TWI860060B - The packaging method and the connecting method for organic photovoltaic module - Google Patents
The packaging method and the connecting method for organic photovoltaic module Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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Abstract
Description
本揭露係有關於一種太陽能電池模組的封裝方法,特別是一種軟性有機太陽能電池模組的封裝方法,及使用其連接複數個軟性有機太陽能電池模組的方法。 This disclosure relates to a solar cell module packaging method, in particular a flexible organic solar cell module packaging method, and a method for connecting a plurality of flexible organic solar cell modules using the same.
有機太陽電池於弱光環境下擁有高光電轉換效率,因此在近年來逐漸被討論用來做為低功耗電子裝置的電力來源,而物聯網的出現,不但改變了我們工作和生活的方式,並且創造了一個讓有機太陽能電池大展長才的應用舞台。全球目前有數量龐大的裝置能與互聯網進行連結,例如手機,可穿戴設備和感測器等會連接到物聯網網絡平台。如此大量的單獨和離網小工具,將會需要輕便的可攜式電池,另外,如何使得這些電池可以方便且及時地進行充電,將會是一個很大的挑戰。同樣地,有機太陽電池在戶外一樣擁有應用利基,尤其在政府推倡綠能政策的推波助瀾下,歸屬於「綠能科技」之有機太陽電池,不但可發揮創能角色,且以其可製作成可透光結構的獨特優勢,可開創出更廣泛的應用場域,例如農業溫室之頂蓬,或是建築整合太陽能電池等。然而,壽命將是影響有機太陽電池切入上述應用面的關鍵因素。 Organic solar cells have high photoelectric conversion efficiency in weak light environments, so they have gradually been discussed in recent years as a power source for low-power electronic devices. The emergence of the Internet of Things has not only changed the way we work and live, but also created an application stage for organic solar cells to show their talents. There are currently a large number of devices in the world that can connect to the Internet, such as mobile phones, wearable devices and sensors that are connected to the Internet of Things network platform. Such a large number of independent and off-grid gadgets will require lightweight portable batteries. In addition, how to make these batteries conveniently and timely rechargeable will be a big challenge. Similarly, organic solar cells also have niche applications outdoors. Especially with the government's promotion of green energy policies, organic solar cells, which belong to "green energy technology", can not only play a creative role, but also open up a wider range of application fields with their unique advantage of being able to be made into light-transmitting structures, such as the canopy of agricultural greenhouses or building integrated solar cells. However, lifespan will be a key factor affecting the entry of organic solar cells into the above applications.
有機太陽電池封裝的習知技術多以玻璃為基板來進行封裝,較少以軟性基材做為開發標的。其方式為將玻璃基材與元件以有機接著劑貼合固 定,並於蓋板與元件間附上吸附劑(getter),其中玻璃的不透氣特性可以阻絕大部份的外界氣體,而吸附劑則是用來吸附透過有機接著劑而滲入之氣體,此種封裝方式效果雖然好,但其缺點為成本高、製程繁複,不僅不利於大面積生產,且無法用於軟性的基材。 The conventional technology of organic solar cell packaging mostly uses glass as the substrate for packaging, and rarely uses soft substrates as the development target. The method is to fix the glass substrate and the component with an organic adhesive, and attach an adsorbent (getter) between the cover and the component. The airtightness of the glass can block most of the external gas, and the adsorbent is used to adsorb the gas that penetrates through the organic adhesive. Although this packaging method has good effects, its disadvantages are high cost and complicated process. It is not only not conducive to large-scale production, but also cannot be used for soft substrates.
先前技術CN206516639U專利中揭露一種封裝太陽能電池的EVA膠膜,所述上層EVA薄膜與中層防紫外線玻璃層、中層防紫外線玻璃層與下層EVA薄膜通過矽烷偶聯劑親水膜緊密聯結在一起,具有優異的抗老化性能。然而,該專利雖具有優異的功能特性,但其為應用於玻璃基材上,無法相容於軟性太陽電池模組。 The prior art CN206516639U patent discloses an EVA film for encapsulating solar cells. The upper EVA film and the middle UV-proof glass layer, and the middle UV-proof glass layer and the lower EVA film are tightly bonded together through a silane coupling agent hydrophilic film, and have excellent anti-aging properties. However, although the patent has excellent functional characteristics, it is applied to a glass substrate and is not compatible with a flexible solar cell module.
