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TWI859644B - Welding quality controlling method, welding bed and molten welding system - Google Patents

Welding quality controlling method, welding bed and molten welding system Download PDF

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TWI859644B
TWI859644B TW111145477A TW111145477A TWI859644B TW I859644 B TWI859644 B TW I859644B TW 111145477 A TW111145477 A TW 111145477A TW 111145477 A TW111145477 A TW 111145477A TW I859644 B TWI859644 B TW I859644B
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temperature
platform
welding
welded
workpiece
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TW202421313A (en
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李捷
杜昭緯
王智楷
童培鈞
林典永
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財團法人金屬工業研究發展中心
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Abstract

A welding quality controlling method is adapted for solving the conventional problem prone to generating the intermetallic compound within the welding line while cooling. The method comprises the following steps. A first workpiece and a second workpiece are provided, and the edges of the first and second workpieces to be welded contact to each other. The to-be-welded welding line is formed a wleded zone within temporary molten state. The wleded zone has at least two metallic phases changing by a relationship with temperature and time in the cooling process. One of the at least two metallic phases generates the intermetallic compound. A predetermined temperatur controlling condition within a specifice time period is defined by a corresponding time-temperature-transformation diagram, thereby controlling the temperature-time relationship of the wleded zone, so that the time period undergoing the metallic phase generating the intermetallic compound in the cooling process can be minimized.

Description

控制銲接品質之方法、銲接平台及熔融式接合系統 Method for controlling welding quality, welding platform and fusion bonding system

本發明係關於一種加工方法,尤其是一種控制銲接品質之方法、銲接平台及熔融式接合系統。 The present invention relates to a processing method, in particular to a method for controlling welding quality, a welding platform and a fusion bonding system.

雷射銲接是利用高能量密度的光源照射材料,使材料吸收雷射能量後產生熱能而熔融乃至汽化形成熔池,再經冷卻將物體接合。惟,在習知技術中,當以雷射進行兩種異質金屬間銲接試著使其接合時,在兩異質金屬之銲接交界處將易於產生金屬間化合物(Intermetallic Compound)。特別是,金屬間化合物在自然冷卻的過程中容易產生硬脆相的結構,使對應的銲道(Welding Line)/銲縫(Welding Joint)容易脆裂,使異質金屬間的經銲接交界處無法有效的接合。 Laser welding uses a high-energy-density light source to irradiate the material, so that the material absorbs the laser energy and generates heat energy to melt or even vaporize to form a molten pool, and then cools the object to join. However, in the known technology, when laser welding is used to try to join two dissimilar metals, intermetallic compounds (Intermetallic Compound) will be easily generated at the welding junction of the two dissimilar metals. In particular, the intermetallic compound is easy to produce a hard and brittle phase structure during the natural cooling process, making the corresponding weld line (Welding Line)/welding joint (Welding Joint) easy to brittle, making the welded junction between the dissimilar metals unable to be effectively joined.

有鑑於此,習知的銲道冷卻方法確實仍有加以改善之必要。 In view of this, the conventional welding channel cooling method still needs to be improved.

為解決上述問題,本發明的目的是提供一種控制銲接品質之方法,可提升銲道接合品質者。 In order to solve the above problems, the purpose of the present invention is to provide a method for controlling welding quality, which can improve the quality of welding track connection.

本發明的次一目的是提供一種銲接平台,可便於控制目標區域的溫度,進而提升銲道接合品質者。 The second purpose of the present invention is to provide a welding platform that can facilitate the control of the temperature of the target area, thereby improving the quality of the welding track.

本發明的次一目的是提供一種熔融式接合系統,可提升銲道接合品質者。 A second object of the present invention is to provide a fusion bonding system that can improve the quality of weld bonding.

本發明全文所述方向性或其近似用語,例如「前」、「後」、「左」、「右」、「上(頂)」、「下(底)」、「內」、「外」、「側面」等,主要係參考附加圖式的方向,各方向性或其近似用語僅用以輔助說明及理解本發明的各實施例,非用以限制本發明。 The directions or similar terms described in the present invention, such as "front", "rear", "left", "right", "upper", "lower", "inner", "outer", "side", etc., are mainly for reference to the directions of the attached drawings. Each direction or similar terms are only used to assist in the description and understanding of the various embodiments of the present invention, and are not used to limit the present invention.

本發明全文所記載的元件及構件使用「一」或「一個」之量詞,僅是為了方便使用且提供本發明範圍的通常意義;於本發明中應被解讀為包括一個或至少一個,且單一的概念也包括複數的情況,除非其明顯意指其他意思。 The quantifiers "one" or "a" used in the components and parts described throughout the present invention are only for the convenience of use and to provide a general meaning of the scope of the present invention; in the present invention, they should be interpreted as including one or at least one, and the single concept also includes the plural case, unless it is obvious that it means otherwise.

本發明全文所述「結合」、「組合」、「組裝」或「設置」等近似用語,主要包含連接後仍可不破壞構件地分離,或是連接後使構件不可分離等型態,係本領域中具有通常知識者可以依據欲相連之構件材質或組裝需求予以選擇者。 The similar terms such as "combination", "assembly", "assembly" or "setting" mentioned in the present invention mainly include the connection that can be separated without damaging the components, or the connection that makes the components inseparable, which can be selected by those with ordinary knowledge in the field according to the materials of the components to be connected or the assembly requirements.

本發明全文所述「耦接」用語,包含電性地及/或訊號地直接或間接連接,係本領域中具有通常知識者可以依據使用需求予以選擇者。 The term "coupling" used throughout this invention includes direct or indirect electrical and/or signal connections, which can be selected by those with ordinary knowledge in the field according to usage requirements.

本發明全文所述有關「控制器」者,係可包含至少一「處理器(Processor)」,所述處理器係指具備特定功能且以硬體或硬體與軟體實現的各式資料處理裝置,以處理分析資訊及/或產生對應控制資訊,例如:電子控制器、伺服器、雲端平台、虛擬機器、桌上型電腦、筆記型電腦、平板電腦或智慧型手機等,係本發明/本創作所屬技術領域中具有通常知識者可以理解。另,可包含對應的資料接收或傳輸單元,以進行所需資料的接收或傳輸。另,可包含對應的資料庫/儲存單元,以儲存所需資料。特別是,除非另外特 別排除或矛盾,所述處理器可以是基於分散式系統架構中的多個處理器的集合,用於包含/代表多個處理器間資訊串流處理的過程、機制及結果。此外,本發明所稱「控制器」係可代表一個整合式技術特徵,可以是以單個控制器耦接並整合控制所耦接的一個或多個裝置,或是多個控制器各別控制其所耦接的裝置等情形,使對應裝置在適合的條件中執行其功能。 The "controller" mentioned in the whole text of the present invention may include at least one "processor", which refers to various data processing devices with specific functions and implemented by hardware or hardware and software to process and analyze information and/or generate corresponding control information, such as: electronic controllers, servers, cloud platforms, virtual machines, desktop computers, laptops, tablet computers or smart phones, etc., which can be understood by those with ordinary knowledge in the technical field to which the present invention/creation belongs. In addition, it may include a corresponding data receiving or transmitting unit to receive or transmit the required data. In addition, it may include a corresponding database/storage unit to store the required data. In particular, unless otherwise specifically excluded or contradictory, the processor may be a collection of multiple processors based on a distributed system architecture, used to include/represent the process, mechanism and result of information stream processing between multiple processors. In addition, the "controller" referred to in the present invention may represent an integrated technical feature, which may be a single controller coupled and integrated to control one or more coupled devices, or multiple controllers separately control the coupled devices, etc., so that the corresponding device performs its function under appropriate conditions.

本發明全文所述有關「銲道」者,包含兩工件在銲接前所預定要進行銲接處/路徑、進行銲接時所形成的熔池及熔池冷卻過程中所形成的區域。此外,所述預定要進行銲接處係對應本發明全文所述「待銲的銲道」者;所述進行銲接時所形成的熔池係對應本發明全文所述「經銲接交界處並(暫時)具有對應的熔融狀態」者;及所述熔池冷卻過程中所形成的區域對應本發明全文所述「經銲接交界處」者。此外,本發明全文所述「冷卻過程」者,係指具有熔融狀態之經銲接交界處/銲道變成穩定固化狀態之經銲接交界處/銲道的過程。 The "weld path" mentioned in the full text of the present invention includes the predetermined welding point/path of the two workpieces before welding, the molten pool formed during welding, and the area formed during the cooling process of the molten pool. In addition, the predetermined welding point corresponds to the "weld path to be welded" mentioned in the full text of the present invention; the molten pool formed during welding corresponds to the "weld junction and (temporarily) having a corresponding molten state" mentioned in the full text of the present invention; and the area formed during the cooling process of the molten pool corresponds to the "weld junction" mentioned in the full text of the present invention. In addition, the "cooling process" described in the entire text of the present invention refers to the process of changing the welded interface/weld track in a molten state into a welded interface/weld track in a stable solidified state.

