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TWI863285B - Titanium plasma hydrogenation machine - Google Patents

Titanium plasma hydrogenation machine Download PDF

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TWI863285B
TWI863285B TW112118246A TW112118246A TWI863285B TW I863285 B TWI863285 B TW I863285B TW 112118246 A TW112118246 A TW 112118246A TW 112118246 A TW112118246 A TW 112118246A TW I863285 B TWI863285 B TW I863285B
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water
filter element
tubular shell
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wavelength
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TW202446726A (en
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韓文卿
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福德綠能有限公司
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Abstract

本發明提供一種水處理設備,其包含: 採用純鈦材料製成之一管狀殼體,其內部具有沿著一橫向軸線延伸之一容置空間; 一波長380 nm之紫外燈管,其外包覆石英管,由該管狀殼體中央位置之一側管以垂直於該橫向軸線的方向插入該管狀殼體內; 於該管狀殼體之兩端各配置有一鈦製管蓋,其各與該管狀殼體兩端接合,其中一端之管蓋係連接至一進水口,及另一端之管蓋係連接至一出水口; 第一道濾芯,其為燒結純鈦粉末材質,具有一濾芯開口接合至該進水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第一道濾芯之殼體內部具有銀粒子鍍膜,及具有一波長265 nm之冷陰極紫外光滅菌器設置於其中;及 第二道濾芯,其為燒結純鈦粉末材質,具有一濾芯開口接合至該出水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第二道濾芯之殼體內部具有奈米金粒子鍍膜,及具有一波長532 nm之冷陰極綠光表面電漿共振反應器設置於其中。 The present invention provides a water treatment device, which comprises: A tubular shell made of pure titanium material, the interior of which has a containing space extending along a transverse axis; An ultraviolet lamp tube with a wavelength of 380 nm, which is covered with a quartz tube, and is inserted into the tubular shell from a side tube at the center of the tubular shell in a direction perpendicular to the transverse axis; A titanium tube cover is disposed at each end of the tubular shell, each of which is connected to the two ends of the tubular shell, and the tube cover at one end is connected to a water inlet, and the tube cover at the other end is connected to a water outlet; The first filter element is made of sintered pure titanium powder material, and has a filter element opening connected to the tube cover at the water inlet end, so as to be arranged in the accommodation space of the tubular shell, wherein the shell of the first filter element has a silver particle coating inside, and a cold cathode ultraviolet sterilizer with a wavelength of 265 nm is arranged therein; and The second filter element is made of sintered pure titanium powder material, and has a filter element opening connected to the tube cover at the water outlet end, so as to be arranged in the accommodation space of the tubular shell, wherein the shell of the second filter element has a nano-gold particle coating inside, and a cold cathode green light surface plasmon resonance reactor with a wavelength of 532 nm is arranged therein.

Description

鈦電漿氫水機Titanium plasma hydrogenation machine

本發明係有關於一種水處理設備,其採用純鈦管材製成,可用於自來水直飲淨水機;且特別有關於一種兼具過濾、產氫、除氯及小分子化等功能的水處理設備。The present invention relates to a water treatment device which is made of pure titanium pipe and can be used in a tap water purifier; and in particular to a water treatment device which has the functions of filtering, hydrogen production, chlorine removal and small molecule conversion.

水處理技術長久以來為使用薄膜過濾為主,一般家用淨水過濾器之外殼及濾芯的材質種類相當多,其基本上為塑膠、活性碳纖維,必須定期拋棄換新,無法清洗重複使用,經年累月耗費高額成本及大量資材,但若未按時更換,則會造成二次污染及細菌感染風險。另外,在工業上有使用金屬不鏽鋼殼體及纖維濾芯之可清洗過濾系統;亦有由鈦金屬製造過濾器之外殼及濾芯,其係用於耐酸鹼腐蝕的化工業,較少見於市售民生飲水的過濾器中。Water treatment technology has long been based on membrane filtration. The materials of the housing and filter element of household water purifiers are quite diverse, and they are basically plastic and activated carbon fibers. They must be discarded and replaced regularly, and cannot be cleaned and reused. Over the years, they consume high costs and a large amount of materials. However, if they are not replaced on time, they will cause secondary pollution and the risk of bacterial infection. In addition, there are industrial washable filter systems that use metal stainless steel housings and fiber filter elements; there are also filter housings and filter elements made of titanium metal, which are used in the chemical industry to resist acid and alkali corrosion, and are rarely seen in commercially available filters for drinking water.

目前市面上的淨水過濾裝置少則使用三或四道,多則七或八道過濾管,例如,典型的逆滲透(RO)淨水器係使用七至八道過濾管加上真空桶。然,過濾管的數目並不一定越多越好,反而可能風險越高,相對費用成本也越高。The water filtration devices currently available on the market use at least three or four, and at most seven or eight filter tubes. For example, a typical reverse osmosis (RO) water purifier uses seven to eight filter tubes plus a vacuum tank. However, the more filter tubes there are, the better. On the contrary, the risk may be higher and the relative cost may be higher.

因此,需要一種過濾管數目減少,濾芯能夠清洗重複使用,及整合過濾、滅菌、除氯、除重金屬、除水垢、產氫、小分子化等多功能於一體之水處理設備。Therefore, there is a need for a water treatment device that reduces the number of filter tubes, allows filter elements to be cleaned and reused, and integrates multiple functions such as filtration, sterilization, chlorine removal, heavy metal removal, scale removal, hydrogen production, and small molecule reduction.

純鈦是安全無毒的金屬,生物可利用性佳,質輕且耐酸鹼腐蝕,適合作為水容器。鈦金屬表面會自然形成氧化膜,或可經高溫加熱氧化處理,為一種耐蝕性極佳、鍍膜穩定性高之材料。亦有使用高溫燒結鈦粉末應用於水處理濾芯,適合用於含剛性顆粒的低黏度料液進行固液分離。Pure titanium is a safe and non-toxic metal with good bioavailability, light weight and acid and alkali corrosion resistance, making it suitable as a water container. An oxide film will naturally form on the surface of titanium metal, or it can be treated by high-temperature heating and oxidation. It is a material with excellent corrosion resistance and high coating stability. High-temperature sintered titanium powder is also used in water treatment filter elements, which are suitable for solid-liquid separation of low-viscosity liquid containing rigid particles.