又例如先前技術TWI457232專利中,揭露一種利用含有聚有機矽氧烷系化合物之層體,以及設置於該含有該聚有機矽氧烷系化合物之層體上之無機物層,來達到增加氣體阻絕率的目的,但其膜層厚度最高達1000nm,且可能會影響整體模組的可彎折性,並不適用於軟性有機太陽電池模組的封裝。 For example, the prior art patent TWI457232 discloses a method of increasing the gas barrier rate by using a layer containing a polyorganosiloxane compound and an inorganic layer disposed on the layer containing the polyorganosiloxane compound. However, the thickness of the film layer is up to 1000nm, and it may affect the bendability of the entire module, and is not suitable for the packaging of flexible organic solar cell modules.
在軟性基材封裝的策略上,由於軟性基材其阻氣率較差,一般作法會在軟性基材上鍍上一層阻氣薄膜以增加阻氣率,通常會以濺鍍、蒸鍍、電漿輔助化學氣相沉積(PECVD)等方式來製作,但這些作法所耗費之成本相對偏高。再者,在阻絕膜上以高成本的製程方式覆蓋一層增加阻氣率的膜層,不僅有影響光穿透度及可彎折性的疑慮,且封裝膠品中的有機溶劑也有可能會與有機太陽電池中的膜層產生反應,進而破壞有機太陽能電池模組的效能。 In the strategy of soft substrate packaging, since the gas barrier rate of soft substrate is relatively poor, the general practice is to coat a layer of gas barrier film on the soft substrate to increase the gas barrier rate. It is usually made by sputtering, evaporation, plasma-assisted chemical vapor deposition (PECVD), etc., but the cost of these methods is relatively high. In addition, coating a layer of film that increases the gas barrier rate on the barrier film with a high-cost process not only has concerns about affecting light transmittance and bendability, but the organic solvent in the packaging glue may also react with the film layer in the organic solar cell, thereby destroying the performance of the organic solar cell module.
另外,亦有利用多層封裝的方式,用以提升軟性太陽電池模組的阻氣能力,然而,多層堆疊的方式勢必導致成本上升並衍生出光穿透度及可 彎折性下降的問題。除此之外,為了延緩外界水氣進入封裝結構內模組的時間,模組與端電極之間勢必會保持一段距離,而模組與端電極之間往往透過導電性的材料加以連接,但該材料會使阻絕膜於貼合時無法緊密接合,故而形成外界水氣進入的途徑。 In addition, there is also a multi-layer packaging method to improve the gas barrier ability of the flexible solar cell module. However, the multi-layer stacking method will inevitably lead to increased costs and the problem of reduced light transmittance and bendability. In addition, in order to delay the time for external moisture to enter the module in the packaging structure, the module and the terminal electrode must be kept at a certain distance. The module and the terminal electrode are often connected through conductive materials, but this material will prevent the barrier film from being tightly bonded during bonding, thus forming a path for external moisture to enter.
鑑於上述技術之諸多問題,本揭露提出一種以一低成本、高性價比之軟性太陽能電池模組的封裝方式,不但可大幅提升有機太陽電池的壽命,亦可廣泛應用於不同之應用場域。本揭露之特色係所利用在一低阻氣率的阻絕膜上,以無溶劑之壓敏膠(Pressure Sensitive Adhesive,PSA),在封裝前處理時降低阻絕膜及膠品中的含水量,之後以雙層整面貼合之方式進行模組封裝。 In view of the many problems of the above-mentioned technologies, this disclosure proposes a low-cost, high-cost-effective flexible solar cell module packaging method, which can not only greatly improve the life of organic solar cells, but also be widely used in different application fields. The characteristics of this disclosure are that it uses a solvent-free pressure sensitive adhesive (PSA) on a barrier film with a low gas barrier rate to reduce the water content in the barrier film and the adhesive during the pre-packaging treatment, and then the module is packaged in a double-layer full-surface bonding method.
再者,為了導引出軟性太陽能電池模組之電力,電極處必須裸露與外部接觸,而這將導致水氧侵入的可能性,且裸露處與模組的距離越近,模組的效率即為更快的劣化,因此,本揭露提出利用模組與外部電極之間不同的連接設計,阻絕水氧由電極接點進入的入侵途徑,於電極接點處以紫外光固化膠填補,而由實驗的結果證明,本揭露之軟性太陽能電池模組的封裝方法可大幅提升模組的壽命。 Furthermore, in order to guide the power of the flexible solar battery module, the electrode must be exposed and in contact with the outside, which will lead to the possibility of water and oxygen intrusion, and the closer the distance between the exposed part and the module, the faster the efficiency of the module will deteriorate. Therefore, the present disclosure proposes to use different connection designs between the module and the external electrode to block the intrusion path of water and oxygen from the electrode contact point, and fill the electrode contact point with ultraviolet curing glue. The experimental results show that the packaging method of the flexible solar battery module disclosed in the present disclosure can greatly increase the life of the module.
