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TWI858471B - Burners and boilers - Google Patents

Burners and boilers Download PDF

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Publication number
TWI858471B
TWI858471B TW111149481A TW111149481A TWI858471B TW I858471 B TWI858471 B TW I858471B TW 111149481 A TW111149481 A TW 111149481A TW 111149481 A TW111149481 A TW 111149481A TW I858471 B TWI858471 B TW I858471B
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Taiwan
Prior art keywords
nozzle
burner
ammonia
supply pipe
fuel supply
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TW111149481A
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Chinese (zh)
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TW202338259A (en
Inventor
冨永幸洋
髙山明正
嶺聡彦
山內康弘
竹井康裕
甘利猛
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日商三菱重工業股份有限公司
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements or dispositions of combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C1/00Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in a carrier gas or air
    • F23C1/12Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in a carrier gas or air gaseous and pulverulent fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D17/00Burners for combustion simultaneously or alternately of gaseous or liquid or pulverulent fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/18Arrangement or mounting of grates or heating means
    • F24H9/1809Arrangement or mounting of grates or heating means for water heaters
    • F24H9/1832Arrangement or mounting of combustion heating means, e.g. grates or burners
    • F24H9/1836Arrangement or mounting of combustion heating means, e.g. grates or burners using fluid fuel

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion Of Fluid Fuel (AREA)

Abstract

燃燒器,具備:第1噴嘴,其成為於軸線方向延伸的筒狀,具有可將一次空氣與煤粉的混合流體予以噴出的前端開口;以及第2噴嘴,其在第1噴嘴內配置成沿著軸線方向延伸,具有位在比第1噴嘴的前端開口還靠混合流體的上游側且可噴出氨的前端部。The burner comprises: a first nozzle, which is cylindrical and extends in an axial direction and has a front end opening for ejecting a mixed fluid of primary air and pulverized coal; and a second nozzle, which is arranged in the first nozzle to extend in the axial direction and has a front end portion located on the upstream side of the mixed fluid than the front end opening of the first nozzle and can eject ammonia.

Description

燃燒器及鍋爐Burners and boilers

本發明關於燃燒器及鍋爐。The present invention relates to a burner and a boiler.

發電用鍋爐等之大型的鍋爐,具有呈中空形狀且於鉛直方向設置的火爐,在該火爐壁使複數個燃燒器沿著火爐的周邊方向來配設。且,大型的鍋爐,在火爐的鉛直方向上方連結有煙道,在該煙道配置有用來產生蒸氣的熱交換器。然後,燃燒器對火爐內噴射燃料與空氣(氧化氣體)的混合氣體藉此形成火炎,並產生燃燒氣體流往煙道。在流動有燃燒氣體的區域設置熱交換器,將在構成熱交換器的傳熱管內流動之水或蒸氣予以加熱來產生過熱蒸氣。Large boilers such as power generation boilers have a hollow furnace arranged in the vertical direction, and a plurality of burners are arranged on the furnace wall along the circumference of the furnace. In addition, a large boiler is connected to a flue above the vertical direction of the furnace, and a heat exchanger for generating steam is arranged in the flue. Then, the burner sprays a mixed gas of fuel and air (oxidizing gas) into the furnace to form a flame, and the generated combustion gas flows into the flue. A heat exchanger is set in the area where the combustion gas flows, and the water or steam flowing in the heat transfer tube constituting the heat exchanger is heated to generate superheated steam.

在此,近年來除了以往的化石燃料以外,關於將氨作為燃料來使用的燃燒器之研究開發有所進展。作為適用這種燃燒器之鍋爐的具體例,已知有下述專利文獻1所記載者。在該鍋爐,是各自獨立地複數設置使化石燃料燃燒的燃燒器與使氨燃燒的燃燒器。 [先前技術文獻] [專利文獻] In recent years, research and development of burners that use ammonia as fuel in addition to conventional fossil fuels has been progressing. As a specific example of a boiler that uses such a burner, the one described in the following patent document 1 is known. In this boiler, a plurality of burners that burn fossil fuels and burn ammonia are independently provided. [Prior art document] [Patent document]

[專利文獻1]日本特開2019-178823號公報[Patent Document 1] Japanese Patent Application Publication No. 2019-178823

[發明所欲解決之問題][The problem the invention is trying to solve]

但是,可設置在鍋爐的燃燒器之總數有限,故如上述般設置以氨為燃料的燃燒器時,以化石燃料為燃料的燃燒器之數量會減少。其結果,例如在無法得到氨的狀況下,有著燃燒器全體的輸出會減少該份量的課題。However, the total number of burners that can be installed in a boiler is limited, so when burners that use ammonia as fuel are installed as described above, the number of burners that use fossil fuels will decrease. As a result, if ammonia is not available, for example, there is a problem that the output of the entire burner will decrease by that amount.

本發明是為了解決上述課題而完成者,其目的在於提供可將氨與化石燃料有效率地作為燃料來使用的燃燒器、及鍋爐。 [解決問題之技術手段] The present invention is completed to solve the above-mentioned problem, and its purpose is to provide a burner and a boiler that can efficiently use ammonia and fossil fuels as fuels. [Technical means for solving the problem]

為了解決上述課題,本發明的燃燒器,具備:第1噴嘴,其成為於軸線方向延伸的筒狀,具有可將一次空氣與煤粉的混合流體予以噴出的前端開口;以及第2噴嘴,其在前述第1噴嘴內配置成沿著前述軸線方向延伸,具有位在比前述第1噴嘴的前端開口還靠前述混合流體的上游側且可噴出氨的前端部。In order to solve the above-mentioned problem, the burner of the present invention comprises: a first nozzle, which is cylindrical and extends in the axial direction, and has a front end opening for spraying a mixed fluid of primary air and pulverized coal; and a second nozzle, which is arranged in the aforementioned first nozzle to extend along the aforementioned axial direction, has a front end portion located on the upstream side of the aforementioned mixed fluid than the front end opening of the aforementioned first nozzle and can spray ammonia.

本發明的鍋爐,具備上述燃燒器與設有該燃燒器的火爐。 [發明之效果] The boiler of the present invention comprises the burner and a furnace equipped with the burner. [Effects of the invention]

根據本發明,可提供可將氨與化石燃料有效率地作為燃料來使用的燃燒器、及鍋爐。According to the present invention, a burner and a boiler that can efficiently use ammonia and fossil fuel as fuel can be provided.

