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TWI858191B - Air purification material and air purification module using the same - Google Patents

Air purification material and air purification module using the same Download PDF

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TWI858191B
TWI858191B TW109141694A TW109141694A TWI858191B TW I858191 B TWI858191 B TW I858191B TW 109141694 A TW109141694 A TW 109141694A TW 109141694 A TW109141694 A TW 109141694A TW I858191 B TWI858191 B TW I858191B
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catalyst
gas purification
purification composite
gas
module
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TW202220742A (en
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陳台彰
楊玫華
曾婉婷
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創星淨聯科技股份有限公司
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Priority to CN202111386993.7A priority patent/CN114558411A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/005Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/104Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/106Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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  • Biomedical Technology (AREA)
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Abstract

An air purification material and air purification module using the same is disclosed. The air purification material includes a plurality of granular catalyst material which is formed by coating catalyst on surface of basic material for decomposing organic in the gas, and a plurality of granular absorption material for absorbing particles in the gas. The total volume of catalyst material is A1, the total volume of absorption material is A2, A1:A2 is between 1:6~1:20. The thickness of the catalyst on the surface of basic material is equal to or smaller than 20 micrometer.

Description

氣體清淨複合材料及具有其之氣體清淨複合模組Gas purification composite material and gas purification composite module having the same

本發明涉及氣體清淨技術領域,尤指一種結合觸媒材料與吸附材料的氣體清淨效果,可提升氣體清淨效率、循環使用,且使用壽命長之氣體清淨複合材料及具有其之氣體清淨複合模組。 The present invention relates to the field of gas purification technology, and in particular to a gas purification effect combining a catalyst material and an adsorbent material, which can improve gas purification efficiency, be recycled, and have a long service life, and a gas purification composite material and a gas purification composite module having the same.

基於環境、生態、健康等因素考量,全世界對於空氣品質的要求也日益提高,包括空氣中的PM2.5、揮發性有機物(Volatile Organic Compounds,VOCs)、二氧化碳(CO2)及濕度等等。 Based on environmental, ecological, and health considerations, the world's requirements for air quality are increasing, including PM2.5, volatile organic compounds (VOCs), carbon dioxide (CO 2 ), and humidity in the air.

由於環境氣體中的灰塵、微粒及有機物對人體具有極大的危害,因此全球各地對於氣體清淨機的需求也不斷增加,對於氣體清淨機的結構更是不斷改良創新,習知用以淨化氣體的材料大致可分為吸附材料與觸媒材料兩大類。 Since dust, particles and organic matter in ambient gas are extremely harmful to the human body, the demand for gas purifiers is increasing around the world, and the structure of gas purifiers is constantly being improved and innovated. It is known that the materials used to purify gas can be roughly divided into two categories: adsorption materials and catalyst materials.

其中,吸附材料包括例如活性碳、沸石等多孔性材質,其工作原理是利用吸附材料吸附(亦即攔截)氣體中的微粒,然而當吸附飽和之後,吸附材料就失去吸附作用,必須更換吸附材料。此外,吸附材料並不具有去除氣體中的有機物及臭味的作用。 Among them, adsorption materials include porous materials such as activated carbon and zeolite. Its working principle is to use adsorption materials to adsorb (i.e. intercept) particles in the gas. However, when the adsorption is saturated, the adsorption material loses its adsorption effect and must be replaced. In addition, the adsorption material does not have the function of removing organic matter and odor in the gas.

其次,觸媒材料包括例如光觸媒、熱觸媒等,其工作原理是利用光照或加熱催化劑的方式分解氣體中的有機物(例如,甲醛、苯類、氨、細菌等)以及微粒及氣體中的臭味。但是觸媒產生作用需要時間,例如大約30秒,但是觸媒材料並無法去除氣體中的塵埃。 Secondly, catalyst materials include photocatalysts, thermal catalysts, etc., and their working principle is to use light or heating catalysts to decompose organic matter (such as formaldehyde, benzene, ammonia, bacteria, etc.) and particles and odors in the gas. However, it takes time for the catalyst to take effect, such as about 30 seconds, but the catalyst material cannot remove dust in the gas.

據此,如何能有一種結合觸媒材料與吸附材料的氣體清淨效果,可提升氣體清淨效率、循環使用,且使用壽命長之「氣體清淨複合材料及具有其之氣體清淨複合模組」,是相關技術領域人士亟待解決之課題。 Therefore, how to have a "gas purification composite material and gas purification composite module having the same" that combines the gas purification effect of catalyst materials and adsorbent materials, can improve gas purification efficiency, be recycled, and have a long service life is an issue that people in the relevant technical field need to solve urgently.