根據本揭露之一實施例,提出軟性有機太陽能電池模組的封裝方法,包括:提供一軟性有機太陽能電池模組、提供二片封裝膜、實施一壓合程序、以及實施一釘孔步驟。軟性有機太陽能電池模組進一步包括正模組電極、負模組電極、正連接電極以及負連接電極;其中,正連接電極與正模組電極電性連接,且負連接電極與負模組電極電性連接。封裝膜包括:阻絕膜層以 及壓敏膠層,壓敏膠層係轉印於阻絕膜層上。壓合程序包括將軟性有機太陽能電池模組置於二片封裝膜之間,且二片封裝膜之壓敏膠層分別與軟性有機太陽能電池模組之上、下表面疊合後進行壓合,以形成一封裝後之軟性有機太陽能電池模組。釘孔步驟包括於封裝後之軟性有機太陽能電池模組上對應於正連接電極及負連接電極處,分別形成正端電極釘孔及負端電極釘孔,以形成一具有端電極之軟性有機太陽能電池模組,其中,正連接電極及負連接電極可透過正端電極釘孔及負端電極釘孔分別與外部線路電性連接。 According to an embodiment of the present disclosure, a method for packaging a flexible organic solar cell module is provided, including: providing a flexible organic solar cell module, providing two packaging films, performing a pressing process, and performing a nailing step. The flexible organic solar cell module further includes a positive module electrode, a negative module electrode, a positive connecting electrode, and a negative connecting electrode; wherein the positive connecting electrode is electrically connected to the positive module electrode, and the negative connecting electrode is electrically connected to the negative module electrode. The packaging film includes: an insulating film layer and a pressure-sensitive adhesive layer, and the pressure-sensitive adhesive layer is transferred onto the insulating film layer. The pressing process includes placing the flexible organic solar cell module between two packaging films, and laminating the pressure-sensitive adhesive layers of the two packaging films with the upper and lower surfaces of the flexible organic solar cell module respectively, and then pressing them together to form a packaged flexible organic solar cell module. The nailing step includes forming a positive terminal electrode nailing hole and a negative terminal electrode nailing hole respectively at the positive connection electrode and the negative connection electrode on the packaged flexible organic solar cell module to form a flexible organic solar cell module with terminal electrodes, wherein the positive connection electrode and the negative connection electrode can be electrically connected to the external circuit through the positive terminal electrode nailing hole and the negative terminal electrode nailing hole respectively.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,於實施該釘孔步驟後,進一步包括實施一封膠步驟,將正端電極釘孔及負端電極釘孔與封裝膜之間的縫隙塗上光固化膠,並照光使其固化。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, wherein, after the nailing step is performed, a sealing step is further performed, wherein a photocurable glue is applied to the gap between the positive electrode nailing hole and the negative electrode nailing hole and the packaging film, and light is irradiated to cure it.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,於實施壓合程序之前,進一步包括真空加熱步驟,包括將二片封裝膜置於真空烘箱內,以攝氏100~110度加熱至少8小時,以去除阻絕膜層及壓敏膠層中殘餘的水氣及氧含量。在本揭露之另一實施例中,上述真空加熱步驟進一步包括將二片封裝膜置於真空烘箱內以攝氏約105度加熱至少8小時。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, before the lamination process is implemented, further includes a vacuum heating step, including placing two pieces of packaging film in a vacuum oven and heating them at 100-110 degrees Celsius for at least 8 hours to remove the residual moisture and oxygen content in the barrier film layer and the pressure-sensitive adhesive layer. In another embodiment of the present disclosure, the above-mentioned vacuum heating step further includes placing two pieces of packaging film in a vacuum oven and heating them at about 105 degrees Celsius for at least 8 hours.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,正模組電極及負模組電極係由導電膠帶製成。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, wherein the positive module electrode and the negative module electrode are made of conductive tape.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,正連接電極及負連接電極係由一銀線或一導電膠帶製成。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, wherein the positive connection electrode and the negative connection electrode are made of a silver wire or a conductive tape.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,正連接電極及負連接電極係由複數條銀線所組成。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, wherein the positive connection electrode and the negative connection electrode are composed of a plurality of silver wires.
