TWI859671B - Blast furnace operation method - Google Patents
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- TWI859671B TWI859671B TW111149329A TW111149329A TWI859671B TW I859671 B TWI859671 B TW I859671B TW 111149329 A TW111149329 A TW 111149329A TW 111149329 A TW111149329 A TW 111149329A TW I859671 B TWI859671 B TW I859671B
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- 238000000034 method Methods 0.000 title claims abstract description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000002994 raw material Substances 0.000 claims abstract description 104
- 229910052742 iron Inorganic materials 0.000 claims abstract description 51
- 239000000571 coke Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 26
- 238000011017 operating method Methods 0.000 claims description 9
- 210000001015 abdomen Anatomy 0.000 claims description 3
- 239000002893 slag Substances 0.000 abstract description 34
- 230000035699 permeability Effects 0.000 abstract description 18
- 230000004927 fusion Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 175
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- 238000012360 testing method Methods 0.000 description 17
- 238000006722 reduction reaction Methods 0.000 description 16
- 238000009423 ventilation Methods 0.000 description 14
- 229910052681 coesite Inorganic materials 0.000 description 11
- 229910052906 cristobalite Inorganic materials 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- 235000012239 silicon dioxide Nutrition 0.000 description 11
- 229910052682 stishovite Inorganic materials 0.000 description 11
- 229910052905 tridymite Inorganic materials 0.000 description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
- 239000012768 molten material Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 229910052593 corundum Inorganic materials 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 description 7
- 239000003245 coal Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 1
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
- C21B5/003—Injection of pulverulent coal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/008—Composition or distribution of the charge
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/06—Making pig-iron in the blast furnace using top gas in the blast furnace process
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
- C21B7/163—Blowpipe assembly
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
- C21B2005/005—Selection or treatment of the reducing gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
Abstract
本發明提供一種高爐操作方法,其於實施使風口前的爐內產生高濃度還原氣體的高爐操作時,即便熔渣中的FeO成分減少,亦可改善於爐下部生成的熔渣性狀,確保爐內的熔著帶及滴落帶中的通氣性。本發明的高爐操作方法是自高爐的爐頂裝入鐵系原料、副原料以及焦炭,並自高爐的風口吹入使風口前的爐內產生高濃度還原氣體的氣體,所述高爐操作方法將所述鐵系原料與所述副原料的原料總成分的鹼度設為規定範圍內。該情況下,較佳為將所述原料總成分的鹼度設為1.0以上且1.7以下的範圍內。The present invention provides a blast furnace operation method, which can improve the properties of the slag generated in the lower part of the furnace and ensure the air permeability in the fusion zone and dripping zone in the furnace even if the FeO component in the slag is reduced when the blast furnace operation is implemented to generate a high-concentration reducing gas in the furnace in front of the tuyere. The blast furnace operation method of the present invention is to charge iron-based raw materials, auxiliary raw materials and coke from the top of the blast furnace, and blow gas from the tuyere of the blast furnace to generate a high-concentration reducing gas in the furnace in front of the tuyere, and the blast furnace operation method sets the alkalinity of the total raw material components of the iron-based raw materials and the auxiliary raw materials to a specified range. In this case, it is preferred to set the alkalinity of the total raw material components to a range of 1.0 or more and 1.7 or less.
Description
本發明是有關於一種使風口前的高爐內產生高濃度還原氣體的高爐操作方法,詳細而言,是有關於一種改善高爐內的熔著帶及滴落帶中的熔渣的性狀而提高高爐內的通氣性的高爐操作方法。 The present invention relates to a blast furnace operating method for generating high-concentration reducing gas in the blast furnace in front of the tuyere. More specifically, it relates to a blast furnace operating method for improving the properties of slag in the molten zone and dripping zone in the blast furnace to increase the permeability in the blast furnace.
近年來,削減作為溫室效應氣體之一的CO2氣體(二氧化碳氣體)的排放量的動態高漲。於利用高爐進行的煉鐵法中,使用炭材作為還原材料,因此產生大量的CO2氣體。因此,鋼鐵業於CO2氣體的排放量中成為主要的產業之一,必須響應削減CO2氣體的排放量這一社會要求。具體而言,高爐操作中的源自煤炭的還原材料比的進一步削減已成為當務之急。所謂源自煤炭的還原材料比,是指製造1噸熔鐵所需的源自煤炭的焦炭及源自煤炭的還原氣體的合計質量。 In recent years, there has been a trend to reduce the emission of CO2 gas (carbon dioxide gas), which is one of the greenhouse gases. In the iron smelting process using blast furnaces, carbon materials are used as reducing materials, so a large amount of CO2 gas is generated. Therefore, the steel industry has become one of the major industries in terms of CO2 gas emissions, and must respond to the social demand for reducing CO2 gas emissions. Specifically, further reduction of the ratio of reducing materials derived from coal in blast furnace operations has become a top priority. The so-called ratio of reducing materials derived from coal refers to the combined mass of coke derived from coal and reducing gases derived from coal required to produce 1 ton of molten iron.
還原材料具有於爐內變成熱而使裝入物升溫的作用、以及將爐內的作為鐵系原料的鐵礦石、鐵礦石的燒結礦、鐵礦石的顆粒還原的作用。為了降低還原材料比以削減CO2氣體的排放量,需要一邊保持爐內的熱量,一邊提高還原材料的還原效率。 The reducing materials have the function of increasing the temperature of the charge by becoming heat in the furnace, and reducing the iron ore, sintered ore of iron ore, and iron ore particles in the furnace, which are iron-based raw materials. In order to reduce the reducing material ratio and reduce the emission of CO2 gas, it is necessary to improve the reduction efficiency of the reducing materials while maintaining the heat in the furnace.
作為以削減CO2氣體的排放量為目的的還原材料,氫備受矚目。利用氫進行的鐵礦石的還原為吸熱反應,但其吸熱量小於 直接還原反應(反應式:FeO+C→Fe+CO),基於氫的還原速度快於基於CO氣體的還原速度。因此,藉由向高爐吹入氫系氣體,可同時實現CO2氣體的排放量的削減以及還原效率的提高。 Hydrogen equipment has attracted much attention as a reducing material for reducing CO2 gas emissions. The reduction of iron ore using hydrogen is an endothermic reaction, but its endothermic amount is smaller than that of a direct reduction reaction (reaction formula: FeO+C→Fe+CO), and the reduction rate based on hydrogen is faster than that based on CO gas. Therefore, by blowing hydrogen-based gas into a blast furnace, it is possible to simultaneously reduce CO2 gas emissions and improve reduction efficiency.