本發明的控制銲接品質之方法,包含:提供一第一工件與一第二工件,使該第一工件與該第二工件要進行銲接的交界處彼此抵接,以界定一待銲的銲道;;該第一工件由一第一材料所製成,該第二工件由一第二材料所製成,該第一材料與該第二材料是一金屬或一合金,且該第一材料與該第二材料的組成元素不同及/或組成元素的比例不同;對所述待銲的銲道形成具有對應熔融狀態的經銲接交界處,在熔融狀態的經銲接交界處具有該第一材料與該第二材料的全部元素或局部元素的熔融成分;在熔融狀態的經銲接交界處在冷卻過程中隨溫度與時間的關係具有至少二種金屬相之變化,且所述至少二種金屬相中之一者會產生金屬間化合物,該至少二種金屬相中的其他者不會產生金屬間化合物,並依對應的一時溫變態圖定義一定期間內的預設溫度控制條件隨時間控制對應的溫度高低,使冷卻過程中經歷會產生金屬 間化合物的金屬相的時間最小化。 The method for controlling welding quality of the present invention comprises: providing a first workpiece and a second workpiece, making the interface between the first workpiece and the second workpiece to be welded abut each other to define a weld path to be welded; the first workpiece is made of a first material, the second workpiece is made of a second material, the first material and the second material are a metal or an alloy, and the first material and the second material have different constituent elements and/or different proportions of constituent elements; forming a weld interface having a corresponding molten state for the weld path to be welded, and forming a weld interface at the molten state; The welded joint has the molten components of all or part of the elements of the first material and the second material; the welded joint in the molten state has at least two metal phases changing with the relationship between temperature and time during the cooling process, and one of the at least two metal phases will produce intermetallic compounds, and the other of the at least two metal phases will not produce intermetallic compounds, and the preset temperature control conditions within a certain period of time are defined according to the corresponding time-temperature deformation diagram to control the corresponding temperature with time, so as to minimize the time of the metal phase that will produce intermetallic compounds during the cooling process.

本發明的銲接平台,配置以實施如本發明之控制銲接品質之方法,該銲接平台,包含:一平台本體,具有一頂面與一底面相對該頂面;一平台冷卻構造,具有至少一進氣通道與多個出氣通道;該進氣通道設置於該平台本體內部,並具有一進氣口以供一氣體通入該進氣通道;該出氣通道與該進氣通道連通,且具有一出氣口朝背離該平台本體的該底面的方向設置;及一平台加熱器,係鄰近該平台本體的該頂面設置。 The welding platform of the present invention is configured to implement the method of controlling welding quality as described in the present invention. The welding platform comprises: a platform body having a top surface and a bottom surface opposite to the top surface; a platform cooling structure having at least one air inlet channel and a plurality of air outlet channels; the air inlet channel is arranged inside the platform body and has an air inlet for a gas to pass into the air inlet channel; the air outlet channel is connected to the air inlet channel and has an air outlet arranged in a direction away from the bottom surface of the platform body; and a platform heater is arranged adjacent to the top surface of the platform body.

本發明的熔融式接合系統,包含:一熔融能量供應器,用以使對應的金屬工件的被照射區域形成熔融狀態;如本發明之銲接平台,該熔融能量供應器與該銲接平台之間係可依預定加工路徑產生相對運動;一冷卻氣體供應器,用以供給一冷卻氣體通入該平台冷卻構造的該進氣通道;一溫度感應器,設置於該平台本體中且鄰近該頂面的位置;及一控制器,分別與該熔融能量供應器、該冷卻氣體供應器、該平台加熱器及該溫度感應器耦接,以用於:控制該熔融能量供應器的功率以對目標區域進行雷射銲接;及接收該溫度感應器所感測之溫度,並根據一目標處理溫度中的溫度與時間關係,調整該冷卻氣體供應器供給至該氣體通道之氣體的流量大小,使目標區域降溫;及/或調整該平台加熱器之輸出功率,使目標區域升溫或維持一定溫度。 The fusion bonding system of the present invention comprises: a fusion energy supplier, used to make the irradiated area of the corresponding metal workpiece form a molten state; such as the welding platform of the present invention, the fusion energy supplier and the welding platform can generate relative movement according to a predetermined processing path; a cooling gas supplier, used to supply a cooling gas to the air inlet channel of the platform cooling structure; a temperature sensor, which is arranged in the platform body and adjacent to the top surface; and a controller, which is respectively connected to the fusion energy supplier and the controller. The supply, the cooling gas supply, the platform heater and the temperature sensor are coupled to: control the power of the melting energy supply to perform laser welding on the target area; and receive the temperature sensed by the temperature sensor, and adjust the flow rate of the gas supplied by the cooling gas supply to the gas channel according to the temperature and time relationship in a target processing temperature to cool the target area; and/or adjust the output power of the platform heater to heat up or maintain a certain temperature in the target area.

據此,本發明的控制銲接品質之方法、銲接平台及熔融式接合系統,透過以對應的預設溫度控制條件進行溫度控制,可達成減少或避免金屬間化合物產生的功效,進而達成提升銲道的穩定性與品質的功效。另,透過該銲接平台具有對應的平台冷卻構造與平台加熱器,可達成便於即時對銲道(經銲接交界處)進行對應溫度控制的功效,特別是以預設溫度控制條件進行溫度控制,而可達成提升銲道的穩定性與品質的功效。另,透過該熔融式接合系統中的該控制器與各裝置間(特別是該溫度感應器、該冷卻氣體供 應器及該平台加熱器)的耦接,可達成即時對銲道進行對應溫度控制的功效,進而達成提升銲道的穩定性與品質的功效。 Accordingly, the method for controlling welding quality, welding platform and fusion bonding system of the present invention can achieve the effect of reducing or avoiding the generation of intermetallic compounds by performing temperature control with corresponding preset temperature control conditions, thereby achieving the effect of improving the stability and quality of the weld. In addition, the welding platform has a corresponding platform cooling structure and platform heater, which can achieve the effect of facilitating the instantaneous corresponding temperature control of the weld (through the weld junction), especially by performing temperature control with preset temperature control conditions, which can achieve the effect of improving the stability and quality of the weld. In addition, by coupling the controller in the fusion bonding system with various devices (especially the temperature sensor, the cooling gas supplier and the platform heater), the corresponding temperature control of the weld can be achieved in real time, thereby achieving the effect of improving the stability and quality of the weld.

其中,所述溫度控制的方法包含透過施加冷卻氣體在經銲接交界處,使經銲接交界處的溫度降低,。如此,透過冷卻氣體的施加,可達成控制銲接品質的功效。 The temperature control method includes applying cooling gas to the welding junction to reduce the temperature of the welding junction. In this way, the effect of controlling the welding quality can be achieved by applying cooling gas.

其中,所述溫度控制的方法包含透過一散熱治具接觸該第一工件與該第二工件,所述散熱治具係具有40W/m‧K以上的導熱係數、散熱鰭片及供冷卻液體流通的液冷通道中的至少一者。如此,透過散熱治具對應的技術特徵,可達成強化工件散熱效率的功效,進而達成可更快速冷卻銲道的功效。 The temperature control method includes contacting the first workpiece and the second workpiece through a heat dissipation fixture, and the heat dissipation fixture has at least one of a thermal conductivity of more than 40W/m‧K, a heat dissipation fin, and a liquid cooling channel for circulating cooling liquid. In this way, through the corresponding technical features of the heat dissipation fixture, the effect of enhancing the heat dissipation efficiency of the workpiece can be achieved, thereby achieving the effect of faster cooling of the weld.

其中,所述溫度控制的方法包含對經銲接交界處提供熱能,使經銲接交界處的溫度升高或維持在特定溫度。如此,透過對銲道提供熱能,可達成控制銲接品質的功效。 The temperature control method includes providing heat energy to the welded junction to increase or maintain the temperature of the welded junction at a specific temperature. In this way, by providing heat energy to the weld, the effect of controlling the welding quality can be achieved.

其中,所述一定期間內是1小時至100小時。如此,透過所述一定期間的溫度控制,可使銲道中的成分形成穩定的結構型態,而可達成提升銲道的穩定性與品質的功效。 The period of time is 1 hour to 100 hours. Thus, by controlling the temperature during the period of time, the components in the weld can form a stable structure, thereby improving the stability and quality of the weld.

其中,該第一材料包含鋁,該第二材料包含銅,所述一定期間內是1至100小時;在該待銲接處形成經銲接交界處的熔融狀態後,在1至36秒內使經銲接交界處的溫度降至200℃以下;再對經銲接交界處提供熱能,使經銲接交界處的溫度維持在140至200℃的狀態持續至所述一定期間結束。如此,透過所述降溫條件,可減少或避免鋁銅間的金屬間化合物的產生;且透過所述溫度維持的條件,可使鋁銅間的銲道形成較穩定的結構型態,進而可達成提升銲道的穩定性與品質的功效。 The first material includes aluminum, the second material includes copper, and the certain period of time is 1 to 100 hours; after the welded junction is molten, the temperature of the welded junction is reduced to below 200°C within 1 to 36 seconds; and then heat energy is provided to the welded junction to maintain the temperature of the welded junction at 140 to 200°C until the end of the certain period of time. In this way, the generation of intermetallic compounds between aluminum and copper can be reduced or avoided through the cooling conditions; and the temperature maintenance conditions can form a more stable structural form of the weld between aluminum and copper, thereby achieving the effect of improving the stability and quality of the weld.

