TWI859464B - Mask container - Google Patents
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- TWI859464B TWI859464B TW110130911A TW110130911A TWI859464B TW I859464 B TWI859464 B TW I859464B TW 110130911 A TW110130911 A TW 110130911A TW 110130911 A TW110130911 A TW 110130911A TW I859464 B TWI859464 B TW I859464B
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/66—Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
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- H10P72/10—
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- Preparing Plates And Mask In Photomechanical Process (AREA)
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Abstract
本發明提供一種光罩容器,其能夠牢固地保持光罩基板,可抑制光罩基板收納部之結露,潔淨度優異,不易令光罩基板表面附著污物(微細粒子),輕量且機械強度優異。 本發明之光罩容器之特徵在於:由容器本體及蓋體形成光罩基板收納部,以光罩基板收納部中收納有光罩基板之狀態進行保存、輸送,容器本體係包含熔體流動速率(MFR)為0.6(g/10分鐘)以下之高密度聚乙烯樹脂,且包含大致平板狀之基部、及自基部之端部沿大致直角方向設置之側壁部的箱狀體,並且為包含內壁及外壁之2層中空構造體。 The present invention provides a photomask container that can firmly hold a photomask substrate, can suppress condensation in a photomask substrate storage portion, has excellent cleanliness, is not easy to cause dirt (fine particles) to adhere to the surface of the photomask substrate, is lightweight and has excellent mechanical strength. The photomask container of the present invention is characterized in that: the photomask substrate storage portion is formed by a container body and a cover, and the photomask substrate is stored and transported in a state where the photomask substrate is stored in the photomask substrate storage portion. The container body is a box-shaped body comprising a high-density polyethylene resin with a melt flow rate (MFR) of less than 0.6 (g/10 minutes), and comprises a roughly flat base, and a side wall portion arranged at a roughly right angle from the end of the base, and is a two-layer hollow structure comprising an inner wall and an outer wall.
Description
本發明係關於一種用於保存、輸送光罩基板之光罩容器。 The present invention relates to a photomask container for storing and transporting photomask substrates.
近年來,為了製造液晶顯示面板等顯示裝置,而於具有無塵室之工廠製作光罩基板,並將所製作之光罩基板輸送至後續步驟之工廠以製造液晶顯示面板等顯示裝置。 In recent years, in order to manufacture display devices such as liquid crystal display panels, photomask substrates are manufactured in factories with clean rooms, and the manufactured photomask substrates are transported to factories for subsequent steps to manufacture display devices such as liquid crystal display panels.
液晶顯示面板等顯示裝置為精密機器,有於輸送光罩基板時,基板表面附著有污物(微細粒子)或者因電損傷等原因使基板電路或基板自身出現破損,而無法製造顯示裝置的情況。 LCD panels and other display devices are precision machines. When transporting the mask substrate, dirt (fine particles) may be attached to the substrate surface, or the substrate circuit or the substrate itself may be damaged due to electrical damage, making it impossible to manufacture the display device.
又,為了使液晶顯示面板等顯示裝置之畫面擴大、或同時對複數個顯示裝置進行曝光以提高生產性、節省人工,而要求光罩基板尺寸加大(面積加大),需要其具有750×750mm以上之大小。又,由於全球化之影響,自光罩基板之製造至液晶顯示面板等顯示裝置等成品之製造不僅於一個工廠內進行,還於日本國內外之相隔遙遠之地區進行,因此將光罩基板收納於光罩容器中並利用卡車、船舶、飛機等進行輸送。 In order to enlarge the screen of display devices such as liquid crystal display panels, or to expose multiple display devices at the same time to improve productivity and save labor, the size of the photomask substrate is required to be larger (larger in area), and it needs to be larger than 750×750mm. In addition, due to the influence of globalization, the manufacturing of the photomask substrate to the manufacturing of finished products such as liquid crystal display panels is not only carried out in one factory, but also in remote areas inside and outside Japan. Therefore, the photomask substrate is stored in a photomask container and transported by trucks, ships, airplanes, etc.
因此,期望上述光罩容器能夠牢固地保持光罩基板,能夠於不令光罩基板表面附著污物(微細粒子)或者不令光罩基板破損之情況下進行輸送,輕量且機械強度優異。又,於利用飛機進行空運時,由於在減壓下或低溫下進行輸送,因此期望:不會對光罩基板或光罩容器附加不必要之應力;可抑制於光罩容器之光罩基板收納部產生結露;潔淨度優異;等。 Therefore, it is expected that the above-mentioned photomask container can firmly hold the photomask substrate, can be transported without causing dirt (fine particles) to adhere to the surface of the photomask substrate or without causing damage to the photomask substrate, and is lightweight and has excellent mechanical strength. In addition, when transporting by airplane, since it is transported under reduced pressure or low temperature, it is expected that: unnecessary stress will not be added to the photomask substrate or the photomask container; condensation can be suppressed in the photomask substrate storage part of the photomask container; the cleanliness is excellent; etc.
