TWI857969B - Polymers for use in electronic devices - Google Patents

Abstract

Disclosed is a polyamine having Formula I. In Formula I: Q¹ is H, R¹ , or R⁹ ; Q² is of H, R² , or R⁹ ; Q³ is R³ or R⁹ ; Q⁴ is R⁴ or R⁹ ; Q⁵ is R⁷ or R⁹ ; R¹ and R² are the same or different at each occurrence and are F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, siloxy, unsubstituted or substituted hydrocarbon aryl, unsubstituted or substituted heteroaryl, or unsubstituted or substituted aryloxy; R³ , R⁴ , R⁵ , R⁶ , and R⁷ are the same or different and are H, F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, siloxy, unsubstituted or substituted hydrocarbon aryl, unsubstituted or substituted heteroaryl, or unsubstituted or substituted aryloxy; R⁸ is alkyl, silyl, unsubstituted or substituted hydrocarbon aryl, or unsubstituted or substituted heteroaryl; R⁹ is the same or different at each occurrence and is NH₂ or ArNH₂ ; Ar is the same or different at each occurrence and is an unsubstituted or substituted C_6-18 hydrocarbon aryl; and a and b are the same or different and are an integer from 0-3. In Formula I, at least two of Q¹ through Q⁵ are R⁹ .

Description

Polymers used in electronic devices

The present disclosure relates to novel polymeric compounds. The present disclosure further relates to methods for preparing such polymeric compounds and electronic devices having at least one layer comprising such materials.

Materials used in electronic applications often have stringent requirements with respect to their structural, optical, thermal, electronic and other properties. As the number of commercial electronic applications continues to increase, the breadth and specificity of the properties required requires innovation in materials with new and/or improved properties. Polyimides represent a class of polymeric compounds that are widely used in a variety of electronic applications. They can serve as flexible alternatives to glass in electronic display devices, provided that they have the right properties. Such materials can be used as components of liquid crystal displays ("LCDs"), where their moderate electrical power consumption, light weight and layer flatness are key characteristics for practical utility. Other uses in electronic display devices where such parameters are prioritized include device substrates, substrates for color filters, cover films, touch screen panels, etc.

Many of these components are also important in the construction and operation of organic electronic devices with organic light emitting diodes ("OLEDs"). OLEDs are promising for many display applications due to their high power conversion efficiency and applicability to a wide range of end uses. They are increasingly used in cell phones, tablet devices, handheld/laptop computers, and other commercial products. In addition to low power consumption, these applications require displays with high information content, full color, and fast video rate response times.

Polyimide films generally have sufficient thermal stability, high glass transition temperature, and mechanical toughness to be worth considering for such applications. Moreover, polyimides generally do not develop haze when subjected to repeated flexing, so they are often preferred over other transparent substrates like polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) in flexible display applications.

Polyimides are typically hard, highly aromatic materials; and as a film/coating is formed, the polymer chains tend to orient in the plane of the film/coating. This results in a difference in refractive index parallel to the film versus perpendicular to it (birefractive index), producing light retardation that can adversely affect display performance. New monomers with novel structural features may result in polyimides with improved properties for specific applications.

There is a continuing need for polymer materials suitable for use in electronic devices.

Provided is a polyamine having formula I: , wherein: ^Q1 is selected from the group consisting of H, ^R1 , and ^R9 ; ^Q2 is selected from the group consisting of H, ^R2 , and ^R9 ; ^Q3 is selected from the group consisting of ^R3 and ^R9 ; ^Q4 is selected from the group consisting of ^R4 and ^R9 ; ^Q5 is selected from the group consisting of ^R7 and ^R9 ; ^R1 and ^R2 are the same or different at each occurrence and are selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; ^R3 , ^R4 , ^R5 , ^R6 , and R ^R7 is the same or different and is selected from the group consisting of H, F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; ^R8 is selected from the group consisting of alkyl, silyl, unsubstituted or substituted aryl, and unsubstituted or substituted heteroaryl; ^R9 is the same or different at each occurrence and is selected from the group consisting of _NH2 and _ArNH2 ; Ar is the same or different at each occurrence and is unsubstituted or substituted _C6-18 aryl; and a and b are the same or different and are integers from 0 to 3; the premise is that at least two of ^Q1 to ^Q5 are ^R9 .

Further provided is a polyamine having repeating units of formula II: , wherein: ^Ra is the same or different at each occurrence and represents one or more tetracarboxylic acid component residues; and ^Rb is the same or different at each occurrence and represents one or more aromatic diamine residues; wherein 10-100 mol% of ^Rb is derived from one or more diamine residues of a diamine having formula I.

Further provided is a composition comprising (a) a polyamine having repeating units of formula II and (b) a high boiling point aprotic solvent.

Further provided is a polyimide having a repeating unit having the structure of Formula III: , wherein ^Ra and ^Rb are as defined in Formula II.

Further provided is a polyimide membrane comprising a polyimide having repeating units of formula III.

Further provided are one or more methods for preparing polyimide membranes, wherein the polyimide has repeating units of formula III.

Further provided is a flexible replacement for glass in electronic devices, wherein the flexible replacement for glass is a polyimide film comprising a polyimide having repeating units of Formula III.

Further provided is an electronic device having at least one layer, the at least one layer comprising a polyimide film, the polyimide film comprising a polyimide having repeating units of Formula III.

Further provided is an organic electronic device, such as an OLED, wherein the organic electronic device contains a flexible replacement for glass as disclosed herein.

The foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the invention as defined by the appended claims.

A polyamine having formula I is provided as described in detail below.

Further provided is a polyamine having repeating units of formula II as described in detail below.

Further provided is a composition comprising (a) a polyamine having repeating units of formula II and (b) a high boiling point aprotic solvent.

Further provided is a polyimide as described in detail below, the repeating unit of the polyimide having the structure of Formula III.

Further provided are one or more methods for preparing polyimide membranes, wherein the polyimide has repeating units of formula III.

Further provided is a flexible replacement for glass in electronic devices, wherein the flexible replacement for glass is a polyimide film comprising a polyimide having repeating units of Formula III.

Further provided is an electronic device having at least one layer, the at least one layer comprising a polyimide film, the polyimide film comprising a polyimide having repeating units of Formula III.

Further provided is an organic electronic device, such as an OLED, wherein the organic electronic device contains a flexible replacement for glass as disclosed herein.

Many aspects and embodiments have been described above and are exemplary and non-restrictive only. After reading this specification, skilled artisans will appreciate that other aspects and embodiments are possible without departing from the scope of the invention.

Other features and benefits of any one or more embodiments will be apparent from the following detailed description and from the claims. The detailed description first presents definitions and clarifications of terms, followed by polyamines of Formula I, polyamides, polyimides, methods for preparing polyimide films, electronic devices, and finally examples.

1.     Definition and clarification of terms

Before presenting the details of the following embodiments, some terms are defined or clarified.

As used in the “Definition and Illustrative Terms”, R, ^Ra , ^Rb , R′, R″ and any other variables are generic names and may be the same as or different from those defined in the formulae.

The term "orientation layer" is intended to refer to the organic polymer layer in a liquid crystal device (LCD) that aligns the molecules closest to each plate as a result of it being rubbed onto the LCD glass in a preferred direction during the LCD manufacturing process.

As used herein, the term "alkyl" includes branched and straight chain saturated aliphatic alkyl groups. Unless otherwise indicated, the term is also intended to include cyclic groups. Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, isobutyl, dibutyl, tertiary butyl, pentyl, isopentyl, neopentyl, cyclopentyl, hexyl, cyclohexyl, isohexyl, etc. The term "alkyl" further includes both substituted and unsubstituted alkyl groups. In some embodiments, the alkyl group can be mono-, di- and tri-substituted. An example of a substituted alkyl group is trifluoromethyl. Other substituted alkyl groups are formed by one or more of the substituents described herein. In certain embodiments, the alkyl group has 1 to 20 carbon atoms. In other embodiments, the group has 1 to 6 carbon atoms. The term is intended to include heteroalkyl groups. Heteroalkyl groups may have from 1 to 20 carbon atoms.

The term "aprotic" refers to a class of solvents that lack acidic hydrogen atoms and therefore cannot act as hydrogen donors. Common aprotic solvents include alkanes, carbon tetrachloride (CCl4), benzene, dimethylformamide (DMF), N-methyl-2-pyrrolidone (NMP), dimethylacetamide (DMAc), etc.

The term "aromatic compound" is intended to refer to an organic compound containing at least one unsaturated cyclic group having 4n+2 delocalized π electrons. The term is intended to cover both aromatic compounds, which have only carbon and hydrogen atoms, and heteroaromatic compounds, in which one or more carbon atoms in the cyclic group has been replaced by another atom such as nitrogen, oxygen, sulfur, etc.

The term "aryl" or "aryl group" refers to a moiety formed by removing one or more hydrogen ("H") or deuterium ("D") from an aromatic compound. An aryl group can be a single ring (monocyclic) or have multiple rings (bicyclic or higher) fused together or covalently linked. "Alkaliaryl" has only carbon atoms in one or more aromatic rings. "Heteroaryl" has one or more heteroatoms in at least one aromatic ring. In some embodiments, alkaliaryl groups have 6 to 60 ring carbon atoms; in some embodiments, 6 to 30 ring carbon atoms. In some embodiments, heteroaryl groups have from 4 to 50 ring carbon atoms; in some embodiments, 4 to 30 ring carbon atoms.

The term "alkoxy" is intended to refer to the group -OR, where R is alkyl.

The term "aryloxy" is intended to refer to the group -OR, where R is aryl.

Unless otherwise indicated, all groups may be substituted or unsubstituted. Optionally substituted groups, such as but not limited to alkyl or aryl, may be substituted with one or more substituents which may be the same or different. Suitable substituents include alkyl, aryl, nitro, cyano, -N(R')(R ^" ), halogen, hydroxyl, carboxyl, alkenyl, alkynyl, cycloalkyl, heteroaryl, alkoxy, aryloxy, heteroaryloxy, alkoxycarbonyl, perfluoroalkyl, perfluoroalkoxy, arylalkyl, silyl, silaneoxy, siloxane, thioalkoxy, -S(O) _2- , -C(=O)-N(R')(R"), (R')(R")N-alkyl, (R')(R")N-alkoxyalkyl, (R')(R")N-alkylaryloxyalkyl, -S(O) _s -aryl (where s = 0 to 2), or -S(O) _s -heteroaryl (where s = 0 to 2). Each R' and R" is independently an optionally substituted alkyl, cycloalkyl or aryl group. R' and R", together with the nitrogen atom to which they are bound, can form a ring system in certain embodiments. The substituents can also be cross-linking groups.

The term "amine" is intended to refer to a compound containing a basic nitrogen atom with a lone pair of electrons, wherein a lone pair of electrons refers to a group of two valence electrons that are not shared with another atom. The term "amine group" refers to the functional group _-NH2 , -NHR, or _-NR2 , wherein R is the same or different at each occurrence and can be an alkyl group or an aryl group. The term "diamine" is intended to refer to a compound containing two basic nitrogen atoms with attached lone pairs of electrons. The term "polyamine" is intended to refer to a compound containing two or more basic nitrogen atoms with attached lone pairs of electrons. The term "aromatic diamine" is intended to refer to an aromatic compound having two amine groups. The term "aromatic polyamine" is intended to refer to an aromatic compound having two or more amine groups. The term "bent diamine" is intended to refer to diamines in which the two basic nitrogen atoms and the associated lone pairs of electrons are arranged asymmetrically around the symmetry center of the corresponding compound or functional group, such as m-phenylenediamine: .

The term "aromatic diamine residue" is intended to refer to a moiety bonded to two amine groups in an aromatic diamine. The term "aromatic polyamine residue" is intended to refer to a moiety bonded to two or more amine groups in an aromatic polyamine. The term "aromatic diisocyanate residue" is intended to refer to a moiety bonded to two isocyanate groups in an aromatic diisocyanate compound. The term "aromatic polyisocyanate residue" is intended to refer to a moiety bonded to two or more isocyanate groups in an aromatic polyisocyanate compound. This is further described below.

The terms "diamine residue" and "diisocyanate residue" are intended to refer to a moiety bonded to two amine groups or two isocyanate groups, respectively, wherein the moiety is aliphatic or aromatic. The terms "polyamine residue" and "polyisocyanate residue" are intended to refer to a moiety bonded to two or more amine groups or two or more isocyanate groups, respectively, wherein the moiety is aliphatic or aromatic.