其中,該頂面具有一凹陷部自該頂面凹陷,且該凹陷部係沿一 方向延伸,以形成一長條狀的凹陷空間;該凹陷部具有一凹陷表面位於該頂面與該底面之間;該進氣通道位於該凹陷部的下方且沿該凹陷部延伸;該出氣口形成於該凹陷表面;該平台加熱器係設置於對應該凹陷部的位置。如此,透過該凹陷部的設置,可當熔融狀態之銲道具有朝該平台本體之該頂面方向局部凸出的部分時,提供一適當的容置空間,以避免銲道與銲接平台因高熱產生結合的狀態,可達成保護銲道形成及避免銲接平台毀損的功效;另,透過該凹陷部的構造,有助於冷卻氣體在對應的凹陷空間中流動,可達成更快速的散熱與降溫的功效;另,透過該平台加熱器係設置該凹陷部的配置,有助於該平台加熱器係對位於要維持溫度的銲道的下方,可達成更有效率地維持銲道溫度的功效;另,透過該凹陷部的構造,亦有助於熱對流在凹陷部形成,使銲道可較均勻受熱,而可達成提升銲道的穩定性與品質的功效。 The top surface has a concave portion which is concave from the top surface, and the concave portion extends in a direction to form a long strip-shaped concave space; the concave portion has a concave surface located between the top surface and the bottom surface; the air inlet channel is located below the concave portion and extends along the concave portion; the air outlet is formed on the concave surface; and the platform heater is arranged at a position corresponding to the concave portion. Thus, by providing the recessed portion, when the weld in the molten state has a portion partially protruding toward the top surface of the platform body, a suitable accommodation space can be provided to prevent the weld and the welding platform from being combined due to high heat, thereby protecting the weld and preventing the welding platform from being damaged. In addition, the structure of the recessed portion helps the cooling gas to flow in the corresponding recessed space, thereby achieving The effect of faster heat dissipation and cooling is achieved. In addition, the configuration of the recessed portion of the platform heater can help the platform heater to be located below the weld to be maintained at a temperature, so that the weld temperature can be maintained more efficiently. In addition, the structure of the recessed portion can also help heat convection to form in the recessed portion, so that the weld can be heated more evenly, thereby achieving the effect of improving the stability and quality of the weld.

其中,該平台加熱器具有一凸出部突出於該凹陷部的該凹陷表面,且未超出該平台本體之該頂面所界定的一平面。如此,透過該凸出部的配置,有助於該平台加熱器更靠近該銲道且不與該銲道干涉,可達成更有效率地維持銲道溫度的功效。 The platform heater has a protrusion that protrudes from the concave surface of the concave portion and does not exceed a plane defined by the top surface of the platform body. Thus, the configuration of the protrusion helps the platform heater to be closer to the weld and not interfere with the weld, so as to achieve the effect of maintaining the weld temperature more efficiently.

1:熔融能量供應器 1: Melting energy supplier

1G:保護氣體供應器 1G: Protective gas supply

1N:氣嘴 1N: Air nozzle

2:銲接平台 2: Welding platform

20:平台本體 20: Platform body

20a:頂面 20a: Top surface

20b:底面 20b: Bottom surface

20c:凹陷部 20c: Depression

20d:凹陷表面 20d: Concave surface

3:平台冷卻構造 3: Platform cooling structure

3G:冷卻氣體供應器 3G: Cooling gas supply

30:進氣通道 30: Air intake duct

30I:進氣口 30I: Air intake

31:出氣通道 31: Exhaust channel

31E:出氣口 31E: Air outlet

4:平台加熱器 4: Platform heater

4P:凸出部 4P: protrusion

5:溫度感應器 5: Temperature sensor

6:散熱治具 6: Heat dissipation fixture

61:鰭片 61: Fins

62:液冷通道 62: Liquid cooling channel

AS2:可選步驟 AS2: Optional step

C:控制器 C: Controller

Ln:自然冷卻之溫度變化線段 Ln: Temperature change line segment of natural cooling

Lp:預設溫度控制條件的一範例線段 Lp: An example line segment of the default temperature control condition

PIC:金屬間化合物生成相 PIC : Intermetallic Compound Formation Phase

PSS:過飽和相 PSS : Supersaturation phase

PS:穩定相 P S : Stable phase

S1,S2,S3:步驟 S1, S2, S3: Steps

W1:第一工件 W1: First workpiece

W2:第二工件 W2: Second workpiece

〔第1圖〕本發明之熔融式接合系統的一較佳實施例的局部立體圖。 [Figure 1] A partial perspective view of a preferred embodiment of the fusion bonding system of the present invention.

〔第2圖〕如第1圖所示的使用情形之局部正視圖。 [Figure 2] A partial front view of the usage as shown in Figure 1.

〔第3圖〕沿第2圖的A-A線剖面圖。 [Figure 3] Sectional view along line A-A of Figure 2.

〔第4圖〕本發明之控制銲接品質之方法的一較佳流程圖。 [Figure 4] A better flow chart of the method for controlling welding quality of the present invention.

〔第5圖〕本發明之散熱治具的一較佳實施例的側視圖。 [Figure 5] A side view of a preferred embodiment of the heat dissipation fixture of the present invention.

〔第6圖〕鋁銅金屬的時溫變態圖。 [Figure 6] Temperature transformation diagram of aluminum and copper metals.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式作詳細說明;此外,在不同圖式中標示相同符號者視為相同,會省略其說明。 In order to make the above and other purposes, features and advantages of the present invention more clearly understood, the following specifically cites the preferred embodiments of the present invention and provides a detailed description in conjunction with the attached drawings; in addition, the same symbols in different drawings are considered the same and their descriptions will be omitted.

請參照第1、2圖所示,其係本發明的熔融式接合系統的一較佳實施例,係包含一熔融能量供應器1、一銲接平台2及一控制器C。該控制器C分別與該熔融能量供應器1及該銲接平台2耦接;該熔融能量供應器1與該銲接平台2之間係可依預定加工路徑產生相對運動,且所述用於產生相關運動的組件或機構係為本領域中具有通常知識者可理解,其詳細構造與原理於本發明中不再贅述。 Please refer to Figures 1 and 2, which are a preferred embodiment of the fusion bonding system of the present invention, including a fusion energy supplier 1, a welding platform 2 and a controller C. The controller C is coupled to the fusion energy supplier 1 and the welding platform 2 respectively; the fusion energy supplier 1 and the welding platform 2 can generate relative motion according to a predetermined processing path, and the components or mechanisms used to generate the relevant motion are understandable to those with common knowledge in the field, and the detailed structure and principle are not repeated in the present invention.

為便利顯示本發明的一較佳實施例,該熔融能量供應器1在本發明的圖式中係以雷射光束供應器的態樣呈現,惟,應注意的是,該熔融能量供應器1係用於供給熔融能量以對兩金屬工件的交界處進行熔融式接合,特別是透過所供給的熔融能量使對應金屬工件的被照射區域形成熔融金屬,使兩金屬工件透過對應的熔融金屬區域接合;因此,所述熔融能量供應器1並不僅限於雷射光束供應器。特別是,所述熔融式接合的方法可例如是弧銲、雷射銲接、電子銲接或電阻銲等方式,所述熔融能量則可對應地為電弧、雷射光束、電子束、熱能,所述的熔融能量供應器1則可對應地為電弧能量供應器、雷射光束供應器、電子束供應器、熱能供應器。此外,上述運用熔融能量進行熔融式接合之技術,係為本領域中具有通常知識者可理解,因此,該熔融能量供應器1的詳細構造與原理於本發明中不再贅述。 In order to conveniently display a preferred embodiment of the present invention, the melting energy supplier 1 is presented in the form of a laser beam supplier in the drawings of the present invention. However, it should be noted that the melting energy supplier 1 is used to supply melting energy to melt-join the interface of two metal workpieces, especially to form molten metal in the irradiated area of the corresponding metal workpiece through the supplied melting energy, so that the two metal workpieces are joined through the corresponding molten metal area; therefore, the melting energy supplier 1 is not limited to a laser beam supplier. In particular, the method of the fusion type joining may be, for example, arc welding, laser welding, electron welding or resistance welding, and the fusion energy may be correspondingly an arc, a laser beam, an electron beam, or thermal energy, and the fusion energy supplier 1 may be correspondingly an arc energy supplier, a laser beam supplier, an electron beam supplier, or a thermal energy supplier. In addition, the above-mentioned technology of using fusion energy for fusion type joining is understandable to those with ordinary knowledge in the field, and therefore, the detailed structure and principle of the fusion energy supplier 1 will not be described in detail in the present invention.

較佳地,該熔融能量供應器1具有一保護氣體噴出裝置,該保護氣體噴出裝置具有一保護氣體供應器1G與一氣嘴1N,用於在該熔融能量 供應器1發射熔融能量對一目標物體的目標區域進行熔融式接合時,由該保護氣體供應器1G供給保護氣體至該氣嘴1N,以由該氣嘴1N同步噴出保護氣體於銲接處,藉以避免該目標區域進行熔融式接合位置產生氧化物的情形。其中,所述保護氣體噴出裝置(保護氣體供應裝置1G與該氣嘴1N)亦為本領域中具有通常知識者可理解,其詳細構造與原理於本發明中不再贅述。所述保護氣體的成分可例如氬氣、氦氣、或氬氦混和氣體,可於銲接過程中,保護銲道避免形成氧化物,並提供冷卻過程中氣冷之作用。 Preferably, the melting energy supplier 1 has a protective gas ejection device, which has a protective gas supplier 1G and a gas nozzle 1N, and is used for supplying protective gas to the gas nozzle 1N from the protective gas supplier 1G when the melting energy supplier 1 emits melting energy to perform melting type joining on a target area of a target object, so that the gas nozzle 1N synchronously ejects protective gas at the welding position, so as to avoid the situation where oxides are generated at the melting type joining position of the target area. Among them, the protective gas ejection device (protective gas supply device 1G and the gas nozzle 1N) is also understandable to those with ordinary knowledge in the field, and its detailed structure and principle are not repeated in the present invention. The protective gas may be composed of argon, helium, or a mixture of argon and helium, which can protect the weld from oxide formation during the welding process and provide air cooling during the cooling process.