為了高爐的穩定操作,需要確保高爐內的鐵系原料熔著的熔著帶的通氣性。但是,於使風口前的爐內產生高濃度還原氣體的高爐操作、以及較先前的操作而言爐內還原氣體濃度高並且還原反應速度快的高爐操作中,高爐內的通氣性並不清楚。 For stable operation of the blast furnace, it is necessary to ensure the air permeability of the melting zone where the iron-based raw materials are melted in the blast furnace. However, in the blast furnace operation that generates high-concentration reducing gas in the furnace before the tuyere, and in the blast furnace operation that has a high concentration of reducing gas in the furnace and a faster reduction reaction rate than the previous operation, the air permeability in the blast furnace is not clear.
高爐於生產銑鐵的同時,亦大量產出作為副產物的高爐熔渣(包含FeO、CaO、Al2O3、MgO、及SiO2等的氧化物)。為了良好地保持爐內的通氣性,需要進行可將所產出的高爐熔渣的黏度抑制得低而確保通液性的原料設計。 While producing ferromillite, blast furnaces also produce a large amount of blast furnace slag (containing oxides such as FeO, CaO, Al2O3 , MgO, and SiO2 ) as a by-product. In order to maintain good air permeability in the furnace , it is necessary to design raw materials that can suppress the viscosity of the produced blast furnace slag to a low level and ensure liquid permeability.
作為用於解決與所述課題類似的問題的現有技術,提出有專利文獻1~專利文獻3中所揭示的技術。 As prior art for solving problems similar to the above-mentioned subject, the technologies disclosed in Patent Documents 1 to 3 are proposed.
於專利文獻1中,揭示有一種自爐頂裝入焦炭、並自風口吹入輔助燃料的高爐操作。根據專利文獻1,藉由將焦炭及輔助燃料的Al2O3與SiO2的比(Al2O3/SiO2)設為0.6以上,且將高爐熔渣的鹼度((CaO+Al2O3+MgO)/SiO2)設為1.8以上,可改善高爐熔渣的性狀,提高通氣性及通液性。 Patent document 1 discloses a blast furnace operation in which coke is charged from the furnace top and auxiliary fuel is blown in from the tuyere. According to Patent document 1, by setting the ratio of Al2O3 to SiO2 ( Al2O3 / SiO2 ) of coke and auxiliary fuel to 0.6 or more, and setting the alkalinity of blast furnace slag ((CaO+ Al2O3 +MgO ) / SiO2 ) to 1.8 or more, the properties of blast furnace slag can be improved, and the gas permeability and liquid permeability can be increased.
於專利文獻2中,揭示有一種自風口將相對於1噸出鐵而為150kg以上的粉煤與熱風一起吹入至高爐內的高爐操作法。根據專利文獻2,藉由在自爐頂裝入的除焦炭以外的裝入物的80%以上中使用SiO2成分為4.0質量%~4.8質量%、MgO成分為1.2 質量%~2.4質量%、CaO成分為6.0質量%~9.0質量%、Al2O3成分為1.9質量%~2.5質量%的燒結礦,即便熔渣組成的FeO成分降低,亦可將滴落熔渣的黏度抑制得低。 Patent document 2 discloses a method for operating a blast furnace in which pulverized coal (150 kg or more per ton of iron produced) is blown into the blast furnace together with hot air from the tuyere. According to patent document 2, by using sintered ore having a SiO2 component of 4.0 mass% to 4.8 mass%, a MgO component of 1.2 mass% to 2.4 mass%, a CaO component of 6.0 mass% to 9.0 mass%, and an Al2O3 component of 1.9 mass% to 2.5 mass% as more than 80% of the charge other than coke charged from the furnace top, the viscosity of the dripping slag can be suppressed to be low even if the FeO component of the slag composition is reduced.
於專利文獻3中,揭示有根據通常所使用的燒結礦中的Al2O3量來調整副原料的調配比率,並使用高強度(破碎指數(shatter index,SI)>92%)且高被還原性(還原性指數(reducibility index,RI)>70%)的燒結礦的高爐操作方法。根據專利文獻3,藉由自高爐風口吹入與高強度且高被還原性的燒結礦、和通常所使用的燒結礦的副原料的調配比率的差相當的量的副原料,可長期穩定地進行高礦石/還原材料比操作。 Patent document 3 discloses a method for operating a blast furnace using a sintered ore with high strength (shatter index (SI)>92%) and high reducibility (reducibility index (RI)>70%) by adjusting the blending ratio of auxiliary raw materials according to the amount of Al2O3 in the sintered ore commonly used. According to Patent document 3, by injecting an auxiliary raw material in an amount corresponding to the difference in the blending ratio of the auxiliary raw materials of the sintered ore with high strength and high reducibility and the sintered ore commonly used from the tuyere of the blast furnace, a high ore/reduced material ratio operation can be performed stably for a long period of time.
[現有技術文獻] [Prior art literature]
[專利文獻] [Patent Literature]
專利文獻1:日本專利特開2004-10948號公報 Patent document 1: Japanese Patent Publication No. 2004-10948
專利文獻2:日本專利特開平9-13107號公報 Patent document 2: Japanese Patent Publication No. 9-13107
專利文獻3:日本專利特開2005-298923號公報 Patent document 3: Japanese Patent Publication No. 2005-298923
但是,該些現有技術均是將自風口吹入SiO2粉末等副原料、包含CaO或SiO2等的輔助燃料或粉煤的高爐操作設為對象,並未提及使風口前的爐內產生高濃度還原氣體的高爐操作中的裝入原料成分或熔渣成分。 However, these existing technologies all target the operation of a blast furnace in which by-raw materials such as SiO2 powder, auxiliary fuels containing CaO or SiO2 , or pulverized coal are blown into the furnace from the tuyere, and do not mention the raw material components or slag components in the blast furnace operation in which a high-concentration reducing gas is produced in the furnace in front of the tuyere.