因此,提出有各種適合輸送之光罩容器。例如,提出有:「一種光罩盒,其特徵在於:其用於在收納有光罩基板之狀態下進行搬送,且具備:保持機構,其保持上述光罩基板;基部,其供設置該保持機構;及蓋部,其裝卸自如地安裝於該基部,並覆蓋上述光罩基板」(例如參照專利文獻1);「一種大型精密片狀(半)成品用密封容器,其特徵在於:其係包含具有要互相抵接之密封用周緣部的大致對稱構造之本體部及蓋體部,且用於在內部收容大型精密片狀成品或半成品(以下總稱為「精密片狀(半)成品」)的容器,本體部及蓋體部分別包含互相平坦地延伸且於中間抵接部互相接合之複數個抗靜電性樹脂板,具有金屬製補強帶狀體沿著接合部自外側密封性地栓定至接合之樹脂板之構造;於本體部之底部,具有可將精密片狀(半)成品固定、支持於互相正交之X、Y及Z方向(即精密片狀(半)成品之縱向、橫向及厚度方向)的固定支持構造;上述固定支持構造具有至少1組支承部與固定支持具,上述支承部用於在其上載置精密片狀(半)成品,上述固定支持具對載置於該支承部上之精密片狀(半)成品之端緣部施加至少厚度方向上之按壓力;固定支持具具有固定於本體部底部之腳部、及可旋動地軸支於該腳部之可動部,該可動部可於倒立位置與倒置開放位置之間旋動,於該倒立位置,對載置於支承部上之精密片狀(半)成品之端 緣部,至少沿其厚度方向施加按壓力,而將其固定支持,於該倒置開放位置,可將精密片狀(半)成品載置於支承部上」(例如參照專利文獻2)等。 Therefore, various photomask containers suitable for transportation have been proposed. For example, "A photomask box, characterized in that it is used for transportation while storing a photomask substrate, and has: a holding mechanism that holds the above-mentioned photomask substrate; a base for setting the holding mechanism; and a cover that is easily installed on the base and covers the above-mentioned photomask substrate" (for example, refer to patent document 1); "A sealed container for large precision sheet-like (semi-)finished products, characterized in that it includes a sealing member that is to be abutted against each other. A container having a main body and a lid with a substantially symmetrical structure with a sealed periphery, and used for accommodating a large precision sheet-shaped finished product or semi-finished product (hereinafter collectively referred to as "precision sheet-shaped (semi-)finished product") inside, wherein the main body and the lid respectively include a plurality of antistatic resin plates extending flatly to each other and joined to each other at a middle abutment portion, and having a structure in which a metal reinforcing belt is bolted to the joined resin plates from the outside along the joint in a sealing manner; at the bottom of the main body, there is a structure in which a metal reinforcing belt is bolted to the joined resin plates from the outside in a sealing manner; A fixed support structure is provided for fixing and supporting the precision sheet (semi) finished product in mutually orthogonal X, Y and Z directions (i.e., the longitudinal, transverse and thickness directions of the precision sheet (semi) finished product); the fixed support structure comprises at least one set of supporting parts and a fixed support, the supporting part is used to carry the precision sheet (semi) finished product thereon, and the fixed support applies a pressing force in at least the thickness direction to the edge of the precision sheet (semi) finished product carried on the supporting part; The fixed support has a foot fixed to the bottom of the main body and a movable part rotatably supported on the foot. The movable part can rotate between an inverted position and an inverted open position. In the inverted position, a pressing force is applied to the end edge of the precision sheet (semi-)finished product placed on the support at least along its thickness direction to fix and support it. In the inverted open position, the precision sheet (semi-)finished product can be placed on the support" (for example, refer to patent document 2).
然而,上述光罩容器存在如下缺點:零件數量多,各零件之製造需要耗費工時,因此生產效率之提高有限,或者需要大量時間來維持品質穩定性,重量較大,不易運輸。 However, the above-mentioned photomask container has the following disadvantages: there are many parts, and the manufacturing of each part requires time-consuming work, so the improvement of production efficiency is limited, or a lot of time is required to maintain quality stability, and the weight is large and difficult to transport.
[專利文獻1]日本專利特開2008-32915號公報 [Patent document 1] Japanese Patent Publication No. 2008-32915
[專利文獻2]日本專利第4476727號公報 [Patent Document 2] Japanese Patent No. 4476727
鑒於上述問題,本發明之目的在於提供一種光罩容器,其輕量且機械強度優異,能夠牢固地保持光罩基板,可抑制光罩基板收納部產生結露,潔淨度優異,不易令光罩基板表面附著污物(微細粒子),可安全、容易地進行輸送,易於製造,生產效率、品質穩定性高,且價格低廉。 In view of the above problems, the purpose of the present invention is to provide a photomask container that is lightweight and has excellent mechanical strength, can firmly hold the photomask substrate, can suppress condensation in the photomask substrate storage part, has excellent cleanliness, is not easy to make dirt (fine particles) adhere to the surface of the photomask substrate, can be safely and easily transported, is easy to manufacture, has high production efficiency and quality stability, and is low in price.
即,本發明係關於:[1]一種光罩容器,其特徵在於:由容器本體及蓋體形成光罩基板收納部,以光罩基板收納部中收納有光罩基板之狀態進行保存、輸送,且容 器本體係包含熔體流動速率(MFR)為0.6(g/10分鐘)以下之高密度聚乙烯樹脂,且包含大致平板狀之基部、及自基部之端部沿大致直角方向設置之側壁部的箱狀體,並且為包含內壁及外壁之2層中空構造體;[2]如上述[1]所記載之光罩容器,其特徵在於:容器本體藉由吹塑成形法一體成形;[3]如上述[1]或[2]所記載之光罩容器,其特徵在於:於基部形成有保持固定光罩基板之光罩基板保持部;[4]如上述[1]至[3]中任一項所記載之光罩容器,其特徵在於:側壁部具有中空部,且較基部之厚度厚;[5]如上述[1]至[4]中任一項所記載之光罩容器,其特徵在於:基部之內壁及/或側壁部之內壁向光罩基板收納部側(上方或內側)變形,一體形成具有中空部之光罩基板保持部;[6]如上述[1]至[5]中任一項所記載之光罩容器,其特徵在於:蓋體係包含熔體流動速率(MFR)為0.6(g/10分鐘)以下之高密度聚乙烯樹脂,且包含大致平板狀之基部、及自基部之端部沿大致直角方向設置之側壁部的箱狀體,並且為包含內壁及外壁之2層中空構造體;[7]如上述[1]至[6]中任一項所記載之光罩容器,其特徵在於:容器本體及蓋體之至少一者之側壁部之上端部向側方延伸設置而形成把手部;[8]如上述[1]至[7]中任一項所記載之光罩容器,其特徵在於:於容器本體及蓋體之至少一者穿設有貫通孔,且於該貫通孔設置有過濾器,從而形成排氣部;[9]如上述[1]至[8]中任一項所記載之光罩容器,其特徵在於:於基部形成有多條肋部; [10]如技術方案1至9中任一項所記載之光罩容器,其特徵在於:表面固有電阻值為108Ω以上且未達1010Ω;以及[11]如上述[1]至[10]中任一項所記載之光罩容器,其特徵在於:於基部之內壁(光罩基板收納部側)積層有防靜電片材或防靜電成型體。 