以下,針對本發明之一實施形態,參照圖式來說明。又,本發明不限定於該實施形態,且,實施形態有複數的情況時,亦包含組合各實施形態的構造。在以下的說明,上或上方表示鉛直方向上側,下或下方表示鉛直方向下側,這鉛直方向並不嚴密,含有誤差。Hereinafter, one embodiment of the present invention will be described with reference to the drawings. Furthermore, the present invention is not limited to the embodiment, and when there are multiple embodiments, the invention also includes a structure combining the embodiments. In the following description, "up" or "above" indicates the upper side in the lead vertical direction, and "down" or "below" indicates the lower side in the lead vertical direction. This lead vertical direction is not strict and contains errors.

圖1,是表示本實施形態之將固體燃料作為主燃料之鍋爐的概略構造圖。FIG. 1 is a schematic structural diagram showing a boiler using solid fuel as a main fuel according to the present embodiment.

(鍋爐的構造) 本實施形態的鍋爐10,是將粉碎固體燃料之後的微粉燃料藉由燃燒器來燃燒,可藉由該燃燒所發生的熱來與供水或蒸氣進行熱交換而產生過熱蒸氣。作為固體燃料,使用有生質燃料或煤炭等。 (Structure of boiler) The boiler 10 of this embodiment burns the fine powder fuel after crushing the solid fuel through a burner, and the heat generated by the combustion can be used to exchange heat with water or steam to generate superheated steam. Biomass fuel or coal, etc. are used as solid fuel.

鍋爐10,具有:火爐11、燃燒裝置20、燃燒氣體通路12。火爐11,是呈四角筒的中空形狀且沿著鉛直方向來設置。構成火爐11之內壁面的火爐壁101,是由複數個傳熱管與將傳熱管彼此予以連接的連管片所構成,將因微粉燃料的燃燒而產生的熱與流通於傳熱管之內部的水或蒸氣進行熱交換來回收,並抑制火爐壁101的溫度上升。The boiler 10 comprises a furnace 11, a combustion device 20, and a combustion gas passage 12. The furnace 11 is in the shape of a square tube and is arranged along the lead vertical direction. The furnace wall 101 constituting the inner wall surface of the furnace 11 is composed of a plurality of heat transfer tubes and connecting tube segments connecting the heat transfer tubes to each other, and the heat generated by the combustion of the pulverized fuel is exchanged with water or steam flowing inside the heat transfer tubes to recover the heat, and the temperature rise of the furnace wall 101 is suppressed.

燃燒裝置20,設置在火爐11的下部區域。在本實施形態,燃燒裝置20,具有安裝在火爐壁101的複數個燃燒器21A、21B、21C、21D、21E、21F(以下有統一記載為「燃燒器21」的情況)。燃燒器21,是將沿著火爐11的周邊方向以均等間隔來配設者(例如,在四角形的火爐11的各角落部所設置之四個)作為一組,而沿著鉛直方向配置複數段。又,在圖1,為了圖示的方便,僅記載一組燃燒器之中的兩個,對各組標上符號21A、21B、21C、21D、21E、21F。火爐的形狀或燃燒器的段數、每段的燃燒器數量、燃燒器的配置等,並不限定於該實施形態。The combustion device 20 is installed in the lower area of the furnace 11. In the present embodiment, the combustion device 20 has a plurality of burners 21A, 21B, 21C, 21D, 21E, and 21F (hereinafter collectively referred to as "burners 21") installed on the furnace wall 101. The burners 21 are arranged at equal intervals along the circumference of the furnace 11 (for example, four burners are arranged at each corner of the quadrilateral furnace 11) as a group, and a plurality of sections are arranged along the vertical direction. In FIG. 1, for the convenience of illustration, only two burners in a group are shown, and each group is marked with the symbols 21A, 21B, 21C, 21D, 21E, and 21F. The shape of the furnace, the number of burner stages, the number of burners per stage, the arrangement of the burners, etc. are not limited to this embodiment.

燃燒器21A、21B、21C、21D、21E、21F,是各自透過複數個微粉燃料供給管22A、22B、22C、22D、22E、22F(以下有統一記載為「微粉燃料供給管22」的情況),來連結於複數個磨碎機(粉碎機)31A、31B、31C、31D、31E、31F(以下有統一記載為「磨碎機31」的情況)。磨碎機31,例如是在內部將粉碎平台(圖示省略)支撐成可驅動旋轉,在粉碎平台的上方使複數個粉碎輥(圖示省略)與粉碎平台的旋轉連動而被支撐成可旋轉的豎輥磨碎機。因粉碎輥與粉碎平台的協同運作而粉碎後的固體燃料,是藉由供給至磨碎機31的一次空氣(搬運用氣體、氧化性氣體)來搬運至磨碎機31所具備的分級機(圖示省略)。在分級機,是分級成適合燃燒器21之燃燒之粒徑以下的微粉燃料、比該粒徑還大的團塊燃料。微粉燃料,是通過分級機來與一次空氣一起透過微粉燃料供給管22被供給至燃燒器21。沒通過分級機的團塊燃料,是在磨碎機31的內部因自身重量而落下至粉碎平台上,再次粉碎。The burners 21A, 21B, 21C, 21D, 21E, and 21F are connected to a plurality of grinders (crushers) 31A, 31B, 31C, 31D, 31E, and 31F (hereinafter collectively referred to as "crushers 31") through a plurality of powder fuel supply pipes 22A, 22B, 22C, 22D, 22E, and 22F (hereinafter collectively referred to as "powder fuel supply pipes 22"). The grinder 31 is, for example, a vertical roller grinder that supports a grinding platform (not shown) internally so as to be rotatable and supports a plurality of grinding rollers (not shown) above the grinding platform so as to be rotatable in conjunction with the rotation of the grinding platform. The solid fuel crushed by the coordinated operation of the crushing roller and the crushing platform is transported to the classifier (not shown) provided in the grinder 31 by the primary air (transportation gas, oxidizing gas) supplied to the grinder 31. In the classifier, the fuel is classified into fine powder fuel with a particle size below that suitable for combustion in the burner 21 and agglomerate fuel with a particle size larger than the particle size. The fine powder fuel is supplied to the burner 21 through the fine powder fuel supply pipe 22 together with the primary air through the classifier. The agglomerate fuel that has not passed through the classifier falls onto the crushing platform due to its own weight inside the grinder 31 and is crushed again.