該銲接平台2包含一平台本體20、一平台冷卻構造3及一平台加熱器4,並較佳地可另包含至少一溫度感測器5。該平台本體20具有一頂面20a與一底面20b相對該頂面20a,該頂面20a係面向該熔融能量供應器1。較佳地,該頂面20a具有一凹陷部20c自該頂面20a凹陷,用以界定一凹陷空間;特別地,該凹陷部20c可沿一方向延伸,以形成一長條狀的凹陷空間。更佳地,該凹陷部20c具有一凹陷表面20d,該凹陷表面20d位於該頂面20a與該底面20b之間。較佳地,所述平台本體20係選自高導熱材料,較佳具有導熱係數40W/m‧K以上,例如可以是由銅或銅合金的材料所製成。 The welding platform 2 includes a platform body 20, a platform cooling structure 3 and a platform heater 4, and preferably further includes at least one temperature sensor 5. The platform body 20 has a top surface 20a and a bottom surface 20b opposite to the top surface 20a, and the top surface 20a faces the melting energy supplier 1. Preferably, the top surface 20a has a recessed portion 20c recessed from the top surface 20a to define a recessed space; in particular, the recessed portion 20c can extend in a direction to form a long strip of recessed space. More preferably, the recessed portion 20c has a recessed surface 20d, and the recessed surface 20d is located between the top surface 20a and the bottom surface 20b. Preferably, the platform body 20 is selected from a high thermal conductivity material, preferably having a thermal conductivity of 40W/m·K or more, for example, it can be made of copper or copper alloy.

除請參照1、2圖外,另請參照第3圖所示,該平台冷卻構造3係設置於該平台本體20,具有至少一進氣通道30與多個出氣通道31。該進氣通道30係設置於該平台本體20內部,並具有一進氣口30I以供一氣體通入該進氣通道30;較佳地,該進氣通道30位於該凹陷部20c的下方且沿該凹陷部20c延伸,特別是可位於該凹陷部20與該平台本體20的該底面20b之間。該出氣通道31與該進氣通道30連通,且具有一出氣口31E朝背離該平台本體20的該底面20b的方向設置;藉此,當一氣體自該進氣口30I通入該進氣通道30時,該氣體將由該出氣通道31的出氣口31E排出,特別是朝向背離該底面20b的方向噴出。較佳地,該出氣口31E係設置於該凹陷部20c, 更佳是形成於該凹陷表面20d。 In addition to referring to FIGS. 1 and 2, please also refer to FIG. 3, where the platform cooling structure 3 is disposed on the platform body 20, and has at least one air inlet channel 30 and a plurality of air outlet channels 31. The air inlet channel 30 is disposed inside the platform body 20, and has an air inlet 30I for allowing a gas to enter the air inlet channel 30; preferably, the air inlet channel 30 is located below the recessed portion 20c and extends along the recessed portion 20c, and in particular, can be located between the recessed portion 20 and the bottom surface 20b of the platform body 20. The outlet channel 31 is connected to the inlet channel 30 and has an outlet 31E disposed in a direction away from the bottom surface 20b of the platform body 20; thereby, when a gas enters the inlet channel 30 from the inlet 30I, the gas will be discharged from the outlet 31E of the outlet channel 31, especially in a direction away from the bottom surface 20b. Preferably, the outlet 31E is disposed in the recessed portion 20c, and more preferably formed in the recessed surface 20d.

較佳地,該出氣通道31係自與該進氣通道30連接處朝該出氣口31E形成漸縮的通道;特別是該出氣通道31與該進氣通道30連接且連通的一連接端31a具有較大的通道面積,該出氣口31E具有較小的通道面積,使該出氣通道31形成所述漸縮的通道。如此透過上述漸縮通道的配置,有助於使自該出氣口31E噴出的氣流具有較高的流速,進而可透過所述高流速氣體噴在要散熱的目標區域上(如第2圖的第一工件W1與第二工件W2)時,可提升對應的散熱速度/效率。 Preferably, the outlet channel 31 forms a gradual channel from the connection with the inlet channel 30 toward the outlet port 31E; in particular, the connecting end 31a of the outlet channel 31 connected to and communicated with the inlet channel 30 has a larger channel area, and the outlet port 31E has a smaller channel area, so that the outlet channel 31 forms the gradual channel. The configuration of the gradual channel helps to make the airflow ejected from the outlet port 31E have a higher flow rate, and then when the high-flow gas is sprayed on the target area to be cooled (such as the first workpiece W1 and the second workpiece W2 in Figure 2), the corresponding heat dissipation speed/efficiency can be improved.

另,本發明之熔融式接合系統另具有一冷卻氣體供應器3G,用於供給該平台冷卻構造3對應的冷卻氣體。詳言之,該冷卻氣體供應裝置3G係可具有對應的閥門與連通管道;所述連通管道係連接於該冷卻氣體供應裝置3G與該進氣通道30間,所述閥門係可控制冷卻氣體流量的大小。如此,該冷卻氣體供應器3G可供給冷卻氣體通入該平台冷卻構造3的該進氣通道30,進而使該多個出氣口31E噴出冷卻氣體。所述冷卻氣體的成分可例如是包含所述保護氣體或大氣,且以係為常溫的氣體,特別是不大於100℃,以通入該銲接平台2進行降溫;較佳地,所述冷卻氣體的溫度可以是不大於25℃。 In addition, the fusion bonding system of the present invention also has a cooling gas supply device 3G, which is used to supply the corresponding cooling gas to the platform cooling structure 3. In detail, the cooling gas supply device 3G can have a corresponding valve and a communication pipe; the communication pipe is connected between the cooling gas supply device 3G and the air inlet channel 30, and the valve can control the size of the cooling gas flow. In this way, the cooling gas supply device 3G can supply cooling gas to the air inlet channel 30 of the platform cooling structure 3, and then the multiple air outlets 31E spray cooling gas. The composition of the cooling gas may include the protective gas or atmosphere, and the gas may be at room temperature, especially not higher than 100°C, and may be passed into the welding platform 2 for cooling; preferably, the temperature of the cooling gas may be not higher than 25°C.

請參照第1、2圖所示,該平台加熱器4係一電阻式加熱器(如第3圖所示)、感應線圈式加熱器(未顯示)或其他加熱器;應注意的是,所述加熱器的實現方式係本領域中具有通常知識者可理解,本發明並不以所舉例者為限。該平台加熱器4係設置於該平台本體20;特別是全部或部分地設置於該平台本體20中,且鄰近該頂面20a設置;以形成一熱源使目標區域(如第4圖的第一工件W1與第二工件W2)鄰近該頂面20a的部分的溫度能被升高。較佳地,該平台加熱器4係設置於對應該凹陷部20c的位置,以加 熱目標區域鄰近該凹陷部20c的部分。更佳地,該平台加熱器4可具有一凸出部4P突出於該凹陷部20c的該凹陷表面20d,且未超出該平台本體20之該頂面20a所界定的一平面;如此,透過該平台加熱器4的該凸出部4P可更靠近所要加熱的目標區域,以提升對應的加熱效率。 Please refer to FIGS. 1 and 2. The platform heater 4 is a resistive heater (as shown in FIG. 3), an induction coil heater (not shown) or other heaters. It should be noted that the implementation of the heater is understandable to those with ordinary knowledge in the field, and the present invention is not limited to the examples. The platform heater 4 is disposed in the platform body 20; in particular, it is disposed in whole or in part in the platform body 20 and disposed adjacent to the top surface 20a to form a heat source so that the temperature of the target area (such as the first workpiece W1 and the second workpiece W2 in FIG. 4) adjacent to the top surface 20a can be increased. Preferably, the platform heater 4 is disposed at a position corresponding to the recessed portion 20c to heat the portion of the target area adjacent to the recessed portion 20c. More preferably, the platform heater 4 may have a protrusion 4P protruding from the concave surface 20d of the concave portion 20c and not exceeding a plane defined by the top surface 20a of the platform body 20; thus, the protrusion 4P of the platform heater 4 can be closer to the target area to be heated, so as to improve the corresponding heating efficiency.

請參照第1圖所示,該溫度感應器5係可用於感測其鄰近處的溫度,且為了更精確獲取對應觀察物件在特定位置上(例如是沿著經銲接的銲道)的溫度分佈,較佳可沿著要觀察位置(經銲接的銲道)均勻配置多個該溫度感測器5,以監控整個觀察區域(經銲接的區域,特別是銲道)的溫度分佈,其相關實現方式及具體裝置為本發明技術領域中具有通常知識者可理解,故不再贅述;可選地,為使本發明之銲接平台2可以更緊密的裝配,所述溫度感測器5可以是片狀、扁平形或貼片式感測器。詳言之,該溫度感應器5係設置於該平台本體20中且鄰近該頂面20a的位置,以用於感測鄰近之目標區域的溫度,特別是用於感測所述目標區域經上述平台冷卻構造3或平台加熱器4作用後的溫度。較佳地,該溫度感應器5設置於鄰近該凹陷部20c;或可選地設置於該凹陷部20c中(未顯示)。 Please refer to FIG. 1 , the temperature sensor 5 can be used to sense the temperature of its vicinity, and in order to more accurately obtain the temperature distribution of the corresponding observation object at a specific position (for example, along the welded weld), it is better to evenly configure a plurality of the temperature sensors 5 along the position to be observed (the welded weld) to monitor the temperature distribution of the entire observation area (the welded area, especially the weld). The relevant implementation method and specific device are understandable to those with ordinary knowledge in the technical field of the present invention, so they are not repeated here; optionally, in order to enable the welding platform 2 of the present invention to be assembled more tightly, the temperature sensor 5 can be a sheet, flat or patch sensor. In detail, the temperature sensor 5 is disposed in the platform body 20 and adjacent to the top surface 20a, so as to sense the temperature of the adjacent target area, especially the temperature of the target area after being acted upon by the platform cooling structure 3 or the platform heater 4. Preferably, the temperature sensor 5 is disposed adjacent to the recess 20c; or optionally disposed in the recess 20c (not shown).