That is, the present invention relates to: [1] a photomask container, characterized in that: a photomask substrate storage portion is formed by a container body and a cover, and the photomask substrate is stored and transported in a state where the photomask substrate is stored in the photomask substrate storage portion, and the container body is a box-shaped body comprising a generally flat base and a side wall portion provided in a generally right angle direction from the end of the base, and is a two-layer hollow structure comprising an inner wall and an outer wall; [2] as described above [1] The photomask container described in the above, characterized in that: the container body is integrally formed by blow molding; [3] The photomask container described in the above [1] or [2], characterized in that: a photomask substrate holding portion for holding and fixing the photomask substrate is formed on the base; [4] The photomask container described in any one of the above [1] to [3], characterized in that: the side wall portion has a hollow portion and is thicker than the base; [5] The photomask container described in any one of the above [1] to [4], characterized in that: the inner wall and/or the side wall of the base The inner wall of the wall portion is deformed toward the side (upper or inner side) of the photomask substrate storage portion to integrally form a photomask substrate holding portion having a hollow portion; [6] As described in any one of the above [1] to [5], the photomask container is characterized in that: the cover body is a box-shaped body comprising a high-density polyethylene resin with a melt flow rate (MFR) of less than 0.6 (g/10 minutes), and comprises a substantially flat base, and a side wall portion provided at a substantially right angle from the end of the base, and is a two-layer hollow structure comprising an inner wall and an outer wall; [7] As described in the above [1] The photomask container as described in any one of [1] to [6] is characterized in that: the upper end of the side wall of at least one of the container body and the cover is extended laterally to form a handle; [8] The photomask container as described in any one of [1] to [7] is characterized in that: a through hole is formed in at least one of the container body and the cover, and a filter is provided in the through hole to form an exhaust part; [9] The photomask container as described in any one of [1] to [8] is characterized in that: a plurality of ribs are formed on the base; [10] A photomask container as described in any one of technical solutions 1 to 9, characterized in that: the surface intrinsic resistance value is greater than 10 8 Ω and less than 10 10 Ω; and [11] A photomask container as described in any one of the above [1] to [10], characterized in that: an antistatic sheet or an antistatic molded body is layered on the inner wall of the base (the side of the photomask substrate storage portion).
本發明之光罩容器之構成如上所述,光罩容器易於製造,價格低廉,輕量且機械強度優異,能夠牢固地保持光罩基板,能夠於不令光罩基板表面附著污物(微細粒子)或者不令光罩基板變形之情況下進行保存、輸送。因此,即便於減壓下或低溫下進行保存、輸送,亦不會使光罩基板或光罩容器負擔不必要之應力,可抑制光罩容器之光罩基板收納部之結露,潔淨度優異,因此適宜利用飛機進行空運。 The structure of the photomask container of the present invention is as described above. The photomask container is easy to manufacture, inexpensive, lightweight and has excellent mechanical strength. It can firmly hold the photomask substrate and can be stored and transported without causing dirt (fine particles) to adhere to the surface of the photomask substrate or without causing the photomask substrate to deform. Therefore, even if it is stored and transported under reduced pressure or at low temperature, the photomask substrate or the photomask container will not bear unnecessary stress, and the condensation of the photomask substrate storage part of the photomask container can be suppressed. The cleanliness is excellent, so it is suitable for air transportation by airplane.
1:容器本體 1: Container body
2:蓋體 2: Cover
3:光罩基板收納部 3: Photomask substrate storage unit
4:光罩基板支持固定部 4: Photomask substrate support and fixing part
5:把手部 5: Handle
6:光罩基板 6: Photomask substrate
7:排氣部 7: Exhaust section
8:視窗部 8: Window section
9:O形環 9: O-ring
11:基部 11: Base
12:側壁部 12: Side wall
13:肋部 13: Ribs
14:缺口凹部 14: Notch concave part
41:螺栓 41: Bolts
42:墊圈 42: Gasket
43:嵌入式螺母 43: Embedded nut
44:光罩基板載置部 44: Photomask substrate mounting unit
45:橫向定位部 45: Horizontal positioning part
71:貫通孔 71:Through hole
72:階差部 72: Class difference section
73:過濾器 73:Filter
74:固定具 74: Fixtures
111:內壁 111: Inner wall
112:外壁 112: Outer wall
113:中空部 113: Hollow part
圖1係表示本發明之光罩容器之一例之概略剖視圖。 FIG1 is a schematic cross-sectional view showing an example of a photomask container of the present invention.
圖2係表示本發明之光罩容器之容器本體之一例的俯視圖。 FIG. 2 is a top view showing an example of the container body of the photomask container of the present invention.
圖3係圖2中之A-A剖視圖。 Figure 3 is the A-A cross-sectional view in Figure 2.
圖4係圖2中之B-B剖視圖。 Figure 4 is a cross-sectional view taken along line B-B in Figure 2.
圖5係表示本發明之光罩容器之容器本體之不同例的俯視圖。 FIG. 5 is a top view showing different examples of the container body of the photomask container of the present invention.
圖6係圖5中之C-C剖視圖。 Figure 6 is the C-C cross-sectional view in Figure 5.
本發明之光罩容器之特徵在於:由容器本體及蓋體形成光罩基板收 納部,以光罩基板收納部中收納有光罩基板之狀態進行保存、輸送,且容器本體係包含熔體流動速率(MFR)為0.6(g/10分鐘)以下之高密度聚乙烯樹脂,且包含大致平板狀之基部、及自基部之端部沿大致直角方向設置之側壁部的箱狀體,並且為包含內壁及外壁之2層中空構造體。 The characteristics of the photomask container of the present invention are: a photomask substrate storage part is formed by a container body and a cover, and the photomask substrate is stored and transported in a state in which the photomask substrate is stored, and the container body is a box-shaped body including a substantially flat base and a side wall portion provided along a substantially right angle direction from the end of the base, and is a two-layer hollow structure including an inner wall and an outer wall.