此外,燃燒器21A、21B、21C、21D、21E、21F,透過氨燃料供給管51,連結於氨供給源52。氨燃料供給管51,是獨立於微粉燃料供給管22,且各自個別地設置。且,在圖1之例,是使複數個氨燃料供給管51從單一的氨供給源52延伸,但亦可在各個氨燃料供給管51設有氨供給源52。燃燒器21的詳細構造待留後述。In addition, the burners 21A, 21B, 21C, 21D, 21E, and 21F are connected to an ammonia supply source 52 through an ammonia fuel supply pipe 51. The ammonia fuel supply pipe 51 is independent of the powder fuel supply pipe 22 and is provided separately. In the example of FIG. 1 , a plurality of ammonia fuel supply pipes 51 extend from a single ammonia supply source 52, but an ammonia supply source 52 may be provided in each ammonia fuel supply pipe 51. The detailed structure of the burner 21 will be described later.

在燃燒器21的安裝位置之火爐11的爐外側,設有風箱(調風器)23,在該風箱23連結有風道(空氣通道)24的一端部。在風道24的另一端部,連結有吹入送風機(FDF:Forced Draft Fan)32。從吹入送風機32供給的空氣,是以設置在風道24的空氣預熱器42來加熱(詳細待後述),透過風箱23來作為二次空氣(燃燒用空氣、氧化性氣體)供給至燃燒器21,而導引至火爐11的內部。A wind box (air regulator) 23 is provided outside the furnace 11 where the burner 21 is installed, and one end of an air duct (air passage) 24 is connected to the wind box 23. A forced draft fan (FDF: Forced Draft Fan) 32 is connected to the other end of the air duct 24. The air supplied from the forced draft fan 32 is heated by an air preheater 42 provided in the air duct 24 (details to be described later), and is supplied to the burner 21 as secondary air (combustion air, oxidizing gas) through the wind box 23, and then guided to the inside of the furnace 11.

燃燒氣體通路12,連結於火爐11之鉛直方向上部。在燃燒氣體通路12,作為用來回收燃燒氣體之熱的熱交換器,設有:過熱器102A、102B、102C(以下,有統稱為「過熱器102」的情況)、再熱器103A、103B(以下,有統稱為「再熱器103」的情況)、省煤器104,使在火爐11產生的燃燒氣體與在各熱交換器的內部流通的供水或蒸氣之間進行熱交換。又,各熱交換器的配置或形狀,並不限定於圖1所記載的形態。The combustion gas passage 12 is connected to the upper part of the furnace 11 in the vertical direction. In the combustion gas passage 12, as heat exchangers for recovering the heat of the combustion gas, superheaters 102A, 102B, 102C (hereinafter, collectively referred to as "superheaters 102"), reheaters 103A, 103B (hereinafter, collectively referred to as "reheaters 103"), and an economizer 104 are provided, so that heat is exchanged between the combustion gas generated in the furnace 11 and the feed water or steam flowing inside each heat exchanger. In addition, the arrangement and shape of each heat exchanger are not limited to the form described in FIG. 1.

在燃燒氣體通路12的下游側,連結有將在熱交換器進行過熱回收的燃燒氣體予以排出的煙道13。煙道13,在與風道24之間設有空氣預熱器(空氣加熱器)42,而在流動於風道24的空氣與在流動於煙道13的燃燒氣體之間進行熱交換,將供給至磨碎機31的一次空氣或供給至燃燒器21的二次空氣予以加熱,藉此從與水或蒸氣進行熱交換後的燃燒氣體進一步進行熱回收。A flue 13 is connected to the downstream side of the combustion gas passage 12 to discharge the combustion gas that has been overheated in the heat exchanger. The flue 13 is provided with an air preheater (air heater) 42 between the flue 13 and the air duct 24, and heat is exchanged between the air flowing in the air duct 24 and the combustion gas flowing in the flue 13, thereby heating the primary air supplied to the grinder 31 or the secondary air supplied to the burner 21, thereby further recovering heat from the combustion gas after the heat exchange with water or steam.

且,在煙道13,在比空氣預熱器42還上游側的位置,設有脫硝裝置43亦可。脫硝裝置43,將具有將氨、尿素水等之氮氧化物予以還原之作用的還原劑,供給至流通於煙道13內的燃燒氣體,使供給了還原劑之燃燒氣體中的氮氧化物(NOx)與還原劑的反應,藉由設置在脫硝裝置43內之脫硝觸媒的觸媒作用來促進,藉此去除、降低燃燒氣體中的氮氧化物。 在煙道13之比空氣預熱器42還下游側,連結有氣體通道41。在氣體通道41,設有:將燃燒氣體中之灰等予以去除的電集塵機等之集塵裝置44或將硫氧化物予以除去的脫硫裝置46等之環境裝置、或是將排氣予以導引至該等之環境裝置的吸引送風機(IDF:Induced Draft Fan)45。氣體通道41的下游端部,連結於煙囪47,將被環境裝置處理過的燃燒氣體,作為排氣而排出系統外。 Furthermore, a denitrification device 43 may be provided in the flue 13 at a position upstream of the air preheater 42. The denitrification device 43 supplies a reducing agent having the function of reducing nitrogen oxides such as ammonia and urea water to the combustion gas flowing in the flue 13, so that the reaction between nitrogen oxides (NOx) in the combustion gas supplied with the reducing agent and the reducing agent is promoted by the catalytic action of the denitrification catalyst provided in the denitrification device 43, thereby removing and reducing nitrogen oxides in the combustion gas. A gas channel 41 is connected to the flue 13 at a position downstream of the air preheater 42. In the gas passage 41, there is a dust collecting device 44 such as an electric dust collector for removing ash from the combustion gas, or an environmental device such as a desulfurization device 46 for removing sulfur oxides, or an induced draft fan (IDF: Induced Draft Fan) 45 for guiding the exhaust gas to such environmental devices. The downstream end of the gas passage 41 is connected to the chimney 47, and the combustion gas treated by the environmental device is discharged out of the system as exhaust gas.