在本揭露之一實施例中,上述任一軟性有機太陽能電池模組的封裝方法,其中,銀線係以蒸鍍方式所形成。 In one embodiment of the present disclosure, in any of the above-mentioned flexible organic solar cell module packaging methods, the silver wire is formed by evaporation.
在本揭露之一實施例中,上述軟性有機太陽能電池模組的封裝方法,其中,釘孔步驟係包括以鈕扣釘孔方法,於封裝後之軟性有機太陽能電池模組上對應於正連接電極及負連接電極處進行釘孔並加上正端電極釘孔及負端電極釘孔,使封裝於封裝膜內之該連接電極及負連接電極可與外部線路電性連接。 In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic solar cell module, wherein the nailing step includes nailing holes corresponding to the positive connection electrode and the negative connection electrode on the packaged flexible organic solar cell module by a button nailing method and adding positive terminal electrode nailing holes and negative terminal electrode nailing holes, so that the connection electrode and the negative connection electrode packaged in the packaging film can be electrically connected to the external circuit.
本揭露依據上述各實施例所揭露之一種軟性有機太陽能電池模組的封裝方法,進一步提出一種連接複數個軟性有機太陽能模組的方法,包括:提供複數個如上述任一實施例之封裝方法所述之封裝後之軟性有機太陽能電池模組、實施連接步驟、以及實施釘孔步驟。其中,所提供之複數個封裝後之軟性有機太陽能電池模組,其正連接電極及負連接電極分別包括至少一銀線。連接步驟,包括將複數個封裝後之軟性有機太陽能電池模組並排,使一封裝後之軟性有機太陽能電池模組之正連接電極與另一封裝後之軟性有機太陽能電池模組之負連接電極靠近,並利用導電膠帶將封裝後之軟性有機太陽能電池模組之正連接電極與另一封裝後之軟性有機太陽能電池模組之負連接電極雙面貼合。實施釘孔步驟,包括將連接步驟所完成連接後之複數個軟性有機太陽能模組的兩端未貼有導電膠帶之正連接電極及負連接電極處,分別形成正端電極釘孔及負端電極釘孔,使完成連接後之複數個軟性有機太陽能模組兩端的正連接電極及負連接電極可透過正端電極釘孔及負端電極釘孔分別與外部線路電性連接。 The present disclosure further provides a method for connecting a plurality of flexible organic solar modules according to a packaging method of a flexible organic solar cell module disclosed in the above embodiments, including: providing a plurality of packaged flexible organic solar cell modules as described in any of the packaging methods of the above embodiments, performing a connection step, and performing a nailing step. In the plurality of packaged flexible organic solar cell modules provided, the positive connection electrode and the negative connection electrode respectively include at least one silver wire. The connecting step includes arranging a plurality of packaged flexible organic solar battery modules side by side so that the positive connection electrode of one packaged flexible organic solar battery module is close to the negative connection electrode of another packaged flexible organic solar battery module, and using a conductive tape to adhere the positive connection electrode of the packaged flexible organic solar battery module to the negative connection electrode of another packaged flexible organic solar battery module on both sides. Implementing the nailing step includes forming positive terminal electrode nailing holes and negative terminal electrode nailing holes at the positive connection electrodes and negative connection electrodes at both ends of the multiple flexible organic solar modules that are connected in the connecting step and are not attached with conductive tape, so that the positive connection electrodes and negative connection electrodes at both ends of the multiple flexible organic solar modules that are connected can be electrically connected to the external circuit through the positive terminal electrode nailing holes and the negative terminal electrode nailing holes.
100:阻絕膜層 100: Barrier film layer
200:壓敏膠層 200: Pressure-sensitive adhesive layer
300:封裝膜 300: Packaging film
400:軟性有機太陽能電池模組 400: Flexible organic solar cell module
411:正模組電極 411: Positive module electrode
412:負模組電極 412: Negative module electrode
421:正連接電極 421: Positive connection electrode
422:負連接電極 422: Negative connection electrode
431:正端電極釘孔 431: Positive electrode nail hole
432:負端電極釘孔 432: Negative electrode nail hole
500:封裝後之軟性有機太陽能電池模組 500: Flexible organic solar cell module after packaging
600:具有端電極之軟性有機太陽能電池模組 600: Flexible organic solar cell module with terminal electrodes
700:光固化膠 700: Light-curing adhesive
800:導電膠帶 800: Conductive tape
S100:壓合程序 S100: Pressing procedure
S200:釘孔步驟 S200: Nailing steps
S300:封膠步驟 S300: Sealing step
第1A圖為本揭露之一實施例之封裝膜及軟性有機太陽能電池模組截面圖示意圖。 Figure 1A is a schematic diagram of a cross-sectional view of a packaging film and a flexible organic solar cell module according to one embodiment of the present disclosure.