於本發明中的高爐操作中,風口前的爐內所生成的還原 氣體的濃度非常高。因此,於爐內引起鐵系原料的還原率的上升以及熔渣中的FeO濃度的減少,熔渣中的FeO成分降低至比所述現有技術中所記載的操作範圍低的範圍。所述現有技術並未考慮到熔渣中的FeO成分進一步降低的情況。 In the blast furnace operation of the present invention, the concentration of the reducing gas generated in the furnace in front of the tuyere is very high. Therefore, the reduction rate of the iron-based raw materials in the furnace increases and the FeO concentration in the slag decreases, and the FeO component in the slag decreases to a range lower than the operating range described in the prior art. The prior art does not take into account the further reduction of the FeO component in the slag.
即,於以風口前的爐內產生的高濃度還原氣體成為圖1(圖1的說明將於以後敘述)的區域A的範圍內(包含H2氣體=0體積%~100體積%、N2氣體=0體積%~71體積%、CO氣體=0體積%~100體積%的範圍內)的方式進行操作時,比先前的操作更促進鐵系原料自低溫的還原,爐下部的鐵系原料的到達還原率上升。該情況下,若保持先前的操作方法的狀態,則有可能因熔渣中的FeO成分的減少而熔渣通液性降低,熔渣滯留於焦炭層的空隙中,爐內通氣阻力增加而誘發竄氣。 That is, when the operation is performed in such a manner that the high-concentration reducing gas generated in the furnace before the tuyere becomes within the range of region A in FIG. 1 (the description of FIG. 1 will be described later) (including the range of H2 gas = 0 volume % to 100 volume %, N2 gas = 0 volume % to 71 volume %, CO gas = 0 volume % to 100 volume %), the reduction of the iron-based raw materials from low temperatures is promoted more than in the previous operation, and the reduction rate of the iron-based raw materials reaching the lower part of the furnace is increased. In this case, if the state of the previous operation method is maintained, the slag permeability may be reduced due to the reduction of the FeO component in the slag, the slag may be retained in the gaps of the coke layer, the ventilation resistance in the furnace may increase, and fumes may be induced.
本發明是鑒於所述情況而成,其目的在於提供一種高爐操作方法,其於實施使風口前的爐內產生高濃度還原氣體的高爐操作時,改善熔渣性狀,即便熔渣中的FeO成分減少,亦可確保高爐內的熔著帶及滴落帶中的通氣性。 The present invention is made in view of the above situation, and its purpose is to provide a blast furnace operation method, which improves the slag properties when the blast furnace operation is implemented to generate high-concentration reducing gas in the furnace in front of the tuyere, and even if the FeO content in the slag is reduced, the air permeability in the molten zone and dripping zone in the blast furnace can be ensured.
用於解決所述課題的本發明的主旨如以下般。 The gist of the present invention for solving the above-mentioned problem is as follows.
[1]一種高爐操作方法,自高爐的爐頂裝入鐵系原料、副原料以及焦炭,並自高爐的風口吹入使風口前的爐內產生高濃度還原氣體的氣體,所述高爐操作方法將所述鐵系原料與所述副原料的原料總成分的鹼度設為規定範圍內。 [1] A blast furnace operation method, wherein iron-based raw materials, auxiliary raw materials and coke are charged from the top of the blast furnace, and gas is blown from the tuyere of the blast furnace to generate high-concentration reducing gas in the furnace in front of the tuyere, wherein the alkalinity of the total raw material component of the iron-based raw materials and the auxiliary raw materials is set within a specified range.
[2]如[1]所述的高爐操作方法,其中將所述原料總成分的鹼度設為1.0以上且1.7以下的範圍內。 [2] A blast furnace operating method as described in [1], wherein the alkalinity of the total raw material components is set within a range of greater than 1.0 and less than 1.7.
[3]如[1]所述的高爐操作方法,其中所述高濃度還原氣體於以爐腹氣體(Bosh gas)組成來表示時為如下組成、即包含H2氣體、N2氣體及CO氣體、且H2氣體、N2氣體及CO氣體的比例處於H2氣體-N2氣體-CO氣體的三元系圖表中的由H2氣體:0體積%、N2氣體:0體積%、CO氣體:100體積%的點、H2氣體:100體積%、N2氣體:0體積%、CO氣體:0體積%的點、H2氣體:29體積%、N2氣體:71體積%、CO氣體:0體積%的點、以及H2氣體:0體積%、N2氣體:37體積%、CO氣體:63體積%的點此四點包圍的區域內的組成,且包含0體積%~100體積%的範圍內的H2氣體、0體積%~71體積%的範圍內的N2氣體、以及0體積%~100體積%的範圍內的CO氣體。 [3] A blast furnace operating method as described in [1], wherein the high-concentration reducing gas has the following composition when expressed as a bosh gas composition, namely, it includes H2 gas, N2 gas and CO gas, and the ratio of H2 gas, N2 gas and CO gas is at a point where H2 gas : 0 volume%, N2 gas : 0 volume%, CO gas: 100 volume%, H2 gas: 100 volume%, N2 gas: 0 volume%, CO gas: 0 volume%, H2 gas: 29 volume%, N2 gas: 71 volume%, CO gas: 0 volume%, and H2 gas: 0 volume%, N2 gas: 10 ... 2 gas: 37 volume %, CO gas: 63 volume % The composition within the area surrounded by these four points includes H 2 gas in the range of 0 volume %~100 volume %, N 2 gas in the range of 0 volume %~71 volume %, and CO gas in the range of 0 volume %~100 volume %.