(燃燒器的構造) 接著,參照圖2與圖3來說明燃燒器21的構造。如該等之圖所示般,燃燒器21具備第1噴嘴61與第2噴嘴62。第1噴嘴61,是成為以軸線O為中心的筒狀。更具體來說,第1噴嘴61,在從軸線O方向觀看時具有矩形環狀的剖面形狀。軸線O,作為一例是沿著實質的水平方向來延伸的虛擬線。第1噴嘴61之軸線O方向一方側的開口,是前端開口63。比該前端開口63還靠軸線O方向另一方側的區域(亦即比前端開口63還內側的區域),是供一次空氣與煤粉之混合流體流動的第1流路64。 (Structure of burner) Next, the structure of the burner 21 is explained with reference to FIG. 2 and FIG. 3. As shown in the figures, the burner 21 has a first nozzle 61 and a second nozzle 62. The first nozzle 61 is cylindrical with the axis O as the center. More specifically, the first nozzle 61 has a rectangular ring-shaped cross-sectional shape when viewed from the axis O direction. The axis O is, for example, a virtual line extending in a substantial horizontal direction. The opening of the first nozzle 61 on one side of the axis O direction is a front end opening 63. The area on the other side of the axis O direction than the front opening 63 (i.e., the area inside the front opening 63) is the first flow path 64 for the mixed fluid of primary air and pulverized coal to flow.

第1流路64,連接於上述微粉燃料供給管22。流入至第1流路64的混合流體,經過前端開口63而噴出至火爐11內。之後,藉由未圖示的點火裝置使混合流體點火,而形成從前端開口63朝向火爐11內延伸的火炎。又,在以下的說明,會將該混合流體之流動方向的上游側簡稱為「上游側」,將其相反之側簡稱為「下游側」。The first flow path 64 is connected to the powder fuel supply pipe 22. The mixed fluid flowing into the first flow path 64 is ejected into the furnace 11 through the front end opening 63. Thereafter, the mixed fluid is ignited by an ignition device (not shown) to form a flame extending from the front end opening 63 toward the furnace 11. In the following description, the upstream side of the flow direction of the mixed fluid will be referred to as the "upstream side", and the opposite side will be referred to as the "downstream side".

在第1噴嘴61之朝向下游側的端面(下游側端面65),形成有作為二次空氣噴出口66的開口。二次空氣噴出口66之上游側的區域,是供二次空氣流動的第2流路68。二次空氣噴出口66,是成為以軸線O為中心的矩形環狀。該二次空氣噴出口66,連通於上述風箱23。從風箱23壓送的二次空氣會從二次空氣噴出口66噴出。使二次空氣混合於火炎,藉此適當調整該火炎的性質(火炎溫度或火炎長度)。An opening serving as a secondary air ejection port 66 is formed on the downstream end face (downstream end face 65) of the first nozzle 61. The upstream region of the secondary air ejection port 66 is a second flow path 68 for the flow of secondary air. The secondary air ejection port 66 is in the shape of a rectangular ring centered on the axis O. The secondary air ejection port 66 is connected to the above-mentioned wind box 23. The secondary air pressed from the wind box 23 is ejected from the secondary air ejection port 66. The secondary air is mixed with the flame, thereby appropriately adjusting the properties of the flame (flame temperature or flame length).

第2噴嘴62,設在第1噴嘴61的第1流路64內。第2噴嘴62,於軸線O方向延伸。且,第2噴嘴62,從軸線O方向觀看時,配置在與呈矩形之前端開口63之重心位置(亦即軸線O上)重疊的位置。第2噴嘴62之上游側的端部,連接於氨燃料供給管51。藉此,從第2噴嘴62噴出作為燃料的氣體氨。又,構成為從第2噴嘴62噴出液體氨亦可。The second nozzle 62 is provided in the first flow path 64 of the first nozzle 61. The second nozzle 62 extends in the direction of the axis O. When viewed from the direction of the axis O, the second nozzle 62 is arranged at a position overlapping with the center of gravity of the rectangular front end opening 63 (i.e., on the axis O). The upstream end of the second nozzle 62 is connected to the ammonia fuel supply pipe 51. Thus, gaseous ammonia as a fuel is ejected from the second nozzle 62. Alternatively, the second nozzle 62 may be configured to eject liquid ammonia.

第2噴嘴62之下游側的前端部67,在軸線O方向位於比第1噴嘴61的前端開口63還上游側。也就是說,第2噴嘴62的前端部67,沒有從前端開口63朝向火爐11側突出。且,前端部67,在軸線O方向,配置在不與前端開口63重疊的位置。The front end portion 67 on the downstream side of the second nozzle 62 is located upstream of the front end opening 63 of the first nozzle 61 in the axis O direction. In other words, the front end portion 67 of the second nozzle 62 does not protrude from the front end opening 63 toward the furnace 11. In addition, the front end portion 67 is arranged at a position that does not overlap with the front end opening 63 in the axis O direction.

第2噴嘴62的剖面形狀,在圖3之例為圓形。但是,第2噴嘴62的剖面形狀亦可為矩形狀或多角形狀、橢圓形狀。The cross-sectional shape of the second nozzle 62 is circular in the example of Fig. 3. However, the cross-sectional shape of the second nozzle 62 may be rectangular, polygonal, or elliptical.