第1B圖為本揭露之一實施例之軟性有機太陽能電池模組俯視圖示意圖。 Figure 1B is a schematic top view of a flexible organic solar cell module according to one embodiment of the present disclosure.
第2A圖為本揭露之一實施例之實施壓合程序後之截面圖示意圖。 Figure 2A is a schematic cross-sectional view of one embodiment of the present disclosure after the pressing process is performed.
第2B圖為本揭露之一實施例之實施壓合程序後之俯視圖示意圖。 Figure 2B is a schematic top view of one embodiment of the present disclosure after the pressing process is performed.
第3A、3B圖為本揭露之一實施例之軟性有機太陽能電池模組的封裝後示意圖。 Figures 3A and 3B are schematic diagrams of a flexible organic solar cell module after packaging according to one embodiment of the present disclosure.
第4圖為本揭露之一實施例之連接複數個封裝後之軟性有機太陽能電池模組示意圖。 Figure 4 is a schematic diagram of a flexible organic solar cell module after connecting multiple packages according to an embodiment of the present disclosure.
以下將參照相關圖式,說明本揭露之一種軟性有機太陽能電池模組的封裝方法之實施例,為了清楚與方便圖式說明之故,圖式中的各部件在尺寸與比例上可能會被誇大或縮小地呈現。在以下描述及/或申請專利範圍中,所使用之技術詞彙應以本技術領域之通常知識者所習知慣用之意思予以解釋,為使便於理解,下述實施例中之相同元件係以相同之符號標示來說明。本揭露中所提到「包括」、「包含」、「具有」等的用語均為開放性的用語,也就是指「包含但不限於」。 The following will refer to the relevant drawings to illustrate an embodiment of a packaging method of a flexible organic solar cell module disclosed in the present disclosure. For the sake of clarity and convenience of the diagram description, the size and proportion of each component in the diagram may be exaggerated or reduced. In the following description and/or patent application scope, the technical terms used should be interpreted in accordance with the meanings commonly known and used by people of ordinary skill in the art. For ease of understanding, the same elements in the following embodiments are illustrated with the same symbols. The terms "including", "comprising", "having", etc. mentioned in this disclosure are all open terms, that is, "including but not limited to".
請參閱第1A圖至第3B圖,其係表示本揭露之一實施例之一種軟性有機太陽能電池模組的封裝方法的流程示意圖。首先,請參閱第1A圖及第1B圖,依據本揭露所提出之軟性有機太陽能電池模組的封裝方法,包括:提供一軟性有機太陽能電池模組400、提供二片封裝膜300、實施壓合程序S100(如第
2A圖及第2B圖所示)、以及實施釘孔步驟S200(如第3A圖及第3B圖所示)。如第1B圖所示,軟性有機太陽能電池模組400進一步包括正模組電極411、負模組電極412、正連接電極421以及負連接電極422;其中,正連接電極421與正模組電極411電性連接,且負連接電極422與負模組電極412電性連接。如第1A圖中所示,封裝膜300包括:阻絕膜層100以及壓敏膠層200,壓敏膠層200係轉印於阻絕膜層100上。請參閱第1A圖至第2B圖,壓合程序S100包括將軟性有機太陽能電池模組400置於二片封裝膜300之間,且二片封裝膜300之壓敏膠層200分別與軟性有機太陽能電池模組400之上、下表面疊合後進行壓合,以形成一封裝後之軟性有機太陽能電池模組500。請再參閱第3A圖及第3B圖,如圖所示,釘孔步驟S200包括於封裝後之軟性有機太陽能電池模組500上對應於正連接電極421及負連接電極422處,分別形成正端電極釘孔431及負端電極釘孔432,以形成一具有端電極之軟性有機太陽能電池模組600,其中,正連接電極421及負連接電極422可透過正端電極釘孔431及負端電極釘孔432分別與外部線路電性連接。