The term "b*" is intended to refer to the b* axis in the CIELab color space, which represents the yellow/blue opposition colors. Yellow is represented by a positive b* value, and blue is represented by a negative b* value. The measured b* value may be affected by the solvent, particularly because solvent selection can affect the color measured on materials exposed to high temperature processing conditions. This may occur as a result of the inherent properties of the solvent and/or properties associated with low levels of impurities contained in the various solvents. A particular solvent is typically preselected to achieve the b* value desired for a particular application.

The term "bi-indexed" is intended to refer to the difference in refractive index in different directions in a polymer film or coating. The term usually refers to the difference between the refractive index along the x- or y-axis (in-plane) and the z-axis (out-of-plane).

The term "charge transport" when referring to a layer, material, component, or structure is intended to mean that such layer, material, component, or structure facilitates the migration of such charges through the thickness of such layer, material, component, or structure with relative efficiency and small charge loss. Hole transport materials favor positive charges; electron transport materials favor negative charges. Although luminescent materials may also have some charge transport properties, the term "charge transport layer, material, component, or structure" is not intended to include layers, materials, components, or structures whose primary function is to emit light.

The term "compound" is intended to mean an uncharged substance composed of molecules, which further include atoms, wherein the atoms cannot be separated from their corresponding molecules by physical means without breaking chemical bonds. The term is intended to include oligomers and polymers.

The term "coefficient of linear thermal expansion (CTE or α)" is intended to refer to the parameter that defines the amount a material expands or contracts with temperature. It is expressed as the change in length per degree Celsius and is usually expressed in units of µm/m/°C or ppm/°C. α = (ΔL/L ₀ )/ΔT

The measured CTE values disclosed herein are generated by known methods during the first or second heating scan. Understanding the relative expansion/contraction characteristics of a material can be an important consideration in the manufacture and/or reliability of electronic devices.

The term "dopant" is intended to refer to a material within a layer that includes a host material that changes one or more electronic properties or one or more target wavelengths of radiation emission, reception, or filtering of the layer as compared to the one or more electronic properties or one or more wavelengths of radiation emission, reception, or filtering of the layer in the absence of such material.

The term "electroactive" when referring to a layer or material is intended to mean a layer or material that electronically facilitates the operation of the device. Examples of electroactive materials include, but are not limited to, materials that conduct, inject, transport, or block electric charge, where the charge can be electrons or holes, or materials that emit radiation or exhibit a change in the concentration of electron-hole pairs when receiving radiation. Examples of inactive materials include, but are not limited to, planarizing materials, insulating materials, and environmental barrier materials.

The term "tensile elongation" or "tensile strain" is intended to refer to the percentage increase in length that occurs in a material before it breaks under an applied tensile stress. It can be measured, for example, by ASTM method D882.

The prefix "fluorine" is intended to indicate that one or more hydrogens in the group have been replaced by fluorine.

The term "glass transition temperature (or _Tg )" is intended to mean the temperature at which a reversible change occurs in an amorphous polymer, or in the noncrystalline regions of a semicrystalline polymer, in which the material suddenly changes from a hard, glassy or brittle state to a flexible or elastic state. Under a microscope, the glass transition occurs when normally coiled, stationary polymer chains become free to rotate and can move past each other. _Tg can be measured using differential scanning calorimetry (DSC), thermomechanical analysis (TMA), or dynamic mechanical analysis (DMA), or other methods.

The prefix "hetero" indicates that one or more carbon atoms have been replaced by different atoms. In some embodiments, the heteroatom is O, N, S, or a combination thereof.

The term "high boiling point" is intended to mean a boiling point above 130°C.

The term "host material" is intended to refer to the material to which the dopant is added. The host material may or may not have one or more electronic properties or capabilities to emit, receive, or filter radiation. In some embodiments, the host material is present in a relatively high concentration.

The term "isothermal weight loss" is intended to refer to a material property that is directly related to its thermal stability. It is typically measured via thermogravimetric analysis (TGA) at a constant target temperature. Materials with high thermal stability typically exhibit very low isothermal weight loss percentages at the required use or processing temperature over a desired time period, and can therefore be used in applications at that temperature without significant strength loss, outgassing, and/or structural changes.

The term "laser particle counter test" refers to a method used to evaluate the particle content of polyamide and other polymer solutions whereby a representative sample of the test solution is spun onto a 5" silicon wafer and soft baked/dried. The particle content of the film thus prepared is evaluated by any number of standard measurement techniques. Such techniques include laser particle detection and other techniques known in the art.

The term "liquid composition" is intended to refer to a liquid medium in which a material is dissolved to form a solution, a liquid medium in which a material is dispersed to form a dispersion, or a liquid medium in which a material is suspended to form a suspension or emulsion.

The term "substrate" is intended to refer to a base on which one or more layers are deposited, for example in the formation of an electronic device. Non-limiting examples include glass, silicon, etc.

The term "1% TGA weight loss" is intended to mean the temperature at which 1% of the original polymer weight is lost due to decomposition (excluding absorbed water).

The term "optical retardation (or _RTH )" is intended to refer to the difference between the average in-plane and out-of-plane refractive indices (ie, birefringence), which is then multiplied by the thickness of the film or coating. Optical retardation is typically measured for a given frequency of light and is reported in nanometers.

The term "organic electronic device" or sometimes "electronic device" is intended herein to refer to a device that includes one or more organic semiconductor layers or one or more materials.

The term "particle content" is intended to refer to the number or count of insoluble particles present in a solution. Measurement of particle content can be performed on the solution itself or on finished materials (sheets, films, etc.) prepared from those membranes. Various optical methods can be used to assess this property.

The term "photoactive" refers to a material or layer that emits light when activated by an applied voltage (as in a light-emitting diode or chemical cell), emits light after absorbing a photon (as in a down-converting phosphor device), or reacts to radiant energy and generates a signal with or without an applied bias (as in a photodetector or photovoltaic cell).

The term "polyamine solution" refers to a solution of a polymer containing an amide unit having an intramolecular cyclization ability to form an amide group.

The term "polyanhydride" refers to a compound having two or more anhydride groups. The term "polyanhydride residue" is intended to refer to a moiety bonded to two or more anhydride groups. This is further described below.

The term "polyimide" refers to a condensation polymer obtained by reacting one or more polyfunctional carboxylic acid components with one or more primary polyamines or polyisocyanates. They contain the imide structure -CO-NR-CO- as a linear or heterocyclic unit along the main chain of the polymer backbone.

The term "satisfactory" when referring to a material property or characteristic is intended to mean that the property or characteristic meets all requirements/needs of the material in use. For example, in the context of the polyimide membranes disclosed herein, an isothermal weight loss of less than 1% at 350°C for 3 hours in nitrogen can be considered a non-limiting example of a "satisfactory" property.

The term "soft bake" is intended to refer to a process commonly used in electronics manufacturing where a coated material is heated to drive off solvents and cure the film. Soft baking is typically performed at temperatures between 90°C and 110°C on a hot plate or in an exhaust oven as a preparation step for subsequent thermal treatment of the coated layer or film.

The term "substrate" refers to a base material that may be rigid or flexible and may include one or more layers of one or more materials, which may include but are not limited to glass, polymers, metals or ceramic materials or combinations thereof. The substrate may or may not include electronic components, circuits or conductive features.

The term "siloxane" refers to the group R ₃ SiOR ₂ Si-, where R is the same or different at each occurrence and is H, C _1-20 alkyl, fluoroalkyl, or aryl. In some embodiments, one or more carbons in the R alkyl group are replaced by Si.

The term "silanoloxy" refers to the group R ₃ SiO-, wherein R is the same or different at each occurrence and is H, C _1-20 alkyl, fluoroalkyl, or aryl.

The term "silyl" refers to the group R ₃ Si-, where R is the same or different at each occurrence and is H, C _1-20 alkyl, fluoroalkyl, or aryl. In some embodiments, one or more carbons in the R alkyl group are replaced by Si.

The term "spin coating" is intended to refer to a process used to deposit a uniform thin film onto a flat substrate. Generally, a small amount of coating material is applied to the center of the substrate, which is spinning at a slow speed or not spinning at all. The substrate is then spun at a specified speed so that the coating material is spread evenly by centrifugal forces.

The term "spiro group" refers to a group having a bicyclic organic moiety, wherein the two rings have one common atom. The rings may be different or identical in nature and may form part of other ring systems. The common atom has two bonds in each ring and is called a spiro atom. In some embodiments, the spiro atom is selected from the group consisting of C and Si.

The term "tensile modulus" is intended to refer to a measure of the stiffness of a solid material that defines the initial relationship between stress (force per unit area) and strain (proportional deformation) in a material such as a film. The unit commonly used is the gigapascal (GPa).

The term "tetracarboxylic acid component" is intended to refer to any one or more of the following: tetracarboxylic acid, tetracarboxylic acid monoanhydride, tetracarboxylic acid dianhydride, tetracarboxylic acid monoester, and tetracarboxylic acid diester.

The term "tetracarboxylic acid component residue" is intended to refer to a moiety bonded to four carboxyl groups in the tetracarboxylic acid component. This is further described below.

The term "transmittance" refers to the percentage of light of a given wavelength impinging on a film that passes through the film so as to be detectable on the other side. Light transmittance measurements in the visible region (380 nm to 800 nm) are particularly useful for characterizing the film color characteristics that are most important for understanding the in-use properties of the polyimide films disclosed herein.

The term "yellowness index (or YI)" refers to the magnitude of yellowness relative to a standard. Positive values of YI indicate the presence and magnitude of yellow. Materials with negative YI appear bluish. It should also be noted, particularly for polymerization and/or curing processes run at high temperatures, that the YI can be solvent dependent. For example, the magnitude of color introduced using DMAC as a solvent may be different from the magnitude of color introduced using NMP as a solvent. This can occur as a result of the inherent properties of the solvent and/or properties associated with the low levels of impurities contained in the various solvents. A particular solvent is typically preselected to achieve the YI value desired for a particular application. In structures in which a substituent bond passes through one or more rings as shown below: , which means that the substituent R can be bonded at any available position on one or more rings.

When used to refer to layers in a device, the phrase "adjacent" does not necessarily mean that one layer is immediately adjacent to another layer. On the other hand, the phrase "adjacent R groups" is used to refer to R groups that are adjacent to each other in a chemical formula (i.e., R groups on atoms that are bound by a bond). Exemplary adjacent R groups are shown below: .

In this specification, unless otherwise expressly indicated or indicated to the contrary by the context of use, where an embodiment of the inventive subject matter is stated or described as comprising, including, containing, having, consisting of, or consisting of certain features or elements, one or more features or elements in addition to those expressly stated or described may also be present in that embodiment. An alternative embodiment of the disclosed inventive subject matter is described as consisting essentially of certain features or elements, wherein features or elements of the embodiment that would substantially change the principle of operation or the distinguishing characteristics of the embodiment are not present therein. Another alternative embodiment of the described inventive subject matter is described as consisting of certain features or elements, in which embodiment, or in insubstantial variations thereof, only the features or elements specifically stated or described are present.

In addition, unless expressly stated to the contrary, "or" refers to an inclusive "or" and not to an exclusive "or". For example, condition A or B is satisfied by any of the following: A is true (or exists) and B is false (or does not exist), A is false (or does not exist) and B is true (or exists), and both A and B are true (or exist).

Moreover, "a/an" is used to describe the elements and components described herein. This is done only for convenience and to give a general sense of the scope of the invention. This description should be interpreted to include one or at least one and the singular also includes the plural unless it is obvious that it is meant otherwise.

The group numbers corresponding to columns in the Periodic Table of the Elements use the "New Notation" convention as found in the CRC Handbook of Chemistry and Physics , 81st edition (2000–2001).

Unless otherwise defined, all technical and scientific terms used herein have the same meanings as commonly understood by those of ordinary skill in the art. Although methods and materials similar or equivalent to those described herein can be used in the practice or testing of embodiments of the present invention, suitable methods and materials are described below. Unless specific paragraphs are cited, all publications, patent applications, patents, and other references mentioned herein are incorporated herein by reference in their entirety. In the event of a conflict, the present specification, including definitions, shall prevail. In addition, the materials, methods, and examples are illustrative only and are not intended to be limiting.

To the extent not described herein, many details regarding specific materials, processing behavior, and circuits are conventional and can be found in textbooks and other sources in the field of organic light emitting diode displays, photodetectors, photovoltaics, and semiconductor components.