(作用效果) 在鍋爐10中,若複數個磨碎機31驅動的話,被粉碎、分級過的微粉燃料,會與一次空氣一起透過微粉燃料供給管22供給至燃燒器21。且,被空氣預熱器42加熱過的二次空氣,是從風道24透過風箱23供給至燃燒器21。燃燒器21,是將使微粉燃料與一次空氣混合而成的微粉燃料混合氣予以吹入至火爐11,並將二次空氣吹入至火爐11。使吹入至火爐11的微粉燃料混合氣著火,而與二次空氣反應藉此形成火炎。在火爐11內的下部區域形成火炎,使高溫的燃燒氣體在火爐11內上升,而流入燃燒氣體通路12。又,在本實施形態,作為氧化性氣體(一次空氣、二次空氣)是使用空氣,但亦可為氧氣比例比空氣還多者或還少者,將氧氣量對所供給之燃料量的比率調整至適當的範圍,藉此在火爐11實現穩定的燃燒。 (Effect) In the boiler 10, if the plurality of grinders 31 are driven, the crushed and classified fine powder fuel is supplied to the burner 21 through the fine powder fuel supply pipe 22 together with the primary air. In addition, the secondary air heated by the air preheater 42 is supplied to the burner 21 from the air duct 24 through the wind box 23. The burner 21 blows the fine powder fuel mixed gas formed by mixing the fine powder fuel and the primary air into the furnace 11, and blows the secondary air into the furnace 11. The fine powder fuel mixed gas blown into the furnace 11 is ignited and reacts with the secondary air to form a flame. A flame is formed in the lower area of the furnace 11, causing the high-temperature combustion gas to rise in the furnace 11 and flow into the combustion gas passage 12. In this embodiment, air is used as the oxidizing gas (primary air, secondary air), but the oxygen ratio may be more or less than that of air, and the ratio of the oxygen amount to the supplied fuel amount is adjusted to an appropriate range, thereby achieving stable combustion in the furnace 11.

流入至燃燒氣體通路12的燃燒氣體,藉由配置在燃燒氣體通路12之內部的過熱器102、再熱器103、省煤器104來與水或蒸氣進行熱交換之後,排出至煙道13,藉由脫硝裝置43來去除氮氧化物,藉由空氣預熱器42來與一次空氣及二次空氣進行熱交換之後,進一步排出至氣體通道41,藉由集塵裝置44來去除灰等,藉由脫硫裝置46來去除硫氧化物之後,從煙囪47排出至系統外。又,從燃燒氣體通路12之各熱交換器及煙道13到氣體通道41之各裝置的配置,並不一定要對於燃燒氣體的流動配置成上述記載的順序。The combustion gas flowing into the combustion gas passage 12 exchanges heat with water or steam through the superheater 102, the reheater 103, and the economizer 104 disposed inside the combustion gas passage 12, and then is discharged to the flue 13, and then nitrogen oxides are removed through the denitrification device 43, and then heat is exchanged with the primary air and the secondary air through the air preheater 42, and then further discharged to the gas passage 41, and then ash and the like are removed through the dust collecting device 44, and sulfur oxides are removed through the desulfurization device 46, and then discharged to the outside of the system from the chimney 47. In addition, the arrangement of each heat exchanger in the combustion gas passage 12 and each device in the flue 13 to the gas passage 41 does not necessarily have to be arranged in the above-described order with respect to the flow of the combustion gas.

在此,本實施形態的燃燒器21,除了將從第1噴嘴61噴出之煤粉與一次空氣的混合流體作為燃料來使用的情況以外,還可將從第2噴嘴62噴出的氨作為燃料來使用。以往,是各自獨立地複數設置使煤粉燃燒的燃燒器與使氨燃燒的燃燒器。Here, the burner 21 of this embodiment can use ammonia ejected from the second nozzle 62 as fuel in addition to the mixed fluid of pulverized coal and primary air ejected from the first nozzle 61. Conventionally, a plurality of burners for burning pulverized coal and ammonia are independently provided.

但是,可設置在火爐11內的燃燒器之總數有限,故如上述般設置以氨為燃料的燃燒器時,以煤粉為燃料的燃燒器之數量會減少。其結果,例如在無法得到氨的狀況下,有著燃燒器全體的輸出會減少該份量的課題。於是,在本實施形態的燃燒器21,以可將煤粉與氨作為燃料來共用的方式,具備第1噴嘴61與第2噴嘴62。藉此,不但可將氨使用作為燃料,而且還在僅將煤粉作為燃料使所有的燃燒器21運作之際,可避免該等燃燒器21的合計輸出降低的情況。However, the total number of burners that can be installed in the furnace 11 is limited, so when burners using ammonia as fuel are installed as described above, the number of burners using pulverized coal as fuel will decrease. As a result, for example, when ammonia is not available, there is a problem that the output of the entire burner will be reduced by that amount. Therefore, in the burner 21 of this embodiment, the first nozzle 61 and the second nozzle 62 are provided in a manner that pulverized coal and ammonia can be used in common as fuel. In this way, not only can ammonia be used as fuel, but also when all the burners 21 are operated using only pulverized coal as fuel, the total output of the burners 21 can be avoided from being reduced.

此外,根據上述構造,第2噴嘴62位在比第1噴嘴61的前端開口63還上游側。藉此,可迴避因為該第2噴嘴62使前端開口63的剖面積減少的情況。於是,在使用煤粉作為燃料之際,在相同流量之一次空氣流量的情況,可迴避噴出速度變快導致點火之不穩定化發生的情況。其結果,可將氨使用作為燃料,並且在使用煤粉作為燃料之際,可迴避第2噴嘴62妨礙該煤粉之流動的情況。藉此,可抑制使用煤粉作為燃料之際之燃燒器21的輸出降低。換言之,可實現與沒有設置第2噴嘴62之情況相同的火炎溫度、火炎長度。Furthermore, according to the above-mentioned structure, the second nozzle 62 is located on the upstream side of the front end opening 63 of the first nozzle 61. Thus, it is possible to avoid the situation where the cross-sectional area of the front end opening 63 is reduced due to the second nozzle 62. Therefore, when using pulverized coal as fuel, at the same flow rate of primary air flow, it is possible to avoid the situation where the jet speed becomes faster and the ignition becomes unstable. As a result, ammonia can be used as fuel, and when using pulverized coal as fuel, it is possible to avoid the situation where the second nozzle 62 hinders the flow of the pulverized coal. Thus, it is possible to suppress the reduction in the output of the burner 21 when using pulverized coal as fuel. In other words, the same flame temperature and flame length as those in the case where the second nozzle 62 is not provided can be achieved.