[4]如[2]所述的高爐操作方法,其中所述高濃度還原氣體於以爐腹氣體組成來表示時為如下組成、即包含H2氣體、N2氣體及CO氣體、且H2氣體、N2氣體及CO氣體的比例處於H2氣體-N2氣體-CO氣體的三元系圖表中的由H2氣體:0體積%、N2氣體:0體積%、CO氣體:100體積%的點、H2氣體:100體積%、N2氣體:0體積%、CO氣體:0體積%的點、H2氣體:29體積%、N2氣體:71體積%、CO氣體:0體積%的點、以及H2氣體:0體積%、N2氣體:37體積%、CO氣體:63體積%的點此四點包圍的區域內的組成,且包含0體積%~100體積%的範圍內的H2氣體、0體積 %~71體積%的範圍內的N2氣體、以及0體積%~100體積%的範圍內的CO氣體。 [4] A blast furnace operating method as described in [2], wherein the high-concentration reducing gas is a composition represented by a furnace gas composition, namely, comprising H2 gas, N2 gas and CO gas, and the ratio of H2 gas, N2 gas and CO gas is at a point in a ternary system diagram of H2 gas- N2 gas-CO gas where H2 gas: 0 volume%, N2 gas: 0 volume%, CO gas: 100 volume%, H2 gas: 100 volume%, N2 gas: 0 volume%, CO gas: 0 volume%, H2 gas: 29 volume%, N2 gas: 71 volume%, CO gas: 0 volume%, and H2 gas: 0 volume%, N2 gas: 10 ... 2 gas: 37 volume %, CO gas: 63 volume % The composition within the area surrounded by these four points includes H 2 gas in the range of 0 volume %~100 volume %, N 2 gas in the range of 0 volume %~71 volume %, and CO gas in the range of 0 volume %~100 volume %.
[5]如[1]至[4]中任一項所述的高爐操作方法,其中所述高濃度還原氣體中的H2氣體量為0Nm3/熔鐵-噸~500Nm3/熔鐵-噸的範圍內。 [5] The blast furnace operating method as described in any one of [1] to [4], wherein the amount of H 2 gas in the high-concentration reducing gas is in the range of 0 Nm 3 /molten iron-ton to 500 Nm 3 /molten iron-ton.
於本發明中,在實施使風口前的爐內產生高濃度還原氣體的高爐操作時,將鐵系原料與副原料的原料總成分的鹼度(質量%CaO/質量%SiO2)設為規定範圍內。藉此,於高爐內的熔著帶及滴落帶中生成的熔渣的黏度得以最佳化,高爐內的熔渣的通液性被控制為能夠操作的範圍內,結果,可良好地保持高爐內的氣體通氣性,實現高爐的穩定操作。 In the present invention, when a blast furnace operation is performed to generate a high-concentration reducing gas in the furnace before the tuyere, the alkalinity (mass% CaO/mass% SiO2 ) of the total raw material components of the iron-based raw materials and the auxiliary raw materials is set within a specified range. Thereby, the viscosity of the slag generated in the molten zone and the dripping zone in the blast furnace is optimized, and the liquid permeability of the slag in the blast furnace is controlled within the operable range. As a result, the gas permeability in the blast furnace can be well maintained, and the stable operation of the blast furnace is achieved.
以下,說明本發明的實施形態。本實施形態的高爐操作方法為如下高爐操作方法,其自高爐的爐頂將鐵系原料、副原料以及焦炭交替且呈層狀地裝入至高爐內,並且自設置於高爐下部的風口向高爐內吹入氣體,利用自風口吹入的氣體使風口前的高爐內生成高濃度還原氣體。鐵系原料中例如包含鐵礦石、鐵礦石的燒結礦、鐵礦石的顆粒、還原鐵及廢鐵。副原料中單獨包含或複合包含SiO2、CaO。使用的鐵系原料、副原料以及焦炭的種類並無特別限制,若為先前的高爐操作中所使用的鐵系原料、副原料以及焦炭,則於本發明中亦可適宜地使用。 The following is an explanation of the embodiment of the present invention. The blast furnace operation method of the present embodiment is a blast furnace operation method in which iron-based raw materials, auxiliary raw materials and coke are alternately and layeredly charged into the blast furnace from the top of the blast furnace, and gas is blown into the blast furnace from a tuyere provided at the bottom of the blast furnace, and a high-concentration reducing gas is generated in the blast furnace in front of the tuyere by the gas blown from the tuyere. The iron-based raw materials include, for example, iron ore, sintered ore of iron ore, iron ore particles, reduced iron and scrap iron. The auxiliary raw materials include SiO 2 and CaO alone or in combination. The types of the iron-based raw materials, auxiliary raw materials, and coke used are not particularly limited. If they are iron-based raw materials, auxiliary raw materials, and coke used in the previous blast furnace operation, they can also be appropriately used in the present invention.
用於生成高濃度還原氣體的氣體包含將高爐內的鐵系原料還原的還原成分。此處,將高爐內的鐵系原料還原的還原成分中不僅包含可將鐵系原料還原的成分即CO氣體、H2氣體、烴氣體,而且亦包含藉由與焦炭的反應或分解反應等而生成還原氣體的成分即CO2氣體、H2O氣體等。 The gas used to generate the high-concentration reducing gas includes a reducing component that reduces the iron-based raw materials in the blast furnace. Here, the reducing component that reduces the iron-based raw materials in the blast furnace includes not only CO gas, H2 gas, and hydrocarbon gas that can reduce the iron-based raw materials, but also CO2 gas, H2O gas, and other components that generate reducing gas by reaction or decomposition reaction with coke.
圖1是於H2氣體-N2氣體-CO氣體的三元系圖表的氣體成分組成中,以爐腹氣體組成表示藉由本實施形態的高爐操作方法使風口前的爐內生成的高濃度還原氣體的成分範圍的圖。所謂本實施形態中的高濃度還原氣體,為使用該高濃度還原氣體將鐵系原料於900℃下還原180分鐘時的平均還原率為80%以上的還原氣體。於以爐腹氣體組成表示該還原氣體時,為如下組成、即包含H2氣體、N2氣體以及CO氣體、且H2氣體、N2氣體以及CO氣體的比例(其中,設為H2氣體+N2氣體+CO氣體=100體積%時的 比例)為圖1中斜線部所表示的區域A(本發明的操作範圍)的範圍內、並且包含0體積%~100體積%的範圍內的H2氣體、0體積%~71體積%的範圍內的N2氣體、以及0體積%~100體積%的範圍內的CO氣體的氣體組成。 Fig. 1 is a diagram showing the composition range of the high-concentration reducing gas generated in the furnace before the tuyere by the blast furnace operation method of this embodiment in the gas component composition of the ternary system diagram of H2 gas- N2 gas-CO gas, using the belly gas composition. The so-called high-concentration reducing gas in this embodiment is a reducing gas in which the average reduction rate of the iron-based raw material is 80% or more when the high-concentration reducing gas is used to reduce the iron-based raw material at 900°C for 180 minutes. When the reducing gas is represented by the furnace gas composition, it is a composition including H2 gas, N2 gas and CO gas, and the ratio of H2 gas, N2 gas and CO gas (wherein the ratio is assumed to be H2 gas + N2 gas + CO gas = 100 volume %) is within the range of area A (the operating range of the present invention) represented by the oblique line portion in FIG. 1, and includes H2 gas in the range of 0 volume % to 100 volume %, N2 gas in the range of 0 volume % to 71 volume %, and CO gas in the range of 0 volume % to 100 volume %.