上述容器本體係藉由吹塑成形法一體成形,較佳為機械強度大,以於輸送時或保存時不易變形或受到破壞,因此包含高密度聚乙烯樹脂。高密度聚乙烯樹脂係藉由中低壓法聚合且密度為0.945~0.965g/cm3之聚乙烯樹脂,可由微量之丙烯、1-丁烯、1-戊烯、1-己烯、1-辛烯等α-烯烴共聚而成。 The container body is formed in one piece by blow molding, preferably with high mechanical strength so as not to be easily deformed or damaged during transportation or storage, and therefore comprises high-density polyethylene resin. High-density polyethylene resin is a polyethylene resin with a density of 0.945-0.965 g/ cm3 polymerized by medium-low pressure method, and can be copolymerized with trace amounts of α-olefins such as propylene, 1-butene, 1-pentene, 1-hexene, and 1-octene.
關於上述高密度聚乙烯樹脂,熔體流動速率(MFR)較小者之膜成形性優異,尤其適合吹塑成形,並且機械強度亦優異,因此熔體流動速率(MFR)為0.6(g/10分鐘)以下,較佳為0.2(g/10分鐘)以下,更佳為0.01~0.1(g/10分鐘)。再者,MFR係JIS K 7210中規定之表示熱塑性樹脂之熔融黏度之指標。 Regarding the above-mentioned high-density polyethylene resin, the one with a smaller melt flow rate (MFR) has excellent film formability, is particularly suitable for blow molding, and has excellent mechanical strength, so the melt flow rate (MFR) is 0.6 (g/10 minutes) or less, preferably 0.2 (g/10 minutes) or less, and more preferably 0.01~0.1 (g/10 minutes). Furthermore, MFR is an indicator of the melt viscosity of thermoplastic resins specified in JIS K 7210.
又,關於上述高密度聚乙烯樹脂之重量平均分子量,於重量平均分子量未達10萬之情形時,機械強度或耐蠕變性等降低,反之,若超過50萬,則熔融黏度升高,熱熔融成形性降低,而不易獲得均勻之容器本體,因此較佳為10萬~50萬。再者,於本發明中,重量平均分子量係藉由凝膠滲透層析法(GPC)測得之值。 In addition, regarding the weight average molecular weight of the high-density polyethylene resin, when the weight average molecular weight is less than 100,000, the mechanical strength or creep resistance is reduced. On the contrary, if it exceeds 500,000, the melt viscosity increases, the hot melt formability decreases, and it is difficult to obtain a uniform container body. Therefore, it is preferably 100,000 to 500,000. Furthermore, in the present invention, the weight average molecular weight is a value measured by gel permeation chromatography (GPC).
於上述高密度聚乙烯樹脂中,可於機械強度等物性不會降低之範圍內少量添加中密度聚乙烯樹脂、低密度聚乙烯樹脂、線狀低密度聚乙烯樹脂、聚丙烯樹脂、乙烯-丙烯共聚物、乙烯-1-丁烯共聚物、乙烯-1-戊烯共聚物、乙烯-1-己烯共聚物、乙烯-1-辛烯共聚物、乙烯-乙酸乙烯酯共聚物、乙烯-(甲基)丙烯酸酯共聚物、乙烯-氯乙烯共聚物、乙烯-丙烯-丁烯共聚物等烯烴系樹脂。 In the above-mentioned high-density polyethylene resin, a small amount of medium-density polyethylene resin, low-density polyethylene resin, linear low-density polyethylene resin, polypropylene resin, ethylene-propylene copolymer, ethylene-1-butene copolymer, ethylene-1-pentene copolymer, ethylene-1-hexene copolymer, ethylene-1-octene copolymer, ethylene-vinyl acetate copolymer, ethylene-(meth)acrylate copolymer, ethylene-vinyl chloride copolymer, ethylene-propylene-butene copolymer and other olefin resins can be added within the range that the physical properties such as mechanical strength are not reduced.
又,於上述高密度聚乙烯樹脂中,亦可視需要添加熱穩定劑、耐熱性提昇劑、光穩定劑、紫外線吸收劑、抗氧化劑、抗靜電劑、衝擊改良劑、防霧劑、阻燃劑、著色劑等。 In addition, heat stabilizers, heat resistance enhancers, light stabilizers, ultraviolet absorbers, antioxidants, antistatic agents, impact modifiers, antifogging agents, flame retardants, colorants, etc. may be added to the above-mentioned high-density polyethylene resin as needed.
上述容器本體包含高密度聚乙烯樹脂,因此易於帶電,易於吸附污物(微細粒子)。因此,光罩基板之表面易於附著污物(微細粒子),易於污染,因此較佳為添加有抗靜電劑,其表面固有電阻值較佳為108Ω以上且未達1010Ω。 The container body is made of high-density polyethylene resin, so it is easy to be charged and easy to absorb dirt (fine particles). Therefore, the surface of the photomask substrate is easy to be attached with dirt (fine particles) and easy to be contaminated, so it is preferably added with an antistatic agent, and its surface intrinsic resistance is preferably greater than 10 8 Ω and less than 10 10 Ω.
作為抗靜電劑,例如可例舉甘油脂肪酸酯系界面活性劑、有機硼系抗靜電劑等以往於塑膠加工中使用之抗靜電劑、碳黑等。 Examples of antistatic agents include glycerol fatty acid ester-based surfactants, organic boron-based antistatic agents, and other antistatic agents that have been used in plastic processing, and carbon black.
作為上述抗靜電劑,較佳為有機硼系抗靜電劑,作為有機硼系抗靜電劑,例如可例舉通式(1)所表示之供體-受體系分子化合物型抗靜電劑。 As the above-mentioned antistatic agent, an organic boron antistatic agent is preferred. As an organic boron antistatic agent, for example, a donor-acceptor system molecular compound type antistatic agent represented by general formula (1) can be cited.