此外,根據上述構造,是對於由混合流體所形成的火炎,供給從二次空氣噴出口66噴出的二次空氣,藉此可調整燃燒效率與火炎溫度。特別是,以包圍前端開口63之周圍的方式形成有二次空氣噴出口66,故可從火炎的周圍完整地供給二次空氣。藉此,使火炎溫度分布均勻化,可更穩定地產生高溫的燃燒氣體。Furthermore, according to the above structure, the secondary air ejected from the secondary air ejection port 66 is supplied to the flame formed by the mixed fluid, thereby adjusting the combustion efficiency and the flame temperature. In particular, the secondary air ejection port 66 is formed so as to surround the front end opening 63, so that the secondary air can be completely supplied from the periphery of the flame. In this way, the flame temperature distribution is made uniform, and a high-temperature combustion gas can be generated more stably.

且,根據上述構造,第2噴嘴62配置在第1噴嘴61之剖面的重心位置(軸線O的位置)。藉此,在將氨作為燃料來使用之際,是成為從二次空氣噴出口66噴出的二次空氣包圍由該氨所形成之火炎周圍的狀態。其結果,在將氨作為燃料來使用之際,亦可使火炎的形狀與溫度穩定化。Furthermore, according to the above-mentioned structure, the second nozzle 62 is arranged at the center of gravity (the position of the axis O) of the cross section of the first nozzle 61. Thereby, when ammonia is used as a fuel, the secondary air ejected from the secondary air ejection port 66 surrounds the flame formed by the ammonia. As a result, the shape and temperature of the flame can be stabilized when ammonia is used as a fuel.

此外,根據上述構造,微粉燃料供給管22與氨燃料供給管51是獨立設置。藉此,可分別圓滑地進行僅以煤粉作為燃料的運轉、僅以氨作為燃料的運轉、以及使雙方作為燃料的運轉。且,可圓滑且即時地切換該等三種運轉狀態。In addition, according to the above structure, the pulverized fuel supply pipe 22 and the ammonia fuel supply pipe 51 are independently provided. Thus, the operation using only pulverized coal as fuel, the operation using only ammonia as fuel, and the operation using both as fuel can be smoothly performed. Moreover, the three operation states can be smoothly and instantly switched.

(其他實施形態) 以上,針對本發明的實施形態參照圖式進行了詳述,但具體的構造並不限定於該實施形態,不超脫本發明之主旨範圍的設計變更等也包含在內。例如,在上述實施形態,說明了僅設置一個第2噴嘴62的例子。但是,如圖4與圖5所示般,複數個第2噴嘴62,是以沿著前端開口63之各邊且佔據其內側的方式,配列成格子狀亦可。 (Other embodiments) The embodiments of the present invention are described in detail with reference to the drawings above, but the specific structure is not limited to the embodiments, and design changes that do not exceed the scope of the present invention are also included. For example, in the above embodiments, an example of only providing a second nozzle 62 is described. However, as shown in Figures 4 and 5, a plurality of second nozzles 62 may be arranged in a grid along the sides of the front end opening 63 and occupying the inner side thereof.

根據上述構造,使複數個第2噴嘴62複數配列成格子狀,藉此可進一步使前端開口63之氨的濃度分布均勻化。藉此,可更穩定地形成火炎。According to the above structure, the plurality of second nozzles 62 are arranged in a grid pattern, thereby making the concentration distribution of ammonia at the front end opening 63 more uniform. Thereby, the flame can be formed more stably.

且,在上述實施形態,說明了本發明的鍋爐是使用固體燃料來作為燃料的鍋爐。作為使用於鍋爐10的固體燃料,是使用煤炭、生質燃料、石油焦(PC:Petroleum Coke)燃料、石油殘渣等。 又,作為鍋爐10的燃料,並不限定於固體燃料,亦可使用重油、輕油、重質油等之石油類或工場廢液等之液體燃料。且,亦可使用天然氣或各種石油氣、製鐵製程等產生的副產氣等之氣體燃料。 此外,亦可適用於組合該等之各種燃料來使用的混合燃燒鍋爐。 Furthermore, in the above-mentioned embodiment, it is explained that the boiler of the present invention is a boiler that uses solid fuel as fuel. As solid fuel used in the boiler 10, coal, biomass fuel, petroleum coke (PC: Petroleum Coke) fuel, petroleum residue, etc. are used. In addition, as the fuel of the boiler 10, it is not limited to solid fuel, and petroleum such as heavy oil, light oil, heavy oil, etc. or liquid fuel such as factory waste liquid can also be used. Moreover, gas fuels such as natural gas or various petroleum gases, by-product gas generated by steelmaking processes, etc. can also be used. In addition, it can also be applied to a mixed combustion boiler that uses a combination of these various fuels.

[附註] 各實施形態所記載之燃燒器21、及鍋爐10,例如把握成如下。 [Note] The burner 21 and boiler 10 described in each embodiment are, for example, understood as follows.

(1)第1樣態的燃燒器21,具備:第1噴嘴61,其成為於軸線O方向延伸的筒狀,具有可將一次空氣與煤粉的混合流體予以噴出的前端開口63;以及第2噴嘴62,其在前述第1噴嘴61內配置成沿著前述軸線O方向延伸,具有位在比前述第1噴嘴61的前端開口63還靠前述混合流體的上游側且可噴出氨的前端部67。(1) A burner 21 of the first embodiment comprises: a first nozzle 61 which is cylindrical and extends in the direction of an axis O and has a front end opening 63 for ejecting a mixed fluid of primary air and pulverized coal; and a second nozzle 62 which is arranged in the first nozzle 61 to extend in the direction of the axis O and has a front end portion 67 which is located on the upstream side of the mixed fluid than the front end opening 63 of the first nozzle 61 and can eject ammonia.

根據上述構造,第2噴嘴62位在比第1噴嘴61的前端開口63還上游側。藉此,可迴避因為該第2噴嘴62使前端開口63的剖面積減少的情況。於是,在使用煤粉作為燃料之際,在相同流量之一次空氣亦可抑制流速的增加,迴避點火的不穩定化。According to the above structure, the second nozzle 62 is located upstream of the front opening 63 of the first nozzle 61. This can avoid the situation where the cross-sectional area of the front opening 63 is reduced due to the second nozzle 62. Therefore, when using pulverized coal as fuel, the increase in the flow rate of primary air at the same flow rate can be suppressed, avoiding ignition instability.