於一實施例中,本發明提出一種氣體清淨複合材料,包含:複數呈顆粒狀之觸媒材料,用以產生觸媒作用以分解氣體中的有機物,觸媒材料係於基材之表面塗布觸媒所構成;以及複數呈顆粒狀之吸附材料,用以吸附氣體中的微粒;其中,觸媒材料的總體積為A1,吸附材料的總體積為A2,A1:A2之比例介於1:6~1:20之間;基材之表面之觸媒之厚度等於或小於20微米。 In one embodiment, the present invention proposes a gas purification composite material, comprising: a plurality of granular catalyst materials for generating catalytic action to decompose organic matter in the gas, the catalyst material being formed by coating the catalyst on the surface of a substrate; and a plurality of granular adsorption materials for adsorbing particles in the gas; wherein the total volume of the catalyst material is A1, the total volume of the adsorption material is A2, and the ratio of A1:A2 is between 1:6 and 1:20; the thickness of the catalyst on the surface of the substrate is equal to or less than 20 microns.

於另一實施例中,本發明提出一種氣體清淨複合模組,包含:一載台,其具有至少一承載單元,承載單元連通載台的相對兩面,於承載單元中設置有氣體清淨複合材料;氣體由載台之第一面流入承載單元並通過氣體清淨複合材料,再由載台相對第一面之第二面流出。 In another embodiment, the present invention proposes a gas purification composite module, comprising: a carrier having at least one supporting unit, the supporting unit connecting two opposite sides of the carrier, and a gas purification composite material is arranged in the supporting unit; the gas flows into the supporting unit from the first side of the carrier and passes through the gas purification composite material, and then flows out from the second side of the carrier opposite to the first side.

請參閱圖1所示,本發明所提供之一種氣體清淨複合材料1,包含複數呈顆粒狀之觸媒材料10及複數呈顆粒狀之吸附材料20。觸媒材料10及吸附材料20之粒徑不限,例如可界於6~50奈米(nm)之範圍。或者,觸媒材料10與吸附材料20之表面積比介於500-2000平方公尺/公克(m2/g)之範圍。 As shown in FIG. 1 , a gas purification composite material 1 provided by the present invention includes a plurality of granular catalyst materials 10 and a plurality of granular adsorbent materials 20. The particle sizes of the catalyst materials 10 and the adsorbent materials 20 are not limited, for example, they can be in the range of 6 to 50 nanometers (nm). Alternatively, the surface area ratio of the catalyst material 10 to the adsorbent material 20 is in the range of 500-2000 square meters/gram (m 2 /g).

觸媒材料10用以產生觸媒作用以分解氣體中的有機物。觸媒材料10係於基材11之表面塗布觸媒12所構成,基材11之表面之觸媒12之厚度T等於或小於20微米。基材11包括但不限於吸附材料、非吸附材料。觸媒12的種類不限,例如,可為光觸媒、熱觸媒或可產生觸媒作用的其他種類觸媒。觸媒12包括但不限於金(Au)、銀(Ag)、光觸媒(TiO2)。 The catalyst material 10 is used to produce a catalytic effect to decompose organic matter in the gas. The catalyst material 10 is formed by coating a catalyst 12 on the surface of a substrate 11, and the thickness T of the catalyst 12 on the surface of the substrate 11 is equal to or less than 20 microns. The substrate 11 includes but is not limited to an adsorbent material and a non-adsorbent material. The type of catalyst 12 is not limited, for example, it can be a photocatalyst, a thermal catalyst, or other types of catalysts that can produce a catalytic effect. The catalyst 12 includes but is not limited to gold (Au), silver (Ag), and a photocatalyst (TiO2).

吸附材料20用以吸附氣體中的微粒。吸附材料20包括但不限於活性碳、沸石等多孔性材質。 The adsorbent material 20 is used to adsorb particles in the gas. The adsorbent material 20 includes but is not limited to porous materials such as activated carbon and zeolite.

觸媒材料10與吸附材料20之間具有特殊的關係。其中,觸媒材料10的總體積為A1,吸附材料20的總體積為A2,A1:A2之比例介於1:6~1:20之間。 There is a special relationship between the catalyst material 10 and the adsorption material 20. The total volume of the catalyst material 10 is A1, the total volume of the adsorption material 20 is A2, and the ratio of A1:A2 is between 1:6 and 1:20.