[化1]
式中,R1、R2分別獨立為碳數12~22之醯基或H,並且R1、R2之至少一者為碳數12~22之醯基,R3、R4、R5分別獨立為CH3、C2H5、CH2OH、C2H4OH、CH2CH(CH3)OH、碳數12~22之烷基或者烯基、碳數合計13~25之醯氧基烷基、或碳數合計14~25之醯胺基烷基,並且R3、R4、R5之至少一者為碳數12~22之烷基或者烯基、碳數合計13~25之醯氧基烷基、或碳數合計14~25之醯胺基烷基。 In the formula, R 1 and R 2 are each independently an acyl group having 12 to 22 carbon atoms or H, and at least one of R 1 and R 2 is an acyl group having 12 to 22 carbon atoms, R 3 , R 4 and R 5 are each independently CH 3 , C 2 H 5 , CH 2 OH, C 2 H 4 OH, CH 2 CH(CH 3 )OH, an alkyl group or alkenyl group having 12 to 22 carbon atoms, an acyloxyalkyl group having a total carbon number of 13 to 25, or an amidoalkyl group having a total carbon number of 14 to 25, and at least one of R 3 , R 4 and R 5 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, an acyloxyalkyl group having a total carbon number of 13 to 25, or an amidoalkyl group having a total carbon number of 14 to 25.
作為通式(1)所表示之抗靜電劑之具體例,例如由下述化學式(2)~(12)表示。 As a specific example of the antistatic agent represented by the general formula (1), it is represented by the following chemical formulas (2) to (12).
[化3]
[化7]
[化11]
上述通式(1)所表示之供體-受體系分子化合物型抗靜電劑可吸附於無機填充劑粉末之表面而製成粉末狀抗靜電劑。作為無機填充劑粉末,只要為以往塑膠成形體中所使用之無機填充劑粉末即可,並無特別限定,例如可例舉:碳酸鈣、碳酸鎂、氧化鋁、氧化鎂、氧化鈦、氫氧化鎂、滑石、雲母、黏土等。 The donor-acceptor system molecular compound type antistatic agent represented by the above general formula (1) can be adsorbed on the surface of the inorganic filler powder to prepare a powdered antistatic agent. As the inorganic filler powder, it can be any inorganic filler powder used in the past plastic moldings without any special limitation, for example: calcium carbonate, magnesium carbonate, aluminum oxide, magnesium oxide, titanium oxide, magnesium hydroxide, talc, mica, clay, etc.
又,製造表面吸附有上述抗靜電劑之無機填充劑粉末之方法並無特別限定,例如可例舉如下方法:對溶解有抗靜電劑之有機溶劑供給無機填充劑粉末,加以攪拌混合,使抗靜電劑吸附於無機填充劑粉末之表面後,使有機溶劑蒸發。 In addition, the method for producing the inorganic filler powder with the antistatic agent adsorbed on the surface is not particularly limited. For example, the following method can be cited: supplying the inorganic filler powder to the organic solvent in which the antistatic agent is dissolved, stirring and mixing, allowing the antistatic agent to be adsorbed on the surface of the inorganic filler powder, and then evaporating the organic solvent.
作為上述有機溶劑,只要為可溶解上述抗靜電劑之有機溶劑即可,並無特別限定,例如可例舉:甲醇、乙醇、丙醇、異丙醇、丁醇等低級醇 類;丙酮、甲基乙基酮、甲基異丁基酮等酮類;乙酸乙酯、乙酸異丙酯等酯類;四氫呋喃等。 As the above-mentioned organic solvent, there is no particular limitation as long as it is an organic solvent that can dissolve the above-mentioned antistatic agent. For example, it can be: lower alcohols such as methanol, ethanol, propanol, isopropanol, butanol, etc. ; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, etc.; esters such as ethyl acetate, isopropyl acetate, etc.; tetrahydrofuran, etc.
相對於高密度聚乙烯樹脂100重量份,上述通式(1)所表示之供體-受體系分子化合物型抗靜電劑之添加量一般較佳為0.01~1.0重量份。 Relative to 100 parts by weight of high-density polyethylene resin, the amount of the donor-acceptor system molecular compound type antistatic agent represented by the above general formula (1) is generally preferably 0.01~1.0 parts by weight.
其次,參照圖式對本發明之光罩容器進行說明。圖1係表示本發明之光罩容器之一例之概略剖視圖。圖中,1為容器本體,2為蓋體。容器本體1及蓋體2皆為箱狀體,藉由使蓋體2覆蓋於容器本體1上而形成光罩基板收納部3。4、4......為光罩基板支持固定部,形成於容器本體1及蓋體2之光罩基板收納部3側,以蓋體2覆蓋於容器本體1上時,容器本體1之光罩基板支持固定部4與蓋體2之光罩基板支持固定部4對向之方式形成。再者,5為把手部。 Next, the photomask container of the present invention is described with reference to the drawings. FIG. 1 is a schematic cross-sectional view showing an example of the photomask container of the present invention. In the figure, 1 is a container body, and 2 is a cover body. The container body 1 and the cover body 2 are both box-shaped bodies, and a photomask substrate storage portion 3 is formed by covering the cover body 2 on the container body 1. 4, 4... are photomask substrate support and fixing portions, which are formed on the sides of the photomask substrate storage portion 3 of the container body 1 and the cover body 2, and are formed in a manner that when the cover body 2 covers the container body 1, the photomask substrate support and fixing portion 4 of the container body 1 and the photomask substrate support and fixing portion 4 of the cover body 2 are opposite to each other. Furthermore, 5 is a handle portion.
為了將光罩基板6收納、固定於上述光罩容器中,例如,將卸除了蓋體2之容器本體1水平放置,將光罩基板6載置於容器本體1之光罩基板支持固定部4上。然後,以形成光罩基板收納部3之方式載置蓋體2,並且藉由容器本體1之光罩基板支持固定部4與蓋體2之光罩基板支持固定部4夾持、固定光罩基板6。最後,利用合成樹脂製帶狀體、金屬製帶狀體等帶狀體進行捆束固定,或利用搭扣、棘輪扣鎖等固定治具等進行固定。 In order to store and fix the photomask substrate 6 in the above-mentioned photomask container, for example, the container body 1 with the cover 2 removed is placed horizontally, and the photomask substrate 6 is placed on the photomask substrate support and fixing portion 4 of the container body 1. Then, the cover 2 is placed in a manner to form the photomask substrate storage portion 3, and the photomask substrate 6 is clamped and fixed by the photomask substrate support and fixing portion 4 of the container body 1 and the photomask substrate support and fixing portion 4 of the cover 2. Finally, it is bundled and fixed using a belt-shaped body such as a synthetic resin belt-shaped body or a metal belt-shaped body, or fixed using a fixing fixture such as a buckle or a ratchet buckle.