二氧化鈦被發現具有在紫外光照射下把水分子分解成氫氣的光化學特性,因而可作為光觸媒材料。二氧化鈦之晶體結構為銳鈦礦相時具有較佳的光觸媒活性,由於銳鈦礦相二氧化鈦的能隙大小約為3.2電子伏特,以能隙大小來換算所需光能的波長,可得出波長為387.5 nm,故欲將二氧化鈦的電子自價帶激發至導電帶,必須提供波長小於387.5 nm的紫外線光源,二氧化鈦才能產生氧化還原反應,達到去除臭味或分解雜質等功效。常見二氧化鈦光觸媒材料係塗布在濾網上以作為空氣過濾之用。Titanium dioxide has been found to have the photochemical property of decomposing water molecules into hydrogen under ultraviolet light, so it can be used as a photocatalyst material. Titanium dioxide has better photocatalytic activity when its crystal structure is in the tantalum phase. Since the energy gap of tantalum phase titanium dioxide is about 3.2 electron volts, the wavelength of the required light energy can be converted to 387.5 nm by using the energy gap size. Therefore, in order to excite the electrons of titanium dioxide from the valence band to the conduction band, an ultraviolet light source with a wavelength less than 387.5 nm must be provided so that titanium dioxide can produce redox reactions and achieve the effects of removing odors or decomposing impurities. Common titanium dioxide photocatalyst materials are coated on filters for air filtration.

波長範圍100至280 nm之紫外光(UV-C)已被證明具有殺菌功能,專業純水系統及一般飲用水已廣泛使用紫外線殺菌法以達到微生物控制目的。Ultraviolet light (UV-C) with a wavelength range of 100 to 280 nm has been proven to have a sterilizing function. Professional water purification systems and general drinking water have widely used UV sterilization to achieve the purpose of microbial control.

在改善水分子的應用上已有利用表面電漿共振(Surface Plasmon Resonance;SPR)效應,使水與奈米金屬顆粒接觸並照光後,獲得小分子團水。奈米金粒子吸收波長532 nm之LED綠光可產生表面電漿共振效應,水會隨之產生共振,進而將水中部分氫鍵打斷,使水分子結構弱化而形成小分子水。經活化之小分子水具有顯著的導電效果、高滲透性,以及抗發炎、抗自由基的效益。In the application of improving water molecules, the surface plasmon resonance (SPR) effect has been used to make water contact with nano-metal particles and illuminate them to obtain small molecular water. Nano-gold particles absorb LED green light with a wavelength of 532 nm to produce a surface plasmon resonance effect, which will cause water to resonate and break some hydrogen bonds in the water, weakening the water molecule structure and forming small molecule water. The activated small molecule water has significant conductivity, high permeability, and anti-inflammatory and anti-free radical benefits.

此外,奈米銀基於靜電力作用亦可用於抗菌。由於細菌的細胞膜多呈負電性,銀離子帶有正電荷,銀離子因靜電可穿透細胞膜而與細菌蛋白質上的硫醇基產生化學反應而凝固,達到殺菌的效果,亦有應用於淨水系統之奈米銀濾材。In addition, nanosilver can also be used for antibacterial purposes based on electrostatic effects. Since bacterial cell membranes are mostly negatively charged, silver ions carry positive charges. Silver ions can penetrate cell membranes due to electrostatic charges and react chemically with thiol groups on bacterial proteins to coagulate, achieving a sterilizing effect. Nanosilver filters are also used in water purification systems.

然,目前仍未有整合鈦金屬材料、半導體材料、光化學(例如光觸媒反應及表面電漿共振)等水處理技術的設計。However, there is still no design that integrates titanium metal materials, semiconductor materials, photochemistry (such as photocatalytic reaction and surface plasmon resonance) and other water treatment technologies.

本發明之目的係提供一種整合純鈦材料及應用技術之水處理設備,其具備水處理的過濾、滅菌、除氯、除重金屬、除水垢、產氫、小分子化等多功能於一體,以製造生飲等級之含氫小分子水。The purpose of the present invention is to provide a water treatment device that integrates pure titanium materials and application technology, which has multiple functions of water treatment such as filtration, sterilization, chlorine removal, heavy metal removal, scale removal, hydrogen production, and small molecule conversion, so as to produce drinking-grade hydrogen-containing small molecule water.

本發明提供一種水處理設備,其包含: 採用純鈦材料製成之一管狀殼體,其內部具有沿著一橫向軸線延伸之一容置空間; 一波長380 nm之紫外燈管,其外包覆石英管,由該管狀殼體中央位置之一側管以垂直於該橫向軸線的方向插入該管狀殼體內; 於該管狀殼體之兩端各配置有一鈦製管蓋,其各與該管狀殼體兩端接合,其中一端之管蓋係連接至一進水口,及另一端之管蓋係連接至一出水口; 第一道濾芯,其為燒結純鈦粉末材質,具有一濾芯開口接合至該進水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第一道濾芯之殼體內部具有銀粒子鍍膜,及具有一波長265 nm之冷陰極紫外光滅菌器設置於其中;及 第二道濾芯,其為燒結純鈦粉末材質,具有一濾芯開口接合至該出水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第二道濾芯之殼體內部具有奈米金粒子鍍膜,及具有一波長532 nm之冷陰極綠光表面電漿共振反應器設置於其中。 The present invention provides a water treatment device, which comprises: A tubular shell made of pure titanium material, the interior of which has a containing space extending along a transverse axis; An ultraviolet lamp tube with a wavelength of 380 nm, which is covered with a quartz tube, and is inserted into the tubular shell from a side tube at the center of the tubular shell in a direction perpendicular to the transverse axis; A titanium tube cover is disposed at each end of the tubular shell, each of which is connected to the two ends of the tubular shell, and the tube cover at one end is connected to a water inlet, and the tube cover at the other end is connected to a water outlet; The first filter element is made of sintered pure titanium powder material, and has a filter element opening connected to the tube cover at the water inlet end, so as to be arranged in the accommodation space of the tubular shell, wherein the shell of the first filter element has a silver particle coating inside, and a cold cathode ultraviolet sterilizer with a wavelength of 265 nm is arranged therein; and The second filter element is made of sintered pure titanium powder material, and has a filter element opening connected to the tube cover at the water outlet end, so as to be arranged in the accommodation space of the tubular shell, wherein the shell of the second filter element has a nano-gold particle coating inside, and a cold cathode green light surface plasmon resonance reactor with a wavelength of 532 nm is arranged therein.

