(與第一傾斜內側側壁的方向相反),可自第三介電鰭狀物502c傾斜至第三介電鰭狀物502c與第四介電鰭狀物502d之間的半導體結構的第二堆疊705。 12 , the portion of the cover structure 404 exposed by the third trench 1102 and not covered by the first mask structure 1104 is removed, so that the inner sidewall of the cover structure 404 is inclined. For example, the third trench 1102 is exposed and the first mask structure 1104 does not cover the cover structure 404 along the sidewalls of the first dielectric fin 502a, the third dielectric fin 502c, and the fifth dielectric fin 502e. Therefore, the portion of the cap structure 404 along the sidewalls of the first dielectric fin 502a, the third dielectric fin 502c, and the fifth dielectric fin 502e is removed, so that the inner sidewalls of the cap structure 404 along the sidewalls of the first dielectric fin 502a, the third dielectric fin 502c, and the fifth dielectric fin 502e are tilted. The tilted sidewalls of the cap structure 404 can tilt from the corresponding dielectric fin 502 to the corresponding stack of the second stack 705 of semiconductor structures. For example, the first inclined inner sidewall of one of the cap structures 404 along the first sidewall of the third dielectric fin 502c can be inclined from the third dielectric fin 502c to the second stack 705 of semiconductor structures between the third dielectric fin 502c and the second dielectric fin 502b. The second inclined inner sidewall of the other of the cap structures 404 along the second sidewall of the third dielectric fin 502c (in the opposite direction to the first inclined inner sidewall) can be inclined from the third dielectric fin 502c to the second stack 705 of semiconductor structures between the third dielectric fin 502c and the fourth dielectric fin 502d.

在一些實施例中,移除第三溝槽1102露出且第一遮罩結構1104未遮罩的第一多個介電結構704的步驟,包括在圖11所示的結構上進行第十五蝕刻製程,以選擇性移除第三溝槽1102露出且第一遮罩結構1104未遮罩的第一多個介電結構704。在第十五蝕刻製程時,第一遮罩結構1104作為蝕刻遮罩,其可避免第十五蝕刻製程蝕刻移除第一遮罩結構1104所遮罩的第一多個介電結構704(與蓋結構404的部分)。因此第十五蝕刻製程選擇性地移除第三溝槽1102所露出且第一遮罩結構1104未遮罩的第一多個介電結構704。此外,第十五蝕刻製程可移除第三溝槽1102露出且第一遮罩結構1104未遮罩的蓋結構404的部分,進而使蓋結構404的內側側壁傾斜。在一些實施例中,第十五蝕刻製程可為乾蝕刻製程、濕蝕刻製程、一些其他蝕刻製程、或上述之組合。如圖12所示,可由第十五蝕刻製程移除第五硬遮罩結構1106。 In some embodiments, the step of removing the first plurality of dielectric structures 704 exposed by the third trench 1102 and not covered by the first mask structure 1104 includes performing a fifteenth etching process on the structure shown in FIG. 11 to selectively remove the first plurality of dielectric structures 704 exposed by the third trench 1102 and not covered by the first mask structure 1104. During the fifteenth etching process, the first mask structure 1104 serves as an etching mask, which can prevent the fifteenth etching process from etching and removing the first plurality of dielectric structures 704 (and a portion of the capping structure 404) covered by the first mask structure 1104. Therefore, the fifteenth etching process selectively removes the first plurality of dielectric structures 704 exposed by the third trench 1102 and not covered by the first mask structure 1104. In addition, the fifteenth etching process can remove the portion of the cap structure 404 exposed by the third trench 1102 and not masked by the first mask structure 1104, thereby tilting the inner sidewall of the cap structure 404. In some embodiments, the fifteenth etching process can be a dry etching process, a wet etching process, some other etching process, or a combination thereof. As shown in FIG. 12 , the fifth hard mask structure 1106 can be removed by the fifteenth etching process.

在第十五蝕刻製程之後,可保留第一多個介電結構704,之後可一起視作保留的介電結構704b/704d。以圖12為例,保留的介電結構704b/704d包括第二介電結構704b與第四介電結構704d(因為第十五蝕刻製程之後保留第二介電結構704b與第四介電結構704d)。應理解的是,第十五蝕刻製程之後可保留第一多個介電結構704的其他介電結構,比如第一多個介電結構704中與第二介電結構704b及第四介電結構704d分開(沿著x軸)的其他介電結構(未圖式,因為剖視 圖沿著圖11的剖線A-A)。應理解的是,保留的介電結構採用”704b/704d”作為標號是為了清楚標示,但不表示保留的介電結構704b/704d侷限於只包括第二介電結構704b與第四介電結構704d。相反地,在第十五蝕刻製程之後,保留的介電結構704b/704d可包含第一多個介電結構704的一或多者(及/或任何組合)。 After the fifteenth etching process, the first plurality of dielectric structures 704 may remain, and may be collectively referred to as the remaining dielectric structures 704b/704d. Taking FIG. 12 as an example, the remaining dielectric structures 704b/704d include the second dielectric structure 704b and the fourth dielectric structure 704d (because the second dielectric structure 704b and the fourth dielectric structure 704d remain after the fifteenth etching process). It should be understood that other dielectric structures of the first plurality of dielectric structures 704 may remain after the fifteenth etching process, such as other dielectric structures of the first plurality of dielectric structures 704 that are separated (along the x-axis) from the second dielectric structure 704b and the fourth dielectric structure 704d (not shown because the cross-sectional view is along the section line A-A of FIG. 11). It should be understood that the retained dielectric structure is labeled "704b/704d" for clarity, but it does not mean that the retained dielectric structure 704b/704d is limited to only the second dielectric structure 704b and the fourth dielectric structure 704d. On the contrary, after the fifteenth etching process, the retained dielectric structure 704b/704d may include one or more (and/or any combination) of the first plurality of dielectric structures 704.

在一些實施例中,保留的介電結構704b/704d可視作第二多個介電鰭狀物蓋,因其覆蓋(並在後續製程步驟中保護)對應的介電鰭狀物502的上表面之部分。舉例來說,第二介電結構704b覆蓋(並在後續製程步驟中保護)第二介電鰭狀物502b的上表面之一部分,而第四介電結構704d覆蓋(並在後續製程部中保護)第四介電鰭狀物502d的上表面之一部分。因此第二介電結構704b可視作第二多個介電鰭狀物蓋的第一介電鰭狀物蓋,而第四介電結構704d可視作第二多個鰭狀物蓋的第二介電鰭狀物蓋。 In some embodiments, the remaining dielectric structures 704b/704d can be considered as a second plurality of dielectric fin caps because they cover (and protect in subsequent process steps) portions of the upper surface of the corresponding dielectric fins 502. For example, the second dielectric structure 704b covers (and protects in subsequent process steps) a portion of the upper surface of the second dielectric fin 502b, and the fourth dielectric structure 704d covers (and protects in subsequent process steps) a portion of the upper surface of the fourth dielectric fin 502d. Therefore, the second dielectric structure 704b can be regarded as a first dielectric fin cap of a second plurality of dielectric fin caps, and the fourth dielectric structure 704d can be regarded as a second dielectric fin cap of a second plurality of fin caps.

如圖13所示,移除第一遮罩結構1104。在一些實施例中,移除第一遮罩結構1104的製程包括在圖12所示的結構上進行移除遮罩的製程。舉例來說,移除遮罩的製程可為蝕刻製程(如濕蝕刻製程、乾蝕刻製程、或類似製程)、灰化製程、上述之組合、或類似製程。 As shown in FIG. 13 , the first mask structure 1104 is removed. In some embodiments, the process of removing the first mask structure 1104 includes performing a mask removal process on the structure shown in FIG. 12 . For example, the mask removal process may be an etching process (such as a wet etching process, a dry etching process, or a similar process), an ashing process, a combination thereof, or a similar process.

如圖13所示,移除第一硬遮罩結構202。在移除第一遮罩結構1104之後,移除第一硬遮罩結構202。在一些實施例中,以第十六蝕刻製程(如濕蝕刻製程、乾蝕刻製程、或類似製程)選擇性移除第一硬遮罩結構202。在一些實施例中,第十六蝕刻製程使第一硬遮罩結構202凹陷而非移除第一硬遮罩結構202,以保留第一硬遮罩結構202的部分於半導體結構的第二堆疊705上(以在後續釋放製程時保護第四半導體結構708)。 As shown in FIG. 13 , the first hard mask structure 202 is removed. After removing the first mask structure 1104, the first hard mask structure 202 is removed. In some embodiments, the first hard mask structure 202 is selectively removed by a sixteenth etching process (such as a wet etching process, a dry etching process, or a similar process). In some embodiments, the sixteenth etching process recesses the first hard mask structure 202 instead of removing the first hard mask structure 202, so as to retain a portion of the first hard mask structure 202 on the second stack 705 of the semiconductor structure (to protect the fourth semiconductor structure 708 during the subsequent release process).

藉由移除(或凹陷)第一硬遮罩結構202,可延伸第三溝槽1102(沿著y方向,見圖11)。在一些實施例中,在第一側壁間隔物702的至少部分底切(沿著x軸)移除(或凹陷)第一硬遮罩結構202,可延伸第三溝槽1102的部分(沿著y 軸)。在其他實施例中,移除(或凹陷)第一硬遮罩結構202所延伸(沿著y軸)的第三溝槽1102之部分的兩側(沿著x軸分開),至少部分地由第一蝕刻停止層1002的側壁所定義。在其他實施例中,移除(或凹陷)第一硬遮罩結構202所延伸(沿著y軸)的第三溝槽1102之部分的兩側(沿著x軸分開),至少部分地由第一硬遮罩結構202(比如第十六蝕刻製程之後保留的第一硬遮罩結構202的其餘部分)的側壁所定義。 The third trench 1102 may be extended (along the y-direction, see FIG. 11 ) by removing (or recessing) the first hard mask structure 202. In some embodiments, the portion of the third trench 1102 may be extended (along the y-axis) by removing (or recessing) the first hard mask structure 202 at least partially undercutting (along the x-axis) the first sidewall spacer 702. In other embodiments, the sides (separated by the x-axis) of the portion of the third trench 1102 extended (along the y-axis) by removing (or recessing) the first hard mask structure 202 are at least partially defined by the sidewalls of the first etch stop layer 1002. In other embodiments, the sides (separated along the x-axis) of the portion of the third trench 1102 from which the first hard mask structure 202 is removed (or recessed) are at least partially defined by the sidewalls of the first hard mask structure 202 (e.g., the remaining portion of the first hard mask structure 202 remaining after the sixteenth etching process).

如圖13所示,多個奈米結構堆疊1302分別形成於鰭狀物210上。舉例來說,第一奈米結構堆疊1302a形成於(比如直接形成於)第一鰭狀物210a上,第二奈米結構堆疊1302b形成於(比如直接形成於)第二鰭狀物210b上,第三奈米結構堆疊1302c形成於(比如直接形成於)第三鰭狀物210c上,第四奈米結構堆疊1302d形成於(比如直接形成於)第四鰭狀物210d上,第五奈米結構堆疊1302e形成於(比如直接形成於)第五鰭狀物210e上,且第六奈米結構堆疊1302f形成於(比如直接形成於)第六鰭狀物210f上。在一些實施例中,在移除第一硬遮罩結構202之後形成奈米結構堆疊1302。 As shown in FIG. 13 , a plurality of nanostructure stacks 1302 are formed on the fins 210 . For example, the first nanostructure stack 1302a is formed on (e.g., directly formed on) the first fin 210a, the second nanostructure stack 1302b is formed on (e.g., directly formed on) the second fin 210b, the third nanostructure stack 1302c is formed on (e.g., directly formed on) the third fin 210c, the fourth nanostructure stack 1302d is formed on (e.g., directly formed on) the fourth fin 210d, the fifth nanostructure stack 1302e is formed on (e.g., directly formed on) the fifth fin 210e, and the sixth nanostructure stack 1302f is formed on (e.g., directly formed on) the sixth fin 210f. In some embodiments, the nanostructure stack 1302 is formed after removing the first hard mask structure 202.

奈米結構堆疊1302橫向分開(沿著z軸)。介電鰭狀物502可橫向分開(沿著z軸)奈米結構堆疊1302。換言之,奈米結構堆疊1302位於介電鰭狀物502的兩側上。舉例來說,第一奈米結構堆疊1302a位於第一介電鰭狀物502a的第一側上,而第二奈米結構堆疊1302b位於第一介電鰭狀物502a的第二側(與第一側相對)上。 The nanostructure stack 1302 is separated laterally (along the z-axis). The dielectric fin 502 can separate the nanostructure stack 1302 laterally (along the z-axis). In other words, the nanostructure stack 1302 is located on both sides of the dielectric fin 502. For example, the first nanostructure stack 1302a is located on the first side of the first dielectric fin 502a, and the second nanostructure stack 1302b is located on the second side (opposite to the first side) of the first dielectric fin 502a.

奈米結構堆疊1302的每一者包括多個奈米結構1304彼此垂直堆疊(沿著y軸),比如一者直接位於另一者上。奈米結構1304橫向延伸(沿著x軸)於鰭狀物210上並彼此平行。每一奈米結構堆疊1302的奈米結構1304延伸(沿著x軸)於對應的一對源極/汲極區之間。舉例來說,第一奈米結構堆疊1302a的奈米結構1304延伸(沿著x軸)於第一對902a的第一源極/汲極區902之間(見圖11),第二奈米 結構堆疊1302b的奈米結構1304延伸(沿著x軸)於第二對902b的第一源極/汲極區902之間(見圖11),第三奈米結構堆疊1302c的奈米結構1304延伸(沿著x軸)於第三對904a的第二源極/汲極區904之間(見圖11),第四奈米結構堆疊1302d的奈米結構1304延伸(沿著x軸)於第四對904b的第二源極/汲極區904之間(見圖11),第五奈米結構堆疊1302e的奈米結構1304延伸(沿著x軸)於第五對902c的第一源極/汲極區902之間(見圖11),且第六奈米結構堆疊1302f的奈米結構1304延伸(沿著x軸)於第六對902d的第一源極/汲極區902之間(見圖11)。 Each of the nanostructure stacks 1302 includes a plurality of nanostructures 1304 stacked vertically (along the y-axis), such as one directly on top of another. The nanostructures 1304 extend laterally (along the x-axis) on the fins 210 and are parallel to each other. The nanostructures 1304 of each nanostructure stack 1302 extend (along the x-axis) between a corresponding pair of source/drain regions. For example, the nanostructure 1304 of the first nanostructure stack 1302a extends (along the x-axis) between the first source/drain regions 902 of the first pair 902a (see FIG. 11 ), the nanostructure 1304 of the second nanostructure stack 1302b extends (along the x-axis) between the first source/drain regions 902 of the second pair 902b (see FIG. 11 ), and the nanostructure 1304 of the third nanostructure stack 1302c extends (along the x-axis) between the second source/drain regions 904 of the third pair 904a (see FIG. 11 ). ), the nanostructure 1304 of the fourth nanostructure stack 1302d extends (along the x-axis) between the second source/drain regions 904 of the fourth pair 904b (see FIG. 11 ), the nanostructure 1304 of the fifth nanostructure stack 1302e extends (along the x-axis) between the first source/drain regions 902 of the fifth pair 902c (see FIG. 11 ), and the nanostructure 1304 of the sixth nanostructure stack 1302f extends (along the x-axis) between the first source/drain regions 902 of the sixth pair 902d (see FIG. 11 ).

在一些實施例中,奈米結構堆疊1302分別與鰭狀物210分開(沿著y軸)。在一些實施例中,奈米結構堆疊1302的奈米結構1304垂直分開(沿著y軸)。舉例來說,第一奈米結構堆疊1302a與第一鰭狀物210a的上表面分開(沿著y軸),且第一奈米結構堆疊1302a的奈米結構1304彼此垂直分開(沿著y軸)。 In some embodiments, the nanostructure stacks 1302 are separated from the fins 210 (along the y-axis). In some embodiments, the nanostructures 1304 of the nanostructure stacks 1302 are separated vertically (along the y-axis). For example, the first nanostructure stack 1302a is separated from the upper surface of the first fin 210a (along the y-axis), and the nanostructures 1304 of the first nanostructure stack 1302a are separated vertically (along the y-axis) from each other.

在一些實施例中,奈米結構1304可具有矩形輪廓,如圖13所示。在其他實施例中,奈米結構1304可具有方形輪廓、卵形輪廓、體育場形(如長圓形)輪廓、六角形輪廓(比如垂直分開的六角形輪廓或合併的六角形輪廓)、一些其他幾何形狀的輪廓、或上述之組合。若奈米結構1304具有方形輪廓,奈米結構1304可視作方形奈米線。若奈米結構1304具有卵形輪廓,則奈米結構1304可視作奈米環。若奈米結構1304具有六角形輪廓或體育場形輪廓,奈米結構1304可視作水平奈米片或水平奈米平板。若奈米結構1304具有六角形輪廓,奈米結構1304可視作六角奈米線。 In some embodiments, nanostructure 1304 may have a rectangular profile, as shown in FIG. 13. In other embodiments, nanostructure 1304 may have a square profile, an oval profile, a stadium-shaped (e.g., oblong) profile, a hexagonal profile (e.g., a vertically separated hexagonal profile or a merged hexagonal profile), some other geometric profile, or a combination thereof. If nanostructure 1304 has a square profile, nanostructure 1304 may be considered a square nanowire. If nanostructure 1304 has an oval profile, nanostructure 1304 may be considered a nanoring. If nanostructure 1304 has a hexagonal profile or a stadium-shaped profile, nanostructure 1304 may be considered a horizontal nanosheet or a horizontal nanoplate. If the nanostructure 1304 has a hexagonal outline, the nanostructure 1304 can be regarded as a hexagonal nanowire.

在一些實施例中,形成奈米結構堆疊1302的製程,包括移除第三溝槽1102(比如延伸的第三溝槽1102)所露出的第三半導體結構706與蓋結構404。藉由移除第三半導體結構706與蓋結構404,可釋放第四半導體結構708以形成奈米結構1304。換言之,在移除第三半導體結構706與蓋結構404之後,可分別保留第四半導體結構708的部分作為奈米結構1304。 In some embodiments, the process of forming the nanostructure stack 1302 includes removing the third semiconductor structure 706 and the capping structure 404 exposed by the third trench 1102 (such as the extended third trench 1102). By removing the third semiconductor structure 706 and the capping structure 404, the fourth semiconductor structure 708 can be released to form the nanostructure 1304. In other words, after removing the third semiconductor structure 706 and the capping structure 404, portions of the fourth semiconductor structure 708 can be retained as the nanostructure 1304.

可由第十七蝕刻製程(如濕蝕刻製程、乾蝕刻製程、或類似製程)移除第三半導體結構706與蓋結構404。由於第三半導體結構706與蓋結構404包括相同半導體材料(比如第一半導體材料如矽鍺),第十七蝕刻製程可選擇性移除第三半導體結構706與蓋結構404,以形成奈米結構1304。在一些實施例中,第十七蝕刻製程可選擇性移除第三半導體結構706與蓋結構404,其可採用濕蝕刻劑如氫氧化銨、氫氧化四甲基銨溶液、乙二胺鄰苯二酚、氫氧化鉀溶液、或類似物。在其他實施例中,第十七蝕刻製程可稍微蝕刻第四半導體結構708的半導體材料(比如第二半導體材料如矽),使奈米結構1304的剖面面積稍微小於第四半導體結構708的剖面面積。應理解的是,第十七蝕刻製程可能不釋放奈米結構1304的一些部分(比如直接位於第一側壁間隔物702之下的部分,見圖11)。相反地,第二側壁間隔物802圍繞奈米結構1304的這些部分(見圖11)。 The third semiconductor structure 706 and the capping structure 404 may be removed by a seventeenth etching process (such as a wet etching process, a dry etching process, or the like). Since the third semiconductor structure 706 and the capping structure 404 include the same semiconductor material (such as the first semiconductor material such as silicon germanium), the seventeenth etching process may selectively remove the third semiconductor structure 706 and the capping structure 404 to form the nanostructure 1304. In some embodiments, the seventeenth etching process may selectively remove the third semiconductor structure 706 and the capping structure 404, and a wet etching agent such as ammonium hydroxide, tetramethylammonium hydroxide solution, ethylenediamine catechol, potassium hydroxide solution, or the like may be used. In other embodiments, the seventeenth etching process may slightly etch the semiconductor material (e.g., the second semiconductor material such as silicon) of the fourth semiconductor structure 708, so that the cross-sectional area of the nanostructure 1304 is slightly smaller than the cross-sectional area of the fourth semiconductor structure 708. It should be understood that the seventeenth etching process may not release some portions of the nanostructure 1304 (e.g., the portion directly under the first sidewall spacer 702, see FIG. 11). Instead, the second sidewall spacer 802 surrounds these portions of the nanostructure 1304 (see FIG. 11).