該控制器C係可分別與該冷卻氣體供應器3G、該平台加熱器4及該溫度感應器5耦接,以接收該溫度感應器5所感測之溫度,並根據一目標處理溫度中的溫度與時間關係,調整該冷卻氣體供應器3G供給至該氣體通道30之氣體的流量大小,使目標區域降溫;或調整該平台加熱器4之輸出功率,使目標區域升溫或維持一定溫度。特別是,該控制器C另可與該熔融能量供應器1、對應的保護氣體供應器1G耦接,以控制該熔融能量供應器1的功率對目標區域進行熔融式接合,並控制保護氣體供應器1G以控制由該氣嘴1N噴出之保護氣體的流量。 The controller C can be coupled to the cooling gas supplier 3G, the platform heater 4 and the temperature sensor 5 respectively to receive the temperature sensed by the temperature sensor 5, and adjust the flow rate of the gas supplied by the cooling gas supplier 3G to the gas channel 30 according to the temperature and time relationship in a target processing temperature to cool the target area; or adjust the output power of the platform heater 4 to heat up the target area or maintain a certain temperature. In particular, the controller C can also be coupled to the melting energy supplier 1 and the corresponding protective gas supplier 1G to control the power of the melting energy supplier 1 to perform melting type joining on the target area, and control the protective gas supplier 1G to control the flow rate of the protective gas sprayed by the gas nozzle 1N.

請參見第2、4圖,據由上述配置,本發明之熔融式接合系統 的使用情形與對應加工方法可說明如下。 Please refer to Figures 2 and 4. Based on the above configuration, the usage and corresponding processing method of the fusion bonding system of the present invention can be described as follows.

步驟S1:提供一第一工件W1與一第二工件W2,使該第一工件W1與該第二工件W2要進行銲接的交界處彼此抵接,以界定一待銲的銲道/待銲路徑。其中,該第一工件W1由一第一材料所製成,該第二工件W2由一第二材料所製成,較佳是該第一工件W1與該第二工件W2係分別由該第一材料與該第二材料所組成。該第一材料與該第二材料是一金屬或一合金,且該第一材料與該第二材料的組成元素不同(兩種異質金屬的態樣)及/或組成元素的比例不同(一種金屬與一種合金的態樣,或兩種合金的態樣),使該第一工件W1與該第二工件W2的在交界處所形成的熔融狀態具有至少二種金屬元素的一第三材料,且該第三材料中的組成元素的成分、比例與該第一材料及該第二材料不同。 Step S1: Provide a first workpiece W1 and a second workpiece W2, so that the junction of the first workpiece W1 and the second workpiece W2 to be welded is abutted against each other to define a weld path to be welded. The first workpiece W1 is made of a first material, and the second workpiece W2 is made of a second material. Preferably, the first workpiece W1 and the second workpiece W2 are respectively composed of the first material and the second material. The first material and the second material are a metal or an alloy, and the first material and the second material have different constituent elements (in the form of two heterogeneous metals) and/or different proportions of constituent elements (in the form of a metal and an alloy, or in the form of two alloys), so that the molten state formed at the junction of the first workpiece W1 and the second workpiece W2 has a third material of at least two metal elements, and the composition and proportion of the constituent elements in the third material are different from those of the first material and the second material.

詳言之,該第一工件W1與該第二工件W2係被固定於該銲接平台2的頂面20a,特別是使所述待銲的銲道對位於該凹陷部20C的上方。此時,該熔融能量供應器1與可選的氣嘴1N,較佳皆是經由該控制器C的控制,係可對位於所述待銲的銲道的一處。 In detail, the first workpiece W1 and the second workpiece W2 are fixed to the top surface 20a of the welding platform 2, especially so that the weld to be welded is aligned above the recessed portion 20C. At this time, the melting energy supplier 1 and the optional air nozzle 1N are preferably controlled by the controller C to be aligned to a part of the weld to be welded.

所述固定該第一工件W1與該第二工件W2的固定方式係使用對應的散熱治具6,以避免該第一工件W1與該第二工件W2因銲接時所產生的熱應力或材料變形而產生偏位。可選地,所述散熱治具6係至少配置於該第一工件W1與該第二工件W2的一側,使該第一工件W1與該第二工件W2固定於該平台本體20與該散熱治具6之間;惟所述散熱治具6固定工件的方式並不以上述為限。 The fixing method of the first workpiece W1 and the second workpiece W2 is to use a corresponding heat dissipation fixture 6 to prevent the first workpiece W1 and the second workpiece W2 from being offset due to thermal stress or material deformation generated during welding. Optionally, the heat dissipation fixture 6 is at least arranged on one side of the first workpiece W1 and the second workpiece W2, so that the first workpiece W1 and the second workpiece W2 are fixed between the platform body 20 and the heat dissipation fixture 6; however, the method of fixing the workpiece by the heat dissipation fixture 6 is not limited to the above.

較佳地,如第5圖所示,所述散熱治具6具有多個鰭片61,以提升該散熱治具6的散熱效率。較佳地,所述散熱治具6具有一液冷通道62,以供對應的冷卻液體通入,以提升該散熱治具6的散熱效率。對應該液 冷通道62,可另具有一冷卻液供應器及對應管路(未顯示),以提供冷卻液通過該液冷通道62。可選地,所述冷卻液供應器亦與該控制器C耦接,以由該控制器C控制所述冷卻液供應器中的冷卻液的輸出。較佳地,所述散熱治具6係選自高導熱材料,較佳具有導熱係數40W/m‧K以上,例如可以是由銅或銅合金的材料所製成。 Preferably, as shown in FIG. 5 , the heat sink fixture 6 has a plurality of fins 61 to improve the heat dissipation efficiency of the heat sink fixture 6. Preferably, the heat sink fixture 6 has a liquid cooling channel 62 for the corresponding cooling liquid to pass through to improve the heat dissipation efficiency of the heat sink fixture 6. Corresponding to the liquid cooling channel 62, there may be a cooling liquid supplier and a corresponding pipeline (not shown) to provide cooling liquid to pass through the liquid cooling channel 62. Optionally, the cooling liquid supplier is also coupled to the controller C so that the controller C controls the output of the cooling liquid in the cooling liquid supplier. Preferably, the heat sink fixture 6 is selected from a high thermal conductivity material, preferably having a thermal conductivity of 40W/m‧K or more, for example, it may be made of copper or copper alloy.

步驟S2:使所述待銲的銲道形成暫時具有對應熔融狀態的經銲接交界處。詳言之,對所述待銲的銲道施加熔融能量,使經熔融能量施加的位置形成暫時具有對應熔融狀態的經銲接交界處。所述的熔融狀態亦可稱為熔池(Welding Pool/Molten Pool)。在熔融狀態的經銲接交界處具有該第一材料與該第二材料的全部元素或局部元素的熔融成分。在一實例中,該熔融狀態係對應一完全熔融溫度,所述完全熔融溫度係高於至少二種金屬元素的熔點;此時,該第一材料與該第二材料的全部元素皆為熔融狀態,並在熔融狀態中形成鍵結。在另一實例中,該熔融狀態係對應一局部熔融溫度,所述局部熔融溫度係介於二種金屬元素的熔點之間;此時,具有熔點低於該局部熔融溫度的一金屬元素形成熔融狀態,並透過金屬高溫下的擴散特性擴散至另一金屬(熔點高於該局部熔融溫度)形成鍵結。 Step S2: The weld track to be welded is formed into a welded junction temporarily having a corresponding molten state. In detail, melting energy is applied to the weld track to be welded, so that the position where the melting energy is applied forms a welded junction temporarily having a corresponding molten state. The molten state can also be called a molten pool (Welding Pool/Molten Pool). The welded junction in the molten state has molten components of all or part of the elements of the first material and the second material. In one example, the molten state corresponds to a complete melting temperature, and the complete melting temperature is higher than the melting points of at least two metal elements; at this time, all elements of the first material and the second material are in a molten state, and a bond is formed in the molten state. In another example, the molten state corresponds to a local melting temperature, which is between the melting points of two metal elements; at this time, a metal element with a melting point lower than the local melting temperature forms a molten state and diffuses to another metal (melting point higher than the local melting temperature) through the diffusion characteristics of the metal at high temperature to form a bond.