本發明之鈦製管材殼體、管蓋及燒結純鈦粉末之濾芯皆經過拋光、高熱氧化處理,因此容器內不易滋生細菌,產生異味;且可反覆清洗使用,無須如一般濾水器更換濾芯,而產生大量耗材。本發明水處理設備之主體結構皆為採用純鈦材料設計而成,所使用之純鈦材料必須經由以下加工程序,包括:拋光處理,熱氧化處理,CNC切割及雷射焊接。高溫熱氧化處理溫度為400℃至900℃,依照溫度不同會產生不同顏色之外觀,400℃可形成金黃色,500℃可形成藍色,600℃可形成紫色,700℃至800℃可形成灰紅色,900℃可形成灰色之氧化鈦膜。The titanium tube shell, tube cover and filter element of sintered pure titanium powder of the present invention have all been polished and subjected to high-temperature oxidation treatment, so it is not easy for bacteria to grow in the container and produce odor; and it can be cleaned and used repeatedly, without the need to replace the filter element like a general water filter, which produces a large amount of consumables. The main structure of the water treatment equipment of the present invention is designed with pure titanium materials. The pure titanium materials used must undergo the following processing procedures, including: polishing treatment, thermal oxidation treatment, CNC cutting and laser welding. The high temperature thermal oxidation treatment temperature is 400℃ to 900℃. Different colors of appearance will be produced according to the temperature. 400℃ can form golden yellow, 500℃ can form blue, 600℃ can form purple, 700℃ to 800℃ can form gray-red, and 900℃ can form a gray titanium oxide film.

管狀殼體之兩端所配置之該等鈦製管蓋係各由一第一法蘭盤及一第二法蘭盤構成,其藉由複數個鈦製螺栓固定。該第一法蘭盤係經由其中央通孔連接至該濾芯開口,將濾芯配置於該管狀殼體之容置空間中;該第二法蘭盤之一側與該第一法蘭盤相連接,另一側係經由其中央通孔連接至一水管轉接頭。The titanium tube covers disposed at both ends of the tubular housing are each composed of a first flange and a second flange, which are fixed by a plurality of titanium bolts. The first flange is connected to the filter element opening through its central through hole, and the filter element is disposed in the accommodation space of the tubular housing; one side of the second flange is connected to the first flange, and the other side is connected to a water pipe adapter through its central through hole.

該第一道濾芯中燒結純鈦粉末濾芯之孔徑為2 µm,將自來水經進水口導入該第一道濾芯之殼體內部,由內向第一道濾芯殼體外溢出至管狀殼體之容置空間中,進行初過濾;該第二道濾芯中燒結純鈦粉末濾芯之孔徑為0.2 µm,將管狀殼體之容置空間中經初過濾的水,由第二道濾芯殼體外進入第二道濾芯殼體內,進行超濾過濾之後,經出水口出水。The pore size of the sintered pure titanium powder filter element in the first filter element is 2 µm. Tap water is introduced into the interior of the shell of the first filter element through the water inlet, and overflows from the inside to the outside of the first filter element shell to the containing space of the tubular shell for primary filtration. The pore size of the sintered pure titanium powder filter element in the second filter element is 0.2 µm. The water that has been initially filtered in the containing space of the tubular shell enters the second filter element shell from the outside of the second filter element shell, and after ultrafiltration, it is discharged through the water outlet.

經由上述第一及第二道濾芯過濾的同時,於第一道濾芯之殼體內層鍍銀粒子及照射波長265 nm之紫外光係具有滅菌作用,並作為光觸媒反應器,產生除氯及產氫作用;於第二濾芯組之殼體內層鍍奈米金粒子及照射波長532 nm之綠光係可作為表面電漿共振反應器,將水小分子化。While being filtered by the first and second filter elements, the silver-plated particles on the inner layer of the shell of the first filter element and the irradiation of ultraviolet light with a wavelength of 265 nm have a sterilization effect and act as a photocatalyst reactor to produce chlorine removal and hydrogen production; the nano-gold particles on the inner layer of the shell of the second filter element group and the irradiation of green light with a wavelength of 532 nm can act as a surface plasmon resonance reactor to reduce water molecules.

因此,本發明之整合純鈦材料及應用技術之水處理設備相當於具備以下功能之裝置組合: (1)     紫外燈滅菌器:純鈦濾芯結合冷陰極紫外燈管特定波長265 nm的應用置放於第一道濾芯內,對自進水口通入的自來水進行紫外光滅菌作用; (2)     光觸媒反應器:純鈦殼體結合紫外燈管特定波長380 nm的應用置放於第一道濾芯過濾後的淨水,進行水與光觸媒、二氧化鈦三者光催化反應,除氯、分解污染物、及產生氫氣等綜效作用; (3)     電漿共振反應器:純鈦濾芯與冷陰極綠光532 nm波長燈管結合應用置放於第二道濾芯內,以綠光光照與濾芯鍍膜金粒子對第一道濾芯過濾的淨水三者進行表面電漿共振,小分子化水及產氫作用,產生水質改質作用。 Therefore, the water treatment equipment of the present invention that integrates pure titanium materials and application technologies is equivalent to a device combination with the following functions: (1)     Ultraviolet light sterilizer: The pure titanium filter element combined with the cold cathode ultraviolet lamp with a specific wavelength of 265 nm is placed in the first filter element to sterilize the tap water introduced from the water inlet with ultraviolet light; (2)     Photocatalyst reactor: The pure titanium shell combined with the ultraviolet lamp with a specific wavelength of 380 nm is placed in the purified water after filtration by the first filter element to perform a photocatalytic reaction between water, photocatalyst, and titanium dioxide to remove chlorine, decompose pollutants, and produce hydrogen; (3)    Plasma resonance reactor: The pure titanium filter element and the cold cathode green light 532 nm wavelength lamp are combined and placed in the second filter element. The green light illumination and the gold particles coated on the filter element are used to perform surface plasma resonance on the purified water filtered by the first filter element, resulting in small molecule water and hydrogen production, thus improving the water quality.