如圖14所示,形成界面層1402於每一奈米結構1304周圍。舉例來說,界面層1402可為氧化物(如氧化矽)、氮化物(如氮化矽)、氮氧化物(如氮氧化矽)、一些其他介電材料、或上述之組合。在一些實施例中,形成界面層1402的製程包括沉積或成長界面層1402於奈米結構1304的表面(如外側側壁)上,且沉積或成長的方法可為化學氣相沉積、物理氣相沉積、原子層沉積、熱氧化、一些其他沉積或成長製程、或上述之組合。在其他實施例中,界面層1402為熱氧化製程所成長的氧化物,因此界面層1402不形成於介電鰭狀物502或保留的介電結構704b/704d上。雖然未圖示於圖14中,但應理解一些實施例亦可形成界面層1402於鰭狀物210的上表面與襯墊層302的上表面上,比如熱氧化製程可成長界面層1402於鰭狀物210的上表面與襯墊層302的上表面上。 As shown in FIG. 14 , an interface layer 1402 is formed around each nanostructure 1304. For example, the interface layer 1402 may be an oxide (e.g., silicon oxide), a nitride (e.g., silicon nitride), an oxynitride (e.g., silicon oxynitride), some other dielectric material, or a combination thereof. In some embodiments, the process of forming the interface layer 1402 includes depositing or growing the interface layer 1402 on a surface (e.g., an outer sidewall) of the nanostructure 1304, and the deposition or growth method may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, thermal oxidation, some other deposition or growth process, or a combination thereof. In other embodiments, the interface layer 1402 is an oxide grown by a thermal oxidation process, so the interface layer 1402 is not formed on the dielectric fin 502 or the retained dielectric structure 704b/704d. Although not shown in FIG. 14, it should be understood that some embodiments may also form the interface layer 1402 on the upper surface of the fin 210 and the upper surface of the pad layer 302, such as the thermal oxidation process may grow the interface layer 1402 on the upper surface of the fin 210 and the upper surface of the pad layer 302.

如圖14所示,閘極介電層1404形成於每一奈米結構1304周圍。閘極介電層1404亦形成於界面層1402周圍、鰭狀物210上、襯墊層302上、介電鰭狀物502上、保留的介電結構704b/704d上、與隔離結構402上。閘極介電層1404 可為或包括高介電常數的介電層如氧化鉿、氧化鋯、鋁酸鉿、矽酸鉿、一些介電常數大於3.9的其他介電材料、或上述之組合。 As shown in FIG. 14 , a gate dielectric layer 1404 is formed around each nanostructure 1304. The gate dielectric layer 1404 is also formed around the interface layer 1402, on the fin 210, on the liner layer 302, on the dielectric fin 502, on the retained dielectric structure 704b/704d, and on the isolation structure 402. The gate dielectric layer 1404 can be or include a high dielectric constant dielectric layer such as bismuth oxide, zirconia, bismuth aluminum oxide, bismuth silicate, some other dielectric materials with a dielectric constant greater than 3.9, or a combination thereof.

在形成界面層1402之後形成閘極介電層1404。在一些實施例中,形成閘極介電層1404的製程可包含沉積閘極介電層1404於界面層1402、鰭狀物210、襯墊層302、介電鰭狀物502、保留的介電結構704b/704d、與隔離結構402的表面上,如圖14所示。舉例來說,閘極介電層1404的沉積方法可為原子層沉積、化學氣相沉積、物理氣相沉積、一些其他沉積製程、或上述之組合。在其他實施例中,可形成閘極介電層1404如順應層。 The gate dielectric layer 1404 is formed after forming the interface layer 1402. In some embodiments, the process of forming the gate dielectric layer 1404 may include depositing the gate dielectric layer 1404 on the interface layer 1402, the fin 210, the liner layer 302, the dielectric fin 502, the remaining dielectric structure 704b/704d, and the surface of the isolation structure 402, as shown in Figure 14. For example, the deposition method of the gate dielectric layer 1404 may be atomic layer deposition, chemical vapor deposition, physical vapor deposition, some other deposition process, or a combination thereof. In other embodiments, a gate dielectric layer 1404 may be formed as a compliant layer.

如圖14所示,閘極層1406形成於閘極介電層1404、鰭狀物210、襯墊層302、介電鰭狀物502、保留的介電結構704b/704d、隔離結構402、與奈米結構堆疊1302上。在一些實施例中,閘極層1406亦形成於每一奈米結構1304周圍與之間,如圖14所示。 As shown in FIG. 14 , a gate layer 1406 is formed on the gate dielectric layer 1404, the fin 210, the liner layer 302, the dielectric fin 502, the retained dielectric structure 704b/704d, the isolation structure 402, and the nanostructure stack 1302. In some embodiments, the gate layer 1406 is also formed around and between each nanostructure 1304, as shown in FIG. 14 .

在一些實施例中,形成閘極層1406的製程包括沉積閘極材料於第三溝槽1102(比如延伸的第三溝槽1102)中、閘極介電層1404上、鰭狀物210上、襯墊層302上、介電鰭狀物502上、保留的介電結構704b/704d上、隔離結構402上、奈米結構堆疊1302上、以及每一奈米結構1304周圍與之間。閘極材料亦沉積於層間介電層1004、第一側壁間隔物702、與第一蝕刻停止層1002上(見圖11)。舉例來說,閘極材料可為或包括多晶矽(如摻雜多晶矽)、金屬(如鋁、鎢、或類似物)、氮化鈦、氮化鉭、碳化鈦鋁、鈦鋁矽化物、一些其他導電材料、或上述之組合。閘極材材料可包含多層閘極材料,比如功函數層(如氮化鈦、氮化鉭、或類似物)、金屬填充層(如鎢)、與類似物。 In some embodiments, the process of forming the gate layer 1406 includes depositing a gate material in the third trench 1102 (e.g., the extended third trench 1102), on the gate dielectric layer 1404, on the fin 210, on the liner layer 302, on the dielectric fin 502, on the remaining dielectric structure 704b/704d, on the isolation structure 402, on the nanostructure stack 1302, and around and between each nanostructure 1304. The gate material is also deposited on the interlayer dielectric layer 1004, the first sidewall spacer 702, and the first etch stop layer 1002 (see FIG. 11). For example, the gate material may be or include polysilicon (such as doped polysilicon), a metal (such as aluminum, tungsten, or the like), titanium nitride, tantalum nitride, titanium aluminum carbide, titanium aluminum silicide, some other conductive material, or a combination thereof. The gate material may include multiple layers of gate material, such as a work function layer (such as titanium nitride, tantalum nitride, or the like), a metal fill layer (such as tungsten), and the like.

舉例來說,閘極材料的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、電化學鍍、無電鍍、一些其他沉積製程、或上述之組合。在沉積閘極材料之後,可在閘極材料上進行平坦化製程如化學機械研磨以移除閘 極材料的上側部分,進而保留閘極材料的下側部分作為閘極層1406。舉例來說,閘極層1406可為或包括多晶矽(如摻雜多晶矽)、金屬(如鋁、鎢、或類似物)、氮化鈦、氮化鉭、碳化鈦鋁、鈦鋁矽化物、一些其他導電材料、或上述之組合。閘極層1406可包含多層,比如功函數層(如氮化鈦、氮化鉭、或類似物)、金屬填充層(如鎢)、與類似物。平坦化製程亦可移除層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上側部分,使閘極層1406、層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上表面共平面。 For example, the gate material may be deposited by chemical vapor deposition, physical vapor deposition, atomic layer deposition, electrochemical plating, electroless plating, some other deposition process, or a combination thereof. After the gate material is deposited, a planarization process such as chemical mechanical polishing may be performed on the gate material to remove the upper portion of the gate material, thereby retaining the lower portion of the gate material as the gate layer 1406. For example, the gate layer 1406 may be or include polysilicon (e.g., doped polysilicon), a metal (e.g., aluminum, tungsten, or the like), titanium nitride, tantalum nitride, titanium aluminum carbide, titanium aluminum silicide, some other conductive material, or a combination thereof. The gate layer 1406 may include multiple layers, such as a work function layer (e.g., titanium nitride, tantalum nitride, or the like), a metal fill layer (e.g., tungsten), and the like. The planarization process can also remove the interlayer dielectric layer 1004, the first etch stop layer 1002, and the upper portion of the first sidewall spacer 702, so that the gate layer 1406, the interlayer dielectric layer 1004, the first etch stop layer 1002, and the upper surface of the first sidewall spacer 702 are coplanar.

如圖15所示,形成多個閘極結構1502於鰭狀物210、襯墊層302、介電鰭狀物502、隔離結構402、與奈米結構堆疊1302上。對應的介電鰭狀物502與對應的保留的介電結構704b/704d橫向分開(沿著z軸)閘極結構1502。閘極結構1502的上表面低於保留的介電結構704b/704d的上表面。在一些實施例中,閘極結構1502的上表面低於第一側壁間隔物702的下表面(見圖11)。閘極結構1502形成於對應多對源極/汲極區之一或多者的源極/汲極區之間。在一些實施例中,閘極結構1502形成於一或多個對應的奈米結構堆疊1302之每一奈米結構1304周圍。 As shown in FIG15 , a plurality of gate structures 1502 are formed on the fins 210, the liner layer 302, the dielectric fins 502, the isolation structures 402, and the nanostructure stack 1302. The corresponding dielectric fins 502 and the corresponding retained dielectric structures 704b/704d are laterally separated (along the z-axis) from the gate structures 1502. The upper surface of the gate structure 1502 is lower than the upper surface of the retained dielectric structures 704b/704d. In some embodiments, the upper surface of the gate structure 1502 is lower than the lower surface of the first sidewall spacer 702 (see FIG11 ). The gate structure 1502 is formed between source/drain regions of one or more of the corresponding pairs of source/drain regions. In some embodiments, the gate structure 1502 is formed around each nanostructure 1304 of one or more corresponding nanostructure stacks 1302.

舉例來說,形成第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c。第二介電結構704b與第二介電鰭狀物502b均橫向分開(沿著z軸)第一閘極結構1502a與第二閘極結構1502b,且第四介電結構704d與第四介電鰭狀物502d均橫向分開(沿著z軸)第二閘極結構1502b與第三閘極結構1502c。第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c的上表面低於第二介電結構704b的上表面與第四介電結構704d的上表面。 For example, a first gate structure 1502a, a second gate structure 1502b, and a third gate structure 1502c are formed. The second dielectric structure 704b and the second dielectric fin 502b both laterally separate (along the z-axis) the first gate structure 1502a and the second gate structure 1502b, and the fourth dielectric structure 704d and the fourth dielectric fin 502d both laterally separate (along the z-axis) the second gate structure 1502b and the third gate structure 1502c. The upper surfaces of the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c are lower than the upper surfaces of the second dielectric structure 704b and the fourth dielectric structure 704d.

第一閘極結構1502a形成於第一對902a的第一源極/汲極區902之間,以及第二對902b的第一源極/汲極區902之間(見圖11)。第二閘極結構1502b形成於第三對904a的第二源極/汲極區904之間,以及第四對904b的第二源極/汲 極區904之間(見圖11)。第三閘極結構1502c形成於第五對902c的第一源極/汲極區902之間,以及第六對902d的第一源極/汲極區902之間(見圖11)。在一些實施例中,第一閘極結構1502a的上表面,低於延伸(沿著z軸)於第一對902a與第二對902b的第一源極/汲極區902之間的第一側壁間隔物702之一者的下表面。在其他實施例中,第二閘極結構1502b及/或第三閘極結構1502c的上表面,低於第一側壁間隔物702之一者的下表面。 The first gate structure 1502a is formed between the first source/drain regions 902 of the first pair 902a and between the first source/drain regions 902 of the second pair 902b (see FIG. 11). The second gate structure 1502b is formed between the second source/drain regions 904 of the third pair 904a and between the second source/drain regions 904 of the fourth pair 904b (see FIG. 11). The third gate structure 1502c is formed between the first source/drain regions 902 of the fifth pair 902c and between the first source/drain regions 902 of the sixth pair 902d (see FIG. 11). In some embodiments, the upper surface of the first gate structure 1502a is lower than the lower surface of one of the first sidewall spacers 702 extending (along the z-axis) between the first source/drain regions 902 of the first pair 902a and the second pair 902b. In other embodiments, the upper surface of the second gate structure 1502b and/or the third gate structure 1502c is lower than the lower surface of one of the first sidewall spacers 702.

第一閘極結構1502a圍繞第一奈米結構堆疊1302a的每一奈米結構1304與第二奈米結構堆疊1302b的每一奈米結構1304。第二閘極結構1502b圍繞第三奈米結構堆疊1302c的每一奈米結構1304與第四奈米結構堆疊1302d的每一奈米結構1304。第三閘極結構1502c圍繞第五奈米結構堆疊1302e的每一奈米結構1304與第六奈米結構堆疊1302f的每一奈米結構1304。 The first gate structure 1502a surrounds each nanostructure 1304 of the first nanostructure stack 1302a and each nanostructure 1304 of the second nanostructure stack 1302b. The second gate structure 1502b surrounds each nanostructure 1304 of the third nanostructure stack 1302c and each nanostructure 1304 of the fourth nanostructure stack 1302d. The third gate structure 1502c surrounds each nanostructure 1304 of the fifth nanostructure stack 1302e and each nanostructure 1304 of the sixth nanostructure stack 1302f.

應理解的是,第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c可圍繞任何數目的奈米結構堆疊1302的每一奈米結構1304,端視半導體裝置1904的預期功能而定。舉例來說,第一閘極結構1502a可形成於一個奈米結構堆疊1302之每一奈米結構1304周圍、形成於兩個奈米結構堆疊1302的每一奈米結構1304周圍(如圖15所示)、形成於三個奈米結構堆疊1302的每一奈米結構1304周圍、或形成於任何其他數目的奈米結構堆疊1302的每一奈米結構1304周圍。應理解的是,第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c可形成於相同數目的奈米結構堆疊1302(比如圖15所示的兩個奈米結構堆疊)之每一奈米結構1304周圍,或者第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c可形成於不同數目的奈米結構堆疊1302之每一奈米結構1304周圍。應理解的是,閘極結構1502形成於其周圍的奈米結構堆疊1302的數目,取決於第一遮罩結構1104的圖案(見圖12)。 It should be understood that the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c may surround each nanostructure 1304 of any number of nanostructure stacks 1302, depending on the intended function of the semiconductor device 1904. For example, the first gate structure 1502a may be formed around each nanostructure 1304 of one nanostructure stack 1302, around each nanostructure 1304 of two nanostructure stacks 1302 (as shown in FIG. 15 ), around each nanostructure 1304 of three nanostructure stacks 1302, or around each nanostructure 1304 of any other number of nanostructure stacks 1302. It should be understood that the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c can be formed around each nanostructure 1304 of the same number of nanostructure stacks 1302 (such as the two nanostructure stacks shown in FIG. 15), or the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c can be formed around each nanostructure 1304 of different numbers of nanostructure stacks 1302. It should be understood that the number of nanostructure stacks 1302 around which the gate structure 1502 is formed depends on the pattern of the first mask structure 1104 (see FIG. 12).

在一些實施例中,形成閘極結構1502的製程包括使閘極層1406(見 圖14)凹陷至低於保留的介電結構704b/704d的上表面。舉例來說,使閘極層1406凹陷的方法可為蝕刻製程(比如濕蝕刻製程、乾蝕刻製程、或類似製程),其對閘極層1406具有選擇性(比如移除閘極層1406的材料而實質上不攻擊閘極介電層1404)。 In some embodiments, the process of forming the gate structure 1502 includes recessing the gate layer 1406 (see FIG. 14 ) to below the upper surface of the retained dielectric structure 704b/704d. For example, the method of recessing the gate layer 1406 may be an etching process (such as a wet etching process, a dry etching process, or the like) that is selective to the gate layer 1406 (such as removing material of the gate layer 1406 without substantially attacking the gate dielectric layer 1404).

在使閘極層1406凹陷之後,保留閘極層的分開下側部分作為閘極結構1502。舉例來說,在使閘極層1406凹陷之後,第二介電結構704b與第四介電結構704d分開閘極層1406的三個下側部分,因此以自對準的方式形成第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c。 After the gate layer 1406 is recessed, the separated lower side portions of the gate layer are retained as the gate structure 1502. For example, after the gate layer 1406 is recessed, the second dielectric structure 704b and the fourth dielectric structure 704d separate the three lower side portions of the gate layer 1406, thereby forming the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c in a self-aligned manner.

由於以自對準方式形成閘極結構1502,此處所述的方法比參考切割金屬閘極製程提供更多優點。參考切割金屬閘極製程包括在此製程階段中形成開口於閘極層1406中,並將介電材料填入這些開口,以切割閘極層1406成閘極結構1502。隨著結構尺寸持續縮小(比如3nm或更小),參考的切割金屬閘極製程會因開口的高深寬比而難以填入開口。不適當地填入開口會造成閘極結構1502之間的電性短路,並可能造成裝置失效。此處提供的改良方法以自對準的方式形成閘極結構1502,因此避免裝置失效並改善產能。 The method described herein provides advantages over the reference cut metal gate process due to the self-aligned formation of the gate structure 1502. The reference cut metal gate process includes forming openings in the gate layer 1406 at this stage of the process and filling the openings with dielectric material to cut the gate layer 1406 into the gate structure 1502. As the structure size continues to shrink (e.g., 3nm or less), the reference cut metal gate process may have difficulty filling the openings due to the high aspect ratio of the openings. Improper filling of the openings may cause electrical shorts between the gate structures 1502 and may cause device failure. The improved method provided herein forms the gate structure 1502 in a self-aligned manner, thereby avoiding device failure and improving production capacity.

如圖15所示,第二蝕刻停止層1504形成於(如直接形成於)閘極結構1502上。在形成閘極結構1502之後,形成第二蝕刻停止層1504。第二蝕刻停止層1504的上表面可低於保留的介電結構704b/704d的上表面。在一些實施例中,第二蝕刻停止層1504的上表面低於第一側壁間隔物702的下表面(見圖11)。在其他實施例中,第二蝕刻停止層1504可為無氟鎢層。第二蝕刻停止層1504可作為後續蝕刻製程中的蝕刻停止層,及/或有助於減少閘極結構1502與後續形成的導電接點(比如電性耦接至閘極結構1502的金屬接點)之間的電阻。 As shown in FIG. 15 , a second etch stop layer 1504 is formed on (e.g., directly on) the gate structure 1502. After the gate structure 1502 is formed, the second etch stop layer 1504 is formed. The upper surface of the second etch stop layer 1504 may be lower than the upper surface of the remaining dielectric structure 704b/704d. In some embodiments, the upper surface of the second etch stop layer 1504 is lower than the lower surface of the first sidewall spacer 702 (see FIG. 11 ). In other embodiments, the second etch stop layer 1504 may be a fluorine-free tungsten layer. The second etch stop layer 1504 may serve as an etch stop layer in a subsequent etching process and/or help reduce the resistance between the gate structure 1502 and a subsequently formed conductive contact (e.g., a metal contact electrically coupled to the gate structure 1502).

在一些實施例中,形成第二蝕刻停止層1504的製程包括沉積第二蝕刻停止層1504於閘極結構1502上,且沉積方法可為化學氣相沉積、物理氣相 沉積、原子層沉積、電化學鍍、無電鍍、一些其他沉積製程、或上述之組合。第二蝕刻停止層1504可由選擇性化學氣相沉積製程,選擇性地沉積於閘極結構1502上。在形成閘極結構1502之後沉積第二蝕刻停止層1504。此外,第二蝕刻停止層1504沉積於形成閘極結構1502的步驟(比如使閘極層1406凹陷)所產生的溝槽(未標示)中。形成閘極結構1502所形成的溝槽,垂直延伸於第一側壁間隔物702的內側側壁之間、延伸至閘極結構1502的上表面、以及延伸至閘極介電層1404的表面(如上表面與側壁,其高於閘極結構1502的上表面)。 In some embodiments, the process of forming the second etch stop layer 1504 includes depositing the second etch stop layer 1504 on the gate structure 1502, and the deposition method may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, electrochemical plating, electroless plating, some other deposition process, or a combination thereof. The second etch stop layer 1504 may be selectively deposited on the gate structure 1502 by a selective chemical vapor deposition process. The second etch stop layer 1504 is deposited after the gate structure 1502 is formed. In addition, the second etch stop layer 1504 is deposited in the trench (not shown) produced by the step of forming the gate structure 1502 (e.g., recessing the gate layer 1406). The trench formed by forming the gate structure 1502 extends vertically between the inner sidewalls of the first sidewall spacer 702, extends to the upper surface of the gate structure 1502, and extends to the surface of the gate dielectric layer 1404 (e.g., the upper surface and the sidewalls, which are higher than the upper surface of the gate structure 1502).