基材11之表面之觸媒12之總重量為W1,基材11與吸附材料20的總重量為W2,W1/W2之比例介於5%~15%之間。依重量比例計算的原因在於,在某些情況下,因不同因素所限,無法具體量測觸媒材料10與吸 附材料20的總體積,因此,可經由重量計算而得知觸媒的比例是否適當。 The total weight of the catalyst 12 on the surface of the substrate 11 is W1, and the total weight of the substrate 11 and the adsorbent material 20 is W2. The ratio of W1/W2 is between 5% and 15%. The reason for calculating by weight ratio is that in some cases, due to various factors, it is impossible to specifically measure the total volume of the catalyst material 10 and the adsorbent material 20. Therefore, whether the ratio of the catalyst is appropriate can be known by weight calculation.

必須說明的是,圖1所示觸媒材料10及吸附材料20皆呈圓形(或可視為球形),然而並不限於此。觸媒材料10及吸附材料20可為相同或不同之規則或不規則之任意幾何形狀之顆粒,且觸媒材料10及吸附材料20的尺寸可以相同或不同。此外,基於觸媒材料10及吸附材料20呈顆粒狀,因此於擺放時也非如圖1所示具有規則性,圖1僅作為說明。 It must be noted that the catalyst material 10 and the adsorbent material 20 shown in FIG. 1 are both round (or spherical), but are not limited to this. The catalyst material 10 and the adsorbent material 20 can be the same or different particles of regular or irregular geometric shapes, and the sizes of the catalyst material 10 and the adsorbent material 20 can be the same or different. In addition, since the catalyst material 10 and the adsorbent material 20 are in the form of particles, they are not placed in a regular manner as shown in FIG. 1, and FIG. 1 is only for illustration.

請參閱圖2所示具有圖1之氣體清淨複合材料之氣體清淨複合模組2。氣體清淨複合模組2包含一載台30,載台30具有複數承載單元31,於載台30設有複數孔洞32,藉由孔洞32使得每一承載單元31連通載台30的相對的第一面33及第二面34。 Please refer to FIG. 2 for a gas purification composite module 2 having the gas purification composite material of FIG. 1. The gas purification composite module 2 includes a carrier 30, the carrier 30 having a plurality of supporting units 31, and a plurality of holes 32 are provided on the carrier 30, and each supporting unit 31 is connected to the first surface 33 and the second surface 34 of the carrier 30 opposite to each other through the holes 32.

於每一承載單元32中設置有氣體清淨複合材料1。氣體清淨複合材料1包括觸媒材料10及吸附材料20。 A gas purification composite material 1 is disposed in each carrier unit 32. The gas purification composite material 1 includes a catalyst material 10 and an adsorbent material 20.

於載台30之第二面34之一側設有一觸媒作用模組40,用以與基材11之表面之觸媒12產生觸媒作用。觸媒作用模組40與觸媒作用模組的距離D等於或小於0.5公分。 A catalyst action module 40 is provided on one side of the second surface 34 of the carrier 30 to produce a catalytic effect with the catalyst 12 on the surface of the substrate 11. The distance D between the catalyst action module 40 and the catalyst action module is equal to or less than 0.5 cm.

如前所述,圖1所示的觸媒12可為光觸媒、熱觸媒或可產生觸媒作用的其他種類觸媒,因此觸媒作用模組40包括但不限於紫外線燈、加熱器。利用紫外線燈的光觸媒再生作用,或是加熱器的熱觸媒再生作用,都能使觸媒12再利用。 As mentioned above, the catalyst 12 shown in FIG. 1 can be a photocatalyst, a thermal catalyst, or other types of catalysts that can produce a catalytic effect, so the catalyst action module 40 includes but is not limited to an ultraviolet lamp and a heater. The photocatalyst regeneration effect of the ultraviolet lamp or the thermal catalyst regeneration effect of the heater can make the catalyst 12 reusable.

觸媒作用模組40的設置位置不限於圖2所示,可依實際所需設置於載台30的上方或下方,只要觸媒作用模組40所產生的紫外線或熱可作用於觸媒材料10即可。 The location of the catalyst action module 40 is not limited to that shown in FIG. 2 , and can be located above or below the carrier 30 as required, as long as the ultraviolet light or heat generated by the catalyst action module 40 can act on the catalyst material 10 .