區域A為於H2氣體-N2氣體-CO氣體的三元系圖表中,由點O(H2氣體:0體積%、N2氣體:0體積%、CO氣體:100體積%)、點P(H2氣體:100體積%、N2氣體:0體積%、CO氣體:0體積%)、點Q(H2氣體:29體積%、N2氣體:71體積%、CO氣體:0體積%)及點R(H2氣體:0體積%、N2氣體:37體積%、CO氣體:63體積%)此四點包圍的範圍內。另外,圖1中比較示出先前的一般的高爐操作範圍的氣體組成。於該區域A中的由點O(H2氣體:0體積%、N2氣體:0體積%、CO氣體:100體積%)、點P(H2氣體:100體積%、N2氣體:0體積%、CO氣體:0體積%)、點Q'(H2氣體:43體積%、N2氣體:57體積%、CO氣體:0體積%)及點R'(H2氣體:0體積%、N2氣體:14體積%、CO氣體:86體積%)此四點包圍的範圍內,將鐵系原料於900℃下還原180分鐘時的平均還原率為90%以上,因此爐內的熔著帶中的熔渣成分中的FeO含量明顯降低。因此,於使風口前的爐內生成該成分範圍的高濃度還原氣體時,由針對恢復包含熔渣的熔融物的滴落量的、原料總成分的鹼度(質量%CaO/質量%SiO2)的調整帶來的效果進一步變高。 Region A is a range surrounded by four points, namely, point O (H 2 gas: 0 volume%, N 2 gas: 0 volume%, CO gas: 100 volume%), point P (H 2 gas: 100 volume%, N 2 gas: 0 volume%, CO gas: 0 volume%), point Q (H 2 gas: 29 volume%, N 2 gas: 71 volume%, CO gas: 0 volume%), and point R (H 2 gas: 0 volume%, N 2 gas: 37 volume%, CO gas: 63 volume%), in the ternary system diagram of H 2 gas-N 2 gas-CO gas. In addition, FIG. 1 shows a comparative gas composition of a general blast furnace operation range in the past. In the area A, within the range surrounded by the four points O (H 2 gas: 0 volume %, N 2 gas: 0 volume %, CO gas: 100 volume %), point P (H 2 gas: 100 volume %, N 2 gas: 0 volume %, CO gas: 0 volume %), point Q' (H 2 gas: 43 volume %, N 2 gas: 57 volume %, CO gas: 0 volume %) and point R' (H 2 gas: 0 volume %, N 2 gas: 14 volume %, CO gas: 86 volume %), the average reduction rate of the iron-based raw material when reduced at 900°C for 180 minutes is above 90%, so the FeO content in the slag component in the molten zone in the furnace is significantly reduced. Therefore, when a high-concentration reducing gas within this composition range is generated in the furnace before the tuyere, the effect of adjusting the alkalinity (mass% CaO/mass% SiO 2 ) of the total raw material components for recovering the dripping amount of the molten material including slag becomes higher.
本發明者等人使用模擬高爐的比例尺1/4的小型試驗爐, 進行使風口前的爐內生成高濃度還原氣體的試驗,對爐內的熔著帶及滴落帶中的熔渣成分進行調查。表1中示出小型試驗爐中所使用的鐵系原料的成分組成的一例。 The inventors of the present invention used a small test furnace with a scale of 1/4 that simulated a blast furnace to conduct an experiment to generate a high-concentration reducing gas in the furnace in front of the tuyere and investigate the slag composition in the molten zone and dripping zone in the furnace. Table 1 shows an example of the composition of the iron-based raw materials used in the small test furnace.
於小型試驗爐中,進行如下試驗,即,將鐵系原料、副原料及焦炭的配方設為與專利文獻2中所記載的操作方法相同、且鐵系原料與副原料的原料總成分的鹼度為2.0的配方,並使風口前的爐內生成高濃度還原氣體。於該試驗條件下,算出爐內的熔著帶中的熔渣成分中,FeO成分小於3.5質量%,SiO2成分為25.4質量%~28.3質量%,Al2O3成分為8.6質量%~9.2質量%,CaO成分為52.5質量%~56.7質量%,MgO成分為5.3質量%~7.3質量%。因熔渣的鹼度變高而為約2.0,且熔渣的滴落量減少至先前試驗的十分之一左右,因此氣體通氣性劣化至能夠穩定地繼續試驗的範圍外。 In a small test furnace, the following test was conducted, i.e., the formula of the iron-based raw material, auxiliary raw material and coke was set to the same as the operation method described in Patent Document 2, and the alkalinity of the total raw material components of the iron-based raw material and auxiliary raw material was 2.0, and a high-concentration reducing gas was generated in the furnace before the tuyere. Under the test conditions, the slag components in the molten zone in the furnace were calculated to have an FeO component of less than 3.5% by mass, an SiO2 component of 25.4% to 28.3% by mass, an Al2O3 component of 8.6% to 9.2% by mass, a CaO component of 52.5% to 56.7% by mass, and an MgO component of 5.3% to 7.3% by mass. Since the alkalinity of the slag increased to about 2.0 and the amount of slag dripping decreased to about one-tenth of that in the previous test, the gas permeability deteriorated to a level beyond the range in which the test could be continued stably.
認為於增加熔渣的滴落量時必須降低生成的熔渣的鹼度。因此,使鐵系原料與副原料的原料總成分的鹼度於0.95~2.23的範圍內變更,進行使風口前的爐內生成高濃度還原氣體的試驗,調查原料總成分的鹼度對熔融物滴落量及通氣阻力指數KS造成的影響。 It is believed that the alkalinity of the generated slag must be reduced when increasing the amount of slag dripping. Therefore, the alkalinity of the total raw material components of iron-based raw materials and auxiliary raw materials was changed within the range of 0.95~2.23, and a test was conducted to generate high-concentration reducing gas in the furnace before the tuyere to investigate the effect of the alkalinity of the total raw material components on the amount of molten material dripping and the ventilation resistance index KS.