如圖15所示,第四介電層1506形成於(如直接形成於)保留的介電結構704b/704d、閘極介電層1404、閘極結構1502、介電鰭狀物502、與第二蝕刻停止層1504上。在形成第二蝕刻停止層1504之後,形成第四介電層1506。第四介電層1506垂直延伸(沿著y軸)於第一側壁間隔物702的內側側壁之間、延伸至第二蝕刻停止層1504的上表面、以及延伸至閘極介電層1404的表面(其高於第二蝕刻停止層1504的上表面)。換言之,形成第四介電層1506於形成閘極結構1502時所形成的溝槽之其餘部分中(比如第二蝕刻停止層1504未填入的溝槽部分)。形成第四介電層1506,使第二介電結構704b的上表面與第四介電結構704d的上表面介於第四介電層1506的最上側表面與最下側表面之間,如圖15所示。在一些實施例中,第四介電層1506的最上側表面實質上平坦。 15 , a fourth dielectric layer 1506 is formed on (e.g., directly on) the remaining dielectric structures 704b/704d, the gate dielectric layer 1404, the gate structure 1502, the dielectric fin 502, and the second etch stop layer 1504. The fourth dielectric layer 1506 is formed after the second etch stop layer 1504 is formed. The fourth dielectric layer 1506 extends vertically (along the y-axis) between the inner sidewalls of the first sidewall spacers 702, to the upper surface of the second etch stop layer 1504, and to the surface of the gate dielectric layer 1404 (which is higher than the upper surface of the second etch stop layer 1504). In other words, the fourth dielectric layer 1506 is formed in the remaining portion of the trench formed when the gate structure 1502 is formed (such as the portion of the trench not filled by the second etch stop layer 1504). The fourth dielectric layer 1506 is formed so that the upper surface of the second dielectric structure 704b and the upper surface of the fourth dielectric structure 704d are between the uppermost surface and the lowermost surface of the fourth dielectric layer 1506, as shown in FIG. 15. In some embodiments, the uppermost surface of the fourth dielectric layer 1506 is substantially flat.

在一些實施例中,形成第四介電層1506的製程包括沉積第三介電材料於保留的介電結構704b/704d、閘極介電層1404、閘極結構1502、介電鰭狀物502、第二蝕刻停止層1504、第一側壁間隔物702、第一蝕刻停止層1002、與層間介電層1004上。換言之,第三介電材料沉積於第一側壁間隔物702的上表面、第一蝕刻停止層1002的上表面、與層間介電層1004的上表面上(見圖11),並填入形成閘極結構1502時所形成的溝槽之其餘部分(比如第二蝕刻停止層1504未填入的溝槽部分)。舉例來說,第三介電材料可為或包括氮化物(如氮化矽)、碳 氮化物(如碳氮化矽)、碳氮氧化矽、氮氧化物(如氮氧化矽)、金屬氧化物(如氧化鋁、氧化鉿、氧化鋯、或氧化釔)、氧化物(如氧化矽)、一些其他介電材料、或上述之組合。第三介電材料與層間介電層1004具有不同的化學組成,因此在後續製程步驟時(比如在形成源極/汲極接點時)可選擇性蝕刻層間介電層1004。 In some embodiments, the process of forming the fourth dielectric layer 1506 includes depositing a third dielectric material on the remaining dielectric structures 704b/704d, the gate dielectric layer 1404, the gate structure 1502, the dielectric fin 502, the second etch stop layer 1504, the first sidewall spacer 702, the first etch stop layer 1002, and the interlayer dielectric layer 1004. In other words, the third dielectric material is deposited on the upper surface of the first sidewall spacer 702, the upper surface of the first etch stop layer 1002, and the upper surface of the interlayer dielectric layer 1004 (see FIG. 11 ), and fills the remaining portion of the trench formed when forming the gate structure 1502 (e.g., the portion of the trench not filled by the second etch stop layer 1504). For example, the third dielectric material may be or include nitride (e.g., silicon nitride), carbonitride (e.g., silicon carbonitride), silicon oxycarbonitride, oxynitride (e.g., silicon oxynitride), metal oxide (e.g., aluminum oxide, yttrium oxide, zirconium oxide, or yttrium oxide), oxide (e.g., silicon oxide), some other dielectric material, or a combination thereof. The third dielectric material has a different chemical composition from the interlayer dielectric layer 1004, so the interlayer dielectric layer 1004 can be selectively etched in subsequent process steps (such as when forming source/drain contacts).

舉例來說,第三介電材料的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。在沉積第三介電材料之後,可在第三介電材料上進行平坦化製程(如化學機械研磨),以移除第三介電材料的上側部分,進而保留第三介電材料的下側部分以作為第四介電層1506。平坦化製程亦移除層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上側部分,使第四介電層1506、層間介電層1004、第一蝕刻停止層1002、與第一側壁間隔物702的上表面共平面。 For example, the deposition method of the third dielectric material may be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof. After the third dielectric material is deposited, a planarization process (such as chemical mechanical polishing) may be performed on the third dielectric material to remove the upper portion of the third dielectric material, thereby retaining the lower portion of the third dielectric material as the fourth dielectric layer 1506. The planarization process also removes the upper portion of the interlayer dielectric layer 1004, the first etch stop layer 1002, and the first sidewall spacer 702, so that the fourth dielectric layer 1506, the interlayer dielectric layer 1004, the first etch stop layer 1002, and the upper surface of the first sidewall spacer 702 are coplanar.

如圖16所示,形成第一開口1602於第四介電層1506中。第一開口1602垂直延伸(沿著y軸)於第一側壁間隔物702之一者的內側側壁與第二蝕刻停止層1504之間。第一開口1602與第二閘極結構1502b至少部分重疊。第一開口1602與第二介電結構704b及/或第四介電結構704d部分重疊。 As shown in FIG. 16 , a first opening 1602 is formed in the fourth dielectric layer 1506. The first opening 1602 extends vertically (along the y-axis) between the inner sidewall of one of the first sidewall spacers 702 and the second etch stop layer 1504. The first opening 1602 at least partially overlaps with the second gate structure 1502b. The first opening 1602 partially overlaps with the second dielectric structure 704b and/or the fourth dielectric structure 704d.

在一些實施例中,第一開口1602與第二閘極結構1502b重疊、與第二介電結構704b部分重疊、並與第四介電結構704d部分重疊。換言之,第二閘極結構1502b位於第一開口1602的側壁之間,第二介電結構704b部分地位於第一開口1602的側壁之間,且第四介電結構704d部分地位於第一開口1602的側壁之間。第一開口1602亦與第三奈米結構堆疊1302c、第四奈米結構堆疊1302d、第三介電鰭狀物502c、第三鰭狀物210c、與第四鰭狀物210d重疊。在一些實施例中,第四介電層1506的內側側壁、第一側壁間隔物702之一的內側側壁、第二蝕刻停止層1504的上表面、與閘極介電層1404的表面(如側壁與上表面),可至少部分地定義第一開口1602的表面(如側壁與下表面)。 In some embodiments, the first opening 1602 overlaps with the second gate structure 1502b, partially overlaps with the second dielectric structure 704b, and partially overlaps with the fourth dielectric structure 704d. In other words, the second gate structure 1502b is located between the sidewalls of the first opening 1602, the second dielectric structure 704b is partially located between the sidewalls of the first opening 1602, and the fourth dielectric structure 704d is partially located between the sidewalls of the first opening 1602. The first opening 1602 also overlaps with the third nanostructure stack 1302c, the fourth nanostructure stack 1302d, the third dielectric fin 502c, the third fin 210c, and the fourth fin 210d. In some embodiments, the inner sidewall of the fourth dielectric layer 1506, the inner sidewall of one of the first sidewall spacers 702, the upper surface of the second etch stop layer 1504, and the surface of the gate dielectric layer 1404 (such as the sidewall and the upper surface) may at least partially define the surface of the first opening 1602 (such as the sidewall and the lower surface).

在一些實施例中,形成第一開口1602的製程包括形成第二遮罩結構1604於第四介電層1506上。舉例來說,第二遮罩結構1604可為或包括正光組及/或負光阻材料、硬遮罩材料、上述之組合、或類似物。在其他實施例中,形成第二遮罩結構1604的製程包括沉積遮罩材料(如正光阻及/或負光阻)於第四介電層1506的上表面上。之後曝光遮罩材料至一圖案(比如經由微影製程如光微影、極紫外線微影、或類似微影)並顯影遮罩材料,以形成第二遮罩結構1604於第四介電層1506上。 In some embodiments, the process of forming the first opening 1602 includes forming a second mask structure 1604 on the fourth dielectric layer 1506. For example, the second mask structure 1604 may be or include positive photoresist and/or negative photoresist materials, hard mask materials, combinations thereof, or the like. In other embodiments, the process of forming the second mask structure 1604 includes depositing a mask material (such as positive photoresist and/or negative photoresist) on the upper surface of the fourth dielectric layer 1506. The mask material is then exposed to a pattern (for example, by a lithography process such as photolithography, extreme ultraviolet lithography, or the like) and the mask material is developed to form the second mask structure 1604 on the fourth dielectric layer 1506.

之後在第四介電層1506上進行第十八蝕刻製程,以移除第二遮罩結構1604未遮罩的第四介電層1506的部分,進而形成第一開口1602於第四介電層1506中。在一些實施例中,第十八蝕刻製程止於第二蝕刻停止層1504上。在其他實施例中,第十八蝕刻製程止於第二蝕刻停止層1504與閘極介電層1404上。第十八蝕刻製程可為乾蝕刻製程、濕蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 Then, an eighteenth etching process is performed on the fourth dielectric layer 1506 to remove the portion of the fourth dielectric layer 1506 not masked by the second mask structure 1604, thereby forming a first opening 1602 in the fourth dielectric layer 1506. In some embodiments, the eighteenth etching process stops on the second etch stop layer 1504. In other embodiments, the eighteenth etching process stops on the second etch stop layer 1504 and the gate dielectric layer 1404. The eighteenth etching process can be a dry etching process, a wet etching process, a reactive ion etching process, some other etching process, or a combination thereof.

由於第二介電結構704b位於第二介電鰭狀物502b上,且第四介電結構704d位於第四介電鰭狀物502d上,可比參考切割金屬閘極製程改善第一開口1602的蝕刻製程容許範圍。在此製程階段中,參考切割金屬閘極製程包括形成開口於閘極層1406中,並將介電材料填入開口,以切割閘極層1406成閘極結構1502。舉例來說,第二介電結構704b與第四介電結構704d使第一開口1602具有較大尺寸(由於微影的解析度限制)及/或自預先定義的位置橫向偏移(由於不良的疊對控制),但仍確保第一開口1602只與所需結構(比如第二閘極結構1502b)重疊。與此相較,若參考切割金屬閘極製程的開口(比如形成閘極層1406中並填有介電材料以形成閘極結構1502的開口)過大及/或對不準,參考切割金屬閘極製程會非預期地移除閘極層1406的部分(及/或非預期地保留閘極層1406的部分),造成裝置失效並降低產能。如此一來,隨著結構尺寸持續縮小(比如3nm或更小), 此處所述的方法可避免裝置失效並改善產能。 Since the second dielectric structure 704b is located on the second dielectric fin 502b and the fourth dielectric structure 704d is located on the fourth dielectric fin 502d, the etching process tolerance of the first opening 1602 can be improved compared to the reference cutting metal gate process. In this process stage, the reference cutting metal gate process includes forming an opening in the gate layer 1406 and filling the opening with a dielectric material to cut the gate layer 1406 into the gate structure 1502. For example, the second dielectric structure 704b and the fourth dielectric structure 704d cause the first opening 1602 to have a larger size (due to lithography resolution limitations) and/or to be laterally offset from a predefined position (due to poor overlay control), while still ensuring that the first opening 1602 only overlaps with desired structures (e.g., the second gate structure 1502b). In contrast, if the opening of the reference cut metal gate process (e.g., the opening formed in the gate layer 1406 and filled with dielectric material to form the gate structure 1502) is too large and/or misaligned, the reference cut metal gate process may unintentionally remove portions of the gate layer 1406 (and/or unintentionally retain portions of the gate layer 1406), causing device failure and reduced productivity. Thus, as the structure size continues to shrink (e.g., 3nm or less), the methods described herein can avoid device failure and improve productivity.

如圖17所示,移除(如剝除)第二遮罩結構1604。如圖17所示,移除第一開口1602所露出的第二蝕刻停止層1504的一部分,並移除第二閘極結構1502b。在一些實施例中,第十九蝕刻製程可移除第二閘極結構1502b與第一開口1602所露出的第二蝕刻停止層1504的部分。在其他實施例中,在移除第二閘極結構1502b之前,閘極結構1502可分別視作導電閘極結構(以區分存在於半導體裝置1904中的功能閘極結構,以及在形成半導體裝置1904時移除的導電閘極結構)。舉例來說,在移除第二閘極結構1502b之前,第一閘極結構1502a、第二閘極結構1502b、與第三閘極結構1502c可分別視作第一導電閘極結構、第二導電閘極結構、與第三導電閘極結構。 As shown in FIG. 17 , the second mask structure 1604 is removed (e.g., stripped). As shown in FIG. 17 , a portion of the second etch stop layer 1504 exposed by the first opening 1602 is removed, and the second gate structure 1502b is removed. In some embodiments, the nineteenth etching process may remove the second gate structure 1502b and the portion of the second etch stop layer 1504 exposed by the first opening 1602. In other embodiments, before removing the second gate structure 1502b, the gate structure 1502 may be respectively regarded as a conductive gate structure (to distinguish between a functional gate structure present in the semiconductor device 1904 and a conductive gate structure removed when the semiconductor device 1904 is formed). For example, before removing the second gate structure 1502b, the first gate structure 1502a, the second gate structure 1502b, and the third gate structure 1502c can be regarded as the first conductive gate structure, the second conductive gate structure, and the third conductive gate structure, respectively.

第十九蝕刻製程為非等向蝕刻。第十九蝕刻製程對第二蝕刻停止層1504與第二閘極結構1502b具有選擇性,因此可移除第二閘極結構1502b與第一開口1602所露出的第二蝕刻停止層1504的部分,而不移除閘極介電層1404的部分或保留的介電結構704b/704d。第十九蝕刻製程可為乾蝕刻製程、濕蝕刻製程、一些其他蝕刻製程、或上述之組合。 The nineteenth etching process is anisotropic etching. The nineteenth etching process is selective to the second etch stop layer 1504 and the second gate structure 1502b, so the second gate structure 1502b and the portion of the second etch stop layer 1504 exposed by the first opening 1602 can be removed without removing a portion of the gate dielectric layer 1404 or the retained dielectric structure 704b/704d. The nineteenth etching process can be a dry etching process, a wet etching process, some other etching process, or a combination thereof.

由於第二介電結構704b橫向分開第一閘極結構1502a與第二閘極結構1502b,且第四介電結構704d橫向分開第二閘極結構1502b與第三閘極結構1502c,因此第二介電結構704b與第四介電結構704d可做為擋牆,使第十九蝕刻製程可選擇性移除第二閘極結構1502b。換言之,由於第二介電結構704b與第四介電結構704d的位置,且延伸於閘極結構1502、第二介電結構704b、與第四介電結構704d的上表面上的第二介電結構704b與第四介電結構704d作為擋牆,可避免第十九蝕刻製程非刻意地移除第一閘極結構1502a與第三閘極結構1502c的部分。因此隨著結構尺寸持續縮小(比如3nm或更小),此處所述的方法更能避免裝置失效並改善產能。 Since the second dielectric structure 704b laterally separates the first gate structure 1502a from the second gate structure 1502b, and the fourth dielectric structure 704d laterally separates the second gate structure 1502b from the third gate structure 1502c, the second dielectric structure 704b and the fourth dielectric structure 704d can serve as a barrier, so that the nineteenth etching process can selectively remove the second gate structure 1502b. In other words, due to the location of the second dielectric structure 704b and the fourth dielectric structure 704d, and the second dielectric structure 704b and the fourth dielectric structure 704d extending on the upper surface of the gate structure 1502, the second dielectric structure 704b, and the fourth dielectric structure 704d as a barrier, the nineteenth etching process can be prevented from unintentionally removing portions of the first gate structure 1502a and the third gate structure 1502c. Therefore, as the structure size continues to shrink (e.g., 3nm or less), the method described herein can better avoid device failure and improve production capacity.

如圖18所示,第二開口1801形成於第一開口1602的邊界中(比如第一開口1602的內側側壁中),並自第一開口1602朝基板212延伸(沿著y軸)。第一開口1602與第二開口1801為自由空間的連續區域(比如任何材料的空洞)。在一些實施例中,形成第二開口1801的製程包括在圖17所示的結構上進行第二十蝕刻製程。舉例來說,第二十蝕刻製程可為濕蝕刻製程、乾蝕刻製程、反應性離子蝕刻製程、一些其他蝕刻製程、或上述之組合。 As shown in FIG. 18 , the second opening 1801 is formed in the boundary of the first opening 1602 (e.g., in the inner sidewall of the first opening 1602 ) and extends from the first opening 1602 toward the substrate 212 (along the y-axis). The first opening 1602 and the second opening 1801 are continuous regions of free space (e.g., a cavity of any material). In some embodiments, the process of forming the second opening 1801 includes performing a twentieth etching process on the structure shown in FIG. 17 . For example, the twentieth etching process may be a wet etching process, a dry etching process, a reactive ion etching process, some other etching process, or a combination thereof.

第十二蝕刻製程移除第一開口1602所露出(及/或之下)的結構(或使結構凹陷)。在一些實施例中,第十二蝕刻製程為高方向性蝕刻,其可垂直(如向下)蝕刻第一開口1602所露出(及/或之下)的結構,而不橫向(如側向)蝕刻第一開口1602所露出(及/或之下)的結構。在其他實施例中,第十二蝕刻製程對第一開口1602所露出(及/或之下)的結構具有選擇性。換言之,第十二蝕刻製程對第一開口1602所露出(及/或之下)的結構之選擇性,高於對第四介電層1506之選擇性。因此藉由在圖17所示的結構上進行第十二蝕刻製程,第十二蝕刻製程可選擇性移除(或凹陷)第一開口1602所露出(及/或之下)的結構。移除與凹陷第一開口1602所露出(及/或之下)的結構(比如藉由第十二蝕刻製程)的內容詳述如下。 The twelfth etching process removes the structure exposed by (and/or under) the first opening 1602 (or recesses the structure). In some embodiments, the twelfth etching process is a highly directional etching process, which can vertically (e.g., downwardly) etch the structure exposed by (and/or under) the first opening 1602, but does not laterally (e.g., sideways) etch the structure exposed by (and/or under) the first opening 1602. In other embodiments, the twelfth etching process is selective to the structure exposed by (and/or under) the first opening 1602. In other words, the selectivity of the twelfth etching process to the structure exposed by (and/or under) the first opening 1602 is higher than the selectivity to the fourth dielectric layer 1506. Therefore, by performing the twelfth etching process on the structure shown in FIG. 17 , the twelfth etching process can selectively remove (or recess) the structure exposed by (and/or below) the first opening 1602. The contents of removing and recessing the structure exposed by (and/or below) the first opening 1602 (for example, by the twelfth etching process) are described in detail as follows.