2.     Polyamines having formula I

The polyamines described herein have Formula I: , wherein: ^Q1 is selected from the group consisting of H, ^R1 , and ^R9 ; ^Q2 is selected from the group consisting of H, ^R2 , and ^R9 ; ^Q3 is selected from the group consisting of ^R3 and ^R9 ; ^Q4 is selected from the group consisting of ^R4 and ^R9 ; ^Q5 is selected from the group consisting of ^R7 and ^R9 ; ^R1 and ^R2 are the same or different at each occurrence and are selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; ^R3 , ^R4 , ^R5 , ^R6 , and R ^R7 is the same or different and is selected from the group consisting of H, F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; ^R8 is selected from the group consisting of alkyl, silyl, unsubstituted or substituted aryl, and unsubstituted or substituted heteroaryl; ^R9 is the same or different at each occurrence and is selected from the group consisting of _NH2 and _ArNH2 ; Ar is the same or different at each occurrence and is unsubstituted or substituted _C6-18 aryl; and a and b are the same or different and are integers from 0 to 3; the premise is that at least two of ^Q1 to ^Q5 are ^R9 .

In some embodiments of Formula I, exactly two of ^Q1 to ^Q5 are ^R9 .

In some embodiments of Formula I, Q ¹ and Q ² are R ⁹ .

In some embodiments of Formula I, Q ³ and Q ⁴ are R ⁹ .

In some embodiments of Formula I, Q ¹ and Q ⁵ are R ⁹ .

In some embodiments of Formula I, Q ¹ is R ⁹ .

In some embodiments of Formula I, Q ¹ is H.

In some embodiments of Formula I, Q ¹ is F.

In some embodiments of Formula I, Q ¹ is CN.

In some embodiments of Formula I, Q ¹ is C _1-20 alkyl; in some embodiments, it is C _1-10 alkyl.

In some embodiments of Formula I, Q ¹ is C _1-20 fluoroalkyl; in some embodiments, C _1-10 fluoroalkyl.

In some embodiments of Formula I, Q ¹ is C _1-20 perfluoroalkyl; in some embodiments, it is C _1-10 perfluoroalkyl.

In some embodiments of Formula I, Q ¹ is C _1-20 alkoxy; in some embodiments, it is C _1-10 alkoxy.

In some embodiments of Formula I, Q ¹ is C _1-20 fluoroalkoxy; in some embodiments, C _1-10 fluoroalkoxy.

In some embodiments of Formula I, Q ¹ is C _1-20 perfluoroalkoxy; in some embodiments, it is C _1-10 perfluoroalkoxy.

In some embodiments of Formula I, Q ¹ is SiH ₃ .

In some embodiments of Formula I, Q ¹ is C _1-12 silyl; in some embodiments, it is C _3-6 silyl.

In some embodiments of Formula I, Q ¹ is C _1-12 silanoxy; in some embodiments, it is C _3-6 silanoxy.

In some embodiments of Formula I, Q ¹ is unsubstituted or substituted C _6-30 aryl; in some embodiments, it is unsubstituted or substituted C _6-18 aryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, Q ¹ is unsubstituted or substituted C _3-30 heteroaryl; in some embodiments, it is unsubstituted or substituted C _3-18 heteroaryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, Q ¹ is unsubstituted or substituted C _6-30 aryloxy; in some embodiments, it is unsubstituted or substituted C _6-18 aryloxy; in some embodiments, it is unsubstituted.

In some embodiments, any of the above aryl, heteroaryl, and aryloxy groups is further substituted with one or more substituents selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, and silalkoxy.

All of the above-described embodiments of Q ¹ in Formula I are equally applicable to Q ² , Q ³ , Q ⁴ , and Q ⁵ in Formula I.

In some embodiments of Formula I, a = 0.

In some embodiments of Formula I, a=1.

In some embodiments of Formula I, a=2.

In some embodiments of Formula I, a=3.

In some embodiments of Formula I, a > 0.

In some embodiments of Formula I, a>0 and at least one R ¹ is F.

In some embodiments of Formula I, a>0 and at least one R ¹ is CN.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 alkyl; in some embodiments, it is C _1-10 alkyl.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 fluoroalkyl; in some embodiments, C _1-10 fluoroalkyl.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 perfluoroalkyl; in some embodiments, C _1-10 perfluoroalkyl.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 alkoxy; in some embodiments it is C _1-10 alkoxy.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 fluoroalkoxy; in some embodiments, C _1-10 fluoroalkoxy.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-20 perfluoroalkoxy; in some embodiments, C _1-10 perfluoroalkoxy.

In some embodiments of Formula I, a > 0 and at least one R ¹ is SiH ₃ .

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-12 silyl; in some embodiments, it is C _3-6 silyl.

In some embodiments of Formula I, a>0 and at least one R ¹ is C _1-12 silanoxy; in some embodiments, it is C _3-6 silanoxy.

In some embodiments of Formula I, a>0 and at least one R ¹ is unsubstituted or substituted C _6-30 aryl; in some embodiments, it is unsubstituted or substituted C _6-18 aryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, a>0 and at least one R ¹ is unsubstituted or substituted C _3-30 heteroaryl; in some embodiments, it is unsubstituted or substituted C _3-18 heteroaryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, a>0 and at least one R ¹ is unsubstituted or substituted C _6-30 aryloxy; in some embodiments, it is unsubstituted or substituted C _6-18 aryloxy; in some embodiments, it is unsubstituted.

In some embodiments, any of the above aryl, heteroaryl, and aryloxy groups is further substituted with one or more substituents selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, and silalkoxy.

In some embodiments of Formula I, b = 0.

In some embodiments of Formula I, b = 1.

In some embodiments of Formula I, b = 2.

In some embodiments of Formula I, b = 3.

In some embodiments of Formula I, b > 0.

In some embodiments of Formula I, b>0 and at least one ^R2 is F.

In some embodiments of Formula I, b>0 and at least one R ² is CN.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 alkyl; in some embodiments, it is C _1-10 alkyl.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 fluoroalkyl; in some embodiments, C _1-10 fluoroalkyl.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 perfluoroalkyl; in some embodiments, C _1-10 perfluoroalkyl.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 alkoxy; in some embodiments it is C _1-10 alkoxy.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 fluoroalkoxy; in some embodiments, C _1-10 fluoroalkoxy.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-20 perfluoroalkoxy; in some embodiments, it is C _1-10 perfluoroalkoxy.

In some embodiments of Formula I, b > 0 and at least one R ² is SiH ₃ .

In some embodiments of Formula I, b>0 and at least one R ² is C _1-12 silyl; in some embodiments, it is C _3-6 silyl.

In some embodiments of Formula I, b>0 and at least one R ² is C _1-12 silanoxy; in some embodiments, it is C _3-6 silanoxy.

In some embodiments of Formula I, b>0 and at least one R ² is unsubstituted or substituted C _6-30 aryl; in some embodiments, it is unsubstituted or substituted C _6-18 aryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, b>0 and at least one R ² is unsubstituted or substituted C _3-30 heteroaryl; in some embodiments, it is unsubstituted or substituted C _3-18 heteroaryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, b>0 and at least one R ² is unsubstituted or substituted C _6-30 aryloxy; in some embodiments, it is unsubstituted or substituted C _6-18 aryloxy; in some embodiments, it is unsubstituted.

In some embodiments, any of the above aryl, heteroaryl, and aryloxy groups is further substituted with one or more substituents selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, and silalkoxy.

In some embodiments of Formula I, R ⁵ = R ⁶ .

In some embodiments of Formula I, R ⁵ ≠ R ⁶ .

In some embodiments of Formula I, R ⁵ = R ⁶ = H.

In some embodiments of Formula I, R ⁵ is H.

In some embodiments of Formula I, R ⁵ is F.

In some embodiments of Formula I, R ⁵ is CN.

In some embodiments of Formula I, R ⁵ is C _1-20 alkyl; in some embodiments, C _1-10 alkyl.

In some embodiments of Formula I, R ⁵ is C _1-20 fluoroalkyl; in some embodiments, C _1-10 fluoroalkyl.

In some embodiments of Formula I, R ⁵ is C _1-20 perfluoroalkyl; in some embodiments, C _1-10 perfluoroalkyl.

In some embodiments of Formula I, R ⁵ is C _1-20 alkoxy; in some embodiments, C _1-10 alkoxy.

In some embodiments of Formula I, R ⁵ is C _1-20 fluoroalkoxy; in some embodiments, C _1-10 fluoroalkoxy.

In some embodiments of Formula I, R ⁵ is C _1-20 perfluoroalkoxy; in some embodiments, C _1-10 perfluoroalkoxy.

In some embodiments of Formula I, R ⁵ is SiH ₃ .

In some embodiments of Formula I, R ⁵ is C _1-12 silyl; in some embodiments, it is C _3-6 silyl.

In some embodiments of Formula I, R ⁵ is C _1-12 silanoxy; in some embodiments, it is C _3-6 silanoxy.

In some embodiments of Formula I, R ⁵ is unsubstituted or substituted C _6-30 aryl; in some embodiments, it is C _6-18 aryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, R ⁵ is unsubstituted or substituted C _3-30 heteroaryl; in some embodiments, it is C _3-18 heteroaryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, R ⁵ is unsubstituted or substituted C _6-30 aryloxy; in some embodiments, it is C _6-18 aryloxy; in some embodiments, it is unsubstituted.

In some embodiments, any of the above aryl, heteroaryl, and aryloxy groups is further substituted with one or more substituents selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, and silalkoxy.

All of the above-described embodiments of R ⁵ in Formula I are equally applicable to R ⁶ in Formula I.

In some embodiments of Formula I, R ⁸ is C _1-20 alkyl; in some embodiments, C _1-10 alkyl.

In some embodiments of Formula I, R ⁸ is C _1-12 silyl; in some embodiments, it is C _3-6 silyl.

In some embodiments of Formula I, R ⁸ is unsubstituted or substituted C _6-30 aryl; in some embodiments, it is C _6-18 aryl; in some embodiments, it is unsubstituted.

In some embodiments of Formula I, R ⁸ is unsubstituted or substituted C _3-30 heteroaryl; in some embodiments, it is C _3-18 heteroaryl; in some embodiments, it is unsubstituted.

In some embodiments, any of the above aryl and heteroaryl groups is further substituted with one or more substituents selected from the group consisting of F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, and silanyloxy.

In some embodiments of Formula I, two R ⁹ groups are present and are the same.

In some embodiments of Formula I, two R ⁹ groups are present and are different.

In some embodiments of Formula I, there are three ^R9 groups and all are the same. In some embodiments, two or three of the ^R9 groups are different.

In some embodiments of Formula I, there are four ^R9 groups and all are the same. In some embodiments, two, three, or four of the ^R9 groups are different.

In some embodiments of Formula I, there are five ^R9 groups and all are the same. In some embodiments, two, three, four, or five of the ^R9 groups are different.

In some embodiments of Formula I, at least one R ⁹ is NH ₂ .

In some embodiments of Formula I, at least one R ⁹ is ArNH ₂ .

In some embodiments of Formula I, at least one R ⁹ is ArNH ₂ , wherein Ar has the formula a: , wherein: R ¹⁰ and R ¹¹ are the same or different at each occurrence and are selected from the group consisting of F, CN, alkyl, fluoroalkyl, unsubstituted or substituted alkaryl, unsubstituted or substituted heteroaryl, alkoxy, fluoroalkoxy, unsubstituted or substituted aryloxy, silyl, and silalkoxy, wherein adjacent R ¹⁰ and/or R ¹¹ groups may be linked together to form a fused ring; p and q are the same or different and are integers from 0 to 4; s is an integer from 0 to 3; and * indicates an attachment point.

In some embodiments of Formula I, Ar is selected from the group consisting of phenyl, biphenyl, and naphthyl, which may be unsubstituted or substituted. In some embodiments, Ar has at least one substituent selected from the group consisting of F, alkyl, fluoroalkyl, alkoxy, and fluoroalkoxy.

In some embodiments of Formula I, the polyamine has Formula IA: , wherein R ¹ to R ⁹ , a, and b are as defined in Formula I. All of the above-described embodiments of R ¹ to R ⁹ , a, and b in Formula I are equally applicable to R ¹ to R ⁹ , a, and b in Formula IA.

In some embodiments of Formula I, the polyamine has Formula IB: , wherein R ¹ , R ² , R ⁵ to R ⁹ , a, and b are as defined in Formula I. All of the above-described embodiments of R ¹ , R ² , R ⁵ to R ⁹ , a, and b in Formula I are equally applicable to R ¹ , R ² , R ⁵ to R ⁹ , a, and b in Formula IB.