詳言之,本發明所特別關注的部分在於,在熔融狀態的經銲接交界處/熔融狀態之銲道(包含該熔池之成分及/或或鄰近該熔池附近(具有上述金屬高溫下的擴散特性))在冷卻過程中隨溫度與時間的關係具有至少二種金屬相(Metallic Phase)之變化,且所述至少二種金屬相中之一者會產生金屬間化合物,該至少二種金屬相中的其他者不會產生金屬間化合物,並依對應的一時溫變態圖(如第6圖所示)定義一定期間內的預設溫度控制條件隨時間控制對應的溫度高低,使冷卻過程中經歷會產生金屬間化合物的金屬相的時間最小化,以減少或避免所述熔融狀態之銲道在冷卻過程中產生金 屬間化合物。詳言之,所述隨溫度與時間的關係具有至少二種金屬相的現象,係與對應熔融成分中含有至少二種金屬元素間的比例有關,且隨處理溫度與時間的變化,在不同的金屬相中,不同元素間在結構與成分上具有對應的變化。較佳地,本發明可應用於鋁銅金屬間、鋁鐵金屬間等各種異質金屬間的銲接。應注意的是,不同的金屬成分間(包含不同成分比例)所對應的預設溫度控制條件亦不相同。 Specifically, the present invention is particularly concerned with the fact that the welded interface/weld channel in a molten state (including the composition of the molten pool and/or the vicinity of the molten pool (having the above-mentioned diffusion characteristics of the metal at high temperature)) has at least two metal phases (Metallic Phase), and one of the at least two metal phases will produce intermetallic compounds, and the other of the at least two metal phases will not produce intermetallic compounds, and the preset temperature control conditions within a certain period of time are defined according to the corresponding time-temperature deformation diagram (as shown in Figure 6) to control the corresponding temperature level with time, so as to minimize the time of the metal phase that will produce intermetallic compounds during the cooling process, so as to reduce or avoid the generation of intermetallic compounds in the molten state during the cooling process. In detail, the phenomenon of having at least two metal phases with the relationship between temperature and time is related to the ratio of at least two metal elements contained in the corresponding molten components, and with the change of processing temperature and time, in different metal phases, different elements have corresponding changes in structure and composition. Preferably, the present invention can be applied to welding between various heterogeneous metals such as aluminum-copper metals and aluminum-iron metals. It should be noted that the preset temperature control conditions corresponding to different metal components (including different component ratios) are also different.

如第6圖所示,其係以該第一工件W1的該第一材料是鋁金屬(合金編號為1xxx鋁合金),該第二工件W2的該第二材料是銅金屬(合金編號為C1100銅合金)為例,並顯示對應的時溫變態圖(TTT Diagram,Time-Temperature-Transformation Diagram)/恆溫變態圖(IT Diagram,Isothermal Transformation Diagram)。第6圖顯示,含有鋁銅兩種異質金屬在熔融狀態中(特別是靠近鋁金屬側),隨溫度與時間的關係具有三種金屬相變化,分別是過飽合相(Supersaturated Phase)PSS、穩定相(Stable Phase)PS及金屬間化合物生成相PIC。所述金屬間化合物生成相PIC是伴隨金屬間化合物鋁二銅(CuAl2)析出的飽和相,亦即所述金屬間化合物生成相PIC是會產生金屬間化合物的金屬相。因此,若要減少或避免金屬間化合物的產生,需在後續一定期間(Time Period)內,隨時間進行對應的溫度控制,以減少或避開經銲接交界處的金屬相符合所述金屬間化合物生成相PIC所對應的條件。 As shown in FIG. 6, the first material of the first workpiece W1 is aluminum metal (alloy number 1xxx aluminum alloy), and the second material of the second workpiece W2 is copper metal (alloy number C1100 copper alloy), and the corresponding time-temperature transformation diagram (TTT Diagram)/isothermal transformation diagram (IT Diagram) are shown. FIG. 6 shows that the two heterogeneous metals containing aluminum and copper have three metal phase changes in the molten state (especially near the aluminum metal side) with the relationship between temperature and time, namely, supersaturated phase (Supersaturated Phase) P SS , stable phase (Stable Phase) P S and intermetallic compound formation phase P IC . The intermetallic compound phase P IC is a saturated phase that precipitates with the intermetallic compound copper (CuAl2), that is, the intermetallic compound phase P IC is a metal phase that will produce intermetallic compounds. Therefore, if the generation of intermetallic compounds is to be reduced or avoided, the corresponding temperature control must be performed over time during a subsequent period of time to reduce or avoid the metal phase at the welding interface meeting the conditions corresponding to the intermetallic compound phase P IC .

續如第6圖所示,線段Ln顯示一標準狀態下(大致上是室溫25℃,一大氣壓下),使對應熔池自然冷卻的溫度變化的一範例;線段Lp則顯示所述預設溫度控制條件的一範例。由該線段Ln與該線段Lp可見,在自然冷卻過程中(即該線段Ln),該線段Ln中經歷所述金屬間化合物生成相PIC的時間較長,而會產生較多的金屬間化合物(鋁二銅)。然而,由於所述鋁二銅之金屬間化合物具有高脆性,將導致經銲接交界處容易斷裂的情形, 係為本發明中所要避免的情形。在透過所述預設溫度控制條件的溫度控制過程中(即該線段Lp),先透過高速冷卻以避免會產生金屬間化合物析出的金屬相,再於一定期間內維持一定溫度,使經銲接交界處具有較佳的金屬相(即完全避開會產生金屬間化合物析出的金屬相,使冷卻過程中經歷會產生金屬間化合物的金屬相的時間最小化(此範例中對應的經歷時間為0))。 As shown in Figure 6, line segment Ln shows an example of the temperature change corresponding to the natural cooling of the molten pool under a standard state (roughly room temperature 25°C, atmospheric pressure); line segment Lp shows an example of the preset temperature control condition. It can be seen from the line segment Ln and the line segment Lp that during the natural cooling process (i.e., the line segment Ln), the line segment Ln undergoes a longer time for the intermetallic compound formation phase PIC , and more intermetallic compounds (aluminum-copper) will be produced. However, since the aluminum-copper intermetallic compound has high brittleness, it will lead to easy fracture at the welding junction, which is a situation to be avoided in the present invention. In the temperature control process through the preset temperature control condition (i.e., the line segment Lp), high-speed cooling is first performed to avoid the metal phase that will produce the precipitation of intermetallic compounds, and then a certain temperature is maintained for a certain period of time so that the welded interface has a better metal phase (i.e., the metal phase that will produce the precipitation of intermetallic compounds is completely avoided, and the time of experiencing the metal phase that will produce intermetallic compounds during the cooling process is minimized (the corresponding time in this example is 0)).

可選步驟AS2:在使所述待銲的銲道形成暫時具有對應熔融狀態的經銲接交界處時,施加一具有保護作用的氣體。詳言之,在對所述待銲的銲道施加熔融能量的同時,可對該待銲的銲道被施加熔融能量處施加一具有保護作用的氣體,以避免對應的熔融態金屬在固化過程中形成非預期的氧化物。上述施加氣體的方法,可透過控制該噴嘴1N噴出對應的保護氣體於工件W1、W2的上側(工件面向該熔融能量供應器1之側)實現,或可透過該出氣口31E噴出對應的冷卻氣體與工件W1、W2的下側(工件面向該頂面20a之側)實現,或可同時透過該噴嘴1N與該出氣口31E噴出對應的氣體實現。較佳地,可另外於該頂面20a側設置額外的固定式噴嘴(未顯示),持續施加對應氣體於該工件W1、W2之上側的經銲接交界處,以減少或避免氧化物產生,且具有冷卻之功效。 Optional step AS2: applying a protective gas when the weld track to be welded forms a corresponding molten state at the welded junction. In detail, while applying melting energy to the weld track to be welded, a protective gas can be applied to the weld track to be welded where the melting energy is applied to prevent the corresponding molten metal from forming unexpected oxides during the solidification process. The above-mentioned method of applying gas can be realized by controlling the nozzle 1N to spray the corresponding protective gas on the upper side of the workpieces W1 and W2 (the side of the workpiece facing the melting energy supplier 1), or by spraying the corresponding cooling gas and the lower side of the workpieces W1 and W2 (the side of the workpiece facing the top surface 20a) through the gas outlet 31E, or by spraying the corresponding gas through the nozzle 1N and the gas outlet 31E at the same time. Preferably, an additional fixed nozzle (not shown) can be set on the side of the top surface 20a to continuously apply the corresponding gas to the welded junction on the upper side of the workpieces W1 and W2 to reduce or avoid the generation of oxides, and have a cooling effect.

步驟S3:根據所述經銲接交界所包含之熔融狀態之成分組成所對應的預設溫度控制條件,對經銲接交界處進行溫度控制,使冷卻過程中經歷會產生金屬間化合物的金屬相的時間最小化,而可使經銲接交界處可減少或避免金屬間化合物的產生;可選地,於完成上述溫度控制後,使溫度降至100℃以下形成一經溫度控制的銲道。特別是,所述預設溫度控制條件係根據經銲接交界所包含之熔融狀態之成分組成的時溫變態圖而定義,以根據對應的時溫變態圖,於一定期間內調整經銲接交界處的溫度,而避免會產生金屬間化合物的金屬變化相。所述一定期間內是1小時至100小時,且對應 的時間長度調整係可以0.1秒作為調整的區間。 Step S3: According to the preset temperature control condition corresponding to the composition of the molten state contained in the welded junction, the temperature of the welded junction is controlled to minimize the time of the metal phase that will produce intermetallic compounds during the cooling process, so that the generation of intermetallic compounds can be reduced or avoided at the welded junction; optionally, after completing the above temperature control, the temperature is reduced to below 100°C to form a temperature-controlled weld. In particular, the preset temperature control condition is defined according to the time-temperature deformation diagram of the composition of the molten state contained in the welded junction, so as to adjust the temperature of the welded junction within a certain period of time according to the corresponding time-temperature deformation diagram to avoid the generation of metal transformation phases that will produce intermetallic compounds. The certain period of time is from 1 hour to 100 hours, and the corresponding time length adjustment can be adjusted in intervals of 0.1 seconds.