本發明另提供一種自來水通過本發明水處理設備之淨水製程,其包括: 第一步驟:過濾與滅菌的雙重作用 自來水從進水口導入孔徑2 µm之第一道濾芯,在第一道濾芯內部產生內壓,由內往外通過濾芯過濾,過濾後水中顆粒雜質為20萬至30萬顆粒單位,同時水流在波長265 nm之紫外線照射下滅菌,並與在濾芯殼體內部的銀粒子鍍膜接觸,強化滅菌作用。 第二步驟:二氧化鈦光觸媒除污除氯產氫 經第一步驟處理後的水進入管狀殼體之容置空間中,純鈦材料製成之管狀殼體經高溫400℃熱氧化處理,形成含有半導體二氧化鈦光觸媒之氧化膜,經波長380 nm之紫外線照射下進行光催化反應,除去水中氯氣、分解污染物、及產生氫氣。 第三步驟:表面電漿共振產氫小分子化 經第二步驟處理後的水經外壓作用,從第二道濾芯之殼體外部進入濾芯內部,第二道濾芯之孔徑為0.2 µm,可過濾掉細菌等級之顆粒,過濾後水中顆粒僅剩數千顆粒單位,達到生飲等級,同時經第二道濾芯內波長532 nm之綠光照射與濾芯殼體內部鍍膜的金粒子進行表面電漿共振作用,將水小分子化改質,並產出更多氫水,提高飲水的機能性效果。 The present invention also provides a water purification process for tap water passing through the water treatment equipment of the present invention, which includes: Step 1: Dual effects of filtration and sterilization Tap water is introduced into the first filter element with a pore size of 2 µm from the water inlet, and internal pressure is generated inside the first filter element. The water passes through the filter element from the inside to the outside, and the particle impurities in the water after filtration are 200,000 to 300,000 particle units. At the same time, the water flow is sterilized under ultraviolet light with a wavelength of 265 nm, and contacts the silver particle coating inside the filter element shell to enhance the sterilization effect. Step 2: Titanium dioxide photocatalyst for decontamination, chlorine removal and hydrogen production The water treated in the first step enters the storage space of the tubular shell. The tubular shell made of pure titanium material is subjected to high temperature 400℃ thermal oxidation treatment to form an oxide film containing semiconductor titanium dioxide photocatalyst. Under the irradiation of ultraviolet light with a wavelength of 380 nm, a photocatalytic reaction is carried out to remove chlorine in the water, decompose pollutants, and produce hydrogen. Step 3: Surface Plasma Resonance Hydrogen Small Molecules After the second step, the water is treated by external pressure and enters the second filter element from the outside of the shell. The pore size of the second filter element is 0.2 µm, which can filter out bacteria-level particles. After filtration, there are only thousands of particles in the water, reaching the drinking level. At the same time, the green light with a wavelength of 532 nm in the second filter element and the gold particles coated on the inside of the filter element shell undergo surface plasmon resonance, which modifies the water into small molecules and produces more hydrogen water, improving the functional effect of drinking water.

根據本發明之態樣,自來水通過本發明水處理設備之淨水製程所獲得之淨水定義為「鈦電漿氫水」,其為經紫外光及銀粒子滅菌,經孔徑0.2 µm的濾芯濾除細菌,經二氧化鈦光觸媒除氯,除臭分解各種污染物,經光觸媒與表面電漿共振的氫分子水,及經表面電漿共振改質的小分子水。According to the present invention, the clean water obtained by the water purification process of the water treatment equipment of the present invention is defined as "titanium plasma hydrogen water", which is sterilized by ultraviolet light and silver particles, filtered by a filter element with a pore size of 0.2 µm, dechlorinated by titanium dioxide photocatalyst, deodorized and decomposed various pollutants, hydrogen molecule water by photocatalyst and surface plasmon resonance, and small molecule water modified by surface plasmon resonance.

本發明水處理設備係可手動拆開設備組件,用水沖洗或超音波清洗濾芯內外及管狀殼體內部。於濾芯內部配置一電磁感應閥,設定水壓小於1公斤時,提醒清洗。於管狀殼體內部亦配置一電磁感應閥,設定水壓小於0.5公斤時,提醒清洗。The water treatment equipment of the present invention can be manually disassembled to clean the filter element and the inside and outside of the tubular housing by water flushing or ultrasonic cleaning. An electromagnetic induction valve is arranged inside the filter element to remind cleaning when the water pressure is set to less than 1 kg. An electromagnetic induction valve is also arranged inside the tubular housing to remind cleaning when the water pressure is set to less than 0.5 kg.

以下參照圖式對實施態樣進一步說明。說明中使用之圖式為示意圖,圖式中各元件之尺寸關係、比例與實際狀況未必相同。The following further describes the embodiments with reference to the drawings. The drawings used in the description are schematic diagrams, and the size relationship and ratio of each element in the drawings may not be the same as the actual situation.

圖1A及圖1B為本發明水處理設備之一具體實施例之示意圖。參照圖1A及圖1B,本發明之水處理設備10係包含:採用純鈦材料製成之一管狀殼體20,其內部具有沿著一橫向軸線延伸之一容置空間;一波長380 nm之紫外燈管35,其外包覆石英管,由該管狀殼體20中央位置之一側管30插入該管狀殼體內;於該管狀殼體之兩端各配置有一鈦製管蓋,其係各由一第一法蘭盤40a及一第二法蘭盤40b構成,其中一端之管蓋係連接至一進水口,及另一端之管蓋係連接至一出水口;第一道濾芯50,其為燒結純鈦粉末材質,具有一濾芯開口接合至該進水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第一道濾芯之殼體內部具有銀粒子鍍膜,及具有一波長265 nm之冷陰極紫外光滅菌器55設置於其中;及第二道濾芯60,其為燒結純鈦粉末材質,具有一濾芯開口接合至該出水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第二道濾芯之殼體內部具有奈米金粒子鍍膜,及具有一波長532 nm之冷陰極綠光表面電漿共振反應器65設置於其中。FIG. 1A and FIG. 1B are schematic diagrams of a specific embodiment of the water treatment device of the present invention. Referring to FIG. 1A and FIG. 1B, the water treatment device 10 of the present invention comprises: a tubular shell 20 made of pure titanium material, the interior of which has a containing space extending along a transverse axis; a wavelength of 380 The ultraviolet lamp tube 35 of 1000 nm is covered with a quartz tube and is inserted into the tubular shell through a side tube 30 at the central position of the tubular shell 20; a titanium tube cap is disposed at each end of the tubular shell, each of which is composed of a first flange 40a and a second flange 40b, wherein the tube cap at one end is connected to a water inlet, and the tube cap at the other end is connected to a water outlet; the first filter element 50 is made of sintered pure titanium powder material, and has a filter element opening connected to the tube cap at the water inlet end, so as to be disposed in the accommodation space of the tubular shell, wherein the shell of the first filter element has a silver particle coating inside, and has a wavelength of 265 nm cold cathode ultraviolet sterilizer 55 is arranged therein; and a second filter element 60, which is a sintered pure titanium powder material, has a filter element opening connected to the pipe cover at the outlet end, so as to be arranged in the accommodating space of the tubular shell, wherein the shell of the second filter element has a nano-gold particle coating inside, and a cold cathode green light surface plasmon resonance reactor 65 with a wavelength of 532 nm is arranged therein.