In some embodiments of Formula I, the polyamine has Formula IC: , wherein ^R1 to ^R6 , ^R8 , ^R9 , a, and b are as defined in Formula I. All of the above-described embodiments of ^R1 to ^R6 , ^R8 , ^R9 , a, and b in Formula I are equally applicable to ^R1 to ^R6 , ^R8 , ^R9 , a, and b in Formula IC.

The new compounds can be prepared using any technique that will produce a C-C or C-N bond. A variety of such techniques are known, such as Suzuki, Yamamoto, Stille, Negishi and metal-catalyzed C-N couplings and metal-catalyzed and oxidative direct arylations, and Diels-Alder cycloaddition reactions. Exemplary preparations are given in the Examples.

A synthetic scheme is shown below: .

In the above scheme, "Bpin" stands for boron pinacolate.

Any of the above embodiments of Formula I can be combined with one or more of the other embodiments, as long as they are not mutually exclusive. For example, the embodiment in which ^Q1 and ^Q2 are ^R7 can be combined with the embodiment in which at least one ^R7 is _NH2 , the embodiment in which a = 0, and the embodiment in which b = 0. A person skilled in the art will understand which embodiments are mutually exclusive and will therefore be easily able to determine the combinations of embodiments contemplated by the present application.

Some non-limiting examples of compounds having Formula I are shown below. Compound 1 Compound 2 Compound 3 Compound 4 Compound 5 Compound 6

3. Polyamine

The polyamine described herein is a reaction product of one or more polyanhydrides and one or more polyamines, wherein 10-100 mol % of the one or more polyamines have formula I.

In some embodiments of the polyamines, a polyamine having Formula I is reacted.

In some embodiments of the polyamines, two different polyamines having Formula I are reacted.

In some embodiments of the polyamines, three different polyamines having Formula I are reacted.

In some embodiments of the polyamines, four different polyamines having Formula I are reacted.

In some embodiments of the polyamines, 20 to 100 mol% of the one or more polyamines have Formula I; in some embodiments, 30 to 100 mol%; in some embodiments, 40 to 100 mol%; in some embodiments, 50 to 100 mol%; in some embodiments, 60 to 100 mol%; in some embodiments, 70 to 100 mol%; in some embodiments, 80 to 100 mol%; in some embodiments, 90 to 100 mol%; in some embodiments, 100%.

In some embodiments of the polyamines, at least one additional polyamine is reacted with one or more polyamines having Formula I.

In some embodiments of the polyamines, an additional polyamine is reacted with one or more polyamines having Formula I.

In some embodiments of the polyamines, two additional polyamines are reacted with one or more polyamines having Formula I.

In some embodiments of the polyamines, three additional polyamines are reacted with one or more polyamines having Formula I.

In some embodiments of the polyamines, four additional polyamines are reacted with one or more polyamines having Formula I.

In some embodiments of the polyamine, the polyamine has a repeating unit structure of Formula II: , wherein: ^Ra is the same or different at each occurrence and represents one or more tetracarboxylic acid residues; and ^Rb is the same or different at each occurrence and represents one or more diamine residues; wherein 10-100 mol% of ^Rb is derived from residues of one or more diamines having formula I.

In some embodiments of Formula II, ^Ra represents a single tetracarboxylic acid component residue.

In some embodiments of Formula II, ^Ra represents two different tetracarboxylic acid component residues.

In some embodiments of Formula II, ^Ra represents three different tetracarboxylic acid residues.

In some embodiments of Formula II, ^Ra represents four different tetracarboxylic acid residues.

In some embodiments of Formula II, ^Ra represents one or more tetracarboxylic dianhydride residues.

Examples of suitable aromatic tetracarboxylic dianhydrides include, but are not limited to, pyromellitic dianhydride (PMDA), 3,3',4,4'-biphenyltetracarboxylic dianhydride (BPDA), 4,4'-oxydiphthalic anhydride (ODPA), 4,4'-hexafluoroisopropylidene diphthalic acid polyanhydride (6FDA), 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA), 3,3',4,4'-diphenyltetracarboxylic dianhydride (DPA), 4,4'-hexafluoroisopropylidene diphthalic acid polyanhydride (6FDA), 3,3',4,4'-diphenyltetracarboxylic dianhydride (DPA ... Benzene sulfonate tetracarboxylic dianhydride (DSDA), 4,4'-bisphenol-A dianhydride (BPADA), hydroquinone diphthalic anhydride (HQDEA), ethylene glycol bis(trimellitic anhydride) (TMEG-100), 4-(2,5-dihydroxytetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene-1,2-dicarboxylic anhydride (DTDA); 4,4'-bisphenol A dianhydride (BPADA), etc. and combinations thereof. The aromatic dianhydrides may be optionally substituted with groups known in the art, including alkyl, aryl, nitro, cyano, -N(R')(R ^" ), halogen, hydroxyl, carboxyl, alkenyl, alkynyl, cycloalkyl, heteroaryl, alkoxy, aryloxy, heteroaryloxy, alkoxycarbonyl, perfluoroalkyl, perfluoroalkoxy, arylalkyl, silyl, silaneoxy, siloxane, thioalkoxy, -S(O) _2- , -C(=O)-N(R')(R"), (R')(R")N-alkyl, (R')(R")N-alkoxyalkyl, (R')(R")N-alkylaryloxyalkyl, -S(O) _s -aryl (wherein s=0-2) or -S(O) _s -heteroaryl (wherein s=0-2). Each R' and R" is independently an alkyl, cycloalkyl or aryl group which is optionally substituted. R' and R", together with the nitrogen atom to which they are bound, can form a ring system in certain embodiments. The substituent can also be a crosslinking group.

In some embodiments of Formula II, ^Ra represents one or more residues from a tetracarboxylic dianhydride selected from the group consisting of PMDA, BPDA, 6FDA, and BTDA.

In some embodiments of Formula II, ^Ra represents a PMDA residue.

In some embodiments of Formula II, ^Ra represents a BPDA residue.

In some embodiments of Formula II, ^Ra represents a 6FDA residue.

In some embodiments of Formula II, ^Ra represents a BTDA residue.

In some embodiments of Formula II, ^Ra represents a PMDA residue and a BPDA residue.

In some embodiments of Formula II, ^Ra represents a PMDA residue and a 6FDA residue.

In some embodiments of Formula II, ^Ra represents a PMDA residue and a BTDA residue.

In some embodiments of Formula II, ^Ra represents a BPDA residue and a 6FDA residue.

In some embodiments of Formula II, ^Ra represents a BPDA residue and a BTDA residue.

In some embodiments of Formula II, ^Ra represents a 6FDA residue and a BTDA residue.

In some embodiments of Formula II, ^Ra represents a PMDA residue, a BPDA residue, and a 6FDA residue.

In Formula II, 10 to 100 mol % of R ^b represents diamine residues from one or more diamines having Formula I as shown above.

In some embodiments of Formula II, 10-100 mol % of R ^b represents a diamine residue from a diamine having Formula I as shown above.

In some embodiments of Formula II, 10-100 mol % of R ^b represents diamine residues from two different diamines, both of which have Formula I as shown above.

In some embodiments of Formula II, 10-100 mol% of ^Rb represents diamine residues from three different diamines all having Formula I as shown above.

In some embodiments of Formula II, 10 to 100 mol % of R ^b represents diamine residues from four or more different diamines all having Formula I as shown above.

In some embodiments of Formula II, 20-100 mol% of R ^b is derived from the residue of one or more diamines of Formula I; in some embodiments, 30-100 mol%; in some embodiments, 40-100 mol%; in some embodiments, 50-100 mol%; in some embodiments, 60-100 mol%; in some embodiments, 70-100 mol%; in some embodiments, 80-100 mol%; in some embodiments, 90-100 mol%; in some embodiments, 100%.

Any of the above embodiments of Formula I in Formula II may be combined with one or more of the other embodiments as long as they are not mutually exclusive.

In some embodiments of Formula II, R ^b represents a diamine residue from one or more diamines having Formula I and at least one additional diamine residue.

In some embodiments of Formula II, R ^b represents a diamine residue from one or more diamines having Formula I and an additional diamine residue.

In some embodiments of Formula II, R ^b represents a diamine residue from one or more diamines having Formula I and two additional diamine residues.

In some embodiments of Formula II, R ^b represents a diamine residue from one or more diamines having Formula I and three additional diamine residues.

In some embodiments of Formula II, the one or more additional diamine residues are derived from the residues of one or more additional aromatic diamines.

In some embodiments, the additional aromatic diamine is selected from the group consisting of p-phenylenediamine (PPD), 2,2'-dimethyl-4,4'-diaminobiphenyl (m-tolidine), 3,3'-dimethyl-4,4'-diaminobiphenyl (o-tolidine), 3,3'-dihydroxy-4,4'-diaminobiphenyl (HAB), 9,9'-bis(4-aminophenyl)fluorene (FDA), o-tolidine sulfone (TSN), 2,3,5,6-tetramethyl-1,4-phenylene diamine (TMPD), 2,4-diamino-1,3,5-trimethylbenzidine (DAM), 3,3',5,5'-tetramethylbenzidine (3355TMB), 2,2'-bis(trifluoromethyl)benzidine (TMPD), 2,4'-diamino-1,3,5-trimethylbenzidine (DAM), 3,3',5,5'-tetramethylbenzidine (3355TMB), 2,2'-bis(trifluoromethyl) ... 4,4'-[1,3-phenylenebis(1-methyl-ethylene)]bisaniline (Bis-M), 4,4'-[1,4-phenylenebis(1-methyl-ethylene)]bisaniline (Bis-P), 4,4'-oxydiphenylamine (4,4'-ODA), metaphenylenediamine (MPD), 3,4'-oxydiphenylamine (3,4'-ODA), 3,3'-diaminodiphenylsulfone (3,3'-DDS), 4,4'-diaminodiphenylsulfone (4,4'-DDS), 4 ,4'-Diaminodiphenyl sulfide (ASD), 2,2-bis[4-(4-amino-phenoxy)phenyl]sulfide (BAPS), 2,2-bis[4-(3-aminophenoxy)-phenyl]sulfide (m-BAPS), 1,4'-bis(4-aminophenoxy)benzene (TPE-Q), 1,3'-bis(4-aminophenoxy)benzene (TPE-R), 1,3'-bis(4-amino-phenoxy)benzene (APB-133), 4,4'-bis(4-aminophenoxy)biphenyl (BAPB), 4,4'-diaminophenylaniline (DABA), methylenebis(aminobenzoic acid) (MBAA), 1,3'-bis(4-aminophenoxy)-2,2-dimethyl hexafluoropropane (DANPG), 1,5-bis(4-aminophenoxy)pentane (DA5MG), 2,2'-bis[4-(4-aminophenoxyphenyl)]hexafluoropropane (HFBAPP), 2,2-bis(4-aminophenyl)hexafluoropropane (Bis-A-AF), 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane (Bis-AP-AF), 2,2-bis(3-amino-4-methylphenyl)hexafluoropropane (Bis-AT-AF), 4,4'-bis(4-amino-2-trifluoromethylphenoxy)biphenyl (6BFBAPB), 3,3'5,5'-tetramethyl-4,4'-diaminodiphenylmethane (TMMDA), etc. and combinations thereof.

In some embodiments of Formula II, ^R represents a diamine residue from one or more diamines having Formula I and a diamine residue from at least one additional diamine, wherein the additional diamine is selected from the group consisting of PPD, 4,4'-ODA, 3,4'-ODA, TFMB, Bis-A-AF, Bis-AT-AF, and Bis-P.

In some embodiments of Formula II, the moiety derived from the monoanhydride monomer is present as the capping group.

In some embodiments, the monoanhydride monomers are selected from the group consisting of phthalic anhydride and analogs and derivatives thereof.

In some embodiments, the monoanhydrides are present in an amount up to 5 mol % of the total tetracarboxylic acid composition.

In some embodiments of Formula II, the moiety derived from the monoamine monomer is present as the capping group.

In some embodiments, the monoamine monomers are selected from the group consisting of aniline and analogs and derivatives thereof.

In some embodiments, the monoamines are present in an amount up to 5 mol % of the total amine composition.

