TWI858191B - Air purification material and air purification module using the same - Google Patents
Air purification material and air purification module using the same Download PDFInfo
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- TWI858191B TWI858191B TW109141694A TW109141694A TWI858191B TW I858191 B TWI858191 B TW I858191B TW 109141694 A TW109141694 A TW 109141694A TW 109141694 A TW109141694 A TW 109141694A TW I858191 B TWI858191 B TW I858191B
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- 239000000463 material Substances 0.000 title claims abstract description 84
- 238000004887 air purification Methods 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 claims abstract description 81
- 239000002245 particle Substances 0.000 claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 238000000746 purification Methods 0.000 claims description 44
- 239000002131 composite material Substances 0.000 claims description 37
- 239000003463 adsorbent Substances 0.000 claims description 25
- 238000001179 sorption measurement Methods 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 13
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 239000005416 organic matter Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011941 photocatalyst Substances 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/005—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
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- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
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Abstract
Description
本發明涉及氣體清淨技術領域,尤指一種結合觸媒材料與吸附材料的氣體清淨效果,可提升氣體清淨效率、循環使用,且使用壽命長之氣體清淨複合材料及具有其之氣體清淨複合模組。 The present invention relates to the field of gas purification technology, and in particular to a gas purification effect combining a catalyst material and an adsorbent material, which can improve gas purification efficiency, be recycled, and have a long service life, and a gas purification composite material and a gas purification composite module having the same.
基於環境、生態、健康等因素考量,全世界對於空氣品質的要求也日益提高,包括空氣中的PM2.5、揮發性有機物(Volatile Organic Compounds,VOCs)、二氧化碳(CO2)及濕度等等。 Based on environmental, ecological, and health considerations, the world's requirements for air quality are increasing, including PM2.5, volatile organic compounds (VOCs), carbon dioxide (CO 2 ), and humidity in the air.
由於環境氣體中的灰塵、微粒及有機物對人體具有極大的危害,因此全球各地對於氣體清淨機的需求也不斷增加,對於氣體清淨機的結構更是不斷改良創新,習知用以淨化氣體的材料大致可分為吸附材料與觸媒材料兩大類。 Since dust, particles and organic matter in ambient gas are extremely harmful to the human body, the demand for gas purifiers is increasing around the world, and the structure of gas purifiers is constantly being improved and innovated. It is known that the materials used to purify gas can be roughly divided into two categories: adsorption materials and catalyst materials.
其中,吸附材料包括例如活性碳、沸石等多孔性材質,其工作原理是利用吸附材料吸附(亦即攔截)氣體中的微粒,然而當吸附飽和之後,吸附材料就失去吸附作用,必須更換吸附材料。此外,吸附材料並不具有去除氣體中的有機物及臭味的作用。 Among them, adsorption materials include porous materials such as activated carbon and zeolite. Its working principle is to use adsorption materials to adsorb (i.e. intercept) particles in the gas. However, when the adsorption is saturated, the adsorption material loses its adsorption effect and must be replaced. In addition, the adsorption material does not have the function of removing organic matter and odor in the gas.
其次,觸媒材料包括例如光觸媒、熱觸媒等,其工作原理是利用光照或加熱催化劑的方式分解氣體中的有機物(例如,甲醛、苯類、氨、細菌等)以及微粒及氣體中的臭味。但是觸媒產生作用需要時間,例如大約30秒,但是觸媒材料並無法去除氣體中的塵埃。 Secondly, catalyst materials include photocatalysts, thermal catalysts, etc., and their working principle is to use light or heating catalysts to decompose organic matter (such as formaldehyde, benzene, ammonia, bacteria, etc.) and particles and odors in the gas. However, it takes time for the catalyst to take effect, such as about 30 seconds, but the catalyst material cannot remove dust in the gas.
據此,如何能有一種結合觸媒材料與吸附材料的氣體清淨效果,可提升氣體清淨效率、循環使用,且使用壽命長之「氣體清淨複合材料及具有其之氣體清淨複合模組」,是相關技術領域人士亟待解決之課題。 Therefore, how to have a "gas purification composite material and gas purification composite module having the same" that combines the gas purification effect of catalyst materials and adsorbent materials, can improve gas purification efficiency, be recycled, and have a long service life is an issue that people in the relevant technical field need to solve urgently.
於一實施例中,本發明提出一種氣體清淨複合材料,包含:複數呈顆粒狀之觸媒材料,用以產生觸媒作用以分解氣體中的有機物,觸媒材料係於基材之表面塗布觸媒所構成;以及複數呈顆粒狀之吸附材料,用以吸附氣體中的微粒;其中,觸媒材料的總體積為A1,吸附材料的總體積為A2,A1:A2之比例介於1:6~1:20之間;基材之表面之觸媒之厚度等於或小於20微米。 In one embodiment, the present invention proposes a gas purification composite material, comprising: a plurality of granular catalyst materials for generating catalytic action to decompose organic matter in the gas, the catalyst material being formed by coating the catalyst on the surface of a substrate; and a plurality of granular adsorption materials for adsorbing particles in the gas; wherein the total volume of the catalyst material is A1, the total volume of the adsorption material is A2, and the ratio of A1:A2 is between 1:6 and 1:20; the thickness of the catalyst on the surface of the substrate is equal to or less than 20 microns.