上述水處理設備之組件皆經高溫400℃以上高溫熱氧化處理,鈦粉末燒結為700℃以上高溫燒結處理。The components of the above water treatment equipment are all subjected to high temperature thermal oxidation treatment at a temperature above 400°C, and the titanium powder is sintered at a high temperature above 700°C.

本發明純鈦粉末燒結製成的多孔性材料濾芯之過濾精度為:第一道濾芯過濾孔徑為2 µm,可過濾水中雜質,過濾後水中顆粒約10至20萬顆;及第二道濾芯過濾孔徑為0.2 µm,可過濾掉細菌等級,過濾後水中顆粒僅數千個。過濾水流量為1公斤至2公斤水壓範圍內,每分鐘為6公升之流量。濾芯與管蓋採法蘭接合,容易拆解,可手動清洗濾芯,定期清洗免換濾芯,可長久使用。The filtration accuracy of the porous material filter element made by sintering pure titanium powder of the present invention is as follows: the pore size of the first filter element is 2 µm, which can filter impurities in the water, and there are about 100,000 to 200,000 particles in the water after filtration; and the pore size of the second filter element is 0.2 µm, which can filter out bacteria, and there are only thousands of particles in the water after filtration. The flow rate of filtered water is within the range of 1 kg to 2 kg water pressure, and the flow rate is 6 liters per minute. The filter element and the pipe cover are flange-joined, which is easy to disassemble, and the filter element can be manually cleaned. Regular cleaning does not require replacement of the filter element, and it can be used for a long time.

第一道濾芯為純鈦粉末燒結濾芯,其於濾芯殼體內部鍍膜奈米薄膜銀粒子,作為水處理滅菌器,與紫外光照射,達成雙重滅菌作用。第二道濾芯為純鈦粉末燒結濾芯,由於鈦具有無磁性的特性,不與其他金屬產生共振,在純鈦基材料之濾芯殼體內部鍍膜奈米薄膜金粒子,作為表面電漿共振腔體。The first filter is a pure titanium powder sintered filter. The inner part of the filter shell is coated with nano-film silver particles, which serves as a water treatment sterilizer. Together with ultraviolet light irradiation, it achieves a double sterilization effect. The second filter is a pure titanium powder sintered filter. Since titanium has a non-magnetic property and does not resonate with other metals, the inner part of the pure titanium-based filter shell is coated with nano-film gold particles, which serves as a surface plasmon resonance cavity.

本發明所使用之冷陰極防水石英燈管裝置包括:冷陰極紫外光波長265 nm燈管,配置於進水口端的第一道濾芯內部;冷陰極紫外光波長380 nm燈管,配置於管狀殼體內部;及冷陰極綠光波長532 nm燈管,配置於出水口端的第二道濾芯內部。The cold cathode waterproof quartz lamp device used in the present invention includes: a cold cathode ultraviolet light wavelength 265 nm lamp, which is arranged inside the first filter core at the water inlet end; a cold cathode ultraviolet light wavelength 380 nm lamp, which is arranged inside the tubular shell; and a cold cathode green light wavelength 532 nm lamp, which is arranged inside the second filter core at the water outlet end.

本發明水處理設備另配置有電源DC 24V,及流量監測之電磁感應閥。配置於濾芯內部之電磁感應閥設定為水壓小於1公斤時提醒清洗;配置於管狀殼體內部之電磁感應閥設定為水壓小於0.5公斤時提醒清洗。The water treatment equipment of the present invention is also equipped with a power supply DC 24V and an electromagnetic induction valve for flow monitoring. The electromagnetic induction valve installed inside the filter element is set to remind cleaning when the water pressure is less than 1 kg; the electromagnetic induction valve installed inside the tubular shell is set to remind cleaning when the water pressure is less than 0.5 kg.

根據本發明之一具體例,其為整合純鈦材料及應用技術之水處理設備,具備過濾、滅菌、除氯、除重金屬、除水垢、產氫、及小分子化等多功能於一體,所產出的淨水達到生飲等級,並為含氫小分子水。管狀殼體與濾芯殼體都經過加熱至400℃高溫熱氧化,形成金黃色氧化鈦膜40 µm,濾芯殼體內鍍有金屬薄膜,其中第一道濾芯內部鍍有銀粒子,作為光觸媒反應器,產生光觸媒反應及滅菌作用;第二道濾芯內部鍍有金粒子,作為電漿共振反應器,金粒子與綠光光源共振,將水小分子化。經兩道濾芯可有效過濾水中雜質、細菌,及去除重金屬及水垢等。紫外光波長265 nm照射濾芯內二氧化鈦及鍍銀粒子亦可形成光觸媒反應器,產生滅菌、除氯及產氫作用;綠光LED波長532 nm與濾芯內鍍金粒子10 nm形成電漿共振腔,可使水小分子化。According to a specific example of the present invention, it is a water treatment device that integrates pure titanium materials and application technology, and has multiple functions such as filtration, sterilization, chlorine removal, heavy metal removal, scale removal, hydrogen production, and small molecule reduction. The produced clean water reaches the drinking level and is hydrogen-containing small molecule water. The tubular shell and the filter shell are heated to 400℃ for high-temperature thermal oxidation to form a golden titanium oxide film of 40 µm. The filter shell is plated with a metal film, in which the first filter is plated with silver particles inside, which serves as a photocatalytic reactor to produce a photocatalytic reaction and sterilization effect; the second filter is plated with gold particles inside, which serves as a plasma resonance reactor. The gold particles resonate with the green light source to reduce the water molecules. The two filters can effectively filter impurities and bacteria in the water, and remove heavy metals and scale, etc. The ultraviolet light with a wavelength of 265 nm can also form a photocatalytic reactor by irradiating the titanium dioxide and silver-plated particles in the filter element, producing sterilization, chlorine removal and hydrogen production; the green light LED with a wavelength of 532 nm and the gold-plated particles of 10 nm in the filter element form a plasma resonance cavity, which can reduce water molecules.