第十二蝕刻製程可移除(如完全移除)第一開口1602所露出(及/或下方)的第三奈米結構堆疊1302c的奈米結構1304、第四奈米結構堆疊1302d的奈米結構1304、以及界面層1402的部分。此外,第十二蝕刻製程使第三介電鰭狀物502c凹陷,進而形成凹陷的介電鰭狀物1802。凹陷的介電鰭狀物1802之上表面低於第一介電鰭狀物502a、第二介電鰭狀物502b、第四介電鰭狀物502d、與第五介電鰭狀物502e的上表面。如圖18所示,第十二蝕刻製程移除兩個奈米結構堆疊1302(比如第三奈米結構堆疊1302c與第四奈米結構堆疊1302d),但應理解第十二蝕刻製程可移除任何數目的奈米結構堆疊1302。具體而言,第十二蝕刻製程可移除約1奈米結構堆疊至約100奈米結構堆疊。 The twelfth etching process may remove (e.g., completely remove) the nanostructure 1304 of the third nanostructure stack 1302c, the nanostructure 1304 of the fourth nanostructure stack 1302d, and a portion of the interface layer 1402 exposed by (and/or below) the first opening 1602. In addition, the twelfth etching process recesses the third dielectric fin 502c to form a recessed dielectric fin 1802. The upper surface of the recessed dielectric fin 1802 is lower than the upper surfaces of the first dielectric fin 502a, the second dielectric fin 502b, the fourth dielectric fin 502d, and the fifth dielectric fin 502e. As shown in FIG. 18 , the twelfth etching process removes two nanostructure stacks 1302 (such as the third nanostructure stack 1302c and the fourth nanostructure stack 1302d), but it should be understood that the twelfth etching process can remove any number of nanostructure stacks 1302. Specifically, the twelfth etching process can remove about 1 nanostructure stack to about 100 nanostructure stacks.

第十二蝕刻製程使第三鰭狀物210c凹陷,以形成第三鰭狀物210c的凹陷部分。第十二蝕刻製程使第四鰭狀物210d凹陷,以形成第四鰭狀物210d的凹陷部分。為了清楚說明,第三鰭狀物210c的凹陷部分之後可視作第一凹陷的半導體鰭狀物1804a,且第四鰭狀物210d的凹陷部分之後可視作第二凹陷的半導體鰭狀物1804b,以更清楚的分別第三鰭狀物210c的第一凹陷的半導體鰭狀物1804a與第四鰭狀物210d的第二凹陷的半導體鰭狀物1804b。然而應理解第一凹陷的半導體鰭狀物1804a可視作第三鰭狀物210c的凹陷部分(並非所有的第三鰭狀物210c具有未凹陷的部分),且第二凹陷的半導體鰭狀物1804b可視作第四鰭狀物210d的凹陷部分(並非所有的第四鰭狀物210d具有未凹陷的部分)。 The twelfth etching process makes the third fin 210c recessed to form a recessed portion of the third fin 210c. The twelfth etching process makes the fourth fin 210d recessed to form a recessed portion of the fourth fin 210d. For the sake of clarity, the recessed portion of the third fin 210c can be regarded as the first recessed semiconductor fin 1804a, and the recessed portion of the fourth fin 210d can be regarded as the second recessed semiconductor fin 1804b, so as to more clearly distinguish the first recessed semiconductor fin 1804a of the third fin 210c and the second recessed semiconductor fin 1804b of the fourth fin 210d. However, it should be understood that the first recessed semiconductor fin 1804a can be regarded as a recessed portion of the third fin 210c (not all third fins 210c have unrecessed portions), and the second recessed semiconductor fin 1804b can be regarded as a recessed portion of the fourth fin 210d (not all fourth fins 210d have unrecessed portions).

在一些實施例中,第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面垂直地位於隔離結構402的下表面(如最下側表面)與上表面(如最上側表面)之間。在其他實施例中,第一凹陷的半導體鰭狀物1804a及/或第二凹陷的半導體鰭狀物1804b的上表面低於隔離結構402的下表面。第一凹陷的半導體鰭狀物1804a的上表面與第二凹陷的半導體鰭狀物1804b的上表面可圓潤化,如圖18所示。在這些實施例中,第一凹陷的半導體鰭狀物1804a的上表面與第二凹陷的半導體鰭狀物1804b的上表面可具有凹陷的形狀。在其他實施例中,第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面可實質上平坦。 In some embodiments, the upper surfaces of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b are vertically located between the lower surface (e.g., the lowermost surface) and the upper surface (e.g., the uppermost surface) of the isolation structure 402. In other embodiments, the upper surfaces of the first recessed semiconductor fin 1804a and/or the second recessed semiconductor fin 1804b are lower than the lower surface of the isolation structure 402. The upper surfaces of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b may be rounded, as shown in FIG. 18 . In these embodiments, the upper surface of the first recessed semiconductor fin 1804a and the upper surface of the second recessed semiconductor fin 1804b may have a recessed shape. In other embodiments, the upper surfaces of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b may be substantially flat.

第十二蝕刻製程使第一開口1602露出(及/或之下)的襯墊層302的部分凹陷。在一些實施例中,使第一開口1602露出(及/或之下)的襯墊層302的部分凹陷,因此襯墊層302的上表面實質上對準第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面。實質上對準第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面之襯墊層302的上表面可圓潤化。在一些實施例中,襯墊層302的圓潤上表面之曲率半徑,與第一凹陷的半導 體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面之曲率半徑相同。在其他實施例中,襯墊層302的圓潤上表面的曲率半徑,不同於第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b的上表面的曲率半徑。在其他實施例中,襯墊層302的圓潤上表面自第一凹陷的半導體鰭狀物1804a與第二凹陷的半導體鰭狀物1804b之實質上平坦上表面,分別弧狀地連接至對應隔離結構402的側壁。 The twelfth etching process recesses the portion of the liner layer 302 exposed by (and/or below) the first opening 1602. In some embodiments, the portion of the liner layer 302 exposed by (and/or below) the first opening 1602 is recessed, so that the upper surface of the liner layer 302 is substantially aligned with the upper surfaces of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b. The upper surface of the liner layer 302 substantially aligned with the upper surfaces of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b can be rounded. In some embodiments, the curvature radius of the rounded upper surface of the pad layer 302 is the same as the curvature radius of the upper surface of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b. In other embodiments, the curvature radius of the rounded upper surface of the pad layer 302 is different from the curvature radius of the upper surface of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b. In other embodiments, the rounded upper surface of the pad layer 302 is connected to the sidewall of the corresponding isolation structure 402 in an arc shape from the substantially flat upper surface of the first recessed semiconductor fin 1804a and the second recessed semiconductor fin 1804b.

第十二蝕刻製程移除保留的介電結構704b/704d的部分(見圖17),以形成第二多個介電結構1806。舉例來說,移除第一開口1602露出(及/或之下)的第二介電結構704b的一部分(見圖17),以保留第二介電結構704b的其餘部分作為第六介電結構1806a,其為第二多個介電結構1806的介電結構之一。此外,移除第一開口1602所露出(及/或之下)的第四介電結構704d的一部分,以保留第四介電介電結構704d的保留部分作為第七介電結構1806b,其為第二多個介電結構1806的另一介電結構。 The twelfth etching process removes the remaining portion of the dielectric structure 704b/704d (see FIG. 17 ) to form a second plurality of dielectric structures 1806. For example, a portion of the second dielectric structure 704b exposed (and/or below) by the first opening 1602 is removed (see FIG. 17 ) to retain the remaining portion of the second dielectric structure 704b as a sixth dielectric structure 1806a, which is one of the dielectric structures of the second plurality of dielectric structures 1806. In addition, a portion of the fourth dielectric structure 704d exposed (and/or below) by the first opening 1602 is removed to retain the remaining portion of the fourth dielectric structure 704d as a seventh dielectric structure 1806b, which is another dielectric structure of the second plurality of dielectric structures 1806.

在一些實施例中,第六介電結構1806a具有L形輪廓(比如沿著剖線A-A)。在其他實施例中,第七介電結構1806b具有L形輪廓(比如沿著剖線A-A)。第六介電結構1806a的L形輪廓與第七介電結構1806b的L形輪廓面對相反方向。舉例來說,第六介電結構1806a具有第一垂直部分(沿著y軸延伸)與第一橫向部分(沿著z軸延伸)。第一橫向部分在第一方向中自第一垂直部分延伸(沿著z軸)。第七介電結構1806b具有第二垂直部分(沿著y軸延伸)與第二橫向部分(沿著z軸延伸)。第二橫向部分在第二方向中自第二垂直部分延伸(沿著z軸),且第二方向與第一方向相反。 In some embodiments, the sixth dielectric structure 1806a has an L-shaped profile (e.g., along the section line A-A). In other embodiments, the seventh dielectric structure 1806b has an L-shaped profile (e.g., along the section line A-A). The L-shaped profile of the sixth dielectric structure 1806a and the L-shaped profile of the seventh dielectric structure 1806b face opposite directions. For example, the sixth dielectric structure 1806a has a first vertical portion (extending along the y-axis) and a first transverse portion (extending along the z-axis). The first transverse portion extends from the first vertical portion in a first direction (along the z-axis). The seventh dielectric structure 1806b has a second vertical portion (extending along the y-axis) and a second transverse portion (extending along the z-axis). The second transverse portion extends from the second vertical portion in a second direction (along the z-axis), and the second direction is opposite to the first direction.

第十二蝕刻製程可移除(比如完全移除)第一開口1602所露出(及/或之下)的閘極介電層1404的部分,進而形成多個閘極介電結構1808。舉例來說,移除第一開口1602所露出(及/或之下)的閘極介電層1404之部分,可保留閘極介 電層1404的第一部分作為第一閘極介電結構1808a,並保留閘極介電層1404的第二部分作為第二閘極介電結構1808b。第一閘極介電結構1808a分開第一閘極結構1502a以及第一鰭狀物210a、第二鰭狀物210b、襯墊層302、隔離結構402、第一介電鰭狀物502a、第二介電鰭狀物502b、第六介電結構1806a、第一奈米結構堆疊1302a的每一奈米結構1304、與第二奈米結構堆疊1302b的每一奈米結構1304。第一閘極介電結構1808a亦分開第六介電結構1806a以及第二蝕刻停止層1504與第四介電層1506。 The twelfth etching process may remove (e.g., completely remove) the portion of the gate dielectric layer 1404 exposed by (and/or below) the first opening 1602, thereby forming a plurality of gate dielectric structures 1808. For example, by removing the portion of the gate dielectric layer 1404 exposed by (and/or below) the first opening 1602, a first portion of the gate dielectric layer 1404 may be retained as a first gate dielectric structure 1808a, and a second portion of the gate dielectric layer 1404 may be retained as a second gate dielectric structure 1808b. The first gate dielectric structure 1808a separates the first gate structure 1502a and the first fin 210a, the second fin 210b, the liner layer 302, the isolation structure 402, the first dielectric fin 502a, the second dielectric fin 502b, the sixth dielectric structure 1806a, each nanostructure 1304 of the first nanostructure stack 1302a, and each nanostructure 1304 of the second nanostructure stack 1302b. The first gate dielectric structure 1808a also separates the sixth dielectric structure 1806a and the second etch stop layer 1504 and the fourth dielectric layer 1506.

第二閘極介電結構1808b分開第三閘極結構1502c以及第五鰭狀物210e、第六鰭狀物210f、襯墊層302、隔離結構402、第四介電鰭狀物502d、第五介電鰭狀物502e、第七介電結構1806b、第五奈米結構堆疊1302e的每一奈米結構1304、與第六奈米結構堆疊1302f的每一奈米結構1304。第二閘極介電結構1808b亦分開第七介電結構1806b以及第二蝕刻停止層1504與第四介電層1506。 The second gate dielectric structure 1808b separates the third gate structure 1502c and the fifth fin 210e, the sixth fin 210f, the liner layer 302, the isolation structure 402, the fourth dielectric fin 502d, the fifth dielectric fin 502e, the seventh dielectric structure 1806b, each nanostructure 1304 of the fifth nanostructure stack 1302e, and each nanostructure 1304 of the sixth nanostructure stack 1302f. The second gate dielectric structure 1808b also separates the seventh dielectric structure 1806b and the second etch stop layer 1504 from the fourth dielectric layer 1506.

由於第十二蝕刻製程為高方向性的蝕刻,其可垂直蝕刻第一開口1602所露出(及/或之下)的結構,且圖18所示的結構之多種表面(如側壁)可實質上對準。舉例來說,第四介電層1506的第一內側側壁實質上對準第一閘極介電結構1808a的外側側壁,且第一閘極介電結構1808a的外側側壁實質上對準第六介電結構1806a的第一側壁(比如第六介電結構1806a的第一垂直部分之側壁)。第四介電層1506的第二內側側壁(與第四介電層1506的第一內側側壁相對)實質上對準第二閘極介電結構1808b的外側側壁,且第二閘極介電結構1808b的外側側壁實質上對準第七介電結構1806b的第一側壁(比如第七介電結構1806b的第二垂直部分之側壁)。第六介電結構1806a的第二側壁(比如第六介電結構1806a的第一橫向部分之一側壁)實質上對準第二介電鰭狀物502b的外側側壁。第七介電結構1806b的第二側壁(比如第七介電結構1806b的第二橫向部分之一側壁)實質上對準第四介電鰭狀物502d的外側側壁。 Since the twelfth etching process is a highly directional etching, it can vertically etch the structure exposed by (and/or below) the first opening 1602, and various surfaces (such as sidewalls) of the structure shown in Figure 18 can be substantially aligned. For example, the first inner sidewall of the fourth dielectric layer 1506 is substantially aligned with the outer sidewall of the first gate dielectric structure 1808a, and the outer sidewall of the first gate dielectric structure 1808a is substantially aligned with the first sidewall of the sixth dielectric structure 1806a (such as the sidewall of the first vertical portion of the sixth dielectric structure 1806a). The second inner sidewall of the fourth dielectric layer 1506 (opposite to the first inner sidewall of the fourth dielectric layer 1506) is substantially aligned with the outer sidewall of the second gate dielectric structure 1808b, and the outer sidewall of the second gate dielectric structure 1808b is substantially aligned with the first sidewall of the seventh dielectric structure 1806b (e.g., the sidewall of the second vertical portion of the seventh dielectric structure 1806b). The second sidewall of the sixth dielectric structure 1806a (e.g., one sidewall of the first lateral portion of the sixth dielectric structure 1806a) is substantially aligned with the outer sidewall of the second dielectric fin 502b. The second sidewall of the seventh dielectric structure 1806b (e.g., one sidewall of the second lateral portion of the seventh dielectric structure 1806b) is substantially aligned with the outer sidewall of the fourth dielectric fin 502d.

在一些實施例中,第一閘極介電結構1808a的外側側壁、第二閘極介電結構1808b的外側側壁、第二多個介電結構1806的表面(如側壁與上表面)、第二介電鰭狀物502b的外側側壁、第四介電鰭狀物502d的外側側壁、凹陷的介電鰭狀物1802的表面(如側壁與上表面)、隔離結構402的表面(如側壁與上側表面)、襯墊層302的上表面、第一凹陷的半導體鰭狀物1804a的上表面、與第二凹陷的半導體鰭狀物1804b的上表面,可至少部分地定義第二開口1801的表面(如側壁與下表面)。在其他實施例中,由於形成第二開口的製程(比如第十二蝕刻製程)移除第一開口1602所露出(及/或之下)的結構(或使結構凹陷),形成第二開口的製程可視作延伸第一開口1602的深度(或高度)所用的製程。 In some embodiments, the outer sidewalls of the first gate dielectric structure 1808a, the outer sidewalls of the second gate dielectric structure 1808b, the surfaces (such as the sidewalls and the upper surface) of the second plurality of dielectric structures 1806, the outer sidewalls of the second dielectric fin 502b, the outer sidewalls of the fourth dielectric fin 502d, the recessed dielectric fin 1802 The surface (such as the sidewall and the upper surface) of the first opening 1601, the surface (such as the sidewall and the upper surface) of the isolation structure 402, the upper surface of the liner layer 302, the upper surface of the first recessed semiconductor fin 1804a, and the upper surface of the second recessed semiconductor fin 1804b can at least partially define the surface (such as the sidewall and the lower surface) of the second opening 1801. In other embodiments, since the process for forming the second opening (such as the twelfth etching process) removes the structure exposed (and/or below) the first opening 1602 (or recesses the structure), the process for forming the second opening can be regarded as a process for extending the depth (or height) of the first opening 1602.

如圖18所示,形成第二開口1801的步驟可形成多個奈米結構場效電晶體1810。舉例來說,形成第二開口1801的步驟可形成第一奈米結構場效電晶體1810a於第二開口1801的第一側上,並形成第二奈米結構場效電晶體1810b於第二開口1801的第二側上,且第一開口1801的第一側與第二側相對。第二開口1801橫向分開(沿著z軸)第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b。在一些實施例中,形成閘極介電結構1808的步驟完成第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b。 As shown in FIG18 , the step of forming the second opening 1801 can form a plurality of nanostructure field effect transistors 1810. For example, the step of forming the second opening 1801 can form a first nanostructure field effect transistor 1810a on a first side of the second opening 1801, and form a second nanostructure field effect transistor 1810b on a second side of the second opening 1801, and the first side and the second side of the first opening 1801 are opposite to each other. The second opening 1801 laterally separates (along the z-axis) the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b. In some embodiments, the step of forming the gate dielectric structure 1808 completes the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b.

第一奈米結構場效電晶體1810a包括第一閘極結構1502a、第一閘極介電結構1808a、第一奈米結構堆疊1302a、第二奈米結構堆疊1302b、第一對902a的第一源極/汲極區902(見圖11)、與第二對902b的第一源極/汲極區902(見圖11)。第一多個選擇性導電通道(未圖示)分別位於第一奈米結構堆疊1302a的奈米結構1304與第二奈米結構堆疊1302b的奈米結構1304中。位於第一奈米結構堆疊1302a的奈米結構1304中的選擇性導電通道,可延伸(沿著x軸)於第一對902a的第一源極/汲極區902之間。位於第二奈米結構堆疊1302b的奈米結構1304中的選擇性導電通道,可延伸(沿著x軸)於第二對902b的第一源極/汲極區902之間。除 了包含兩個奈米結構堆疊與對應的兩對第一源極/汲極區902之外,應理解第一奈米結構場效電晶體1810a可包含任何數目的奈米結構堆疊與對應的任何數目的多對第一源極/汲極區902。 The first nanostructure field effect transistor 1810a includes a first gate structure 1502a, a first gate dielectric structure 1808a, a first nanostructure stack 1302a, a second nanostructure stack 1302b, a first source/drain region 902 of a first pair 902a (see FIG. 11 ), and a first source/drain region 902 of a second pair 902b (see FIG. 11 ). A first plurality of selective conductive channels (not shown) are respectively located in the nanostructure 1304 of the first nanostructure stack 1302a and the nanostructure 1304 of the second nanostructure stack 1302b. The selective conductive channel in the nanostructure 1304 of the first nanostructure stack 1302a can extend (along the x-axis) between the first source/drain regions 902 of the first pair 902a. The selective conductive channel in the nanostructure 1304 of the second nanostructure stack 1302b can extend (along the x-axis) between the first source/drain regions 902 of the second pair 902b. In addition to including two nanostructure stacks and corresponding two pairs of first source/drain regions 902, it should be understood that the first nanostructure field effect transistor 1810a can include any number of nanostructure stacks and any number of corresponding multiple pairs of first source/drain regions 902.

第二奈米結構場效電晶體1810b包括第三閘極結構1502c、第二閘極介電結構1808b、第五奈米結構堆疊1302e、第六奈米結構堆疊1302f、第五對902c的第一源極/汲極區902(見圖11)、與第六對902d的第一源極/汲極區902(見圖11)。第二多個選擇性導電通道(為圖示)分別位於第五奈米結構堆疊1302e的奈米結構1304與第六奈米結構堆疊1302f的奈米結構1304中。位於第五奈米結構堆疊1302e的奈米結構1304中的選擇性導電通道,延伸(沿著x方向)於第五對902c的第一源極/汲極區902之間。位於第六奈米結構堆疊1302f的奈米結構1304中的選擇性導電通道,延伸(沿著x軸)於第六對902d的第一源極/汲極區902之間。除了包含兩個奈米結構堆疊與對應的兩對第一源極/汲極區902之外,應理解第二奈米結構場效電晶體1810b可包含任何數目的奈米結構堆疊與對應的任何數目的多對第一源極/汲極區902。亦應理解的是,第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b可包含相同(或不同)數目的奈米結構堆疊,與對應的多對第一源極/汲極區902。 The second nanostructure field effect transistor 1810b includes a third gate structure 1502c, a second gate dielectric structure 1808b, a fifth nanostructure stack 1302e, a sixth nanostructure stack 1302f, a first source/drain region 902 of a fifth pair 902c (see FIG. 11 ), and a first source/drain region 902 of a sixth pair 902d (see FIG. 11 ). A second plurality of selective conductive channels (not shown) are respectively located in the nanostructure 1304 of the fifth nanostructure stack 1302e and the nanostructure 1304 of the sixth nanostructure stack 1302f. The selective conductive path in the nanostructure 1304 of the fifth nanostructure stack 1302e extends (along the x-axis) between the first source/drain regions 902 of the fifth pair 902c. The selective conductive path in the nanostructure 1304 of the sixth nanostructure stack 1302f extends (along the x-axis) between the first source/drain regions 902 of the sixth pair 902d. In addition to including two nanostructure stacks and two corresponding pairs of first source/drain regions 902, it should be understood that the second nanostructure field effect transistor 1810b may include any number of nanostructure stacks and any number of corresponding pairs of first source/drain regions 902. It should also be understood that the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b may include the same (or different) number of nanostructure stacks and corresponding multiple pairs of first source/drain regions 902.