於輸送收納有上述光罩基板6之光罩容器1時,可直接以水平放置狀態進行輸送,亦可於光罩容器1安裝腳輪,以腳輪位於下側之方式立起, 以光罩基板6豎立之狀態進行輸送。 When transporting the mask container 1 containing the above-mentioned mask substrate 6, it can be directly transported in a horizontal position, or casters can be installed on the mask container 1 and the mask substrate 6 can be transported in a vertical position with the casters at the bottom.
圖2係表示本發明之光罩容器之容器本體1之一例的俯視圖,圖3為圖2中之A-A剖視圖,圖4為圖2中之B-B剖視圖。圖中,1為容器本體,係包含大致平板狀之基部11、及自基部11之端部沿大致直角方向設置之側壁部12的箱狀體。基部11包含內壁111及外壁112,係藉由在其等之間部分地形成中空部113而設置肋部13之2層中空構造體。再者,基部11亦可為內壁111與外壁112密接之2層構造體。 FIG. 2 is a top view showing an example of a container body 1 of the photomask container of the present invention, FIG. 3 is an A-A cross-sectional view in FIG. 2, and FIG. 4 is a B-B cross-sectional view in FIG. 2. In the figure, 1 is a container body, which is a box-shaped body including a substantially flat base 11 and a side wall 12 provided along a substantially right angle direction from the end of the base 11. The base 11 includes an inner wall 111 and an outer wall 112, and is a two-layer hollow structure in which a rib 13 is provided by partially forming a hollow portion 113 therebetween. Furthermore, the base 11 may also be a two-layer structure in which the inner wall 111 and the outer wall 112 are in close contact.
又,側壁部12包含內壁111及外壁112,係於其等之間形成有中空部113之2層中空構造體,為了輕量化及補強而較基部之厚度厚。 In addition, the side wall portion 12 includes an inner wall 111 and an outer wall 112, and is a two-layer hollow structure with a hollow portion 113 formed therebetween. For the purpose of lightness and reinforcement, the thickness is thicker than the base portion.
又,5、5......為供手指插入以使光罩容器移動之把手部,於側壁部12之上端部形成有複數個。把手部5係於側壁部12之上端部向側方延伸設置之側緣部設置貫通孔而形成。 Furthermore, 5, 5...are handles for inserting fingers to move the photomask container, and a plurality of handles are formed at the upper end of the side wall 12. The handle 5 is formed by providing a through hole at the side edge extending laterally from the upper end of the side wall 12.
圖中,4、4......係供載置並支持固定光罩基板之包含烯烴系樹脂、ABS(acrylonitrile-butadiene-styrene,丙烯腈-丁二烯-苯乙烯)樹脂等製造之實心柱狀體的光罩基板支持固定部,由螺栓41固定於基部11之光罩基板收納部3側。 In the figure, 4, 4... are solid columnar photomask substrate support and fixing parts made of olefin resin, ABS (acrylonitrile-butadiene-styrene) resin, etc. for mounting and supporting the photomask substrate, which are fixed to the photomask substrate storage part 3 side of the base 11 by bolts 41.
再者,42係介存於螺栓41與基部11之間並使兩者緊密固定之墊圈,43係固定於光罩基板支持固定部4之下方內部並藉由與螺栓41螺合而將基 部11與光罩基板收納部3固定之嵌入式螺母。上述光罩基板支持固定部4亦可與先前公知之任意支持用保持機構、定位用保持機構(例如參照專利文獻1、2)等併用。 Furthermore, 42 is a washer interposed between the bolt 41 and the base 11 to tightly fix the two, and 43 is an embedded nut fixed to the lower inner part of the photomask substrate support and fixing part 4 and screwed with the bolt 41 to fix the base 11 and the photomask substrate storage part 3. The above-mentioned photomask substrate support and fixing part 4 can also be used in conjunction with any previously known supporting holding mechanism, positioning holding mechanism (for example, refer to patent documents 1 and 2).
圖中,7係用於使光罩基板收納部3內部與外部連通,使內外之氣體能夠移動,而使內外之溫度、濕度、壓力等保持相同的排氣部。排氣部7以於基部11之內壁111及外壁112形成階差部72之方式穿設有貫通孔71,於階差部72以堵塞貫通孔71之方式積層有過濾器73,過濾器73由環狀之固定具74固定形成於基部11。 In the figure, 7 is an exhaust part used to connect the inside and outside of the photomask substrate storage part 3 so that the gas inside and outside can move and keep the temperature, humidity, pressure, etc. inside and outside the same. The exhaust part 7 is provided with a through hole 71 in a manner of forming a step part 72 on the inner wall 111 and the outer wall 112 of the base 11, and a filter 73 is stacked on the step part 72 in a manner of blocking the through hole 71. The filter 73 is fixed to the base 11 by a ring-shaped fixture 74.
藉由形成上述排氣部7,光罩基板收納部3內部與外部之內外氣體連通,光罩基板收納部3內部與外部之氣壓、濕度及溫度不存在差異,而可抑制於利用飛機輸送時,因氣壓差而使光罩容器變形、受到破壞或者因溫度差而於光罩基板收納部3內產生結露。 By forming the exhaust portion 7, the inside and outside gases of the photomask substrate storage portion 3 are connected, and there is no difference in air pressure, humidity and temperature between the inside and outside of the photomask substrate storage portion 3, which can prevent the mask container from being deformed or damaged due to air pressure difference or condensation from occurring in the photomask substrate storage portion 3 due to temperature difference when transported by airplane.
圖中,8係用於視察光罩基板收納部3內部以觀察所收納之光罩基板6之視窗部。視窗部8係藉由在基部11穿設貫通孔並嵌入聚碳酸酯樹脂、ABS樹脂等透明樹脂板、玻璃板等而形成。 In the figure, 8 is a window for inspecting the inside of the photomask substrate storage part 3 to observe the stored photomask substrate 6. The window part 8 is formed by drilling a through hole in the base 11 and embedding a transparent resin plate such as polycarbonate resin, ABS resin, or a glass plate.