當需要對經銲接交界處進行降溫時,可透過該控制器C的控制使該出氣口31E對經銲接交界處噴出冷卻氣體;特別是透過該控制器C控制對應的冷卻氣體供應器3G通入冷卻氣體至該進氣通道30,以使冷卻氣體自該出氣口31E噴出;如此,可在一定期間內使經銲接交界處的溫度符合預設溫度控制條件。較佳地,為提升對經銲接交界處的冷卻,亦可透過所述散熱治具6具有高導熱係數、或具有對應的散熱鰭片61、或具有供冷卻液體通入的液冷通道62,以提升經銲接交界處的散熱效率,進而提升冷卻效率。 When the temperature of the welded junction needs to be lowered, the controller C can be used to control the air outlet 31E to spray cooling gas to the welded junction; in particular, the controller C controls the corresponding cooling gas supplier 3G to pass cooling gas to the air inlet channel 30, so that the cooling gas is sprayed from the air outlet 31E; in this way, the temperature of the welded junction can meet the preset temperature control conditions within a certain period of time. Preferably, in order to improve the cooling of the welded junction, the heat dissipation fixture 6 can also have a high thermal conductivity, or have a corresponding heat dissipation fin 61, or have a liquid cooling channel 62 for the cooling liquid to pass through, so as to improve the heat dissipation efficiency of the welded junction, thereby improving the cooling efficiency.

當需要對經銲接交界處進行升溫時,對經銲接交界處提供熱能,使經銲接交界處的溫度升高或維持在特定溫度,以在一定期間內使經銲接交界處的溫度符合預設溫度控制條件。詳言之,可透過該控制器C的控制平台加熱器4升溫以對經銲接交界處進行升溫。 When the temperature of the welded junction needs to be increased, heat energy is provided to the welded junction to increase the temperature of the welded junction or maintain it at a specific temperature, so that the temperature of the welded junction meets the preset temperature control conditions within a certain period of time. In detail, the temperature of the welded junction can be increased by controlling the platform heater 4 of the controller C.

較佳是,該控制器C係根據該溫度感應器5所感測的溫度,並根據當前金屬成分間所對應的預設溫度控制條件,控制上述冷卻方法及/或加熱方法對經銲接交界處進行降溫及/或升溫,以在一定期間內使經銲接交界處的溫度符合預設溫度控制條件。 Preferably, the controller C controls the above cooling method and/or heating method to cool down and/or heat up the welded junction according to the temperature sensed by the temperature sensor 5 and the preset temperature control conditions corresponding to the current metal components, so that the temperature of the welded junction meets the preset temperature control conditions within a certain period of time.

舉例而言,該第一工件W1是鋁金屬,該第二工件W2是銅金屬為例,並以第6圖之鋁銅之時溫變態圖為基礎,可先透過該控制器C的控制使該出氣口31E對經銲接交界處噴出冷卻氣體,並較佳透過該控制器C的控制使冷卻液通過該散熱治具6的該液冷通道62,使經銲接交界處依時間的溫度變化,在一定期間內未符合或僅有短暫的歷時(Duration)符合其所對應的金屬間化合物生成相PIC依時間的溫度變化範圍;所述短暫的歷時例如是數秒,較佳不超過5秒。另,可選地,為了使經銲接交界處具有較好的特性,可透過該控制器C控制該平台加熱器4對經銲接交界處進行加熱,使經銲接交 界處依時間的溫度變化,在一定期間內的一歷時(Duration),符合其所對應的穩定相PS依時間的溫度變化範圍;所述歷時可例如是0.5小時以上。 For example, the first workpiece W1 is aluminum metal, and the second workpiece W2 is copper metal, and based on the temperature transformation diagram of aluminum and copper in Figure 6, the controller C can be controlled to spray cooling gas from the air outlet 31E to the welded interface, and preferably the controller C can be controlled to allow cooling liquid to pass through the liquid cooling channel 62 of the heat dissipation fixture 6, so that the temperature change at the welded interface over time does not meet or only meets the temperature change range of the corresponding intermetallic compound generation phase PIC over time within a certain period of time for a short duration; the short duration is, for example, several seconds, preferably not more than 5 seconds. In addition, optionally, in order to make the welded junction have better characteristics, the controller C can control the platform heater 4 to heat the welded junction so that the temperature change of the welded junction over time, for a duration within a certain period of time, meets the corresponding stable phase P S temperature change range over time; the duration can be, for example, more than 0.5 hours.

承上,以第6圖為基礎,在一較佳範例中,所述一定期間為1~100小時。在該待銲接處形成經銲接交界處的熔融狀態後,立即在1~36秒內使對應的經銲接交界處的溫度降至200℃以下(更佳是150℃以下);再對經銲接交界處提供熱能,使經銲接交界處的溫度維持在140~200℃的狀態持續至所述一定期間結束。詳言之,透過36秒內降至200℃,可避開金屬間化合物生成相PIC。另,透過溫度維持在140~200℃的狀態持續1~100小時,可使經銲接交界處的處於穩定相Ps或過飽合相PSS。如此,透過上述方式相較自然冷卻方式所獲得經銲接交界處的金相,具有更緊密的銲接結合性,更少的金屬間化合物的產生,及更少且更小的氣孔,而大幅提升鋁銅之異質金屬間的銲接強度與穩定性。 Based on FIG. 6, in a preferred example, the certain period of time is 1 to 100 hours. After the welded portion forms a molten state at the welded junction, the temperature of the corresponding welded junction is immediately reduced to below 200°C (preferably below 150°C) within 1 to 36 seconds; and then heat energy is provided to the welded junction to maintain the temperature of the welded junction at 140 to 200°C until the certain period of time ends. In detail, by reducing the temperature to 200°C within 36 seconds, the formation of intermetallic compounds can be avoided. In addition, by maintaining the temperature at 140~200℃ for 1~100 hours, the welded interface can be in the stable phase Ps or supersaturated phase P SS . In this way, the metallographic phase of the welded interface obtained by the above method has a tighter welding bond, less intermetallic compound generation, and fewer and smaller pores than that obtained by the natural cooling method, which greatly improves the welding strength and stability between the dissimilar metals of aluminum and copper.

應注意的是,為了使該溫度感應器5所感測溫度貼近所述經銲接交界處的溫度,對應的感測溫度可再根據該溫度感應器5的位置、其與經銲接交界處的距離、工件材質及銲接平台材質等因素中的至少一者進行補償,以貼近所述經銲接交界處的真實溫度,而可更精準的控制銲道的品質。 It should be noted that in order to make the temperature sensed by the temperature sensor 5 close to the temperature of the welded junction, the corresponding sensed temperature can be compensated according to at least one of the factors such as the position of the temperature sensor 5, its distance from the welded junction, the material of the workpiece and the material of the welding platform, so as to be close to the actual temperature of the welded junction, and the quality of the weld can be more accurately controlled.

應注意的是,本發明所提出之銲接平台2可適用於各種銲接方法的作業,特別是可適用於對經銲接交界處的溫度控制(進行降溫及/或升溫)。 It should be noted that the welding platform 2 proposed in the present invention can be applied to various welding methods, and in particular can be applied to temperature control (cooling and/or heating) at the welding interface.

綜上所述,本發明的控制銲接品質之方法、銲接平台及熔融式接合系統,針對經銲接交界處之金屬相的變化中的會產生金屬間化合物之金屬相者,透過對應的預設溫度控制條件,可減少或避免金屬間化合物的產生。另,透過銲接平台具有對應的平台冷卻構造與平台加熱器,可適用於對經銲接交界處的溫度控制。另,透過平台本體具有較高導熱係數,可便於快速調 整平台本體上方工件的溫度。另,透過溫度感應器的配置,可即時感測工件溫度,特別是感測經銲接加工處的溫度,可作為溫度控制與調整的依據。 In summary, the method for controlling welding quality, welding platform and fusion bonding system of the present invention can reduce or avoid the generation of intermetallic compounds through the corresponding preset temperature control conditions for the metal phases that will generate intermetallic compounds during the change of the metal phase at the welding interface. In addition, the welding platform has a corresponding platform cooling structure and platform heater, which can be applied to the temperature control of the welding interface. In addition, the platform body has a higher thermal conductivity, which can facilitate the rapid adjustment of the temperature of the workpiece above the platform body. In addition, through the configuration of the temperature sensor, the workpiece temperature can be sensed in real time, especially the temperature of the welding processing area, which can be used as a basis for temperature control and adjustment.

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當包含後附之申請專利範圍所記載的文義及均等範圍內之所有變更。又,上述之數個實施例能夠組合時,則本發明包含任意組合的實施態樣。 Although the present invention has been disclosed using the above preferred embodiments, they are not intended to limit the present invention. Any person skilled in the art can make various changes and modifications to the above embodiments within the spirit and scope of the present invention. These changes and modifications are still within the technical scope protected by the present invention. Therefore, the protection scope of the present invention includes all changes within the meaning and equivalent scope recorded in the attached patent application scope. In addition, when the above several embodiments can be combined, the present invention includes any combination of implementations.