如圖19所示,第五介電層1902形成於(比如填入)第一開口1602與第二開口1801中。第五介電層1902形成於第一凹陷半導體鰭狀物1804a、第二凹陷半導體鰭狀物1804b、襯墊層302、隔離結構402、凹陷的介電鰭狀物1802、介電鰭狀物502、第二多個介電結構1806、與閘極介電結構1808上。在一些實施例中,第五介電層1902具有平坦上表面。 As shown in FIG. 19 , the fifth dielectric layer 1902 is formed in (e.g., filled into) the first opening 1602 and the second opening 1801. The fifth dielectric layer 1902 is formed on the first recessed semiconductor fin 1804a, the second recessed semiconductor fin 1804b, the liner layer 302, the isolation structure 402, the recessed dielectric fin 1802, the dielectric fin 502, the second plurality of dielectric structures 1806, and the gate dielectric structure 1808. In some embodiments, the fifth dielectric layer 1902 has a flat upper surface.

在一些實施例中,形成第五介電層1902的製程包括沉積第四介電材料於第一凹陷的半導體鰭狀物1804a、第二凹陷的半導體鰭狀物1804b、襯墊層302、隔離結構402、凹陷的介電鰭狀物1802、介電鰭狀物502、第二多個介電 結構1806、閘極介電結構1808、閘極結構1502、第二蝕刻停止層1504、第四介電層1506、第一側壁間隔物702、第一蝕刻停止層1002、與層間介電層1004上。換言之,第四介電材料形成於第四介電層1506的上表面、第一側壁間隔物702的上表面、第一蝕刻停止層1002的上表面、與層間介電層1004的上表面上(見圖11),並填入(比如完全填入)第二開口1801與第一開口1602。 In some embodiments, the process of forming the fifth dielectric layer 1902 includes depositing a fourth dielectric material on the first recessed semiconductor fin 1804a, the second recessed semiconductor fin 1804b, the liner layer 302, the isolation structure 402, the recessed dielectric fin 1802, the dielectric fin 502, the second plurality of dielectric structures 1806, the gate dielectric structure 1808, the gate structure 1502, the second etch stop layer 1504, the fourth dielectric layer 1506, the first sidewall spacer 702, the first etch stop layer 1002, and the interlayer dielectric layer 1004. In other words, the fourth dielectric material is formed on the upper surface of the fourth dielectric layer 1506, the upper surface of the first sidewall spacer 702, the upper surface of the first etch stop layer 1002, and the upper surface of the interlayer dielectric layer 1004 (see FIG. 11 ), and fills (e.g., completely fills) the second opening 1801 and the first opening 1602.

舉例來說,第四介電材料可為或包括氮化物(如氮化矽)、碳氮化矽、碳氮氧化矽、氮氧化物(如氮氧化矽)、金屬氧化物(如氧化鋁、氧化鉿、氧化鋯、或氧化釔)、氧化物(如氧化矽)、一些其他介電材料、或上述之組合。第四介電材料與層間介電層1004的化學組成不同,因此在後續製程步驟時(比如在形成源極/汲極接點時)可選擇性蝕刻層間介電層1004。在一些實施例中,第四介電材料與第三介電材料的化學組成相同,比如採用相同的介電材料。在其他實施例中,第四介電材料與第三介電材料具有不同的化學組成,比如第三介電材料與第四介電材料為不同的介電材料。 For example, the fourth dielectric material may be or include a nitride (such as silicon nitride), silicon carbonitride, silicon carbonitride oxide, nitride oxide (such as silicon oxynitride), metal oxide (such as aluminum oxide, yttrium oxide, zirconium oxide, or yttrium oxide), oxide (such as silicon oxide), some other dielectric material, or a combination thereof. The fourth dielectric material has a different chemical composition from the interlayer dielectric layer 1004, so the interlayer dielectric layer 1004 can be selectively etched in subsequent process steps (such as when forming source/drain contacts). In some embodiments, the fourth dielectric material has the same chemical composition as the third dielectric material, such as using the same dielectric material. In other embodiments, the fourth dielectric material has a different chemical composition from the third dielectric material, such as the third dielectric material and the fourth dielectric material are different dielectric materials.

舉例來說,第四介電材料的沉積方法可為化學氣相沉積、物理氣相沉積、原子層沉積、一些其他沉積製程、或上述之組合。在沉積第四介電材料之後,可在第四介電材料上進行平坦化製程如化學機械研磨以移除第四介電材料的上側部分,進而保留第四介電材料的下側部分作為第五介電層1902。平坦化製程亦可移除層間介電層1004、第一蝕刻停止層1002、第一側壁間隔物702、與第四介電層1506的上側部分,使第五介電層1902、層間介電層1004、第一蝕刻停止層1002、第一側壁間隔物702、與第四介電層1506的上表面共平面。 For example, the deposition method of the fourth dielectric material can be chemical vapor deposition, physical vapor deposition, atomic layer deposition, some other deposition process, or a combination thereof. After depositing the fourth dielectric material, a planarization process such as chemical mechanical polishing can be performed on the fourth dielectric material to remove the upper portion of the fourth dielectric material, thereby retaining the lower portion of the fourth dielectric material as the fifth dielectric layer 1902. The planarization process can also remove the interlayer dielectric layer 1004, the first etch stop layer 1002, the first sidewall spacer 702, and the upper portion of the fourth dielectric layer 1506, so that the fifth dielectric layer 1902, the interlayer dielectric layer 1004, the first etch stop layer 1002, the first sidewall spacer 702, and the upper surface of the fourth dielectric layer 1506 are coplanar.

第五介電層1902橫向分開(沿著z軸)第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b。在一些實施例中,第五介電層1902改善第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b之間的電性絕緣,進而改善裝置效能。舉例來說,隨著結構尺寸持續縮小(比如3nm或更小), 第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b之間的橫向空間(沿著z軸)會縮小,這會造成第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b的漏電流。第五介電層1902可減少漏電流,進而改善第一奈米結構場效電晶體1810a及/或第二奈米結構場效電晶體1810b的裝置效能。 The fifth dielectric layer 1902 separates the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b laterally (along the z-axis). In some embodiments, the fifth dielectric layer 1902 improves the electrical insulation between the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b, thereby improving device performance. For example, as the structure size continues to shrink (e.g., 3nm or less), the lateral space (along the z-axis) between the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b will shrink, which will cause leakage current of the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b. The fifth dielectric layer 1902 can reduce the leakage current, thereby improving the device performance of the first nanostructure field effect transistor 1810a and/or the second nanostructure field effect transistor 1810b.

由於第六介電結構1806a位於第二介電鰭狀物502b上,且第七介電結構1806b位於第四介電鰭狀物502d上,因此第五介電層1902的形成方式為自對準的方式。舉例來說,在沉積第四介電材料時,第四介電材料將自對準第六介電結構1806a的第一側壁(比如第六介電結構1806a的第一垂直部分的側壁)與第七介電結構1806b的第一側壁(比如第七介電結構1806b的第二垂直部分的側壁)。因此以自對準方式形成第五介電層1902,以自對準第五介電層(沿著z軸)。因此隨著結構尺寸持續縮小(比如3nm或更小),此處所述的方法可改善第一奈米結構場效電晶體1810a及/或第二奈米結構場效電晶體1810b的裝置效能。 Since the sixth dielectric structure 1806a is located on the second dielectric fin 502b and the seventh dielectric structure 1806b is located on the fourth dielectric fin 502d, the fifth dielectric layer 1902 is formed in a self-aligned manner. For example, when the fourth dielectric material is deposited, the fourth dielectric material will self-align the first sidewall of the sixth dielectric structure 1806a (e.g., the sidewall of the first vertical portion of the sixth dielectric structure 1806a) and the first sidewall of the seventh dielectric structure 1806b (e.g., the sidewall of the second vertical portion of the seventh dielectric structure 1806b). Therefore, the fifth dielectric layer 1902 is formed in a self-aligned manner to self-align the fifth dielectric layer (along the z-axis). Therefore, as the structure size continues to shrink (e.g., 3nm or less), the method described herein can improve the device performance of the first nanostructure field effect transistor 1810a and/or the second nanostructure field effect transistor 1810b.

雖然未圖示,但應理解內連線結構可形成於第一奈米結構場效電晶體1810a、第二奈米結構場效電晶體1810b、層間介電層1004、第四介電層1506、與第五介電層1902上,以預先定義的方式使半導體裝置1904的多種電子裝置(如第一奈米結構場效電晶體1810a、第二奈米結構場效電晶體1810b、與類似電子裝置)電性耦接在一起。舉例來說,內連線結構的形成方法可為(1)形成導電源極/汲極接點(如金屬接點)穿過層間介電層1004至第一源極/汲極區902及/或第二源極/汲極區904;(2)形成導電閘極接點(如金屬接點)穿過第四介電層1506及/或第五介電層1902至閘極結構1502;(3)形成額外層間介電層堆疊於層間介電層1004、第四介電層1506、與第五介電層1902上;以及(4)形成導電線路(如金屬線路)與導電通孔(如金屬通孔)於額外層間介電層堆疊中,以預先定義的方式使半導體裝置1904的多種電子裝置(如第一奈米結構場效電晶體1810a、第二奈米結構場效電晶體1810b、或類似物)電性耦接在一起。 Although not shown, it should be understood that the interconnect structure can be formed on the first nanostructure field effect transistor 1810a, the second nanostructure field effect transistor 1810b, the interlayer dielectric layer 1004, the fourth dielectric layer 1506, and the fifth dielectric layer 1902 to electrically couple various electronic devices of the semiconductor device 1904 (such as the first nanostructure field effect transistor 1810a, the second nanostructure field effect transistor 1810b, and similar electronic devices) in a predetermined manner. For example, the method for forming the interconnect structure may include: (1) forming a conductive source/drain contact (such as a metal contact) through the interlayer dielectric layer 1004 to the first source/drain region 902 and/or the second source/drain region 904; (2) forming a conductive gate contact (such as a metal contact) through the fourth dielectric layer 1506 and/or the fifth dielectric layer 1902 to the gate structure 1502; (3) forming an additional interlayer dielectric layer stacked on the interlayer dielectric layer; (4) forming conductive lines (such as metal lines) and conductive vias (such as metal vias) in the additional interlayer dielectric layer stack to electrically couple the various electronic devices (such as the first nanostructure field effect transistor 1810a, the second nanostructure field effect transistor 1810b, or the like) of the semiconductor device 1904 in a predetermined manner.

在一些實施例中,源極/汲極接點的形成方法可為自對準接點製程。舉例來說,第四介電層1506與第五介電層1902的化學組成與層間介電層1004的化學組成不同如上述,因此可選擇性蝕刻層間介電層1004。此外,第四介電層1506與第五介電層1902覆蓋閘極結構1502而不覆蓋層間介電層1004,如上所述。因此可進行蝕刻製程以選擇性蝕刻層間介電層1004,進而形成源極/汲極接點開口(及/或溝槽)於層間介電層1004中,以露出源極/汲極區。之後將導電材料如鎢、銅、或類似物填入源極/汲極接點開口(及/或溝槽),並在導電材料上進行平坦化製程,以齊平導電材料作為源極/汲極區接點。應理解的是,再將導電材料填入源極/汲極接點開口(及/或溝槽)之前,可進行矽化製程以形成矽化物層於接點開口(及/或溝槽)所露出的源極/汲極區上。 In some embodiments, the source/drain contacts may be formed by a self-aligned contact process. For example, the chemical composition of the fourth dielectric layer 1506 and the fifth dielectric layer 1902 is different from the chemical composition of the interlayer dielectric layer 1004 as described above, so the interlayer dielectric layer 1004 may be selectively etched. In addition, the fourth dielectric layer 1506 and the fifth dielectric layer 1902 cover the gate structure 1502 but not the interlayer dielectric layer 1004, as described above. Therefore, an etching process may be performed to selectively etch the interlayer dielectric layer 1004, thereby forming source/drain contact openings (and/or trenches) in the interlayer dielectric layer 1004 to expose the source/drain region. Thereafter, a conductive material such as tungsten, copper, or the like is filled into the source/drain contact openings (and/or trenches), and a planarization process is performed on the conductive material to level the conductive material as a source/drain region contact. It should be understood that before filling the source/drain contact openings (and/or trenches) with conductive material, a silicide process may be performed to form a silicide layer on the source/drain region exposed by the contact openings (and/or trenches).

由於蝕刻製程選擇性地蝕刻層間介電層1004,蝕刻製程不會露出閘極結構1502(比如不會蝕刻第四介電層1506與第五介電層1902以露出閘極結構1502)。因此若源極/汲極接點開口(及/或溝槽)過大及/或對不準,導電材料(或矽化物層)將不會沉積於閘極結構1502上,進而避免閘極結構1502與源極/汲極區(如第一源極/汲極區902及/或第二源極/汲極區904)之間的電性短路。相反地,可沉積導電材料(與矽化物層),使導電材料自對準源極/汲極區(比如第一源極/汲極區902及/或第二源極/汲極區904)。綜上所述,一些實施例的第四介電層1506可視作第一自對準接點介電結構,而第五介電層1902可視作第二自對準接點介電結構。 Since the etching process selectively etches the interlayer dielectric layer 1004, the etching process will not expose the gate structure 1502 (for example, the fourth dielectric layer 1506 and the fifth dielectric layer 1902 will not be etched to expose the gate structure 1502). Therefore, if the source/drain contact opening (and/or trench) is too large and/or misaligned, the conductive material (or silicide layer) will not be deposited on the gate structure 1502, thereby avoiding electrical short circuit between the gate structure 1502 and the source/drain region (such as the first source/drain region 902 and/or the second source/drain region 904). Instead, a conductive material (and a silicide layer) may be deposited so that the conductive material self-aligns the source/drain region (e.g., the first source/drain region 902 and/or the second source/drain region 904). In summary, the fourth dielectric layer 1506 of some embodiments may be considered as a first self-aligned contact dielectric structure, and the fifth dielectric layer 1902 may be considered as a second self-aligned contact dielectric structure.

在一些實施例中,在形成內連線結構之後完成半導體裝置1904(如積體電路)。至少對上述理由而言,此處所述的方法所形成的半導體裝置1904之第一奈米結構場效電晶體1810a與第二奈米結構場效電晶體1810b之間的空間減少(比如在第二奈米結構堆疊1302b與第五奈米結構堆疊1302e之間的橫向空間(沿著z軸)小於40nm)。綜上所述,此處所述的方法隨著結構尺寸持續縮小(比如 3nm或更小),可改善產能、避免裝置失效、或改善裝置效能等等,如上詳述。 In some embodiments, the semiconductor device 1904 (e.g., an integrated circuit) is completed after the interconnect structure is formed. For at least the reasons described above, the space between the first nanostructure field effect transistor 1810a and the second nanostructure field effect transistor 1810b of the semiconductor device 1904 formed by the method described herein is reduced (e.g., the lateral space (along the z-axis) between the second nanostructure stack 1302b and the fifth nanostructure stack 1302e is less than 40nm). In summary, the method described herein can improve production capacity, avoid device failure, or improve device performance, etc. as the structure size continues to shrink (e.g., 3nm or less), as described in detail above.

圖20A至20C係一些實施例中,奈米結構場效電晶體1810之間的空間減少的半導體裝置1904之多種圖式。圖20A顯示一些實施例中,奈米結構場效電晶體1810之間的空間減少的半導體裝置1904的透視圖。圖20B顯示圖20A的半導體裝置1904沿著圖20A的剖線A-A的剖視圖。圖20C顯示圖20A的半導體裝置1904沿著圖20A的剖線B-B的剖視圖。 20A to 20C are various diagrams of a semiconductor device 1904 with reduced space between nanostructure field effect transistors 1810 in some embodiments. FIG. 20A shows a perspective view of a semiconductor device 1904 with reduced space between nanostructure field effect transistors 1810 in some embodiments. FIG. 20B shows a cross-sectional view of the semiconductor device 1904 of FIG. 20A along the section line A-A of FIG. 20A. FIG. 20C shows a cross-sectional view of the semiconductor device 1904 of FIG. 20A along the section line B-B of FIG. 20A.

如圖20A至20C所示,第二多個介電結構1806橫向延伸(沿著x軸),使第二多個介電結構1806底切對應的第一側壁間隔物702的下表面。舉例來說,第六介電結構1806a(與第七介電結構1806b)橫向延伸(沿著x軸),使第六介電結構1806a(與第七介電結構1806b)底切第一側壁間隔物702之一者的下表面(比如延伸(沿著z軸)於第一對902a、第二對902b、第五對902c、與第六對902d的第一源極/汲極區902之間的第一側壁間隔物702之一者的下表面)。在一些實施例中,第六介電結構1806a(與第七介電結構1806b)接觸(比如直接接觸)第一側壁間隔物702之一者的下表面。在其他實施例中,第一閘極結構1502a(與第三閘極結構1502c)、第二蝕刻停止層1504、與第四介電層1506,可底切第一側壁間隔物702之一者的下表面。 20A to 20C , the second plurality of dielectric structures 1806 extend laterally (along the x-axis) such that the second plurality of dielectric structures 1806 undercut the lower surface of the corresponding first sidewall spacers 702. For example, the sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) extend laterally (along the x-axis) such that the sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) undercut the lower surface of one of the first sidewall spacers 702 (e.g., the lower surface of one of the first sidewall spacers 702 extending (along the z-axis) between the first source/drain regions 902 of the first pair 902a, the second pair 902b, the fifth pair 902c, and the sixth pair 902d). In some embodiments, the sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) contacts (e.g., directly contacts) the lower surface of one of the first sidewall spacers 702. In other embodiments, the first gate structure 1502a (and the third gate structure 1502c), the second etch stop layer 1504, and the fourth dielectric layer 1506 may undercut the lower surface of one of the first sidewall spacers 702.

在一些實施例中,第六介電結構1806a(與第七介電結構1806b)橫向延伸(沿著x軸)於第一蝕刻停止層1002的相對內側側壁之間。舉例來說,第一蝕刻停止層1002具有相對的第一內側側壁2002與第二內側側壁2004。第一內側側壁2002與第二內側側壁2004沿著第一側壁間隔物702之一者的兩側外側側壁延伸(沿著y軸)。第六介電結構1806a(與第七介電結構1806b)橫向延伸(沿著x軸)於第一內側側壁2002與第二內側側壁2004之間。在一些實施例中,第六介電結構1806a(與第七介電結構1806b)接觸(如直接接觸)第一內側側壁2002與第二內側側壁2004。 In some embodiments, the sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) extend laterally (along the x-axis) between opposing inner sidewalls of the first etch stop layer 1002. For example, the first etch stop layer 1002 has opposing first and second inner sidewalls 2002 and 2004. The first and second inner sidewalls 2002 and 2004 extend along both outer sidewalls of one of the first sidewall spacers 702 (along the y-axis). The sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) extend laterally (along the x-axis) between the first inner sidewall 2002 and the second inner sidewall 2004. In some embodiments, the sixth dielectric structure 1806a (and the seventh dielectric structure 1806b) contacts (such as directly contacts) the first inner sidewall 2002 and the second inner sidewall 2004.

圖21係一些實施例中,圖20A至20C的半導體裝置沿著圖20A的剖線B-B的剖視圖。為了使圖式清楚,圖21不包含一些結構特徵的標號。 FIG. 21 is a cross-sectional view of the semiconductor device of FIGS. 20A to 20C along the section line B-B of FIG. 20A in some embodiments. In order to make the figure clear, FIG. 21 does not include the labels of some structural features.