根據本發明水處理設備10之一具體例,參照圖2之組裝分解圖。水處理設備10所設計之構造為圓形管狀,為沿著橫向軸線延伸以臥式平放,兩端各具有一管蓋,與管狀殼體20接合。管狀殼體的長度為60至80公分長,外徑8至12公分,殼體厚度為0.1至0.5公分。管狀殼體之容置空間中於兩端各安裝一濾芯,濾芯長度為10至30公分,內徑為5至7公分,濾芯殼體厚度為約0.1公分,鈦粉末燒結厚度為約100 µm,濾芯為單開口型式,開口端可使用螺牙與兩端之管蓋接合。第一道濾芯50係通過水管轉接頭70與進水口接合,為初過濾,孔徑為2至5 µm,向濾芯殼體內部進水,由內向濾芯殼體外溢出至管狀殼體之容置空間中;第二道濾芯60係通過水管轉接頭70與出水口接合,為超濾過濾,孔徑為約0.2 µm,管狀殼體之容置空間中經初過濾的水,由第二道濾芯的濾芯殼體外進入內部,並流入出水口出水。管狀殼體中央位置設有一側管30,用於裝置UV-A波長380 nm之紫外光燈管,燈管外包覆石英管,經由該側管30以垂直於該管狀殼體20的方向插入管狀殼體中;第一道濾芯50的濾芯殼體內裝置波長254至265 nm之紫外燈管,紫外光與濾芯殼體內氧化鈦與銀粒子係作為光觸媒反應器,同時具有滅菌、吸附氯及產氫的作用;第二道濾芯60的濾芯殼體內裝置波長532 nm之綠光燈管,綠光與濾芯殼體內的金粒子產生電漿共振,將其中的水小分子化。管狀殼體20兩端之管蓋係由二片鈦板加工製成,如法蘭盤型式,其例如為八角形,藉由複數個鈦製螺栓固定,例如為4個、6個或8個長約5公分的鈦製螺栓;第一法蘭盤40a係經由其中央通孔及朝向該管狀殼體側之凸緣以螺牙連接至該濾芯開口,及第二法蘭盤40b係經由其中央通孔以螺牙連接至進水口端或出水口端之水管轉接頭70、紫外燈管電源接頭、及水平管80。於濾芯(50及60)與第一法蘭盤40a、第二法蘭盤40b與水管轉接頭70、水管轉接頭70與水平管80之間分別具有O型環(90及100)使組件接合更緊密。According to a specific embodiment of the water treatment device 10 of the present invention, refer to the assembly exploded view of FIG2. The structure of the water treatment device 10 is designed to be a round tube, extending along the transverse axis to be laid horizontally, with a tube cover at each end, which is connected to the tubular shell 20. The length of the tubular shell is 60 to 80 cm, the outer diameter is 8 to 12 cm, and the shell thickness is 0.1 to 0.5 cm. A filter element is installed at each end of the accommodating space of the tubular shell. The length of the filter element is 10 to 30 cm, the inner diameter is 5 to 7 cm, the thickness of the filter element shell is about 0.1 cm, and the sintered thickness of the titanium powder is about 100 µm. The filter element is a single-opening type, and the open end can be connected to the tube caps at both ends using screw threads. The first filter element 50 is connected to the water inlet through the water pipe adapter 70, which is the primary filtration, and has a pore size of 2 to 5 µm. Water enters the filter element shell and overflows from the inside to the outside of the filter element shell into the accommodating space of the tubular shell. The second filter element 60 is connected to the water outlet through the water pipe adapter 70, which is the ultrafiltration, and has a pore size of about 0.2 µm. The water in the accommodating space of the tubular shell that has undergone the primary filtration enters the inside from the outside of the filter element shell of the second filter element, and flows into the water outlet for discharge. A side tube 30 is provided at the center of the tubular shell for installing an ultraviolet lamp with a UV-A wavelength of 380 nm. The lamp is covered with a quartz tube and inserted into the tubular shell 20 through the side tube 30 in a direction perpendicular to the tubular shell 20. An ultraviolet lamp with a wavelength of 254 to 265 nm is installed in the filter shell of the first filter 50. The ultraviolet light and the titanium oxide and silver particles in the filter shell serve as photocatalyst reactors, and have the functions of sterilization, chlorine adsorption and hydrogen production. A green light lamp with a wavelength of 532 nm is installed in the filter shell of the second filter 60. The green light and the gold particles in the filter shell generate plasma resonance to reduce the water therein into small molecules. The tube covers at both ends of the tubular shell 20 are made of two titanium plates, such as flange type, which is octagonal, and fixed by a plurality of titanium bolts, such as 4, 6 or 8 titanium bolts about 5 cm long; the first flange 40a is connected to the filter element opening by screw threads through its central through hole and the flange facing the side of the tubular shell, and the second flange 40b is connected to the water pipe adapter 70 at the water inlet end or the water outlet end, the ultraviolet lamp power connector, and the horizontal tube 80 by screw threads through its central through hole. O-rings (90 and 100) are respectively provided between the filter element (50 and 60) and the first flange 40a, between the second flange 40b and the water pipe adapter 70, and between the water pipe adapter 70 and the horizontal pipe 80 to make the assembly joint more tightly.

此外,本發明之水處理設備中另可配置相關模組化組件,包括:漏水斷路器、水流量計、紫外光燈及LED綠光燈電源適配器等。In addition, the water treatment equipment of the present invention can be equipped with related modular components, including: a water leakage circuit breaker, a water flow meter, an ultraviolet lamp and an LED green light power adapter, etc.

根據本發明水處理設備10之另一具體例,參照圖3之組裝分解圖。UV-A波長380 nm之紫外光燈管係以石英管110包覆,其經由管狀殼體20中央的側管,以垂直於該管狀殼體的方向,藉由矽膠環將該石英管110設置於管狀殼體20之容置空間,並以套管120、螺栓130、墊片140將石英管110固定至該管狀殼體中。According to another embodiment of the water treatment device 10 of the present invention, refer to the assembly exploded view of FIG3. The UV-A wavelength 380 nm ultraviolet lamp is covered with a quartz tube 110, which is arranged in the accommodation space of the tubular shell 20 through a side tube in the center of the tubular shell 20 in a direction perpendicular to the tubular shell by a silicone ring, and the quartz tube 110 is fixed to the tubular shell by a sleeve 120, a bolt 130, and a gasket 140.