氣體G1由載台30之第一面33流入各承載單元31並通過氣體清淨複合材料1時,氣體G1中的有害微粒(例如PM2.5)可被吸附材料20吸附,至於氣體G1中的有機物則可經由觸媒材料10與觸媒作用模組設置40的作用而被分解,因此由載台30相對於第一面33之第二面34流出的為乾淨氣體G2。 When the gas G1 flows from the first surface 33 of the carrier 30 into each carrier unit 31 and passes through the gas purification composite material 1, harmful particles (such as PM2.5) in the gas G1 can be adsorbed by the adsorption material 20, and the organic matter in the gas G1 can be decomposed by the catalyst material 10 and the catalyst action module device 40. Therefore, the gas G2 flows out from the second surface 34 of the carrier 30 relative to the first surface 33.

本發明提供的氣體清淨複合模組2設有複數承載單元31,每一承載單元31中可平均填充有顆粒狀的氣體清淨複合材料1,然本實施例是針對當氣體G1進入氣體清淨複合模組2的方向為水平方向之情況時,除此之外,亦可僅設置一個承載單元31,原則在於可平均填充氣體清淨複合材料1,對於氣體G1可提供均勻的吸附過濾以及觸媒過濾作用即可,且利用觸媒作用模組40可使觸媒12再生。 The gas purification composite module 2 provided by the present invention is provided with a plurality of carrier units 31, and each carrier unit 31 can be evenly filled with granular gas purification composite material 1. However, this embodiment is for the case where the direction in which the gas G1 enters the gas purification composite module 2 is horizontal. In addition, only one carrier unit 31 can be provided. The principle is that the gas purification composite material 1 can be evenly filled, and uniform adsorption filtration and catalyst filtration can be provided for the gas G1, and the catalyst 12 can be regenerated by using the catalyst action module 40.

綜上所述,本發明所提供之氣體清淨複合材料及具有其之氣體清淨複合模組,其觸媒材料與吸附材料之總體積之間,或者,其觸媒材料與吸附材料之總重量之間,或者,觸媒材料的觸媒厚度,具有特殊的設計比例及數值,不僅結合了觸媒材料與吸附材料的氣體清淨效果,而且可提升氣體清淨效率、循環使用,且使用壽命長。 In summary, the gas purification composite material and the gas purification composite module provided by the present invention have a special design ratio and value between the total volume of the catalyst material and the adsorbent material, or the total weight of the catalyst material and the adsorbent material, or the catalyst thickness of the catalyst material, which not only combines the gas purification effect of the catalyst material and the adsorbent material, but also improves the gas purification efficiency, recycling, and long service life.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed as above by the embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be subject to the scope of the attached patent application.

1:氣體清淨複合材料 1: Gas purification composite material

10:觸媒材料 10: Catalyst materials

11:基材 11: Base material

12:觸媒 12: Catalyst

20:吸附材料 20: Adsorption material

2:氣體清淨複合模組 2: Gas purification composite module

30:載台 30: Carrier

31:承載單元 31: Carrier unit

32:孔洞 32: Holes

33:第一面 33: First page

34:第二面 34: Second side

40:觸媒作用模組設置 40: Catalyst action module settings

A1,A2:總體積 A1, A2: Total volume

D:距離 D: Distance

G1:氣體 G1: Gas

G2:乾淨氣體 G2: Clean gas

T:厚度 T:Thickness

W1,W2:總重量 W1, W2: total weight

圖1為本發明之氣體清淨複合材料之一實施例之結構示意圖。 Figure 1 is a schematic diagram of the structure of an embodiment of the gas purification composite material of the present invention.

圖2為本發明之氣體清淨複合模組之一實施例之結構示意圖。 Figure 2 is a schematic structural diagram of an embodiment of the gas purification composite module of the present invention.

1:氣體清淨複合材料 1: Gas purification composite material

10:觸媒材料 10: Catalyst materials

11:基材 11: Base material

12:觸媒 12: Catalyst

20:吸附材料 20: Adsorption material

T:厚度 T:Thickness

Claims (7)