於另一實施例中,本發明提出一種氣體清淨複合模組,包含:一載台,其具有至少一承載單元,承載單元連通載台的相對兩面,於承載單元中設置有氣體清淨複合材料;氣體由載台之第一面流入承載單元並通過氣體清淨複合材料,再由載台相對第一面之第二面流出。 In another embodiment, the present invention proposes a gas purification composite module, comprising: a carrier having at least one supporting unit, the supporting unit connecting two opposite sides of the carrier, and a gas purification composite material is arranged in the supporting unit; the gas flows into the supporting unit from the first side of the carrier and passes through the gas purification composite material, and then flows out from the second side of the carrier opposite to the first side.
請參閱圖1所示,本發明所提供之一種氣體清淨複合材料1,包含複數呈顆粒狀之觸媒材料10及複數呈顆粒狀之吸附材料20。觸媒材料10及吸附材料20之粒徑不限,例如可界於6~50奈米(nm)之範圍。或者,觸媒材料10與吸附材料20之表面積比介於500-2000平方公尺/公克(m2/g)之範圍。
As shown in FIG. 1 , a gas purification
觸媒材料10用以產生觸媒作用以分解氣體中的有機物。觸媒材料10係於基材11之表面塗布觸媒12所構成,基材11之表面之觸媒12之厚度T等於或小於20微米。基材11包括但不限於吸附材料、非吸附材料。觸媒12的種類不限,例如,可為光觸媒、熱觸媒或可產生觸媒作用的其他種類觸媒。觸媒12包括但不限於金(Au)、銀(Ag)、光觸媒(TiO2)。
The
吸附材料20用以吸附氣體中的微粒。吸附材料20包括但不限於活性碳、沸石等多孔性材質。
The
觸媒材料10與吸附材料20之間具有特殊的關係。其中,觸媒材料10的總體積為A1,吸附材料20的總體積為A2,A1:A2之比例介於1:6~1:20之間。
There is a special relationship between the
基材11之表面之觸媒12之總重量為W1,基材11與吸附材料20的總重量為W2,W1/W2之比例介於5%~15%之間。依重量比例計算的原因在於,在某些情況下,因不同因素所限,無法具體量測觸媒材料10與吸
附材料20的總體積,因此,可經由重量計算而得知觸媒的比例是否適當。
The total weight of the
必須說明的是,圖1所示觸媒材料10及吸附材料20皆呈圓形(或可視為球形),然而並不限於此。觸媒材料10及吸附材料20可為相同或不同之規則或不規則之任意幾何形狀之顆粒,且觸媒材料10及吸附材料20的尺寸可以相同或不同。此外,基於觸媒材料10及吸附材料20呈顆粒狀,因此於擺放時也非如圖1所示具有規則性,圖1僅作為說明。
It must be noted that the
請參閱圖2所示具有圖1之氣體清淨複合材料之氣體清淨複合模組2。氣體清淨複合模組2包含一載台30,載台30具有複數承載單元31,於載台30設有複數孔洞32,藉由孔洞32使得每一承載單元31連通載台30的相對的第一面33及第二面34。
Please refer to FIG. 2 for a gas
於每一承載單元32中設置有氣體清淨複合材料1。氣體清淨複合材料1包括觸媒材料10及吸附材料20。
A gas
於載台30之第二面34之一側設有一觸媒作用模組40,用以與基材11之表面之觸媒12產生觸媒作用。觸媒作用模組40與觸媒作用模組的距離D等於或小於0.5公分。
A
如前所述,圖1所示的觸媒12可為光觸媒、熱觸媒或可產生觸媒作用的其他種類觸媒,因此觸媒作用模組40包括但不限於紫外線燈、加熱器。利用紫外線燈的光觸媒再生作用,或是加熱器的熱觸媒再生作用,都能使觸媒12再利用。
As mentioned above, the
觸媒作用模組40的設置位置不限於圖2所示,可依實際所需設置於載台30的上方或下方,只要觸媒作用模組40所產生的紫外線或熱可作用於觸媒材料10即可。
The location of the
氣體G1由載台30之第一面33流入各承載單元31並通過氣體清淨複合材料1時,氣體G1中的有害微粒(例如PM2.5)可被吸附材料20吸附,至於氣體G1中的有機物則可經由觸媒材料10與觸媒作用模組設置40的作用而被分解,因此由載台30相對於第一面33之第二面34流出的為乾淨氣體G2。
When the gas G1 flows from the
本發明提供的氣體清淨複合模組2設有複數承載單元31,每一承載單元31中可平均填充有顆粒狀的氣體清淨複合材料1,然本實施例是針對當氣體G1進入氣體清淨複合模組2的方向為水平方向之情況時,除此之外,亦可僅設置一個承載單元31,原則在於可平均填充氣體清淨複合材料1,對於氣體G1可提供均勻的吸附過濾以及觸媒過濾作用即可,且利用觸媒作用模組40可使觸媒12再生。
The gas
綜上所述,本發明所提供之氣體清淨複合材料及具有其之氣體清淨複合模組,其觸媒材料與吸附材料之總體積之間,或者,其觸媒材料與吸附材料之總重量之間,或者,觸媒材料的觸媒厚度,具有特殊的設計比例及數值,不僅結合了觸媒材料與吸附材料的氣體清淨效果,而且可提升氣體清淨效率、循環使用,且使用壽命長。 In summary, the gas purification composite material and the gas purification composite module provided by the present invention have a special design ratio and value between the total volume of the catalyst material and the adsorbent material, or the total weight of the catalyst material and the adsorbent material, or the catalyst thickness of the catalyst material, which not only combines the gas purification effect of the catalyst material and the adsorbent material, but also improves the gas purification efficiency, recycling, and long service life.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed as above by the embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be subject to the scope of the attached patent application.