本發明之另一態樣係自來水通過上述水處理設備產生「鈦電漿氫水」之淨水製程,其包括: 第一步驟:過濾與滅菌的雙重作用 自來水從進水口導入孔徑2 µm之第一道濾芯,在第一道濾芯內部產生內壓,由內往外通過濾芯過濾,過濾後水中顆粒雜質為20萬至30萬顆粒單位,同時水流在波長265 nm之紫外線照射下滅菌,並與在濾芯殼體內部的銀粒子鍍膜接觸,強化滅菌作用。 第二步驟:二氧化鈦光觸媒除污除氯產氫 經第一步驟處理後的水進入管狀殼體之容置空間中,純鈦材料製成之管狀殼體經高溫400℃熱氧化處理,形成含有半導體二氧化鈦光觸媒之氧化膜,經波長380 nm之紫外線照射下進行光催化反應,除去水中氯氣、分解污染物、及產生氫氣。 第三步驟:表面電漿共振產氫小分子化 經第二步驟處理後的水經外壓作用,從第二道濾芯之殼體外部進入濾芯內部,第二道濾芯之孔徑為0.2 µm,可過濾掉細菌等級之顆粒,過濾後水中顆粒僅剩數千顆粒單位,達到生飲等級,同時經第二道濾芯內波長532 nm之綠光照射與濾芯殼體內部鍍膜的金粒子進行表面電漿共振作用,將水小分子化改質,並產出更多氫水,提高飲水的機能性效果。 Another aspect of the present invention is a water purification process in which tap water passes through the above-mentioned water treatment equipment to produce "titanium plasma hydrogen water", which includes: Step 1: Dual effects of filtration and sterilization Tap water is introduced into the first filter element with a pore size of 2 µm from the water inlet, and internal pressure is generated inside the first filter element. It is filtered from the inside to the outside through the filter element. After filtration, the particle impurities in the water are 200,000 to 300,000 particle units. At the same time, the water flow is sterilized under ultraviolet light with a wavelength of 265 nm, and contacts the silver particle coating inside the filter element shell to enhance the sterilization effect. Step 2: Titanium dioxide photocatalyst for decontamination, chlorine removal and hydrogen production The water treated in the first step enters the storage space of the tubular shell. The tubular shell made of pure titanium material is subjected to high temperature 400℃ thermal oxidation treatment to form an oxide film containing semiconductor titanium dioxide photocatalyst. Under the irradiation of ultraviolet light with a wavelength of 380 nm, a photocatalytic reaction is carried out to remove chlorine in the water, decompose pollutants, and produce hydrogen. Step 3: Surface Plasma Resonance Hydrogen Small Molecules After the second step, the water is treated by external pressure and enters the second filter element from the outside of the shell. The pore size of the second filter element is 0.2 µm, which can filter out bacteria-level particles. After filtration, there are only thousands of particles in the water, reaching the drinking level. At the same time, the green light with a wavelength of 532 nm in the second filter element and the gold particles coated on the inside of the filter element shell undergo surface plasmon resonance, which modifies the water into small molecules and produces more hydrogen water, improving the functional effect of drinking water.

雖然本發明已參照較佳具體例及舉例性附圖敘述如上,惟其應不被視為係限制性者。熟悉本技藝者對其形態及具體例之內容做各種修改、省略及變化,均不離開本發明之申請專利範圍之所主張範圍。Although the present invention has been described above with reference to the preferred embodiments and exemplary drawings, it should not be considered as restrictive. A person skilled in the art may make various modifications, omissions and changes to the form and contents of the embodiments without departing from the scope of the invention.

10:水處理設備10: Water treatment equipment

20:管狀殼體20: Tubular shell

30:側管30: Side tube

35:波長380 nm之紫外燈管35: UV lamp with a wavelength of 380 nm

40a:第一法蘭盤40a: First Franchise

40b:第二法蘭盤40b: Second Franchise

50:第一道濾芯50: First filter

55:波長265 nm之冷陰極紫外光滅菌器55: Cold cathode UV sterilizer with a wavelength of 265 nm

60:第二道濾芯60: Second filter

65:波長532 nm之冷陰極綠光表面電漿共振反應器65: 532 nm cold cathode green light surface plasmon resonance reactor

70:水管轉接頭70: Water pipe adapter

80:水平管80: Horizontal pipe

90:O型環90:O-ring

100:O型環100:O-ring

110:石英管110:Quartz tube

120:套管120: Casing

130:螺栓130: Bolt

140:墊片140: Gasket

圖1A及圖1B係表示本發明水處理設備之一具體例之剖面示意圖。 圖2係表示本發明水處理設備之一具體例中各組件之組裝分解圖。 圖3係表示本發明水處理設備之另一具體例中各組件之組裝分解圖。 FIG. 1A and FIG. 1B are schematic cross-sectional views of a specific example of the water treatment device of the present invention. FIG. 2 is an exploded view of the assembly of each component in a specific example of the water treatment device of the present invention. FIG. 3 is an exploded view of the assembly of each component in another specific example of the water treatment device of the present invention.

10:水處理設備 10: Water treatment equipment

20:管狀殼體 20: Tubular shell

40a:第一法蘭盤 40a: First Flange

40b:第二法蘭盤 40b: Second Franchise

50:第一道濾芯 50: First filter element

70:水管轉接頭 70: Water pipe adapter

80:水平管 80: Horizontal pipe

90:O型環 90: O-ring

110:石英管 110: Quartz tube

120:套管 120: Casing

130:螺栓 130: Bolts

140:墊片 140: Gasket

Claims (6)