關於熔融物滴落量,於實驗後回收試驗中滴落的熔融物,利用重量計測定其總重量。通氣阻力指數KS是作為以在爐內溫度為1000℃以上的區域中測定的壓力損失、與根據操作條件推測的物性值為基礎而算出的通氣阻力K值(1/m)的積分值來算出。 Regarding the amount of molten material dripping, the molten material dripping during the test was recovered after the experiment, and its total weight was measured using a weight meter. The ventilation resistance index KS was calculated as the integral value of the ventilation resistance K value (1/m) calculated based on the pressure loss measured in the range of the furnace temperature above 1000°C and the physical property value estimated based on the operating conditions.
<通氣阻力指數KS的算出方法> <Calculation method of ventilation resistance index KS>
通氣阻力K值(1/m)是藉由下述(1)式來算出。 The ventilation resistance K value (1/m) is calculated using the following formula (1).
K=(△P/H)/(ρgas 0.7×μgas 0.3×vgas 1.7)...(1) K=(△P/H)/(ρ gas 0.7 ×μ gas 0.3 ×v gas 1.7 )...(1)
此處,△P為壓力損失(Pa),H為爐內填充層層厚(m),ρgas為氣體密度(kg/m3),μgas為氣體黏度(Pa.s),vgas為氣體流速(m/s)。△P是藉由在風口與試驗爐上部(比填充層更靠上部的空間)的爐壁設置壓力計並計算壓力的差量而求出。關於H,自例如於試驗爐上部穿孔的孔插入測定用夾具來測定填充層表面的位置,並使用填充層表面位置與設置有風口的位置於高度方向上的距離作為H。可使用雷射距離計測定填充層表面的位置。ρgas可根據自風口導入的氣體成分、爐內的溫度、以及爐內的壓力來算出。μgas可根據自風口導入的氣體成分、與爐內的溫度來算出。vgas可根據自風口導入的氣體流量、爐內的溫度、以及爐內的壓力來算出。此處,爐內的溫度是於與填充層對應的位置的爐壁設置多個溫度計,並使用該溫度計的測定值的平均值。同樣地,爐內的壓力是於與填充層對應的位置的爐壁設置多個壓力計,並使用該壓力計的測定值的平 均值。亦可使用△P的算出中使用的風口的壓力與填充層上部的壓力的平均值作為爐內的壓力。 Here, ΔP is the pressure loss (Pa), H is the thickness of the filling layer in the furnace (m), ρ gas is the gas density (kg/m 3 ), μ gas is the gas viscosity (Pa.s), and v gas is the gas flow rate (m/s). ΔP is obtained by installing a pressure gauge on the furnace wall at the tuyere and the upper part of the test furnace (the space above the filling layer) and calculating the pressure difference. Regarding H, a measuring jig is inserted from a hole drilled in the upper part of the test furnace, for example, to measure the position of the filling layer surface, and the distance in the height direction between the filling layer surface position and the position where the tuyere is installed is used as H. The position of the filling layer surface can be measured using a laser distance meter. ρ gas can be calculated based on the composition of the gas introduced from the tuyere, the temperature in the furnace, and the pressure in the furnace. μ gas can be calculated based on the composition of the gas introduced from the tuyere, and the temperature in the furnace. v gas can be calculated based on the flow rate of the gas introduced from the tuyere, the temperature in the furnace, and the pressure in the furnace. Here, the temperature in the furnace is obtained by installing a plurality of thermometers on the furnace wall at a position corresponding to the filling layer, and using the average value of the measured values of the thermometers. Similarly, the pressure in the furnace is obtained by installing a plurality of pressure gauges on the furnace wall at a position corresponding to the filling layer, and using the average value of the measured values of the pressure gauges. The average value of the pressure at the tuyere used in the calculation of ΔP and the pressure on the top of the filling layer can also be used as the pressure in the furnace.
通氣阻力指數KS是藉由下述(2)式來算出。 The ventilation resistance index KS is calculated using the following formula (2).
於(2)式中,Tmax為測定爐內壓力損失的最高溫度,雖然每次測定均不同,但為1500℃~1650℃左右。 In formula (2), Tmax is the maximum temperature for measuring the pressure loss in the furnace. Although it is different for each measurement, it is around 1500℃~1650℃.
圖2是表示於使風口前的爐內生成高濃度還原氣體的試驗中,原料總成分的鹼度對熔融物滴落量造成的影響的圖形。圖2的橫軸為原料總成分的鹼度(質量%CaO/質量%SiO2),縱軸為熔融物滴落量(g)。 Figure 2 is a graph showing the effect of the alkalinity of the total raw material components on the amount of melt dripping in an experiment in which a high-concentration reducing gas is generated in the furnace before the tuyere. The horizontal axis of Figure 2 is the alkalinity of the total raw material components (mass%CaO/mass% SiO2 ), and the vertical axis is the amount of melt dripping (g).
圖3是表示於使風口前的爐內生成高濃度還原氣體的試驗中,原料總成分的鹼度對通氣阻力指數KS造成的影響的圖形。圖3的橫軸為原料總成分的鹼度(質量%CaO/質量%SiO2),縱軸為通氣阻力指數KS(105℃/m)。 Fig. 3 is a graph showing the effect of the alkalinity of the total raw material components on the ventilation resistance index KS in an experiment in which a high-concentration reducing gas is generated in the furnace before the tuyere. The horizontal axis of Fig. 3 is the alkalinity of the total raw material components (mass%CaO/mass% SiO2 ), and the vertical axis is the ventilation resistance index KS ( 105 ℃/m).
如圖2所示,於鐵系原料與副原料的原料總成分的鹼度為1.0~1.7的範圍內,熔融物滴落量增加。另外,如圖3所示,確認到於鐵系原料與副原料的原料總成分的鹼度為1.0~1.7的範圍內,通氣阻力指數KS降低至作為目標值的2000以下。通氣阻 力指數KS的目標值2000為能夠繼續穩定的試驗的閾值。所謂穩定的試驗,是指填充層表面高度相對於時間而言均勻地降低,不會產生竄氣等故障的試驗。 As shown in Figure 2, the amount of molten material dripping increases when the alkalinity of the total raw material components of the iron-based raw materials and auxiliary raw materials is in the range of 1.0 to 1.7. In addition, as shown in Figure 3, it is confirmed that the ventilation resistance index KS decreases to below 2000, which is the target value, when the alkalinity of the total raw material components of the iron-based raw materials and auxiliary raw materials is in the range of 1.0 to 1.7. The target value of the ventilation resistance index KS of 2000 is the threshold value for the test to continue stably. The so-called stable test refers to a test in which the surface height of the filling layer decreases uniformly with respect to time, and no faults such as fumes occur.