In some embodiments, the poly(amidite) has a weight average molecular weight ( _Mw ) greater than 100,000 based on gel permeation chromatography versus polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) greater than 150,000 based on gel permeation chromatography versus polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight (M _W ) greater than 200,000 based on gel permeation chromatography versus polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) greater than 250,000 based on gel permeation chromatography with polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight (M _W ) greater than 300,000 based on gel permeation chromatography versus polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) between 100,000 and 400,000 based on gel permeation chromatography with polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) between 200,000 and 400,000 based on gel permeation chromatography with polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) between 250,000 and 350,000 based on gel permeation chromatography with polystyrene standards.

In some embodiments, the polyamine has a weight average molecular weight ( _MW ) between 200,000 and 300,000 based on gel permeation chromatography with polystyrene standards.

Any of the above embodiments of polyamine may be combined with one or more of the other embodiments, as long as they are not mutually exclusive.

The overall polyamine composition can be named by symbols commonly used in the art. For example, a polyamine having a tetracarboxylic acid component of 100% ODPA and a diamine component of 90 mol% Bis-P and 10 mol% TFMB can be represented as: ODPA//Bis-P/TFMB 100//90/10.

Also provided is a liquid composition comprising (a) a polyamine having repeating units of formula II and (b) a high boiling point aprotic solvent. The liquid composition is also referred to herein as a "polyamine solution".

In some embodiments, the high boiling point aprotic solvent has a boiling point of 150°C or higher.

In some embodiments, the high boiling point aprotic solvent has a boiling point of 175°C or higher.

In some embodiments, the high boiling point aprotic solvent has a boiling point of 200°C or higher.

In some embodiments, the high boiling point aprotic solvent is a polar solvent. In some embodiments, the solvent has a dielectric constant greater than 20.

Some examples of high boiling point aprotic solvents include, but are not limited to, N-methyl-2-pyrrolidone (NMP), dimethylacetamide (DMAc), dimethylsulfoxide (DMSO), dimethylformamide (DMF), γ-butyrolactone, dibutyl carbitol, butyl carbitol acetate, diethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, and the like, and combinations thereof.

In some embodiments of the liquid composition, the solvent is selected from the group consisting of NMP, DMAc, and DMF.

In some embodiments of the liquid composition, the solvent is NMP.

In some embodiments of liquid compositions, the solvent is DMAc.

In some embodiments of liquid compositions, the solvent is DMF.

In some embodiments of the liquid composition, the solvent is gamma-butyrolactone.

In some embodiments of the liquid composition, the solvent is dibutyl carbitol.

In some embodiments of the liquid composition, the solvent is butyl carbitol acetate.

In some embodiments of the liquid composition, the solvent is diethylene glycol monoethyl ether acetate.

In some embodiments of the liquid composition, the solvent is propylene glycol monoethyl ether acetate.

In some embodiments, more than one of the above noted high boiling point aprotic solvents is used in the liquid composition.

In some embodiments, additional co-solvents are used in the liquid composition.

In some embodiments, the liquid composition is >1 wt % polyamine in >99 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 1 wt % to 5 wt % polyamine in 95 wt % to 99 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 5 wt % to 10 wt % polyamine in 90 wt % to 95 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 10 wt % to 15 wt % polyamine in 85 wt % to 90 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 15 wt % to 20 wt % polyamine in 80 wt % to 85 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 20 wt % to 25 wt % polyamine in 75 wt % to 80 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 25 wt % to 30 wt % polyamine in 70 wt % to 75 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 30 wt % to 35 wt % polyamine in 65 wt % to 70 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 35 wt % to 40 wt % polyamine in 60 wt % to 65 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 40 wt % to 45 wt % polyamine in 55 wt % to 60 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 45 wt % to 50 wt % polyamine in 50 wt % to 55 wt % high boiling point aprotic solvent.

In some embodiments, the liquid composition is 50 wt % polyamine in 50 wt % high boiling point aprotic solvent.

The polyamide solution may further contain any of a number of additives as desired. Such additives may be antioxidants, heat stabilizers, adhesion promoters, coupling agents (such as silanes), inorganic fillers or various reinforcing agents, as long as they do not adversely affect the desired properties of the polyimide.

The polyamine solution can be prepared using various available methods for introducing the components (i.e., monomers and solvents). Some methods of producing the polyamine solution include: (a)   A method in which the polyamine component and the polyacid anhydride component are premixed together and then the mixture is added to the solvent in batches while stirring. (b)   A method in which the solvent is added to the stirred mixture of the polyamine and polyacid anhydride components. (The opposite of (a) above) (c)   A method in which the polyamine is dissolved separately in the solvent and then the polyacid anhydride is added thereto in a ratio that allows the reaction rate to be controlled. (d)   A method in which the polyacid anhydride component is dissolved separately in the solvent and then the amine component is added thereto in a ratio that allows the reaction rate to be controlled. (e)   A method in which a polyamine component and a polyacid anhydride component are dissolved in a solvent respectively and then the solutions are mixed in a reactor. (f)   A method in which a polyamine acid having an excess of a polyamine component and another polyacid anhydride component having an excess of a polyacid anhydride component are formed in advance and then reacted with each other in a reactor, particularly in such a manner that a non-random or block copolymer is produced. (g)   A method in which a specific portion of the polyamine component and the polyacid anhydride component are reacted first, and then the remaining polyamine component is reacted, or vice versa. (h)   A method in which the components are added to a part or all of a solvent in any order in part or in whole, and in addition in which part or all of any component may be added as a solution in a part or all of a solvent. (i) A method in which one of the polyanhydride components is first reacted with one of the polyamine components to obtain a first polyamine. The other polyanhydride component is then reacted with the other polyamine component to obtain a second polyamine. The polyamines are then combined in any of a variety of ways prior to film formation.

Generally speaking, a polyamine solution can be obtained by any of the polyamine solution preparation methods disclosed above.

The polyimide solution may then be filtered one or more times to reduce the particle content. The polyimide film produced from such a filtered solution may exhibit a reduced number of defects and thereby produce superior performance in the electronic applications disclosed herein. An evaluation of the filtration efficiency may be performed by laser particle counter testing, wherein a representative sample of the polyimide solution is poured onto a 5" silicon wafer. After soft baking/drying, the particle content of the film is evaluated by any number of laser particle counting techniques on commercially available instruments known in the art.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content of less than 40 particles as measured by a laser particle counter test.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content of less than 30 particles as measured by a laser particle counter test.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content of less than 20 particles as measured by a laser particle counter test.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content of less than 10 particles as measured by laser particle counter testing.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content between 2 particles and 8 particles as measured by laser particle counter testing.

In some embodiments, a polyamide solution is prepared and filtered to produce a particle content between 4 particles and 6 particles as measured by laser particle counter testing.

An exemplary preparation of a polyamine solution is given in the Examples.

4. Polyimide

A polyimide obtained by imidization of the above polyimide is provided. "Imidization" means intramolecular cyclization of an amide group to form an imide group. In some embodiments, thermal imidization is used. In some embodiments, chemical imidization is used. In some embodiments, a combination of thermal imidization and chemical imidization is used.

In some embodiments, the polyimide has a repeating unit structure of Formula III: , wherein: ^Ra is the same or different at each occurrence and represents one or more tetracarboxylic acid component residues; and ^Rb is the same or different at each occurrence and represents one or more aromatic diamine residues; wherein 10-100 mol% of ^Rb is derived from the residues of one or more diamines having formula I.

All of the above-described embodiments for ^Ra and ^Rb in Formula II are equally applicable to ^Ra and ^Rb in Formula III.

Any of the above embodiments of Formula I in Formula III may be combined with one or more of the other embodiments, as long as they are not mutually exclusive.

Polyimides can be prepared from any suitable polyimide precursors such as polyamines, polyamine esters, polyisoimides, and polyamide salts.

Also provided is a polyimide membrane, wherein the polyimide has a repeating unit structure of Formula III as described above.

Polyimide films can be made by coating a polyimide precursor onto a substrate and subsequently imidizing it. This can be achieved by either a thermal conversion method or a chemical conversion method.

Furthermore, if the polyimide is soluble in a suitable coating solvent, it can be provided as an already imidized polymer dissolved in a suitable coating solvent and coated as the polyimide.

In some embodiments, a polyimide film comprising a polyimide having repeating units of Formula III has both a high glass transition temperature and a low coefficient of thermal expansion (CTE).

In some embodiments of the polyimide film, for polyimide films cured at temperatures greater than 325°C, the glass transition temperature ( _Tg ) is greater than 300°C; in some embodiments, greater than 350°C; and in some embodiments, greater than 375°C.

In some embodiments of the polyimide film, for a first measurement, the in-plane coefficient of thermal expansion (CTE) is less than 50 ppm/°C between 50°C and 200°C; in some embodiments, less than 35 ppm/°C; in some embodiments, less than 20 ppm/°C; in some embodiments, less than 15 ppm/°C.

In some embodiments of the polyimide film, for the second measurement, the in-plane coefficient of thermal expansion (CTE) is less than 50 ppm/°C between 50°C and 200°C; in some embodiments, less than 40 ppm/°C.

In some embodiments of the polyimide membrane, the 1% TGA weight loss temperature is greater than 350°C; in some embodiments, it is greater than 400°C; in some embodiments, it is greater than 450°C.

In some embodiments of the polyimide film, the tensile modulus is between 1.5 GPa and 15.0 GPa; in some embodiments, between 1.5 GPa and 10.0 GPa; in some embodiments, between 1.5 GPa and 7.5 GPa; in some embodiments, between 1.5 GPa and 5.0 GPa.

In some embodiments of the polyimide film, the elongation at break is greater than 10%.

In some embodiments of the polyimide film, the birefringence is less than 1.0; in some embodiments, less than 0.1; in some embodiments, less than 0.05.

In some embodiments of the polyimide film, the optical retardation at 550 nm is less than 500; in some embodiments, less than 400; in some embodiments, less than 350.

In some embodiments of the polyimide film, the haze is less than 1.0%; in some embodiments, it is less than 0.5%.

In some embodiments of polyimide films, b* is less than 7.5; in some embodiments, it is less than 5.0.

In some embodiments of polyimide films, the YI is less than 12; in some embodiments, it is less than 10.

In some embodiments of the polyimide film, the transmittance at 450 nm is greater than 50%; in some embodiments, greater than 80%.

In some embodiments of the polyimide film, the transmittance at 550 nm is greater than 70%; in some embodiments, greater than 80%.

In some embodiments of the polyimide film, the transmittance at 750 nm is greater than 70%; in some embodiments, greater than 80%.

Any of the above embodiments of the polyimide film may be combined with one or more of the other embodiments, as long as they are not mutually exclusive.

5. Method for preparing polyimide membrane

In general, polyimide films can be prepared from polyimide precursors by chemical or thermal conversion. In some embodiments, the films are prepared from corresponding polyamide acid solutions by chemical or thermal conversion methods. The polyimide films disclosed herein (especially when used as a flexible replacement for glass in electronic devices) are prepared by thermal conversion methods.

Generally speaking, polyimide films can be prepared from corresponding polyamide solutions by chemical or thermal conversion methods. The polyimide films disclosed herein (especially when used as a flexible replacement for glass in electronic devices) are prepared by thermal conversion or modified thermal conversion methods and chemical conversion methods.

Chemical conversion methods are described in U.S. Patent Nos. 5,166,308 and 5,298,331, which are incorporated herein by reference in their entirety. In such methods, a conversion chemical is added to a polyamide solution. Conversion chemicals found to be useful in the present invention include, but are not limited to: (i) one or more dehydrating agents, such as aliphatic anhydrides (acetic anhydride, etc.) and anhydrides; and (ii) one or more catalysts, such as aliphatic tertiary amines (triethylamine, etc.), tertiary amines (dimethylaniline, etc.), and heterocyclic tertiary amines (pyridine, picoline, isoquinoline, etc.). The anhydride dehydrating material is typically used in a slight molar excess of the amount of amide groups present in the polyamide solution. The amount of acetic anhydride used is typically about 2.0 to 3.0 moles per equivalent of polyamine. Generally, an equivalent amount of tertiary amine catalyst is used.

Thermal conversion methods may or may not employ conversion chemicals (i.e., catalysts) to convert the polyamide pouring solution into polyimide. If conversion chemicals are used, the method may be considered a modified thermal conversion method. In both types of thermal conversion methods, only heat energy is used to heat the membrane to not only dry the membrane of the solvent but also to carry out the imidization reaction. Thermal conversion methods with or without conversion catalysts are generally used to prepare the polyimide membranes disclosed herein.