一種水處理設備,其包含:採用純鈦材料製成之一管狀殼體,其內部具有沿著一橫向軸線延伸之一容置空間;一波長380nm之紫外燈管,其外包覆石英管,由該管狀殼體中央位置之一側管以垂直於該橫向軸線的方向插入該管狀殼體內;於該管狀殼體之兩端各配置有一鈦製管蓋,其各與該管狀殼體兩端接合,其中一端之管蓋係連接至一進水口,及另一端之管蓋係連接至一出水口;第一道濾芯,其為燒結純鈦粉末材質,孔徑為2μm,具有一濾芯開口接合至該進水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第一道濾芯之殼體內部具有銀粒子鍍膜,及具有一波長265nm之冷陰極紫外光滅菌器設置於其中;及第二道濾芯,其為燒結純鈦粉末材質,孔徑為0.2μm,具有一濾芯開口接合至該出水口端之管蓋,以配置於該管狀殼體之容置空間中,其中,該第二道濾芯之殼體內部具有奈米金粒子鍍膜,及具有一波長532nm之冷陰極綠光表面電漿共振反應器設置於其中。 A water treatment device, comprising: a tubular shell made of pure titanium material, the interior of which has a containing space extending along a transverse axis; an ultraviolet lamp tube with a wavelength of 380nm, the outer surface of which is covered with a quartz tube, and a side tube at the center of the tubular shell is inserted into the tubular shell in a direction perpendicular to the transverse axis; a titanium tube cover is disposed at each end of the tubular shell, each of which is connected to the two ends of the tubular shell, wherein the tube cover at one end is connected to a water inlet, and the tube cover at the other end is connected to a water outlet; a first filter element, which is a sintered pure titanium powder material, has a pore size of 2μm, and has a filter element The opening of the pipe cap connected to the water inlet end is arranged in the accommodation space of the tubular shell, wherein the shell of the first filter element has a silver particle coating inside, and a cold cathode ultraviolet sterilizer with a wavelength of 265nm is arranged therein; and the second filter element is a sintered pure titanium powder material with a pore size of 0.2μm, and has a filter element opening connected to the pipe cap of the water outlet end, so as to be arranged in the accommodation space of the tubular shell, wherein the shell of the second filter element has a nano-gold particle coating inside, and a cold cathode green light surface plasmon resonance reactor with a wavelength of 532nm is arranged therein. 如請求項1之水處理設備,其中,該等鈦製管蓋係各由一第一法蘭盤及一第二法蘭盤構成,其藉由複數個鈦製螺栓固定。 As in claim 1, the water treatment equipment, wherein the titanium pipe covers are each composed of a first flange and a second flange, which are fixed by a plurality of titanium bolts. 如請求項2之水處理設備,其中,該第一法蘭盤係經由其中央通孔連接至該濾芯開口,將濾芯配置於該管狀殼體之容置空間中;及該第二法蘭盤之一側與該第一法蘭盤相連接,另一側係經由其中央通孔連接至一水管轉接頭。 As in claim 2, the water treatment equipment, wherein the first flange is connected to the filter element opening via its central through hole, and the filter element is arranged in the accommodation space of the tubular shell; and one side of the second flange is connected to the first flange, and the other side is connected to a water pipe adapter via its central through hole. 如請求項1之水處理設備,其中,所使用之純鈦材料必 須經由以下加工程序,包括:拋光處理,熱氧化處理,CNC切割及雷射焊接。 For water treatment equipment in Item 1 of the application, the pure titanium material used must undergo the following processing procedures, including: polishing, thermal oxidation, CNC cutting and laser welding. 如請求項4之水處理設備,其中,熱氧化處理之溫度為400℃至900℃。 For example, the water treatment equipment of claim 4, wherein the temperature of thermal oxidation treatment is 400°C to 900°C. 一種自來水通過請求項1至5中任一項之水處理設備之淨水製程,其包括:過濾與滅菌雙重作用之步驟:自來水從進水口導入孔徑2μm之第一道濾芯,在第一道濾芯內部產生內壓,由內往外通過濾芯過濾,過濾後水中顆粒雜質為20萬至30萬顆粒單位,同時水流在波長265nm之紫外線照射下滅菌,並與在濾芯殼體內部的銀粒子鍍膜接觸,強化滅菌作用;二氧化鈦光觸媒除污除氯產氫之步驟:經前述步驟處理後的水進入管狀殼體之容置空間中,純鈦材料製成之管狀殼體形成含有半導體二氧化鈦光觸媒之氧化膜,經波長380nm之紫外線照射下進行光催化反應,除去水中氯氣、分解污染物、及產生氫氣;及表面電漿共振產氫小分子化之步驟:水經外壓作用,從第二道濾芯之殼體外部進入濾芯內部,第二道濾芯之孔徑為0.2μm,可過濾掉細菌等級之顆粒,過濾後水中顆粒僅剩數千顆粒單位,達到生飲等級,同時經第二道濾芯內波長532nm之綠光照射與濾芯殼體內部鍍膜的金粒子進行表面電漿共振作用,將水小分子化改質,並產出更多氫水,提高飲水的機能性效果。 A water purification process for tap water through any of the water treatment equipment of claim 1 to 5, comprising: a dual-action step of filtration and sterilization: tap water is introduced from the water inlet into a first filter element with a pore size of 2 μm, an internal pressure is generated inside the first filter element, and the water is filtered from the inside to the outside through the filter element, and the number of particulate impurities in the water after filtration is 200,000 to 300,000 At the same time, the water flow is sterilized under the 265nm wavelength ultraviolet irradiation and contacts the silver particle coating inside the filter shell to enhance the sterilization effect; the titanium dioxide photocatalytic decontamination and chlorine removal and hydrogen production steps: the water treated by the above steps enters the containing space of the tubular shell, and the tubular shell made of pure titanium material forms a semiconductor dioxide containing The titanium oxide photocatalyst oxide film undergoes photocatalytic reaction under the irradiation of ultraviolet light with a wavelength of 380nm, removing chlorine from the water, decomposing pollutants, and generating hydrogen; and the step of surface plasmon resonance hydrogen production into small molecules: water enters the filter element from the outside of the second filter element shell under external pressure. The pore size of the second filter element is 0.2μm, which can filter out bacteria-level particles. After filtering, there are only thousands of particles in the water, reaching the drinking level. At the same time, the green light with a wavelength of 532nm in the second filter element and the gold particles coated on the inside of the filter element shell undergo surface plasmon resonance, which modifies the water into small molecules and produces more hydrogen water, improving the functional effect of drinking water.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201532971A (en) * 2013-06-21 2015-09-01 Univ Taipei Medical Apparatus and process for preparation of small water cluster and small water cluster prepared therefrom
TW202021652A (en) * 2018-12-14 2020-06-16 友達晶材股份有限公司 Filter material, water filter device, water purification system and biological water composition wherein the filter material includes a carrier and an active silicon material
CN111957972A (en) * 2020-07-31 2020-11-20 石家庄金钛净化设备有限公司 Preparation method of titanium filter element anti-corrosion film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201532971A (en) * 2013-06-21 2015-09-01 Univ Taipei Medical Apparatus and process for preparation of small water cluster and small water cluster prepared therefrom
TW202021652A (en) * 2018-12-14 2020-06-16 友達晶材股份有限公司 Filter material, water filter device, water purification system and biological water composition wherein the filter material includes a carrier and an active silicon material
CN111957972A (en) * 2020-07-31 2020-11-20 石家庄金钛净化设备有限公司 Preparation method of titanium filter element anti-corrosion film

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