如圖21所示,第四介電層1506具有第一高度H1。在一些實施例中,第一高度H1介於約5nm至約50nm之間。介電鰭狀物502具有第二高度H2。第二高度H2可介於約30nm至約80nm之間。奈米結構堆疊1302具有第三高度H3(比如第一奈米結構堆疊1302a的最上側奈米結構1304之最上側表面與第一奈米結構堆疊1302a的最下側奈米結構1304之最下側表面之間的距離)。第三高度H3可介於約30nm至約80nm之間。在一些實施例中,第三高度H3實質上等於第二高度H2。在一些實施例中,第三高度H3與第二高度H2不同(比如第三高度H3小於第二高度H2)。 As shown in FIG. 21 , the fourth dielectric layer 1506 has a first height H 1 . In some embodiments, the first height H 1 is between about 5 nm and about 50 nm. The dielectric fin 502 has a second height H 2 . The second height H 2 may be between about 30 nm and about 80 nm. The nanostructure stack 1302 has a third height H 3 (e.g., the distance between the uppermost surface of the uppermost nanostructure 1304 of the first nanostructure stack 1302a and the lowermost surface of the lowermost nanostructure 1304 of the first nanostructure stack 1302a). The third height H 3 may be between about 30 nm and about 80 nm. In some embodiments, the third height H 3 is substantially equal to the second height H 2 . In some embodiments, the third height H3 is different from the second height H2 (eg, the third height H3 is smaller than the second height H2 ).

第二多個介電結構1806分別具有垂直部分2102(沿著y軸延伸)與橫向部分2104(沿著z軸延伸)。舉例來說,第六介電結構1806a具有第一垂直部分2102a(沿著y軸延伸)與第一橫向部分2104a(沿著z軸延伸)。第一橫向部分2104a在第一方向中自第一垂直部分2102a延伸(沿著z軸)。第七介電結構1806b具有第二垂直部分2102b(沿著y軸延伸)與第二橫向部分2104b(沿著z軸延伸)。第二橫向部分2104b在第二方向中自第二垂直部分2102b延伸(沿著z軸),且第二方向與第一方向相反。 The second plurality of dielectric structures 1806 respectively have a vertical portion 2102 (extending along the y-axis) and a transverse portion 2104 (extending along the z-axis). For example, the sixth dielectric structure 1806a has a first vertical portion 2102a (extending along the y-axis) and a first transverse portion 2104a (extending along the z-axis). The first transverse portion 2104a extends from the first vertical portion 2102a in a first direction (along the z-axis). The seventh dielectric structure 1806b has a second vertical portion 2102b (extending along the y-axis) and a second transverse portion 2104b (extending along the z-axis). The second transverse portion 2104b extends from the second vertical portion 2102b in a second direction (along the z-axis), and the second direction is opposite to the first direction.

第二多個介電結構1806具有第四高度H4。第四高度H4對應第二多個介電結構1806的垂直部分2102的高度。在一些實施例中,第四高度H4為整體高度,比如第六介電結構1806a的最上側表面與第六介電結構1806a的最下側表面之間的距離。在一些實施例中,第二高度H2與第四高度H4之間的比例介於3:5至16:1之間。在其他實施例中,第二高度H2與第四高度H4的比例介於8:5至6:1之間。在其他實施例中,第四高度H4介於約5nm至約50nm之間。 The second plurality of dielectric structures 1806 have a fourth height H4 . The fourth height H4 corresponds to the height of the vertical portion 2102 of the second plurality of dielectric structures 1806. In some embodiments, the fourth height H4 is an overall height, such as the distance between the uppermost surface of the sixth dielectric structure 1806a and the lowermost surface of the sixth dielectric structure 1806a. In some embodiments, the ratio between the second height H2 and the fourth height H4 is between 3:5 and 16:1. In other embodiments, the ratio between the second height H2 and the fourth height H4 is between 8:5 and 6:1. In other embodiments, the fourth height H4 is between about 5 nm and about 50 nm.

第二多個介電結構1806具有第五高度H5。第五高度H5對應第二多 個介電結構1806的橫向部分2104的高度。在一些實施例中,第四高度H4與第五高度H5之間的差異大於或等於3nm。在其他實施例中,第四高度H4與第五高度H5之間的差異介於約3nm至47nm之間。在其他實施例中,第五高度H5介於約1Å至約47nm之間。 The second plurality of dielectric structures 1806 has a fifth height H5 . The fifth height H5 corresponds to the height of the lateral portion 2104 of the second plurality of dielectric structures 1806. In some embodiments, the difference between the fourth height H4 and the fifth height H5 is greater than or equal to 3 nm. In other embodiments, the difference between the fourth height H4 and the fifth height H5 is between about 3 nm and 47 nm. In other embodiments, the fifth height H5 is between about 1 Å and about 47 nm.

奈米結構1304具有第一寬度W1。在一些實施例中,第一寬度W1介於約50nm至約150nm之間。奈米結構1304具有第六高度H6。第六高度H6可介於約3nm至約10nm之間。奈米結構堆疊1302的奈米結構1304彼此分開的第一距離D1可介於約3nm至約15nm之間。在一些實施例中,奈米結構堆疊1302可包含約2至10個奈米結構1304。 Nanostructure 1304 has a first width W1 . In some embodiments, first width W1 is between about 50 nm and about 150 nm. Nanostructure 1304 has a sixth height H6 . Sixth height H6 may be between about 3 nm and about 10 nm. Nanostructures 1304 of nanostructure stack 1302 may be separated from each other by a first distance D1 between about 3 nm and about 15 nm. In some embodiments, nanostructure stack 1302 may include about 2 to 10 nanostructures 1304.

第二多個介電結構1806具有第二寬度W2。在一些實施例中,第二寬度W2與第四高度H4的比例介於1:10至20:1之間。在其他實施例中,第二寬度W2與第一寬度W1的比例介於1:30至1:1之間。在其他實施例中,第二寬度W2介於約5nm至約100nm之間。 The second plurality of dielectric structures 1806 have a second width W2 . In some embodiments, the ratio of the second width W2 to the fourth height H4 is between 1:10 and 20:1. In other embodiments, the ratio of the second width W2 to the first width W1 is between 1:30 and 1:1. In other embodiments, the second width W2 is between about 5 nm and about 100 nm.

第五介電層1902自凹陷的介電鰭狀物1802的下表面朝半導體的基板212延伸(沿著y軸)第二距離D2。換言之,第二距離D2對應自第五介電層1902的最下側表面至凹陷的介電鰭狀物1802的最下側表面之距離。在一些實施例中,第二距離D2介於約20nm至約100nm之間。 The fifth dielectric layer 1902 extends (along the y-axis) a second distance D2 from the lower surface of the recessed dielectric fin 1802 toward the semiconductor substrate 212. In other words, the second distance D2 corresponds to the distance from the lowermost surface of the fifth dielectric layer 1902 to the lowermost surface of the recessed dielectric fin 1802. In some embodiments, the second distance D2 is between about 20 nm and about 100 nm.

圖22係一些實施例中,圖21的半導體裝置1904的區域2106的透視圖。 FIG. 22 is a perspective view of region 2106 of semiconductor device 1904 of FIG. 21 in some embodiments.

如圖22所示,第一垂直部分2102a自第二介電鰭狀物502b延伸(沿著y軸)至第一閘極介電結構1808a。第一橫向部分2104a自第一垂直部分2102a延伸(沿著z軸)。在一些實施例中,第六介電結構1806a具有第一周邊部分2202與第二周邊部分2204。第一周邊部分2202與第二周邊部分2204分開(沿著x軸)。 As shown in FIG. 22 , the first vertical portion 2102a extends from the second dielectric fin 502b (along the y-axis) to the first gate dielectric structure 1808a. The first lateral portion 2104a extends from the first vertical portion 2102a (along the z-axis). In some embodiments, the sixth dielectric structure 1806a has a first peripheral portion 2202 and a second peripheral portion 2204. The first peripheral portion 2202 is separated from the second peripheral portion 2204 (along the x-axis).

第一垂直部分2102a延伸(沿著x軸)於第一周邊部分2202與第二周 邊部分2204之間。第一橫向部分2104a延伸(沿著x軸)於第一周邊部分2202與第二周邊部分2204之間。第一周邊部分2202與第二周邊部分2204位於(比如直接位於)第一側壁間隔物702之一的下表面之下。在一些實施例中,第一周邊部分2202的外側側壁與第二周邊部分2204的外側側壁,分別實質上對準第一側壁間隔物702之一的外側側壁。在其他實施例中,第一周邊部分2202的外側側壁可接觸(比如直接接觸)第一蝕刻停止層1002的第二內側側壁2004(見圖20C)。在其他實施例中,第二周邊部分2204的外側側壁可接觸(比如直接接觸)第一蝕刻停止層1002的第一內側側壁2002(見圖20C)。 The first vertical portion 2102a extends (along the x-axis) between the first peripheral portion 2202 and the second peripheral portion 2204. The first transverse portion 2104a extends (along the x-axis) between the first peripheral portion 2202 and the second peripheral portion 2204. The first peripheral portion 2202 and the second peripheral portion 2204 are located (e.g., directly below) a lower surface of one of the first sidewall spacers 702. In some embodiments, an outer sidewall of the first peripheral portion 2202 and an outer sidewall of the second peripheral portion 2204 are respectively substantially aligned with an outer sidewall of one of the first sidewall spacers 702. In other embodiments, the outer sidewall of the first peripheral portion 2202 may contact (e.g., directly contact) the second inner sidewall 2004 of the first etch stop layer 1002 (see FIG. 20C ). In other embodiments, the outer sidewall of the second peripheral portion 2204 may contact (e.g., directly contact) the first inner sidewall 2002 of the first etch stop layer 1002 (see FIG. 20C ).

第六介電結構1806a具有第一上表面2208與第二上表面2210。第一上表面2208對應第一垂直部分2102a的上表面。第二上表面2210對應第一橫向部分2104a的上表面。 The sixth dielectric structure 1806a has a first upper surface 2208 and a second upper surface 2210. The first upper surface 2208 corresponds to the upper surface of the first vertical portion 2102a. The second upper surface 2210 corresponds to the upper surface of the first horizontal portion 2104a.

第一上表面2208位於第二上表面2210上。在一些實施例中,第一上表面2208為第六介電結構1806a的最上側表面。第二上表面2210橫向位於(沿著z軸)第一上表面2208與第二介電鰭狀物502b之間(見圖21)。第一上表面2208橫向地位於(沿著z軸)第二上表面2210與第一閘極結構1502a之間(見圖21)。 The first upper surface 2208 is located on the second upper surface 2210. In some embodiments, the first upper surface 2208 is the uppermost surface of the sixth dielectric structure 1806a. The second upper surface 2210 is located laterally (along the z-axis) between the first upper surface 2208 and the second dielectric fin 502b (see FIG. 21). The first upper surface 2208 is located laterally (along the z-axis) between the second upper surface 2210 and the first gate structure 1502a (see FIG. 21).

第一閘極介電結構1808a沿著第六介電結構1806a的第一上表面2208延伸。在一些實施例中,第一閘極介電結構1808a亦沿著第一閘極介電結構1808a的第一側壁、第二介電鰭狀物502b的第一側壁、第二鰭狀物210b的上表面、第一介電鰭狀物502a的側壁、第一介電鰭狀物502a的上表面、與第一鰭狀物210a的上表面延伸(見圖20B)。第一閘極介電結構1808a的第一側壁自第一上表面2208垂直延伸(沿著y軸)至第二介電鰭狀物502b。在一些實施例中,第一閘極介電結構1808a的第一側壁實質上對準第二介電鰭狀物502b的第一側壁。在其他實施例中,第一閘極介電結構1808a沿著第一上表面2208、第一閘極介電結構1808a的側壁、第二介電鰭狀物502b的側壁、第二鰭狀物210b的上表面、第一介電鰭 狀物502a的側壁、第一介電鰭狀物502a的上表面、與第一鰭狀物210a的上表面連續延伸。 The first gate dielectric structure 1808a extends along the first upper surface 2208 of the sixth dielectric structure 1806a. In some embodiments, the first gate dielectric structure 1808a also extends along the first sidewall of the first gate dielectric structure 1808a, the first sidewall of the second dielectric fin 502b, the upper surface of the second fin 210b, the sidewall of the first dielectric fin 502a, the upper surface of the first dielectric fin 502a, and the upper surface of the first fin 210a (see FIG. 20B ). The first sidewall of the first gate dielectric structure 1808a extends vertically (along the y-axis) from the first upper surface 2208 to the second dielectric fin 502b. In some embodiments, the first sidewall of the first gate dielectric structure 1808a is substantially aligned with the first sidewall of the second dielectric fin 502b. In other embodiments, the first gate dielectric structure 1808a extends continuously along the first upper surface 2208, the sidewall of the first gate dielectric structure 1808a, the sidewall of the second dielectric fin 502b, the upper surface of the second fin 210b, the sidewall of the first dielectric fin 502a, the upper surface of the first dielectric fin 502a, and the upper surface of the first fin 210a.

第一閘極介電結構1808a具有兩側的第一側壁與第二側壁。換言之,第一閘極介電結構1808a的第二側壁與第一側壁橫向分開(沿著z軸)。第一閘極介電結構1808a的第二側壁自第一上表面2208垂直延伸至第二上表面2210(沿著y軸)。在一些實施例中,第一閘極介電結構1808a的第二側壁實質上對準第一閘極介電結構1808a的一側壁。 The first gate dielectric structure 1808a has a first sidewall and a second sidewall on both sides. In other words, the second sidewall of the first gate dielectric structure 1808a is laterally separated from the first sidewall (along the z-axis). The second sidewall of the first gate dielectric structure 1808a extends vertically from the first upper surface 2208 to the second upper surface 2210 (along the y-axis). In some embodiments, the second sidewall of the first gate dielectric structure 1808a is substantially aligned with a sidewall of the first gate dielectric structure 1808a.

第一閘極介電結構1808a的第三側壁與第一閘極介電結構1808a的第一側壁相對。換言之,第一閘極介電結構1808a的第三側壁與第一閘極介電結構1808a的第一側壁橫向分開(沿著z軸)。第一閘極介電結構1808a的第三側壁自第二上表面2210垂直延伸(沿著y軸)至第一閘極介電結構1808a的下表面(比如接觸第二介電鰭狀物502b的上表面之第一閘極介電結構1808a的最下側表面)。第二上表面2210橫向地位於(沿著z軸)第一閘極介電結構1808a的第二側壁與第一閘極介電結構1808a的第三側壁之間。在一些實施例中,第二上表面2210自第一閘極介電結構1808a的第三側壁延伸至第一閘極介電結構1808a的第二側壁。在其他實施例中,第一閘極介電結構1808a的第三側壁實質上對準第二介電鰭狀物502b的第二側壁(與第二介電鰭狀物502b的第一側壁相對),且第二介電鰭狀物502b的第一側壁與第二側壁橫向分開(沿著z軸)。 The third sidewall of the first gate dielectric structure 1808a is opposite to the first sidewall of the first gate dielectric structure 1808a. In other words, the third sidewall of the first gate dielectric structure 1808a is laterally separated from the first sidewall of the first gate dielectric structure 1808a (along the z-axis). The third sidewall of the first gate dielectric structure 1808a extends vertically (along the y-axis) from the second upper surface 2210 to the lower surface of the first gate dielectric structure 1808a (e.g., the lowermost surface of the first gate dielectric structure 1808a that contacts the upper surface of the second dielectric fin 502b). The second upper surface 2210 is laterally located (along the z-axis) between the second sidewall of the first gate dielectric structure 1808a and the third sidewall of the first gate dielectric structure 1808a. In some embodiments, the second upper surface 2210 extends from the third sidewall of the first gate dielectric structure 1808a to the second sidewall of the first gate dielectric structure 1808a. In other embodiments, the third sidewall of the first gate dielectric structure 1808a is substantially aligned with the second sidewall of the second dielectric fin 502b (opposite to the first sidewall of the second dielectric fin 502b), and the first sidewall of the second dielectric fin 502b is laterally separated from the second sidewall (along the z-axis).

在一些實施例中,第一上表面2208高於第一閘極結構1502a的上表面(如最上側的表面,見圖21)。在其他實施例中,第二上表面2210低於第一閘極結構1502a的上表面(見圖21)。第一上表面2208可高於第二蝕刻停止層1504。第二上表面2210可低於第二蝕刻停止層1504。雖然圖22顯示第六介電結構1806a的特徵(如結構特徵),但應理解多個介電結構的每一者可包括實質上類似的特徵。 In some embodiments, the first upper surface 2208 is higher than the upper surface of the first gate structure 1502a (such as the uppermost surface, see FIG. 21). In other embodiments, the second upper surface 2210 is lower than the upper surface of the first gate structure 1502a (see FIG. 21). The first upper surface 2208 may be higher than the second etch stop layer 1504. The second upper surface 2210 may be lower than the second etch stop layer 1504. Although FIG. 22 shows features (such as structural features) of the sixth dielectric structure 1806a, it should be understood that each of the plurality of dielectric structures may include substantially similar features.

圖23係一些實施例中,形成奈米結構場效電晶體之間的空間減少 之半導體裝置的方法之流程圖2300。雖然圖23在此處所示的流程圖2300顯示一系列的動作或事件,但應理解這些動作或事件的說明順序並非用於侷限實施例。舉例來說,可由不同順序進行一些動作,及/或一些動作可與此處所示及/或所述的動作或事件之外的其他動作或事件一起發生。此外,一或多個實施例不必實施此處所述的所有動作,且可由一或多個分開的動作及/或方式執行一或多個此處所述的動作。 FIG. 23 is a flowchart 2300 of a method for forming a semiconductor device with reduced space between nanostructured field effect transistors in some embodiments. Although the flowchart 2300 shown in FIG. 23 herein shows a series of actions or events, it should be understood that the order in which these actions or events are described is not intended to limit the embodiments. For example, some actions may be performed in a different order and/or some actions may occur with other actions or events other than those shown and/or described herein. In addition, one or more embodiments need not implement all of the actions described herein, and one or more actions described herein may be performed by one or more separate actions and/or methods.

在步驟2302中,分別形成多個奈米結構堆疊於多個半導體鰭狀物上,其中多個奈米結構堆疊的每一者包括多個堆疊的奈米結構,其中多個介電鰭狀物分別橫向分開多個奈米結構堆疊,其中第一介電結構位於介電鰭狀物的第一介電鰭狀物上,且第二介電結構位於介電鰭狀物的第二介電鰭狀物上,且其中鰭狀物的第三介電鰭狀物橫向位於第一介電鰭狀物與第二介電鰭狀物之間,並橫向位於第一介電結構與第二介電結構之間。圖1-13示的一些實施例之一系列圖式對應步驟2302。 In step 2302, a plurality of nanostructure stacks are formed on a plurality of semiconductor fins, wherein each of the plurality of nanostructure stacks includes a plurality of stacked nanostructures, wherein a plurality of dielectric fins separate the plurality of nanostructure stacks laterally, wherein a first dielectric structure is located on a first dielectric fin of the dielectric fins, and a second dielectric structure is located on a second dielectric fin of the dielectric fins, and wherein a third dielectric fin of the fins is laterally located between the first dielectric fin and the second dielectric fin, and laterally located between the first dielectric structure and the second dielectric structure. A series of diagrams of some embodiments shown in FIGS. 1-13 correspond to step 2302.

在步驟2304中,形成多個導電閘極結構於奈米結構堆疊之上、半導體鰭狀物之上、以及奈米結構堆疊的奈米結構周圍,其中第一介電鰭狀物橫向分開導電閘極結構的第一導電閘極結構與第二導電閘極結構,其中第二介電鰭狀物橫向分開導電閘極結構的第三導電閘極結構與第二導電閘極結構,且其中第二導電閘極結構橫向地位於第一介電鰭狀物與第二介電鰭狀物之間。圖14與15所示的一些實施例之一系列剖視圖對應步驟2304。 In step 2304, a plurality of conductive gate structures are formed on the nanostructure stack, on the semiconductor fin, and around the nanostructure of the nanostructure stack, wherein the first dielectric fin laterally separates the first conductive gate structure and the second conductive gate structure of the conductive gate structure, wherein the second dielectric fin laterally separates the third conductive gate structure and the second conductive gate structure of the conductive gate structure, and wherein the second conductive gate structure is laterally located between the first dielectric fin and the second dielectric fin. A series of cross-sectional views of some embodiments shown in FIGS. 14 and 15 correspond to step 2304.