Please refer to Figures 1A to 3B, which are schematic diagrams of a process of packaging a flexible organic solar cell module according to an embodiment of the present disclosure. First, please refer to Figures 1A and 1B. According to the packaging method of the flexible organic solar cell module proposed in the present disclosure, it includes: providing a flexible organic
應了解,在本揭露之實施例中所使用之壓敏膠層200係於封裝之前先轉印於阻絕膜層100上,因此,在轉印過程中需注意避免於壓敏膠層200與阻絕膜層100之間產生小氣泡。一般來說,會產生小氣泡的主要原因之一係因為在轉印過程中貼合不平整,而使得壓敏膠層200與阻絕膜層100包覆大氣/空氣。存在於小氣泡中的水氣及氧氣將進一步導致軟性有機太陽能模組的快速劣化,進而影響整體模組的使用壽命。
It should be understood that the pressure-
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,於實施釘孔步驟S200後,進一步包括實施一封膠步驟S300(請
參閱第3A圖及第3B圖),將正端電極釘孔431及負端電極釘孔432與封裝膜300之間的縫隙塗上光固化膠700,並照光使其固化。值得注意的是,由於光固化膠700可有效用於阻絕空氣或大氣,因此不僅可用於填充正端電極釘孔431、負端電極釘孔432與封裝膜300之間的縫隙。在另一實施例中,當實施壓合程序S100後,若封裝後,封裝膜300與軟性有機太陽能電池模組400之間殘存有空氣或有其他可能導致元件曝露於大氣之處,皆可利用光固化膠700來進一步填充並固化,以達到阻絕大氣、延長元件使用壽命之目的。
In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic
應注意的是,在本揭露的一實施例中,若在封裝後封裝膜內殘存有水氣或是正端電極釘孔431、負端電極釘孔432與封裝膜300間存在空隙且未以光固化膠700填補,則封裝後之軟性有機太陽能電池模組600的效率在不到50小時便會降至初始值的80%以下,反之,若以光固化膠700填補縫隙,並確實阻絕水氣入侵通道,則封裝後之軟性有機太陽能電池模組的效率在經過測試600小時之後仍能維持在初始值的80%以上。
It should be noted that in one embodiment of the present disclosure, if there is residual moisture in the packaging film after packaging or there is a gap between the positive
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,於實施壓合程序S100之前,進一步包括真空加熱步驟,包括將二片封裝膜300置於真空烘箱內,以攝氏100~110度加熱至少8小時,以去除阻絕膜層100及壓敏膠層200中殘餘的水氣及氧含量。在本揭露之另一實施例中,上述真空加熱步驟進一步包括將二片封裝膜300置於真空烘箱內以攝氏約103度、104度、105度、106度、107度、108度、109度加熱至少8小時、或至少9小時、或至少10小時、或至少11小時。較佳為以攝氏約105度加熱至少8小時,加熱溫度及時間可視阻絕膜層100及壓敏膠層200中殘餘的水氣及氧含量揮發的情況而適當調整。
In one embodiment of the present disclosure, the packaging method of the flexible organic
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,正模組電極411及負模組電極412係由導電膠帶製成。
In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,正連接電極421及負連接電極422係由一銀線或一導電膠帶製成。
In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic
在本揭露之另一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,正連接電極421及負連接電極422係由銀線製成。應了解,導電膠帶相較於銀線而言,其厚度較厚,因此,若所使用的是導電膠帶,則在封裝後容易因為導電膠帶具有一定厚度的關係,使得封裝膜300壓合導電膠帶時,導電膠帶的周邊處無法完全密合而存在有空隙/大氣,此亦為水氣入侵封裝模組內的途徑之一。此時,可於這些空隙處注入光固化膠700並照光固化,亦可有效阻絕水氣入侵的途徑,有效提升封裝後之軟性有機太陽能電池模組600的使用壽命。
In another embodiment of the present disclosure, in the packaging method of the above-mentioned flexible organic
除此之外,在上述的實施例中,上述軟性有機太陽能電池模組400的封裝方法中,正連接電極421及負連接電極422若由導電膠帶製成,且封裝後封裝膜300內存在有空隙,則整體模組效率經測試不到50小時便會降至低於初始的80%。然而,當使用光固化膠700將上述封裝膜300內的空隙全部填滿以阻絕水氣入侵時,則經測試整體模組效率降至80%的時間可延長至約200小時。更進一步來說,當正連接電極421及負連接電極422是由銀線製成,且封裝後封裝膜300內不存在有空隙或所有空隙皆以光固化膠700填滿時,則整體模組效率即使在經過600小時後,仍可維持在初始值的80%以上。