一種氣體清淨複合材料,包含:複數呈顆粒狀之觸媒材料,用以產生觸媒作用以分解氣體中的有機物,該觸媒材料係於基材之表面塗布觸媒所構成,該基材之表面之該觸媒之厚度等於或小於20微米,該觸媒材料粒徑界於6~50奈米(nm)之範圍,該基材包括吸附材料、非吸附材料;以及複數呈顆粒狀之吸附材料,用以吸附氣體中的微粒;其中,該觸媒材料的總體積為A1,該吸附材料的總體積為A2,A1:A2之比例介於1:6~1:20之間;該基材之表面之該觸媒之總重量為W1,該基材與該吸附材料的總重量為W2,W1/W2之比例介於5%~15%之間,該觸媒材料與該吸附材料之表面積比介於500-2000平方公尺/公克。 A gas purification composite material comprises: a plurality of granular catalyst materials for generating catalytic action to decompose organic matter in the gas, the catalyst material is formed by coating the catalyst on the surface of a substrate, the thickness of the catalyst on the surface of the substrate is equal to or less than 20 microns, the particle size of the catalyst material is within the range of 6 to 50 nanometers (nm), the substrate comprises an adsorbent material and a non-adsorbent material; and a plurality of granular adsorbent materials for adsorbing Particles in the gas; wherein the total volume of the catalyst material is A1, the total volume of the adsorbent material is A2, and the ratio of A1:A2 is between 1:6 and 1:20; the total weight of the catalyst on the surface of the substrate is W1, the total weight of the substrate and the adsorbent material is W2, the ratio of W1/W2 is between 5% and 15%, and the surface area ratio of the catalyst material to the adsorbent material is between 500-2000 square meters/gram. 如請求項1之氣體清淨複合材料,其中該觸媒可為光觸媒、熱觸媒或可產生觸媒作用的其他種類觸媒。 As in claim 1, the gas purification composite material, wherein the catalyst may be a photocatalyst, a thermal catalyst, or other types of catalysts that can produce a catalytic effect. 如請求項1之氣體清淨複合材料,其中該吸附材料包括活性碳、沸石。 As in claim 1, the gas purification composite material, wherein the adsorption material includes activated carbon and zeolite. 如請求項1之氣體清淨複合材料,其中該觸媒包括金(Au)、銀(Ag)或二氧化鈦(TiO2)。 The gas purification composite material of claim 1, wherein the catalyst comprises gold (Au), silver (Ag) or titanium dioxide (TiO 2 ). 一種具有請求項1至4中的其中一項之氣體清淨複合材料的氣體清淨複合模組,其包含:一載台,其具有至少一承載單元,該承載單元連通該載台的相對兩面,於該承載單元中設置有該氣體清淨複合材料;氣體由該載台之第一面流入該承載單元並通過該氣體清淨複合材料,再由該載台相對於該第一面之第 二面流出。 A gas purification composite module having a gas purification composite material according to any one of claims 1 to 4, comprising: a carrier having at least one supporting unit, the supporting unit connecting two opposite sides of the carrier, the gas purification composite material being arranged in the supporting unit; gas flows into the supporting unit from the first side of the carrier and passes through the gas purification composite material, and then flows out from the second side of the carrier opposite to the first side. 如請求項5之氣體清淨複合模組,其更包括一觸媒作用模組,該觸媒作用模組與該氣體清淨複合模組的距離等於或小於0.5公分。 The gas purification composite module of claim 5 further includes a catalyst action module, and the distance between the catalyst action module and the gas purification composite module is equal to or less than 0.5 cm. 如請求項5之氣體清淨複合模組,該觸媒作用模組包括紫外線燈、加熱器。 For example, in the gas purification composite module of claim 5, the catalyst action module includes an ultraviolet lamp and a heater.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107174946A (en) * 2017-06-09 2017-09-19 北京丰泽绿源环境技术有限公司 A kind of indoor air handler and method
TW201808446A (en) * 2016-06-30 2018-03-16 巴斯夫公司 Manganese oxide based catalyst and catalyst device for the removal of formaldehyde and volatile organic compounds
CN211098254U (en) * 2019-11-15 2020-07-28 深圳中汇新材料科技有限公司 Graphene photocatalyst air harmful substance adsorption box

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2991195B1 (en) * 1998-08-19 1999-12-20 日本電気株式会社 Air purifier and air cleaning system using environmental catalyst
TWI286492B (en) * 2004-12-28 2007-09-11 Ind Tech Res Inst Catalytic inorganic membrane and using the same
JP2011072961A (en) * 2009-10-01 2011-04-14 Toei Sangyo Kk Adsorbing and decomposing material, and method for producing adsorbing and decomposing material
CN108295842A (en) * 2018-02-05 2018-07-20 唐吉龙 A kind of composite photocatalyst material for air purifier
TWM615347U (en) * 2020-11-27 2021-08-11 創星淨聯科技股份有限公司 Air purification module having air purification material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201808446A (en) * 2016-06-30 2018-03-16 巴斯夫公司 Manganese oxide based catalyst and catalyst device for the removal of formaldehyde and volatile organic compounds
CN107174946A (en) * 2017-06-09 2017-09-19 北京丰泽绿源环境技术有限公司 A kind of indoor air handler and method
CN211098254U (en) * 2019-11-15 2020-07-28 深圳中汇新材料科技有限公司 Graphene photocatalyst air harmful substance adsorption box

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