(2)第2樣態的燃燒器21,是(1)的燃燒器21,其中,亦可進一步具有二次空氣噴出口66,其設在前述第1噴嘴61之前述前端開口63的周圍,呈環狀且可噴出二次空氣。(2) The burner 21 of the second embodiment is the burner 21 of (1), wherein it may further have a secondary air injection port 66 which is provided around the aforementioned front end opening 63 of the aforementioned first nozzle 61 and is annular and capable of injecting secondary air.

根據上述構造,是對於由混合流體所形成的火炎供給二次空氣,藉此可調整燃燒效率與火炎溫度。According to the above structure, secondary air is supplied to the flame formed by the mixed fluid, thereby adjusting the combustion efficiency and the flame temperature.

(3)第3樣態的燃燒器21,是(1)或(2)的燃燒器21,其中,前述第2噴嘴62,配置在前述第1噴嘴61之剖面的重心位置亦可。(3) The burner 21 of the third aspect is the burner 21 of (1) or (2), wherein the second nozzle 62 may be arranged at the center of gravity of the cross section of the first nozzle 61.

根據上述構造,第2噴嘴62配置在第1噴嘴61之剖面的重心位置,故在使用氨作為燃料之際,可使火炎的形狀穩定化。According to the above structure, the second nozzle 62 is arranged at the center of gravity of the cross section of the first nozzle 61, so when ammonia is used as the fuel, the shape of the flame can be stabilized.

(4)第4樣態的燃燒器21,是(1)至(3)中任一樣態的燃燒器21,其中,前述第1噴嘴61的前述前端開口63,在從前述軸線O方向觀看時呈矩形狀,前述第2噴嘴62,沿著前述前端開口63的各邊空出間隔來複數配列成格子狀亦可。(4) A fourth embodiment of the burner 21 is a burner 21 of any one of the embodiments (1) to (3), wherein the front end opening 63 of the first nozzle 61 is rectangular when viewed from the direction of the axis O, and the second nozzle 62 may be arranged in a lattice shape with spaces between the sides of the front end opening 63.

根據上述構造,使複數個第2噴嘴62複數配列成格子狀,藉此可使前端開口63之氨的濃度分布均勻化。藉此,可更穩定地形成火炎。According to the above structure, the plurality of second nozzles 62 are arranged in a grid pattern, thereby making the concentration distribution of ammonia at the front end opening 63 uniform. Thereby, the flame can be formed more stably.

(5)第5樣態的燃燒器21,是(1)至(4)中任一樣態的燃燒器21,其中,前述第1噴嘴61,連接於從可供給煤粉的磨碎機31延伸的微粉燃料供給管22,前述第2噴嘴62,連接於與前述微粉燃料供給管22個別地設置且可供給氨的氨燃料供給管51亦可。(5) The burner 21 of the fifth embodiment is a burner 21 of any one of the embodiments (1) to (4), wherein the first nozzle 61 is connected to a pulverized fuel supply pipe 22 extending from a grinder 31 for supplying pulverized coal, and the second nozzle 62 is connected to an ammonia fuel supply pipe 51 which is separately provided from the pulverized fuel supply pipe 22 and for supplying ammonia.

根據上述構造,由於微粉燃料供給管22與氨燃料供給管51是獨立設置,故可分別圓滑地進行僅以煤粉作為燃料的運轉、僅以氨作為燃料的運轉、以及使雙方作為燃料的運轉。According to the above structure, since the pulverized fuel supply pipe 22 and the ammonia fuel supply pipe 51 are independently provided, operation using only pulverized coal as fuel, operation using only ammonia as fuel, and operation using both as fuel can be smoothly performed.

(6)第6樣態的鍋爐10,具備(1)至(5)中任一樣態的燃燒器21與設有該燃燒器21的火爐11。(6) A sixth embodiment of the boiler 10 includes the burner 21 of any one of the embodiments (1) to (5) and a furnace 11 provided with the burner 21.

根據上述構造,可提供鍋爐10,其可將氨作為燃料來使用,且在僅將煤粉作為燃料的情況不會使輸出降低。 [產業上的可利用性] According to the above structure, a boiler 10 can be provided which can use ammonia as a fuel and does not reduce the output when only pulverized coal is used as a fuel. [Industrial Applicability]

根據本發明,可提供可將氨與化石燃料有效率地作為燃料來使用的燃燒器、及鍋爐。According to the present invention, a burner and a boiler that can efficiently use ammonia and fossil fuel as fuel can be provided.

10:鍋爐 11:火爐 12:燃燒氣體通路 13:煙道 20:燃燒裝置 21,21A,21B,21C,21D,21E,21F:燃燒器 22,22A,22B,22C,22D,22E,22F:微粉燃料供給管 23:風箱(調風器) 24:風道(空氣通道) 31:磨碎機(粉碎機) 32:吹入送風機(FDF) 41:氣體通道 42:空氣預熱器 43:脫硝裝置 44:集塵裝置 45:吸引送風機(IDF) 46:脫硫裝置 47:煙囪 51:氨燃料供給管 52:氨供給源 61:第1噴嘴 62:第2噴嘴 63:前端開口 64:第1流路 65:下游側端面 66:二次空氣噴出口 67:前端部 68:第2流路 101:火爐壁 102:過熱器 102A:第1過熱器 102B:第2過熱器 102C:第3過熱器 103:再熱器 103A:第1再熱器 103B:第2再熱器 104:省煤器 10: Boiler 11: Furnace 12: Combustion gas passage 13: Flue 20: Combustion device 21,21A,21B,21C,21D,21E,21F: Burner 22,22A,22B,22C,22D,22E,22F: Micro-powder fuel supply pipe 23: Bellows (air regulator) 24: Air duct (air duct) 31: Grinding mill (crusher) 32: Injection fan (FDF) 41: Gas duct 42: Air preheater 43: Denitrification device 44: Dust collector 45: Induction fan (IDF) 46: Desulfurization device 47: Chimney 51: Ammonia fuel supply pipe 52: Ammonia supply source 61: First nozzle 62: Second nozzle 63: Front opening 64: First flow path 65: Downstream side surface 66: Secondary air injection port 67: Front end 68: Second flow path 101: Furnace wall 102: Superheater 102A: First superheater 102B: Second superheater 102C: Third superheater 103: Reheater 103A: First reheater 103B: Second reheater 104: Economizer

[圖1] 表示本發明之實施形態之鍋爐之構造的示意圖。 [圖2] 表示本發明之實施形態之燃燒器之構造的剖面圖。 [圖3] 從軸線方向觀看本發明之實施形態之燃燒器的圖。 [圖4] 表示本發明之實施形態之燃燒器之變形例的剖面圖。 [圖5] 從軸線方向觀看本發明之實施形態之燃燒器之變形例的圖。 [Fig. 1] A schematic diagram showing the structure of a boiler according to an embodiment of the present invention. [Fig. 2] A cross-sectional view showing the structure of a burner according to an embodiment of the present invention. [Fig. 3] A view showing the burner according to an embodiment of the present invention as viewed from the axial direction. [Fig. 4] A cross-sectional view showing a variation of the burner according to an embodiment of the present invention. [Fig. 5] A view showing a variation of the burner according to an embodiment of the present invention as viewed from the axial direction.