The specific process parameters are pre-selected taking into account that it is not only the film composition that produces the properties of interest. Instead, the curing temperature and the temperature ramp profile also play an important role in achieving the most desirable properties for the intended use disclosed herein. The polyimide should be imidized at or above the maximum temperature of any subsequent processing step (e.g., deposition of one or more inorganic or other layers required to produce a functional display), but below the temperature at which significant thermal degradation/discoloration of the polyimide occurs. It should also be noted that an inert atmosphere is generally preferred, particularly when a higher processing temperature is used for imidization.

For the polyamides/polyimids disclosed herein, when subsequent processing temperatures exceeding 300°C are required, temperatures of 300°C to 320°C are typically employed. Selection of an appropriate cure temperature allows for a fully cured polyimide that achieves an optimal balance of thermal and mechanical properties. Due to such very high temperatures, an inert atmosphere is required. Typically, furnace oxygen levels of >100 ppm should be employed. Very low oxygen levels enable the use of the highest cure temperatures without significant degradation/discoloration of the polymer. Catalysts that accelerate the imidization process are effective in achieving higher levels of imidization at cure temperatures between about 200°C and 300°C. This approach may be employed as desired if the flexible device is prepared at a higher cure temperature below the _Tg of the polyimide.

The amount of time for each possible cure step is also an important process consideration. Generally speaking, the time used for the highest temperature cure should be kept to a minimum. For example, for a 320°C cure, the cure time can be as long as an hour or so under an inert atmosphere; but at higher cure temperatures, this time should be shortened to avoid thermal degradation. Generally speaking, higher temperatures dictate shorter times. Those of ordinary skill in the art will recognize the balance between temperature and time in order to optimize the properties of the polyimide for a particular end use.

In some embodiments, the polyamide solution is converted into the polyimide film by a thermal conversion method.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is less than 50 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is less than 40 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is less than 30 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is less than 20 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is between 10 μm and 20 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is between 15 μm and 20 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate so that the soft-baked thickness of the resulting film is 18 μm.

In some embodiments of the thermal conversion method, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is less than 10 μm.

In some embodiments of the thermal conversion method, the coated substrate is soft baked in proximity mode on a hot plate, where nitrogen is used to hold the coated substrate just above the hot plate.

In some embodiments of the thermal conversion method, the coated substrate is soft baked on a hot plate in full contact mode, where the coated substrate is in direct contact with the hot plate surface.

In some embodiments of the thermal conversion method, the coated substrate is soft baked on a hot plate using a combination of proximity mode and full contact mode.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 80°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 90°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 100°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 110°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 120°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 130°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked using a hot plate set at 140°C.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of more than 10 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of less than 10 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of less than 8 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of less than 6 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of 4 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of less than 4 minutes.

In some embodiments of the thermal conversion method, the coated substrate is soft baked for a total time of less than 2 minutes.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at two preselected temperatures for two preselected time intervals, where the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 3 preselected temperatures for 3 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at four preselected temperatures for four preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 5 preselected temperatures for 5 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 6 preselected temperatures for 6 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 7 preselected temperatures for 7 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 8 preselected temperatures for 8 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 9 preselected temperatures for 9 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the soft baked coated substrate is then cured at 10 preselected temperatures for 10 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 80°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 100°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 100°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 150°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 150°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 200°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 200°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 250°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 250°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 300°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 300°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 350°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 350°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 400°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 400°C.

In some embodiments of the thermal conversion method, the preselected temperature is equal to 450°C.

In some embodiments of the thermal conversion method, the preselected temperature is greater than 450°C.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 2 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 5 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 10 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 15 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 20 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 25 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 30 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 35 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 40 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 45 minutes.

In some of the thermal conversion methods, one or more of the preselected time intervals is 50 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 55 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is 60 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is greater than 60 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 60 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 90 minutes.

In some embodiments of the thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 120 minutes.

In some embodiments of the thermal conversion method, the method for preparing a polyimide film comprises the following steps in order: coating the polyamide solution described above onto a substrate; soft baking the coated substrate; treating the soft baked coated substrate at a plurality of preselected temperatures for a plurality of preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

In some embodiments of the thermal conversion method, the method for preparing a polyimide film consists of the following steps in sequence: coating the polyamide solution described above onto a substrate; soft baking the coated substrate; treating the soft baked coated substrate at multiple preselected temperatures for multiple preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

In some embodiments of the thermal conversion method, the method for preparing a polyimide film mainly consists of the following steps in sequence: coating the polyamide solution described above onto a substrate; soft-baking the coated substrate; treating the soft-baked coated substrate at multiple preselected temperatures for multiple preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

Typically, the polyamide solution/polyimide disclosed herein is coated/cured onto a supporting glass substrate to facilitate processing during the rest of the display manufacturing process. At some point in the process determined by the display manufacturer, the polyimide coating is removed from the supporting glass substrate by a mechanical or laser stripping process. These processes separate the polyimide from the glass as a film with the deposited display layer and achieve a flexible form. Typically, the polyimide film with the deposited layer is then bonded to a thicker but still flexible plastic film to provide support for subsequent display manufacturing.

Also provided are improved thermal conversion processes wherein the conversion catalyst generally permits the imidization reaction to proceed at lower temperatures than would be possible in the absence of such conversion catalyst.

In some embodiments, the polyamide solution is converted into a polyimide film via a modified thermal conversion method.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains a conversion catalyst selected from the group consisting of tertiary amines.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains a conversion catalyst selected from the group consisting of tributylamine, dimethylethanolamine, isoquinoline, 1,2-dimethylimidazole, N-methylimidazole, 2-methylimidazole, 2-ethyl-4-imidazole, 3,5-lutidine, 3,4-lutidine, 2,5-lutidine, 5-methylbenzimidazole, etc.

In some embodiments of the improved thermal conversion process, the conversion catalyst is present at 5 wt % or less of the polyamide solution.

In some embodiments of the improved thermal conversion process, the conversion catalyst is present at 3 wt % or less of the polyamide solution.

In some embodiments of the improved thermal conversion process, the conversion catalyst is present at 1 wt % or less of the polyamine solution.

In some embodiments of the improved thermal conversion process, the conversion catalyst is present at 1 wt % of the polyamine solution.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains tributylamine as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamic acid solution further contains dimethylethanolamine as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains isoquinoline as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 1,2-dimethylimidazole as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 3,5-lutidine as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 5-methylbenzimidazole as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains N-methylimidazole as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 2-methylimidazole as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 2-ethyl-4-imidazole as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 3,4-lutidine as a conversion catalyst.

In some embodiments of the improved thermal conversion method, the polyamine solution further contains 2,5-lutidine as a conversion catalyst.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto a substrate such that the soft-baked thickness of the resulting film is less than 50 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto a substrate such that the soft-baked thickness of the resulting film is less than 40 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto a substrate such that the soft-baked thickness of the resulting film is less than 30 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto a substrate such that the resulting film has a soft-baked thickness of less than 20 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is between 10 μm and 20 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is between 15 μm and 20 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto the substrate such that the soft-baked thickness of the resulting film is 18 μm.

In some embodiments of the improved thermal conversion process, the polyamide solution is coated onto a substrate such that the resulting film has a soft-baked thickness of less than 10 μm.

In some embodiments of the improved thermal conversion method, the coated substrate is soft baked in proximity mode on a hot plate, where nitrogen is used to hold the coated substrate just above the hot plate.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked on a hot plate in full contact mode, wherein the coated substrate is in direct contact with the hot plate surface.

In some embodiments of the improved thermal conversion method, the coated substrate is soft-baked on a hot plate using a combination of proximity mode and full contact mode.

In some embodiments of the improved thermal conversion process, the coated substrate is soft-baked using a hot plate set at 80°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft-baked using a hot plate set at 90°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft-baked using a hot plate set at 100°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked using a hot plate set at 110°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft-baked using a hot plate set at 120°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked using a hot plate set at 130°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked using a hot plate set at 140°C.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of more than 10 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of less than 10 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of less than 8 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of less than 6 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of 4 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of less than 4 minutes.

In some embodiments of the improved thermal conversion process, the coated substrate is soft baked for a total time of less than 2 minutes.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at two preselected temperatures for two preselected time intervals, where the time intervals can be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at three preselected temperatures for three preselected time intervals, wherein each of the time intervals may be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at four preselected temperatures for four preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at 5 preselected temperatures for 5 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at six preselected temperatures for six preselected time intervals, wherein each of the time intervals may be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at 7 preselected temperatures for 7 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at 8 preselected temperatures for 8 preselected time intervals, wherein each of the time intervals may be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at 9 preselected temperatures for 9 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the improved thermal conversion process, the soft baked coated substrate is then cured at 10 preselected temperatures for 10 preselected time intervals, where each of the time intervals can be the same or different.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 80°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 100°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 100°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 150°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 150°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 200°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 200°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 220°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 220°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 230°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 230°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 240°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 240°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 250°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 250°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 260°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 260°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 270°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 270°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 280°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 280°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 290°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is greater than 290°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is equal to 300°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 300°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 290°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 280°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 270°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 260°C.

In some embodiments of the improved thermal conversion method, the preselected temperature is less than 250°C.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 2 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 5 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 10 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 15 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 20 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 25 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 30 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 35 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 40 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 45 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 50 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 55 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is 60 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is greater than 60 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 60 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 90 minutes.

In some embodiments of the improved thermal conversion method, one or more of the preselected time intervals is between 2 minutes and 120 minutes.

In some embodiments of the improved thermal conversion method, the method for preparing a polyimide film comprises the following steps in sequence: coating the polyamide solution containing the conversion chemical described above onto a substrate; soft baking the coated substrate; treating the soft baked coated substrate at a plurality of preselected temperatures for a plurality of preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

In some embodiments of the improved thermal conversion method, the method for preparing a polyimide film consists of the following steps in sequence: coating the polyamide solution containing the conversion chemical described above onto a substrate; soft baking the coated substrate; treating the soft baked coated substrate at multiple preselected temperatures for multiple preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

In some embodiments of the improved thermal conversion method, the method for preparing a polyimide film consists essentially of the following steps in sequence: coating the polyamide solution containing the conversion chemical described above onto a substrate; soft baking the coated substrate; treating the soft baked coated substrate at a plurality of preselected temperatures for a plurality of preselected time intervals, whereby the polyimide film exhibits properties that meet those electronic applications disclosed herein.

6. Electronic devices

The polyimide films disclosed herein can be applied to multiple layers in electronic display devices such as OLED and LCD displays. Non-limiting examples of such layers include device substrates, touch panels, substrates for color filters, cover films, etc. The property requirements of the specific materials of each application are unique and can be solved by one or more appropriate compositions and one or more processing conditions of the polyimide films disclosed herein.

In some embodiments, a flexible replacement for glass in electronic devices is a polyimide film comprising a polyimide having repeating units of Formula III as described in detail above.

In some embodiments, an organic electronic device is provided having at least one layer comprising a polyimide film having repeating units of Formula III as described in detail above.

Organic electronic devices that may benefit from having one or more layers comprising at least one compound as described herein include, but are not limited to: (1) devices that convert electrical energy into radiation (e.g., LEDs, LED displays, lighting devices, light sources, or diode lasers), (2) devices that detect signals by electronic means (e.g., photodetectors, photoconductive cells, photoresistors, photorelays, phototransistors, phototubes, IR detectors, biosensors), (3) devices that convert radiation into electrical energy (e.g., photovoltaic devices or solar cells), (4) devices that convert light of one wavelength into light of a longer wavelength (e.g., down-converting phosphor devices); and (5) A device comprising one or more electronic components, the one or more electronic components comprising one or more organic semiconductor layers (e.g., transistors or diodes). Other uses of the composition according to the invention include coating materials for memory storage devices, antistatic films, biosensors, electrochromic devices, solid electrolytic capacitors, energy storage devices (such as rechargeable batteries) and electromagnetic shielding applications.