在步驟2306中,形成第一介電層以覆蓋導電閘極結構、第一介電結構、與第二介電結構。圖15所示的一些實施例之剖視圖對應步驟2306。 In step 2306, a first dielectric layer is formed to cover the conductive gate structure, the first dielectric structure, and the second dielectric structure. The cross-sectional views of some embodiments shown in FIG. 15 correspond to step 2306.

在步驟2308中,形成第一開口於第一介電層中,其中第一開口與第二導電閘極結構重疊、與第一介電結構部分地重疊、並與第二介電結構部分地重疊。圖16所示的一些實施例之剖視圖對應步驟2308。 In step 2308, a first opening is formed in the first dielectric layer, wherein the first opening overlaps with the second conductive gate structure, partially overlaps with the first dielectric structure, and partially overlaps with the second dielectric structure. The cross-sectional views of some embodiments shown in FIG. 16 correspond to step 2308.

在步驟2310中,移除第二導電閘極結構。圖17所示的一些實施例之剖視圖對應步驟2310。 In step 2310, the second conductive gate structure is removed. The cross-sectional views of some embodiments shown in FIG. 17 correspond to step 2310.

在步驟2312中,移除第一開口下的第一介電結構的一部分與第二介電結構的一部分,以分別形成第三介電結構於第一鰭狀物上與第四介電結構於第二鰭狀物上。圖18所示的一些實施例之剖視圖對應步驟2312。 In step 2312, a portion of the first dielectric structure and a portion of the second dielectric structure under the first opening are removed to form a third dielectric structure on the first fin and a fourth dielectric structure on the second fin, respectively. The cross-sectional views of some embodiments shown in FIG. 18 correspond to step 2312.

在步驟2314中,移除第一開口下的奈米結構堆疊並使第一開口下的半導體鰭狀物凹陷,以形成第二開口於第一開口下。圖18所示的一些實施例之剖視圖對應步驟2314。 In step 2314, the nanostructure stack under the first opening is removed and the semiconductor fin under the first opening is recessed to form a second opening under the first opening. The cross-sectional views of some embodiments shown in FIG. 18 correspond to step 2314.

在步驟2316中,形成第二介電層於第一開口與第二開口中,其中第二介電層至少部分地覆蓋第三介電結構與第四介電結構。圖19所示的一些實施例之剖視圖對應步驟2316。 In step 2316, a second dielectric layer is formed in the first opening and the second opening, wherein the second dielectric layer at least partially covers the third dielectric structure and the fourth dielectric structure. The cross-sectional views of some embodiments shown in FIG. 19 correspond to step 2316.

本發明一些實施例提供半導體裝置。半導體裝置包括半導體鰭狀物,自半導體基板垂直凸起。多個半導體奈米結構,直接位於半導體鰭狀物上並垂直堆疊。閘極結構,位於半導體鰭狀物上並圍繞半導體奈米結構。介電鰭狀物,位於半導體基板上,其中閘極結構與半導體奈米結構位於介電鰭狀物的第一側上,且其中介電鰭狀物的上表面低於閘極結構的上表面。介電結構,直接位於介電鰭狀物上,其中介電結構的第一上表面高於閘極結構的上表面。介電層,至少部分地位於半導體基板上,其中介電層位於介電鰭狀物的第二側上,且介電鰭狀物的第一側與第二側相對,其中介電層的上表面高於閘極結構的上表面與介電結構的第一上表面,且其中介電層的下表面低於介電鰭狀物的上表面。 Some embodiments of the present invention provide a semiconductor device. The semiconductor device includes a semiconductor fin protruding vertically from a semiconductor substrate. A plurality of semiconductor nanostructures are directly located on the semiconductor fin and stacked vertically. A gate structure is located on the semiconductor fin and surrounds the semiconductor nanostructure. A dielectric fin is located on the semiconductor substrate, wherein the gate structure and the semiconductor nanostructure are located on a first side of the dielectric fin, and wherein the upper surface of the dielectric fin is lower than the upper surface of the gate structure. A dielectric structure is directly located on the dielectric fin, wherein the first upper surface of the dielectric structure is higher than the upper surface of the gate structure. A dielectric layer is at least partially disposed on a semiconductor substrate, wherein the dielectric layer is disposed on the second side of the dielectric fin, and the first side and the second side of the dielectric fin are opposite to each other, wherein the upper surface of the dielectric layer is higher than the upper surface of the gate structure and the first upper surface of the dielectric structure, and wherein the lower surface of the dielectric layer is lower than the upper surface of the dielectric fin.

在一些實施例中,介電結構具有L形輪廓。 In some embodiments, the dielectric structure has an L-shaped profile.

在一些實施例中,介電結構包括第二上表面,其介於介電結構的第一上表面與介電鰭狀物的上表面之間。 In some embodiments, the dielectric structure includes a second upper surface disposed between the first upper surface of the dielectric structure and the upper surface of the dielectric fin.

在一些實施例中,介電結構的第一上表面橫向地位於介電結構的第二上表面與閘極結構之間。 In some embodiments, the first upper surface of the dielectric structure is laterally located between the second upper surface of the dielectric structure and the gate structure.

在一些實施例中,半導體裝置更包括:閘極介電結構,位於閘極結構與半導體鰭狀物之間,其中閘極介電結構分開介電鰭狀物與閘極結構,並分開介電結構與閘極結構。 In some embodiments, the semiconductor device further includes: a gate dielectric structure located between the gate structure and the semiconductor fin, wherein the gate dielectric structure separates the dielectric fin from the gate structure, and separates the dielectric structure from the gate structure.

在一些實施例中,閘極介電結構沿著半導體鰭狀物的上表面、介電鰭狀物的第一側壁、介電結構的第一側壁、與介電結構的第一上表面連續延伸。 In some embodiments, the gate dielectric structure extends continuously along the upper surface of the semiconductor fin, the first sidewall of the dielectric fin, the first sidewall of the dielectric structure, and the first upper surface of the dielectric structure.

在一些實施例中,介電結構的第二側壁與介電結構的第一側壁相對,並實質上對準閘極介電結構的側壁。 In some embodiments, the second sidewall of the dielectric structure is opposite to the first sidewall of the dielectric structure and is substantially aligned with the sidewall of the gate dielectric structure.

在一些實施例中,介電結構包括第三側壁,且介電結構的第三側壁與介電結構的第一側壁相對;以及介電結構的第二側壁橫向地位於介電結構的第一側壁與介電結構的第三側壁之間。 In some embodiments, the dielectric structure includes a third sidewall, and the third sidewall of the dielectric structure is opposite to the first sidewall of the dielectric structure; and the second sidewall of the dielectric structure is laterally located between the first sidewall of the dielectric structure and the third sidewall of the dielectric structure.

在一些實施例中,介電結構的第二上表面自介電結構的第三側壁橫向延伸至介電結構的第二側壁;以及介電結構的第二上表面垂直地位於介電結構的第一上表面與介電鰭狀物的上表面之間。 In some embodiments, the second upper surface of the dielectric structure extends laterally from the third sidewall of the dielectric structure to the second sidewall of the dielectric structure; and the second upper surface of the dielectric structure is vertically located between the first upper surface of the dielectric structure and the upper surface of the dielectric fin.

在一些實施例中,介電結構的第三側壁實質上對準介電鰭狀物的第二側壁,且介電鰭狀物的第二側壁與介電鰭狀物的第一側壁相對。 In some embodiments, the third sidewall of the dielectric structure is substantially aligned with the second sidewall of the dielectric fin, and the second sidewall of the dielectric fin is opposite to the first sidewall of the dielectric fin.

本發明一些實施例提供半導體裝置。半導體裝置包括第一半導體鰭狀物與第二半導體鰭狀物,自半導體基板垂直凸起,其中第二半導體鰭狀物與第一半導體鰭狀物在第一方向中橫向分開,其中第一半導體鰭狀物與第二半導體鰭狀物在第二方向中橫向延伸並彼此平行,且其中第二方向實質上垂直於第一方向。第一閘極結構,位於第一半導體鰭狀物上。第二閘極結構,位於第二半導體鰭狀物上,並與第一閘極結構在第一方向中橫向分開。第一介電鰭狀 物,位於半導體基板上,其中第一介電鰭狀物位於第一半導體鰭狀物與第二半導體鰭狀物之間,以及第一閘極結構與第二閘極結構之間。第二介電鰭狀物,位於半導體基板上,並在第一方向中與第一介電鰭狀物橫向分開,其中第二介電鰭狀物位於第一半導體鰭狀物與第二半導體鰭狀物之間,以及第一閘極結構與第二閘極結構之間。第一介電結構,位於第一介電鰭狀物上。第二介電結構,位於第二介電鰭狀物上,並在第一方向中與第一半導體鰭狀物橫向分開。介電層,至少部分地位於半導體基板上,其中第一介電結構橫向分開介電層與第一閘極結構的第一部分,且第二介電結構橫向分開介電層與第二閘極結構的第一部分。 Some embodiments of the present invention provide a semiconductor device. The semiconductor device includes a first semiconductor fin and a second semiconductor fin, which protrude vertically from a semiconductor substrate, wherein the second semiconductor fin is laterally separated from the first semiconductor fin in a first direction, wherein the first semiconductor fin and the second semiconductor fin extend laterally in a second direction and are parallel to each other, and wherein the second direction is substantially perpendicular to the first direction. A first gate structure is located on the first semiconductor fin. A second gate structure is located on the second semiconductor fin and is laterally separated from the first gate structure in the first direction. A first dielectric fin is disposed on the semiconductor substrate, wherein the first dielectric fin is disposed between the first semiconductor fin and the second semiconductor fin, and between the first gate structure and the second gate structure. A second dielectric fin is disposed on the semiconductor substrate and is laterally separated from the first dielectric fin in a first direction, wherein the second dielectric fin is disposed between the first semiconductor fin and the second semiconductor fin, and between the first gate structure and the second gate structure. A first dielectric structure is disposed on the first dielectric fin. A second dielectric structure is disposed on the second dielectric fin and is laterally separated from the first semiconductor fin in the first direction. A dielectric layer is at least partially disposed on a semiconductor substrate, wherein a first dielectric structure laterally separates the dielectric layer from a first portion of a first gate structure, and a second dielectric structure laterally separates the dielectric layer from a first portion of a second gate structure.

在一些實施例中,半導體裝置更包括:第四介電結構,位於第一閘極結構上並部分地覆蓋第一介電結構;第五介電結構,位於第二閘極結構上並部分地覆蓋第二介電結構,其中:介電層橫向地位於第四介電結構與第五介電結構之間;介電層部分地覆蓋第一介電結構與第二介電結構;以及介電層的最下側表面低於第四介電結構的最下側表面與第五介電結構的最下側表面。 In some embodiments, the semiconductor device further includes: a fourth dielectric structure located on the first gate structure and partially covering the first dielectric structure; a fifth dielectric structure located on the second gate structure and partially covering the second dielectric structure, wherein: the dielectric layer is laterally located between the fourth dielectric structure and the fifth dielectric structure; the dielectric layer partially covers the first dielectric structure and the second dielectric structure; and the bottom surface of the dielectric layer is lower than the bottom surface of the fourth dielectric structure and the bottom surface of the fifth dielectric structure.

在一些實施例中,第一介電結構具有L形輪廓;以及第二介電結構具有L形輪廓。 In some embodiments, the first dielectric structure has an L-shaped profile; and the second dielectric structure has an L-shaped profile.

在一些實施例中,第一介電結構的第一上表面高於第一閘極結構的上表面;第一介電結構的第二上表面位於第一介電結構的第一上表面與第一介電鰭狀物的上表面之間;第二介電結構的第一上表面高於第二閘極結構的上表面;第二介電結構的第二上表面位於第二介電結構的第一上表面與第二介電鰭狀物的上表面之間;以及第一介電結構的第二上表面與第二介電結構的第二上表面,橫向地位於第一介電結構的第一上表面與第二介電結構的第一上表面之間。 In some embodiments, the first upper surface of the first dielectric structure is higher than the upper surface of the first gate structure; the second upper surface of the first dielectric structure is located between the first upper surface of the first dielectric structure and the upper surface of the first dielectric fin; the first upper surface of the second dielectric structure is higher than the upper surface of the second gate structure; the second upper surface of the second dielectric structure is located between the first upper surface of the second dielectric structure and the upper surface of the second dielectric fin; and the second upper surface of the first dielectric structure and the second upper surface of the second dielectric structure are laterally located between the first upper surface of the first dielectric structure and the first upper surface of the second dielectric structure.

在一些實施例中,半導體裝置更包括:垂直堆疊的多個第一半導 體奈米結構,直接位於第一半導體鰭狀物上,其中第一半導體奈米結構在第二方向中自第一源極/汲極區延伸至第二源極/汲極區;以及垂直堆疊的多個第二半導體奈米結構,直接位於第二半導體鰭狀物上,其中第二半導體奈米結構在第二方向中自第三源極/汲極區延伸至第四源極/汲極區,且其中第三源極/汲極區及第四源極/汲極區在第一方向中與第一源極/汲極區及第二源極/汲極區分開。 In some embodiments, the semiconductor device further includes: a plurality of first semiconductor nanostructures stacked vertically, directly located on the first semiconductor fin, wherein the first semiconductor nanostructure extends from the first source/drain region to the second source/drain region in the second direction; and a plurality of second semiconductor nanostructures stacked vertically, directly located on the second semiconductor fin, wherein the second semiconductor nanostructure extends from the third source/drain region to the fourth source/drain region in the second direction, and wherein the third source/drain region and the fourth source/drain region are separated from the first source/drain region and the second source/drain region in the first direction.

在一些實施例中,第一閘極結構延伸圍繞第一半導體奈米結構,且第二閘極結構延伸圍繞第二半導體奈米結構。 In some embodiments, the first gate structure extends around the first semiconductor nanostructure, and the second gate structure extends around the second semiconductor nanostructure.

在一些實施例中,半導體裝置更包括:第三介電鰭狀物,位於半導體基板上並與第一介電鰭狀物及第二介電鰭狀物橫向分開,其中第三介電鰭狀物位於第一介電鰭狀物與第二介電鰭狀物之間,且其中第三介電鰭狀物的上表面低於第一介電鰭狀物的上表面與第二介電鰭狀物的上表面。 In some embodiments, the semiconductor device further includes: a third dielectric fin, located on the semiconductor substrate and laterally separated from the first dielectric fin and the second dielectric fin, wherein the third dielectric fin is located between the first dielectric fin and the second dielectric fin, and wherein the upper surface of the third dielectric fin is lower than the upper surface of the first dielectric fin and the upper surface of the second dielectric fin.

在一些實施例中,第一介電結構,自第一介電鰭狀物的上表面垂直延伸;以及第二介電結構,自第二介電鰭狀物的上表面垂直延伸。 In some embodiments, the first dielectric structure extends vertically from the upper surface of the first dielectric fin; and the second dielectric structure extends vertically from the upper surface of the second dielectric fin.

在一些實施例中,介電層覆蓋第三介電鰭狀物;介電層的第一部分朝第一介電鰭狀物與第三介電鰭狀物之間的半導體基板垂直延伸;介電層的第二部分朝第二介電鰭狀物與第三介電鰭狀物之間的半導體基板垂直延伸;介電層的第一部分的下表面圓潤化;以及介電層的第二部分的下表面圓潤化。 In some embodiments, the dielectric layer covers the third dielectric fin; the first portion of the dielectric layer extends vertically toward the semiconductor substrate between the first dielectric fin and the third dielectric fin; the second portion of the dielectric layer extends vertically toward the semiconductor substrate between the second dielectric fin and the third dielectric fin; the lower surface of the first portion of the dielectric layer is rounded; and the lower surface of the second portion of the dielectric layer is rounded.

本發明一些實施例提供半導體裝置的形成方法。方法包括接收工件。工件包括第一介電鰭狀物,位於半導體基板上並橫向地位於第一多個半導體奈米結構與第二多個半導體奈米結構之間;第二介電鰭狀物,位於半導體基板上並橫向地位於第三多個半導體奈米結構與第二多個半導體奈米結構之間;第一導電閘極結構,位於半導體基板上並圍繞第一多個半導體奈米結構;第二導電閘極結構,位於半導體基板上並圍繞第二多個半導體奈米結構;第三導電閘極結構,位於半導體基板上並圍繞第三多個半導體奈米結構,其中第二導電 閘極結構位於第一導電閘極結構與第三導電閘極結構之間,並與第一導電閘極結構及第三導電閘極結構橫向分開;第一介電結構,直接位於第一介電鰭狀物上,其中第一介電結構與第一介電鰭狀物橫向分開第一導電閘極結構與第二導電閘極結構;以及第二介電結構,直接位於第二介電鰭狀物上,其中第二介電結構與第二介電鰭狀物橫向分開第三導電閘極結構與第二導電閘極結構。形成第一介電層於第一介電鰭狀物、第二介電鰭狀物、第一多個半導體奈米結構、第二多個半導體奈米結構、第三多個半導體奈米結構、第一介電結構、第二介電結構、第一導電閘極結構、第二導電閘極結構、與第三導電閘極結構上。形成第一開口於第一介電層中,其中第一開口與第一介電結構、第二介電結構、與第二導電閘極結構至少部分重疊。移除第二導電閘極結構。移除第一開口下的第一介電結構之一部分,以形成直接位於第一介電鰭狀物上的第三介電結構。移除第一開口下的第二介電結構之一部分,以形成直接位於第二介電鰭狀物上的第四介電結構。移除第二多個半導體奈米結構,以形成第二開口於第一開口下。形成第二介電層於第一開口與第二開口中,並至少部分地覆蓋第三介電結構與第四介電結構。 Some embodiments of the present invention provide a method for forming a semiconductor device. The method includes receiving a workpiece. The workpiece includes a first dielectric fin, located on a semiconductor substrate and laterally located between a first plurality of semiconductor nanostructures and a second plurality of semiconductor nanostructures; a second dielectric fin, located on the semiconductor substrate and laterally located between a third plurality of semiconductor nanostructures and the second plurality of semiconductor nanostructures; a first conductive gate structure, located on the semiconductor substrate and surrounding the first plurality of semiconductor nanostructures; a second conductive gate structure, located on the semiconductor substrate and surrounding the second plurality of semiconductor nanostructures; a third conductive gate structure, located on the semiconductor substrate and surrounding the first plurality of semiconductor nanostructures; The invention relates to a semiconductor nanostructure, wherein the second conductive gate structure is located between the first conductive gate structure and the third conductive gate structure and is laterally separated from the first conductive gate structure and the third conductive gate structure; the first dielectric structure is directly located on the first dielectric fin, wherein the first dielectric structure and the first dielectric fin laterally separate the first conductive gate structure and the second conductive gate structure; and the second dielectric structure is directly located on the second dielectric fin, wherein the second dielectric structure and the second dielectric fin laterally separate the third conductive gate structure and the second conductive gate structure. A first dielectric layer is formed on a first dielectric fin, a second dielectric fin, a first plurality of semiconductor nanostructures, a second plurality of semiconductor nanostructures, a third plurality of semiconductor nanostructures, a first dielectric structure, a second dielectric structure, a first conductive gate structure, a second conductive gate structure, and a third conductive gate structure. A first opening is formed in the first dielectric layer, wherein the first opening at least partially overlaps with the first dielectric structure, the second dielectric structure, and the second conductive gate structure. The second conductive gate structure is removed. A portion of the first dielectric structure under the first opening is removed to form a third dielectric structure directly on the first dielectric fin. A portion of the second dielectric structure under the first opening is removed to form a fourth dielectric structure directly on the second dielectric fin. The second plurality of semiconductor nanostructures are removed to form a second opening under the first opening. A second dielectric layer is formed in the first opening and the second opening, and at least partially covers the third dielectric structure and the fourth dielectric structure.

上述實施例之特徵有利於本技術領域中具有通常知識者理解本發明。本技術領域中具有通常知識者應理解可採用本發明作基礎,設計並變化其他製程與結構以完成上述實施例之相同目的及/或相同優點。本技術領域中具有通常知識者亦應理解,這些等效置換並未脫離本發明精神與範疇,並可在未脫離本發明之精神與範疇的前提下進行改變、替換、或更動。 The features of the above embodiments are helpful for those with ordinary knowledge in the art to understand the present invention. Those with ordinary knowledge in the art should understand that the present invention can be used as a basis to design and change other processes and structures to achieve the same purpose and/or the same advantages of the above embodiments. Those with ordinary knowledge in the art should also understand that these equivalent substitutions do not deviate from the spirit and scope of the present invention, and can be changed, replaced, or modified without departing from the spirit and scope of the present invention.