1:熔融能量供應器 1: Melting energy supplier

1N:氣嘴 1N: Air nozzle

2:銲接平台 2: Welding platform

20:平台本體 20: Platform body

20a:頂面 20a: Top

20b:底面 20b: Bottom surface

20c:凹陷部 20c: Depression

20d:凹陷表面 20d: Concave surface

3:平台冷卻構造 3: Platform cooling structure

30:進氣通道 30: Air intake duct

30I:進氣口 30I: Air intake

31:出氣通道 31: Exhaust channel

31E:出氣口 31E: Air outlet

4:平台加熱器 4: Platform heater

4P:凸出部 4P: protrusion

5:溫度感應器 5: Temperature sensor

6:散熱治具 6: Heat dissipation fixture

W1:第一工件 W1: First workpiece

W2:第二工件 W2: Second workpiece

Claims (10)

一種控制銲接品質之方法,包含:提供一第一工件與一第二工件,使該第一工件與該第二工件要進行銲接的交界處彼此抵接,以界定一待銲的銲道;該第一工件由一第一材料所製成,該第二工件由一第二材料所製成,該第一材料與該第二材料是一金屬或一合金,且該第一材料與該第二材料的組成元素不同及/或組成元素的比例不同;使所述待銲的銲道形成暫時具有對應熔融狀態的經銲接交界處,在熔融狀態的經銲接交界處具有該第一材料與該第二材料的全部元素或局部元素的熔融成分;在熔融狀態的經銲接交界處在冷卻過程中隨溫度與時間的關係具有至少二種金屬相之變化,且所述至少二種金屬相中之一者會產生金屬間化合物,該至少二種金屬相中的其他者不會產生金屬間化合物,並依對應的一時溫變態圖定義一定期間內的預設溫度控制條件隨時間控制對應的溫度高低,使冷卻過程中經歷會產生金屬間化合物的金屬相的時間最小化;及根據所述熔融狀態的經銲接交界所包含之熔融成分所對應的預設溫度控制條件,在一定期間內對所述經銲接交界處進行溫度控制。 A method for controlling welding quality comprises: providing a first workpiece and a second workpiece, making the junction of the first workpiece and the second workpiece to be welded abut each other to define a weld path to be welded; the first workpiece is made of a first material, and the second workpiece is made of a second material, the first material and the second material are a metal or an alloy, and the first material and the second material have different constituent elements and/or different proportions of constituent elements; making the weld path to be welded form a welded junction temporarily having a corresponding molten state, and the welded junction in the molten state has a molten component of all elements or partial elements of the first material and the second material. ; The welded junction in the molten state has at least two metal phase changes in the relationship between temperature and time during the cooling process, and one of the at least two metal phases will produce intermetallic compounds, and the other of the at least two metal phases will not produce intermetallic compounds, and the preset temperature control conditions within a certain period of time are defined according to the corresponding time-temperature deformation diagram to control the corresponding temperature with time, so as to minimize the time of the metal phase that will produce intermetallic compounds during the cooling process; and the welded junction is temperature controlled within a certain period of time according to the preset temperature control conditions corresponding to the molten components contained in the welded junction in the molten state. 如請求項1之控制銲接品質之方法,其中,所述溫度控制的方法包含透過施加冷卻氣體在經銲接交界處,使經銲接交界處的溫度降低。 A method for controlling welding quality as claimed in claim 1, wherein the temperature control method includes applying cooling gas to the welding junction to reduce the temperature of the welding junction. 如請求項1之控制銲接品質之方法,其中,所述溫度控制的方法包含透過一散熱治具接觸該第一工件與該第二工件,所述散熱治具係具有40W/m‧K以上的導熱係數、散熱鰭片及供冷卻液體流通的液冷通道中的至少一者。 A method for controlling welding quality as claimed in claim 1, wherein the temperature control method includes contacting the first workpiece and the second workpiece through a heat sink, and the heat sink has at least one of a thermal conductivity of 40 W/m‧K or more, a heat sink fin, and a liquid cooling channel for circulating cooling liquid. 如請求項1之控制銲接品質之方法,其中,所述溫度控制的方法包含對經銲接交界處提供熱能,使經銲接交界處的溫度升高或維持在特定溫度。 A method for controlling welding quality as claimed in claim 1, wherein the temperature control method includes providing heat energy to the welded junction to increase the temperature of the welded junction or maintain it at a specific temperature. 如請求項1至4中任一項之控制銲接品質之方法,其中,所述一定期間內是1至100小時。 A method for controlling welding quality as in any one of claims 1 to 4, wherein the certain period of time is 1 to 100 hours. 如請求項1至4中任一項之控制銲接品質之方法,其中,該第一材料包含鋁,該第二材料包含銅,所述一定期間內是1至100小時;在該待銲接處形成經銲接交界處的熔融狀態後,在1至36秒內使經銲接交界處的溫度降至200℃以下;再對經銲接交界處提供熱能,使經銲接交界處的溫度維持在140至200℃的狀態持續至所述一定期間結束。 A method for controlling welding quality as claimed in any one of claims 1 to 4, wherein the first material comprises aluminum, the second material comprises copper, and the certain period of time is 1 to 100 hours; after the welded joint is formed into a molten state, the temperature of the welded joint is reduced to below 200°C within 1 to 36 seconds; and heat energy is provided to the welded joint so that the temperature of the welded joint is maintained at 140 to 200°C until the end of the certain period of time. 一種銲接平台,配置以實施如請求項1至6中任一項之控制銲接品質之方法,該銲接平台包含:一平台本體,具有一頂面與一底面相對該頂面;一平台冷卻構造,具有至少一進氣通道與多個出氣通道;該進氣通道設置於該平台本體內部,並具有一進氣口以供一氣體通入該進氣通道;該出氣通道與該進氣通道連通,且具有一出氣口朝背離該平台本體的該底面的方向設置;及一平台加熱器,係鄰近該平台本體的該頂面設置。 A welding platform, configured to implement a method for controlling welding quality as in any one of claims 1 to 6, the welding platform comprising: a platform body, having a top surface and a bottom surface opposite to the top surface; a platform cooling structure, having at least one air inlet channel and a plurality of air outlet channels; the air inlet channel is arranged inside the platform body, and has an air inlet for a gas to pass into the air inlet channel; the air outlet channel is connected to the air inlet channel, and has an air outlet arranged in a direction away from the bottom surface of the platform body; and a platform heater, which is arranged adjacent to the top surface of the platform body. 如請求項7之銲接平台,其中,該頂面具有一凹陷部自該頂面凹陷,且該凹陷部係沿一方向延伸,以形成一長條狀的凹陷空間;該凹陷部具有一凹陷表面位於該頂面與該底面之間;該進氣通道位於該凹陷部的下方且沿該凹陷部延伸;該出氣口形成於該凹陷表面;該平台加熱器係設置於對應該凹陷部的位置。 As in claim 7, the welding platform, wherein the top surface has a recessed portion recessed from the top surface, and the recessed portion extends in a direction to form a long strip of recessed space; the recessed portion has a recessed surface located between the top surface and the bottom surface; the air inlet channel is located below the recessed portion and extends along the recessed portion; the air outlet is formed on the recessed surface; the platform heater is arranged at a position corresponding to the recessed portion. 如請求項8之銲接平台,其中,該平台加熱器具有一凸出部突出於該凹陷部的該凹陷表面,且未超出該平台本體之該頂面所界定的一平面。 As in claim 8, the welding platform, wherein the platform heater has a protrusion protruding from the concave surface of the concave portion and does not exceed a plane defined by the top surface of the platform body. 一種熔融式接合系統,包含: 一熔融能量供應器,用以使對應的金屬工件的被照射區域形成熔融狀態;如請求項7至9中任一項之銲接平台,該熔融能量供應器與該銲接平台之間係可依預定加工路徑產生相對運動;一冷卻氣體供應器,用以供給一冷卻氣體通入該平台冷卻構造的該進氣通道;一溫度感應器,設置於該平台本體中且鄰近該頂面的位置;及一控制器,分別與該熔融能量供應器、該冷卻氣體供應器、該平台加熱器及該溫度感應器耦接,以用於:控制該熔融能量供應器的功率以對目標區域進行熔融式接合;及接收該溫度感應器所感測之溫度,並根據一目標處理溫度中的溫度與時間關係,調整該冷卻氣體供應器供給至該氣體通道之氣體的流量大小,使目標區域降溫;及/或調整該平台加熱器之輸出功率,使目標區域升溫或維持一定溫度。 A melting type joining system comprises: a melting energy supplier for making the irradiated area of the corresponding metal workpiece form a molten state; a welding platform as in any one of claims 7 to 9, wherein the melting energy supplier and the welding platform can generate relative movement according to a predetermined processing path; a cooling gas supplier for supplying a cooling gas into the air inlet channel of the platform cooling structure; a temperature sensor disposed in the platform body and adjacent to the top surface; and a controller, respectively connected to the melting energy supplier and the welding platform; The melt energy supplier, the cooling gas supplier, the platform heater and the temperature sensor are coupled to: control the power of the melt energy supplier to perform melt-type bonding on the target area; and receive the temperature sensed by the temperature sensor, and adjust the flow rate of the gas supplied by the cooling gas supplier to the gas channel according to the temperature and time relationship in a target processing temperature to cool the target area; and/or adjust the output power of the platform heater to heat up the target area or maintain a certain temperature.
TW111145477A 2022-11-28 2022-11-28 Welding quality controlling method, welding bed and molten welding system TWI859644B (en)

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TWI251518B (en) * 2004-02-27 2006-03-21 Chung Shan Inst Of Science Method of brazing titanium alloy to stainless steel
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