根據該些結果,確認到藉由將鐵系原料與副原料的原料總成分的鹼度設為1.0~1.7的範圍內,可穩定地進行使風口前的爐內生成高濃度還原氣體的試驗。 Based on these results, it was confirmed that by setting the alkalinity of the total raw material components of the iron-based raw materials and auxiliary raw materials in the range of 1.0 to 1.7, it was possible to stably conduct an experiment to generate a high-concentration reducing gas in the furnace before the tuyere.
本實施形態的高爐操作方法是基於所述試驗結果而成者,且為如下高爐操作方法,其中自高爐的爐頂裝入鐵系原料、副原料以及焦炭,並自高爐的風口吹入使風口前的爐內產生高濃度還原氣體的氣體,所述高爐操作方法將裝入的鐵系原料與裝入的副原料的原料總成分的鹼度設為規定範圍內。 The blast furnace operation method of this embodiment is based on the test results, and is a blast furnace operation method in which iron-based raw materials, auxiliary raw materials and coke are charged from the top of the blast furnace, and gas is blown from the tuyere of the blast furnace to generate high-concentration reducing gas in the furnace in front of the tuyere, and the alkalinity of the total raw material components of the charged iron-based raw materials and the charged auxiliary raw materials is set within a specified range.
此處,裝入的鐵系原料與裝入的副原料的原料總成分的鹼度較佳為1.0以上且1.7以下的範圍內。藉此,可提高高爐爐下部的熔融物的滴落性與通氣性。於鐵系原料與副原料的原料總成分的鹼度小於1.0的情況下、以及鐵系原料與副原料的原料總成分的鹼度超過1.7的情況下,熔渣的黏度均上升並脫離穩定操作範圍,因此欠佳。 Here, the alkalinity of the total raw material components of the charged iron-based raw materials and the charged auxiliary raw materials is preferably within the range of 1.0 or more and 1.7 or less. This can improve the dripping and air permeability of the molten material in the lower part of the blast furnace. When the alkalinity of the total raw material components of the iron-based raw materials and the auxiliary raw materials is less than 1.0, and when the alkalinity of the total raw material components of the iron-based raw materials and the auxiliary raw materials exceeds 1.7, the viscosity of the slag increases and deviates from the stable operating range, which is not good.
再者,裝入的鐵系原料與副原料的原料總成分的鹼度更佳為1.1以上且1.7以下,進而佳為1.4以上且1.5以下。藉此,熔渣的黏度進一步降低,可進一步提高熔融物的滴落性與通氣性。於原料調整時,較佳為將熔渣量設為400kg/熔鐵-噸以下。藉由將熔渣量設為400kg/熔鐵-噸以下,可抑制由自低溫區域熔出的熔融 物量的增加所致的通氣性的降低。 Furthermore, the alkalinity of the total raw material components of the charged iron-based raw materials and auxiliary raw materials is preferably 1.1 or more and 1.7 or less, and further preferably 1.4 or more and 1.5 or less. Thereby, the viscosity of the slag is further reduced, and the dripping and air permeability of the molten material can be further improved. When adjusting the raw materials, it is preferred to set the slag amount to 400kg/molten iron-ton or less. By setting the slag amount to 400kg/molten iron-ton or less, the decrease in air permeability caused by the increase in the amount of molten material melted out from the low temperature area can be suppressed.
另外,高濃度還原氣體較佳為該高濃度還原氣體中的H2氣體量(包含烴中的氫在內)為0Nm3/熔鐵-噸~500Nm3/熔鐵-噸的範圍內。藉此,可抑制爐內溫度的降低及還原反應速度的降低。另一方面,若高濃度還原氣體中的H2氣體量超過500Nm3/熔鐵-噸,則爐內溫度降低,還原反應速度降低,因此欠佳。另外,於以單質的形式吹入H2氣體的情況下,為了將風口前溫度保持為操作範圍內,較佳為於對H2氣體進行加熱後予以送風。 In addition, the high-concentration reducing gas preferably has an H 2 gas amount (including hydrogen in hydrocarbons) in the range of 0 Nm 3 /molten iron-ton to 500 Nm 3 /molten iron-ton. This can suppress the decrease in the temperature in the furnace and the decrease in the reduction reaction rate. On the other hand, if the H 2 gas amount in the high-concentration reducing gas exceeds 500 Nm 3 /molten iron-ton, the temperature in the furnace decreases and the reduction reaction rate decreases, which is not preferred. In addition, when H 2 gas is blown in a single form, in order to keep the temperature before the tuyere within the operating range, it is preferred to blow the H 2 gas after heating it.
如以上所說明般,於本實施形態的高爐操作方法中,在實施使風口前的爐內產生高濃度還原氣體的高爐操作時,將裝入的鐵系原料與裝入的副原料的原料總成分的鹼度控制為規定範圍內。藉此,於高爐內的熔著帶及滴落帶中生成的熔渣的黏度得以最佳化,高爐內的熔渣的通液性被控制為能夠操作的範圍內,可良好地保持高爐內的氣體通氣性,可實現穩定操作。 As described above, in the blast furnace operation method of this embodiment, when the blast furnace operation is performed to generate high-concentration reducing gas in the furnace before the tuyere, the alkalinity of the total raw material components of the charged iron-based raw materials and the charged auxiliary raw materials is controlled within a specified range. Thereby, the viscosity of the slag generated in the molten zone and the dripping zone in the blast furnace is optimized, and the liquid permeability of the slag in the blast furnace is controlled within the range that can be operated, so that the gas permeability in the blast furnace can be well maintained, and stable operation can be achieved.