An illustration of a polyimide film that can serve as a flexible alternative to glass as described herein is shown in FIG. 1 . The flexible film 100 can have properties as described in the embodiments of the present disclosure. In some embodiments, the polyimide film that can serve as a flexible alternative to glass is included in an electronic device. FIG. 2 illustrates the case where the electronic device 200 is an organic electronic device. The device 200 has a substrate 100, an anode layer 110 and a second electrical contact layer, a cathode layer 130, and a photoactive layer 120 therebetween. Additional layers may be present as desired. Adjacent to the anode may be a hole injection layer (not shown), sometimes referred to as a buffer layer. Adjacent to the hole injection layer may be a hole transport layer (not shown) containing a hole transport material. Adjacent to the cathode may be an electron transport layer (not shown) containing electron transport material. Alternatively, the device may use one or more additional hole injection layers or hole transport layers (not shown) adjacent to the anode 110 and/or one or more additional electron injection layers or electron transport layers (not shown) adjacent to the cathode 130. The layers between 110 and 130 are individually and collectively referred to as organic active layers. Additional layers that may or may not be present include color filters, touch panels, and/or guard plates. One or more of the layers (in addition to the substrate 100) may also be made of the polyimide film disclosed herein.

These different layers will be discussed further herein with reference to Figure 2. However, the discussion applies equally to other configurations.

In some embodiments, the different layers have the following thickness ranges: substrate 100, 5-100 microns, anode 110, 500-5000 Å, in some embodiments, 1000-2000 Å; hole injection layer (not shown), 50-2000 Å, in some embodiments, 200-1000 Å; hole transport layer (not shown), 50-3000 Å, in some embodiments, 200-2000 Å; photoactive layer 120, 10-2000 Å, in some embodiments, 100-1000 Å; electron transport layer (not shown), 50-2000 Å, in some embodiments, 100-1000 Å; cathode 130, 200-10000 Å Å, in some embodiments, 300-5000 Å. The desired ratio of layer thicknesses will depend on the exact nature of the materials used.

In some embodiments, an organic electronic device (OLED) contains a flexible replacement for glass as disclosed herein.

In some embodiments, an organic electronic device is provided, wherein the device substrate comprises a polyimide film disclosed herein. In some embodiments, the device is an organic light emitting diode (OLED).

In some embodiments, the organic electronic device includes a substrate, an anode, a cathode, and a photoactive layer therebetween, and further includes one or more additional organic active layers. In some embodiments, the additional organic active layer is a hole transport layer. In some embodiments, the additional organic active layer is an electron transport layer. In some embodiments, the additional organic active layer is both a hole transport layer and an electron transport layer.

Anode 110 is an electrode that is particularly effective for injecting positive charge carriers. It can be made of materials such as metals, mixed metals, alloys, metal oxides or mixed metal oxides, or it can be a conductive polymer, and mixtures thereof. Suitable metals include Group 11 metals, metals in Groups 4, 5 and 6, and transition metals in Groups 8 to 10. If the anode is to be light-transmitting, mixed metal oxides of Groups 12, 13 and 14 metals are generally used, such as indium tin oxide. The anode can also contain organic materials such as polyaniline, as described in "Flexible light-emitting diodes made from soluble conducting polymer", Nature, Vol. 357, pp. 477-479 (June 11, 1992). At least one of the anode and cathode should be at least partially transparent to allow the generated light to be observed.

The optional hole injection layer may include a hole injection material. The term "hole injection layer" or "hole injection material" is intended to refer to a conductive or semiconductive material and may have one or more functions in an organic electronic device, including but not limited to planarization of underlying layers, charge transport and/or charge injection properties, removal of impurities such as oxygen or metal ions, and other aspects that are beneficial or improve the performance of the organic electronic device. The hole injection material may be a polymer, oligomer, or small molecule and may be in the form of a solution, dispersion, suspension, emulsion, colloidal mixture, or other composition.

The hole injection layer 120 may be formed of a polymer material, such as polyaniline (PANI) or polyethylenedioxythiophene (PEDOT), which is typically doped with a protonic acid. The protonic acid may be, for example, poly(styrenesulfonic acid), poly(2-acrylamido-2-methyl-1-propanesulfonic acid), etc. The hole injection layer 120 may include a charge transfer compound, such as copper phthalocyanine and tetrathiafulvalene-tetracyanoquinodimethane system (TTF-TCNQ). In some embodiments, the hole injection layer 120 is made of a dispersion of a conductive polymer and a colloid-forming polymer acid. Such materials have been described in, for example, published U.S. Patent Applications 2004-0102577, 2004-0127637, and 2005-0205860.

Other layers may include hole transport materials. Examples of hole transport materials for hole transport layers are summarized in, for example, Kirk-Othmer Encyclopedia of Chemical Technology by Y. Wang, 4th edition, Vol. 18, pp. 837-860, 1996. Both hole transport small molecules and polymers may be used. Commonly used hole transport molecules include, but are not limited to: 4,4',4"-tris(N,N-diphenyl-amino)-triphenylamine (TDATA); 4,4',4"-tris(N-3-methylphenyl-N-phenyl-amino)-triphenylamine (MTDATA); N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine (TPD); 4,4'-bis( Carbazole-9-yl) biphenyl (CBP); 1,3-bis(carbazole-9-yl)benzene (mCP); 1,1-bis[(di-4-methylphenylamino)phenyl]cyclohexane (TAPC); N,N'-bis(4-methylphenyl)-N,N'-bis(4-ethylphenyl)-[1,1'-(3,3'-dimethyl)biphenyl]-4,4'-diamine (ETPD); tetrakis-(3-methylphenyl)-N,N, N’,N’-2,5-phenylenediamine (PDA); α-phenyl-4-N,N-diphenylaminostyrene (TPS); p-(diethylamino)benzaldehyde diphenylhydrazone (DEH); triphenylamine (TPA); bis[4-(N,N-diethylamino)-2-methylphenyl](4-methylphenyl)methane (MPMP); 1-phenyl-3-[p-(diethylamino)styryl]-5-[p-(diphenylamine)phenyl]- [0013] The hole transporting polymers used herein include, but are not limited to, polyvinylcarbazole, (phenylmethyl)polysilane, poly(dioxythiophene), polyaniline, and polypyrrole. It is also possible to obtain hole transporting polymers by incorporating hole transporting molecules such as those mentioned above into polymers such as polystyrene and polycarbonate. In some cases, triarylamine polymers are used, especially triarylamine-fluorene copolymers. In some cases, the polymers and copolymers are crosslinkable. Examples of crosslinkable hole transport polymers can be found, for example, in published U.S. Patent Application 2005-0184287 and published PCT Application WO 2005/052027. In some embodiments, the hole transport layer is doped with a p-type dopant, such as tetrafluorotetracyanoquinodimethane and perylene-3,4,9,10-tetracarboxyl-3,4,9,10-dianhydride.

Depending on the application of the device, the photoactive layer 120 can be a light-emitting layer activated by an applied voltage (such as in a light-emitting diode or a photoelectric electrochemical cell), a material layer that absorbs light and emits light with a longer wavelength (such as in a down-conversion phosphor device), or a material layer that reacts to radiant energy and generates a signal with or without an applied bias (such as in a photodetector or a photovoltaic device).

In some embodiments, the photoactive layer comprises a compound comprising an emissive compound as a photoactive material. In some embodiments, the photoactive layer further comprises a host material. Examples of host materials include, but are not limited to, chrysene, phenanthrene, triphenylene, phenanthroline, naphthalene, anthracene, quinoline, isoquinoline, quinoline, phenylpyridine, carbazole, indolecarbazole, furan, benzofuran, dibenzofuran, benzodifuran, and metal quinoline complexes. In some embodiments, the host material is deuterated.

In some embodiments, the photoactive layer comprises (a) a dopant capable of electroluminescence having an emission maximum between 380 and 750 nm, (b) a first host compound, and (c) a second host compound. Suitable second host compounds are described above.

In some embodiments, the photoactive layer includes only (a) a dopant capable of electroluminescence having an emission maximum between 380 and 750 nm, (b) a first host compound, and (c) a second host compound, wherein there are no additional materials present that would substantially change the operating principle or distinguishing characteristics of the layer.

In some embodiments, the first subject is present at a higher concentration than the second subject based on weight in the photoactive layer.

In some embodiments, the weight ratio of the first subject to the second subject in the photoactive layer is in the range of 10:1 to 1:10. In some embodiments, the weight ratio is in the range of 6:1 to 1:6; in some embodiments, 5:1 to 1:2; in some embodiments, 3:1 to 1:1.

In some embodiments, the weight ratio of the dopant to the total host is in the range of 1:99 to 20:80; in some embodiments, in the range of 5:95 to 15:85.

In some embodiments, the photoactive layer includes (a) a red-emitting dopant, (b) a first host compound, and (c) a second host compound.

In some embodiments, the photoactive layer includes (a) a green-light-emitting dopant, (b) a first host compound, and (c) a second host compound.

In some embodiments, the photoactive layer includes (a) a yellow-emitting dopant, (b) a first host compound, and (c) a second host compound.

The optional layer can simultaneously function to promote electron transport and also act as a confining layer to prevent exciton quenching at the layer interface. Preferably, the layer promotes electron mobility and reduces exciton quenching.

In some embodiments, such layers include other electron transport materials. Examples of electron transport materials that can be used in the optional electron transport layer include metal chelated oxinoid compounds, including metal quinolate derivatives such as tris(8-hydroxyquinolinato)aluminum (AlQ), bis(2-methyl-8-hydroxyquinolinato)(p-phenylphenol)aluminum (BAlq), tetrakis(8-hydroxyquinolinato)eum (HfQ) and tetrakis(8-hydroxyquinolinato)zirconium (ZrQ); and azole compounds such as 2-(4-biphenyl)-5-(4-tert-butylphenyl)-1, 3,4-diazole (PBD), 3-(4-biphenyl)-4-phenyl-5-(4-tert-butylphenyl)-1,2,4-triazole (TAZ) and 1,3,5-tri(phenyl-2-benzimidazole)benzene (TPBI); quinoline derivatives, such as 2,3-bis(4-fluorophenyl)quinoline; phenanthene, such as 4,7-diphenyl-1,10-phenanthene (DPA) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthene (DDPA); trioxane; fullerene; and mixtures thereof. In some embodiments, the electron transport material is selected from the group consisting of metal quinoline salts and phenanthene derivatives. In some embodiments, the electron transport layer further comprises an n-type dopant. N-type dopant materials are well known. n-type dopants include, but are not limited to, Group 1 and Group 2 metals; Group 1 and Group 2 metal salts, such as LiF, CsF, and Cs ₂ CO ₃ ; Group 1 and Group 2 metal organic compounds, such as lithium quinolate; and molecular n-type dopants, such as stealth dyes, metal complexes, such as W ₂ (hpp) ₄ (wherein hpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido-[1,2-a]-pyrimidine) and cobalt cyclopentadienyl, tetrathiacene, bis(ethylenedithio)tetrathiafulvalene, heterocyclic groups or divalent groups, and dimers, oligomers, polymers, dispiro compounds, and polycyclic compounds of heterocyclic groups or divalent groups.

An optional electron injection layer may be deposited over the electron transport layer. Examples of electron injection materials include, but are not limited to, organometallic compounds containing Li, LiF, _Li2O , lithium quinolate; organometallic compounds containing Cs, CsF, _Cs2O , and _Cs2CO3 . This layer may react with the underlying electron transport layer, the overlying cathode, or both. When an electron injection layer is present, the amount of material deposited is typically in the range of 1-100 _Å , in some embodiments 1-10 Å.

The cathode 130 is an electrode that is particularly effective for injecting electrons or negative charge carriers. The cathode can be any metal or non-metal having a work function lower than that of the anode. The material for the cathode can be selected from the alkali metals of Group 1 (e.g., Li, Cs), Group 2 (alkaline earth) metals, Group 12 metals, including rare earth elements and ytterbium, and ytterbium. Materials such as aluminum, indium, calcium, barium, samarium, and magnesium, and combinations thereof, can be used.

It is known to have other layers in organic electronic devices. For example, there may be multiple layers (not shown) between the anode 110 and the hole injection layer (not shown) to control the amount of positive charge injected and/or provide bandgap matching of the layers, or to serve as a protective layer. Layers known in the art, such as ultra-thin layers of copper phthalocyanine, silicon oxynitride, fluorocarbons, silanes, or metals (such as Pt) may be used. Alternatively, some or all of the anode layer 110, active layer 120, or cathode layer 130 may be surface treated to increase charge carrier transport efficiency. It is preferred to determine the selection of materials for each component layer by balancing the positive and negative charges in the emitter layer to provide a device with high electroluminescent efficiency.

It should be understood that each functional layer may be composed of more than one layer.

The device layer can generally be formed by any deposition technique or combination of techniques, including vapor deposition, liquid deposition, and thermal transfer. Substrates such as glass, plastic, and metal can be used. Conventional vapor deposition techniques such as thermal evaporation, chemical vapor deposition, etc. can be used. The organic layer can be applied from a solution or dispersion in a suitable solvent using conventional coating or printing techniques, including but not limited to coating, dip coating, roll-to-roll technology, inkjet printing, continuous nozzle printing, screen printing, gravure printing, etc.