2300:流程圖 2300: Flowchart

2302,2304,2306,2308,2310,2312,2314,2316:步驟 2302,2304,2306,2308,2310,2312,2314,2316: Steps

Claims (10)

一種半導體裝置,包括:一半導體鰭狀物,自一半導體基板垂直凸起;多個半導體奈米結構,直接位於該半導體鰭狀物上並垂直堆疊;一閘極結構,位於該半導體鰭狀物上並圍繞該些半導體奈米結構;一介電鰭狀物,位於該半導體基板上,其中該閘極結構與該些半導體奈米結構位於該介電鰭狀物的第一側上,且其中該介電鰭狀物的上表面低於該閘極結構的上表面;一介電結構,直接位於該介電鰭狀物上,其中該介電結構的第一上表面高於該閘極結構的上表面;以及一介電層,至少部分地位於該半導體基板上,其中該介電層位於該介電鰭狀物的第二側上,且該介電鰭狀物的第一側與第二側相對,其中該介電層的上表面高於該閘極結構的上表面與該介電結構的第一上表面,且其中該介電層的下表面低於該介電鰭狀物的上表面。 A semiconductor device includes: a semiconductor fin protruding vertically from a semiconductor substrate; a plurality of semiconductor nanostructures directly located on the semiconductor fin and stacked vertically; a gate structure located on the semiconductor fin and surrounding the semiconductor nanostructures; a dielectric fin located on the semiconductor substrate, wherein the gate structure and the semiconductor nanostructures are located on a first side of the dielectric fin, and wherein an upper surface of the dielectric fin is lower than an upper surface of the gate structure; A dielectric structure directly located on the dielectric fin, wherein the first upper surface of the dielectric structure is higher than the upper surface of the gate structure; and a dielectric layer at least partially located on the semiconductor substrate, wherein the dielectric layer is located on the second side of the dielectric fin, and the first side and the second side of the dielectric fin are opposite, wherein the upper surface of the dielectric layer is higher than the upper surface of the gate structure and the first upper surface of the dielectric structure, and wherein the lower surface of the dielectric layer is lower than the upper surface of the dielectric fin. 如請求項1之半導體裝置,其中該介電結構具有L形輪廓。 A semiconductor device as claimed in claim 1, wherein the dielectric structure has an L-shaped profile. 一種半導體裝置,包括:一第一半導體鰭狀物與一第二半導體鰭狀物,自一半導體基板垂直凸起,其中該第二半導體鰭狀物與該第一半導體鰭狀物在一第一方向中橫向分開,其中該第一半導體鰭狀物與該第二半導體鰭狀物在一第二方向中橫向延伸並彼此平行,且其中該第二方向實質上垂直於該第一方向;一第一閘極結構,位於該第一半導體鰭狀物上;一第二閘極結構,位於該第二半導體鰭狀物上,並與該第一閘極結構在該第一方向中橫向分開;一第一介電鰭狀物,位於該半導體基板上,其中該第一介電鰭狀物位於該 第一半導體鰭狀物與該第二半導體鰭狀物之間,以及該第一閘極結構與該第二閘極結構之間;一第二介電鰭狀物,位於該半導體基板上,並在該第一方向中與該第一介電鰭狀物橫向分開,其中該第二介電鰭狀物位於該第一半導體鰭狀物與該第二半導體鰭狀物之間,以及該第一閘極結構與該第二閘極結構之間;一第一介電結構,位於該第一介電鰭狀物上;一第二介電結構,位於該第二介電鰭狀物上,並在該第一方向中與該第一半導體鰭狀物橫向分開;以及一介電層,至少部分地位於該半導體基板上,其中該第一介電結構橫向分開該介電層與該第一閘極結構的第一部分,且該第二介電結構橫向分開該介電層與該第二閘極結構的第一部分。 A semiconductor device comprises: a first semiconductor fin and a second semiconductor fin protruding vertically from a semiconductor substrate, wherein the second semiconductor fin is laterally separated from the first semiconductor fin in a first direction, wherein the first semiconductor fin and the second semiconductor fin extend laterally and parallel to each other in a second direction, and wherein the second direction is substantially perpendicular to the semiconductor substrate. the first direction; a first gate structure located on the first semiconductor fin; a second gate structure located on the second semiconductor fin and laterally separated from the first gate structure in the first direction; a first dielectric fin located on the semiconductor substrate, wherein the first dielectric fin is located between the first semiconductor fin and the second semiconductor fin, and the first a second dielectric fin disposed on the semiconductor substrate and laterally separated from the first dielectric fin in the first direction, wherein the second dielectric fin is disposed between the first semiconductor fin and the second semiconductor fin, and between the first gate structure and the second gate structure; a first dielectric structure disposed between the first dielectric fin and the second gate structure a second dielectric structure located on the second dielectric fin and laterally separated from the first semiconductor fin in the first direction; and a dielectric layer at least partially located on the semiconductor substrate, wherein the first dielectric structure laterally separates the dielectric layer from a first portion of the first gate structure, and the second dielectric structure laterally separates the dielectric layer from a first portion of the second gate structure. 如請求項3之半導體裝置,更包括:一第四介電結構,位於該第一閘極結構上並部分地位於該第一介電結構上;一第五介電結構,位於該第二閘極結構上並部分地位於該第二介電結構上,其中:該介電層橫向地位於該第四介電結構與該第五介電結構之間;該介電層部分地位於該第一介電結構與該第二介電結構上;以及該介電層的最下側表面低於該第四介電結構的最下側表面與該第五介電結構的最下側表面。 The semiconductor device of claim 3 further includes: a fourth dielectric structure located on the first gate structure and partially located on the first dielectric structure; a fifth dielectric structure located on the second gate structure and partially located on the second dielectric structure, wherein: the dielectric layer is laterally located between the fourth dielectric structure and the fifth dielectric structure; the dielectric layer is partially located on the first dielectric structure and the second dielectric structure; and the bottom surface of the dielectric layer is lower than the bottom surface of the fourth dielectric structure and the bottom surface of the fifth dielectric structure. 一種半導體裝置,包括:多個第一半導體奈米結構,位於一第一半導體鰭狀物上;多個第二半導體奈米結構,位於一第二半導體鰭狀物上;一第一閘極結構,位於該第一半導體鰭狀物之上以及該些第一半導體奈米結構周圍; 一第二閘極結構,位於該第二半導體鰭狀物之上以及該些第二半導體奈米結構周圍;一第一介電鰭狀物,橫向地位於該些第一半導體奈米結構與該些第二半導體奈米結構之間;一第二介電鰭狀物,橫向地位於該些第一半導體奈米結構與該些第二半導體奈米結構之間;一第一介電結構,位於該第一介電鰭狀物上,其中該第一介電結構具有一第一L形輪廓;一第二介電結構,位於該第二介電鰭狀物上,其中該第二介電結構具有一第二L形輪廓,且其中該第一L形輪廓與該第二L形輪廓面向相反方向;以及一介電層,橫向分開該第一介電鰭狀物與該第二介電鰭狀物、橫向分開該第一閘極結構與該第二閘極結構、並橫向分開該第一介電結構與該第二介電結構,其中該介電層自該介電層的下表面垂直延伸至該介電層的上表面,其中該介電層的下表面低於該第一半導體鰭狀物的上表面,其中該介電層的上表面高於該第一介電結構,且其中該第一介電結構橫向分開該介電層與該第一閘極結構,而該第二介電結構橫向分開該介電層與該第二閘極結構。 A semiconductor device includes: a plurality of first semiconductor nanostructures located on a first semiconductor fin; a plurality of second semiconductor nanostructures located on a second semiconductor fin; a first gate structure located on the first semiconductor fin and around the first semiconductor nanostructures; a second gate structure located on the second semiconductor fin and around the second semiconductor nanostructures; The invention relates to a semiconductor nanostructure having a first dielectric fin disposed around the semiconductor nanostructure; a first dielectric fin disposed laterally between the first semiconductor nanostructure and the second semiconductor nanostructure; a second dielectric fin disposed laterally between the first semiconductor nanostructure and the second semiconductor nanostructure; a first dielectric structure disposed on the first dielectric fin, wherein the first dielectric structure has a first L-shaped profile; and a second a dielectric structure located on the second dielectric fin, wherein the second dielectric structure has a second L-shaped profile, and wherein the first L-shaped profile and the second L-shaped profile face opposite directions; and a dielectric layer laterally separating the first dielectric fin from the second dielectric fin, laterally separating the first gate structure from the second gate structure, and laterally separating the first dielectric structure from the second dielectric junction. The dielectric layer vertically extends from the lower surface of the dielectric layer to the upper surface of the dielectric layer, wherein the lower surface of the dielectric layer is lower than the upper surface of the first semiconductor fin, wherein the upper surface of the dielectric layer is higher than the first dielectric structure, and wherein the first dielectric structure laterally separates the dielectric layer and the first gate structure, and the second dielectric structure laterally separates the dielectric layer and the second gate structure. 一種半導體裝置的形成方法,包括:接收一工件,且該工件包括:一介電鰭狀物,位於一半導體基板之上以及多個第一半導體奈米結構與多個第二半導體奈米結構之間;一第一導電閘極結構,位於該半導體基板之上以及該些第一半導體奈米結構周圍;一第二導電閘極結構,位於該半導體基板之上以及該些第二半導體奈米結構周圍;以及 一介電鰭狀物蓋,位於該介電鰭狀物上,其中該介電鰭狀物蓋與該介電鰭狀物橫向地位於該第一導電閘極結構與該第二導電閘極結構之間,且其中該第一導電閘極結構的上表面與該第二導電閘極結構的上表面垂直地位於該介電鰭狀物蓋的第一上表面與該半導體基板之間;形成一介電層於該介電鰭狀物、該些第一半導體奈米結構、該些第二半導體奈米結構、該第一導電閘極結構、該第二導電閘極結構、與該介電鰭狀物蓋上;形成一第一開口於該介電層中,其中該第一開口部分地位於該介電鰭狀物蓋與該第二導電閘極結構上;以及進行第一蝕刻製程以移除該第二導電閘極結構,且該第一蝕刻製程經由該第一開口暴露該第二導電閘極結構至一第一蝕刻劑。 A method for forming a semiconductor device includes: receiving a workpiece, wherein the workpiece includes: a dielectric fin located on a semiconductor substrate and between a plurality of first semiconductor nanostructures and a plurality of second semiconductor nanostructures; a first conductive gate structure located on the semiconductor substrate and around the first semiconductor nanostructures; a second conductive gate structure located on the semiconductor substrate and around the second semiconductor nanostructures; and a dielectric fin cap located on the dielectric fin, wherein the dielectric fin cap and the dielectric fin are laterally located between the first conductive gate structure and the second conductive gate structure, and wherein the first conductive gate The upper surface of the first conductive gate structure and the upper surface of the second conductive gate structure are vertically located between the first upper surface of the dielectric fin cap and the semiconductor substrate; a dielectric layer is formed on the dielectric fin, the first semiconductor nanostructures, the second semiconductor nanostructures, the first conductive gate structure, the second conductive gate structure, and the dielectric fin cap; a first opening is formed in the dielectric layer, wherein the first opening is partially located on the dielectric fin cap and the second conductive gate structure; and a first etching process is performed to remove the second conductive gate structure, and the first etching process exposes the second conductive gate structure to a first etchant through the first opening. 如請求項6之半導體裝置的形成方法,更包括:在移除該第二導電閘極結構之後,進行一第二蝕刻製程以移除該些第二半導體奈米結構,且第二蝕刻製程經由該第一開口暴露該些第二半導體奈米結構至一第二蝕刻劑,其中該第二蝕刻製程移除該介電鰭狀物蓋的第一部分,且其中該第二蝕刻製程形成一第二開口於該第一開口的外側邊界內。 The method for forming a semiconductor device as claimed in claim 6 further includes: after removing the second conductive gate structure, performing a second etching process to remove the second semiconductor nanostructures, and the second etching process exposes the second semiconductor nanostructures to a second etchant through the first opening, wherein the second etching process removes the first portion of the dielectric fin cap, and wherein the second etching process forms a second opening within the outer boundary of the first opening. 一種半導體裝置的形成方法,包括:形成一第一堆疊的半導體結構於一第一半導體鰭狀物上;形成一第二堆疊的半導體結構於一第二半導體鰭狀物上;形成一介電鰭狀物,其橫向地位於該第一堆疊的半導體結構與該第二堆疊的半導體結構之間;形成一介電帶結構於該介電鰭狀物之上,且該介電帶結構橫向地位於該第一堆疊的半導體結構與該第二堆疊的半導體結構之間;移除該第一堆疊的半導體結構的一部分以形成一第三堆疊的半導體結構; 移除該第二堆疊的半導體結構的一部分以形成一第四堆疊的半導體結構;移除該介電帶結構的一部分以形成一介電結構於該介電鰭狀物上,且該介電結構橫向地位於該第三堆疊的半導體結構與該第四堆疊的半導體結構之間;蝕刻該第三堆疊的半導體結構與該第四堆疊的半導體結構,以形成一第一奈米結構堆疊於該第一半導體鰭狀物上,並形成一第二奈米結構堆疊於該第二半導體鰭狀物上;形成一閘極層於該第一半導體鰭狀物之上、該第二半導體鰭狀物之上、該介電鰭狀物之上、該介電結構之上、該第一奈米結構堆疊周圍、以及該第二奈米結構堆疊周圍;使該閘極層凹陷至低於該介電結構的上表面,以形成一第一閘極結構於該第一奈米結構堆疊周圍與該介電結構的第一側上,並形成一第二閘極結構於該第二奈米結構堆疊周圍與該介電結構的第二側上,且該介電結構的第一側與第二側相對;形成一介電層於該第一閘極結構、該第二閘極結構、該介電鰭狀物、與該介電結構上;形成一開口於該介電層中,其中該開口位於該介電結構與該第二閘極結構上;以及在形成該開口於該介電層中之後,移除該第二閘極結構,其中該開口用於移除該第二閘極結構。 A method for forming a semiconductor device includes: forming a first stacked semiconductor structure on a first semiconductor fin; forming a second stacked semiconductor structure on a second semiconductor fin; forming a dielectric fin, which is laterally located between the first stacked semiconductor structure and the second stacked semiconductor structure; forming a dielectric tape structure on the dielectric fin, and the dielectric tape structure is laterally located between the first stacked semiconductor structure and the second stacked semiconductor structure; removing the dielectric tape structure; A portion of the first stacked semiconductor structure is removed to form a third stacked semiconductor structure; a portion of the second stacked semiconductor structure is removed to form a fourth stacked semiconductor structure; a portion of the dielectric tape structure is removed to form a dielectric structure on the dielectric fin, and the dielectric structure is laterally located between the third stacked semiconductor structure and the fourth stacked semiconductor structure; the third stacked semiconductor structure and the fourth stacked semiconductor structure are etched to form a first nanostructure stack The method further comprises forming a first gate structure on the first semiconductor fin, and forming a second nanostructure stack on the second semiconductor fin; forming a gate layer on the first semiconductor fin, on the second semiconductor fin, on the dielectric fin, on the dielectric structure, around the first nanostructure stack, and around the second nanostructure stack; making the gate layer recessed to a level lower than the upper surface of the dielectric structure to form a first gate structure around the first nanostructure stack and on the first side of the dielectric structure, and forming a A second gate structure is formed around the second nanostructure stack and on the second side of the dielectric structure, and the first side of the dielectric structure is opposite to the second side; a dielectric layer is formed on the first gate structure, the second gate structure, the dielectric fin, and the dielectric structure; an opening is formed in the dielectric layer, wherein the opening is located on the dielectric structure and the second gate structure; and after forming the opening in the dielectric layer, the second gate structure is removed, wherein the opening is used to remove the second gate structure. 如請求項8之半導體裝置的形成方法,其中採用該開口移除該第二閘極結構的步驟包括:進行一蝕刻製程,其經由該開口暴露該第二閘極結構至一蝕刻劑。 A method for forming a semiconductor device as claimed in claim 8, wherein the step of removing the second gate structure using the opening includes: performing an etching process that exposes the second gate structure to an etchant through the opening. 一種半導體裝置的形成方法,包括:接收一工件,且該工件包括: 一第一介電鰭狀物,位於一半導體基板上並橫向地位於多個第一半導體奈米結構與多個第二半導體奈米結構之間;一第二介電鰭狀物,位於該半導體基板上並橫向地位於多個第三半導體奈米結構與該些第二半導體奈米結構之間;一第一導電閘極結構,位於該半導體基板上並圍繞該些第一半導體奈米結構;一第二導電閘極結構,位於該半導體基板上並圍繞該些第二半導體奈米結構;一第三導電閘極結構,位於該半導體基板上並圍繞該些第三半導體奈米結構,其中該第二導電閘極結構位於該第一導電閘極結構與該第三導電閘極結構之間,並與該第一導電閘極結構及該第三導電閘極結構橫向分開;一第一介電結構,位於該第一介電鰭狀物上,其中該第一介電結構與該第一介電鰭狀物橫向分開該第一導電閘極結構與該第二導電閘極結構;以及一第二介電結構,位於該第二介電鰭狀物上,其中該第二介電結構與該第二介電鰭狀物橫向分開該第三導電閘極結構與該第二導電閘極結構;形成一第一介電層於該第一介電鰭狀物、該第二介電鰭狀物、該些第一半導體奈米結構、該些第二半導體奈米結構、該些第三半導體奈米結構、該第一介電結構、該第二介電結構、該第一導電閘極結構、該第二導電閘極結構、與該第三導電閘極結構上;形成一第一開口於該第一介電層中,其中該第一開口至少部分地位於該第一介電結構、該第二介電結構、與該第二導電閘極結構上;移除該第二導電閘極結構;移除該第一開口下的該第一介電結構之一部分,以形成該第一介電鰭狀物 上的一第三介電結構;移除該第一開口下的該第二介電結構之一部分,以形成該第二介電鰭狀物上的一第四介電結構;移除該些第二半導體奈米結構,以形成一第二開口於該第一開口下;以及形成一第二介電層於該第一開口與該第二開口中,並至少部分地位於該第三介電結構與該第四介電結構上。 A method for forming a semiconductor device includes: receiving a workpiece, wherein the workpiece includes: a first dielectric fin, located on a semiconductor substrate and laterally located between a plurality of first semiconductor nanostructures and a plurality of second semiconductor nanostructures; a second dielectric fin, located on the semiconductor substrate and laterally located between a plurality of third semiconductor nanostructures and the second semiconductor nanostructures; a first conductive gate structure, located on the semiconductor substrate and surrounding the first semiconductor nanostructures; a second conductive gate structure, located on the semiconductor substrate and surrounding the second semiconductor nanostructures; a third conductive gate structure located on the semiconductor substrate and surrounding the third semiconductor nanostructures, wherein the second conductive gate structure is located between the first conductive gate structure and the third conductive gate structure and is laterally separated from the first conductive gate structure and the third conductive gate structure; a first dielectric structure located on the first dielectric fin, wherein the first dielectric structure and the first dielectric fin laterally separate the first conductive gate structure and the second conductive gate structure; and a second dielectric structure located on the second dielectric fin, wherein the second The third conductive gate structure and the second conductive gate structure are laterally separated by the dielectric structure and the second dielectric fin; a first dielectric layer is formed on the first dielectric fin, the second dielectric fin, the first semiconductor nanostructures, the second semiconductor nanostructures, the third semiconductor nanostructures, the first dielectric structure, the second dielectric structure, the first conductive gate structure, the second conductive gate structure, and the third conductive gate structure; a first opening is formed in the first dielectric layer, wherein the first opening is at least partially located between the first dielectric structure, the second dielectric structure, and the third conductive gate structure. structure, and the second conductive gate structure; removing the second conductive gate structure; removing a portion of the first dielectric structure under the first opening to form a third dielectric structure on the first dielectric fin; removing a portion of the second dielectric structure under the first opening to form a fourth dielectric structure on the second dielectric fin; removing the second semiconductor nanostructures to form a second opening under the first opening; and forming a second dielectric layer in the first opening and the second opening, and at least partially on the third dielectric structure and the fourth dielectric structure.
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