21:燃燒器 21: Burner

61:第1噴嘴 61: No. 1 nozzle

62:第2噴嘴 62: No. 2 nozzle

63:前端開口 63: Front opening

64:第1流路 64: Flow path 1

65:下游側端面 65: Downstream end face

66:二次空氣噴出口 66: Secondary air outlet

67:前端部 67: Front end

68:第2流路 68: Second flow path

O:軸線 O: Axis

Claims (8)

一種燃燒器,具備:第1噴嘴,其成為於軸線方向延伸的筒狀,具有可將一次空氣與煤粉的混合流體予以噴出的前端開口;以及第2噴嘴,其在前述第1噴嘴內配置成沿著前述軸線方向延伸,具有位在比前述第1噴嘴的前端開口還靠前述混合流體的上游側且可噴出氨的前端部,進一步具有二次空氣噴出口,其設在前述第1噴嘴之前述前端開口的周圍,呈環狀且可噴出二次空氣,前述第2噴嘴,配置在前述第1噴嘴之剖面的重心位置。 A burner comprises: a first nozzle, which is cylindrical and extends in an axial direction, and has a front opening for ejecting a mixed fluid of primary air and coal powder; and a second nozzle, which is arranged in the first nozzle to extend along the axial direction, has a front end portion located upstream of the front opening of the first nozzle and can eject ammonia, and further has a secondary air ejection port, which is arranged around the front opening of the first nozzle, is annular and can eject secondary air, and the second nozzle is arranged at the center of gravity of the cross section of the first nozzle. 如請求項1所述之燃燒器,其中,前述第1噴嘴的前述前端開口,在從前述軸線方向觀看時呈矩形狀,前述第2噴嘴,沿著前述前端開口的各邊空出間隔來複數配列成格子狀。 The burner as described in claim 1, wherein the front end opening of the first nozzle is rectangular when viewed from the axis direction, and the second nozzles are arranged in a grid pattern with spaces between them along each side of the front end opening. 如請求項1所述之燃燒器,其中,前述第1噴嘴的前述前端開口,在從前述軸線方向觀看時呈矩形狀,前述第2噴嘴,沿著前述前端開口的各邊空出間隔來複數配列成格子狀。 The burner as described in claim 1, wherein the front end opening of the first nozzle is rectangular when viewed from the axis direction, and the second nozzles are arranged in a grid pattern with spaces between them along each side of the front end opening. 如請求項1所述之燃燒器,其中,前述第1噴嘴,連接於從可供給煤粉的磨碎機延伸的微粉燃料供給管,前述第2噴嘴,連接於與前述微粉燃料供給管個別地設置且可供給氨的氨燃料供給管。 The burner as described in claim 1, wherein the first nozzle is connected to a pulverized fuel supply pipe extending from a pulverizer for supplying pulverized coal, and the second nozzle is connected to an ammonia fuel supply pipe which is separately provided from the pulverized fuel supply pipe and can supply ammonia. 如請求項1所述之燃燒器,其中,前述第 1噴嘴,連接於從可供給煤粉的磨碎機延伸的微粉燃料供給管,前述第2噴嘴,連接於與前述微粉燃料供給管個別地設置且可供給氨的氨燃料供給管。 The burner as described in claim 1, wherein the first nozzle is connected to a pulverized fuel supply pipe extending from a pulverizer for supplying pulverized coal, and the second nozzle is connected to an ammonia fuel supply pipe which is separately provided from the pulverized fuel supply pipe and can supply ammonia. 如請求項2所述之燃燒器,其中,前述第1噴嘴,連接於從可供給煤粉的磨碎機延伸的微粉燃料供給管,前述第2噴嘴,連接於與前述微粉燃料供給管個別地設置且可供給氨的氨燃料供給管。 The burner as described in claim 2, wherein the first nozzle is connected to a pulverized fuel supply pipe extending from a pulverizer for supplying pulverized coal, and the second nozzle is connected to an ammonia fuel supply pipe which is separately provided from the pulverized fuel supply pipe and can supply ammonia. 如請求項3所述之燃燒器,其中,前述第1噴嘴,連接於從可供給煤粉的磨碎機延伸的微粉燃料供給管,前述第2噴嘴,連接於與前述微粉燃料供給管個別地設置且可供給氨的氨燃料供給管。 The burner as described in claim 3, wherein the first nozzle is connected to a pulverized fuel supply pipe extending from a pulverizer for supplying pulverized coal, and the second nozzle is connected to an ammonia fuel supply pipe which is separately provided from the pulverized fuel supply pipe and can supply ammonia. 一種鍋爐,具備:如請求項1至7中任一項所述之燃燒器、設有該燃燒器的火爐。 A boiler comprising: a burner as described in any one of claims 1 to 7, and a furnace equipped with the burner.
TW111149481A 2022-03-30 2022-12-22 Burners and boilers TWI858471B (en)

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JP2020041748A (en) * 2018-09-11 2020-03-19 株式会社Ihi Burner and boiler
CN111094848A (en) * 2017-07-31 2020-05-01 通用电气技术有限公司 Coal nozzle assembly for steam generating device

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CN110873326A (en) * 2018-08-29 2020-03-10 赫普科技发展(北京)有限公司 Ammonia mixing combustion system and carbon dioxide emission reduction method adopting same
JP2020041748A (en) * 2018-09-11 2020-03-19 株式会社Ihi Burner and boiler

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