[實施例] [Implementation example]
使用大型高爐實施如下高爐操作試驗,即,自爐頂交替裝入鐵系原料、副原料以及焦炭,使自爐頂裝入的鐵系原料與副原料的原料總成分的鹼度發生變化,並使風口前的爐內生成高濃度還原氣體。表2中示出了試驗結果的一例。 A large blast furnace was used to conduct the following blast furnace operation test, that is, iron-based raw materials, auxiliary raw materials and coke were alternately charged from the top of the furnace, the alkalinity of the total raw material composition of the iron-based raw materials and auxiliary raw materials charged from the top of the furnace was changed, and a high-concentration reducing gas was generated in the furnace in front of the tuyere. An example of the test results is shown in Table 2.
如表2所示般,確認到於將自爐頂裝入的鐵系原料與副原料的原料總成分的鹼度設為本發明的範圍的發明例1~發明例4中,滴落性及通氣性良好,能夠進行穩定操作。另一方面,於自爐頂裝入的鐵系原料與副原料的原料總成分的鹼度為本發明的範圍外的比較例1~比較例3中,無法獲得充分的滴落量,通氣性亦不良。 As shown in Table 2, it was confirmed that in Invention Examples 1 to 4, in which the alkalinity of the total raw material components of the iron-based raw materials and auxiliary raw materials charged from the top of the furnace was set within the range of the present invention, the dripping property and the ventilation property were good and stable operation was possible. On the other hand, in Comparative Examples 1 to 3, in which the alkalinity of the total raw material components of the iron-based raw materials and auxiliary raw materials charged from the top of the furnace was outside the range of the present invention, sufficient dripping amount could not be obtained and ventilation property was also poor.
圖1是於H2氣體-N2氣體-CO氣體的三元系圖表的氣體成分組成中,以爐腹氣體組成表示藉由本實施形態的高爐操作方法使風口前的爐內生成的高濃度還原氣體的成分範圍的圖。 FIG1 is a diagram showing the composition range of the high-concentration reducing gas generated in the furnace before the tuyere by the blast furnace operation method of the present embodiment, using the belly gas composition in the gas component composition of the ternary system diagram of H2 gas-N2 gas-CO gas.
圖2是表示於使風口前的爐內生成高濃度還原氣體的試驗中,原料總成分的鹼度對熔融物滴落量造成的影響的圖形。 Figure 2 is a graph showing the effect of the alkalinity of the total raw material composition on the amount of molten material dripping in an experiment in which a high-concentration reducing gas is generated in the furnace in front of the tuyere.
圖3是表示於使風口前的爐內生成高濃度還原氣體的試驗中,原料總成分的鹼度對通氣阻力指數KS造成的影響的圖形。 Figure 3 is a graph showing the effect of the alkalinity of the total raw material components on the ventilation resistance index KS in an experiment in which a high-concentration reducing gas is generated in the furnace in front of the tuyere.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW514668B (en) * | 1997-09-26 | 2002-12-21 | Technolohical Resources Pty Lt | A process of producing molten metals |
| TWI396749B (en) * | 2008-03-31 | 2013-05-21 | Nippon Steel & Sumitomo Metal Corp | Producing method of reduced iron |
| JP2015199978A (en) * | 2014-04-04 | 2015-11-12 | 新日鐵住金株式会社 | High furnace operation method using reduced iron |
| CN105349725A (en) * | 2015-11-07 | 2016-02-24 | 衡南扬钢冶金技术有限公司 | Spontaneous combustion reduction method iron-smelting method and smelting device |
| CN110229939A (en) * | 2019-07-15 | 2019-09-13 | 陶立群 | A kind of non-burnt iron-smelting device of two sections of kiln processes |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US2790711A (en) * | 1957-04-30 | Molten | ||
| US3460934A (en) * | 1966-12-19 | 1969-08-12 | John J Kelmar | Blast furnace method |
| JP2962195B2 (en) | 1995-06-27 | 1999-10-12 | 住友金属工業株式会社 | Blast furnace operation method |
| JPH09143516A (en) * | 1995-11-17 | 1997-06-03 | Nippon Steel Corp | Operating method of vertical furnace |
| JP2002060809A (en) * | 2000-08-08 | 2002-02-28 | Nippon Steel Corp | Low blast furnace blast furnace operation method using sintered ore with adjusted chemical composition |
| JP3705243B2 (en) | 2002-06-05 | 2005-10-12 | 住友金属工業株式会社 | Blast furnace operation method |
| JP2005298923A (en) | 2004-04-13 | 2005-10-27 | Nippon Steel Corp | High ore / reducing material ratio operation method in blast furnace |
| BR112012003786B1 (en) * | 2009-08-21 | 2021-11-16 | Nippon Steel Corporation | AGGLOMERATE CONTAINING UNBURNT CARBON FOR BLAST FURNACES AND ITS PRODUCTION PROCESS |
| JP2013082971A (en) * | 2011-10-11 | 2013-05-09 | Nippon Steel & Sumitomo Metal Corp | Method for operating blast furnace |
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-
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW514668B (en) * | 1997-09-26 | 2002-12-21 | Technolohical Resources Pty Lt | A process of producing molten metals |
| TWI396749B (en) * | 2008-03-31 | 2013-05-21 | Nippon Steel & Sumitomo Metal Corp | Producing method of reduced iron |
| JP2015199978A (en) * | 2014-04-04 | 2015-11-12 | 新日鐵住金株式会社 | High furnace operation method using reduced iron |
| CN105349725A (en) * | 2015-11-07 | 2016-02-24 | 衡南扬钢冶金技术有限公司 | Spontaneous combustion reduction method iron-smelting method and smelting device |
| CN110229939A (en) * | 2019-07-15 | 2019-09-13 | 陶立群 | A kind of non-burnt iron-smelting device of two sections of kiln processes |
Non-Patent Citations (1)
| Title |
|---|
| 期刊 大野陽太郎・松浦正博 (Yotaro OHNO and Masahiro MATSUURA) 酸素高炉プロセスにおける炉内装入物の昇温,反応特性 (Heating-up and Reaction Characteristics of Burdens in Oxygen Blast Furnace Process)Blast Furnace Process) 鉄と鋼 1990 年 76 巻 8 号 p. 1262-1269 日本鉄鋼協会 平成元年 4 月本会講演大会にて発表 平成元年 8 月 15 日受付 (Received Aug. 15, 1989) 60-67 * |
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