In addition, in the above-mentioned embodiment, in the packaging method of the above-mentioned flexible organic
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,正連接電極421及負連接電極422係由複數條銀線所組成。進一步說明,在本實施例中,正連接電極421及負連接電極422係由複數條銀線所組成,且在封裝後並不存在有任何空隙或以光固化膠700填滿任何存在的空隙或可能的入侵途徑後,整體模組的效率即使在經過600小時後仍可維持在初始值的80%以上。詳細說明,在本實施例中,當正連接電極421及負連接電極422係由複數條銀線所組成並完成上述封裝後,將整體模組置於溫度65℃/濕度65%的高溼熱環境下,利用標準光源(1-sun)連續照光進行耐久性測試。結果顯示,依照本揭露上述的封裝方法所製作而成的封裝後之軟性有機太陽能電池模組600,即使在高溼熱環境下測試經過600小時,整體模組效率仍可高於80%(換算成實際使用環境壽命約為3年),具有良好的抗性,且具有再現性。
In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic
在本揭露之一實施例中,上述軟性有機太陽能電池模組400的封裝方法,其中,釘孔步驟S200係包括以鈕扣釘孔方法,於封裝後之軟性有機太陽能電池模組500上對應於正連接電極421及負連接電極422處進行釘孔並加上正端電極釘孔431及負端電極釘孔432,使封裝於封裝膜內之正連接電極421及負連接電極422可與外部線路電性連接。一般來說,當有機太陽能電池模組在完成封裝後,模組左右兩端必須有電極拉出的區域(即正、負連接電極),此區域必須與外部的電力裝置連接,所以,正、負連接電極在原先以阻絕膜300貼合封裝的部份,必須穿破阻絕膜300,其得裡面的正連接電極421及負連接電極422裸露出來,而這樣的方式通常會造成水氧侵入的途徑,故在完成正、負連接電極與外部連接的設置後,會實施一封膠步膠S300,其利用光固化膠700將原先裸露處進行封裝,如第3A圖及第3B圖所示。
In one embodiment of the present disclosure, the packaging method of the above-mentioned flexible organic
接著請參閱第4圖。本揭露依據上述各實施例所揭露之一種軟性有機太陽能電池模組400的封裝方法,進一步提出一種連接複數個軟性有機太陽能模組的方法,包括:提供複數個如上述任一實施例之封裝方法所述之封裝後之軟性有機太陽能電池模組500、實施連接步驟、以及實施釘孔步驟。其中,所提供之複數個封裝後之軟性有機太陽能電池模組500,其正連接電極421及負連接電極422分別包括至少一銀線。連接步驟,包括將複數個封裝後之軟性有機太陽能電池模組500並排,使一封裝後之軟性有機太陽能電池模組500之正連接電極421與另一封裝後之軟性有機太陽能電池模組500之負連接電極422靠近,並利用導電膠帶800將封裝後之軟性有機太陽能電池模組500之正連接電極421與另一封裝後之軟性有機太陽能電池模組500之負連接電極422雙面貼合。實施釘孔步驟,包括將連接步驟所完成連接後之複數個軟性有機太陽能模組的兩端未貼有導電膠帶800之正連接電極421及負連接電極422處,分別形成正端電極釘孔431及負端電極釘孔432,使完成連接後之複數個軟性有機太陽能模組兩端的正連接電極421及負連接電極422可透過正端電極釘孔431及負端電極釘孔432分別與外部線路電性連接。連接後的複數個軟性有機太陽能模組,其整體如第4圖所示意。
Next, please refer to FIG. 4. The present disclosure further provides a method for connecting a plurality of flexible organic solar modules according to a packaging method of a flexible organic
綜上所述,本揭露之軟性有機太陽能電池模組的封裝方法有以下優點: In summary, the packaging method of the flexible organic solar cell module disclosed herein has the following advantages:
一、本揭露之封裝方法可有效提高軟性有機太陽電池模組壽命。 1. The packaging method disclosed herein can effectively improve the life of the flexible organic solar cell module.
二、本揭露之封裝方法利用軟性的阻絕膜層及壓敏膠層,以雙面壓合的方式,完整覆蓋整個軟性有機太陽電池模組,使軟性有機太陽能電池模組整體於封裝後仍具有高度之可彎折性。 2. The packaging method disclosed herein utilizes a soft barrier film layer and a pressure-sensitive adhesive layer to completely cover the entire flexible organic solar cell module by double-sided lamination, so that the flexible organic solar cell module as a whole still has a high degree of bendability after packaging.