圖中,9係用於使蓋體2覆蓋於容器本體1上而形成光罩基板收納部3時將光罩基板收納部3牢固地密封之O形環,O形環9嵌入至容器本體1之側壁部12之上表面上形成之凹槽中。O形環9較佳為包含矽系橡膠、氟橡膠、胺基甲酸酯系橡膠、降烯系橡膠等彈性樹脂。 In the figure, 9 is an O-ring used to firmly seal the photomask substrate storage part 3 when the cover 2 is covered on the container body 1 to form the photomask substrate storage part 3. The O-ring 9 is embedded in a groove formed on the upper surface of the side wall part 12 of the container body 1. The O-ring 9 is preferably made of silicone rubber, fluoro rubber, urethane rubber, or decompression rubber. Elastic resins such as olefin rubber.
圖中,13、13......係為了補強容器本體1而設於基部11之肋部。肋部13係藉由在內壁111與外壁112之間設置中空部113而形成。再者,肋部13可藉由使內壁111或/及外壁112彎曲來形成中空部113或不形成中空部113而形成。又,肋部13較佳為設置多條,亦可設於側壁部12。 In the figure, 13, 13... are ribs provided on the base 11 to reinforce the container body 1. The rib 13 is formed by providing a hollow portion 113 between the inner wall 111 and the outer wall 112. Furthermore, the rib 13 can be formed by bending the inner wall 111 and/or the outer wall 112 to form the hollow portion 113 or without forming the hollow portion 113. In addition, the rib 13 is preferably provided in multiple strips, and can also be provided on the side wall portion 12.
圖中,14、14......係供設置固定治具(例如搭扣、棘輪扣鎖等)且設於側壁部12之上端部附近之缺口部,上述固定治具用於將使蓋體2覆蓋於容器本體1上而形成光罩基板收納部之光罩容器密閉固定。又,將光罩容器密閉固定時,可藉由合成樹脂或金屬製之繩狀體、帶狀體進行捆束。 In the figure, 14, 14... are notches provided near the upper end of the side wall 12 for setting a fixing fixture (such as a buckle, a ratchet buckle, etc.). The fixing fixture is used to seal and fix the photomask container that covers the cover 2 on the container body 1 to form a photomask substrate storage portion. When the photomask container is sealed and fixed, it can be bundled by a rope-like body or a belt-like body made of synthetic resin or metal.
圖5係表示本發明之光罩容器之容器本體之不同例之俯視圖,圖6係圖5中之C-C剖視圖。1為容器本體,容器本體1係藉由吹塑成形而一體成形,且包含大致平板狀之基部11、及自基部11之端部沿大致直角方向設置之側壁部12的箱狀體,並且基部11及側壁部12為包含內壁111及外壁112之局部中空之2層中空構造體。 FIG. 5 is a top view showing different examples of the container body of the photomask container of the present invention, and FIG. 6 is a C-C cross-sectional view in FIG. 5. 1 is a container body, which is integrally formed by blow molding and includes a substantially flat base 11 and a box-shaped body with a side wall 12 provided along a substantially right angle from the end of the base 11, and the base 11 and the side wall 12 are partially hollow two-layered hollow structures including an inner wall 111 and an outer wall 112.
圖中,12係自基部11之端部沿大致直角方向設置之側壁部,側壁部12為利用內壁111及外壁112於內部形成中空部113之中空2層構造體。側壁部12由於為中空2層構造體,因此較基部11之厚度厚,於側壁部12之上表面形成有凹槽,於凹槽中嵌入有O形環9。 In the figure, 12 is a side wall portion provided along a substantially right angle direction from the end of the base portion 11. The side wall portion 12 is a hollow two-layer structure body that uses an inner wall 111 and an outer wall 112 to form a hollow portion 113 inside. Since the side wall portion 12 is a hollow two-layer structure body, it is thicker than the base portion 11. A groove is formed on the upper surface of the side wall portion 12, and an O-ring 9 is embedded in the groove.
圖中,4、4......係供載置並支持固定光罩基板之光罩基板支持固定 部。光罩基板支持固定部4係使基部11之內壁111及/或側壁部12之內壁111向光罩基板收納部側(上方或內側)變形,於基部11及側壁部12之內壁111與外壁112之間形成中空部113,而與基部11及側壁部12一體成形。 In the figure, 4, 4... are the photomask substrate support and fixing parts for placing and supporting the photomask substrate. The photomask substrate support and fixing part 4 deforms the inner wall 111 of the base 11 and/or the inner wall 111 of the side wall 12 toward the side (upper or inner side) of the photomask substrate storage part, and forms a hollow part 113 between the inner wall 111 and the outer wall 112 of the base 11 and the side wall 12, and is formed integrally with the base 11 and the side wall 12.
光罩基板支持固定部4藉由中空部113形成內側較低之階差部。階差部之內側較低,較低之階差部之上表面成為光罩基板載置部44,階差部之外側較高之側面成為橫向定位部45。即,保存、輸送之光罩基板其端部載置於光罩基板載置部44、44......上,且藉由橫向定位部45、45......而被定位並被牢固地固定。 The photomask substrate support and fixing part 4 forms a step portion with a lower inner side through the hollow part 113. The inner side of the step portion is lower, and the upper surface of the lower step portion becomes the photomask substrate mounting portion 44, and the higher side surface of the step portion becomes the lateral positioning portion 45. That is, the end of the photomask substrate to be stored and transported is placed on the photomask substrate mounting portion 44, 44..., and is positioned and firmly fixed by the lateral positioning portions 45, 45...
上述容器本體1較佳為藉由吹塑成形法成形。所謂吹塑成形法,係將熱塑性樹脂以熔融狀態擠出成形,成形出筒狀之型坯,接著將所獲得之型坯供給至成形模具,對型坯內吹送氣體並且對成形模具進行鎖模而製造成形體的方法。 The container body 1 is preferably formed by blow molding. The so-called blow molding method is a method of extruding a thermoplastic resin in a molten state to form a cylindrical parison, then supplying the obtained parison to a forming mold, blowing gas into the parison and locking the forming mold to form a shape.