1:氣體清淨複合材料 1: Gas purification composite material
10:觸媒材料 10: Catalyst materials
11:基材 11: Base material
12:觸媒 12: Catalyst
20:吸附材料 20: Adsorption material
2:氣體清淨複合模組 2: Gas purification composite module
30:載台 30: Carrier
31:承載單元 31: Carrier unit
32:孔洞 32: Holes
33:第一面 33: First page
34:第二面 34: Second side
40:觸媒作用模組設置 40: Catalyst action module settings
A1,A2:總體積 A1, A2: Total volume
D:距離 D: Distance
G1:氣體 G1: Gas
G2:乾淨氣體 G2: Clean gas
T:厚度 T:Thickness
W1,W2:總重量 W1, W2: total weight
圖1為本發明之氣體清淨複合材料之一實施例之結構示意圖。 Figure 1 is a schematic diagram of the structure of an embodiment of the gas purification composite material of the present invention.
圖2為本發明之氣體清淨複合模組之一實施例之結構示意圖。 Figure 2 is a schematic structural diagram of an embodiment of the gas purification composite module of the present invention.
1:氣體清淨複合材料 1: Gas purification composite material
10:觸媒材料 10: Catalyst materials
11:基材 11: Base material
12:觸媒 12: Catalyst
20:吸附材料 20: Adsorption material
T:厚度 T:Thickness
Claims (7)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW109141694A TWI858191B (en) | 2020-11-27 | 2020-11-27 | Air purification material and air purification module using the same |
| CN202111386993.7A CN114558411A (en) | 2020-11-27 | 2021-11-22 | Gas cleaning composite material and gas cleaning composite module having the same |
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| TW109141694A TWI858191B (en) | 2020-11-27 | 2020-11-27 | Air purification material and air purification module using the same |
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| Publication Number | Publication Date |
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| TW202220742A TW202220742A (en) | 2022-06-01 |
| TWI858191B true TWI858191B (en) | 2024-10-11 |
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| CN (1) | CN114558411A (en) |
| TW (1) | TWI858191B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107174946A (en) * | 2017-06-09 | 2017-09-19 | 北京丰泽绿源环境技术有限公司 | A kind of indoor air handler and method |
| TW201808446A (en) * | 2016-06-30 | 2018-03-16 | 巴斯夫公司 | Manganese oxide based catalyst and catalyst device for the removal of formaldehyde and volatile organic compounds |
| CN211098254U (en) * | 2019-11-15 | 2020-07-28 | 深圳中汇新材料科技有限公司 | Graphene photocatalyst air harmful substance adsorption box |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2991195B1 (en) * | 1998-08-19 | 1999-12-20 | 日本電気株式会社 | Air purifier and air cleaning system using environmental catalyst |
| TWI286492B (en) * | 2004-12-28 | 2007-09-11 | Ind Tech Res Inst | Catalytic inorganic membrane and using the same |
| JP2011072961A (en) * | 2009-10-01 | 2011-04-14 | Toei Sangyo Kk | Adsorbing and decomposing material, and method for producing adsorbing and decomposing material |
| CN108295842A (en) * | 2018-02-05 | 2018-07-20 | 唐吉龙 | A kind of composite photocatalyst material for air purifier |
| TWM615347U (en) * | 2020-11-27 | 2021-08-11 | 創星淨聯科技股份有限公司 | Air purification module having air purification material |
-
2020
- 2020-11-27 TW TW109141694A patent/TWI858191B/en active
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- 2021-11-22 CN CN202111386993.7A patent/CN114558411A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201808446A (en) * | 2016-06-30 | 2018-03-16 | 巴斯夫公司 | Manganese oxide based catalyst and catalyst device for the removal of formaldehyde and volatile organic compounds |
| CN107174946A (en) * | 2017-06-09 | 2017-09-19 | 北京丰泽绿源环境技术有限公司 | A kind of indoor air handler and method |
| CN211098254U (en) * | 2019-11-15 | 2020-07-28 | 深圳中汇新材料科技有限公司 | Graphene photocatalyst air harmful substance adsorption box |
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| CN114558411A (en) | 2022-05-31 |
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