三、本揭露之封裝方法所揭露之模組電極、連接電極與端電極釘孔等導電材料之間的連接方式以及光固化膠封裝方式等,可有效阻絕因連接材料之間時所造成的水氣入侵途徑。 3. The connection method between the module electrode, the connecting electrode and the terminal electrode nail hole and other conductive materials disclosed in the packaging method disclosed in this disclosure, as well as the light-curing adhesive packaging method, can effectively block the intrusion path of water vapor caused by the connection between the materials.
四、本揭露之封裝方法進一步於端電極釘孔周邊區域輔以光固化膠強化,改善習知技術中大氣環境中的水氧由端電極釘孔區域侵入所造成的劣化情況。 Fourth, the packaging method disclosed herein further strengthens the area around the terminal electrode nail hole with a photocurable adhesive to improve the deterioration caused by the water and oxygen in the atmospheric environment invading the terminal electrode nail hole area in the prior art.
本揭露之軟性有機太陽能電池模組的封裝方法已經過許多測試,包括加速測試實驗,結果都顯示本揭露之封裝方法確實可大幅提升軟性太陽電池模組整體的使用壽命。 The packaging method of the flexible organic solar cell module disclosed herein has been subjected to many tests, including accelerated test experiments, and the results have shown that the packaging method disclosed herein can indeed significantly increase the overall service life of the flexible solar cell module.
當然,上述各實施例僅用於舉例說明而非限制本揭露的範圍,任何根據上述實施例的軟性有機太陽能電池模組的封裝方法之等效修改或變更仍應包含在本揭露的專利範圍內。 Of course, the above embodiments are only used for illustration and not to limit the scope of the present disclosure. Any equivalent modification or change of the packaging method of the flexible organic solar cell module according to the above embodiments should still be included in the patent scope of the present disclosure.
綜上所述,可見本揭露在突破先前之技術下,確實已達到所欲增進之功效,且也非熟悉該項技藝者所易於思及,其所具之進步性、實用性,顯已符合專利之申請要件,爰依法提出專利申請,懇請 貴局核准本件發明專利申請案,以勵創作,實感德便。 In summary, it can be seen that this disclosure has indeed achieved the desired improved effect by breaking through the previous technology, and it is not easy for people familiar with the technology to think of. Its progress and practicality obviously meet the patent application requirements. Therefore, I have filed a patent application in accordance with the law and sincerely request your office to approve this invention patent application to encourage creativity. I really appreciate your kindness.
以上所述僅為舉例性,而非為限制性者。其它任何未脫離本揭露之精神與範疇,而對其進行之等效修改或變更,均應該包含於後附之申請專利範圍中。 The above description is for illustrative purposes only and is not intended to be limiting. Any other equivalent modifications or changes that do not depart from the spirit and scope of this disclosure should be included in the scope of the attached patent application.
411:正模組電極 411: Positive module electrode
412:負模組電極 412: Negative module electrode
421:正連接電極 421: Positive connection electrode
422:負連接電極 422: Negative connection electrode
431:正端電極釘孔 431: Positive electrode nail hole
432:負端電極釘孔 432: Negative electrode nail hole
600:具有端電極之軟性有機太陽能電池模組 600: Flexible organic solar cell module with terminal electrodes
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201130944A (en) * | 2009-11-18 | 2011-09-16 | 3M Innovative Properties Co | Flexible assembly and method of making and using the same |
| US20180309005A1 (en) * | 2010-07-02 | 2018-10-25 | 3M Innovative Properties Company | Barrier assembly |
| EP3511965A1 (en) * | 2016-09-06 | 2019-07-17 | Zeon Corporation | Solar battery module |
| US20200013912A1 (en) * | 2016-08-02 | 2020-01-09 | Zeon Corporation | Solar cell module |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201130944A (en) * | 2009-11-18 | 2011-09-16 | 3M Innovative Properties Co | Flexible assembly and method of making and using the same |
| US20180309005A1 (en) * | 2010-07-02 | 2018-10-25 | 3M Innovative Properties Company | Barrier assembly |
| US20200013912A1 (en) * | 2016-08-02 | 2020-01-09 | Zeon Corporation | Solar cell module |
| EP3511965A1 (en) * | 2016-09-06 | 2019-07-17 | Zeon Corporation | Solar battery module |
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