For liquid phase precipitation methods, one of ordinary skill in the art can readily determine the appropriate solvent for a particular compound or related class of compounds. For some applications, it is desirable that the compounds be dissolved in a non-aqueous solvent. Such non-aqueous solvents may be relatively polar, such as _C1 to _C20 alcohols, ethers, and acid esters, or may be relatively non-polar, such as _C1 to _C12 alkanes or aromatic compounds such as toluene, xylene, trifluorotoluene, and the like. Other suitable liquids for making liquid compositions comprising the novel compounds (as solutions or dispersions as described herein) include, but are not limited to, chlorinated hydrocarbons (e.g., dichloromethane, chloroform, chlorobenzene), aromatic hydrocarbons (e.g., substituted and unsubstituted toluenes and xylenes, including trifluorotoluene), polar solvents (e.g., tetrahydrofuran (THP), N-methylpyrrolidone), esters (e.g., ethyl acetate), alcohols (isopropanol), ketones (cyclopentanone), and mixtures thereof. Suitable solvents for electroluminescent materials have been described, for example, in published PCT application WO 2007/145979.

In some embodiments, the device is made by liquid deposition of a hole injection layer, a hole transport layer, and a photoactive layer, and by vapor deposition of an anode, an electron transport layer, an electron injection layer, and a cathode onto a flexible substrate.

It should be understood that the efficiency of the device can be improved by optimizing other layers in the device. For example, more efficient cathodes such as Ca, Ba, or LiF can be used. Shaped substrates and new hole transport materials that result in lower operating voltages or increased quantum efficiency are also applicable. Additional layers can also be added to tailor the energy levels of various layers and promote electroluminescence.

In some embodiments, the device has the following structures in order: substrate, anode, hole injection layer, hole transport layer, photoactive layer, electron transport layer, electron injection layer, cathode.

Although methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, suitable methods and materials are described below. In addition, the materials, methods, and examples are illustrative only and are not intended to be limiting. All publications, patent applications, patents, and other references mentioned herein are incorporated herein by reference in their entirety.

Examples

The concepts described herein will be further illustrated in the following examples, which do not limit the scope of the invention described in the patent application.

Example 1

This example illustrates the preparation of a diamine having formula I (compound 4).

(a) 2,6-Bis(4-amino-2-trifluoromethylphenyl)anthracene (3) .

A mixture of 2,6-bis-Bpin anthracene 1 (14.5 g, 33.71 mmol), 4-bromo-3-(trifluoromethyl)aniline 2 (24.27 g, 101.13 mmol), Pd(PPh ₃ ) ₄ (3.9 g, 3.37 mmol) and potassium carbonate (23.29 g, 169 mmol) in toluene (400 ml), ethanol (200 ml) and water (80 ml) was degassed and stirred under a nitrogen atmosphere for 3 days while heating at 85° C. The product 3 (9.7 g) precipitated from the reaction mixture was collected by hot filtration. The filtrate was cooled and the precipitate was collected by filtration to yield 3.2 g of a product with a lower purity. ¹ H-NMR (DMSO-d ₆ , 500 MHz): 5.69 (s, 4H), 6.88 (dd, 2H, J1 = 2 Hz, J2 = 8 Hz), 7.03 (d, 2H, J = 2 Hz), 7.18 (d, 2H, J = 8 Hz), 7.40 (d, 2H, J = 9 Hz ), 7.92 (s, 2H), 8.05 (d, 2H, J = 9 Hz), 8.58 (s, 2H).

(b) 6,14-Bis(4-amino-2-trifluoromethylphenyl)-3a,4,9,9a-tetrahydro-2-phenyl-4,9[1’,2’]-benzo-1H-benzo[f]isoindole-1,3(2H)-dione (Compound 4).

A mixture of product 3 (7.637 g, 15.38 mmol), N-phenylmaleimide (7.96 g, 45.97 mmol) was heated in 1,2-dichlorobenzene (100 ml) at 150 ° C. under a nitrogen atmosphere for 1.5 hours. After that, an additional amount of maleimide (4.6 g) was added, and the mixture was heated at the same temperature for 1 hour. The reaction mixture was cooled, the solvent was evaporated using a rotary evaporator, and the residue was subjected to chromatography on a silica gel column using a gradient elution with dichloromethane and a dichloromethane-acetone mixture. The product containing fractions were collected and the eluent was evaporated to yield 6.41 g of diamine compound 4 which could be further purified by crystallization from a mixture of dichloromethane and hexane. ¹ H-NMR (DMSO-d ₆ , 500 MHz): 3.41 (dd, 1H, J1 = 4 Hz, J2 = 9 Hz), 3.47 (dd, 1H, J1 = 4 Hz, J2 = 9 Hz), 4.91 (t, 2H, J = 4 Hz), 5.62 (s, 4H), 6.53-6.5 5 (m, 2H), 6.78 (td, 2H, J1 = 2Hz, J2 = 8 Hz), 6.89 (d, 1H, J = 8 Hz), 6.95 (dd, 2H, J1 = 2 Hz, J2 = 8 Hz), 7.02 (d, 1H, J = 8 Hz), 7.06 (d, 1H, J = 8 Hz), 7.10 (d, 1H, J = 8 Hz), 7.18 (s, 1H), 7.30 (d, 1H, J = 8 Hz), 7.32-7.33 (m, 3H), 7.41 (s, 1H), 7.49 (d, 1H, J = 8 Hz). ¹³ C-NMR (DMSO-d ₆ , 125 MHz, restricted isomers): 176.35, 176.25, 148.83, 148.78, 141.7, 140.7, 139.4, 139.2, 138.9, 138.3, 133.64, 133.6, 132.3, 129.13, 128.9, 127.9, 127.7, 127.5, 127.4, 127.11, 127.0, 126.0, 125.5, 124.7, 124.2, 123.8, 123.7, 117.0, 110.87, 110.83, 55.4, 47.22, 47.17, 45.0. ¹⁹ F-NMR (DMSO-d ₆ , 470 MHz, restricted conformational isomers): 55.27, 55.35.

Example 2

This example illustrates the preparation of a liquid composition comprising a polyamine having Formula II.

Diamine compound 4 (4.5 g, 6.72 mmol), BPDA (2.768 g, 9.408 mmol), PMDA (0.293 g, 1.344 mmol), TFMB (2.152 g, 6.72 mmol) and N-methylpyrrolidone (62 g) were reacted at ambient temperature, followed by the addition of PMDA (45 mg) in portions. NMP was partially distilled off to a final polymer content of 21 wt% and a viscosity of 27390 cP. GPC: Mn = 96941, Mw = 203561, Mp = 195824, Mz = 324327, PDI = 2.10.

Example 3

This example illustrates the preparation of a polyimide membrane, wherein the polyimide has Formula III.

The polyimide solution from Example 2 was filtered through a microfilter, spun onto a clean silicon wafer, soft-baked on a hot plate at 90°C, and placed in a furnace. The furnace was purged with nitrogen and heated to a maximum temperature of 320°C. The wafer was removed from the furnace, soaked in water, and manually layered to produce a polyimide film sample.

The polyimide film with a thickness of 8.62 µm has the following properties: Haze: 0.19 % T _g : 327°C CTE (first measurement): 34.1 ppm/°C Birefringence (633 nm): 0.042 Tensile modulus: 4.77 GPa Tensile strength: 198.7 MPa Elongation at break: 24.6 % 1% TGA loss: 415°C Optical retardation: 369

It should be noted that not all of the activities described above in the general description or examples are required, that a portion of a specific activity may not be required, and that one or more other activities may be performed in addition to those described. Furthermore, the order in which the activities are listed is not necessarily the order in which they are performed.

In the foregoing description, the concepts have been described with reference to specific embodiments. However, one skilled in the art may make various modifications and changes without departing from the scope of the invention as set forth in the following claims. Therefore, the description and the accompanying drawings should be regarded as illustrative rather than restrictive, and all such modifications are intended to be included within the scope of the invention.

Benefits, other advantages, and solutions to problems have been described above with respect to specific embodiments. However, benefits, advantages, solutions to problems, and any one or more features that may cause any benefit, advantage, or solution to appear or become more obvious are not to be construed as key, necessary, or essential features of any or all claims.

It is to be understood that, for the sake of clarity, certain features described herein in the context of a separate embodiment may also be provided in a single embodiment in combination. Conversely, for the sake of brevity, each feature described in the context of a single embodiment may also be provided individually or in any sub-combination. The use of numerical values within each range specified herein is expressed as an approximation, just as both the minimum and maximum values within the range are preceded by the word "about". In this way, slight variations above and below the range may be used to achieve substantially the same results as the values within the range. Moreover, the disclosure of such ranges is intended as a continuous range of each value included between the minimum and maximum averages, including fractional values that may be generated when some components of a value are mixed with components of different values. In addition, when disclosing wider and narrower ranges, it is within the expectation of the present invention to match the minimum value from one range with the maximum value from another range, and vice versa.

without

Embodiments are illustrated in the accompanying drawings to improve understanding of the concepts as presented herein.

FIG. 1 includes an illustration of one example of a polyimide film that can serve as a flexible alternative to glass.

FIG. 2 includes an illustration of an example of an electronic device including a flexible alternative to glass.

A skilled person in the art will appreciate that the objects in the drawings are shown for simplicity and clarity and are not necessarily drawn to scale. For example, the size of some objects in the drawings may be exaggerated relative to other objects to help improve understanding of the embodiments.

Claims (9)

A polyamine having formula I:

wherein: ^Q1 is selected from the group consisting of H, ^R1 , and ^R9 ; ^Q2 is selected from the group consisting of H, ^R2 , and ^R9 ; ^Q3 is selected from the group consisting of ^R3 and ^R9 ; ^Q4 is selected from the group consisting of ^R4 and ^R9 ; ^Q5 is selected from the group consisting of ^R7 and ^R9 ; ^R1 and ^R2 are the same or different at each occurrence and are selected from the group consisting of: F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; ^R3 , ^R4 , ^R5 , ^R6 , and R ^{R 7} is the same or different and is selected from the group consisting of H, F, CN, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, silyl, silalkoxy, unsubstituted or substituted alkaryl, unsubstituted or substituted heteroaryl, and unsubstituted or substituted aryloxy; R ⁸ is selected from the group consisting of alkylene, silylene, unsubstituted or substituted alkaryl, and unsubstituted or substituted heteroaryl; R ⁹ is the same or different at each occurrence and is selected from the group consisting of NH ₂ and ArNH; Ar is the same or different at each occurrence and is unsubstituted or substituted C ₆ alkaryl; and a and b are the same or different and are integers from 0 to 3; with the premise that at least two of Q ¹ to Q ⁵ are R ⁹ , wherein the polyamine does not include diamine 2 to diamine 4 represented by the following formula:

The polyamine of claim 1, which has the formula IA:

wherein R ¹ -R ⁹ , a and b are as defined in claim 1. The polyamine of claim 1, which has the formula IB:

wherein R ¹ , R ² , R ⁵ -R ⁹ , a and b are as defined in claim 1. The polyamine of claim 1, having the formula IC:

wherein R ¹ to R ⁶ , R ⁸ , R ⁹ , a and b are as defined in claim 1. A polyamine having repeating units of formula II:

wherein: ^Ra is the same or different at each occurrence and represents one or more tetracarboxylic acid component residues; and ^Rb is the same or different at each occurrence and represents one or more aromatic diamine residues; wherein 10 to 100 mol % of ^Rb is derived from one or more diamine residues of a polyamine having formula I as claimed in claim 1. A liquid composition comprising (a) the polyamine as claimed in claim 5, and (b) a high boiling point aprotic solvent. A polyimide having repeating units of formula III:

wherein: ^Ra is the same or different at each occurrence and represents one or more tetracarboxylic acid component residues; and ^Rb is the same or different at each occurrence and represents one or more aromatic diamine residues; wherein 10 to 100 mol % of ^Rb is derived from one or more diamine residues of a polyamine having formula I as claimed in claim 1. An organic electronic device having at least one layer, wherein the at least one layer comprises a polyimide film having repeating units of formula III as in claim 7. An organic electronic device as claimed in claim 8, wherein the layer is used in a device component selected from the group consisting of: a device substrate, a color filter substrate, a cover film, and a touch screen panel.

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