藉由利用吹塑成形法進行成形,能夠一體地且容易地成形出大型之容器本體1,所獲得之容器本體1為內壁及外壁之2層構造,局部具有中空部,並且無縫地一體成形,輕量且機械強度優異。 By using the blow molding method, a large container body 1 can be easily formed in one piece. The obtained container body 1 is a two-layer structure of an inner wall and an outer wall, partially has a hollow part, and is seamlessly formed in one piece. It is lightweight and has excellent mechanical strength.
蓋體2只要為作為容器本體1之蓋發揮功能者即可,並無特別限定,但若蓋體2與容器本體1為相同形狀,則如圖1所示,能夠容易地將光罩基板6收納、保持於光罩基板收納部3內,因此較佳。即,蓋體較佳為包含熔體流動速率(MFR)為0.6(g/10分鐘)以下之高密度聚乙烯樹脂,且包含大致 平板狀之基部、及自基部之端部垂直設置之側壁部的箱狀體,並且為包含內壁及外壁之2層構造體。 The cover body 2 is not particularly limited as long as it functions as a cover of the container body 1. However, if the cover body 2 is the same shape as the container body 1, as shown in FIG1, the photomask substrate 6 can be easily stored and held in the photomask substrate storage portion 3, which is preferred. That is, the cover body is preferably a box-shaped body including a high-density polyethylene resin with a melt flow rate (MFR) of 0.6 (g/10 minutes) or less, and including a roughly flat base and a side wall portion vertically arranged from the end of the base, and is a two-layer structure including an inner wall and an outer wall.
又,為了使光罩基板收納部內不帶電,可於基部之內壁(光罩基板收納部側)積層防靜電片材、防靜電成形體等,亦可塗佈、積層防靜電塗料。 In addition, in order to prevent the photomask substrate storage part from being charged, antistatic sheets, antistatic molded bodies, etc. can be layered on the inner wall of the base (the side of the photomask substrate storage part), or antistatic coatings can be applied or layered.
本發明之光罩容器輕量且機械強度優異,能夠牢固地保持光罩基板,能夠於不令光罩基板表面附著污物(微細粒子)或者不令光罩基板變形之情況下進行輸送。即便於減壓下或低溫下進行輸送,亦不會使光罩基板或光罩容器負擔不必要之應力,可抑制光罩容器之光罩基板收納部之結露,潔淨度優異,故適宜利用飛機進行空運,因此適宜用作保存、輸送光罩時之光罩容器。 The photomask container of the present invention is lightweight and has excellent mechanical strength. It can firmly hold the photomask substrate and can be transported without causing dirt (fine particles) to adhere to the surface of the photomask substrate or without causing the photomask substrate to deform. Even when transported under reduced pressure or low temperature, the photomask substrate or the photomask container will not bear unnecessary stress. It can suppress condensation in the photomask substrate storage part of the photomask container and has excellent cleanliness, so it is suitable for air transportation by airplane. Therefore, it is suitable for use as a photomask container for storing and transporting masks.
Claims (11)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020140441 | 2020-08-21 | ||
| JP2020-140441 | 2020-08-21 |
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| Publication Number | Publication Date |
|---|---|
| TW202212460A TW202212460A (en) | 2022-04-01 |
| TWI859464B true TWI859464B (en) | 2024-10-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW110130911A TWI859464B (en) | 2020-08-21 | 2021-08-20 | Mask container |
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| Country | Link |
|---|---|
| JP (1) | JP7333925B2 (en) |
| CN (1) | CN116097168A (en) |
| TW (1) | TWI859464B (en) |
| WO (1) | WO2022039254A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200700925A (en) * | 2004-11-24 | 2007-01-01 | Entegris Inc | Photomask container |
| JP2007091296A (en) * | 2005-09-29 | 2007-04-12 | Hoya Corp | Mask blank storage container, mask blank storage method and mask blank storage body |
| US7607543B2 (en) * | 2005-02-27 | 2009-10-27 | Entegris, Inc. | Reticle pod with isolation system |
| CN104321132A (en) * | 2012-03-30 | 2015-01-28 | 三菱丽阳株式会社 | Composite hollow fiber membrane and hollow fiber membrane module |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3944699B2 (en) * | 2001-11-06 | 2007-07-11 | 信越化学工業株式会社 | Substrate storage container |
| US7309460B2 (en) * | 2004-11-24 | 2007-12-18 | Entegris, Inc. | Photomask container |
| RU2640774C2 (en) * | 2013-10-21 | 2018-01-11 | Тбм Ко., Лтд. | Method of manufacturing filler-containing polymer sheet |
| JP6828276B2 (en) * | 2016-06-09 | 2021-02-10 | 大日本印刷株式会社 | Thermosetting resin film and its manufacturing method, laminate and packaging material |
| WO2019235399A1 (en) * | 2018-06-04 | 2019-12-12 | Sekisui Fuller Company, Ltd. | Thermoplastic resin film, meltable bag, and packaged hot-melt adhesive |
-
2021
- 2021-08-20 TW TW110130911A patent/TWI859464B/en active
- 2021-08-20 JP JP2022544017A patent/JP7333925B2/en active Active
- 2021-08-20 CN CN202180050837.5A patent/CN116097168A/en active Pending
- 2021-08-20 WO PCT/JP2021/030541 patent/WO2022039254A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200700925A (en) * | 2004-11-24 | 2007-01-01 | Entegris Inc | Photomask container |
| US7607543B2 (en) * | 2005-02-27 | 2009-10-27 | Entegris, Inc. | Reticle pod with isolation system |
| JP2007091296A (en) * | 2005-09-29 | 2007-04-12 | Hoya Corp | Mask blank storage container, mask blank storage method and mask blank storage body |
| CN104321132A (en) * | 2012-03-30 | 2015-01-28 | 三菱丽阳株式会社 | Composite hollow fiber membrane and hollow fiber membrane module |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2022039254A1 (en) | 2022-02-24 |
| JPWO2022039254A1 (en) | 2022-02-24 |
| CN116097168A (en) | 2023-05-09 |
| KR20230049743A (en) | 2023-04-13 |
| JP7333925B2 (en) | 2023-08-28 |
| TW202212460A (en) | 2022-04-01 |
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